Interpolymer Of Two Or More Diene Monomers Patents (Class 524/573)
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Patent number: 11859039Abstract: Branched block copolymers, derived from alkenyl aromatic hydrocarbon-1,3-diene monomer system, and branched polyisoprene homopolymers, derived from isoprene, are obtained by polymerization in the presence of an anionic initiator; at a temperature from 0° C. to 100° C.; followed by coupling with a multifunctional coupling agent of formula (R1O)3Si—Y—Si(OR2)3, wherein R1 and R2 are independently C1-C6 alkyl groups; and Y is a C2-C8 alkylene group. The polymers thus obtained can be used in many applications, including rubber cements having high solids content and low zero shear viscosities, and for producing aqueous latices therefrom.Type: GrantFiled: December 3, 2019Date of Patent: January 2, 2024Assignee: CARIFLEX PTE. LTD.Inventors: Adrie van der Huizen, Wouter de Jong, Henk van de Weg, Maarten Tromp, Laurens Engelen
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Patent number: 11530287Abstract: A conjugated diene-based rubber including a polymer block (A) containing isoprene monomer unit as the main component and a polymer block (B) containing 1,3-butadiene monomer unit as the main component, wherein at least one of the polymer block (A) and the polymer block (B) contains a unit of a vinyl compound having a functional group interactive with silica, the polymer block (A) has a weight average molecular weight (Mw) in the range of 1,000 to 30,000, and the entire conjugated diene-based rubber has a weight average molecular weight (Mw) in the range of 50,000 to 5,000,000.Type: GrantFiled: September 28, 2018Date of Patent: December 20, 2022Assignees: ZEON CORPORATION, SUMITOMO CHEMICAL COMPANY, LIMITED, ZS ELASTOMERS CO., LTD.Inventors: Takuro Sakurai, Takashi Iizuka, Mana Fujii, Hisakatsu Hama
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Patent number: 10920047Abstract: Crumb rubber obtained from recycled tires is subjected to an interlinked substitution process. The process utilizes a reactive component that interferes with sulfur bonds. The resulting treated rubber exhibits properties similar to those of the virgin composite rubber structure prior to being granulated, and is suitable for use in fabricating new tires, engineered rubber articles, and asphalt rubber for use in waterproofing and paving applications.Type: GrantFiled: August 25, 2020Date of Patent: February 16, 2021Inventor: William B. Coe
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Publication number: 20150133600Abstract: A method for producing a conjugated diene rubber is provided which includes the steps of: (a) forming a polymer block (A) by using a polymerization initiator in an inert solvent, the polymer block (A) having an active terminal and containing a specific amount of an isoprene monomeric unit and a specific amount of an aromatic vinyl monomeric unit; (b) forming a polymer block (B) having an active terminal and containing a specific amount of a 1,3-butadiene monomeric unit and, as needed, a specific amount of an aromatic vinyl monomeric unit, thereby obtaining a conjugated diene polymer chain having an active terminal and having the polymer block (A) and a polymer block (B); (c) bringing a specific amount of a predetermined denaturant into reaction with the active terminal of the conjugated diene polymer chain having the active terminal.Type: ApplicationFiled: August 14, 2013Publication date: May 14, 2015Inventors: Takashi Iizuka, Tatsuo Sasajima
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Patent number: 8901195Abstract: A two part high solids low volatile organic compounds durable curable waterproof liquid rubber formulation with a solids content of at least 60 percent solids by volume based on the total coating formulation, wherein a first component has EPDM, a solvent, a curative, an additive, and a blend of a pigment and a filler. The second component contains solvent and a metal drier.Type: GrantFiled: February 12, 2014Date of Patent: December 2, 2014Assignee: Lion Copolyer Geismar, LLCInventors: Michael J. Molnar, Arthur J. Fontenot, III, Harold William Young, Jr., Daniel S. Nelson, Augusto Caesar Ibay
