Four Or More Fluorine Atoms Patents (Class 524/546)
  • Publication number: 20130109790
    Abstract: Described herein is a composition, article and method thereof, wherein the composition comprises (i) a fluoropolymer and (ii) an ionic liquid.
    Type: Application
    Filed: July 8, 2011
    Publication date: May 2, 2013
    Applicant: 3M INNOVATIVE PROPERTIES COMPANY
    Inventors: Tatsuo Fukushi, Haruhiko Miyazawa, Jun Fujita, Atsushi Toyota, William M. Lamanna, Shih-Hung Chou
  • Patent number: 8426509
    Abstract: The invention pertains to a thermoplastic fluoropolymer composition comprising: at least one thermoplastic partially fluorinated fluoropolymer having a melt flow index (MFI) of less than 10 g/10 min, as measured according to ASTM D-1238 under a piston load of 5 kg polymer A; from 0.05 to 5% by weight of A at least one (per)fluoropolyether, polymer B; and from 0 to 10% by weight of A of at least one per(halo)fluoropolymer polymer C. The addition of a (per)fluoropolyether B and, optionally, of a per(halo)fluoropolymer C advantageously enables improvement of rheological behavior of thermoplastic partially fluorinated fluoropolymer A, making possible processing in less severe conditions and yielding final parts with outstanding surface aspect and good homogeneity and coherency. Still objects of the inventions are the process for manufacturing said thermoplastic fluoropolymer composition and the articles thereof.
    Type: Grant
    Filed: June 27, 2006
    Date of Patent: April 23, 2013
    Assignee: Solvay Solexis S.p.A.
    Inventors: Julio A. Abusleme, Giulo Brinati, Pier Antonio Guarda
  • Publication number: 20130089671
    Abstract: The present invention generally relates to a novel polymeric material formed, at least in part, from monomeric material comprising 2,3,3,3-tetrafluoropropene (CF3CF?CH2, 1234yf), to polymeric compositions, to coating compositions, and to uses thereof.
    Type: Application
    Filed: October 4, 2012
    Publication date: April 11, 2013
    Applicant: HONEYWELL INTERNATIONAL INC.
    Inventor: HONEYWELL INTERNATIONAL INC.
  • Publication number: 20130079461
    Abstract: A novel aqueous polymerization process for making fluoropolymer dispersions is disclosed in which non-ionic non-fluorinated emulsifier is used to produce fluoropolymer emulsions. The emulsifiers used in the invention are those that contain segments of polyethylene glycol, polypropylene glycol, and/or polytetamethylene glycol with repeating units of 3 to 100. The process and fluoropolymer produced contain no fluorinated surfactant.
    Type: Application
    Filed: November 20, 2012
    Publication date: March 28, 2013
    Applicant: Arkema Inc.
    Inventors: Ramin Amin-Sanayei, Christyn B. Olmstead
  • Patent number: 8404309
    Abstract: Blended fluoropolymer compositions that may be applied as a coating to a flexible substrate. The compositions include at least one high molecular weight polytetrafluoroethylene (HPTFE), at least one a low molecular weight polytetrafluoroethylene (LPTFE) and at least one melt processible fluoropolymer (MPF). After being applied to the flexible substrate, optionally over a primer or basecoat and/or midcoat and then cured, the compositions form coatings that demonstrate improvement in one or more of abrasion resistance, release characteristics, translucency/transparency, and impermeability.
    Type: Grant
    Filed: September 25, 2009
    Date of Patent: March 26, 2013
    Assignee: Whitford Corporation
    Inventors: Leonard W. Harvey, Helen L. Brain
  • Patent number: 8403332
    Abstract: The seal member includes a tetrafluoroethylene-propylene copolymer (FEPM) and carbon nanofibers. The seal member has a number of cycles to fracture of 10 or more when subjected to a tension fatigue test at a temperature of 150° C., a maximum tensile stress of 2 N/mm, and a frequency of 1 Hz. The seal member exhibits excellent heat resistance and abrasion resistance.
    Type: Grant
    Filed: December 28, 2009
    Date of Patent: March 26, 2013
    Assignees: Nissan Kogyo Co., Ltd, Schlumberger Technology Corporation, Shinshu University
    Inventors: Toru Noguchi, Hiroyuki Ueki, Shigeki Inukai, Masaei Ito, Raghu Madhavan, Morinobu Endo, Satoshi Iinou
  • Patent number: 8399565
    Abstract: The invention pertains to a thermoplastic fluoropolymer composition comprising: at least one thermoplastic partially fluorinated fluoropolymer having a melt flow index (MFI) of less than 10 g/10 min, as measured according to ASTM D-1238 under a piston load of 5 kg polymer A; from 0.05 to 5% by weight of A at least one (per)fluoropolyether, polymer B; and from 0 to 10% by weight of A of at least one per(halo)fluoropolymer polymer C. The addition of a (per)fluoropolyether B and, optionally, of a per(halo)fluoropolymer C advantageously enables improvement of rheological behavior of thermoplastic partially fluorinated fluoropolymer A, making possible processing in less severe conditions and yielding final parts with outstanding surface aspect and good homogeneity and coherency. Still objects of the inventions are the process for manufacturing said thermoplastic fluoropolymer composition and the articles thereof.
