Four Or More Fluorine Atoms Patents (Class 524/546)
  • Patent number: 5484503
    Abstract: A sealant composition comprises a dispersion of a fluorocarbon polymer with particles no larger than 25 micrometers in a low volatility liquid and up to 50 percent of a higher volatility liquid. Also covered is an applicator for applying the sealant to the gasket of an electrochemical cell.
    Type: Grant
    Filed: February 23, 1993
    Date of Patent: January 16, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Walther G. Grot
  • Patent number: 5482640
    Abstract: Aqueous dispersions of PTFE and TiO.sub.2 stabilized from the effects of freeze/thaw cycles are disclosed, wherein the stabilizing agents are monohydric alcohols and monoamines having less than five carbon atoms.
    Type: Grant
    Filed: October 28, 1994
    Date of Patent: January 9, 1996
    Assignee: Consep, Inc.
    Inventor: Thomas H. Eberlein
  • Patent number: 5466743
    Abstract: The invention concerns a polyethylene-based ski coating containing up to 5%-wt of a fluorinated additive. This ski coating is especially suitable for making downhill and cross-country skis.
    Type: Grant
    Filed: May 27, 1993
    Date of Patent: November 14, 1995
    Assignee: Isosport Verbundbauteile Gesellschaft m.b.H.
    Inventor: Robert Schamesberger
  • Patent number: 5461107
    Abstract: An elastomeric composition having improved resistance to chemical attack is provided, the elastomeric composition including a perfluoroelastomer and a non-fibrillating particulate fluorographite. Also, a process for improving the processibility and resistance to chemical attack of a perfluoroelastomer is provided, in which the perfluoroelastomer is mixed with a non-fibrillating fluorocarbon particulate polymer to form a elastomeric composition which is processed at a temperature less than the melting temperature of the non-fibrillating fluorocarbon particulate polymer to disperse the fluorocarbon polymer throughout the perfluoroelastomer while maintaining the fluorocarbon polymer in particulate form. A method of making a seal which is resistant to chemical attack for preventing the leakage of a fluid between a first member and a second member is also provided.
    Type: Grant
    Filed: September 14, 1994
    Date of Patent: October 24, 1995
    Assignee: Greene, Tweed & Co.
    Inventors: Harshad P. Amin, Carl A. Aufdermarsh
  • Patent number: 5459191
    Abstract: Perfluorinated cycloalkane solvents for dissolving high melting polymers containing tetrafluoroethylene, are disclosed. These solvents dissolve such polymers more rapidly, and/or are more stable, than previously known solvents. Also disclosed is a process for dissolution of the polymers and their resulting solutions. The solutions are useful for making polymer films, coatings and for encapsulating objects.
    Type: Grant
    Filed: March 31, 1994
    Date of Patent: October 17, 1995
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: William H. Tuminello, Robert J. Cavanaugh
  • Patent number: 5439896
    Abstract: A thermosetting powdery coating composition which comprises, in admixture: (A) from 40 to 98 parts by weight of a fluorine-containing copolymer, which is a copolymer of a fluoroolefin and a comonomer having a crosslinkable reactive group, e.g., hydroxy, carboxyl, amino and glycidyl groups, containing at least 10% by weight of fluorine and having an intrinsic viscosity of 0.05-2 dl/g (30.degree. C., tetrahydrofuran), a glass transition temperature of 30.degree.-120.degree. C. and a weight loss by heating which does not exceed 2% and (B) from 60 to 2 parts by weight of a curing agent capable of forming crosslinks by reacting with the crosslinkable reactive groups in (A), except for the composition wherein (A) is a hydroxyl group and a weight loss by heating which does not exceed 2% and (B) is a blocked isocyanate compound.
    Type: Grant
    Filed: September 28, 1993
    Date of Patent: August 8, 1995
    Assignees: Nippon Oil and Fats Company, Limited, Asahi Glass Company, Ltd.
