Fluorine-containing Monomer Contains F And C Only Or Only F, C, And H Patents (Class 524/545)
  • Patent number: 7754836
    Abstract: Disclosed is a water- and oil-repellent agent comprising the following fluorine-containing copolymer (A). The fluorine-containing copolymer (A) comprises: (a1) a fluoroalkyl group-containing polymerizable monomer of the formula: wherein Y is a divalent organic group [for example, an aliphatic group having 1 to 10 carbon atoms, an aromatic or cycloaliphatic group having 6 to 10 carbon atoms, a —SO2N(R1)R2— group (in which R1 is a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and R2 is an alkylene group having 1 to 10 carbon atoms), a —CON(R1)R2— group (in which R1 is a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and R2 is an alkylene group having 1 to 10 carbon atoms), or a —CH2CH(OY1)CH2— group (in which Y1 is a hydrogen atom or an acyl group having 1 to 4 carbon atoms)]; and Rf is a linear or branched fluoroalkyl or fluoroalkenyl group having 1 to 6 carbon atoms; and (a2) vinylidene chloride.
    Type: Grant
    Filed: August 30, 2006
    Date of Patent: July 13, 2010
    Assignee: Daikin Industries, Ltd.
    Inventor: Masato Kashiwagi
  • Patent number: 7754121
    Abstract: A material comprising aerogel particles and a polytetrafluoroethylene (PTFE) binder is formed having a thermal conductivity of less than or equal to 25 mW/m K at atmospheric conditions. The material is moldable or formable, having little or no shedding of filler particles, and may be formed into structures such as tapes or composites, for example, by bonding the material between two outer layers. Advantageously, composites may be flexed, stretched, or bent without significant dusting or loss of insulating properties.
    Type: Grant
    Filed: April 5, 2007
    Date of Patent: July 13, 2010
    Assignee: Gore Enterprise Holdings, Inc.
    Inventors: Cedomila Ristic-Lehmann, Brian Farnworth, Anita Dutta
  • Patent number: 7754795
    Abstract: A coating composition having (i) an aqueous dispersion of fluoropolymer particles comprising a non-melt processible polymer of tetrafluoroethylene, (ii) a fluorinated surfactant, (iii) a non-ionic non-fluorinated surfactant and (iv) a non-fluorinated polymer, wherein the fluorinated surfactant is selected from fluorinated carboxylic acids or salts thereof of the general formula (I): [Rf—O-L-COO?]iXi+??(I) wherein L represents a linear partially or fully fluorinated alkylene group or an aliphatic hydrocarbon group, Rf represents a linear partially or fully fluorinated aliphatic group or a linear partially or fully fluorinated aliphatic group interrupted with one or more oxygen atoms, Xi+ represents a cation having the valence i and i is 1, 2 or 3.
    Type: Grant
    Filed: May 25, 2006
    Date of Patent: July 13, 2010
    Assignee: 3M Innovative Properties Company
    Inventors: Klaus Hintzer, Michael Jürgens, Harald Kaspar, Herbert Koenigsmann, Kai Helmut Lochhaas, Andreas R. Maurer, Werner Schwertfeger, Tilman Zipplies, Ludwig Mayer, Michael C. Dadalas, George G. I. Moore, Jay F. Schulz, Richard M. Flynn
  • Patent number: 7745530
    Abstract: The present invention provides an aqueous emulsion resin composition which comprises: (a) a resin composition containing at least one fluoroolefin polymer having crosslinkable group(s) at a terminus and/or a side chain of its molecule and at least one non-fluoroolefin polymer having crosslinkable group(s) at a terminus and/or a side chain of its molecule; and (b) at least one curing agent selected from the group consisting of isocyanates, melamines, hydrazides, carbodiimides, silanes and epoxides; and provides an aqueous emulsion resin compositions containing at least one chemically bonded product of a fluoroolefin polymer and a non-fluoroolefin polymer bonded to each other via at least one covalent bond at a terminus and/or a side chain of the molecules wherein one or both of the fluoroolefin polymer and the non-fluoroolefin polymer have crosslinkable group(s).
    Type: Grant
    Filed: June 28, 2002
    Date of Patent: June 29, 2010
    Assignee: Daikin Industries, Ltd.
    Inventors: Nobuo Mitsuhata, Tsunehiko Fuwa, Susumu Wada, Keiko Kunimasa, Haruhiko Mohri, Nobuo Fukita
  • Publication number: 20100152363
    Abstract: A process comprising polymerizing at least one fluorinated monomer in an aqueous medium containing initiator and polymerization agent to form an aqueous dispersion of particles of fluoropolymer, the polymerization agent comprising: fluoropolyether acid or salt thereof having a number average molecular weight of at least about 800 g/mol; and fluorosurfactant having the formula: [R1—On-L-A?]Y+ wherein: R1 is a linear or branched partially or fully fluorinated aliphatic group which may contain ether linkages; n is 0 or 1; L is a linear or branched alkylene group which may be nonfluorinated, partially fluorinated or fully fluorinated and which may contain ether linkages; A? is an anionic group selected from the group consisting of carboxylate, sulfonate, sulfonamide anion, and phosphonate; and Y+ is hydrogen, ammonium or alkali metal cation; with the proviso that the chain length of R1—On-L- is not greater than 6 atoms.
