Fluorine-containing Monomer Contains F And C Only Or Only F, C, And H Patents (Class 524/545)
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Patent number: 7754836Abstract: Disclosed is a water- and oil-repellent agent comprising the following fluorine-containing copolymer (A). The fluorine-containing copolymer (A) comprises: (a1) a fluoroalkyl group-containing polymerizable monomer of the formula: wherein Y is a divalent organic group [for example, an aliphatic group having 1 to 10 carbon atoms, an aromatic or cycloaliphatic group having 6 to 10 carbon atoms, a —SO2N(R1)R2— group (in which R1 is a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and R2 is an alkylene group having 1 to 10 carbon atoms), a —CON(R1)R2— group (in which R1 is a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and R2 is an alkylene group having 1 to 10 carbon atoms), or a —CH2CH(OY1)CH2— group (in which Y1 is a hydrogen atom or an acyl group having 1 to 4 carbon atoms)]; and Rf is a linear or branched fluoroalkyl or fluoroalkenyl group having 1 to 6 carbon atoms; and (a2) vinylidene chloride.Type: GrantFiled: August 30, 2006Date of Patent: July 13, 2010Assignee: Daikin Industries, Ltd.Inventor: Masato Kashiwagi
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Patent number: 7754121Abstract: A material comprising aerogel particles and a polytetrafluoroethylene (PTFE) binder is formed having a thermal conductivity of less than or equal to 25 mW/m K at atmospheric conditions. The material is moldable or formable, having little or no shedding of filler particles, and may be formed into structures such as tapes or composites, for example, by bonding the material between two outer layers. Advantageously, composites may be flexed, stretched, or bent without significant dusting or loss of insulating properties.Type: GrantFiled: April 5, 2007Date of Patent: July 13, 2010Assignee: Gore Enterprise Holdings, Inc.Inventors: Cedomila Ristic-Lehmann, Brian Farnworth, Anita Dutta
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Patent number: 7754795Abstract: A coating composition having (i) an aqueous dispersion of fluoropolymer particles comprising a non-melt processible polymer of tetrafluoroethylene, (ii) a fluorinated surfactant, (iii) a non-ionic non-fluorinated surfactant and (iv) a non-fluorinated polymer, wherein the fluorinated surfactant is selected from fluorinated carboxylic acids or salts thereof of the general formula (I): [Rf—O-L-COO?]iXi+??(I) wherein L represents a linear partially or fully fluorinated alkylene group or an aliphatic hydrocarbon group, Rf represents a linear partially or fully fluorinated aliphatic group or a linear partially or fully fluorinated aliphatic group interrupted with one or more oxygen atoms, Xi+ represents a cation having the valence i and i is 1, 2 or 3.Type: GrantFiled: May 25, 2006Date of Patent: July 13, 2010Assignee: 3M Innovative Properties CompanyInventors: Klaus Hintzer, Michael Jürgens, Harald Kaspar, Herbert Koenigsmann, Kai Helmut Lochhaas, Andreas R. Maurer, Werner Schwertfeger, Tilman Zipplies, Ludwig Mayer, Michael C. Dadalas, George G. I. Moore, Jay F. Schulz, Richard M. Flynn
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Patent number: 7745530Abstract: The present invention provides an aqueous emulsion resin composition which comprises: (a) a resin composition containing at least one fluoroolefin polymer having crosslinkable group(s) at a terminus and/or a side chain of its molecule and at least one non-fluoroolefin polymer having crosslinkable group(s) at a terminus and/or a side chain of its molecule; and (b) at least one curing agent selected from the group consisting of isocyanates, melamines, hydrazides, carbodiimides, silanes and epoxides; and provides an aqueous emulsion resin compositions containing at least one chemically bonded product of a fluoroolefin polymer and a non-fluoroolefin polymer bonded to each other via at least one covalent bond at a terminus and/or a side chain of the molecules wherein one or both of the fluoroolefin polymer and the non-fluoroolefin polymer have crosslinkable group(s).Type: GrantFiled: June 28, 2002Date of Patent: June 29, 2010Assignee: Daikin Industries, Ltd.Inventors: Nobuo Mitsuhata, Tsunehiko Fuwa, Susumu Wada, Keiko Kunimasa, Haruhiko Mohri, Nobuo Fukita
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Publication number: 20100152363Abstract: A process comprising polymerizing at least one fluorinated monomer in an aqueous medium containing initiator and polymerization agent to form an aqueous dispersion of particles of fluoropolymer, the polymerization agent comprising: fluoropolyether acid or salt thereof having a number average molecular weight of at least about 800 g/mol; and fluorosurfactant having the formula: [R1—On-L-A?]Y+ wherein: R1 is a linear or branched partially or fully fluorinated aliphatic group which may contain ether linkages; n is 0 or 1; L is a linear or branched alkylene group which may be nonfluorinated, partially fluorinated or fully fluorinated and which may contain ether linkages; A? is an anionic group selected from the group consisting of carboxylate, sulfonate, sulfonamide anion, and phosphonate; and Y+ is hydrogen, ammonium or alkali metal cation; with the proviso that the chain length of R1—On-L- is not greater than 6 atoms.Type: ApplicationFiled: February 25, 2010Publication date: June 17, 2010Applicant: E.I. DU PONT DE NEMOURS AND COMPANYInventors: Paul Douglas Brothers, Subhash Vishnu Gangal