    Inventors: Haruki Ito, Kenzou Maeda, Nobuyuki Miyazaki, Masao Unoki, Chiaki Sagawa, Motoi Kamba
  • Patent number: 5428096
    Abstract: An oil-repellent fluororubber composition obtained by compounding a low-molecular weight tetrafluoroethylene resin with a peroxide crosslinked fluororubber having a Mooney viscosity of 90 or more ML.sub.1+10 (100.degree. C.) or compounding a low-molecular weight tetrafluoroethylene resin and an inorganic filler selected from powders of solid substances, such as iron, nickel, cobalt, iron-cobalt alloy, molybdenum, tungsten, tantalum and tungsten-carbide, having surface energy higher than that of copper with a peroxide crosslinked fluororubber. An oil-repellent fluororubber elastomer having excellent oil repellency and at the same time maintaining original mechanical and physical characteristics sufficiently can be obtained, using easily available materials on the market without any special means of processing and treatment.
    Type: Grant
    Filed: February 18, 1994
    Date of Patent: June 27, 1995
    Assignee: Kinyosha Company, Limited
    Inventor: Noritomo Fukunaga
  • Patent number: 5420191
    Abstract: Shaped PTFE compositions are disclosed having low creep which are produced by the application of pressure and elevated temperature. Also disclosed is a process for making shaped compositions with low creep by the application of pressure and elevated temperature.
    Type: Grant
    Filed: August 30, 1993
    Date of Patent: May 30, 1995
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Edward G. Howard, Jr., Arthur Z. Moss
  • Patent number: 5418270
    Abstract: A composition comprises fibrillated polytetrafluoroethylene, molybdenum disulfide and a thermoplastic elastomeric material. In the composition, fibrillatable polytetrafluoroethylene is preassociated with molybdenum disulfide and combined with a thermoplastic elastomeric copolymer in relative amounts from as low as about 2 parts per hundred rubber to as high as about 12 parts per hundred rubber, with the balance thermoplastic elastomeric copolymer and filler. The composition can further include an unpolymerized polytetrafluoroethylene binder residue of the fibrillated polytetrafluoroethylene.
    Type: Grant
    Filed: April 12, 1994
    Date of Patent: May 23, 1995
    Assignee: Alphaflex Industries, Inc.
    Inventor: William E. Peters
  • Patent number: 5399598
    Abstract: An asphalt composition comprises asphalt mixed with an asphalt modifier, which combines a thermoplastic elastomeric copolymer and an effective amount of a fibrillated polytetrafluoroethylene and molybdenum disulfide particles. The thermoplastic elastomeric copolymer preferably comprises two incompatible polymers forming a two-phase copolymer including a thermoplastic end block polymer and an elastomeric mid block polymer. Preferably, the thermoplastic end block polymer is a styrene polymer and the elastomeric mid block polymer is selected from a group consisting of polybutadiene, polyisoprene and poly(ethylene-butylene). The asphalt modifier is made by mixing together under high shear, as for example, in a twin screw extruder, particles of a thermoplastic elastomeric copolymer, fibrillatable polytetrafluoroethylene and molybdenum disulfide until the fibrillatable polytetrafluoroethylene is substantially fibrillated and combined with the thermoplastic elastomeric copolymer.
    Type: Grant
    Filed: March 3, 1994
    Date of Patent: March 21, 1995
    Assignee: Alphaflex Industries
    Inventor: William E. Peters
  • Patent number: 5397829
    Abstract: Copolymers of tetrafluoroethylene (TFE) and hexafluoropropylene (HFP) having high HFP content and end-of-melting temperature, T.sub.m (end), as low as 200.degree. C. are disclosed. Exceptional performance as a processing aid in polyolefins results from having T.sub.m (end) of the TFE/HFP copolymer close to the processing temperature of the polyolefin. These TFE/HFP copolymers are soluble in fluorinated cyclic solvents. Copolymer/solvent systems copolymer at significant concentrations in selected solvents are fluid and stable at room temperature.
    Type: Grant
    Filed: November 23, 1993
    Date of Patent: March 14, 1995
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Richard A. Morgan, William H. Tuminello, Mark E. Wagman
  • Patent number: 5393819
    Abstract: A bitumen and asphalt modifier comprises thermoplastic elastomeric copolymer and an effective amount of a fibrillated polytetrafluoroethylene and molybdenum disulfide particles. The thermoplastic elastomeric copolymer comprises two incompatible polymers forming a two-phase copolymer including a thermoplastic end block polymer and an elastomeric mid block polymer. The asphalt modifier is made by mixing together under high shear particles of a thermoplastic elastomeric copolymer, fibrillatable polytetrafluoroethylene and molybdenum disulfide until the fibrillatable polytetrafluoroethylene is substantially fibrillated and combined with the thermoplastic elastomeric copolymer.