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Publication number: 20140275404Abstract: The present invention relates to a conjugated diene based polymer comprising a monomer unit derived from at least one conjugated diene selected from 1,3-butadiene and isoprene and a monomer unit derived from a compound having two conjugated carbon-carbon double bonds and one or more non-conjugated carbon-carbon double bond.Type: ApplicationFiled: March 5, 2014Publication date: September 18, 2014Applicant: Sumitomo Chemical Company, LimitedInventor: Mana FUJII
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Publication number: 20130281588Abstract: A composition includes an elastomer and a ketoximo silane or a ketoxime additive.Type: ApplicationFiled: August 31, 2011Publication date: October 24, 2013Applicant: Bridgestone CorporationInventors: Chenchy J. Lin, Yaohong Chen, Atsushi Fukushima, William L. Hergenrother, Terrence E. Hogan
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Patent number: 8546506Abstract: The invention features compositions and methods for producing polymers of isoprene derived from renewable resources such as isoprene produced from cultured cells that use renewable carbon sources. A starting isoprene composition, such as a bioisoprene composition, is distinguished from petroleum based isoprene by the purity profile (such as lower levels of certain C5 hydrocarbons other than isoprene, presence of certain compounds associated with the biological process for production) and the relative content of the carbon isotopes. Polymers obtained by polymerization of such starting isoprene composition according to this invention, such as a polyisoprene homopolymer or a copolymer having repeat units that are derived from isoprene, are distinguishable from isoprene containing polymers from petrochemical resources.Type: GrantFiled: June 16, 2010Date of Patent: October 1, 2013Assignees: The Goodyear Tire & Rubber Company, Danisco US Inc.Inventors: Joseph C. McAuliffe, Sergey Paramonov, Stephan Rodewald, Karl J. Sanford
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Patent number: 8333903Abstract: The present invention relates to a Phase Change Material (PCM) composition comprising a) from 20 to 80 wt % of a PCM; and b) from 20 to 80 wt % of one or more polymers chosen from the group consisting of b1) Very Low Density Polyethylene (VLDPE) having a density equal or lower than 0.910 g/cm3 measured according to ASTM 792; b2) Ethylene Propylene Rubber (EPR) having a density equal or lower than 0.900 g/cm3 measured according to ASTM 792; b3) Styrene Ethylene Butadiene Styrene (SEBS) copolymers; and b4) Styrene Butadiene Styrene (SBS) copolymers. The PCM composition of the present invention can be used in applications where thermal management is needed, like for example in building, automotive, packaging, garments and footwear.Type: GrantFiled: June 20, 2011Date of Patent: December 18, 2012Assignees: E I du Pont de Nemours and CompanyInventors: Loic Pierre Rolland, Raymond Joseph Reisdorf
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Patent number: 8334340Abstract: A sulfur-containing cycloaliphatic compound, useful as a crosslinker for filled sulfur-vulcanizable elastomer compositions, is represented by the general formula: G[—CaH2a—S—S(?O)b—R]n wherein G is a saturated, monocyclic aliphatic group of valence n containing from 5 to 12 carbon atoms and optionally containing at least one halogen or a saturated monocyclic silicone [RSiO—]n[R2SiO—]p group of valence n; each R independently is a monovalent hydrocarbon of up to 20 carbon atoms; each occurrence of subscripts a and b independently is an integer wherein a is 2 to 6 and b is 1 or 2; n is an integer of from 3 to 6; and p is an integer of from 0 to 3.Type: GrantFiled: October 30, 2008Date of Patent: December 18, 2012Assignee: Momentive Performance Materials, Inc.Inventors: Michael Joseph O'Brien, Robert James Perry, Richard W. Cruse, William Michael York, Carla Recker, Thomas Kramer, Katharina Herzog
