Ester Contains Two Or More Ester Groups Or At Least One Carboxylic Ester Group And At Least One Free Acid Group; Or Carboxylic Acid Contains Two Or More Free Carboxyl Groups Patents (Class 524/559)
  • Patent number: 4764554
    Abstract: The thickener comprises:(a) 25-45% of methacrylic acid, acrylic acid or a mixture thereof;(b) 25-65% of alkyl acrylate such as methyl acrylate, ethyl acrylate, butyl acrylate, alkyl methacrylate such as methyl methacrylate, ethyl methacrylate, butyl methacrylate, lauryl methacrylate or a mixture thereof;(c) 1-40% of an ester of composition; ##STR1## in which R is a C.sub.12 -C.sub.25 alkyl group, n=at least 10; m=at least 5 A=H, --(CH.sub.2 CH.sub.2 O).sub.n --R, C.sub.1 -C.sub.20 alkyl,--(CH.sub.2 CH.sub.2 O)m-H or --(CH.sub.2 CH.sub.2 O).sub.m --CH.sub.3(d) 0-1% of a polyethylenically unsaturated monomer effective for chain branching or crosslinking such as diallyl maleate, diallyl phthalate, divinyl benzene, allyl methacrylate, ethylene glycol dimethacrylate, or trimethylol propane triacrylate,(e) optionally, but preferably, up to 10% of an ethylenically unsaturated hydrophylic monomer.
    Type: Grant
    Filed: June 1, 1987
    Date of Patent: August 16, 1988
    Assignee: Crown Decorative Products Limited
    Inventor: Christopher J. Tonge
  • Patent number: 4740546
    Abstract: An aqueous dispersion of a vinyl copolymer resin is prepared by polymerizing 1 to 15 parts by weight of a polyoxyethylene-containing hydrophilic polymerizable vinyl monomer of which polyoxyethylene moiety has an average molecular weight of 2,000 to 10,000, 99 to 85 parts by weight of at least one specific polymerizable vinyl monomer and 0 to 5 parts by weight of alpha, beta-unsaturated carboxylic acids, salts thereof or anhydrides thereof in an organic solvent, and dispersing the resulting vinyl copolymer resin solution in water.
    Type: Grant
    Filed: June 5, 1987
    Date of Patent: April 26, 1988
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Tsuyoshi Masuda, Zengo Ninomiya
  • Patent number: 4731402
    Abstract: Floor covering adhesives substantially comprisingA. a dispersion of a copolymer of20-60% by weight of vinylidene chloride34-80% by weight of a mixture of 40-80 parts by weight of esters of acrylic acid with C.sub.1 -C.sub.18 -alkanols and 20-60 parts by weight of vinyl esters and0.5 to 6% by weight of .alpha.,62 -monoolefinically unsaturated C.sub.3 -C.sub.5 -mono- and/or dicarboxylic acids and/or amides thereof and/or vinyl sulfonate,B. 30-150 parts by weight (solid), based on 100 parts of a copolymer of A, of tackifying resins from the group of the rosins and derivatives thereof,C. 0-50 parts by weight, based on 100 parts of resin B, of plasticizers and/or liquid resins and also, if desired,D. fillers,are shampoo-resistant and have a high peel strength.
    Type: Grant
    Filed: October 21, 1986
    Date of Patent: March 15, 1988
    Assignee: BASF Aktiengesellschaft
    Inventors: Erich Penzel, Lothar Maempel, Hans J. Neumann, Karl-Clemens Peters, Oral Aydin
  • Patent number: 4730016
    Abstract: Disclosed herein is a resin composition obtained by mixing an olefin-base resin, which has in turn been obtained by partially neutralizing a free carboxyl group in a random copolymer of an .alpha.-olefin and an .alpha.,.beta.-ethylenically-unsaturated monocarboxylic or dicarboxylic acid, with a volatile rust preventive in a specific amount or more. The resin composition has excellent rust preventive properties and can hence be used advantageously as a wrapping material for metal products.
    Type: Grant
    Filed: April 14, 1986
    Date of Patent: March 8, 1988
    Assignee: Aicerro Chemical Company Limited
    Inventors: Akira Fujii, Yasuhisa Isobe, Kenichi Hashiudo
  • Patent number: 4722954
    Abstract: A solid flexible polymeric material is formed by solidifying a water-based latex which contains an inorganic filler. The filler is sand and this may be stabilized in the latex with xanthan gum. The solid material may be a formed or non-foamed layer which may be used as integral carpet backing, as carpet underlay, or as an adhesive for bonding a reinforcing fabric to the back of carpeting.