    Type: Application
    Filed: February 25, 2010
    Publication date: June 17, 2010
    Applicant: E.I. DU PONT DE NEMOURS AND COMPANY
    Inventors: Paul Douglas Brothers, Subhash Vishnu Gangal
  • Patent number: 7718727
    Abstract: Fluoroplastics containing fluorocarbon resins and silicones are prepared by first mixing a fluorocarbon resin with a compatibilizer, then adding a curable organopolysiloxane with a radical initiator, and vulcanizing the organopolysiloxane in the mixture. The fluoroplastics can be processed by various techniques, such as extrusion, vacuum forming, injection molding, blow molding or compression molding, to fabricate plastic parts. The resulting fabricated parts can be re-processed (recycled) with little or no degradation of mechanical properties.
    Type: Grant
    Filed: May 7, 2009
    Date of Patent: May 18, 2010
    Assignee: Dow Corning Corporation
    Inventors: Mark Hartmann, Igor Chorvath, Lauren Tonge, Robert Oldinski, James Thompson, David Romenesko, Kermit Kwan, Stephen Warren
  • Patent number: 7714047
    Abstract: The present invention provides a method of producing a fluoropolymer aqueous dispersion by which the fluorine-containing emulsifier contained in the fluoropolymer aqueous dispersion as obtained after polymerization can be efficiently removed as well as a fluoropolymer aqueous dispersion low in fluorine-containing emulsifier concentration. The present invention is a method of producing a fluoropolymer aqueous dispersion which comprises carrying out a concentration treatment comprising a concentration operation of a pretreatment fluoropolymer aqueous dispersion, wherein the pretreatment fluoropolymer aqueous dispersion is obtained by carrying out a polymerization in an aqueous medium in the presence of a fluorine-containing surfactant (A), the fluorine-containing surfactant (A) is a fluorine-containing surfactant having an octanol/water partition coefficient of 1.5 to 3.5.
    Type: Grant
    Filed: June 1, 2009
    Date of Patent: May 11, 2010
    Assignee: Daikin Industries, Ltd.
    Inventors: Nobuhiko Tsuda, Chie Sawauchi, Yasuhiko Sawada, Tetsuo Shimizu
  • Patent number: 7705074
    Abstract: A process comprising polymerizing at least one fluorinated monomer in an aqueous medium containing initiator and polymerization agent to form an aqueous dispersion of particles of fluoropolymer, the polymerization agent comprising: fluoropolyether acid or salt thereof having a number average molecular weight of at least about 800 g/mol; and fluorosurfactant having the formula: [R1—On-L-A?] Y+ wherein: R1 is a linear or branched partially or fully fluorinated aliphatic group which may contain ether linkages; n is 0 or 1; L is a linear or branched alkylene group which may be nonfluorinated, partially fluorinated or fully fluorinated and which may contain ether linkages; A? is an anionic group selected from the group consisting of carboxylate, sulfonate, sulfonamide anion, and phosphonate; and Y+ is hydrogen, ammonium or alkali metal cation; with the proviso that the chain length of R1—On-L- is not greater than 6 atoms.
    Type: Grant
    Filed: November 9, 2007
    Date of Patent: April 27, 2010
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Paul Douglas Brothers, Subhash Vishnu Gangal
  • Patent number: 7705085
    Abstract: A composition includes an elastomeric composition. The elastomeric composition can include a fluoroelastomer composition, and the elastomeric composition is substantially free of an epichlorohydrin composition. The composition can further include a filler material which includes a reinforcement-grade carbon black. The composition can further include a peroxide curative.
    Type: Grant
    Filed: April 6, 2007
    Date of Patent: April 27, 2010
    Assignee: 3M Innovative Properties Company
    Inventor: Pradip K. Bandyopadhyay
  • Patent number: 7705083
    Abstract: Ionically curable fluoroelastomers based on vinylidenfluoride (VDF) comprising: a) 100 parts by weight of fluoroelastomer based on vinylidenfluoride (VDF) substantially polar end groups free; b) from 0.1 to 0.35 phr of accelerating agent; c) from 1 to 15 phr of curing agent; d) from 2 to 20 phr of one or more inorganic acid acceptors, preferably bivalent metal oxides; e) from 0 to 3 phr, preferably from 0 to 1.5 phr of one or more basic compounds preferably hydroxides of bivalent metals or of weak acid metal salts; f) from 0 to 80 phr of reinforcing fillers; g) from 0 to 3 phr of coadjuvants of processability.
    Type: Grant
    Filed: April 26, 2005
    Date of Patent: April 27, 2010
    Assignee: Solvay Solexis S.p.A.
    Inventors: Milena Stanga, Margherita Albano, Vincenzo Arcella
  • Patent number: 7700700
    Abstract: This invention relates to a heterogeneous copolymer composition of polyvinylidene fluoride with one or more perfluoroalkyl ethers. These copolymers have excellent low temperature impact properties, while maintaining a high melting point.
    Type: Grant
    Filed: January 26, 2007
    Date of Patent: April 20, 2010
    Assignee: Arkema Inc.
    Inventors: Roice Wille, Gregory O'Brien
  • Publication number: 20100092759
    Abstract: The invention describes a particulate filled film, useful as a backsheet for a photovoltaic construct.