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Patent number: 8318846Abstract: An object of the present invention is to provide an olefin-based thermoplastic elastomer composition that has both weatherability and flexibility at low temperatures, is excellent in fluidity, and causes no stickiness even in the use at high temperatures; a process oil composition for elastomers that serves as the raw material of the thermoplastic elastomer composition and contributes to the above characteristics; and an oil-extended elastomer containing the process oil composition. The process oil composition for elastomers of the present invention has a property that, when 20 parts by weight of the process oil composition for elastomers are blended with respect to 100 parts by weight of a propylene homopolymer, the melting point of the propylene homopolymer is lowered by 2 to 4.5° C. compared to that of the propylene homopolymer without blending.Type: GrantFiled: November 10, 2006Date of Patent: November 27, 2012Assignee: Mitsui Chemicals, Inc.Inventors: Yuichi Ito, Hidenari Nakahama, Kotaro Ichino
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Publication number: 20120199200Abstract: An edge seal for manufacturing two-pane or multi-pane insulating glass or solar modules includes a sealant and a bonding agent. The sealant contains a polymer modified with special reactive groups and has the following overall composition: olefinic polymers included in an amount from about 10% to about 90% by weight of the total composition; at least one filler included in an amount from about 10% to about 65% by weight of the total composition; at least one inorganic filler that is a thermal and oxidative stabilizer in an amount from about 2% to about 30%; at least one of a desiccant and a water scavenger included in an amount from about 2.5% to about 25% by weight of the total composition; and at least one aging resistor including an anti-oxidant or UV stabilizer included in an amount from about 0% to about 3% by weight of the total composition.Type: ApplicationFiled: October 14, 2010Publication date: August 9, 2012Applicant: ADCP Products, Inc.Inventors: Harald Becker, Heike Brucher, Norbert Schott
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Publication number: 20120196976Abstract: The invention relates to the use of an adhesive composition between a vulcanized rubber part and an uncured or prevulcanized or vulcanized rubber part, based on at least one highly unsaturated elastomer chosen from the group formed by natural rubber, polyisoprene, polybutadiene, styrene-butadiene, styrene-isoprene and butadiene-isoprene copolymers and styrene-butadiene-isoprene terpolymers, an aliphatic solvent and a “curing” system comprising at least one stable aryl dinitrile oxide compound.Type: ApplicationFiled: March 30, 2010Publication date: August 2, 2012Applicants: Michelin Rechercheet Technique S.A., Societe De Technologie MichelinInventors: José Carlos Araujo Da Silva, Vincent Hunault, Pierre Robert, Anne Veyland
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Patent number: 8207275Abstract: A functionalized polymer defined by the formula ?-R1-?, where ? is a polymer chain, R1 is a bond or a divalent organic group, and ? is a sulfur-containing heterocycle.Type: GrantFiled: May 24, 2010Date of Patent: June 26, 2012Assignee: Bridgestone CorporationInventors: Terrence E. Hogan, Christine Rademacher, William Hergenrother, David F. Lawson
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Publication number: 20120157571Abstract: A rubber composition that can be used for the manufacture of tires, based on at least one diene elastomer; one sulphur-based crosslinking system; one inorganic filler as reinforcing filler; one coupling agent of general formula I below: (HO)3-nR1nSi—Z—Sm—R2 wherein in which: R1, which are identical or different, each represent a monovalent hydrocarbon-based group chosen from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 18 carbon atoms; R2 represents a monovalent hydrocarbon-based group chosen from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 30 carbon atoms; Z represents a divalent bonding group comprising from 1 to 18 carbon atoms; n is an integer equal to 0, 1 or 2; and m is a number greater than or equal to 2.Type: ApplicationFiled: May 20, 2010Publication date: June 21, 2012Applicants: Michelin Recherche et Technique S.A., Societe De Technologie MichelinInventors: Karine Longchambon, José Carlos Araujo Da Silva, Nocolas Seeboth