    Type: Grant
    Filed: June 27, 2006
    Date of Patent: March 19, 2013
    Assignee: Solvay Solexis S.p.A.
    Inventors: Julio A. Abusleme, Giulo Brinati, Pier Antonio Guarda
  • Patent number: 8399063
    Abstract: An anticurl backing layer dispersion, including: a volatile carrier liquid, solid organic or inorganic particles, and a surfactant, wherein the dispersion does not include a binder. An anitcurl backing layer composition including the above-described dispersion, a binder solution comprising a binder and a volatile carrier liquid, and optionally a resin, is also disclosed.
    Type: Grant
    Filed: February 10, 2006
    Date of Patent: March 19, 2013
    Assignee: Xerox Corporation
    Inventors: Cindy C. Chen, Bryan G. Ng, Lanhui Zhang, Man Kit Yip
  • Publication number: 20130066010
    Abstract: The present invention provides a molded article for a biodiesel fuel having excellent durability against a biodiesel fuel. The invention is a molded article for a biodiesel fuel of which the surface to be contacted with a biodiesel fuel is made of a fluorine-containing ethylenic resin.
    Type: Application
    Filed: November 5, 2012
    Publication date: March 14, 2013
    Applicant: DAIKIN INDUSTRIES, LTD.
    Inventor: Daikin Industries, Ltd.
  • Publication number: 20130059961
    Abstract: A composition comprising at least one vinylidene fluoride (VDF) polymer [polymer (F)]; and inorganic particles at least partially coated with at least one perfluoropolyether block copolymer [polymer (E)] comprising: A) one or more (per)fluoropolyoxyalkylene segment (chain Rf), comprising recurring units having at least one catenary ether bond and at least one fluorocarbon moiety, and B) one or more polyalkylene segment (chain Ra) comprising recurring units of formula: —(CR1R2—CR3R4)—, wherein R1, R2, R3, R4, equal to or different from each other, are selected from the group consisting of H, halogens (preferably F, Cl); C1-C6 (hydro)carbon groups, optionally containing fluorine or other heteroatoms, preferably perfluoroalkyl or (per)fluorooxyalkyl. The invention also discloses a method of coating various substrates using said composition.
    Type: Application
    Filed: May 19, 2011
    Publication date: March 7, 2013
    Applicant: SOLVAY SA
    Inventors: Vincenzo Arcella, Eliana Ieva, Shiow-Ching Lin, Marco Avataneo, Giuseppe Marchionni
  • Publication number: 20130040148
    Abstract: To provide a coating composition capable of forming a coating film having excellent functions on the surface of a solar heat-collecting reflective plate, and a solar heat-collecting reflective plate obtainable by such a composition, as well as processes for their production. A coating composition for coating the surface of a solar heat-collecting reflective plate, which comprises a fluorinated copolymer having repeating units derived from ethylene and repeating units derived from tetrafluoroethylene, and a solvent capable of dissolving the fluorinated copolymer at a temperature of not higher than the melting point of the fluorinated copolymer; a solar heat-collecting reflective plate obtainable by such a composition; and processes for producing such a composition and a reflective plate.
    Type: Application
    Filed: October 16, 2012
    Publication date: February 14, 2013
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventor: ASAHI GLASS COMPANY, LIMITED
  • Patent number: 8362168
    Abstract: The present invention provides an aqueous fluoropolymer dispersion having good mechanical characteristics and storage stability and containing substantially no fluorinated surfactant. The present invention is related to an aqueous fluoropolymer dispersion comprising a dispersed fluoropolymer particle with an average primary particle diameter of 50 to 400 nm, a surface layer of the dispersed fluoropolymer particle being obtained by emulsion polymerization of a monomer composition consisting of 99.999 to 98 mole percent of tetrafluoroethylene and 0.001 to 2 mole percent of a modifier monomer, a fluorinated surfactant content being not higher than 50 ppm, a fluoropolymer content being 20 to 75% by mass, and a nonfluorinated nonionic surfactant content being 2 to 15% by mass relative to 100% by mass of the fluoropolymer.
    Type: Grant
    Filed: August 8, 2011
    Date of Patent: January 29, 2013
    Assignee: Daikin Industries, Ltd.