    Type: Grant
    Filed: February 25, 1994
    Date of Patent: February 28, 1995
    Assignee: Alphaflex Industries
    Inventor: William E. Peters
  • Patent number: 5354787
    Abstract: It is an object of the present invention to provide a soil-stabilizing agent with less emission of dust, good reactivity, good behavior at mixing and good dispersibility and a method for soil stabilizing treatment capable of restraining the emission of dust in the procedure of sprinkling and mixing of the soil-stabilizing agent to soil.The soil-stabilizing agent according to the present invention comprises a mixture of a material mainly composed of quick lime and/or calcined dolomite and fibrillatable polytetrafluoroethylene resin.And the method for soil-stabilizing treatment according to the present invention comprises the following steps; adding a mixture of a material mainly composed of quick lime and/or calcined dolomite and fibrillatable polytetrafluoroethylene resin to soil, and mixing them under the hydration heat generated by the reaction between the quick lime and/or calcined dolomite with moisture in the soil to form hydrated material.
    Type: Grant
    Filed: February 4, 1993
    Date of Patent: October 11, 1994
    Assignees: Nippon Hodo Co., Ltd., Murakashi Lime Industry Co., Ltd., Du Pont-Mitsui Fluorochemicals Co., Ltd.
    Inventors: Tetsuya Shimoda, Katuaki Ishikawa, Teruo Urano, Hiroshi Miyaji, Masatsune Ogura
  • Patent number: 5349003
    Abstract: An aqueous fluorine-containing polymer dispersion having particle diameters of 0.05-3 .mu.m, which is obtainable by emulsion-polymerizing 5-95 parts by weight of a monomer mixture consisting of at least one monomer selected from the group consisting of alkyl acrylates whose alkyl groups have 1-18 carbon atoms and alkyl methacrylates whose alkyl groups have 1-18 carbon atoms and optionally an ethylenically unsaturated compound copolymerizable with the alkyl acrylates and the alkyl methacrylates, in an aqueous medium in the presence of 100 parts by weight of particles of a vinylidene fluoride polymer; and an aqueous dispersion containing a fluorine-containing polymer which consists essentially of 95-30 parts by weight (in terms of solids content) of said aqueous fluorine-containing polymer dispersion and 5-70 parts by weight (in terms of solids content) of an aqueous dispersion of a water-soluble resin and/or a water-dispersible resin.
    Type: Grant
    Filed: February 9, 1993
    Date of Patent: September 20, 1994
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Minoru Kato, Teruo Hiraharu, Koichi Nishiwaki, Hiroshi Tadenuma
  • Patent number: 5340864
    Abstract: A fluororubber-containing powder coating composition comprising a fluororubber, an adhesion-preventing material and optionally a cross-linking agent, which composition has an particle size of 10 to 2,000 .mu.m and an apparent density of at least 0.2 g/cc, which provides a homogeneous smooth coated film having no or only a small amount of bubbles.
    Type: Grant
    Filed: May 25, 1993
    Date of Patent: August 23, 1994
    Assignee: Daikin Industries Ltd.
    Inventors: Nobuyuki Tomihashi, Masafumi Akamatsu, Yutaka Ueta
  • Patent number: 5328946
    Abstract: Perfluorinated cycloalkane solvents for dissolving high melting polymers containing tetrafluoroethylene, are disclosed. These solvents dissolve such polymers more rapidly, and/or are more stable, than previously known solvents. Also disclosed is a process for dissolution of the polymers and their resulting solutions. The solutions are useful for making polymer films, coatings and for encapsulating objects.
    Type: Grant
    Filed: August 28, 1992
    Date of Patent: July 12, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: William H. Tuminello, Robert J. Cavanaugh
  • Patent number: 5321059
    Abstract: A process for preparing a filler-containing PTFE granular powder, which comprises mixing uniformly a PTFE powder having an average particle size of not more than 100 .mu.m and a (semi-)hydrophilic filler which is surface-treated with an organosilane of the formula: ##STR1## in a two-phase liquid medium comprising water and a water-insoluble organic liquid having a surface tension of not more than 35 dynes/cm at 25.degree. C. Accordingly to the process, the separation of filler can be avoided, and a colorless molded article can be provided.