    Type: Application
    Filed: October 9, 2009
    Publication date: April 15, 2010
    Inventors: Hua Fan, Keith C. Hong, Gurkirat S. Sekhon, Karen Conley, Julia DiCorleto Gibson
  • Patent number: 7696268
    Abstract: The present invention provides a method of producing a fluoropolymer aqueous dispersion by which the fluorine-containing emulsifier contained in the fluoropolymer aqueous dispersion as obtained after polymerization can be efficiently removed as well as a fluoropolymer aqueous dispersion low in fluorine-containing emulsifier concentration. The present invention is a method of producing a fluoropolymer aqueous dispersion which comprises carrying out a concentration treatment comprising a concentration operation of a pretreatment fluoropolymer aqueous dispersion, wherein the pretreatment fluoropolymer aqueous dispersion is obtained by carrying out a polymerization in an aqueous medium in the presence of a fluorine-containing surfactant (A), the fluorine-containing surfactant (A) is a fluorine-containing surfactant having an octanol/water partition coefficient of 1.5 to 3.5.
    Type: Grant
    Filed: October 29, 2004
    Date of Patent: April 13, 2010
    Assignee: Daikin Industries, Ltd.
    Inventors: Nobuhiko Tsuda, Chie Sawauchi, Yasuhiko Sawada, Tetsuo Shimizu
  • Patent number: 7691936
    Abstract: Fine fluoropolymer powders substantially fluorinated surfactant free, in particular fluorinated ionic surfactants, preferably perfluorooctanoic acid or its salts, comprising an anionic polyelectrolyte.
    Type: Grant
    Filed: July 18, 2006
    Date of Patent: April 6, 2010
    Assignee: Solvay Solexis S.p.A.
    Inventors: Marco Malvasi, Stefano Ferrero, Valeri Kapeliouchko
  • Patent number: 7678859
    Abstract: Provided is a method comprising polymerizing at least one fluorinated monomer in an aqueous emulsion polymerization in the presence of a carbosilane surfactant having at least one hydrophobic part, wherein the hydrophobic part has at least one silicon atom, and having at least one hydrophilic part, with the proviso that the carbosilane contains no Si—O bonds.
    Type: Grant
    Filed: September 14, 2006
    Date of Patent: March 16, 2010
    Assignee: 3M Innovative Properties Company
    Inventors: Peter Bissinger, Michael C. Dadalas, Klaus Hintzer, Ludwig Mayer, Werner Schwertfeger, Tilman C. Zipplies
  • Patent number: 7666949
    Abstract: A curative composition comprising a cation and an anion of the formula Anq?Qpm+, wherein m, n, p, and q are positive integers, wherein m*p=n*q, wherein Qm+ is an organo onium, and Aq? is an anion, provided that at least one Aq? is selected from the formula: wherein each R independently is H, halo, alkyl, aryl, aralkyl, or cycloalkyl, and which also may be halogenated, fluorinated, or perfluorinated, wherein two or more of R and R? groups may together form a ring, wherein each R group independently may contain one or more heteroatom(s), wherein R? can be the same as R, with the proviso that R? cannot be halo. Also provided are a fluoropolymer composition including this curative, a method of making a fluoropolymer, and fluoropolymer articles containing curable or cured fluoropolymer compositions.
    Type: Grant
    Filed: June 13, 2008
    Date of Patent: February 23, 2010
    Assignee: 3M Innovative Properties Company
    Inventors: Werner M. A. Grootaert, Eric W. Adair, Miguel A. Guerra
  • Patent number: 7666927
    Abstract: A process for reducing fluorosurfactant content of a stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion comprising contacting the stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion with an anion exchange resin comprising a polymer and quaternary ammonium functional groups to reduce fluorosurfactant content, the functional groups being resistant to degradation which releases trialkylamines. The anion exchange resin is separated from the dispersion after the fluorosurfactant content has been reduced.
    Type: Grant
    Filed: December 2, 2005
    Date of Patent: February 23, 2010
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: James R. Combes, David William Johnson, Stephen Thomas Breske
  • Patent number: 7662886
    Abstract: Processable rubber compositions contain a vulcanized elastomeric material dispersed in a matrix of a thermoplastic polymeric material. The vulcanized elastomeric material is a peroxide cure polymeric material containing repeating units derived from fluorine-containing monomers and at least one peroxide cure site monomer. In one embodiment the matrix forms a continuous phase and the vulcanized elastomeric material is in the form of particles forming a non-continuous phase. The compositions are made by combining a radical curing system, a fluorocarbon elastomer material, and a fluoroplastic material, and heating the mixture at a temperature and for a time sufficient to effect vulcanization of the elastomeric material, while mechanical energy is applied to mix the mixture during the heating step. Shaped articles may be readily formed from the rubber compositions according to conventional thermoplastic processes such as blow molding, injection molding, and extrusion.
    Type: Grant
    Filed: September 30, 2008
    Date of Patent: February 16, 2010
    Assignee: Freudenberg-NOK General Partnership
    Inventor: Edward Hosung Park
  • Patent number: 7659333
    Abstract: The present invention provides a fluorinated surfactant having the general formula: [Rf—(O)t—CQH—CF2—O]n—R—G??(I) wherein Rf represents a partially or fully fluorinated aliphatic group optionally interrupted with one or more oxygen atoms, Q is CF3 or F, R is an aliphatic or aromatic hydrocarbon group, G represents a carboxylic or sulphonic acid or salt thereof, t is 0 or 1 and n is 1, 2 or 3. The surfactant is particularly useful in polymerizing fluorinated monomers in an aqueous emulsion polymerization.