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Publication number: 20120142840Abstract: Method of manufacturing granulates or continuous strips intended for feeding an extrusion machine, formed of a gel comprising at least, as majority elastomer, a styrene thermoplastic elastomer and more than 200 phr of an extender oil, each element of the granulate having a given surface area. The granulate element is sized so that the compactness, of a granulate element, is less than a value decreasing from 1500 m?1 to 375 m?1 and deposited on the surface of said granulates is an anti-tack agent having a value increasing from 2 cm3 to 8 cm3 per m2 of granulate surface area, when the mean size of the particles of said anti-tack agent increases from a value of 1 ?m to 100 ?m.Type: ApplicationFiled: March 8, 2010Publication date: June 7, 2012Applicant: Societe de Technologie MichelinInventors: Vincent Abad, Jean-Marie Mus
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Patent number: 8183327Abstract: The present invention provides: a rubber composition for a tire having favorable productivity, excellent heat aging resistance and abrasion resistance, and excellent fuel economy; and a pneumatic tire using the rubber composition. The rubber composition contains neither soluble sulfur nor insoluble sulfur, and contains diene rubber, 1-15 parts by mass of compound 1 represented by formula (1) and 0.1-5 parts by mass of compound 2 represented by formula (2), per 100 parts by mass of the diene rubber, and the amount ratio of compound 1 to compound 2 (compound 1/compound 2) is 1-8. wherein R1-R4 are the same or different, and represent C1-20 alkyl, C6-20 aryl, or C7-20 aralkyl, and n represents an integer of 1-12; wherein R5-R7 are the same or different, and represent C5-12 alkyl, x and y are the same or different, and represent an integer of 2-4, and m represents an integer of 0-10.Type: GrantFiled: September 23, 2010Date of Patent: May 22, 2012Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Kazuo Hochi
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Patent number: 8168715Abstract: According to the invention, a sliding coating for winter sports equipment is provided, which has a copolymer (I) and optionally a copolymer (II), wherein the sliding coating for a winter sports equipment comprises a copolymer (I) having 10% or more of structural building blocks derived from propylene monomers, based on the total number of the structural building blocks of the copolymer (I), and 1% or more of structural building blocks derived from another olefin, based on the total number of the structural building blocks of the copolymer (I), wherein the sliding coating does not have a copolymer, which has 50% or more of structural building blocks derived from ethylene monomers, based on the total number of the structural building blocks of the copolymer.Type: GrantFiled: December 21, 2005Date of Patent: May 1, 2012Inventor: Florian Felix
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Patent number: 8143344Abstract: The present invention is further directed to a method of producing a particulate composite of silica and elastomer comprising the steps of dispersing a diene based elastomer in a hydrophobic liquid to form an elastomer dispersion; mixing the elastomer dispersion with an aqueous solution of an alkali metal silicate to form a mixture; adding a precipitating agent to the mixture to precipitate a porous silica onto the dispersed elastomer to form a particulate composite of silica and elastomer comprising a porous silica shell at least partially surrounding a core of diene based elastomer; and optionally adding a separating agent to remove the hydrophobic liquid from the particulate composite.Type: GrantFiled: December 3, 2009Date of Patent: March 27, 2012Assignee: The Goodyear Tire & Rubber CompanyInventors: Georges Koster, Wolfgang Lauer
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Patent number: 8053512Abstract: A backbone modified polymer comprising the reaction product of an elastomeric polymer and a sulfide modifier represented by Formula 1: AS—Y-Zm (Formula 1), and wherein Y is (C12-C100) aralkyl, (C12-C100) aryl, (C12-C100) alkyl, or (C12-C100) dialkylether (alkyl-O-alkyl), and wherein each may be optionally substituted with (C1-C4alkyl, (C1-C4alkoxy, (C7-C16aryl, (C7-C16 aralkyl, nitrile, amine, NO2, alkoxy, or thioalkyl; S is sulfur; A is hydrogen, —(S)p—R1 or -MR2R3R4; Z is —SH, —S-MR5R6R7, —S—(S)p—R8, —NR9R10, —NR11COR12, —O—CO—R13, —NCO, or —COOR14; M is silicon or tin; N is nitrogen; O is oxygen; m is the number one, two or three; p is the number one, two, three, four or five; R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12, R13 and R14 are the same or different, and are each, independently, selected from hydrogen (H), (C1-C16) alkyl, (C6-C16) aryl, (C7-C16) aralkyl or (C3-C30) tri(hydrocarbyl)silyl, and wherein the hydrocarbyl groups are each independently selected from (C1-C16) alkyl, (C6-C16) aryl, orType: GrantFiled: December 14, 2007Date of Patent: November 8, 2011Assignee: Styron Europe GmbHInventors: Sven K. H. Thiele, Joachim Kiesekamp