    Type: Grant
    Filed: November 9, 1992
    Date of Patent: June 14, 1994
    Assignee: Daikin Industries, Ltd.
    Inventors: Norimasa Honda, Kazuhide Sawada, Kenjiro Idemori, Hirokazu Yukawa
  • Patent number: 5308913
    Abstract: A wholly aromatic polyester resin composition contains:(1) a wholly aromatic polyester resin,(2) at least one member selected from a glass fiber and a silica-alumina fiber,(3) glass beads,(4) titanium oxide, and(5) a fluorocarbon polymerThe wholly aromatic polyester resin composition has high heat resistance and mechanical strengths, low anisotropy and excellent appearance, and shows low dissolution of components, excellent releasability and non-tackiness. It can be molded into an ovenware.
    Type: Grant
    Filed: January 2, 1992
    Date of Patent: May 3, 1994
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kuniaki Asai, Tadayasu Kobayashi, Mituo Maeda
  • Patent number: 5290835
    Abstract: An electrical or electronic part having excellent resistance to moist heat, such as a coil bobbin, a condenser case, an IC carrier, a plug, a socket or a fuse case, formed from a polybutylene naphthalenedicarboxylate resin as a raw material; and a flame-retardant resin composition and an electrical part therefrom are also provided. The flame-retardant resin composition exhibits high fluidity and forms little burr, and the electrical part has excellent flame retardancy and well-balanced properties.
    Type: Grant
    Filed: October 21, 1992
    Date of Patent: March 1, 1994
    Assignee: Teijin Limited
    Inventors: Toshio Hatayama, Mie Sasaki, Takeshi Kojima, Yoshinari Ogawa, Sakae Shimotsuma, Kouichi Sakai
  • Patent number: 5276261
    Abstract: 1,1,1,2-Tetrafluoroethane is a good chain-transfer agent for the preparation of polymers of tetrafluoroethylene in aqueous colloidal dispersion.
    Type: Grant
    Filed: November 30, 1992
    Date of Patent: January 4, 1994
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Ludwig Mayer, Gernot Lohr
  • Patent number: 5268411
    Abstract: A fluorine-containing polymer composition comprising a solvent containing a block compound composed of a polyfluorinated segment and a hydrocarbon segment and a fluorine-containing polymer having a fluorine-containing aliphatic cyclic structure dissolved in the solvent.
    Type: Grant
    Filed: February 17, 1993
    Date of Patent: December 7, 1993
    Assignee: Asahi Glass Company Ltd.
    Inventors: Shunsuke Yokotsuka, Isamu Kaneko, Kazuya Oharu
  • Patent number: 5258447
    Abstract: The invention provides a copolymer which comprises, as essential components, 25-75 mol % of a fluoroolefin such as CTFE, 10-70 mol % of a carboxylic acid vinyl ester, 3-75 mol % of a hydroxyl-containing allyl ether and 0.1-20 mol % of an unsaturated carboxylic acid having at least 6 carbon atoms in the molecule. The copolymer is soluble in various organic solvents and curable, e.g., with a blocked polyisocyanate or a modified melamine resin. The copolymer can be prepared by a suspension polymerization method in an aqueous medium and hence can be made very low in the contents of unreacted residual monomers. The copolymer is very suitable for use in electrodeposition paints.
    Type: Grant
    Filed: March 23, 1992
    Date of Patent: November 2, 1993
    Assignee: Central Glass Company, Limited
    Inventors: Toshio Koishi, Mikio Ootani, Toru Koshita
  • Patent number: 5242962
    Abstract: Aqueous fluoropolymer formulations containing in finely divided form from 15 to 75% by weight of a fluoropolymer which preferably has at least 40% by weight of tetrafluoroethylene units, from 0.5 to 10% by weight of an organic compound which has at least two, preferably 2-4, isocyanate groups and, optionally, up to 20% by weight of auxiliary or additive substances are prepared and used for coating yarn, in particular sewing yarn, and textile sheet materials.
    Type: Grant
    Filed: February 2, 1989
    Date of Patent: September 7, 1993
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Bernhard Jahn
  • Patent number: 5240978
    Abstract: A flame resistant molding composition containing a polycarbonate resin, a graft polymer and, as a flame retarding agent a phosphoric acid ester of novolak in combination with an anti drip agent is disclosed. The composition may further contain a thermoplastic copolymer and/or polyalkylene terephthalate. A process for the preparation of the composition is also disclosed.