    Inventors: Chie Sawauchi, Nobuhiko Tsuda
  • Publication number: 20130023620
    Abstract: A process for manufacturing a fluoropolymer hybrid organic/inorganic composite comprising: (i) mixing at least one fluoropolymer comprising recurring units derived from at least one (meth)acrylic monomer [monomer (MA)] of formula: at least one metal compound [compound (M)] of formula: X4-mAYm, wherein each of R1, R2, R3, equal or different from each other, is independently a hydrogen atom or a C1-C3 hydrocarbon group, and ROH is a hydrogen atom or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group [polymer (F)]; wherein m is an integer from 1 to 4, A is a metal selected from the group consisting of Si, Ti and Zr, Y is a hydrolysable group, X is a hydrocarbon group comprising one or more functional groups; (ii) reacting at least a fraction of hydroxyl groups of the ROH groups of said monomer (MA) of said polymer (F) with at least a fraction of said compound (M), to obtain a grafted polymer comprising pendant —Ym-1AX4-m groups, with m, Y, A and X having same meaning as above; and (iii) hy
    Type: Application
    Filed: March 31, 2011
    Publication date: January 24, 2013
    Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
    Inventors: Julio A. Abusleme, Riccardo Pieri, Ivan Pagin
  • Patent number: 8357739
    Abstract: A thermoplastic composition that includes a base polymer, a fluoropolymer, and a fluoride scavenger having suitable fluoride levels such that use in the electronics industry is appropriate. An extrusion method may be used for making the thermoplastic composition. The compositions may then be used to form a molded article. The composition has lower fluoride levels as compared to thermoplastic compositions without the fluoride scavenger making it suitable for use in electronic applications, as well as medical or food or beverage applications where fluoride ions are a concern.
    Type: Grant
    Filed: December 11, 2006
    Date of Patent: January 22, 2013
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Xin Huang, Tong Sun, Huagui Yang, David Xiangping Zou
  • Patent number: 8357747
    Abstract: The present invention describes polymer compositions comprising fluoroelastomer and expanded perlite and uses thereof.
    Type: Grant
    Filed: December 28, 2007
    Date of Patent: January 22, 2013
    Assignee: Imerys Filtration Minerals, Inc.
    Inventors: Michael Greene, Roger Norman Rothon, Nigel Julian Keith Danvers, Qingchun Hu
  • Publication number: 20130017334
    Abstract: To provide a coating composition containing a fluorinated copolymer having repeating units derived from ethylene and tetrafluoroethylene, which can be formed into a coating film by coating and which can be produced at a relatively low temperature, and a process for its production, and a process for forming a coating film of the fluorinated copolymer by using this composition, which can be carried out at a relatively low temperature. A coating composition comprising microparticles of a fluorinated copolymer (ETFE) having repeating units derived from ethylene and repeating units derived from tetrafluoroethylene, and a solvent capable of dissolving ETFE at a temperature of not higher than the melting point of ETFE, wherein the microparticles of ETFE are microparticles precipitated from a solution having ETFE dissolved in the solvent, and are dispersed in the solvent.
    Type: Application
    Filed: September 14, 2012
    Publication date: January 17, 2013
    Applicant: ASAHI GLASS COMPANY, Limited
    Inventors: Takashi NAKANO, Tomoyuki FUJITA, Hiroshi YAMAMOTO, Yoshitomo MORIZAWA, Naoko SHIROTA
  • Patent number: 8354469
    Abstract: The invention concerns a composition comprising: at least one melt-processible per(halo)fluoropolymer (polymer A); from 0.01 to 5% by weight of polymer A of at least one smoke-suppressant agent (S) having a decomposition temperature of at least 350° C., selected from the group consisting of molybdenum derivatives, borates of an alkaline-earth metal or of a group 12 transition metal, and mixtures thereof; optionally, at least one oxide of a metal different from molybdenum. The composition of the invention excels simultaneously in providing excellent insulating properties on meal wires or optical fibers, outstanding processing parameters for high speed cable manufacture and high performance ratings on flammability, smoke generation and fuel load. Advantageously, cables comprising said composition comply with 25/50/8 requirements according to NFPA-255 and -259 for limited combustible materials.
    Type: Grant
    Filed: November 23, 2006
    Date of Patent: January 15, 2013
    Assignee: Solvay Solexis, Inc.
    Inventors: Anthony V. Zangara, Jeffrey A. Hrivnak
  • Patent number: 8354461
    Abstract: The present invention discloses a foamable composition. The foamable composition includes a partially-crystalline melt processible perfluoropolymer and a foam nucleating package. The foamable composition has a uniform foam cell size where the foam cell size of at least 90% of the foamed cells is 50 micrometers or less. The foam nucleating package ranges from 0.1 to 10 wt % of the combined weight of the perfluoropolymer and the foam nucleating package.
    Type: Grant
    Filed: March 24, 2009
    Date of Patent: January 15, 2013
    Assignee: E I du Pont de Nemours and Company
    Inventors: Sundar Kilnagar Venkataraman, Robert Thomas Young
  • Publication number: 20120328885
    Abstract: Methods and apparatus for depositing polymer films are provided herein. In some embodiments a method for depositing a dielectric film may include flowing a liquid polymer precursor material through an orifice spaced apart from a substrate upon which the liquid polymer precursor material is to be deposited; providing a potential difference between the orifice and the substrate to attract the liquid polymer towards the substrate and form a deposited material on the substrate; and curing the deposited material to form a dielectric film on the substrate.