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Publication number: 20110180195Abstract: Alkoxy-modified silsesquioxane compounds are described. The alkoxy-modified silsesquioxane compounds contain an alkoxysilane group that participates in an alkoxysilane-silica reaction as a silica dispersing agent in rubber, with the release of zero to about 0.1% by weight of the rubber of volatile organic compounds (VOC), especially alcohol, during compounding and further processing. Further described are methods for making alkoxy-modified silsesquioxanes, methods for making vulcanizable rubber compounds containing alkoxy-modified silsesquioxanes, vulcanizable rubber compounds containing alkoxy-modified silsesquioxanes, and pneumatic tires comprising a component that contains alkoxy-modified silsesquioxanes.Type: ApplicationFiled: September 16, 2010Publication date: July 28, 2011Applicant: Bridgestone CorporationInventors: William L. Hergenrother, Chenchy J. Lin, Terrence E. Hogan, Ashley S. Hilton
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Publication number: 20110130511Abstract: A modified natural rubber particle having carbon-carbon double bonds assigned to multifunctional vinyl monomers graft-copolymerized onto the surface of the modified natural rubber particle, which is prepared by graft-copolymerization of multifunctional vinyl monomers having two or more carbon-carbon double bonds onto natural rubber particles or deproteinized natural rubber particles. One of the methods for producing a modified natural rubber particle includes the steps of: forming inclusion complex of the multifunctional vinyl monomers having two or more carbon-carbon double bonds with a guest-protecting agent to protect at least one of the double bonds of the multifunctional vinyl monomers; graft-copolymerizing the resulting inclusion complex onto natural rubber particles or deproteinized natural rubber particles; and deprotecting the protected double bonds by removing the guest-protecting agent from the obtained graft-copolymer.Type: ApplicationFiled: July 9, 2009Publication date: June 2, 2011Applicants: TOKAI RUBBER INDUSTRIES, LTD., NATIONAL UNIVERSITY CORPORATION NAGAOKA UNIVERSITY OF TECHNOLOGYInventors: Osamu Wakisaka, Akihiro Shibahara, Seiichi Kawahara, Yoshimasa Yamamoto, Nanthaporn Pukkate
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Patent number: 7943696Abstract: A vulcanized rubber composition comprising the vulcanization product of a functional polymer, where the functional polymer is defined by the formula where R is selected from C1 to C6 trialkyl-silyl groups, C1 to C20 alkyl groups, C4 to C20 cycloalkyl groups, C6 to C20 aryl groups, thienyl, furyl, and pyridyl groups; and R may optionally have attached thereto any of the following functional groups: C1 to C10 alkyl groups, C6 to C20 aryl groups, C2 to C10 alkenyl groups, C3 to C10 non-terminal alkynyl groups, ethers, tert-amines, oxazolines, thiazolines, phosphines, sulfides, silyls, and mixtures thereof; where R1 is selected from C2 to C8 alkylene groups, where X is NR, and where ? is a polymer chain.Type: GrantFiled: September 15, 2009Date of Patent: May 17, 2011Assignee: Bridgestone CorporationInventors: Terrence E. Hogan, William Hergenrother, Yuan-Yong Yan, David Lawson
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Publication number: 20100216939Abstract: Pneumatic rubber tire with an outer, circumferential tread comprised of specialized cis 1,4-polybutadiene rubber based silica/carbon black reinforced rubber composition.Type: ApplicationFiled: February 24, 2009Publication date: August 26, 2010Inventors: Junling Zhao, Aaron Scott Puhala, Steven Wayne Cronin, Paul Harry Sandstrom, John Joseph Andre Verthe
