Interpolymerized With Hydrocarbon Containing A Single Ethylenic Group Patents (Class 524/562)
  • Patent number: 5373041
    Abstract: A pressure sensitive adhesive composition which can be applied by hot melt techniques to one surface and adhered to a second surface by contact at ambient temperature, to thereby bond the two surfaces together. The adhesive composition is made of certain ethylene/n-butyl acrylate copolymers together with tackifier and optionally, plasticizer.
    Type: Grant
    Filed: August 27, 1990
    Date of Patent: December 13, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: George W. Prejean
  • Patent number: 5369166
    Abstract: A copolymer latex is provided which comprises 30 to 90% by weight of a conjugated diene monomer unit, 9 to 50% by weight of an ethylenically unsaturated nitrile monomer unit, 0.1 to 20% by weight of an ethylenically unsaturated acid monomer unit and 0 to 20% by weight of an other ethylenically unsaturated monomer unit copolymerizable therewith, having a polystyrene-converted weight average molecular weight of 50,000 to 500,000, and containing 45% or less of methyl ethyl ketone insoluble matter. The latex is presented by emulsion polymerization using a polymerization initiator containing a peroxide whose decomposition temperature giving a half-life period of 10 hours is 100.degree. C. or higher and a reducing agent. The latex is used advantageously for dip molding.
    Type: Grant
    Filed: March 2, 1993
    Date of Patent: November 29, 1994
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Yutaka Ozawa, Hisanori Ohta
  • Patent number: 5330565
    Abstract: Active agent-containing printing ink which contains fine particles of thermoplastic polymer containing an active agent. The effect of active agent contained in a printed matter can be properly and effectually produced for a long period of time without causing undesirable release or deterioration of the active agent in printing and uses.
    Type: Grant
    Filed: December 7, 1992
    Date of Patent: July 19, 1994
    Assignee: Nippon Petrochemicals Company Limited
    Inventors: Hachiro Saitoh, Toshimichi Matsui
  • Patent number: 5322867
    Abstract: A bituminous composition comprising a bituminous component, a polymer which comprises at least one block of a conjugated diolefin and at least one block of an acrylic monomer such as an alkyl methacrylate and from 0.001 parts to 1 part by weight of a polyfunctional amine having at least two amino groups. An acid or anhydride functionalized conjugated diene block copolymer may be used in place of the acrylic monomer polymer.
    Type: Grant
    Filed: August 12, 1993
    Date of Patent: June 21, 1994
    Assignee: Shell Oil Company
    Inventor: Robert Q. Kluttz
  • Patent number: 5292795
    Abstract: A stable polymer dispersion having an average particle size of no more than 1 micron comprising water, a surfactant and a polymer comprising at least one conjugated diolefin block and/or vinyl aromatic hydrocarbon block and at least one acrylic monomer block with the structure ##STR1## wherein R.sub.1 is selected from the group consisting of hydrogen, phenyl and alkyl radicals which are linear or branched and contain from 1 to 10 carbon atoms, and R.sub.2 is a cyclic or non-cyclic alkyl radical which is branched at the first carbon atom, contains from 1 to 14 carbon atoms and may contain a tertiary amine or an ether linkage.
    Type: Grant
    Filed: May 8, 1992
    Date of Patent: March 8, 1994
    Assignee: Shell Oil Company
    Inventors: Jeffrey G. Southwick, David M. Austgen, Jr.
  • Patent number: 5283061
    Abstract: A color display facsimile of a cosmetic product comprised of the formulation of an original cosmetic product and prescribed amounts of each of a thermoplastic, copolymeric hardening agent and a hydrocarbonous-based temperature control component. The resultant display facsimile is capable of exhibiting the exact-likeness characteristics of true color, size, and shape of the original cosmetic product. The method for preparing said color display facsimile is also disclosed.
    Type: Grant
    Filed: March 12, 1992
    Date of Patent: February 1, 1994
    Assignee: Revlon Consumer Products Corporation
    Inventors: Melvin E. Kamen, Philip Bernstein, Rene T. Rivero
  • Patent number: 5270119
    Abstract: Disclosed are cellulosic sheet material, e.g., liner board, coated with an aqueous emulsion of polystyrene or styrene-alkyl acrylate copolymers, which when dried impart, inter alia, skid or slip resistant properties to the sheet material. The polymer has a glass transition temperature of, for example, 70.degree. C. to 100.degree. C. and an average particle size of from 70 to 150 nanometers.
    Type: Grant
    Filed: October 2, 1991
    Date of Patent: December 14, 1993
    Assignee: PPG Industries, Inc.