    Type: Grant
    Filed: November 21, 2006
    Date of Patent: February 9, 2010
    Assignee: 3M Innovative Properties Company
    Inventors: Klaus Hintzer, Michael Jürgens, Harald Kaspar, Herbert Königsmann, Kai Helmut Lochhaas, Andreas R. Maurer, Tilman C. Zipplies, Richard M. Flynn
  • Publication number: 20100029831
    Abstract: A fluorine-containing elastomer composition, which comprises (A) a fluorine-containing elastomer consisting of a copolymer comprising (a) tetrafluoroethylene, (b) perfluoro(alkyl vinyl ether) or perfluoro-(alkoxyalkyl vinyl ether), and (c) a cyano group-containing perfluorovinyl ether, (B) a cross-linking agent, and (C) spherical silica, wherein the spherical silica is high purity amorphous silica particles obtained by calcining metallic silica powders, and cooling the resulting vaporous silicon oxide. The present fluorine-containing elastomer composition can provide seal materials having distinguished processability, product appearance, plasma resistance, etc. by the cyano group-containing perfluoroelastomer having a good heat resistance and only silica as contained therein.
    Type: Application
    Filed: September 25, 2007
    Publication date: February 4, 2010
    Inventors: Mitsuru Meada, Yasunori Yanai
  • Publication number: 20100009197
    Abstract: Provided are compositions comprising a) a fluoroplastic; b) an aromatic material having exactly one hydroxyl group, wherein the aromatic material is free of thiol groups, and wherein the hydroxyl group is bonded to an aromatic carbon; c) a salt former compound capable of forming a salt with the aromatic material; and d) optionally a phase transfer catalyst. Also provided are reaction products of the described compositions, multi-layer articles comprising the compositions and reaction products, and methods for making the compositions, reaction products, and articles.
    Type: Application
    Filed: October 12, 2007
    Publication date: January 14, 2010
    Applicant: 3M INNOVATIVE PROPERTIES COMPANY
    Inventors: Naiyong Jing, Blake E. Chandler, Gregg D. Dahlke
  • Publication number: 20090297751
    Abstract: Perfluoropolymer composites are provided which are obtained by dispersing layered-silicates having properties of swelling or cleaving in dispersion media in perfluoropolymers and having the ratio of the viscosity, V0.1, at 0.1 rad/sec by a parallel plate mode of a dynamic rheometer to the viscosity, V1, measured at 1 rad/sec is 1.5 or greater, viscosity being measured at 340° C. A method for making the perfluoropolymer composites is provided, and molded articles therefrom. And additionally, perfluoropolymer composites, where layered-silicates having properties of swelling or cleaving in dispersion media are dispersed in perfluoropolymers, with the storage elasticity of 2 times or higher than that of fluoropolymers, at temperatures greater than the glass transition temperature of perfluoropolymers.
    Type: Application
    Filed: June 11, 2009
    Publication date: December 3, 2009
    Applicant: DUPONT-MITSUI FLUOROCHEMICALS CO LTD
    Inventors: Pham Hoai Nam, Jeong Chang Lee, Kenji Oki, Hajime Sato
  • Patent number: 7625974
    Abstract: A non-dripping, flame retardant, fluoropolymeric composition comprising: (a) a fluoropolymeric base polymer; (b) at least one char forming agent; and (c) a compatibilizer agent. The fluoropolymeric base polymer is preferably selected from the group consisting of PVDF (polyvinylidene fluoride), ECTFE, poly-ethylene chlorotrifluoroethylene, and ETFE poly-ethylene tetrafluoroethylene. Such compositions are especially useful for appliance wire, aerospace/military wire, cable raceways, blown fiber tubes, fire alarm cables, circuit integrity cables, fiber optic distribution cables & breakout components, heat tracing cable jacket, stage lighting cable, industrial cable, shipboard cable (military & passenger), shielded cable jackets.
    Type: Grant
    Filed: September 29, 2006
    Date of Patent: December 1, 2009
    Assignee: AlphaGary Corporation
    Inventors: Mark A. Jozokos, Yevgeniy I. Globus
  • Publication number: 20090286088
    Abstract: Interpolymers of 1-99 mol % vinyl fluoride and 99-1 mol % of at least one highly fluorinated monomer such as tetrafluoroethylene are disclosed. The interpolymers are characterized by the presence of ionic end groups and are prepared by polymerizing VF and fluorinated monomer in water with water-soluble free-radical initiators such as azoamidine initiators or persulfate initiators at temperatures within the range of 60 to 100° C. and reactor pressures within the range of 1 to 12 MPa (145 to 1760 psi). The invention further provides for protective self-supporting films and coatings formed from nonaqueous dispersions of the interpolymers, both for use on the surfaces of substrates including metal, plastic, ceramic, glass, concrete, fabric and wood.