    Type: Grant
    Filed: February 12, 1986
    Date of Patent: February 2, 1988
    Inventor: Gerald Hallworth
  • Patent number: 4685931
    Abstract: An aqueous dispersion of a copolymer offrom about 50 to 60% by weight ethyl acrylatefrom about 30 to 40% by weight methacrylic acidfrom about 5 to 15% by weight acrylic acid andfrom about 0.02 to 0.04% by weight of a polyethylenically copolymerizable monomer, for example ethylene glycol dimethacrylate. The dispersion is suitable as an additive for aqueous, mildly acidic preparations of hydrogen peroxide to impart an increased viscosity to them after neutralization. The hydrogen peroxide preparations in question are particularly suitable for use as a developer composition for oxidative hair dyes and hair bleaches.
    Type: Grant
    Filed: December 13, 1985
    Date of Patent: August 11, 1987
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Ludwig Schieferstein, Detlef Hollenberg, Norbert Maak
  • Patent number: 4661548
    Abstract: An aqueous copolymer emulsion useful as a ceramic tile adhesive contains filler material, a zinc compound and an aqueous emulsion of a copolymer containing residues of an unsaturated aliphatic hydrocarbon monomer, an unsaturated monomer copolymerizable therewith and a small amount of residues containing carboxyl groups.
    Type: Grant
    Filed: November 20, 1985
    Date of Patent: April 28, 1987
    Assignee: Scott Bader Company Limited
    Inventor: Robert G. Parker
  • Patent number: 4661545
    Abstract: The invention relates to a thermoplastic moulding compound consisting of:A. at least 95% (wt) of a copolymer consisting of1. 50-95 moles % styrene and/or .alpha.-methylstyrene2. 50-55 moles % unsaturated dicarboxylic anhydrideB. at most 5% (wt) of an phosphite with the general formula of ##STR1## where R represents hydrogen or the residue of an alkyl, cycloalkyl, aryl, alkaryl or aralkyl, while the R substituents need not to be the same and may contain heteroatoms.It has been found that additions of these phosphites to SMA-containing moulding compounds checks the decomposition of SMA, prevents the moulding compound from getting stuck to the processing equipment and consequently reduces corrosion to a high degree.
    Type: Grant
    Filed: October 31, 1985
    Date of Patent: April 28, 1987
    Assignee: Stamicarbon B.V. (Licensing subsidiary of DSM)
    Inventors: Wilhelmus G. M. Bruls, Eize Roerdink
  • Patent number: 4654393
    Abstract: A process is disclosed for preparing a solid, water absorbing, cross-linked polyacrylate resin including combining potassium acrylate and a polyvinyl monomer, such as N,N-methylene bisacrylamide, with water in an amount of 55 to 80 combined weight percent of potassium acrylate and polyvinyl monomer based on the total weight of potassium acrylate, polyvinyl monomer and water to form a monomer mixture, and adding a polymerization initiator to the monomer mixture to initiate polymerization of the monomer mixture. The monomer mixture then is polymerized without external heating by utilizing the exothermic heat of reaction as substantially the only non-ambient energy source to drive water away from said polyacrylate resin to form the cross-linked polyacrylate resin having a water content sufficiently low (i.e. 15% or less) to be powdered, such as by pulverization, without an intermediate drying step.
    Type: Grant
    Filed: May 6, 1985
    Date of Patent: March 31, 1987
    Assignee: American Colloid Company
    Inventors: Muneharu Mikita, Shozo Tanioku, Takayasu Touda
  • Patent number: 4654396
    Abstract: A dispersion, having highly dilatant flow, of a carboxyl-containing copolymer of monoolefinically unsaturated monomers, wherein the temperature dependence of the critical shearing rate is greatly reduced by incorporation of from 0.1 to 30% by weight of oxides, hydroxides, carbonates and/or water soluble salts of monovalent or divalent metals.
    Type: Grant
    Filed: September 9, 1985
    Date of Patent: March 31, 1987
    Assignee: BASF Aktiengesellschaft
    Inventors: Richard Bung, Klaus Haas, Martin Laun, Franz Schmidt, Gerhard Welzel
  • Patent number: 4654397
    Abstract: A process for the preparation of aqueous polymer dispersions which have a low film-forming temperature but still give films having a high block resistance, and the use of these polymer dispersions as binders for coating materials.