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Patent number: 7671126Abstract: The invention relates to a tire having a tread which contains coal dust to promote a fast wearing tread running surface designed to expel internally heated tread rubber.Type: GrantFiled: December 3, 2008Date of Patent: March 2, 2010Assignee: The Goodyear Tire & Rubber CompanyInventors: Paul Harry Sandstrom, Steven Wayne Cronin, Thomas Charles Lippello, III, Mark Alan Keto, Larry Alan Kraus
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Patent number: 7612144Abstract: An initiator is presented for anionically polymerizing monomers, to provide a functional head group on the polymer. A polymer having a functional head group derived from a sulfur containing anionic initiator, and optionally as additional functional group resulting from the use of a functional terminating reagent, coupling agent or linking agent is also provided. A method is presented for anionically polymerizing monomers comprising the step of polymerizing the monomers with a sulfur containing anionic initiator to provide a functional head group on the polymer. An elastomeric compound, comprising a functional polymer and filler is also described. Also provided is a tire having decreased rolling resistance resulting from a tire component containing a vulcanizable elastomeric compound.Type: GrantFiled: September 13, 2007Date of Patent: November 3, 2009Assignee: Bridgestone CorporationInventors: Terrence E. Hogan, William Hergenrother, Yuan-Yong Yan, David Lawson
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Publication number: 20090143502Abstract: Aqueous dispersions containing hydrophobic materials that are useful as reduced volatile organic content may be utilized as a coating, a stain, a resin, a polymer, or an additive. Specifically, the aqueous dispersion may contain one or more of a carboxyalkyl cellulose ester, such as carboxymethyl cellulose acetate butyrate, a fluorosurfactant, such as a polyoxetane fluorosurfactant or a fluoroaliphatic polymeric ester based surfactant, a water dispersible resin, and optionally, a C-11 ketone and/or surfactant.Type: ApplicationFiled: July 11, 2006Publication date: June 4, 2009Applicant: Wood Coatings Research Group, Inc.Inventor: Ronald Obie
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Publication number: 20090111936Abstract: The invention relates to a bright stock base oil blend comprising of a paraffinic base oil component having a viscosity at 100° C. of from 8 to 25 mm?/sec and a residual and de-asphalted oil component, and the use of said blend as part of a gear oil or a cylinder oil formulation, and other uses.Type: ApplicationFiled: July 3, 2006Publication date: April 30, 2009Inventor: David John Wedlock
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Publication number: 20090062457Abstract: A block copolymer of the formula [S-I-(I/B)]nX or [S-I-(I/B)-/B]nX or mixtures thereof wherein each S is independently a polymer block of an alkenyl arene; each I is a polymer block of isoprene; each B is a polymer block of butadiene and each (I/B) is a mixed random polymer block of isoprene and butadiene in a weight ratio I:B of from about 10:90 to about 90:10, n is an integer equal to or greater than 2, X is the residue of a coupling agent, and wherein the alkenyl arene content of the block copolymer represents a weight ratio of the alkenyl arene block to conjugated diene block of the total block copolymer and is in the range of from about 15 to about 35 wt %.Type: ApplicationFiled: September 4, 2007Publication date: March 5, 2009Applicant: KRATON POLYMERS U.S. LLCInventors: Dale L. HANDLIN, JR., Carl L. WILLIS, Robert C. BENING
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Patent number: 7441574Abstract: The present invention relates to a pneumatic tire including at least one component, said at least one component including a rubber composition, said rubber composition including at least one diene based rubber; and at least one metal organic framework material including divalent zinc and a multidentate organic ligand, wherein the at least one metal organic framework material at least partially incorporates at least one guest additive.Type: GrantFiled: August 17, 2006Date of Patent: October 28, 2008Assignee: The Goodyear Tire & Rubber CompanyInventors: Georges Koster, Claude Ernest Felix Boes, Rene Jean Zimmer, Hans-Bernd Fuchs, Fahri Ozel, Wolfgang Albert Lauer, Lothar Braun