    Type: Application
    Filed: March 7, 2008
    Publication date: November 19, 2009
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventor: Ronald Earl Uschold
  • Patent number: 7604861
    Abstract: The present invention provides a fluororesin composition, which is excellent in moldability and crack resistance, a process for preparing the composition and a cable evenly coated with the composition. Specifically, the present invention provides a fluororesin composition wherein polytetrafluoroethylene is compounded to a terpolymer comprising tetrafluoroethylene, hexafluoropropylene and perfluoroalkyl vinylether. Also, the present invention provides a process for preparing the composition which comprises kneading with a multi-screw kneader. Furthermore, the present invention provides a cable which is coated with the resin.
    Type: Grant
    Filed: December 18, 2006
    Date of Patent: October 20, 2009
    Assignee: Daikin Industries, Ltd.
    Inventors: Masayuki Namimatsu, Yoshiyuki Hiraga, Yoshiyuki Takase, Tadahiro Yabu
  • Publication number: 20090250137
    Abstract: A water transmission tubing for controlling the flow of water under pressure comprises a tubular inner liner of generally uniform cross-sectional configuration continuous with the length of the tubing and having an anti-bacterial agent for preventing the growth of bacteria on the inside wall of the tube. The inner liner contains a dispersed slip additive that forms a low friction surface inside the tubing for preventing adherence of slime to the inside of the tubing. The slip additive can comprise a fluoroelastomer, a fluoropolymer, a silicone resinous material, or mixtures thereof. The liner can be a separate inner layer of a multi-layer dripline, a monolayer form of the dripline or the inside of a drip irrigation emitter. The invention is particularly useful in subsurface treatment of wastewater.
    Type: Application
    Filed: March 27, 2009
    Publication date: October 8, 2009
    Inventor: Rodney Ruskin
  • Patent number: 7598312
    Abstract: A process for preparing a halogenated polymer in a medium comprising liquid or supercritical carbon dioxide, comprising a step involving the radical polymerization of at least one halogenated monomer and at least one step involving cross-flow filtration; and a cross-flow filtration device.
    Type: Grant
    Filed: July 12, 2006
    Date of Patent: October 6, 2009
    Assignee: Solvay (Société Anonyme)
    Inventors: Jean-Marie Blaude, Roland Martin
  • Publication number: 20090234061
    Abstract: A process for producing a fluororesin sheet containing a filler includes a step of rolling a sheet-forming resin composition including a fluororesin, a filler and a processing aid at a roll temperature of from 40 to 80° C. The processing aid includes at least 30% by mass of a petroleum hydrocarbon solvent having a fractionating temperature of not higher than 120° C. based on 100% by mass of the amount of the processing aid. The fluororesin sheet so produced provides high stress relaxation properties along with high hermetic sealing properties even when the content of the fluororesin is low and the content of the filler is high.
    Type: Application
    Filed: March 19, 2007
    Publication date: September 17, 2009
    Applicant: NIPPON VALQUA INDUSTRIES, LTD.
    Inventor: Shinya Kurokawa
  • Patent number: 7576164
    Abstract: Compositions of fluoroelastomers containing copolymerized units of tetrafluoroethylene, propylene, a first cure site selected from the group consisting of i) trifluoroethylene, ii) 3,3,3-trifluoropropene-1, iii) 1,2,3,3,3-pentafluoropropylene, iv) 1,1,3,3,3-pentafluoropropylene, and v) 2,3,3,3-tetrafluoropropene, and a second cure site selected from the group consisting of i) copolymerized units of a brominated cure site monomer, ii) copolymerized units of an iodinated cure site monomer, iii) copolymerized units of a chlorinated cure site monomer, iv) brominated endgroups, v) iodinated endgroups and vi) a combination of any of i)-v) are readily curable with polyhydroxy curing systems. The resulting cured articles have a combination of excellent resistance to alkaline fluids, superior tensile properties and compression set resistance, and excellent adhesion to metal substrates. Optionally, the fluoroelastomers may be dual cured by both a polyhydroxy system and an organic peroxide system.
    Type: Grant
    Filed: February 27, 2007
    Date of Patent: August 18, 2009
    Assignee: Du Pont Performance Elastomers LLC.
    Inventors: John G. Bauerle, Christopher J. Bish, Theresa M. Dobel, Phan L. Tang
  • Patent number: 7566762
    Abstract: The present invention relates to a process for preparing a fluoropolymer containing at least one kind of fluoroolefin, which comprises carrying out polymerization in the presence of a surfactant represented by the formula (1): (wherein R1 and R2 may be the same or different respectively, and represent an alkyl group or an alkenyl group, R3 is a hydrogen atom, an alkyl group or an alkenyl group, the total carbon number of R1 to R3 is 2 to 25, L? is a group represented by —SO3?, —OSO3?, —PO3?, —OPO3? or —COO?, and M+ is a monovalent cation). Thereby, polymerization can be carried out with excellent production efficiency in the presence of a small amount of a surfactant, and a fluoropolymer can be prepared without lowering various physical properties such as water resistance by the surfactant.
    Type: Grant
    Filed: December 22, 2004
    Date of Patent: July 28, 2009
    Assignee: Daikin Industries, Ltd.
    Inventors: Masao Otsuka, Satoshi Tokuno, Katsuya Nakai
  • Publication number: 20090181237
    Abstract: Hydrophobic coating systems, suspensions for forming hydrophobic coatings, and methods for fabricating hydrophobic coatings are provided. In an exemplary embodiment, a hydrophobic coating system comprises a substrate and a hydrophobic coating disposed on the substrate. The hydrophobic coating comprises agglomerates formed of a fluorinated polymer and a plurality of chemically inert particles having an average size of no greater than about 0.1 ?m. The hydrophobic coating exhibits contact angles greater than about 90 degrees.
