Interpolymerized With Hydrocarbon Containing A Single Ethylenic Group Patents (Class 524/562)
  • Patent number: 4526910
    Abstract: Disclosed is an essentially solvent-based, organic, high-solids coating composition containing (A) a film-forming binder system containing a crosslinkable resin having a weight average molecular weight of from about 500 to about 10,000; (B) substantially colorless, substantially inorganic microparticles stably dispersed in the coating composition; and (C) a solvent system for the crosslinkable resin. The substantially inorganic microparticles prior to incorporation in the coating composition range in size from about 1 to about 150 nanometers and are in the form of a sol of the microparticles in which the surface of the inorganic microparticles is essentially free of carbon-containing molecules chemically bonded to the inorganic microparticles.
    Type: Grant
    Filed: September 6, 1983
    Date of Patent: July 2, 1985
    Assignee: PPG Industries, Inc.
    Inventors: Suryya K. Das, Paul P. Greigger, William G. Boberski, James E. Jones, Raymond F. Schappert, Jerome A. Seiner
  • Patent number: 4522958
    Abstract: Disclosed is an essentially solvent-based, organic, high-solids coating composition containing (A) a film-forming binder system containing a crosslinkable resin having a weight average molecular weight of from about 500 to about 10,000; (B) substantially colorless, substantially inorganic microparticles stably dispersed in the coating composition; and (C) a solvent system for the crosslinkable resin. The inorganic microparticles prior to incorporation in the coating composition range in size from about 1 to about 150 nanometers and are in the form of a sol of the microparticles in which carbon-containing molecules are chemically bonded to the inorganic microparticles at the surface of the microparticles.
    Type: Grant
    Filed: September 6, 1983
    Date of Patent: June 11, 1985
    Assignee: PPG Industries, Inc.
    Inventors: Suryya K. Das, William G. Boberski, Paul P. Greigger, James E. Jones, Raymond F. Schappert, Jerome A. Seiner
  • Patent number: 4522972
    Abstract: An aqueous copolymer dispersion can be prepared, with a particular choice of the monomers and the ratios of their amounts, from styrene, esters of acrylic or methacrylic acid, vinyl esters, monomers containing hydroxyl groups, acrylic and/or methacrylic acid, acrylamide or methacrylamide and addition compounds of glycidyl esters of branched monocarboxylic acids with unsaturated carboxylic acids, by polymerization in the presence of an anionic emulsifier and a radical initiator and, if appropriate, a non-ionic emulsifier, which dispersion, in combination with an aminoplast resin, provides thermosetting coatings with excellent properties. These coatings provide highly elastic, weather-resistant, water-resistant surface coatings, which have high adhesion and are free of flaws, on metallic substrates.
    Type: Grant
    Filed: July 14, 1982
    Date of Patent: June 11, 1985
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Josef Mondt, Thaddaus Wirth
  • Patent number: 4500673
    Abstract: An aqueous latex is disclosed which possesses improved water resistance at reduced acrylic ester content for use in exterior latex paints. This latex comprises an aqueous emulsion copolymer of monomers consisting essentially of from 10% to 30% of vinylidene chloride together with 20% to about 50% of styrene, and from 40% to 60% of monoethylenic ester, preferably acrylic or methacrylic esters, the mixture of monomers providing the copolymer with a glass transition temperature in the range of -10.degree. C. to +10.degree. C., and from 0% to 10.0% of a monomer promoting adhesion, the proportions being based on the total weight of monomers copolymerized.
    Type: Grant
    Filed: November 21, 1983
    Date of Patent: February 19, 1985
    Assignee: DeSoto, Inc.
    Inventors: James E. Devona, Martin L. Essigmann
  • Patent number: 4493912
    Abstract: A method of preparing a novel electromagnetic wave attenuating composition comprising forming a curable film forming coating composition and thereafter dispersing an effective amount of an electrically conductive additive in said curable film forming composition under low shear conditions to form said electromagnetic wave blocking composition.