    Inventor: Michael J. Yanutola
  • Patent number: 5270380
    Abstract: A method for extending the open time of an aqueous coating composition is provided. This method extends the time during which an aqueous coating can be applied or rebrushed without damaging the film. The open time improvement of this invention is useful for a variety of coatings including paints, stains, varnishes, adhesives, and inks. The aqueous coating composition contains a latex polymer and a modifying compound. More particularly, the latex polymer contains a first reactable group which is complementary to and reacts with a second reactable group in the modifying compound. The complementary reactable groups in the latex polymer and modifying compound provide ionic or covalent binding.
    Type: Grant
    Filed: October 13, 1992
    Date of Patent: December 14, 1993
    Assignee: Rohm and Haas Company
    Inventors: Linda A. Adamson, Richard F. Merritt, Asare Nkansah, Jungsik Lee
  • Patent number: 5266628
    Abstract: A coating composition which may be water based and which is adapted for metallic substrates is disclosed, having: (1) binder resin comprising acrylic polymer having carboxy functionality, and (2) a curing agent comprising hydroxyalkylamide, wherein the ratio of hydroxy groups in the hydroxyalkylamide to carboxy groups in the binder resin is less than 0.5:1, preferably less than 0.4 to 1, and most preferably less than 0.35 to 1. The composition has been found to yield films exhibiting good resistance to water at high temperatures, thereby rendering them particularly suitable for use on metal food and beverage containers that are subjected to sterilization or pasteurization processes.
    Type: Grant
    Filed: March 31, 1992
    Date of Patent: November 30, 1993
    Assignee: PPG Industries, Inc.
    Inventors: William A. Essary, Michael T. List
  • Patent number: 5236493
    Abstract: An antifouling coating composition comprising a binder comprising a non-volatile amine and rosin or maleinised or fumarised rosin. The non-volatile amine is preferably an amine of the formula I ##STR1## where R.sup.1 is a monovalent hydrocarbon group derived from a diterpene and R.sup.2 and R.sup.3 are hydrogen, alkyl or aryl, preferably present in a proportion by weight of 9:1 to 1:9 relative to the rosin or maleinised or fumarised rosin.
    Type: Grant
    Filed: April 12, 1991
    Date of Patent: August 17, 1993
    Assignee: Courtaulds Coatings (Holdings) Limited
    Inventors: Julian E. Hunter, James Reid, David E. J. Arnold, George Hails, deceased, Kenneth F. Baxter
  • Patent number: 5234989
    Abstract: Self-stabilized resin latexes are provided which contain carboxylate salts of post-chlorinated ethylene copolymers having chlorine contents of 20-60 weight percent. The ethylene copolymer salts are derived from ethylene/acrylic acid or ethylene/methacrylic acid copolymers containing 1.5-12 mole percent copolymerized units of acrylic or methacrylic acid. The latexes are particularly useful for preparing resorcinol formaldehyde adhesives.
    Type: Grant
    Filed: April 6, 1992
    Date of Patent: August 10, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: John C. Chen, Royce E. Ennis
  • Patent number: 5230950
    Abstract: Extended polymer compositions are provided which comprise polymers containing pendant functional groups of the formula: ##STR1## extended, i.e. admixed with a chalcogenide having the empirical formula ##STR2## wherein R.sub.1 is a divalent organic radical at least 3 atoms in length, X is organoacyl or cyano, A is a chalcogen, each of R.sub.9 and R.sub.10 is independently selected from hydrogen, NR.sub.11 R.sub.12, NR.sub.13 and monovalent organic radicals, at least one of R.sub.9 and R.sub.10 being NR.sub.11 R.sub.12 or NR.sub.13, each of R.sub.11 and R.sub.12 is independently selected from hydrogen and monovalent organic radicals, and R.sub.13 is a divalent organic radical. These compositions can be extended with significant proportions of the described chalcogenides with corresponding reductions in polymer concentration without significant loss of physical properties. The resulting combinations are particularly useful as binders and coatings.
    Type: Grant
    Filed: October 7, 1991
    Date of Patent: July 27, 1993
    Assignee: Rohm and Haas Company
    Inventor: Charles L. Kissel
  • Patent number: 5213866
    Abstract: Carpet and textile coating compositions are formulated to include fiber or flock pieces so as to improve the tuft pull strength and dimensional stability of the carpet or textile. The coating compositions comprise 10 to 70%, by weight, of a latex binder and 30 to 90%, by weight, of at least one filler, wherein the filler comprises about 0.001 to 100%, by weight, of fiber or flock pieces. Any natural or synthetic fiber may be used in the coating compositions of this invention.