    Type: Application
    Filed: January 16, 2008
    Publication date: July 16, 2009
    Applicant: HONEYWELL INTERNATIONAL, INC.
    Inventors: Mark Kaiser, Belinda S. Foor
  • Patent number: 7560506
    Abstract: A water- and oil-repellent composition consisting of (A) a fluorine-containing copolymer comprising at least 20% by weight (based on the copolymer) of (a1) units derived from a polymerizable monomer having a C1-6 polyfluoroalkyl group or a polyfluoroalkenyl group, (B) a surfactant component comprising as the essential components (b1) a nonionic surfactant having an HLB value of 12 or below and (b2) a nonionic surfactant having an HLB value of 15 or above, and (C) an aqueous medium substantially consisting of water. This composition is free from operationally or environmentally undesirable solvents and superior to conventional ones in stabilities such as mechanical stability, chemical stability, and long-term shelf stability.
    Type: Grant
    Filed: April 14, 2005
    Date of Patent: July 14, 2009
    Assignee: Daikin Industries, Ltd.
    Inventor: Masato Kashiwagi
  • Patent number: 7547742
    Abstract: Fluoroplastics containing fluorocarbon resins and silicones are prepared by first mixing a fluorocarbon resin with a compatibilizer, then adding a curable organopolysiloxane with a radical initiator, and vulcanizing the organopolysiloxane in the mixture. The fluoroplastics can be processed by various techniques, such as extrusion, vacuum forming, injection molding, blow molding or compression molding, to fabricate plastic parts. The resulting fabricated parts can be re-processed (recycled) with little or no degradation of mechanical properties.
    Type: Grant
    Filed: June 4, 2004
    Date of Patent: June 16, 2009
    Assignee: Dow Corning Corporation
    Inventors: Mark Hartmann, Igor Chorvath, Lauren Tonge, Robert Oldinski, James Thompson, David Romenesko, Kermit Kwan, Stephen Warren
  • Patent number: 7544736
    Abstract: The present invention is drawn to a method of generating functionalized latex particulates in a colloidal suspension. The method can comprise steps of protecting functional groups present on polymerizable monomers with photo labile groups to form protected monomers; polymerizing the protected monomers to form a protected polymer; and exposing the protected polymer to a wavelength of light that removes the photo labile groups from the functional groups, thereby forming the functionalized latex particulates. These latex particulates can be used in a wide variety of applications, including in ink-jet ink printing applications.
    Type: Grant
    Filed: October 25, 2005
    Date of Patent: June 9, 2009
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Zhang-Lin Zhou, Sivapackia Ganapathiappan
  • Patent number: 7544753
    Abstract: A process for producing an elastic fluorocopolymer, by emulsion-polymerizing at least one fluoromonomer (a), a vinyl ester monomer (b) represented by the formula CR1R2?CR3COOCH?CH2 optionally, at least one hydrocarbon monomer (c) selected from the group consisting of ethylene, propylene and a vinyl ether, in an aqueous medium to produce an elastic fluorocopolymer latex, adjusting the pH of the elastic fluorocopolymer latex to from 1 to 9, and coagulating the elastic fluorocopolymer latex to isolate an elastic fluorocopolymer.
    Type: Grant
    Filed: January 3, 2007
    Date of Patent: June 9, 2009
    Assignee: Asahi Glass Company, Limited
    Inventors: Junpei Nomura, Hiroshi Funaki, Hiroki Kamiya
  • Patent number: 7528184
    Abstract: A perfluoroelastomer composition comprises a perfluoroelastomer (e.g., tetrafluoroethylene/perfluoro(methyl vinyl ether) copolymer), an organic peroxide (e.g., 2,5-dimethyl-2,5-di(tert-butylperoxy)hexane and a scorch retarder (e.g., o-phenylphenol), and the perfluoroelastomer composition is excellent in processability and unlikely to scorch. Furthermore, a perfluoro rubber molded article obtained by thermal crosslinking of the perfluoroelastomer composition is excellent in rubber physical properties such as tensile strength and elongation at break and in a compression set property.
    Type: Grant
    Filed: August 18, 2006
    Date of Patent: May 5, 2009
    Assignee: Asahi Glass Company, Limited
    Inventors: Hiroshi Funaki, Makoto Honda, Masayuki Saito, Hiroki Kamiya
  • Publication number: 20090082519
    Abstract: The present invention provides the process for preparing a fluorine-containing polymer which can easily and efficiently separate a fluorine-containing polymer and water from an aqueous dispersion of a fluorine-containing polymer, and the fluorine-containing polymer obtained by the mentioned preparation process. Further the present invention provides the molded article obtained by crosslinking a curable composition comprising the above-mentioned fluorine-containing polymer and a crosslinking agent. The preparation process is a process for preparing a fluorine-containing polymer comprising a step for heat-treating an aqueous dispersion of a fluorine-containing polymer having a concentration of 3 to 70% by weight to obtain the fluorine-containing polymer having a water content of not more than 1% by weight.