    Type: Grant
    Filed: December 2, 1985
    Date of Patent: March 31, 1987
    Assignee: BASF Aktiengesellschaft
    Inventors: Rudolf Mueller-Mall, Michael Melan, Eckehardt Wistuba, Lothar Matthaei
  • Patent number: 4645789
    Abstract: Crosslinked water absorbent carboxylic polyelectrolytes and articles made therefrom are provided. The polyelectrolytes are crosslinked using a di- or tri-functional aziridine crosslinking agent.
    Type: Grant
    Filed: August 29, 1985
    Date of Patent: February 24, 1987
    Assignee: Personal Products Company
    Inventor: Shmuel Dabi
  • Patent number: 4642324
    Abstract: A vinyl chloride resin composition comprising a copolymer derived from 70 to 99.8% by weight of vinyl chloride, 0.2 to 30% by weight of a monoester of an alpha, beta-unsaturated dicarboxylic acid, 0 to 2% by weight of a compound having two or more active double bonds in the molecule and 0 to 20% by weight of another vinyl compound, a mono- or divalent metal compound and a plasticizer.
    Type: Grant
    Filed: February 14, 1985
    Date of Patent: February 10, 1987
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Toshiaki Kobayashi, Hiromichi Arakawa, Tatsuo Ohira
  • Patent number: 4636258
    Abstract: An ink composition for thermal transfer printing of about 30 to 50 weight percent of a masterbatch including a pigment or dye uniformly dispersed in a copolymer of at least one of styrene and an .alpha.-olefin and at least one of a maleic anhydride and a dialkyl maleate and about 50 to 70 weight percent wax or resin is provided. The ink composition is suitable for use as the ink layer of an electrothermal transfer recording sheet.
    Type: Grant
    Filed: August 20, 1985
    Date of Patent: January 13, 1987
    Assignee: Seiko Epson Kabushiki Kaisha
    Inventors: Seiichi Hayashi, Katsumori Takei, Takahiro Usui, Yoshitaka Yamaguchi, Makoto Taniguchi
  • Patent number: 4614759
    Abstract: Surface sizing agents for paper containing aqueous or aqueous-alcoholic alkali metal, amine or ammonium salt solutions of copolymers of maleic anhydride and diisobutylene and, if appropriate, a vinyl monomer of the formula ##STR1## in which R designates H, --CH.sub.3, --C.sub.2 H.sub.5, --OR.sub.2, --OCOCH.sub.3, ##STR2## or --CH.sub.2 --O--COCH.sub.3, R.sub.1 designates H or --CH.sub.3 andR.sub.2 designates alkyl, the anhydride groups of the copolymers being bis-esterified to the extent of 25-90 mol % with primary aliphatic monoalcohols with 1 to 12 C atoms.
    Type: Grant
    Filed: August 5, 1985
    Date of Patent: September 30, 1986
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gunter Sackmann, Ulrich Beck, Heinz Baumgen
  • Patent number: 4613639
    Abstract: Plastisols and organosols which have a long shelf life at room temperature, are based on a mixture of a finely divided synthetic resin with a plasticizer and may or may not contain additional pigments, fillers, volatile organic solvents and other assistants are prepared by a process in which an inert or reactive protective colloid or emulsifier, or a mixture of these, is added to a dispersion of a finely divided synthetic resin in a plasticizer, the dispersion as such not having a long shelf life at room temperature.These plastisols can be used as coating materials, sealants and adhesives.
    Type: Grant
    Filed: October 24, 1985
    Date of Patent: September 23, 1986
    Assignee: BASF Aktiengesellschaft
    Inventors: Rainer Blum, Rolf Osterloh
  • Patent number: 4605698
    Abstract: Polyfunctional aziridines useful in crosslinking applications have been developed which are reaction products of (1) ethylene imine and (2) acrylates of alkoxylated trimethylol propane, neopentyl glycol, pentaerythritol, bis phenol A, bis phenol F and glycerol, each having a degree of alkoxylation of from about 2 to about 12. Examples are the bis aziridine of the diacrylate of the adduct of neopentyl glycol and 2 moles of ethylene oxide and the tris aziridine of the triacrylate of the adduct of trimethylol propane and 3 moles of ethylene oxide.
    Type: Grant
    Filed: September 12, 1985
    Date of Patent: August 12, 1986
    Assignee: Diamond Shamrock Chemicals Company
    Inventor: Frank C. Briden
  • Patent number: 4604420
    Abstract: Vulcanizable polymer compositions with improved scorch are provided comprising a carboxylated nitrile rubber or a carboxylated styrene-butadiene rubber, one or more polyvalent metal oxides and one or more alkali metal salts selected from the lithium, sodium and potassium salts of C.sub.12-18 -alkanoic acids.