    Type: Grant
    Filed: October 21, 1992
    Date of Patent: May 25, 1993
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Ronald L. Swope, Cheri L. McConnell, Larry S. Fulton
  • Patent number: 5202375
    Abstract: A polymeric emulsion comprising a (i) polymer, (ii) water, and (iii) a surfactant is useful for producing a water-resistant film. The polymer comprises about 25 to about 90 weight percent of a soft monomer whose homopolymer has a T.sub.g of less than about -20.degree. C., about 10 to about 75 weight percent of a hard monomer whose homopolymer has a T.sub.g of greater than about 30.degree. C., about 1 to about 5 weight percent of an olefinic carboxylic acid, and about 0.5 to about 5 weight percent of a cross-linking agent. Typically, the polymer comprises less than about 1 weight percent surfactant and has a T.sub.g of about -50.degree. to about 50.degree. C. and an average particle size of less than about 250 nm. The emulsion generally comprises at least about 40 weight percent solids and has a surface tension of at least about 45 dynes/cm.
    Type: Grant
    Filed: May 6, 1991
    Date of Patent: April 13, 1993
    Assignee: Rohm and Haas Company
    Inventor: John Biale
  • Patent number: 5175205
    Abstract: A latex system can be made from a combination of acids in a base monomer wherein methylenesuccinic acid is used with at least one other monocarboxylic acid.The latex system provides a high pH latex that can be used to treat fiber substrates or alternatively can be blended with other latexes to form coatings.
    Type: Grant
    Filed: October 30, 1991
    Date of Patent: December 29, 1992
    Assignee: The B. F. Goodrich Company
    Inventor: Philip Y. Yang
  • Patent number: 5159011
    Abstract: Aqueous formulations of copolymer latices and polyisocyanate dispersions, containingA) from 5 to 40% by weight of one or more synthetic resins of(a) from 0.1 to 20 parts by weight of one or more monoolefinically unsaturated monomers which carry one or more groups which are reactive with isocyanates and(b) from 80 to 99.9 parts by weight of one or more mono- or diolefinically unsaturated monomers which are copolymerizable with (a) and have no acidic hydrogen atoms,B) from 0.5 to 5% by weight of one or more finely divided, stabilized polyisocyanates,C) effective amounts of dispersants andD) from 5 to 40% by weight of one or more finely divided fillers,are used as coating materials for woven and nonwoven substrates.
    Type: Grant
    Filed: July 16, 1991
    Date of Patent: October 27, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Maria G. Rau, Rainer Blum, Gerd Louis
  • Patent number: 5143729
    Abstract: Ultra-violet screening compounds have been combined with hydrophobic fluid and solid-repellent compounds to provide a spray, and ultimately a thin solid adherent layering, deposit or coating for fabrics and the like that simultaneously imparts both fade or photodegradiation-resisting properties, and fluid and soil repellent properties.
    Type: Grant
    Filed: February 25, 1991
    Date of Patent: September 1, 1992
    Assignee: Fadeguard, Inc.
    Inventor: Peter B. Thompson
  • Patent number: 5143960
    Abstract: A composition comprising (i) a copolymer of ethylene; one or more polar unsaturated alcohols, acids, or esters; and a N-substituted maleimide or (ii) a copolymer of ethylene and one or more polar unsaturated alcohols, acids, or esters grafted with an N-substituted maleimide.
    Type: Grant
    Filed: September 12, 1989
    Date of Patent: September 1, 1992
    Assignee: Nippon Unicar Company Limited
    Inventors: Akitaka Senuma, Toshiyuki Nagai, Kiroku Tsukada, Akio Hayashi
  • Patent number: 5141988
    Abstract: An improved blister resistant paper coating polymer latex for paper coating comprising an aliphatic conjugated diene monomer, monoethylenic monomers and an ethylenically unsaturated carboxylic acid monomer and including a molecular weight modifier such as an organosulfur compound and a base.
    Type: Grant
    Filed: August 10, 1990
    Date of Patent: August 25, 1992
    Assignee: Reichhold Chemicals, Inc.
    Inventors: David W. Suwala, Emil G. Sammak
  • Patent number: 5124384
    Abstract: In a sealant composition comprising a polymer latex, filler, plasticizer, silane adhesion promoter, and fumed silica, the improvement which comprises as the plasticizer a C.sub.1 -C.sub.8 alkyl aryl phthalate, an N-(C.sub.1 -C.sub.8)alkyl arylsulfonamide, or mixtures thereof.