    Type: Application
    Filed: April 28, 2006
    Publication date: March 26, 2009
    Applicant: DAIKIN INDUSTRIES, LTD.
    Inventors: Masaki Irie, Yosuke Nishimura, Manabu Fujisawa
  • Publication number: 20090053462
    Abstract: The invention provides a polymer, useful as a surfactant and textile reagent, comprising: (a) monomeric units containing a lipophobic group, said monomeric units comprising a compound of Formula: (I); wherein: Z is a spacer; R is H or methyl; Rf is a lipophobic group, R2 and R3 are each independently H or halo; X is —O— or a covalent bond; and o is 0 or 1 or 2; (b) optionally but preferably, monomeric units containing an attachment group; and (c) optionally but preferably, monomeric units containing a hydrophobic group.
    Type: Application
    Filed: April 21, 2006
    Publication date: February 26, 2009
    Inventors: Ji Guo, Joseph M. DeSimone, Paul R. Resnick
  • Publication number: 20090047541
    Abstract: Methods and systems of dielectric film materials to be used in capacitors. At least some of the illustrative embodiments are dielectric materials in the form of polymer film comprising a blend of polyvinylidene fluoride (PVDF) and at least one selected from the group consisting of: polyethylene terephthalate (PET); polycarbonate (PC); polyethylene naphthalate (PEN); polyphenylene sulfide (PPS); polytetrafluoroethylene (PTFE); polystyrene (PST); polysulphone (PS); polyethermide (PEM); and polyimide (PI).
    Type: Application
    Filed: August 15, 2007
    Publication date: February 19, 2009
    Applicant: LITHIUM POWER TECHNOLOGIES, INC.
    Inventor: M. Zafar Munshi
  • Publication number: 20090048391
    Abstract: A composition for aqueous coating material which has a low content of an organic solvent and presents little burden on the environment and which is excellent in storage stability. A composition for aqueous coating material, which comprises a synthetic resin containing a fluorinated copolymer (A) comprising from 40 to 60 mol % of a fluoro-olefin unit, from 3 to 50 mol % of an alkyl vinyl ether or alkyl vinyl ester unit, from 4 to 30 mol % of a hydroxyl group-containing vinyl ether unit and 0.
    Type: Application
    Filed: October 9, 2008
    Publication date: February 19, 2009
    Applicant: Asahi Glass Company, Limited
    Inventors: Naoko Sumi, Takashi Morizumi, Isao Kimura
  • Patent number: 7488781
    Abstract: Crosslinkable perfluoroelastomer compositions having low metal content and low compression set when crosslinked, and processes for producing the same, are provided. Compositions comprising terpolymers of TFE, PAVE, and CNVE having a metal content of less than 3000 ppb may be formed into high purity transparent perfluoroelastomer parts.
    Type: Grant
    Filed: May 25, 2005
    Date of Patent: February 10, 2009
    Assignee: Gore Enterprise Holdings, Inc.
    Inventors: Ping Xu, Jack Hegenbarth, Xin Kang Chen, Jian Hou
  • Publication number: 20090036586
    Abstract: The present invention provides a halogen gas-resistant perfluoro elastomer molded article obtained by molding and crosslinking a composition comprising: (A) 100 parts by mass of a perfluoro elastomer comprising copolymerization units comprising (A1) a perfluoro olefin; (A2) a perfluorovinyl ether; and (A3) a curing site monomer selected from the group consisting of an olefin fluoride having a nitrile group, a vinyl fluoride ether having a nitrile group and a mixture thereof, the curing site monomer (A3) being contained in an amount of 1.0 to 8.0 mol %; and (B) 0.1 to 10 parts by mass of a specific crosslinking agent represented by the following formula (a).
    Type: Application
    Filed: July 29, 2008
    Publication date: February 5, 2009
    Applicant: NICHIAS CORPORATION
    Inventors: Hideyuki Shishitani, Naoya Kuzawa, Takeshi Kuboyama
  • Publication number: 20090030090
    Abstract: The present invention is directed to carbon nanotube (CNT)/polymer composites, i.e., nanocomposites, wherein the CNTs in such nanocomposites are highly dispersed in a polymer matrix, and wherein the nanocomposites comprise a compatibilizing surfactant that interacts with both the CNTs and the polymer matrix. The present invention is also directed to methods of making these nanocomposites. In some such methods, the compatibilizing surfactant provides initial CNT dispersion and subsequent mixing with a polymer. The present invention is also directed to methods of using these nanocomposites in a variety of applications.
    Type: Application
    Filed: August 2, 2005
    Publication date: January 29, 2009
    Applicant: University of Houston
    Inventors: Ramanan Krishnamoorti, Cynthia A. Mitchell, Jeffrey L. Bahr
  • Publication number: 20080303184
    Abstract: A composition of fluoropolymer and dispersed conductive particulate provides an electrically conductive polymeric material resistant to static charge buildup. Radiation curing, especially electron beam radiation curing, is favored for curing fluoroelastomer-based precursor articles into desired electrically conductive articles.