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Patent number: 7718727Abstract: Fluoroplastics containing fluorocarbon resins and silicones are prepared by first mixing a fluorocarbon resin with a compatibilizer, then adding a curable organopolysiloxane with a radical initiator, and vulcanizing the organopolysiloxane in the mixture. The fluoroplastics can be processed by various techniques, such as extrusion, vacuum forming, injection molding, blow molding or compression molding, to fabricate plastic parts. The resulting fabricated parts can be re-processed (recycled) with little or no degradation of mechanical properties.Type: GrantFiled: May 7, 2009Date of Patent: May 18, 2010Assignee: Dow Corning CorporationInventors: Mark Hartmann, Igor Chorvath, Lauren Tonge, Robert Oldinski, James Thompson, David Romenesko, Kermit Kwan, Stephen Warren
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Patent number: 7714047Abstract: The present invention provides a method of producing a fluoropolymer aqueous dispersion by which the fluorine-containing emulsifier contained in the fluoropolymer aqueous dispersion as obtained after polymerization can be efficiently removed as well as a fluoropolymer aqueous dispersion low in fluorine-containing emulsifier concentration. The present invention is a method of producing a fluoropolymer aqueous dispersion which comprises carrying out a concentration treatment comprising a concentration operation of a pretreatment fluoropolymer aqueous dispersion, wherein the pretreatment fluoropolymer aqueous dispersion is obtained by carrying out a polymerization in an aqueous medium in the presence of a fluorine-containing surfactant (A), the fluorine-containing surfactant (A) is a fluorine-containing surfactant having an octanol/water partition coefficient of 1.5 to 3.5.Type: GrantFiled: June 1, 2009Date of Patent: May 11, 2010Assignee: Daikin Industries, Ltd.Inventors: Nobuhiko Tsuda, Chie Sawauchi, Yasuhiko Sawada, Tetsuo Shimizu
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Patent number: 7705074Abstract: A process comprising polymerizing at least one fluorinated monomer in an aqueous medium containing initiator and polymerization agent to form an aqueous dispersion of particles of fluoropolymer, the polymerization agent comprising: fluoropolyether acid or salt thereof having a number average molecular weight of at least about 800 g/mol; and fluorosurfactant having the formula: [R1—On-L-A?] Y+ wherein: R1 is a linear or branched partially or fully fluorinated aliphatic group which may contain ether linkages; n is 0 or 1; L is a linear or branched alkylene group which may be nonfluorinated, partially fluorinated or fully fluorinated and which may contain ether linkages; A? is an anionic group selected from the group consisting of carboxylate, sulfonate, sulfonamide anion, and phosphonate; and Y+ is hydrogen, ammonium or alkali metal cation; with the proviso that the chain length of R1—On-L- is not greater than 6 atoms.Type: GrantFiled: November 9, 2007Date of Patent: April 27, 2010Assignee: E. I. du Pont de Nemours and CompanyInventors: Paul Douglas Brothers, Subhash Vishnu Gangal
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Patent number: 7705085Abstract: A composition includes an elastomeric composition. The elastomeric composition can include a fluoroelastomer composition, and the elastomeric composition is substantially free of an epichlorohydrin composition. The composition can further include a filler material which includes a reinforcement-grade carbon black. The composition can further include a peroxide curative.Type: GrantFiled: April 6, 2007Date of Patent: April 27, 2010Assignee: 3M Innovative Properties CompanyInventor: Pradip K. Bandyopadhyay
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Patent number: 7705083Abstract: Ionically curable fluoroelastomers based on vinylidenfluoride (VDF) comprising: a) 100 parts by weight of fluoroelastomer based on vinylidenfluoride (VDF) substantially polar end groups free; b) from 0.1 to 0.35 phr of accelerating agent; c) from 1 to 15 phr of curing agent; d) from 2 to 20 phr of one or more inorganic acid acceptors, preferably bivalent metal oxides; e) from 0 to 3 phr, preferably from 0 to 1.5 phr of one or more basic compounds preferably hydroxides of bivalent metals or of weak acid metal salts; f) from 0 to 80 phr of reinforcing fillers; g) from 0 to 3 phr of coadjuvants of processability.Type: GrantFiled: April 26, 2005Date of Patent: April 27, 2010Assignee: Solvay Solexis S.p.A.Inventors: Milena Stanga, Margherita Albano, Vincenzo Arcella
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Patent number: 7700700Abstract: This invention relates to a heterogeneous copolymer composition of polyvinylidene fluoride with one or more perfluoroalkyl ethers. These copolymers have excellent low temperature impact properties, while maintaining a high melting point.Type: GrantFiled: January 26, 2007Date of Patent: April 20, 2010Assignee: Arkema Inc.Inventors: Roice Wille, Gregory O'Brien
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Publication number: 20100092759Abstract: The invention describes a particulate filled film, useful as a backsheet for a photovoltaic construct.Type: ApplicationFiled: October 9, 2009Publication date: April 15, 2010Inventors: Hua Fan, Keith C. Hong, Gurkirat S. Sekhon, Karen Conley, Julia DiCorleto Gibson