    Type: Grant
    Filed: August 15, 1983
    Date of Patent: January 15, 1985
    Assignee: General Electric Company
    Inventors: Charles D. Dudgeon, Maynard R. Winstead
  • Patent number: 4492784
    Abstract: An adhesive composition for binding a resinous, essentially non-elastomeric monovinyl aromatic-conjugated diene copolymer to itself, consisting essentially of (a) from about 10-90 weight percent of at least one solvent selected from the group consisting of perchloroethylene, 1,1-dichloroethane, and 1,1,1-trichloroethane and (b) from about 90-10 weight percent of a copolymer consisting of a vinyl arene and an acrylate.
    Type: Grant
    Filed: August 16, 1983
    Date of Patent: January 8, 1985
    Assignee: Phillips Petroleum Company
    Inventor: Harold D. Boultinghouse
  • Patent number: 4478968
    Abstract: A process for preparing a resin extended pigment from crude pigment is disclosed. The process involves dry premilling the crude pigment either with or without the resin followed by comilling the premilled pigment with the resin in the presence of water under alkaline conditions. Preferably an organic liquid which wets the resin and the pigment and can improve the crystallinity of the pigment is present in the water milling step.
    Type: Grant
    Filed: April 6, 1983
    Date of Patent: October 23, 1984
    Assignee: Ciba-Geigy Corporation
    Inventor: Edward E. Jaffe
  • Patent number: 4469754
    Abstract: Heat seal compositions and articles including the compositions are disclosed. The compositions exhibit a broad temperature range for making heat seals of variable strengths and are useful as the sole heat seal composition in making flexible packages requiring both permanent and peelable seals.
    Type: Grant
    Filed: May 14, 1982
    Date of Patent: September 4, 1984
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: George L. Hoh, Donald A. Vassallo
  • Patent number: 4444935
    Abstract: A composition comprising a thermoplastic resin in admixture with a mold release effective amount of an acrylate.
    Type: Grant
    Filed: December 15, 1982
    Date of Patent: April 24, 1984
    Assignee: General Electric Company
    Inventors: Kenneth F. Miller, Garland G. Lee
  • Patent number: 4438234
    Abstract: A composition comprising a thermoplastic resin and a mold release effective amount of a vinyl ether.
    Type: Grant
    Filed: December 15, 1982
    Date of Patent: March 20, 1984
    Assignee: General Electric Company
    Inventors: Niles R. Rosenquist, Garland G. Lee
  • Patent number: 4438232
    Abstract: An adhesive composition having improved properties for pressure sensitive adhesive applications has been developed comprising a latex of a polymer formed by polymerizing 40-10 percent vinyl or vinylidene monoaromatic monomer, 45-70 percent C.sub.4-6 cojugated diene, 1-5 percent unsaturated acid, and 5-30 percent C.sub.1-8 alkyl ester of acrylic or methacrylic acid. The adhesive preferably also contains a tackifier resin. The adhesive is useful on a number of applications including the manufacture of labels and tapes.
    Type: Grant
    Filed: August 10, 1982
    Date of Patent: March 20, 1984
    Assignee: Polysar Limited
    Inventor: Ivan S. Lee
  • Patent number: 4418168
    Abstract: Improved stability is imparted to suspension and emulsion polymerized dry particulate vinylidene chloride resin by adding thereto a dispersion of an oil insoluble inorganic particulate stabilizing additive in a liquid plasticizer/stabilizer medium with sufficient mixing to ensure generally uniform distribution of the dispersion onto the resin particles. Optionally, a hindered phenol may be incorporated into the dispersion.
    Type: Grant
    Filed: March 18, 1982
    Date of Patent: November 29, 1983
    Assignee: The Dow Chemical Company
    Inventor: Earl H. Johnson
  • Patent number: 4414360
    Abstract: The production of a toughened, mar-resistant floor film includes the steps:(a) applying to a floor surface a liquid solution containing a cross-linking ingredient,(b) and buffing said floor surface with said solution thereon in moist condition to heat the solution and surface and produce cross-linking of said ingredient with the floor surface.
    Type: Grant
    Filed: November 9, 1981
    Date of Patent: November 8, 1983
    Assignee: Purex Corporation
    Inventors: Walter J. Hackett, Peter E. Galena
  • Patent number: 4399251
    Abstract: A composition comprising a thermoplastic resin and a mold release effective amount of an olefin.