    Type: Application
    Filed: May 20, 2008
    Publication date: December 11, 2008
    Applicant: Freudenberg-NOK General Partnership
    Inventor: Edward Hosung PARK
  • Publication number: 20080305363
    Abstract: Disclosed herein are pigments comprising mostly rutile TiO2, wherein the mostly rutile TiO2 consists essentially of low abrasion TiO2 particles produced by introducing a metal halide into the chloride process. Further disclosed are ink, can coatings, fibers, papers, and plastics comprising the pigment. Also disclosed herein are pigments comprising the low abrasion TiO2 pigments comprising TiO2 particles which have been further heat treated at a temperature of at least about 800° C. in an oxidizing atmosphere for a time period of at least about 1 hour.
    Type: Application
    Filed: August 15, 2008
    Publication date: December 11, 2008
    Inventors: Michael Andrew Hofmann, Charles David Musick, Narayanan Sankara Subramanian, Kostantinos Kourtakis, Austin Henry Reid, JR.
  • Patent number: 7462667
    Abstract: The present invention provides an aqueous coating composition comprising (i) particles of a non-melt processible polymer of tetrafluoroethylene and (ii) a non-fluorinated polymer selected from the group consisting of a polysulfone, a polyamide, a polyimide, a polyamide-imide, a polybismaleimide and mixtures thereof, wherein said particles are core-shell particles whereby the shell comprises a copolymer of tetrafluoroethylene and a partially fluorinated or non-fluorinated comonomer. The aqueous coating composition may be used for providing a primer coating on a substrate such as a metal or glass substrate. Such primer coating may provide good or excellent non-stick coatings combined with good or excellent scratch and wear resistance of the coating. Also, such primer coating may provide for good to excellent PTFE coatings that can resist hot salt water. The aqueous coating composition may also be used to provide other coating layers of a multi-layer coating.
    Type: Grant
    Filed: June 30, 2005
    Date of Patent: December 9, 2008
    Assignee: 3M Innovative Properties Company
    Inventors: Michael C. Dadalas, Klaus Hintzer, Gernot Loehr, Tilman Zipplies
  • Publication number: 20080292809
    Abstract: A composition for applying a coating on a support at low temperature from a dispersion of at least a component of the coating to be deposited in the composition. The composition includes at least a strong and heavy solvent with a boiling point higher than 150° C. approximately, and a weak solvent with a boiling point less than 100° C. approximately. The solvents forming the composition must constitute a mixture that evaporates at a temperature less than 100° C. The composition is particularly useful for forming electrodes or electrolyte in lithium-ion batteries. The method and the device used for forming the coating use a dispersion spreader and an infrared lamp.
    Type: Application
    Filed: August 6, 2008
    Publication date: November 27, 2008
    Applicant: HYDRO-QUEBEC
    Inventors: Abdelbast GUERFI, Fernand Brochu, Monique Masse, Karim Zaghib
  • Patent number: 7452926
    Abstract: A resin pulley according to the present invention is obtained by molding a resin composition containing a phenol resin serving as a base resin, 15 to 50% by weight of an inorganic powder having a Mohs hardness of not less than 6.5, 20 to 40% by weight of a reinforcing fiber, and 1 to 5% by weight of a lubricant and thermosetting the phenol resin, and is superior in dimensional stability and strength, is also superior in wear resistance particularly in a dust atmosphere or the like, and is superior in practicality as an alternate to a metal pulley.
    Type: Grant
    Filed: August 28, 2003
    Date of Patent: November 18, 2008
    Assignees: JTEKT Corporation, Hitachi Chemical Co., Ltd.
    Inventors: Hirokazu Arai, Takeshi Tsuda, Hiroto Oda
  • Patent number: 7449524
    Abstract: A curable fluorocarbon elastomer is dynamically cured in the presence of a major amount of a non-curing thermoplastic material and a minor amount of a second fluorocarbon elastomer that does not cure under the dynamic vulcanization conditions. The non-curing elastomer is preferably present at from 1 to 20 parts based on 100 parts of the curing fluorocarbon elastomer. Processable rubber compositions comprise a continuous phase of a thermoplastic material, particles of a cured fluorocarbon elastomer dispersed in the continuous phase, and an uncured fluorocarbon elastomer at a level of 10 parts or less per 100 parts of the cured fluorocarbon elastomer. Shaped articles such as gaskets and seals are produced by thermoplastic processing of the processable rubber compositions.
    Type: Grant
    Filed: January 5, 2005
    Date of Patent: November 11, 2008
    Assignee: Freudenberg-NOK General Partnership
    Inventors: Edward Hosung Park, Francis Joseph Walker
  • Patent number: 7449523
    Abstract: Processable rubber compositions contain a vulcanized fluorocarbon elastomer and wear reducing additives dispersed in a matrix of a thermoplastic polymeric material. In one embodiment the matrix forms a continuous phase and the vulcanized elastomeric material is in the form of particles forming a non-continuous phase. The compositions are made by combining a curative, an uncured fluorocarbon elastomer, a wear reducing additive and a thermoplastic material, and heating the mixture at a temperature and for a time sufficient to effect vulcanization of the elastomeric material, while mechanical energy is applied to mix the mixture during the heating step. Shaped articles such as seals, gaskets, O-rings, and hoses may be readily formed from the rubber compositions according to conventional thermoplastic processes such as blow molding, injection molding, and extrusion.
    Type: Grant
    Filed: December 27, 2004
    Date of Patent: November 11, 2008
    Assignee: Freudenberg-NOK General Partnership
    Inventor: Edward Hosung Park