    Type: Application
    Filed: June 15, 2012
    Publication date: December 27, 2012
    Applicant: APPLIED MATERIALS, INC.
    Inventor: SUKTI CHATTERJEE
  • Patent number: 8338519
    Abstract: A PTFE resin composition, which comprises PTFE resin, and metal carbide powder having a Vickers hardness of 1,200 HV, or more, and which preferably further contains an inorganic filler other than the metal carbide powder, for example, carbon fibers, glass fibers, etc., has an improved abrasion resistance, when molded into resin seal rings, etc., by reducing a self-abrasion amount of the resin against hard mating metals having a rough surface (Rz of about 6.3 to about 9.0 according to JIS B0601-1994), and by polishing the mating material roughness rapidly.
    Type: Grant
    Filed: October 12, 2006
    Date of Patent: December 25, 2012
    Assignee: NOK Corporation
    Inventors: Kazuhiro Yamamoto, Shinya Nakaoka, Takaaki Yasudomi
  • Patent number: 8338518
    Abstract: A novel aqueous polymerization process for making fluoropolymer dispersions is disclosed in which non-ionic non-fluorinated emulsifier is used to produce fluoropolymer emulsions. The emulsifiers used in the invention are those that contain segments of polyethylene glycol, polypropylene glycol, and/or polytetamethylene glycol with repeating units of 3 to 100. The process and fluoropolymer produced contain no fluorinated surfactant.
    Type: Grant
    Filed: December 8, 2006
    Date of Patent: December 25, 2012
    Assignee: Arkema Inc.
    Inventors: Ramin Amin-Sanayei, Christyn Olmstead
  • Patent number: 8329813
    Abstract: A process for reducing the fluoroether carboxylic acid or salt content of aqueous fluoropolymer dispersion. The fluoroether carboxylic acid or salt employed comprises fluoroether carboxylic acid or salt having the formula below: [R1—O-L-COO?]Y+ wherein R1 is a linear, branched or cyclic partially or fully fluorinated aliphatic group which may contain ether linkages; L is a branched partially or fully fluorinated alkylene group which may contain ether linkages; and Y+ is hydrogen, ammonium or alkali metal cation. The process comprises adding stabilizer to the aqueous fluoropolymer dispersion to form a stabilized aqueous fluoropolymer dispersion and heating the stabilized aqueous fluoropolymer dispersion to decarboxylate the fluoroether carboxylic acid or salt to produce a fluoroether byproduct. At least a portion of the fluoroether byproduct is removed.
    Type: Grant
    Filed: May 5, 2010
    Date of Patent: December 11, 2012
    Assignee: E I du Pont de Nemours and Company
    Inventors: David William Johnson, Kenneth Scott Teter
  • Publication number: 20120309892
    Abstract: A binder composition for the positive electrode of an electric storage device. The composition contains polymer alloy particles composed of: a polymer (A) having a recurring unit derived from vinylidene fluoride, ethylene tetrafluoride, propylene hexafluoride, or mixtures thereof; a polymer (B) having a recurring unit derived from an unsaturated carboxylic acid ester; and water. The average diameter of the polymer alloy particles is 50 to 400 nm. The polymer alloy particles are synthesized by absorbing a monomer (b) to the polymer (A) and polymerizing the monomer (b) to synthesize the polymer (B).
    Type: Application
    Filed: December 28, 2011
    Publication date: December 6, 2012
    Applicant: JSR CORPORATION
    Inventors: Yoshiharu Ootsuka, Hironori Kitaguchi, Nobuyuki Fujihara
  • Publication number: 20120298196
    Abstract: The present invention provides a weather-resistant sheet for a solar cell module, which has better adhesion to a water impermeable sheet, better blocking resistance against the water impermeable sheet, and better adhesion to EVA that is a sealant; a weather-resistant sheet for a solar cell module in which a cured coating film layer thereof can suppress UV transmission significantly; a product including the sheet; and a process for producing the sheet.
    Type: Application
    Filed: January 13, 2011
    Publication date: November 29, 2012
    Applicant: DAIKIN INDUSTRIES, LTD.
    Inventors: Hideto Nakagawa, Kenji Goboh, Kazuko Aoki, Takayuki Araki, Hiroshi Torii, Yoshihisa Yamamoto, Eiji Fujita
  • Publication number: 20120302678
    Abstract: The present invention relates to an ionic liquid-polymer gel membrane with improved gas permeability, and a preparation method thereof, and more specifically, to a membrane prepared to allow an ionic liquid to be dispersed in a polymer gel, thereby improving gas permeability. Particularly, the present invention relates to an ionic liquid-polymer gel membrane wherein membrane selectivity and permeability exceed an upper bound by increasing the amount of dispersed ionic liquid, and a preparation method thereof. The preparation method of the membrane for separating a specific gas from a mixture gas according to the present invention comprises the following steps of: mixing a polymer, an ionic liquid and PC as a solvent to prepare a mixture solution; and drying the mixture solution to remove the solvent from the mixture solution. In addition, the polymer is polyvinylidene fluoride-hexafluoropropyl copolymer (PVdF-HFP), and the ionic liquid is 1-ethyl-3-methylimidazolium tetrafluoroborate ([emim][BF4]).