    Type: Grant
    Filed: December 7, 1981
    Date of Patent: August 16, 1983
    Assignee: General Electric Company
    Inventor: Garland G. Lee
  • Patent number: 4394128
    Abstract: Taught is a method of sizing polyester yarn for weaving comprising the steps of applying thereto a latex having an acid pH and of a free radical initiated vinyl polymer having a weight average molecular weight of from about 300,000 to about 2,500,000, said polymer in dried film form being hydrophobic and not redispersible in a solution at a pH of from about 2 to 7 but redispersible by an aqueous alkaline medium, said polymer being prepared from monomers consisting essentially of by weight, 45-65% butyl acrylate a total of 28-45% styrene and/or methyl methacrylate and a total of 8-14% acrylic acid and/or methacrylic acid, and drying the yarn.
    Type: Grant
    Filed: October 31, 1980
    Date of Patent: July 19, 1983
    Assignee: Rohm and Haas Company
    Inventor: Hal C. Morris
  • Patent number: 4388424
    Abstract: A lightweight extrudible or trowellable caulk or sealant composition can be compounded from polymeric acrylic binders containing dispersed therein sufficient microballoons with minor amounts of the ingredients to provide a pliable caulk material exhibiting good heat insulation properties, low shrinkage, and flexability in use.
    Type: Grant
    Filed: November 5, 1981
    Date of Patent: June 14, 1983
    Assignee: SCM Corporation
    Inventors: Samuel C. Kennell, Ronald F. Witkiewicz
  • Patent number: 4371642
    Abstract: A process is disclosed for preparing resin extended pigments containing from 10% to 75% and preferably 25% to 50% by weight, based on the amount of pigment and resin present. The crude pigment and resin are premilled dry, such as in a ball mill, in a manner equivalent to that used to prepare small particle size highly aggregated pigment. Following premilling the pigment and resin are milled in an organic liquid capable of ripening the pigment particles to pigmentary size or simply improving their crystallinity which organic liquid at 30.degree. C., can dissolve no more than 5 g/l and preferably no more than 2 g/l of the resin.
    Type: Grant
    Filed: July 7, 1981
    Date of Patent: February 1, 1983
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Edward E. Jaffe
  • Patent number: 4370450
    Abstract: A process for the production of modified polypropylene particles by polymerizing vinyl monomers in aqueous suspension wherein (a) an aqueous suspension is prepared which, based on 100 to 2000 parts by weight of water, contains 100 parts by weight of polypropylene particles, 4 to 30 parts by weight of a polar vinyl monomer and based on 100 parts by weight of the monomer, 0.1 to 10 parts by weight of a radical chain polymerization initiator which has a half life of at least 2 h at a temperature of 80.degree. to 135.degree. C. and 10 to 1200 parts by weight of an organic solvent which is capable of swelling polypropylene, of which the boiling point at 760 Torr is at least 100.degree. C. and which is miscible with the monomers in any proportion; (b) the aqueous suspension is heated without decomposition of the initiator, the polypropylene being swollen and the monomer penetrating into the polypropylene, after which (c) the aqueous suspension is kept at temperatures of .gtoreq.85.degree. C.
    Type: Grant
    Filed: May 26, 1981
    Date of Patent: January 25, 1983
    Assignee: Bayer Aktiengesellschaft
    Inventors: Ulrich Grigo, Josef Merten, Rudolf Binsack
  • Patent number: 4369272
    Abstract: A process is disclosed for preparing resin extended pigments containing from 10% to 75% and preferably 20% to 50% by weight, based on the amount of pigment and resin present. The crude pigment and resin are comilled, such as in a ball mill, in a manner equivalent to that used to prepare pigmentary grade pigment from crude pigment. Liquids if they are present should not affect the free flowing nature of the mill powder. The resin is a polyolefin or a copolymer of ethylene and up to 25% of acrylic acid, methacrylic acid, vinyl acetate, or oxidized ethylene units preferably softening at from 80.degree. to 140.degree. C.
    Type: Grant
    Filed: July 7, 1981
    Date of Patent: January 18, 1983
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Edward E. Jaffe
  • Patent number: 4366293
    Abstract: This invention provides a graft copolymer of at least one acrylic monomer and polystyrene, in which at least about 8 percent of the total weight of said graft copolymer is derived from acrylic acid, methacrylic acid, or both. It also provides anionic aqueous dispersions of such graft copolymers and coating compositions containing them.