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Patent number: 7696268Abstract: The present invention provides a method of producing a fluoropolymer aqueous dispersion by which the fluorine-containing emulsifier contained in the fluoropolymer aqueous dispersion as obtained after polymerization can be efficiently removed as well as a fluoropolymer aqueous dispersion low in fluorine-containing emulsifier concentration. The present invention is a method of producing a fluoropolymer aqueous dispersion which comprises carrying out a concentration treatment comprising a concentration operation of a pretreatment fluoropolymer aqueous dispersion, wherein the pretreatment fluoropolymer aqueous dispersion is obtained by carrying out a polymerization in an aqueous medium in the presence of a fluorine-containing surfactant (A), the fluorine-containing surfactant (A) is a fluorine-containing surfactant having an octanol/water partition coefficient of 1.5 to 3.5.Type: GrantFiled: October 29, 2004Date of Patent: April 13, 2010Assignee: Daikin Industries, Ltd.Inventors: Nobuhiko Tsuda, Chie Sawauchi, Yasuhiko Sawada, Tetsuo Shimizu
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Patent number: 7691936Abstract: Fine fluoropolymer powders substantially fluorinated surfactant free, in particular fluorinated ionic surfactants, preferably perfluorooctanoic acid or its salts, comprising an anionic polyelectrolyte.Type: GrantFiled: July 18, 2006Date of Patent: April 6, 2010Assignee: Solvay Solexis S.p.A.Inventors: Marco Malvasi, Stefano Ferrero, Valeri Kapeliouchko
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Patent number: 7678859Abstract: Provided is a method comprising polymerizing at least one fluorinated monomer in an aqueous emulsion polymerization in the presence of a carbosilane surfactant having at least one hydrophobic part, wherein the hydrophobic part has at least one silicon atom, and having at least one hydrophilic part, with the proviso that the carbosilane contains no Si—O bonds.Type: GrantFiled: September 14, 2006Date of Patent: March 16, 2010Assignee: 3M Innovative Properties CompanyInventors: Peter Bissinger, Michael C. Dadalas, Klaus Hintzer, Ludwig Mayer, Werner Schwertfeger, Tilman C. Zipplies
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Patent number: 7666949Abstract: A curative composition comprising a cation and an anion of the formula Anq?Qpm+, wherein m, n, p, and q are positive integers, wherein m*p=n*q, wherein Qm+ is an organo onium, and Aq? is an anion, provided that at least one Aq? is selected from the formula: wherein each R independently is H, halo, alkyl, aryl, aralkyl, or cycloalkyl, and which also may be halogenated, fluorinated, or perfluorinated, wherein two or more of R and R? groups may together form a ring, wherein each R group independently may contain one or more heteroatom(s), wherein R? can be the same as R, with the proviso that R? cannot be halo. Also provided are a fluoropolymer composition including this curative, a method of making a fluoropolymer, and fluoropolymer articles containing curable or cured fluoropolymer compositions.Type: GrantFiled: June 13, 2008Date of Patent: February 23, 2010Assignee: 3M Innovative Properties CompanyInventors: Werner M. A. Grootaert, Eric W. Adair, Miguel A. Guerra
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Patent number: 7666927Abstract: A process for reducing fluorosurfactant content of a stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion comprising contacting the stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion with an anion exchange resin comprising a polymer and quaternary ammonium functional groups to reduce fluorosurfactant content, the functional groups being resistant to degradation which releases trialkylamines. The anion exchange resin is separated from the dispersion after the fluorosurfactant content has been reduced.Type: GrantFiled: December 2, 2005Date of Patent: February 23, 2010Assignee: E.I. du Pont de Nemours and CompanyInventors: James R. Combes, David William Johnson, Stephen Thomas Breske
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Patent number: 7662886Abstract: Processable rubber compositions contain a vulcanized elastomeric material dispersed in a matrix of a thermoplastic polymeric material. The vulcanized elastomeric material is a peroxide cure polymeric material containing repeating units derived from fluorine-containing monomers and at least one peroxide cure site monomer. In one embodiment the matrix forms a continuous phase and the vulcanized elastomeric material is in the form of particles forming a non-continuous phase. The compositions are made by combining a radical curing system, a fluorocarbon elastomer material, and a fluoroplastic material, and heating the mixture at a temperature and for a time sufficient to effect vulcanization of the elastomeric material, while mechanical energy is applied to mix the mixture during the heating step. Shaped articles may be readily formed from the rubber compositions according to conventional thermoplastic processes such as blow molding, injection molding, and extrusion.Type: GrantFiled: September 30, 2008Date of Patent: February 16, 2010Assignee: Freudenberg-NOK General PartnershipInventor: Edward Hosung Park
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Patent number: 7659333Abstract: The present invention provides a fluorinated surfactant having the general formula: [Rf—(O)t—CQH—CF2—O]n—R—G??(I) wherein Rf represents a partially or fully fluorinated aliphatic group optionally interrupted with one or more oxygen atoms, Q is CF3 or F, R is an aliphatic or aromatic hydrocarbon group, G represents a carboxylic or sulphonic acid or salt thereof, t is 0 or 1 and n is 1, 2 or 3. The surfactant is particularly useful in polymerizing fluorinated monomers in an aqueous emulsion polymerization.Type: GrantFiled: November 21, 2006Date of Patent: February 9, 2010Assignee: 3M Innovative Properties CompanyInventors: Klaus Hintzer, Michael Jürgens, Harald Kaspar, Herbert Königsmann, Kai Helmut Lochhaas, Andreas R. Maurer, Tilman C. Zipplies, Richard M. Flynn