    Type: Grant
    Filed: March 22, 1985
    Date of Patent: August 5, 1986
    Assignee: Polysar Limited
    Inventor: Kyosaku Sato
  • Patent number: 4577007
    Abstract: Resorcinol monobenzoate is reacted through the hydroxyl group preferably with an acrylic prepolymer containing glycidyl methacrylate. The product can be used in coating compositions and films to give highly ultraviolet absorbent properties.
    Type: Grant
    Filed: December 21, 1984
    Date of Patent: March 18, 1986
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Michael DeBergalis
  • Patent number: 4558084
    Abstract: What are disclosed are plastisols of copolymers of methyl methacrylate with from 0.1 to 10 weight percent of itaconic acid or of itaconic acid anhydride, which copolymers have a glass transition temperature above 50.degree. C., a degree of polymerization higher than 400 and an average particle size ranging from 0.1 to 500 microns and contain, per 100 parts by weight of the copolymer, from 100 to 1000 parts by weight of an organic plasticizer compatible with the copolymer, and optional fillers and further conventional additives.
    Type: Grant
    Filed: September 20, 1982
    Date of Patent: December 10, 1985
    Assignee: Rohm GmbH
    Inventors: Peter Quis, Werner Siol, Joachim Buechse, Hubert Rauch
  • Patent number: 4558087
    Abstract: A vinyl chloride resin composition for production of hard articles. The composition comprises 100 parts by weight of a graft polymer and not more than 40 parts by weight of electrically conductive carbon black. The graft polymer is obtained by polymerizing 99 to 60% by weight of vinyl chloride or a monomeric mixture composed of at least 80% by weight of vinyl chloride and not more than 20% by weight of a monomer copolymerizable with it in the presence of 1 to 40% by weight of a copolymer composed of 5 to 75% by weight of methyl methacrylate and 95 to 25% by weight of ethylene.
    Type: Grant
    Filed: July 11, 1984
    Date of Patent: December 10, 1985
    Assignee: Nippon Zeon Co. Ltd.
    Inventors: Masahiro Yamakawa, Mamoru Nakamura, Toyoichi Arai
  • Patent number: 4542181
    Abstract: Latices of vinyl acetate polymers comprising particles having an average diameter between 0.05 and 1 .mu.m and being present in the latex at a concentration of between 10 and 70% by weight. The polymers have a glass transition temperature between -20.degree. and 50.degree. C. The latices also contain a protective colloid comprising a water-soluble polymer (a) containing at least one monomer selected from the group consisting of N-methylolacrylamide and N-methylolmethacrylamide and a water-soluble polymer (b) of ethylene glycol, the polymer (b) having a molecular weight between 1,000 and 50,000.The latices are prepared by polymerization in aqueous emulsion, in the presence of both an initiator and the above-reference protective colloid. The latices may be applied as binders in the manufacture of paints, glues, paper, textiles, floor coverings and mortar additives.
    Type: Grant
    Filed: August 5, 1982
    Date of Patent: September 17, 1985
    Assignee: Rhone-Poulenc Specialties Chimiques
    Inventors: Jean-Luc Schuppiser, Jean-Claude Daniel
  • Patent number: 4542182
    Abstract: Latices of particles of vinyl acetate/olefin copolymers. The particles have an average diameter between 0.05 and 1 .mu.M. The copolymers have a glass transition temperature between -30.degree. and 50.degree. C. The particles are present in the latices in a concentration between 10 and 70% by weight. The latices contain a protective colloid comprising a water-soluble polymer (a) containing at least one monomer selected from the group consisting of N-methylolacrylamide and N-methylolmethacrylamide and a water-soluble polymer (b) of ethylene glycol, wherein polymer (b) has a molecular weight of between 1,000 and 50,000.The latices are prepared by polymerization in aqueous emulsion, in the presence of an initiator and the above-described protective colloid.The latices may be applied as binders in the manufacture of paints, glues, paper, textiles, floor coverings and mortar additives.
    Type: Grant
    Filed: August 5, 1982
    Date of Patent: September 17, 1985
    Assignee: Rhone-Poulenc Specialties Chimiques
    Inventors: Jean-Luc Schuppiser, Jean-Claude Daniel
  • Patent number: 4537926
    Abstract: Described is an aqueous chip resistant coating composition exhibiting a viscosity of at least 5,000 centipoise, preferably containing binders with a high molecular weight, preferably at least 20,000. Although these coatings may be applied to a variety of substrates, for coating electrocoated substrates the following eight binders are particularly preferred: ethylene vinyl acetate copolymer, carboxylated ethylene vinyl acetate, epoxy functional acrylic resin, carboxylated styrene-butadiene resin, carboxylated acrylic, hydroxy functional acrylic, self-crosslinking acrylic; and carboxylated PVC acrylic. Generally, it is preferred to apply the chip resistant coating via an airless spray and the heat curing the coating.