    Type: Grant
    Filed: June 17, 1981
    Date of Patent: December 28, 1982
    Assignee: Mobil Oil Corporation
    Inventor: Michael A. Tobias
  • Patent number: 4360640
    Abstract: This invention provides a graft copolymer of at least one acrylic monomer and a random copolymer of a styrene and allyl alcohol, in which at least about 8 percent of the total weight of said graft copolymer is derived from acrylic acid, methacrylic acid, or both. It also provides anionic aqueous dispersions of such graft copolymers and coating compositions containing them.
    Type: Grant
    Filed: June 17, 1981
    Date of Patent: November 23, 1982
    Assignee: Mobil Oil Corporation
    Inventor: Michael A. Tobias
  • Patent number: 4360642
    Abstract: This invention provides a graft copolymer of at least one acrylic monomer and a random copolymer of a styrene and (meth)acrylonitrile, in which at least about 8 percent of the total weight of said graft copolymer is derived from acrylic acid, methacrylic acid, or both. It also provides anionic aqueous dispersions of such graft copolymers and coating compositions containing them.
    Type: Grant
    Filed: June 18, 1981
    Date of Patent: November 23, 1982
    Assignee: Mobil Oil Corporation
    Inventor: Michael A. Tobias
  • Patent number: 4353997
    Abstract: The disclosure of this application is directed to a water-curable composition comprising a water-curable, silane modified alkylene-alkyl acrylate copolymer, a mineral filler and a halogenated flame retardant additive. These compositions are useful as extrudates about wires and cables providing insulation or jacketing thereon characterized by resistance to deformation and by flame retardancy.
    Type: Grant
    Filed: April 2, 1981
    Date of Patent: October 12, 1982
    Assignee: Union Carbide Corporation
    Inventor: Michael J. Keogh
  • Patent number: 4349643
    Abstract: A reaction injection molding process for producing a coated polyurethane part in which a liquid mixture of polyurethane reactants is injected into a mold where it is reacted and molded into a shaped part at elevated temperatures. The surface of the mold is coated, prior to molding, with a coating composition containing a polyurethane catalyst. The catalyst acts to bond the coating composition to the molded part so that the shaped part upon removal from the mold contains a firmly adherent coating of the coating composition.
    Type: Grant
    Filed: March 30, 1981
    Date of Patent: September 14, 1982
    Assignee: International Telephone and Telegraph Corporation
    Inventor: Gulam Mohiuddin
  • Patent number: 4341213
    Abstract: Nonwoven fabrics are bonded by a binding agent which comprises an aqueous dispersion of an organic polymer coupled to an inorganic filler by means of an organosilane or organotitanate coupling agent. Such fabrics possess properties which render them exceptionally suitable for use as top sheets for disposable diapers and the like.
    Type: Grant
    Filed: August 13, 1981
    Date of Patent: July 27, 1982
    Assignee: The Kendall Co.
    Inventor: Lawrence B. Cohen
  • Patent number: 4336166
    Abstract: Storage-stable, ice-proof, adhesives characterized by superior rheological and machining properties are prepared from an ammoniacal mixture of starch, a zinc salt of a carboxylated styrene-acrylate resin, peptizer and water.
    Type: Grant
    Filed: February 13, 1981
    Date of Patent: June 22, 1982
    Assignee: National Starch and Chemical Corporation
    Inventors: Anatole G. Penczuk, Julius Sirota
  • Patent number: 4320038
    Abstract: The disclosure of this application is directed to a composition of a copolymer of an alkylene-alkyl acrylate, a talc filler coated with a metal salt of a fatty acid and a non-polar flame retardant additive. The compositions of this invention are useful as insulation about electrical conductors, providing insulated electrical conductors which have improved flame retardant properties and improved insulation resistance.
    Type: Grant
    Filed: November 25, 1980
    Date of Patent: March 16, 1982
    Assignee: Union Carbide Corporation
    Inventor: Michael J. Keogh
  • Patent number: T102701
    Abstract: A liquid ink for use in ink jet printing, comprising a water-based dye, a water-soluble styrene/acrylic copolymer as the sole binder constituent, water and ammonia as a volatile drying conformant.
    Type: Grant
    Filed: March 1, 1982
    Date of Patent: February 1, 1983
    Inventors: Robert S. Cutler, Sterritt R. Fuller, Jr.