    Type: Grant
    Filed: May 20, 1992
    Date of Patent: August 31, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl Fuhr, Friedemann Muller, Karl-Heinz Ott, Jochen Schoeps, Horst Peters, Werner Ballas
  • Patent number: 5237049
    Abstract: A process for purifying fluoropolymers by contacting them at temperatures above 140.degree. C. with a liquid perfluorinated cycloalkane. The resulting polymers are particularly useful where polymers with reduced impurities are desirable, such as in medical devices and in parts for the semiconductor manufacturing industry. The liquid perfluorinated cycloalkanes improve the adhesion of fluoropolymer to themselves and other materials.
    Type: Grant
    Filed: August 28, 1992
    Date of Patent: August 17, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Robert J. Cavanaugh, William H. Tuminello
  • Patent number: 5232975
    Abstract: A process for preconsolidating a planar porous fiber-thermoplastic resin layer which is unconstrained in the inplane directions by heating the layer to above the melting point of the resin, then applying pressure to the plane of the layer causing resin flow, thus orienting the fibers in the plane of the layer.
    Type: Grant
    Filed: January 16, 1992
    Date of Patent: August 3, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Clifford K. Deakyne
  • Patent number: 5219910
    Abstract: Concentrated, aqueous, colloidal dispersions of tetrafluoroethylene polymers having a polymer solids content of 25 to 70% by weight, which comprise, as the dispersion stabilizer, an amine oxide of the formula ##STR1## in which R.sup.1 is an alkyl radical having 6 to 22 carbon atoms or a mixture of such alkyl radicals and R.sup.2 is an alkyl radical having 1 to 22 carbon atoms or a mixture of such alkyl radicals, and in which R.sup.1 and R.sup.2 are identical or different and 50 to 0% by weight of the alkyl radicals R.sup.1 and R.sup.2 can be replaced by alkenyl radicals having 6 to 22 carbon atoms and having 1 to 3 C.dbd.C double bonds, are obtained by concentration with addition of these dispersion stabilizers. The dispersions are used for impregnating yarns and textile sheet-like structures.
    Type: Grant
    Filed: July 17, 1992
    Date of Patent: June 15, 1993
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Karlheinz Stahl, Wolfgang Neumann, Hubert Seitz
  • Patent number: 5216068
    Abstract: The properties of agglomerated molding powders of PTFE and hydrophobic fillers are improved if the agglomerates are washed after completing the agglomerating process with a liquid medium which contains a surface-active agent.
    Type: Grant
    Filed: December 13, 1990
    Date of Patent: June 1, 1993
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Tilman Zipplies
  • Patent number: 5210123
    Abstract: A vinylidene fluoride-hexafluoroisobutylene copolymer powder is employed to thicken a conventional fluorine-containing liquid lubricant to provide a grease composition which has improved lubrication character in metal bearing subjected to the simultaneous conditions of high load, high speed and elevated temperature.
    Type: Grant
    Filed: October 1, 1990
    Date of Patent: May 11, 1993
    Assignee: Dow Corning Corporation
    Inventor: Gerardo Caporiccio
  • Patent number: 5210112
    Abstract: It is an object of the present invention to provide a soil-stabilizing agent with less emission of dust, good reactivity, good behavior at mixing and good dispersibility and a method for soil stabilizing treatment capable of restraining the emission of dust in the procedure of sprinkling and mixing of the soil-stabilizing agent to soil.The soil-stabilizing agent according to the present invention comprises a mixture of a material mainly composed of quick lime and/or calcined dolomite and fibrillatable polytetrafluoroethylene resin.And the method for soil-stabilizing treatment according to the present invention comprises the following steps; adding a mixture of a material mainly composed of quick lime and/or calcined dolomite and fibrillatable polytetrafluoroethylene resin to soil, and mixing them under the hydration heat generated by the reaction between the quick lime and/or calcined dolomite with moisture in the soil to form hydrated material.
    Type: Grant
    Filed: July 8, 1991
    Date of Patent: May 11, 1993
    Assignee: Nippon Hodo Co., Ltd.