    Type: Grant
    Filed: April 6, 1984
    Date of Patent: August 27, 1985
    Assignee: Grow Group, Inc.
    Inventors: Daniel M. Kivel, Gerhard M. Weber
  • Patent number: 4526910
    Abstract: Disclosed is an essentially solvent-based, organic, high-solids coating composition containing (A) a film-forming binder system containing a crosslinkable resin having a weight average molecular weight of from about 500 to about 10,000; (B) substantially colorless, substantially inorganic microparticles stably dispersed in the coating composition; and (C) a solvent system for the crosslinkable resin. The substantially inorganic microparticles prior to incorporation in the coating composition range in size from about 1 to about 150 nanometers and are in the form of a sol of the microparticles in which the surface of the inorganic microparticles is essentially free of carbon-containing molecules chemically bonded to the inorganic microparticles.
    Type: Grant
    Filed: September 6, 1983
    Date of Patent: July 2, 1985
    Assignee: PPG Industries, Inc.
    Inventors: Suryya K. Das, Paul P. Greigger, William G. Boberski, James E. Jones, Raymond F. Schappert, Jerome A. Seiner
  • Patent number: 4522971
    Abstract: Resorcinol monobenzoate is reacted through the hydroxyl group preferably with an acrylic prepolymer containing glycidyl methacrylate. The product can be used in coating compositions and films to give highly ultraviolet absorbent properties.
    Type: Grant
    Filed: February 25, 1983
    Date of Patent: June 11, 1985
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Michael DeBergalis
  • Patent number: 4519920
    Abstract: A copolymer of maleic acid (MA) and (meth)acrylic acid (AA), or a salt thereof, wherein the molar ratio (MA/AA) .gamma. of the constituent monomers is 1.15 to 2.7, the average molecular weight MW is 1000 to 8000, and (.gamma.).times.(MW) is at least 3000. The copolymer is useful as a calcium ion capturing agent, in a process for treating water to inhibit formation of scale surfaces contacted by the water.
    Type: Grant
    Filed: April 9, 1984
    Date of Patent: May 28, 1985
    Assignee: Kao Soap Co., Ltd.
    Inventors: Yasuhisa Fukumoto, Noboru Moriyama
  • Patent number: 4506041
    Abstract: A binder of this invention is a powder which comprises an intimate mixture of a copolymer of maleic anhydride with an olefinically unsaturated compound selected from the group consisting of an aliphatic .alpha.-olefin having 2 to 8 carbon atoms, styrene and methyl vinyl ether, 0.2 to 2.0 equivalents of a caustic alkali per carboxyl equivalent of said copolymer, and if desired, 30 to 500 parts by weight of an alkaline earth metal hydroxide per 100 parts of the total weight of said copolymer and said caustic alkali, and if desired, up to 300 parts by weight of additive per 100 parts of the total weight of said copolymer and said caustic alkali. A process for preparing a mold according to this invention comprises mixing said powdered binder with refractory particles and a small amount of water under agitation, and forming the resulting mixture into a shaped product, whereafter the shaped product is hardened by blowing CO.sub.2 gas therethrough.
    Type: Grant
    Filed: June 30, 1983
    Date of Patent: March 19, 1985
    Assignees: Hitachi, Ltd., Kinsei Kogyo Co., Ltd.
    Inventors: Takatoshi Tanigawa, Sakari Yaegashi, Tetsuo Nakazawa, Masahiko Hatazi, Tadao Nango
  • Patent number: 4497929
    Abstract: A latex composition having utility in articles such as photographic elements is disclosed. The composition comprises loadable polymer particles having recurring units a, b and c wherein:component a is 10 to 100 weight percent of a tetrahydrofurfuryl monomer having the structure: ##STR1## in which R.sub.1 represents O or NH; andR.sub.2 represents H or lower alkyl of about 1 to 6 carbon atoms;component b is 0 to 20 weight percent of a hydrophilic monomer andcomponent c is 0 to 90 weight percent of a hydrophobic monomer.