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Publication number: 20100029831Abstract: A fluorine-containing elastomer composition, which comprises (A) a fluorine-containing elastomer consisting of a copolymer comprising (a) tetrafluoroethylene, (b) perfluoro(alkyl vinyl ether) or perfluoro-(alkoxyalkyl vinyl ether), and (c) a cyano group-containing perfluorovinyl ether, (B) a cross-linking agent, and (C) spherical silica, wherein the spherical silica is high purity amorphous silica particles obtained by calcining metallic silica powders, and cooling the resulting vaporous silicon oxide. The present fluorine-containing elastomer composition can provide seal materials having distinguished processability, product appearance, plasma resistance, etc. by the cyano group-containing perfluoroelastomer having a good heat resistance and only silica as contained therein.Type: ApplicationFiled: September 25, 2007Publication date: February 4, 2010Inventors: Mitsuru Meada, Yasunori Yanai
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Publication number: 20100009197Abstract: Provided are compositions comprising a) a fluoroplastic; b) an aromatic material having exactly one hydroxyl group, wherein the aromatic material is free of thiol groups, and wherein the hydroxyl group is bonded to an aromatic carbon; c) a salt former compound capable of forming a salt with the aromatic material; and d) optionally a phase transfer catalyst. Also provided are reaction products of the described compositions, multi-layer articles comprising the compositions and reaction products, and methods for making the compositions, reaction products, and articles.Type: ApplicationFiled: October 12, 2007Publication date: January 14, 2010Applicant: 3M INNOVATIVE PROPERTIES COMPANYInventors: Naiyong Jing, Blake E. Chandler, Gregg D. Dahlke
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Publication number: 20090297751Abstract: Perfluoropolymer composites are provided which are obtained by dispersing layered-silicates having properties of swelling or cleaving in dispersion media in perfluoropolymers and having the ratio of the viscosity, V0.1, at 0.1 rad/sec by a parallel plate mode of a dynamic rheometer to the viscosity, V1, measured at 1 rad/sec is 1.5 or greater, viscosity being measured at 340° C. A method for making the perfluoropolymer composites is provided, and molded articles therefrom. And additionally, perfluoropolymer composites, where layered-silicates having properties of swelling or cleaving in dispersion media are dispersed in perfluoropolymers, with the storage elasticity of 2 times or higher than that of fluoropolymers, at temperatures greater than the glass transition temperature of perfluoropolymers.Type: ApplicationFiled: June 11, 2009Publication date: December 3, 2009Applicant: DUPONT-MITSUI FLUOROCHEMICALS CO LTDInventors: Pham Hoai Nam, Jeong Chang Lee, Kenji Oki, Hajime Sato
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Patent number: 7625974Abstract: A non-dripping, flame retardant, fluoropolymeric composition comprising: (a) a fluoropolymeric base polymer; (b) at least one char forming agent; and (c) a compatibilizer agent. The fluoropolymeric base polymer is preferably selected from the group consisting of PVDF (polyvinylidene fluoride), ECTFE, poly-ethylene chlorotrifluoroethylene, and ETFE poly-ethylene tetrafluoroethylene. Such compositions are especially useful for appliance wire, aerospace/military wire, cable raceways, blown fiber tubes, fire alarm cables, circuit integrity cables, fiber optic distribution cables & breakout components, heat tracing cable jacket, stage lighting cable, industrial cable, shipboard cable (military & passenger), shielded cable jackets.Type: GrantFiled: September 29, 2006Date of Patent: December 1, 2009Assignee: AlphaGary CorporationInventors: Mark A. Jozokos, Yevgeniy I. Globus
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Publication number: 20090286088Abstract: Interpolymers of 1-99 mol % vinyl fluoride and 99-1 mol % of at least one highly fluorinated monomer such as tetrafluoroethylene are disclosed. The interpolymers are characterized by the presence of ionic end groups and are prepared by polymerizing VF and fluorinated monomer in water with water-soluble free-radical initiators such as azoamidine initiators or persulfate initiators at temperatures within the range of 60 to 100° C. and reactor pressures within the range of 1 to 12 MPa (145 to 1760 psi). The invention further provides for protective self-supporting films and coatings formed from nonaqueous dispersions of the interpolymers, both for use on the surfaces of substrates including metal, plastic, ceramic, glass, concrete, fabric and wood.Type: ApplicationFiled: March 7, 2008Publication date: November 19, 2009Applicant: E. I. DU PONT DE NEMOURS AND COMPANYInventor: Ronald Earl Uschold
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Patent number: 7604861Abstract: The present invention provides a fluororesin composition, which is excellent in moldability and crack resistance, a process for preparing the composition and a cable evenly coated with the composition. Specifically, the present invention provides a fluororesin composition wherein polytetrafluoroethylene is compounded to a terpolymer comprising tetrafluoroethylene, hexafluoropropylene and perfluoroalkyl vinylether. Also, the present invention provides a process for preparing the composition which comprises kneading with a multi-screw kneader. Furthermore, the present invention provides a cable which is coated with the resin.Type: GrantFiled: December 18, 2006Date of Patent: October 20, 2009Assignee: Daikin Industries, Ltd.Inventors: Masayuki Namimatsu, Yoshiyuki Hiraga, Yoshiyuki Takase, Tadahiro Yabu