    Type: Grant
    Filed: November 16, 1990
    Date of Patent: June 23, 1992
    Assignee: Air Products and Chemicals, Inc.
    Inventor: Joel E. Goldstein
  • Patent number: 5120359
    Abstract: The present invention provides:(1) an ink composition erasable with a rubber eraser, the composition comprising 1 to 50% of a pigment, 3 to 50% of a resin having a film-forming temperature of 40.degree. C. or higher, 0.5 to 50% of an organic solvent and 7 to 60% of water, based on the weight of the ink composition;(2) an ink composition erasable with a rubber eraser, the composition comprising 2 to 90% of a pigment coated with a resin having a film-forming temperature of 40.degree. C. or higher, 0.5 to 30% of an organic solvent and 0.5 to 30% of water, based on the weight of the ink composition; and(3) an ink composition erasable with a rubber eraser, the composition comprising 2 to 90% of a pigment coated with a resin having a film-forming temperature of 40.degree. C. or higher, 1.5 to 55% of an emulsion (calculated as solids), 0.5 to 30% of an organic solvent and 4.0 to 60% of water, based on the weight of the ink composition.
    Type: Grant
    Filed: October 26, 1989
    Date of Patent: June 9, 1992
    Assignee: Sakura Color Products Corporation
    Inventors: Shingo Uzukawa, Yukito Shoji
  • Patent number: 5026765
    Abstract: Carpet coating compositions are disclosed which comprise 40 to 80 percent by weight filler and 20 to 60 percent by weight of a latex binder, the binder comprising an emulsion polymer ofa) 40 to 80% by weight of a vinyl ester of an alkomoic acid, the acid having from 1 to 13 carbon atoms;b) 5 to 25% by weight of a copolymerizable comonomer having a Tg of at least 50.degree. C.; and;c) 10 to 30% ethylene.
    Type: Grant
    Filed: December 15, 1989
    Date of Patent: June 25, 1991
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Howard G. Katz, David Lunsford, Paul R. Mudge
  • Patent number: 5025062
    Abstract: Coating materials based on synthetic resin contain, as binders, polymers which consist ofA) from 60 to 100% by weight of a tert-butyl ester of an .alpha.,.beta.-ethylenically unsaturated carboxylic acid or dicarboxylic acid of not more than 5 carbon atoms or a mixture of such tert-butyl esters,B) from 0 to 40% by weight of an acrylate or methacrylate of a nontertiary C.sub.1 -C.sub.20 -alkanol or a mixture of these monomers,C) from 0 to 20% by weight of vinyl chloride, vinyl acetate and/or vinyl propionate, the relationship m.sub.C .ltoreq.0.5 m.sub.B being applicable to the amounts m.sub.B and m.sub.C of the monomers B and C,C) from 0 to 10% by weight of acrylic acid, methacrylic acid, acrylamide and/or methacrylamide andE) from 0 to 5% by weight of other copolymerizable monomers.
    Type: Grant
    Filed: May 3, 1990
    Date of Patent: June 18, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Gregor Ley, Wolfgang Schultze, Johannes Vinke, Eckehardt Wistuba
  • Patent number: 4997857
    Abstract: A stabilizer for polymer/polyols characterized by four key features: (1) prepared from a starting polyol having a functionality greater than 4; (2) having at least 60% retained unsaturation; (3) having a viscosity greater than 2000 cSt; and (4) prepared where the starting polyol is capped with alkylene oxide and/or the adduct formed between the starting polyol and the reactive unsaturated compound is capped with ethylene oxide.
    Type: Grant
    Filed: September 30, 1986
    Date of Patent: March 5, 1991
    Assignee: Arco Chemical Technology, Inc.
    Inventors: John F. Timberlake, Siusun K. Leung, Edgar G. Shook, Donald W. Simroth, Richard C. Myerly
  • Patent number: 4975478
    Abstract: The weather and UV-light resistance of polyacetal resin compositions is improved by incorporating into polyacetal resin a stabilizing package comprised of at least one stabilizing agent selected from benzotriazoles, benzophenones, aromatic benzoates, cyanoacrylates, oxalanilides, and hindered amines, and an acylate resin selected from homopolymers or copolymers of acrylic or methacrylic acid, and ester derivatives thereof.
    Type: Grant
    Filed: August 3, 1989
    Date of Patent: December 4, 1990
    Assignee: Polyplastics Co., Ltd.