    Type: Grant
    Filed: July 19, 1982
    Date of Patent: February 5, 1985
    Assignee: Eastman Kodak Company
    Inventors: James W. Brown, Tsang J. Chen, Michael A. Schen
  • Patent number: 4481324
    Abstract: Enhanced lubricating properties and good heat stability upon processing are imparted to thermoplastic materials such as polyvinyl chloride, polypropylene and acrylonitrile-butadiene-styrene resins by the incorporation therein of a polyglycerol ester of a C.sub.8 to C.sub.22 fatty acid. The ester is characterized by a degree of polymerization ranging from 2 to 8 and a degree of acid substitution ranging from 1 to 10.
    Type: Grant
    Filed: February 25, 1983
    Date of Patent: November 6, 1984
    Assignee: Glyco Inc.
    Inventors: Larry K. Hall, Marvin Rosen
  • Patent number: 4460721
    Abstract: A printing ink or varnish having a binder comprising isopropylmethacrylate and hydrophilic comonomers, particularly unsaturated carboxylic acids, their hydroxyalkyl esters, or a mixture thereof; preferably in combination with cellulose esters such as nitrocellulose, as an additional binder. The ink or varnish also contains dissolved or undissolved dyes, as well as a lower alkyl alcohol solvent. The printing and coatings thus produced are characterized by hardness and a high sealing stability.
    Type: Grant
    Filed: May 24, 1983
    Date of Patent: July 17, 1984
    Assignee: Rohm GmbH Chemische Fabrik
    Inventors: Wilhelm Elser, Manfred Munzer
  • Patent number: 4452776
    Abstract: A hydrogel implant article of significant softness, pliability and elasticity when dry as well as when wet consists of a random cross-linked copolymer of 2-hydroxyethyl acrylate and an alkyl acrylate. The acrylate hydrogel article is useful, in one instance, as the material to produce a scleral buckle in retinal detachment surgery.
    Type: Grant
    Filed: March 12, 1982
    Date of Patent: June 5, 1984
    Assignee: Eye Research Institute of Retina Foundation
    Inventor: Miguel F. Refojo
  • Patent number: 4451632
    Abstract: A process for preparing, in aqueous emulsion, controlled interpolymer compositions. The interpolymer compositions have polymerized therein from about 86 to 92 mole percent, vinylidene chloride, from about 14 to 8 mole percent of a comonomer mixture of methyl methacrylate and a comonomer selected from the group consisting of acrylonitrile, methacrylic acid and methacrylonitrile in a ratio of the comonomer to methyl methacrylate of from about 0.5:1 to 2:1, and from about 0.5 to 1.0 weight percent itaconic acid, based on weight of vinylidene chloride plus comonomer mixture. The interpolymers are prepared in a three step process. The third step, or Step III, wherein monomer feeding is step-wise reduced for a portion of the step and a polymerization initiator is added at generally the same constant rate as the rate of addition in Steps I and II, generally reduces the amount of unreacted mixed monomers remaining after monomer addition is completed.
    Type: Grant
    Filed: July 6, 1982
    Date of Patent: May 29, 1984
    Assignee: The Dow Chemical Company
    Inventors: Dale S. Gibbs, Warren L. Treptow
  • Patent number: 4440885
    Abstract: An aqueous emulsion of a solid, water insoluble or limited water soluble organic peroxide is provided that has improved stability, dilutability and safety but still having an average particle size of 1.5 microns or less and a good particle size distribution. The emulsion has from about 10 weight percent of the emulsion of a solid peroxide selected from the group of hydroperoxides .alpha., -oxy and .alpha.-peroxy hydroperoxides, dialkyl peroxides, aldehyde and ketone peroxides, diacyl peroxides, peroxyesters, peroxy acids, peroxydicarbonates, monoperoxycarbonates and perketals.The emulsion also has a hydrocarbon solvent having a high kauri-butanol number if the organic peroxide has a substantial amount of aromaticity and a low kauri-butanol number if the organic peroxide has little or no aromaticity and one or more nonioic emulsifiers and at least about 20 weight percent of water.
    Type: Grant
    Filed: April 2, 1982
    Date of Patent: April 3, 1984
    Assignee: PPG Industries, Inc.
    Inventor: Albert E. Tamosauskas
  • Patent number: 4421889
    Abstract: Dispersion paints with high wet adhesion are obtained if, as the binder thereof, an aqueous plastics dispersion is used, the polymer content of which includes monomeric units of an acetoacetic acid ester of an unsaturated alcohol, especially vinyl or allyl alcohol or a diester of a dihydroxy compound in which one acyl radical is acetoacetyl and the other acyl radical is an acrylic or methacrylic radical. The preparation of paints with a low pigment content is especially facilitated by the use of such a dispersion.