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Patent number: 7351759Abstract: An elastomeric composition usable for the manufacture of tires, based on at least (i) a diene elastomer, (ii) an inorganic filler as reinforcing filler and (iii), as (inorganic filler/diene elastomer) coupling agent, a polysilylated organosilicon compound which is at least bifunctional and can be grafted onto the elastomer by means of a sulfur group having a polythiosulfenamide function, of formula: ?Si—A—Sx—NR1R2 ,??(I) in which: A is a divalent bond group, whether straight-chain or branched, which makes it possible to join the polythiosulfenamide group to a first silicon atom of the organosilicon compound; x is an integer or fractional number of from 2 to 4; R1 represents hydrogen, a monovalent hydrocarbon group, or R2; and R2 represents the grouping: —B—Si?, in which: B is a divalent bond group, whether straight-chain or branched; Si represents a second silicon atom of the organosilicon compound. The invention also concerns tires and tire treads comprising a composition of this type.Type: GrantFiled: December 11, 2003Date of Patent: April 1, 2008Assignee: Michelin Recherche et Technique S.A.Inventors: José-Carlos Araujo-Da-Silva, Christiane Blanchard, Gérard Mignani, Salvatore Pagano, Jean-Claude Tardivat
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Patent number: 7335411Abstract: Vulcanizable elastomeric compositions and vulcanizates are prepared by employing a strong acid. The strong acid is believed to enhance the reaction between a silica particle and a silica-reactive compound.Type: GrantFiled: October 26, 2005Date of Patent: February 26, 2008Assignee: Bridgestone CorporationInventors: Chenchy Jeffrey Lin, William L. Hergenrother
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Patent number: 7319123Abstract: An initiator is presented for anionically polymerizing monomers, to provide a functional head group on the polymer. A polymer having a functional head group derived from a sulfur containing anionic initiator, and optionally as additional functional group resulting from the use of a functional terminating reagent, coupling agent or linking agent is also provided. A method is presented for anionically polymerizing monomers comprising the step of polymerizing the monomers with a sulfur containing anionic initiator to provide a functional head group on the polymer. An elastomeric compound, comprising a functional polymer and filler is also described. Also provided is a tire having decreased rolling resistance resulting from a tire component containing a vulcanizable elastomeric compound.Type: GrantFiled: December 2, 2006Date of Patent: January 15, 2008Assignee: Bridgestone CorporationInventors: Terrence E. Hogan, William Hergenrother, Yuan-Yong Yan, David Lawson
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Patent number: 7241824Abstract: A sulphur-vulcanizable rubber composition usable for the manufacture of tires, based on at least: (A)—one diene elastomer selected from the group consisting of polybutadienes, natural rubber, synthetic polyisoprenes, butadiene copolymers, isoprene copolymers and mixtures of these elastomers (component A); (B)—a reinforcing white filler (component B); (C)—a coupling agent (white filler/diene elastomer) bearing at least one activated double ethylene bond (component C), with which there is associated: (D)—between 0.05 and 1 phr (parts by weight per hundred of elastomer) of a heat-triggered radical initiator (component D). The coupling agent is in particular an alkoxysilane of the family of alkoxy(C1–C4)-silylpropyls, in particular a trialkoxy(C1–C4)-silylpropyl methacrylate, in particular trimethoxy-silylpropyl methacrylate. Process for preparing such a rubber composition. Tire or semi-finished product, in particular tread, for a tire comprising a rubber composition according to the invention.Type: GrantFiled: June 24, 2002Date of Patent: July 10, 2007Assignee: Michelin Recherche et Technique S.A.Inventors: Jean-Luc Mangeret, Jean-Claude Tardivat