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Publication number: 20090250137Abstract: A water transmission tubing for controlling the flow of water under pressure comprises a tubular inner liner of generally uniform cross-sectional configuration continuous with the length of the tubing and having an anti-bacterial agent for preventing the growth of bacteria on the inside wall of the tube. The inner liner contains a dispersed slip additive that forms a low friction surface inside the tubing for preventing adherence of slime to the inside of the tubing. The slip additive can comprise a fluoroelastomer, a fluoropolymer, a silicone resinous material, or mixtures thereof. The liner can be a separate inner layer of a multi-layer dripline, a monolayer form of the dripline or the inside of a drip irrigation emitter. The invention is particularly useful in subsurface treatment of wastewater.Type: ApplicationFiled: March 27, 2009Publication date: October 8, 2009Inventor: Rodney Ruskin
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Patent number: 7598312Abstract: A process for preparing a halogenated polymer in a medium comprising liquid or supercritical carbon dioxide, comprising a step involving the radical polymerization of at least one halogenated monomer and at least one step involving cross-flow filtration; and a cross-flow filtration device.Type: GrantFiled: July 12, 2006Date of Patent: October 6, 2009Assignee: Solvay (Société Anonyme)Inventors: Jean-Marie Blaude, Roland Martin
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Publication number: 20090234061Abstract: A process for producing a fluororesin sheet containing a filler includes a step of rolling a sheet-forming resin composition including a fluororesin, a filler and a processing aid at a roll temperature of from 40 to 80° C. The processing aid includes at least 30% by mass of a petroleum hydrocarbon solvent having a fractionating temperature of not higher than 120° C. based on 100% by mass of the amount of the processing aid. The fluororesin sheet so produced provides high stress relaxation properties along with high hermetic sealing properties even when the content of the fluororesin is low and the content of the filler is high.Type: ApplicationFiled: March 19, 2007Publication date: September 17, 2009Applicant: NIPPON VALQUA INDUSTRIES, LTD.Inventor: Shinya Kurokawa
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Patent number: 7576164Abstract: Compositions of fluoroelastomers containing copolymerized units of tetrafluoroethylene, propylene, a first cure site selected from the group consisting of i) trifluoroethylene, ii) 3,3,3-trifluoropropene-1, iii) 1,2,3,3,3-pentafluoropropylene, iv) 1,1,3,3,3-pentafluoropropylene, and v) 2,3,3,3-tetrafluoropropene, and a second cure site selected from the group consisting of i) copolymerized units of a brominated cure site monomer, ii) copolymerized units of an iodinated cure site monomer, iii) copolymerized units of a chlorinated cure site monomer, iv) brominated endgroups, v) iodinated endgroups and vi) a combination of any of i)-v) are readily curable with polyhydroxy curing systems. The resulting cured articles have a combination of excellent resistance to alkaline fluids, superior tensile properties and compression set resistance, and excellent adhesion to metal substrates. Optionally, the fluoroelastomers may be dual cured by both a polyhydroxy system and an organic peroxide system.Type: GrantFiled: February 27, 2007Date of Patent: August 18, 2009Assignee: Du Pont Performance Elastomers LLC.Inventors: John G. Bauerle, Christopher J. Bish, Theresa M. Dobel, Phan L. Tang
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Patent number: 7566762Abstract: The present invention relates to a process for preparing a fluoropolymer containing at least one kind of fluoroolefin, which comprises carrying out polymerization in the presence of a surfactant represented by the formula (1): (wherein R1 and R2 may be the same or different respectively, and represent an alkyl group or an alkenyl group, R3 is a hydrogen atom, an alkyl group or an alkenyl group, the total carbon number of R1 to R3 is 2 to 25, L? is a group represented by —SO3?, —OSO3?, —PO3?, —OPO3? or —COO?, and M+ is a monovalent cation). Thereby, polymerization can be carried out with excellent production efficiency in the presence of a small amount of a surfactant, and a fluoropolymer can be prepared without lowering various physical properties such as water resistance by the surfactant.Type: GrantFiled: December 22, 2004Date of Patent: July 28, 2009Assignee: Daikin Industries, Ltd.Inventors: Masao Otsuka, Satoshi Tokuno, Katsuya Nakai
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Publication number: 20090181237Abstract: Hydrophobic coating systems, suspensions for forming hydrophobic coatings, and methods for fabricating hydrophobic coatings are provided. In an exemplary embodiment, a hydrophobic coating system comprises a substrate and a hydrophobic coating disposed on the substrate. The hydrophobic coating comprises agglomerates formed of a fluorinated polymer and a plurality of chemically inert particles having an average size of no greater than about 0.1 ?m. The hydrophobic coating exhibits contact angles greater than about 90 degrees.Type: ApplicationFiled: January 16, 2008Publication date: July 16, 2009Applicant: HONEYWELL INTERNATIONAL, INC.Inventors: Mark Kaiser, Belinda S. Foor