    Inventor: Sadatsugu Okuda
  • Patent number: 4962141
    Abstract: Aqueous emulsions containing an ethylene-vinyl chloride (EVCl) copolymer and tetramethylol glycoluril are described for use as binder compositions suitable for application onto nonbonded filter paper. The emulsions are prepared by incorporating 4 to 10 wt % tetramethylol glycoluril, based on the total weight of the emulsion copolymer, into an aqueous disperson of a copolymer consisting essentially of 65 to 90 wt % vinyl chloride 5 to 35 wt % ethylene and optionally, up to 10 wt % of a hydroxyalkyl- or carboxylic acid-containing functional comonomer. The polymerization is conducted in the presence of a stabilizing system consisting essentially of 3 to 15 wt % polyvinyl alcohol. Filter paper impregnated with these emulsions maintain tensile strength and flexibility upon being subjected to hot oil.
    Type: Grant
    Filed: March 20, 1989
    Date of Patent: October 9, 1990
    Assignee: Air Products and Chemicals, Inc.
    Inventors: John G. Iacoviello, George Davidowich, Bheema R. Vijayendran, John S. Sadowski
  • Patent number: 4957955
    Abstract: Plastisols of 80 to 5% by weight plasticizer and 20 to 95% by weight particulate polymer containing(a) from 5 to 60% by weight acrylonitrile, methacrylonitrile or mixture thereof(b) from 15 to 95% by weight styrene, .alpha.-methyl styrene or mixture thereof(c) from 0 to 10% by weight of a carboxylic acid copolymerizable with the monomers (a) and (b),(d) from 0 to 30% by weight and, in the absence of component (c), from 10 to 30% by weight of an alkylester of acrylic acid, methacrylic acid or mixtures thereofoptionally a diluent and other constituents, the percentages by weight of plasticizer and polymer being based on the sum of plasticizer and polymer and a process for making such plastisols.
    Type: Grant
    Filed: December 12, 1988
    Date of Patent: September 18, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wolfgang Saur, Herbert Schreiber, Gunter Hilken, Rolf Peter
  • Patent number: 4871787
    Abstract: A flame retardant electrical insulating composition having an antifungal action comprises 100 parts by weight of a polyolefin, 50-300 parts by weight of a metal hydroxide, and at least 0.2 parts by weight of an amine compound. Also, a flame retardant electrical insulating composition having an antifungal action comprises 100 parts by weight of an ethylene-vinyl acetate copolymer with a vinyl acetate content of at least 20 wt % or an ethylene-ethyl acrylate copolymer with an ethyl acrylate content of at least 20 wt %, 50-300 parts by weight of a metal hydroxide, at least 0.2 parts by weight of an amine compound, and at least 0.5 parts by weight of a hydroxyl group containing lubricant.
    Type: Grant
    Filed: June 22, 1988
    Date of Patent: October 3, 1989
    Assignee: Hitachi Cable Ltd.
    Inventors: Yasuaki Yamamoto, Hiroaki Tsukada, Masami Sorimachi, Akihiro Hori
  • Patent number: 4861821
    Abstract: Copolymers produced from 0.5-20% by weight mono-, bis- or trismethylolphenyl allyl ether (I) of formula: ##STR1## n being from 1 to 3, and from 80-99.5 % by weight ethylenic monomers, at least one being a (meth)acrylic monomer are useful in the preparation of coatings, particularly in the field of paints, varnishes, inks and adhesives. Radical polymerization is employed with different stages of polymerization.
    Type: Grant
    Filed: June 26, 1987
    Date of Patent: August 29, 1989
    Assignee: Societe Chimique Des Charbonnages S.A.
    Inventors: Jean Aubry, Serge Cassiani-Ingoni, Remi Hauschild
  • Patent number: 4855402
    Abstract: A self-emulsifiable resin powder can be dispersed in water without utilizing additional surfactants or expanding large amounts of mechanical energy. Such self-emulsifiable resin powders offer numerous distinct advantages over conventional latices. One of the most important benefits that is realized by utilizing self-emulsifiable resin powders is that they can be shipped dry which is the equivalent to shipping a latex with a 100 percent solids content. In other words, such self-emulsifiable resin powders eliminate the necessity for shipping water in latices. The self-emulsifiable resin powders disclosed herein also have the advantage of having low carboxyl contents and of being dispersible into aqueous systems which contain virtually no surfactants. These self-emulsifiable resins contain a relatively small proportion of repeat units which are derived from both acrylic acid and methacrylic acid.