    Type: Application
    Filed: March 23, 2010
    Publication date: November 29, 2012
    Applicant: KOREA INSTITUTE OF ENERGY RESEARCH
    Inventors: Il Hyun Baek, Sung Chan Nam, Jung Hoon Park, Yeo Il Yoon, Sang Do Park
  • Publication number: 20120295117
    Abstract: A coating material including a perfluorocarbon sulfonic acid resin which is a copolymer including a polymerization unit represented by —(CF2—CFZ)—, in the formula, Z being H, Cl, F, or a C1-C3 perfluoroalkyl group, and a polymerization unit represented by —(CF2—CF(—O—(CF2)m—SO3H))—, in the formula, m being an integer of 1 to 12, and the perfluorocarbon sulfonic acid resin has an equivalent weight EW of 200 to 1000. Also disclosed is a laminate including a base material and a hydrophilic layer formed from the coating material.
    Type: Application
    Filed: January 31, 2011
    Publication date: November 22, 2012
    Applicants: DAIKIN INDUSTRIES, LTD., ASAHI KASEI E-MATERIALS CORPORATION
    Inventors: Yuko Iizuka, Naoto Miyake, Tadashi Ino, Masahiro Kondo, Katsuhiko Imoto
  • Publication number: 20120247531
    Abstract: Anti-reflective coatings and coating solutions, optically transparent elements and improved processes for preparing AR coatings and coating solutions are described. The anti-reflective coatings are formed from a fluoropolymer derived from at least one fluoropropene compound. The fluoropolymer may applied as a coating solution that is curable at low temperatures.
    Type: Application
    Filed: March 28, 2011
    Publication date: October 4, 2012
    Applicant: HONEYWELL INTERNATIONAL INC.
    Inventors: SUDIP MUKHOPADHYAY, DAVID NALEWAJEK
  • Publication number: 20120247457
    Abstract: The present invention is to provide a coating composition for surface coating capable of forming a cured coating film layer that protects a reflective substrate of a solar heat-collecting reflective plate and that is excellent in the impact resistance and the weather resistance such as the heat resistance and the water resistance, as well as a solar heat-collecting reflective plate having such a cured coating film layer, and a process for its production. A coating composition for surface coating to be used for the production of a solar heat-collecting reflective plate having a reflective substrate made of metal, which comprises a fluoropolymer (A) having units (A1) derived from a fluoroolefin and units (A2) having a crosslinkable group. Further, a solar heat-collecting reflective plate having a cured coating film layer formed from the coating composition for surface coating, and a process for its production.
    Type: Application
    Filed: June 13, 2012
    Publication date: October 4, 2012
    Applicant: Asahi Glass Company, Limited
    Inventors: Shun SAITO, Masataka Aikawa, Takashi Takayanagi, Sho Masuda
  • Patent number: 8278366
    Abstract: The present invention relates generally to the use of talc as a chemical foaming agent in perfluoropolymers to form foamable and foamed compositions. For example, in one aspect, a foamable composition is disclosed, which comprises (i) one or more base perfluoropolymers comprising at least 50 percent by weight of the composition, and (ii) talc blended with the one or more base perfluoropolymers, where the talc comprises 3 percent to about 15 percent by weight of the composition. Each of the perfluoropolymers is selected from the group consisting of tetrafluoroethylene/perfluoromethylvinyl ether copolymer (MFA), hexafluoropropylene/tetrafluoroethylene copolymer (FEP) and perfluoroalkoxy (PFA) and any blend thereof, where hydrogen-containing fluoropolymers are absent from the composition. The one or more base perfluoropolymers are melt-processable at one or more elevated processing temperatures of at least about 600° F.
    Type: Grant
    Filed: May 17, 2011
    Date of Patent: October 2, 2012
    Inventors: Charles Glew, Kenneth Boyle, Bradley L. Kent, Jeffrey A. Hrivnak
  • Publication number: 20120231332
    Abstract: A binder composition of the present invention is for a non-aqueous secondary battery with excellent adhesion between an electrode active material and a current collector. A degree of electrode swelling with an electrolytic solution at a high temperature is small. This binder composition can be used in production of an electrode mixture for a non-aqueous secondary battery. The binder composition can comprise a binder made of a fluorinated copolymer having repeating units derived from tetrafluoroethylene and repeating units derived from propylene, and a solvent or dispersing medium, wherein the fluorinated copolymer has a weight average molecular weight of from 10,000 to 300,000.