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Patent number: 7560506Abstract: A water- and oil-repellent composition consisting of (A) a fluorine-containing copolymer comprising at least 20% by weight (based on the copolymer) of (a1) units derived from a polymerizable monomer having a C1-6 polyfluoroalkyl group or a polyfluoroalkenyl group, (B) a surfactant component comprising as the essential components (b1) a nonionic surfactant having an HLB value of 12 or below and (b2) a nonionic surfactant having an HLB value of 15 or above, and (C) an aqueous medium substantially consisting of water. This composition is free from operationally or environmentally undesirable solvents and superior to conventional ones in stabilities such as mechanical stability, chemical stability, and long-term shelf stability.Type: GrantFiled: April 14, 2005Date of Patent: July 14, 2009Assignee: Daikin Industries, Ltd.Inventor: Masato Kashiwagi
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Patent number: 7547742Abstract: Fluoroplastics containing fluorocarbon resins and silicones are prepared by first mixing a fluorocarbon resin with a compatibilizer, then adding a curable organopolysiloxane with a radical initiator, and vulcanizing the organopolysiloxane in the mixture. The fluoroplastics can be processed by various techniques, such as extrusion, vacuum forming, injection molding, blow molding or compression molding, to fabricate plastic parts. The resulting fabricated parts can be re-processed (recycled) with little or no degradation of mechanical properties.Type: GrantFiled: June 4, 2004Date of Patent: June 16, 2009Assignee: Dow Corning CorporationInventors: Mark Hartmann, Igor Chorvath, Lauren Tonge, Robert Oldinski, James Thompson, David Romenesko, Kermit Kwan, Stephen Warren
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Patent number: 7544736Abstract: The present invention is drawn to a method of generating functionalized latex particulates in a colloidal suspension. The method can comprise steps of protecting functional groups present on polymerizable monomers with photo labile groups to form protected monomers; polymerizing the protected monomers to form a protected polymer; and exposing the protected polymer to a wavelength of light that removes the photo labile groups from the functional groups, thereby forming the functionalized latex particulates. These latex particulates can be used in a wide variety of applications, including in ink-jet ink printing applications.Type: GrantFiled: October 25, 2005Date of Patent: June 9, 2009Assignee: Hewlett-Packard Development Company, L.P.Inventors: Zhang-Lin Zhou, Sivapackia Ganapathiappan
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Patent number: 7544753Abstract: A process for producing an elastic fluorocopolymer, by emulsion-polymerizing at least one fluoromonomer (a), a vinyl ester monomer (b) represented by the formula CR1R2?CR3COOCH?CH2 optionally, at least one hydrocarbon monomer (c) selected from the group consisting of ethylene, propylene and a vinyl ether, in an aqueous medium to produce an elastic fluorocopolymer latex, adjusting the pH of the elastic fluorocopolymer latex to from 1 to 9, and coagulating the elastic fluorocopolymer latex to isolate an elastic fluorocopolymer.Type: GrantFiled: January 3, 2007Date of Patent: June 9, 2009Assignee: Asahi Glass Company, LimitedInventors: Junpei Nomura, Hiroshi Funaki, Hiroki Kamiya
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Patent number: 7528184Abstract: A perfluoroelastomer composition comprises a perfluoroelastomer (e.g., tetrafluoroethylene/perfluoro(methyl vinyl ether) copolymer), an organic peroxide (e.g., 2,5-dimethyl-2,5-di(tert-butylperoxy)hexane and a scorch retarder (e.g., o-phenylphenol), and the perfluoroelastomer composition is excellent in processability and unlikely to scorch. Furthermore, a perfluoro rubber molded article obtained by thermal crosslinking of the perfluoroelastomer composition is excellent in rubber physical properties such as tensile strength and elongation at break and in a compression set property.Type: GrantFiled: August 18, 2006Date of Patent: May 5, 2009Assignee: Asahi Glass Company, LimitedInventors: Hiroshi Funaki, Makoto Honda, Masayuki Saito, Hiroki Kamiya
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Publication number: 20090082519Abstract: The present invention provides the process for preparing a fluorine-containing polymer which can easily and efficiently separate a fluorine-containing polymer and water from an aqueous dispersion of a fluorine-containing polymer, and the fluorine-containing polymer obtained by the mentioned preparation process. Further the present invention provides the molded article obtained by crosslinking a curable composition comprising the above-mentioned fluorine-containing polymer and a crosslinking agent. The preparation process is a process for preparing a fluorine-containing polymer comprising a step for heat-treating an aqueous dispersion of a fluorine-containing polymer having a concentration of 3 to 70% by weight to obtain the fluorine-containing polymer having a water content of not more than 1% by weight.Type: ApplicationFiled: April 28, 2006Publication date: March 26, 2009Applicant: DAIKIN INDUSTRIES, LTD.Inventors: Masaki Irie, Yosuke Nishimura, Manabu Fujisawa
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Publication number: 20090053462Abstract: The invention provides a polymer, useful as a surfactant and textile reagent, comprising: (a) monomeric units containing a lipophobic group, said monomeric units comprising a compound of Formula: (I); wherein: Z is a spacer; R is H or methyl; Rf is a lipophobic group, R2 and R3 are each independently H or halo; X is —O— or a covalent bond; and o is 0 or 1 or 2; (b) optionally but preferably, monomeric units containing an attachment group; and (c) optionally but preferably, monomeric units containing a hydrophobic group.Type: ApplicationFiled: April 21, 2006Publication date: February 26, 2009Inventors: Ji Guo, Joseph M. DeSimone, Paul R. Resnick