    Type: Grant
    Filed: June 16, 1988
    Date of Patent: August 8, 1989
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Mariano Salazar
  • Patent number: 4824901
    Abstract: Surface treating water-absorbent resins with a polyquaternary amine substantially increases both the rate of water absorption and the quantity of water absorbed and retained by the resin. In addition to improved water absorbing properties, the surface-treated resins maintain the necessary "dry feel" required for most applications.
    Type: Grant
    Filed: April 25, 1988
    Date of Patent: April 25, 1989
    Assignee: American Colloid Company
    Inventors: William Alexander, Mark Anderson, Barbara R. Regan
  • Patent number: 4808484
    Abstract: A peelable protective film is disclosed, which is processed from a composition comprising 100 parts by weight of an ethylene/methyl methacrylate copolymer, from 0.01 to 0.1 part by weight of an inorganic filler, and from 0.01 to 1.0 part by weight of a slip agent. The protective film of the invention, when wrapped around articles having a tacky surface, exhibits good adhesion to the substrate and has a low peeling strength and, therefore, can be readily peeled away as required.
    Type: Grant
    Filed: August 26, 1987
    Date of Patent: February 28, 1989
    Assignees: Sumitomo Chemical Co., Ltd., Japan Butyl Co., Ltd.
    Inventors: Kunio Yamada, Kohzoh Miyazaki, Yoshitaka Oowatari, Yoshio Egami, Toshio Honma
  • Patent number: 4804693
    Abstract: Masonry structures are susceptible to cracking due to distortion caused by movement of their foundation, vibration, and/or drying out subsequent to the construction of the structure. Such cracking often occurs after the structure has been painted. This results in the crack being transmitted through the coating of paint. Upon repainting of the masonry structure new cracks often develop and are transmitted through the paint coating within a short period of time.This invention discloses a crack resistant coating for masonary structures comprising:(1) a crack absorbing layer which is contiguous to the masonry structure which contains beads which are essentially spherical and which are bound by a resin binder, and(2) a conventional coating layer which is contiguous to and covers the crack absorbing layer.
    Type: Grant
    Filed: December 22, 1986
    Date of Patent: February 14, 1989
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: John D. Harvey, Andre V. Gindre
  • Patent number: 4795762
    Abstract: A new water-swellable composition of a gelling agent based on hydrolyzed homo- or copolymers of acrylonitrile and of an inert metal oxide was synthesized. In the process, 1 to 22% of the nitrile groups were saponified to amide groups and 99 to 78% to alkali-metal salts. The obtained composition had a spongy structure and was characterized by high values with regard to both swelling capacity and swelling rate. Therefore it is particularly suitable for diaper manufacture and for agricultural use.
    Type: Grant
    Filed: April 16, 1987
    Date of Patent: January 3, 1989
    Assignee: Akzo NV
    Inventors: Michael Diamantoglou, Christoph Josefiak, Helmut Magerlein
  • Patent number: 4742102
    Abstract: Styrene polymer and copolymer compositions containing both glycerin fatty acid monoester-alkylene oxide adducts and glycerin fatty acid monoesters as antistatic agents produce prolonged antistatic effects unaffected by water washing, showing a resistivity of 10.sup.9 -10.sup.10 .OMEGA., without losing the transparency and mechanical strengths inherent in styrene polymers and copolymers.
    Type: Grant
    Filed: July 28, 1986
    Date of Patent: May 3, 1988
    Assignee: Nippon Steel Chemical Co., Ltd.
    Inventors: Nobutoshi Iwata, Hisanori Kato
  • Patent number: 4740546
    Abstract: An aqueous dispersion of a vinyl copolymer resin is prepared by polymerizing 1 to 15 parts by weight of a polyoxyethylene-containing hydrophilic polymerizable vinyl monomer of which polyoxyethylene moiety has an average molecular weight of 2,000 to 10,000, 99 to 85 parts by weight of at least one specific polymerizable vinyl monomer and 0 to 5 parts by weight of alpha, beta-unsaturated carboxylic acids, salts thereof or anhydrides thereof in an organic solvent, and dispersing the resulting vinyl copolymer resin solution in water.
    Type: Grant
    Filed: June 5, 1987
    Date of Patent: April 26, 1988
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Tsuyoshi Masuda, Zengo Ninomiya
  • Patent number: 4713411
    Abstract: A pigment composition is composed of an intimate mixture of an organic pigment and a polymer. The content of the organic pigment is 75-95 wt. % based on the whole pigment composition. Monomers which form the polymer include 0-40 wt. % of styrene, 20-70 wt. % of a methacrylic ester and 20-50 wt. % of methacrylic acid. The total proportion of styrene, the methacrylic ester and methacrylic acid is at least 85 wt. % of the entire monomers. The pigment composition is prepared by mixing the organic pigment with an aqueous alkaline solution, which contains the polymer and an alkali metal salt, alkali metal hydroxide, lower amine or ammonium, to form an aqueous dispersion. The organic pigment and polymer are then subjected to coprecipitation, preferably, by lowering the pH of the aqueous dispersion beyond 7.0.