    Type: Grant
    Filed: May 13, 1983
    Date of Patent: December 20, 1983
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Helmut Braun, Helmut Rinno, Werner Stelzel
  • Patent number: 4418163
    Abstract: A water absorbing composite comprises an inorganic powder, and a highly absorbent resin covering the whole surfaces of the individual particles of the inorganic powder. The resin is obtained by reacting with a basic substance a polymer containing as a monomeric constituent an .alpha.,.beta.-unsaturated compound having in its molecule one or two carboxyl groups, or one or two other groups convertible to a carboxyl group or groups, and by crosslinking the reaction product with a polyamine. The composite is useful as a water retaining agent for agriculture and horticulture, or as a dehydrating agent for oil.
    Type: Grant
    Filed: August 13, 1982
    Date of Patent: November 29, 1983
    Assignee: Kuraray Co., Ltd.
    Inventors: Tetsuo Murakami, Hirotoshi Miyazaki, Hiroshi Harima
  • Patent number: 4399060
    Abstract: Semiconductive elastomeric compositions useful as the outer layer on insulated electric cables and suitable for high temperature vulcanization techniques.
    Type: Grant
    Filed: February 10, 1981
    Date of Patent: August 16, 1983
    Assignee: E. I. Du Pont de Nemours & Co.
    Inventor: Gary L. Glass
  • Patent number: 4388438
    Abstract: The method of preparing aqueous dispersions of copolymers of styrene dibutyl maleate and acrylic or methacrylic acid or monobutyl maleate consists in adding a monomer mixture comprising styrene in the amount of 40-90% by weight, dibutyl maleate in the amount of 10-60% by weight acrylic or methacrylic acid or monobutyl maleate in the amount of 1.0-10.0% by weight in relation to the sum of styrene monomer and dibutyl maleate into the emulsion water known constituents such as:ionic emulsifier - non-ionic emulsifier, buffer, sodium acrylate, N-methylolmethacrylamide to which, prior to polymerization, an alkylene glycol comprising 2-6 carbon atoms in the alkylene group is added. The alkylene glycol is added in the amount of 1-6% by weight in relation to the sum of styrene monomer and dibutyl maleate while, the ratio of alkylene glycol to the methacrylic acid or monobutyl maleate contained in the monomer mixture is 1:0.2-2. The polymerization process is conducted at a temperature of 70.degree.-90.degree. C.
    Type: Grant
    Filed: January 6, 1981
    Date of Patent: June 14, 1983
    Assignee: Osrodek Badaw Cze-Rozwojowy Kauczukow I Tworzyw Winylowych
    Inventors: Maria Knypl, Eugeniusz Knypl, Marian Starzak, Ewa Mieczkowska, Urszula Pawlus, Romuald Palubicki, Mieczyslaw Ficek, Jozef Goldynia
  • Patent number: 4370460
    Abstract: Gasoline-soluble copolymers containing, as copolymerized units,(A) from 10 to 40% by weight of styrene,(B) from 10 to 50% by weight of tert.-butyl acrylate and/or vinyl pivalate,(C) from 20 to 40% by weight of isobutyl methacrylate,(D) from 5 to 20% by weight of acrylic acid esters and/or methacrylic acid esters of alkanols of 10 to 20 carbon atoms and(E) from 0 to 5% by weight of monoolefinically unsaturated monocarboxylic acids and/or dicarboxylic acids of 3 to 5 carbon atoms and/or their .beta.-hydroxyalkyl esters and/or monoalkyl esters of the dicarboxylic acids,the amount of component (D) being from 20 to 50% by weight of that of component (A), and the sum of the percentages of A to E being 100, are particularly suitable for use as binders for gasoline-containing masonry paints and renders.
    Type: Grant
    Filed: June 16, 1981
    Date of Patent: January 25, 1983
    Assignee: BASF Aktiengesellschaft
    Inventors: Gerhard Neubert, Eckehardt Wistuba
  • Patent number: 4363886
    Abstract: An amphoteric water-in-oil self-inverting polymer emulsion is prepared which contains a copolymer of (1) a nonionic vinyl monomer and (2) an amphoteric vinyl monomer or a terpolymer of (1) a nonionic vinyl monomer, (2) an anionic vinyl monomer and (3) a cationic vinyl monomer in the aqueous phase, a hydrocarbon oil for the oil phase, a water-in-oil emulsifying agent and an inverting surfactant. An example of a copolymer is a copolymer of (1) a nonionic vinyl monomer such as acrylamide or methacrylamide and (2) an amphoteric vinyl monomer such as a reaction product of dimethylaminoethyl methacrylate and monochloroacetic acid. An example of a terpolymer is a terpolymer of (1) a nonionic vinyl monomer such as acrylamide or methacrylamide, (2) an anionic vinyl monomer such as sodium acrylate and (3) a cationic vinyl monomer such as a triethyl ammonium ethyl methacrylate methosulfate salt.