    Inventors: Tetsuya Shimoda, Katuaki Ishikawa, Teruo Urano, Hiroshi Miyaji, Masatsune Ogura
  • Patent number: 5198491
    Abstract: A tetrafluoroethylene base polymer-containing coating composition comprising a dispersion of a tetrafluoroethylene base polymer having a molecular weight of at least 5,000,000 in a liquid medium containing a surfactant, which is particularly useful for coating a fixing heater roller and a cooking utensil.
    Type: Grant
    Filed: May 22, 1992
    Date of Patent: March 30, 1993
    Assignee: Daikin Industries Ltd.
    Inventors: Norimasa Honda, Mutsusuke Namba, Yoshiaki Kataoka
  • Patent number: 5194481
    Abstract: Flame-retardant thermoplastic polyester resin compositions are formed by melt-blending a polyester base resin, and a flame-retardant package which includes (i) an organohalogen flame retardant, and (ii) a low-sulfate containing antimony oxide (i.e., having a sulfate content of 0.05% by weight or less) as an auxiliary flame retardant. The compositions of this invention may optionally include a drip-resistant effective amount of a polytetrafluoroethylene resin. The low sulfate-containing antimony oxide is preferably antimony trioxide.
    Type: Grant
    Filed: November 25, 1991
    Date of Patent: March 16, 1993
    Assignee: Polyplastics Co., Ltd.
    Inventors: Tatsuaki Takagi, Hiroyuki Amano
  • Patent number: 5179153
    Abstract: Polyimide compositions containing both graphite and fluoropolymer exhibit superior wear performance against aluminum.
    Type: Grant
    Filed: September 9, 1991
    Date of Patent: January 12, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Daniel E. George
  • Patent number: 5166251
    Abstract: A corrosive resistant coating with deep drawability characteristics which is applied to a metal substrate as a wet film and then heated to dry and initiate curing to provide a protective coating tenaciously bonded to the substrate. The composition has a corrosion inhibiting powder metal, a drawing agent of polytetrafluorethylene (PTFE), a primary bonding resin, and a vehicle of solvents. Preferably, the coating composition also has a secondary organic resin and thixotropic, metal suspension and hydroscopic agents. The cured coating composition on a metal substrate, in most instances, eliminates the needs for additional die drawing compounds when deep cold drawing the coated metal substrate.
    Type: Grant
    Filed: July 11, 1990
    Date of Patent: November 24, 1992
    Assignee: Depor Industries, Inc.
    Inventors: L. Donald Barrett, Burkhard Flamme, Dale R. Hahn, Peter E. Pelloski
  • Patent number: 5165975
    Abstract: A contrast medium-containing tube is provided which is a thermoplastic resin tube incorporated with a white bismuth compound composed mainly of bismuth oxide containing 70-85 wt % bismuth and having a particle diameter substantially smaller than 20 .mu.m. This contrast medium-containing tube looks white and remains white in appearance over a long period of time. It is easy to carry out extrusion molding for producing this contrast medium-containing tube.
    Type: Grant
    Filed: April 30, 1991
    Date of Patent: November 24, 1992
    Assignee: Junkosma Co., Ltd.
    Inventor: Keigo Goshiki
  • Patent number: 5153253
    Abstract: A bearing material comprising in wt %: 5 to 30 PTFE; 5 to 60 bronze; 1 to 20 graphite; balance PVDF is described together with test results of bearings having a lining of the material.
    Type: Grant
    Filed: November 13, 1990
    Date of Patent: October 6, 1992
    Assignee: The Glacier Metal Company Limited
    Inventors: Philip J. Moisey, Glyndwr J. Davies, Janette Johnston
  • Patent number: 5143729
    Abstract: Ultra-violet screening compounds have been combined with hydrophobic fluid and solid-repellent compounds to provide a spray, and ultimately a thin solid adherent layering, deposit or coating for fabrics and the like that simultaneously imparts both fade or photodegradiation-resisting properties, and fluid and soil repellent properties.
    Type: Grant
    Filed: February 25, 1991
    Date of Patent: September 1, 1992
    Assignee: Fadeguard, Inc.
    Inventor: Peter B. Thompson
  • Patent number: 5115026
    Abstract: Process for the production of a composite material based on a polymer matrix comprising homogeneously dispersed therein an organic and/or inorganic filler, said process consisting in mixing together the aqueous dispersions of the single components, in which the dispersed particles of the dispersion have a surface charge of the same sign and "zeta potential" between 10 and 100 mV (in absolute value) and wherein the ratio (in absolute value) between the "zeta potentials" of the particles of each dispersion is between 0.2 and 5.