    Type: Grant
    Filed: June 2, 1986
    Date of Patent: December 15, 1987
    Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.
    Inventors: Kazuo Kanou, Takamitu Shinoda, Yukio Kanbara
  • Patent number: 4705836
    Abstract: Composites comprising(A) general formula (I), compound of ##STR1## [in the formula, R.sub.1 indicates either hydrogen or methyl group and R.sub.2 indicates hydrogen, alkyl radical with carbon number 1-5 to be possibly substituted with halogen, alkyleneoxide group with carbon number 2-4 to be possibly substituted with halogen or --(CH.sub.2 CH.sub.2 O)nH group (n=integral number of 1-4) to be possibly substituted with either halogen or methyl group],(B) vinyl compounds and/or silane compounds, and optionally(C) free radical developing agent and/or light sensitizer have not only an excellent adhesiveness but anti-irritation and anti-harmfulness against tissue, pulp and the like, for teeth and dentin.
    Type: Grant
    Filed: November 1, 1985
    Date of Patent: November 10, 1987
    Assignee: Nippon Shiken Dental Co., Ltd.
    Inventors: Masasuke Ohtsuka, Yoshinori Harada, Shigeo Tokita, Hideyo Maniwa
  • Patent number: 4704429
    Abstract: The method of producing a toughened, mar-resistant floor film includes the steps:(a) applying to the floor surface a polish containing a cross-linking agent selected from the group that consists essentially of methylated melamine and sodium benzoate, and(b) dry buffing said surface to heat the polish and surface and produce cross-linking of the cross-linking agent within the film and with the floor surface.
    Type: Grant
    Filed: August 20, 1984
    Date of Patent: November 3, 1987
    Assignee: Turco Purex Industrial Corp.
    Inventors: Walter Hackett, Peter E. Galena
  • Patent number: 4680332
    Abstract: Disclosed is a heterophase ink composition comprised of a water insoluble polymer dispersed in a liquid medium, the polymer containing therein an oil soluble dye, and a nonionic stabilizer permanently attached thereto.
    Type: Grant
    Filed: January 24, 1986
    Date of Patent: July 14, 1987
    Assignee: Xerox Corporation
    Inventors: Michael L. Hair, Kar P. Lok, Christopher K. Ober, Melvin D. Croucher, Raymond W. Wong
  • Patent number: 4654397
    Abstract: A process for the preparation of aqueous polymer dispersions which have a low film-forming temperature but still give films having a high block resistance, and the use of these polymer dispersions as binders for coating materials.
    Type: Grant
    Filed: December 2, 1985
    Date of Patent: March 31, 1987
    Assignee: BASF Aktiengesellschaft
    Inventors: Rudolf Mueller-Mall, Michael Melan, Eckehardt Wistuba, Lothar Matthaei
  • Patent number: 4639394
    Abstract: Non-aqueous dispersions of polymeric microparticles are disclosed. The dispersions are prepared by free radical initiated addition polymerization of a polymerizable monomer in the presence of a dispersion stabilizer in an organic liquid. The dispersion stabilizer is a styrene polymer terminated with an alpha, beta-ethylenically unsaturated group. The polymeric microparticles are useful as rheology modifiers in coating compositions.
    Type: Grant
    Filed: April 1, 1985
    Date of Patent: January 27, 1987
    Assignee: PPG Industries, Inc.
    Inventors: Suryya K. Das, Rostyslaw Dowbenko
  • Patent number: 4634724
    Abstract: Masonry structures are susceptible to cracking due to distortion caused by movement of their foundation, vibration, and/or drying out subsequent to the construction of the structure. Such cracking often occurs after the structure has been painted. This results in the crack being transmitted through the coating of paint. Upon repainting of the masonry structure new cracks often develop and are transmitted through the paint coating within a short period of time.This invention discloses a crack resistant coating for masonry structures comprising:(1) a crack absorbing layer which is contiguous to the masonry structure which contains beads which are essentially spherical and which are bound by a resin binder, and(2) a conventional coating layer which is contiguous to and covers the crack absorbing layer.