    Type: Application
    Filed: April 20, 2012
    Publication date: September 13, 2012
    Applicant: Asahi Glass Company, Limited
    Inventor: Takehiro KOSE
  • Patent number: 8263224
    Abstract: Disclosed is a resin composition containing a hexagonal ferrite and a resin, which is characterized in that the hexagonal ferrite is contained in an amount of 50-98 parts by weight per 100 parts by weight of the total of the resin composition.
    Type: Grant
    Filed: November 28, 2007
    Date of Patent: September 11, 2012
    Assignee: Asahi Kasei Chemicals Corporation
    Inventor: Tetsuji Tokiwa
  • Publication number: 20120214924
    Abstract: The present invention is directed to compositions, baths, and methods for composite plating including polytetrafluoroethylene (PTFE), and more particularly, to compositions, baths, and methods of composite plating with PTFE in a metal or alloy matrix where the materials used in the process contain no or essentially no PFOS (perfluorooctane sulfonate) and/or no PFOA (perfluorooctanoic acid).
    Type: Application
    Filed: February 22, 2011
    Publication date: August 23, 2012
    Inventor: Michael David FELDSTEIN
  • Patent number: 8247076
    Abstract: Composition comprising fluoropolymers, such as polytetrafluoroethylene (PTFE), poly(hexafluoroethylene), poly(tetrafluoroethylene-hexafluoroethylene), and poly(tetrafluoroethylene-ethylene-propylene), which are dispersed in flame retardants, such as organic, bromine compounds and/or organic phosphorus compounds, and that consist of particles that comprise one or more fluoropolymers and flame retardants. The fluoropolymers may be enveloped by the flame retardant.
    Type: Grant
    Filed: December 2, 2004
    Date of Patent: August 21, 2012
    Assignee: Bromine Compounds Ltd.
    Inventors: Yoav Bar-Yaakov, Pierre Georlette, Daniel Plewinski, Ita Finberg
  • Patent number: 8247519
    Abstract: The invention is directed to shaped articles fabricated from polyamides comprising fluoroether functionalized aromatic moieties. Particular polyamides include nylon 6, 6 and nylon 6 copolyamides that comprise fluoroether functionalized aromatic amide repeat units. The shaped articles hereof are characterized by reduced surface tension and are useful for imparting soil resistant films, molded parts, fibers, fabrics, and carpets.
    Type: Grant
    Filed: June 22, 2011
    Date of Patent: August 21, 2012
    Assignee: E I du Pont de Nemours and Company
    Inventors: Neville Everton Drysdale, David Neil Marks, Fredrik Nederberg
  • Patent number: 8247486
    Abstract: Creep resistant fluoropolymer is made by blending a melt-fabricable fluoropolymer having a melt flow rate of no greater than about 7 g/10 min with milled carbon fiber and forming the resultant blend into an article, the carbon fiber content of the blend being from about 15 to 35 wt % based on the combined weight of the carbon fiber and the fluoropolymer.
    Type: Grant
    Filed: June 11, 2009
    Date of Patent: August 21, 2012
    Assignee: E.I. du Pont de Nemours and Company
    Inventor: Jacob Lahijani
  • Publication number: 20120208030
    Abstract: A coated leather substrate having at least one surface that comprises at least one first layer above that surface and at least one second layer above that first layer and, the first layer comprises at least one polymer and wherein the second layer being different in its chemical composition from the first layer comprises the reaction product of a cross-linking reaction of at least one first composition said first composition comprising one or more compounds having at least one fluoropolyether segment and at least two cross-linkable groups and said second composition comprising at least one fluorinated polyolefin. Furthermore are provided a coating composition, methods of coating leather substrates and use of the coating compositions.
    Type: Application
    Filed: October 27, 2010
    Publication date: August 16, 2012
    Inventor: Frans A. Audenaert
  • Publication number: 20120196974
    Abstract: A cured perfluoroelastomer diaphragm comprises A) perfluoroelastomer and B) 10 to 50 parts by weight, per hundred parts by weight perfluoroelastomer, of carbon black a nitrogen adsorption specific area of 70-150 m2/g and a dibutyl phthalate absorption of 90-180 ml/100 g.
    Type: Application
    Filed: August 8, 2011
    Publication date: August 2, 2012
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventors: KAORI IWAMOTO, BUNICHI RAI
  • Patent number: 8222322
    Abstract: A method of making a fluoropolymer dispersion by first providing a fluoropolymer dispersion comprising fluoropolymer particles and one or more fluorinated surfactants selected from fluorinated carboxylic acids or salts thereof having the general formula: [Rf—O-L-COO?]iXi+??(I) wherein L represents a linear fully fluorinated alkylene group, Rf represents a linear partially or fully fluorinated aliphatic group or a linear partially or fully fluorinated aliphatic group interrupted with one oxygen atom, Xi+ represents a cation having the valence i and i is 1, 2 or 3; then adding one or more non-fluorinated surfactants selected from anionic and non-ionic surfactants followed by reducing the total amount of the one or more fluorinated surfactants to an amount of not more than 500 ppm, for example not more than 250 ppm based on the total weight of the dispersion while maintaining or increasing the amount of solids in the dispersion.