    Type: Grant
    Filed: September 13, 1988
    Date of Patent: May 19, 1992
    Assignee: Ausimont S.p.A.
    Inventors: Mario Visca, Giancarlo Boero, Daria Lenti
  • Patent number: 5110858
    Abstract: A composition comprising tetrafluoroethylene polymers, selected poly(2,2-dialkylpropiolactones) and particulate carbon, especially conductive carbon. It is useful as a molding compound for making parts, especially for electrical uses.
    Type: Grant
    Filed: March 23, 1990
    Date of Patent: May 5, 1992
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Young H. Kim
  • Patent number: 5102931
    Abstract: The subject of the invention is flameproofed, non-dripping polyamide moulding compounds which contain specific amounts of the following:A) Phosphinic acid esters of polyphenols based on phenolaldehyde/ketone condensates,B) Anti-dripping agents (such as polyfluoroethylene polymers or aramides),C) Zinc borate,D) Thermoplastics with a predominantly aromatic main chain and a high thermal deflection temperature (Vicat B.gtoreq.180.degree. C.),and, if applicable, reinforcing agents and other additives for flameproofing and processing.
    Type: Grant
    Filed: July 23, 1990
    Date of Patent: April 7, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl Fuhr, Friedemann Muller, Karl-Heinz Ott, Aziz El-Sayed, Peter-Rolf Muller, Martin Wandel
  • Patent number: 5093409
    Abstract: Thermally and hydrolytically stable fluorocopolymers, especially melt-processible fluorocopolymers, for example, tetrafluoroethylene/hexafluoropropylene copolymers, having --COOH and/or --COF groups on the polymer chains are contacted and reacted with a secondary or tertiary amine and heated at 160.degree. -400.degree. C. for a time sufficient to convert --COOH and/or --COF groups to stable --CF.sub.2 H groups, the resultant stabilized copolymers being useful, for example, in electrically conductive compositions having a good combination of melt flow and electrical conductivity.
    Type: Grant
    Filed: March 21, 1991
    Date of Patent: March 3, 1992
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Marlin D. Buckmaster
  • Patent number: 5085863
    Abstract: A tube comprises a wall formed from thermoplastic material. The wall is provided with an X-ray opaque agent comprised of a white bismuth compound mixture of bismuth oxide and a white bismuth salt such as bismuth nitrate and bismuth sulfate, the bismuth compound mixture having a bismuth content of 83 to 88% by weight.
    Type: Grant
    Filed: April 17, 1990
    Date of Patent: February 4, 1992
    Assignee: Junkosha Co., Ltd.
    Inventor: Keigo Goshiki
  • Patent number: 5081171
    Abstract: A liquid composition for protecting a positively charged surface, the composition comprising: negatively charged polytetrafluoroethylene polymer resin particles and at least one member of the group consisting of methyltrimethoxysilane and an amino functional polysiloxane; whereby the negatively charged polytetrafluoroethylene molecules fuse to the surface upon exposure to ambient temperatures above about 68 degrees Fahrenheit.
    Type: Grant
    Filed: February 14, 1989
    Date of Patent: January 14, 1992
    Inventor: Charles R. Nixon
  • Patent number: 5081176
    Abstract: Aromatic thermoplastic compositions are provided having reduced total smoke released upon burning in accordance with ASTM-EO96. The aromatic thermplastic compositions utilize an effective amount of tin monoxide, and which are substantially free of antimony trioxide and brominated organic flame retardant resins. Minor amounts of polytetrafluoroethylene resin and glass fiber also contribute to the reduction of total smoke release upon burning of the thermoplastic polyester.
    Type: Grant
    Filed: September 24, 1990
    Date of Patent: January 14, 1992
    Assignee: General Electric Company
    Inventor: Douglas G. Hamilton
  • Patent number: 5075365
    Abstract: Orifices, cavities or interstices which are formed when printing plates are mounted on plate cylinders are closed and/or sealed by means of a sealing or closing compound, a pasty material which is viscoplastic at room temperature and based on a dispersion of a solid, highly fluorinated olefin polymer powder in an inert, sparingly volatile, organic dispersing liquid being used as the sealing or closing compound.