    Type: Grant
    Filed: September 3, 1985
    Date of Patent: January 6, 1987
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: John D. Harvey, Andre V. Gindre
  • Patent number: 4618640
    Abstract: A hot-melt adhesive composition containing an ethylene copolymer, wax and a tackifying resin as major components, the composition being characterized in that the tackifying resin is partially fumarinized and/or partially maleinized, disproportionated rosin ester.
    Type: Grant
    Filed: March 20, 1985
    Date of Patent: October 21, 1986
    Assignee: Arakawa Kagaku Kogyo Kabushiki Kaisha
    Inventors: Seiichi Tsuchida, Yoshihiro Kodama, Hiroari Hara
  • Patent number: 4586937
    Abstract: An antimisting hydrocarbon solution comprising a hydrocarbon mixed with a copolymer of an alphaolefin and a vinyl alkylenecarboxylic acid, wherein the concentration of said copolymer in said hydrocarbon is about 0.05 to about 2 grams per 100 ml of said solution, wherein said copolymer has the formula: ##STR1## wherein R.sub.1 is an alkyl group having about 1 to about 25 carbon atoms, R.sub.2 is an alkylene group having about 3 to 17 carbon atoms, x is about 95.0 to about 99.99 mole % and y is about 0.01 to about 5 mole %.
    Type: Grant
    Filed: June 29, 1984
    Date of Patent: May 6, 1986
    Assignee: Exxon Research and Engineering Co.
    Inventors: Ilan Duvdevani, John A. Eckert, Donald N. Schulz, Kissho Kitano
  • Patent number: 4548968
    Abstract: A process for preparing a resin extended pigment from crude pigment is disclosed. The process involves dry premilling the crude pigment with the resin followed by comilling the pre-milled pigment with the resin in the presence of water under alkaline conditions.
    Type: Grant
    Filed: June 1, 1984
    Date of Patent: October 22, 1985
    Assignee: Ciba Geigy Corporation
    Inventor: Edward E. Jaffe
  • Patent number: 4539359
    Abstract: A one component moisture curable composition containing (A) a hydrolyzable silyl group-containing vinyl polymer and (B) an acid phosphoric compound having ##STR1## linkage in the molecule as a hardener, which has excellent recoatability, curing property and adhesion to other paint films and is particularly suitable as a coating composition for use in multicoat coating.
    Type: Grant
    Filed: August 5, 1983
    Date of Patent: September 3, 1985
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yasushi Kato, Hisao Furukawa
  • Patent number: 4529762
    Abstract: Compositions and processes for the aqueous emulsion polymerization of ethylenically unsaturated monomers using mixed emulsifiers containing(a) about 99.5 to about 10 parts by weight of an .alpha.-sulfocarboxylic acid alkyl ester containing from 8 to 24 carbon atoms in the carboxylic acid portion and from 1 to 4 carbon atoms in the alcohol portion, and(b) from about 0.5 to about 90 parts by weight of an .alpha.-sulfocarboxylic acid containing from 8 to 24 carbon atoms, and if desired,other anionic and/or non-anionic emulsifiers and/or protective colloids; the mixed emulsifier optionally being completely or partly present in salt form.
    Type: Grant
    Filed: October 18, 1984
    Date of Patent: July 16, 1985
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Rainer Hoefer, Karl Schmid, Bernd Wegemund, Bernhard Bartnick
  • Patent number: 4526815
    Abstract: The method of producing a toughened, mar-resistant floor film includes the steps:(a) applying to the floor surface a polish containing a cross-linking agent selected from the group that consists essentially of methylated melamine and sodium benzoate, and(b) dry buffing said surface to heat the polish and surface and produce cross-linking of the cross-linking agent within the film and with the floor surface.
    Type: Grant
    Filed: November 4, 1983
    Date of Patent: July 2, 1985
    Assignee: TP Industrial, Inc.
    Inventors: Walter J. Hackett, Peter E. Galena
  • Patent number: RE34141
    Abstract: The weather and UV-light resistance of polyacetal resin compositions is improved by incorporating into polyacetal resin a stabilizing package comprised of at least one stabilizing agent selected from benzotriazoles, benzophenones, aromatic benzoates, cyanoacrylates, oxalanilides, and hindered amines, and an acylate resin selected from homopolymers or copolymers of acrylic or methacrylic acid, and ester derivatives thereof.
    Type: Grant
    Filed: August 1, 1991
    Date of Patent: December 8, 1992
    Assignee: Polyplastics Co., Ltd.
    Inventor: Sadatsugu Okuda