    Type: Grant
    Filed: January 8, 2010
    Date of Patent: July 17, 2012
    Assignee: 3M Innovative Properties Company
    Inventors: Klaus Hintzer, Michael Jürgens, Harald Kaspar, Herbert Koenigsmann, Kai Helmut Lochhaas, Andreas R. Maurer, Werner Schwertfeger, Tilman Zipplies, Ludwig Mayer, Michael C Dadalas, George G. I. Moore, Jay F. Schulz, Richard M. Flynn
  • Patent number: 8211964
    Abstract: A curable composition including a fluorine-containing elastomer having a cyano group in its trunk chain and/or side chain and inorganic nitride particles in an amount of 0.1 to 20 parts by weight based on 100 parts by weight of the fluorine-containing elastomer, or a curable composition including a specific crosslinking agent selected from an oxazole crosslinking agent, an imidazole crosslinking agent and a thiazole crosslinking agent, a fluorine-containing elastomer having a cure site crosslinkable with the crosslinking agent and inorganic nitride particles. Also disclosed is a molded article obtained by curing the above-mentioned curable composition, and a process for production of a molded article which includes a step of primary vulcanization of the curable composition and a step of secondary vulcanization following the primary vulcanization.
    Type: Grant
    Filed: July 24, 2006
    Date of Patent: July 3, 2012
    Assignee: Daikin Industries, Ltd.
    Inventor: Seiichi Hirano
  • Publication number: 20120156408
    Abstract: The disclosure provides to a PDC element protective system including a mask configured to protect a non-leached portion of a leached polycrystalline diamond compact (PDC) element during a leaching process. The mask may be formed from or coated with polytetrafluoroethylene (PTFE). The disclosure also provides a leaching system containing such a mask and a leaching vessel as well as methods of using the protective and leaching systems. The disclosure further provides a Lewis acid-based leaching agent and methods of its use. Finally, the disclosure provides a method of recycling a PDC or carbide element using a Lewis acid-based leaching agent.
    Type: Application
    Filed: June 24, 2011
    Publication date: June 21, 2012
    Inventors: Ram L. Ladi, Stephen W. Almond
  • Publication number: 20120156417
    Abstract: A stain resistant, oil and water repellent composition comprising a copolymer prepared from fluorinated methacrylate, carbonate methacrylate, and methacrylic acid or salt thereof, a method of providing stain resistance, oil and water repellency to substrates, and a treated substrate.
    Type: Application
    Filed: November 21, 2011
    Publication date: June 21, 2012
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventors: Joel M. Pollino, Anilkumar Raghavanpillai, Brad M. Rosen, Siddhartha Shenoy, Libby Xiaowei Hu
  • Publication number: 20120156504
    Abstract: The present invention relates to a coating material composition for a liquid immersion exposure apparatus, which is used for the purpose of forming a lyophobic layer on a surface of a component member of the liquid immersion exposure apparatus which performs a light exposure of a substrate by irradiating with an exposure beam through a liquid, in which the composition contains a fluorine-containing polymer which has, in the main chain, a repeating unit that has a fluorine-containing aliphatic ring structure containing two or three etheric oxygen atoms which are not adjacent to each other, in the ring structure.
    Type: Application
    Filed: February 29, 2012
    Publication date: June 21, 2012
    Inventors: Yoko TAKEBE, Osamu Yokokoji
  • Patent number: 8202955
    Abstract: The present invention provides an aqueous fluoropolymer dispersion having good mechanical characteristics and storage stability and containing substantially no fluorinated surfactant. The present invention is related to an aqueous fluoropolymer dispersion comprising a dispersed fluoropolymer particle with an average primary particle diameter of 50 to 400 nm, a surface layer of the dispersed fluoropolymer particle being obtained by emulsion polymerization of a monomer composition consisting of 99.999 to 98 mole percent of tetrafluoroethylene and 0.001 to 2 mole percent of a modifier monomer, a fluorinated surfactant content being not higher than 50 ppm, a fluoropolymer content being 20 to 75% by mass, and a nonfluorinated nonionic surfactant content being 2 to 15% by mass relative to 100% by mass of the fluoropolymer.
    Type: Grant
    Filed: July 5, 2007
    Date of Patent: June 19, 2012
    Assignee: Daikin Industries, Ltd.
    Inventors: Chie Sawauchi, Nobuhiko Tsuda
  • Publication number: 20120125772
    Abstract: A printed gas sensor is disclosed. The sensor may include a porous substrate, an electrode layer, a liquid or gel electrolyte layer, and an encapsulation layer. The electrode layer comprises two or more electrodes that are formed on one side of the porous substrate. The liquid or gel electrolyte layer is in electrolytic contact with the two or more electrodes. The encapsulation layer encapsulates the electrode layer and electrolyte layer thereby forming an integrated structure with the porous substrate.