    Type: Grant
    Filed: September 4, 1981
    Date of Patent: December 14, 1982
    Assignee: Diamond Shamrock Corporation
    Inventors: Stanley A. Lipowski, John J. Miskel, Jr.
  • Patent number: 4360605
    Abstract: Dental glass ionomer cements are obtained by using as a mixing component for preparing the final cement mixture either a liquid mixing component comprising an aqueous solution of a certain maleic acid-acrylic acid-copolymer and optionally usual additives or a solid, powdery mixing component comprising a powder mixture of a glass ionomer cement powder and the maleic acid-acrylic acid-copolymer in solid form and optionally usual additives.
    Type: Grant
    Filed: August 5, 1980
    Date of Patent: November 23, 1982
    Assignee: Espe Fabrik pharmazeutischer Praparate GmbH
    Inventors: Werner Schmitt, Robert Purrmann, Peter Jochum, Oswald Gasser
  • Patent number: 4346027
    Abstract: Polymer compositions are described that confer an enhanced balance of wet and dry strength properties to a cellulosic substrate while leaving the substrate soft and porous. The compositions comprise a hydrophilic air-curing polymer and a polyol with a carbon to oxygen ratio of less than 3:1, typified by glycerol.
    Type: Grant
    Filed: September 19, 1980
    Date of Patent: August 24, 1982
    Assignee: Monsanto Company
    Inventor: Donald N. Van Eenam
  • Patent number: 4342677
    Abstract: A liquid for setting dental cements comprising a aqueous solution of a copolymer of acryclic acid and maleic acid, tartaric acid and one or more fluorocomplex salt.
    Type: Grant
    Filed: May 14, 1981
    Date of Patent: August 3, 1982
    Assignee: G-C Dental Industrial Corp.
    Inventors: Hiroaki Muramatsu, Kentaro Tomioka, Kazuo Hirota, Shoji Akahane
  • Patent number: 4330450
    Abstract: An amphoteric water-in-oil self-inverting polymer emulsion is prepared which contains a copolymer of (1) a nonionic vinyl monomer and (2) an amphoteric vinyl monomer or a terpolymer of (1) a nonionic vinyl monomer, (2) an anionic vinyl monomer and (3) a cationic vinyl monomer in the aqueous phase, a hydrocarbon oil for the oil phase, a water-in-oil emulsifying agent and an inverting surfactant. An example of a copolymer is a copolymer of (1) a nonionic vinyl monomer such as acrylamide or methacrylamide and (2) an amphoteric vinyl monomer such as a reaction product of dimethylaminoethyl methacrylate and monochloroacetic acid. An example of a terpolymer is a terpolymer of (1) a nonionic vinyl monomer such as acrylamide or methacrylamide, (2) an anionic vinyl monomer such as sodium acrylate and (3) a cationic vinyl monomer such as a triethyl ammonium ethyl methacrylate methosulfate salt.
    Type: Grant
    Filed: October 15, 1979
    Date of Patent: May 18, 1982
    Assignee: Diamond Shamrock Corporation
    Inventors: Stanley A. Lipowski, John J. Miskel, Jr.
  • Patent number: 4321176
    Abstract: A method of forming a latex coating composition is disclosed in which there is first formed an aqueous emulsion of liquid droplets of water-insoluble polyol, such as a propylene oxide adduct of bisphenol. A, with the aid of a surfactant, and monoethylenically unsaturated monomers to be copolymerized are incorporated in the polyol emulsion while conditions of elevated temperature and catalysis are maintained to cause polymerization of said monomers in association with said polyol. The polyol is used in an amount of about 1% to about 25%, based on the weight of the materials which are copolymerized, and the monomers desirably include from about 0.5% to about 10% on the same basis of a reactive monomer, such as isobutoxymethyl acrylamide.
    Type: Grant
    Filed: January 10, 1980
    Date of Patent: March 23, 1982
    Assignee: DeSoto, Inc.
    Inventors: Kazys Sekmakas, Raj Shah