    Type: Grant
    Filed: March 25, 1988
    Date of Patent: December 24, 1991
    Assignee: BASF Aktiengesellschaft
    Inventor: Guenter Wallbillich
  • Patent number: 5070129
    Abstract: An improved polyolefin composition, film product, and a method of preparation are provided. Fluoropolymers, preferably fluoroelastomers, and metal stearates, are added to polyolefins. The composition has and exhibits improved impact strength and better processability.
    Type: Grant
    Filed: February 6, 1990
    Date of Patent: December 3, 1991
    Assignee: Phillips Petroleum Company
    Inventor: Fay W. Bailey
  • Patent number: 5043393
    Abstract: According to the present invention, there is provided an improvement of a process for producing fluorine-containing copolymers comprising copolymerizing(a) a chlorinated fluoroolefin,(b) vinyl ether, and(c) an organosilicon compound having an olefinically unsaturated bond and a hydrolyzable bond,the improvement resides in that a chlorine trapping agent is allowed to exist in the system during the copolymerization reaction and/or the purification of the resulting copolymer, and the fluorine-containing copolymers are free from coloration.Further, according to the present invention, a fluorine-containing copolymer composition containing a specific curing catalyst is also provided and said composition is excellent in adhesion to substrates or base materials.
    Type: Grant
    Filed: December 1, 1989
    Date of Patent: August 27, 1991
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Shiro Honma, Takashi Izumi, Hajime Inagaki, Sakae Murakami
  • Patent number: 5021527
    Abstract: The present invention provides a fluorine-containing water- and oil-repellent composition comprising a fluorine-containing acrylate represented by the formula: ##STR1## wherein X is a fluorine atom or --CFX.sup.1 X.sup.2 group (wherein X.sup.1 and X.sup.2 are the same or different and are each a hydrogen atom or fluorine atom), Y is alkylene having 1 to 3 carbon atoms, --CH.sub.2 CH.sub.2 N(R)SO.sub.2 -- group (wherein R is alkyl having 1 to 4 carbon atoms) or --CH.sub.2 CH(OZ)CH.sub.2 -- (wherein Z is a hydrogen atom or acetyl), and Rf is fluoroalkyl having 3 to 21 carbon atoms, or fluoroalkyl having 3 to 21 carbon atoms and 1 to 10 oxygen atoms in its carbon chain (wherein no two oxygen atoms are present adjacent to each other).
    Type: Grant
    Filed: December 11, 1989
    Date of Patent: June 4, 1991
    Assignee: Daikin Industries, Ltd.
    Inventors: Akira Ohmori, Hiroshi Inukai
  • Patent number: 5021501
    Abstract: The present invention provides a fluorine-containing water- and oil-repellent composition comprising a fluorine-containing acrylate represented by the formula: ##STR1## wherein X is a fluorine atom or --CFX.sup.1 X.sup.2 group (wherein X.sup.1 and X.sup.2 are the same or different and are each a hydrogen atom or fluorine atom), Y is alkylene having 1 to 3 carbon atoms, --CH.sub.2 CH.sub.2 N(R)SO.sub.2 -- group (wherein R is alkyl having 1 to 4 carbon atoms) or --CH.sub.2 CH(OZ)CH.sub.2 -- (wherein Z is a hydrogen atom or acetyl), and Rf is fluoroalkyl having 3 to 21 carbon atoms, or fluoroalkyl having 3 to 21 carbon atoms and 1 to 10 oxygen atoms in its carbon chain (wherein no two oxygen atoms are present adjacent to each other).
    Type: Grant
    Filed: December 11, 1989
    Date of Patent: June 4, 1991
    Assignee: Daikin Industries, Ltd.
    Inventors: Akira Ohmori, Hiroshi Inukai
  • Patent number: 5008327
    Abstract: An electrodeposition coating composition comprising a fluorine-containing copolymer, a curing agent and an aqueous medium, said composition having a fluorine ion content of not more than 15 ppm.According to the composition of the present invention, since a bad influence to electrodeposition due to fluorine ion can be remarkably inhibited, the excellent electrodeposited film can be obtained therefrom.
    Type: Grant
    Filed: August 8, 1990
    Date of Patent: April 16, 1991
    Assignees: Kansai Paint Co., Ltd., Daikin Industries, Ltd.
    Inventors: Shinji Shirai, Hiroyuki Negishi, Nobuyuki Tomihashi, Masayuki Yamane