    Type: Application
    Filed: November 24, 2010
    Publication date: May 24, 2012
    Applicant: KWJ ENGINEERING INC.
    Inventors: Joseph R. Stetter, Edward F. Stetter, Daniel Ebeling, Melvin Findlay, Vinay Patel
  • Patent number: 8178457
    Abstract: Circuit modules and methods of construction thereof that contain composite meta-material dielectric bodies that have high effective values of real permittivity but which minimize reflective losses, through the use of host dielectric (organic or ceramic), materials having relative permittivities substantially less than ceramic dielectric inclusions embedded therein. The composite meta-material bodies permit reductions in physical lengths of electrically conducting elements such as antenna element(s) without adversely impacting radiation efficiency. The meta-material structure may additionally provide frequency band filtering functions that would normally be provided by other components typically found in an RF front-end.
    Type: Grant
    Filed: July 21, 2008
    Date of Patent: May 15, 2012
    Inventor: L. Pierre de Rochemont
  • Patent number: 8178612
    Abstract: The present invention relates to an aqueous/oil emulsion containing fluoropolymer that is capable of forming thick coatings in a single pass, which coatings after drying and baking are free of cracks.
    Type: Grant
    Filed: January 19, 2005
    Date of Patent: May 15, 2012
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Jurgen Hofmans
  • Publication number: 20120116003
    Abstract: A process is provided for the polymerization of fluoromonomer to an dispersion of fluoropolymer particles in an aqueous medium in a polymerization reactor, by (a) providing the aqueous medium in the reactor, (b) adding the fluoromonomer to the reactor, (c) adding initiator to the aqueous medium, the combination of steps (b) and (c) being carried out essentially free of hydrocarbon-containing surfactant and resulting in the kickoff of the polymerization of the fluoromonomer, and (d) metering hydrocarbon-containing surfactant into the aqueous medium after the kickoff of polymerization, e.g. after the concentration of the fluoropolymer in the aqueous medium is at least 0.6 wt %, the metering being at a rate reducing the telogenic activity of said surfactant while maintaining surface activity.
    Type: Application
    Filed: November 9, 2011
    Publication date: May 10, 2012
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventors: Paul Douglas Brothers, Subhash Vishnu Gangal, Dipti Dilip Khasnis
  • Publication number: 20120116009
    Abstract: The problem of lack of uniform dispersion of a fluoropolymer as a flame retardant additive to thermoplastic resins is solved by a dispersion of a fluoropolymer in a flame retardant which is then blended as particles with a thermoplastic resin in molten form. Furthermore, flame retardant precursors are reacted in the presence of a fluoropolymer to form a molten flame retardant mixed with the fluoropolymer in another aspect.
    Type: Application
    Filed: January 17, 2012
    Publication date: May 10, 2012
    Applicant: BROMINE COMPOUNDS LTD.
    Inventors: Yoav Bar-Yaakov, Pierre Georlette, Daniel Plewinski, Ita Finberg
  • Publication number: 20120107581
    Abstract: A composition for producing an optically clear, well bonded superhydrophobic coating includes a plurality of hydrophobic particles comprising an average particle size of about 200 nm or less, a binder at a binder concentration of from about 0.1 wt. % to about 0.5 wt. %, and a solvent. The hydrophobic particles may be present in the composition at a particle concentration of from about 0.1 wt. % to about 1 wt. %. An optically transparent, superhydrophobic surface includes a substrate, a plurality of hydrophobic particles having an average particle size of about 200 nm or less dispersed over the substrate, and a discontinuous binder layer bonding the hydrophobic particles to the substrate, where the hydrophobic particles and the binder layer form an optically transparent, superhydrophobic coating.
    Type: Application
    Filed: November 2, 2010
    Publication date: May 3, 2012
    Inventors: John T. Simpson, Linda A. Lewis
  • Publication number: 20120101215
    Abstract: The present invention provides a method of manufacturing a polytetrafluoroethylene (PTFE) product offering better productivity and a higher degree of flexibility in form of the product to be obtained than the conventional methods of manufacturing a PTFE product, and a method of manufacturing PTFE particle aggregate obtained as an intermediate while manufacturing a PTFE product. According to the manufacturing methods, aggregate of PTFE particles including water and a surfactant is obtained by applying force to a dispersion of PTFE particles containing PTFE particles, a surfactant and water as a dispersion medium, where the force makes the PTFE particles approach or contact with each other. Such a manufacturing method may be carried out, for example, with a chamber (1) shown in FIG. 1.
    Type: Application
    Filed: December 23, 2011
    Publication date: April 26, 2012
    Applicant: NITTO DENKO CORPORATION
    Inventors: Takashi WANO, Yuri HORIE, Atsushi TANAKA, Osamu TABEI, Yozo NAGAI