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Publication number: 20090047541Abstract: Methods and systems of dielectric film materials to be used in capacitors. At least some of the illustrative embodiments are dielectric materials in the form of polymer film comprising a blend of polyvinylidene fluoride (PVDF) and at least one selected from the group consisting of: polyethylene terephthalate (PET); polycarbonate (PC); polyethylene naphthalate (PEN); polyphenylene sulfide (PPS); polytetrafluoroethylene (PTFE); polystyrene (PST); polysulphone (PS); polyethermide (PEM); and polyimide (PI).Type: ApplicationFiled: August 15, 2007Publication date: February 19, 2009Applicant: LITHIUM POWER TECHNOLOGIES, INC.Inventor: M. Zafar Munshi
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Publication number: 20090048391Abstract: A composition for aqueous coating material which has a low content of an organic solvent and presents little burden on the environment and which is excellent in storage stability. A composition for aqueous coating material, which comprises a synthetic resin containing a fluorinated copolymer (A) comprising from 40 to 60 mol % of a fluoro-olefin unit, from 3 to 50 mol % of an alkyl vinyl ether or alkyl vinyl ester unit, from 4 to 30 mol % of a hydroxyl group-containing vinyl ether unit and 0.Type: ApplicationFiled: October 9, 2008Publication date: February 19, 2009Applicant: Asahi Glass Company, LimitedInventors: Naoko Sumi, Takashi Morizumi, Isao Kimura
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Patent number: 7488781Abstract: Crosslinkable perfluoroelastomer compositions having low metal content and low compression set when crosslinked, and processes for producing the same, are provided. Compositions comprising terpolymers of TFE, PAVE, and CNVE having a metal content of less than 3000 ppb may be formed into high purity transparent perfluoroelastomer parts.Type: GrantFiled: May 25, 2005Date of Patent: February 10, 2009Assignee: Gore Enterprise Holdings, Inc.Inventors: Ping Xu, Jack Hegenbarth, Xin Kang Chen, Jian Hou
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Publication number: 20090036586Abstract: The present invention provides a halogen gas-resistant perfluoro elastomer molded article obtained by molding and crosslinking a composition comprising: (A) 100 parts by mass of a perfluoro elastomer comprising copolymerization units comprising (A1) a perfluoro olefin; (A2) a perfluorovinyl ether; and (A3) a curing site monomer selected from the group consisting of an olefin fluoride having a nitrile group, a vinyl fluoride ether having a nitrile group and a mixture thereof, the curing site monomer (A3) being contained in an amount of 1.0 to 8.0 mol %; and (B) 0.1 to 10 parts by mass of a specific crosslinking agent represented by the following formula (a).Type: ApplicationFiled: July 29, 2008Publication date: February 5, 2009Applicant: NICHIAS CORPORATIONInventors: Hideyuki Shishitani, Naoya Kuzawa, Takeshi Kuboyama
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Publication number: 20090030090Abstract: The present invention is directed to carbon nanotube (CNT)/polymer composites, i.e., nanocomposites, wherein the CNTs in such nanocomposites are highly dispersed in a polymer matrix, and wherein the nanocomposites comprise a compatibilizing surfactant that interacts with both the CNTs and the polymer matrix. The present invention is also directed to methods of making these nanocomposites. In some such methods, the compatibilizing surfactant provides initial CNT dispersion and subsequent mixing with a polymer. The present invention is also directed to methods of using these nanocomposites in a variety of applications.Type: ApplicationFiled: August 2, 2005Publication date: January 29, 2009Applicant: University of HoustonInventors: Ramanan Krishnamoorti, Cynthia A. Mitchell, Jeffrey L. Bahr
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Publication number: 20080303184Abstract: A composition of fluoropolymer and dispersed conductive particulate provides an electrically conductive polymeric material resistant to static charge buildup. Radiation curing, especially electron beam radiation curing, is favored for curing fluoroelastomer-based precursor articles into desired electrically conductive articles.Type: ApplicationFiled: May 20, 2008Publication date: December 11, 2008Applicant: Freudenberg-NOK General PartnershipInventor: Edward Hosung PARK
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Publication number: 20080305363Abstract: Disclosed herein are pigments comprising mostly rutile TiO2, wherein the mostly rutile TiO2 consists essentially of low abrasion TiO2 particles produced by introducing a metal halide into the chloride process. Further disclosed are ink, can coatings, fibers, papers, and plastics comprising the pigment. Also disclosed herein are pigments comprising the low abrasion TiO2 pigments comprising TiO2 particles which have been further heat treated at a temperature of at least about 800° C. in an oxidizing atmosphere for a time period of at least about 1 hour.Type: ApplicationFiled: August 15, 2008Publication date: December 11, 2008Inventors: Michael Andrew Hofmann, Charles David Musick, Narayanan Sankara Subramanian, Kostantinos Kourtakis, Austin Henry Reid, JR.
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Patent number: 7462667Abstract: The present invention provides an aqueous coating composition comprising (i) particles of a non-melt processible polymer of tetrafluoroethylene and (ii) a non-fluorinated polymer selected from the group consisting of a polysulfone, a polyamide, a polyimide, a polyamide-imide, a polybismaleimide and mixtures thereof, wherein said particles are core-shell particles whereby the shell comprises a copolymer of tetrafluoroethylene and a partially fluorinated or non-fluorinated comonomer. The aqueous coating composition may be used for providing a primer coating on a substrate such as a metal or glass substrate. Such primer coating may provide good or excellent non-stick coatings combined with good or excellent scratch and wear resistance of the coating. Also, such primer coating may provide for good to excellent PTFE coatings that can resist hot salt water. The aqueous coating composition may also be used to provide other coating layers of a multi-layer coating.Type: GrantFiled: June 30, 2005Date of Patent: December 9, 2008Assignee: 3M Innovative Properties CompanyInventors: Michael C. Dadalas, Klaus Hintzer, Gernot Loehr, Tilman Zipplies
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Publication number: 20080292809Abstract: A composition for applying a coating on a support at low temperature from a dispersion of at least a component of the coating to be deposited in the composition. The composition includes at least a strong and heavy solvent with a boiling point higher than 150° C. approximately, and a weak solvent with a boiling point less than 100° C. approximately. The solvents forming the composition must constitute a mixture that evaporates at a temperature less than 100° C. The composition is particularly useful for forming electrodes or electrolyte in lithium-ion batteries. The method and the device used for forming the coating use a dispersion spreader and an infrared lamp.Type: ApplicationFiled: August 6, 2008Publication date: November 27, 2008Applicant: HYDRO-QUEBECInventors: Abdelbast GUERFI, Fernand Brochu, Monique Masse, Karim Zaghib
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Patent number: 7452926Abstract: A resin pulley according to the present invention is obtained by molding a resin composition containing a phenol resin serving as a base resin, 15 to 50% by weight of an inorganic powder having a Mohs hardness of not less than 6.5, 20 to 40% by weight of a reinforcing fiber, and 1 to 5% by weight of a lubricant and thermosetting the phenol resin, and is superior in dimensional stability and strength, is also superior in wear resistance particularly in a dust atmosphere or the like, and is superior in practicality as an alternate to a metal pulley.Type: GrantFiled: August 28, 2003Date of Patent: November 18, 2008Assignees: JTEKT Corporation, Hitachi Chemical Co., Ltd.Inventors: Hirokazu Arai, Takeshi Tsuda, Hiroto Oda
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Patent number: 7449524Abstract: A curable fluorocarbon elastomer is dynamically cured in the presence of a major amount of a non-curing thermoplastic material and a minor amount of a second fluorocarbon elastomer that does not cure under the dynamic vulcanization conditions. The non-curing elastomer is preferably present at from 1 to 20 parts based on 100 parts of the curing fluorocarbon elastomer. Processable rubber compositions comprise a continuous phase of a thermoplastic material, particles of a cured fluorocarbon elastomer dispersed in the continuous phase, and an uncured fluorocarbon elastomer at a level of 10 parts or less per 100 parts of the cured fluorocarbon elastomer. Shaped articles such as gaskets and seals are produced by thermoplastic processing of the processable rubber compositions.Type: GrantFiled: January 5, 2005Date of Patent: November 11, 2008Assignee: Freudenberg-NOK General PartnershipInventors: Edward Hosung Park, Francis Joseph Walker
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Patent number: 7449523Abstract: Processable rubber compositions contain a vulcanized fluorocarbon elastomer and wear reducing additives dispersed in a matrix of a thermoplastic polymeric material. In one embodiment the matrix forms a continuous phase and the vulcanized elastomeric material is in the form of particles forming a non-continuous phase. The compositions are made by combining a curative, an uncured fluorocarbon elastomer, a wear reducing additive and a thermoplastic material, and heating the mixture at a temperature and for a time sufficient to effect vulcanization of the elastomeric material, while mechanical energy is applied to mix the mixture during the heating step. Shaped articles such as seals, gaskets, O-rings, and hoses may be readily formed from the rubber compositions according to conventional thermoplastic processes such as blow molding, injection molding, and extrusion.Type: GrantFiled: December 27, 2004Date of Patent: November 11, 2008Assignee: Freudenberg-NOK General PartnershipInventor: Edward Hosung Park