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Patent number: 7205360Abstract: A preparation process for a copolymer having two blocks usable in a sulphur-cross-linkable rubber composition of reduced hysteresis in the cross-linked state, such a block copolymer in which one of the blocks is a polyisoprene and the other a diene elastomer other than a polyisoprene, and this rubber composition for tire treads. A process for the preparation of this copolymer involves copolymerizing one or more monomers including a conjugated diene other than isoprene using a catalytic system including at least one hydrocarbon solvent, a compound A of a metal of group IIIA, a compound B of an alkaline-earth metal and a polymeric initiator C having a C—Li bond which is constituted of a monolithiated polyisoprene intended to form the polyisoprene block, the number-average molecular weight Mn1 of the polyisoprene block being between 2,500 and 20,000 g/mol.Type: GrantFiled: April 30, 2004Date of Patent: April 17, 2007Assignee: Michelin Recherche et Technique S.A.Inventors: Pierre Robert, Jean-Michel Favrot, Pierre Lesage
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Patent number: 7202295Abstract: A rubber composition usable for the manufacture of tires, based on at least one diene elastomer, a reinforcing inorganic filler and a coupling agent providing the bond between the inorganic filler and the elastomer, wherein said inorganic filler comprises a silicon carbide having the following characteristics: (a) a BET specific surface area of between 20 and 200 m2/g; (b) an average particle size (by mass), dW, of between 10 and 350 nm. Tires or semi-finished products for tires such as treads comprising said rubber composition.Type: GrantFiled: July 2, 2003Date of Patent: April 10, 2007Assignee: Michelin Recherche et Technique S.A.Inventors: Laure Simonot, Thierry Chartier, Emmanuel Custodero
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Patent number: 7199175Abstract: A tire tread comprising a rubber composition based on (phr: parts by weight per hundred parts of elastomer): (i) a diene elastomer; (ii) more than 50 phr of an inorganic filler as reinforcing filler; (iii) between 2 and 15 phr of an (inorganic filler/diene elastomer) coupling agent; (iv) between 1 and 10 phr of a methylene acceptor, and (v) between 0.5 and 5 phr of a methylene donor. This tread has, after mechanical running-in of the tire for which it is intended (“auto-accommodation”), a rigidity gradient which increases radially from the surface towards the inside of the tread. Use of such a tread for the manufacturing or recapping of tires. Tires comprising a tread according to the invention, in particular of the snow or ice type (“winter” tires).Type: GrantFiled: January 28, 2003Date of Patent: April 3, 2007Assignee: Michelin Recherche et Technique S.A.Inventor: Didier Vasseur
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Patent number: 7148303Abstract: The present invention relates to an elastomeric polymer having repeating units derived from at least one isomonoolefin monomer, at least one multiolefin monomer, at least one diisoalkenylbenzene monomer, and optionally further copolymerizable monomers, wherein the polymer has a Mooney viscosity (ML 1+8@125° C. according to ASTM D1646) of less than 40 units and a Shore A hardness higher than 65 points @ 23° C. (according to ASTM D2240) as well as a curable composition containing the elastomeric polymer and a shaped article manufactured from the curable composition.Type: GrantFiled: February 16, 2005Date of Patent: December 12, 2006Assignee: Lanxess Inc.Inventors: Adam Gronowski, Akhtar Osman
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Patent number: 7084201Abstract: A composition of matter and a solvent system for use in providing a water resistant coating to basement walls is disclosed. The solvent system comprises a chlorinated solvent blend. The solvent system and coating composition have no flash point, are non-flammable and provide an improved consistent coating when applied to walls.Type: GrantFiled: November 14, 2003Date of Patent: August 1, 2006Assignee: Wall-Guard Corporation of OhioInventors: Michael Garfield, Paul E. Marshall, Jr.
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Patent number: 6794428Abstract: A coupler is described for use in carbon black filled rubber compositions. The coupler includes an amine group and a thiol group or a polysulfidic linkage. The coupler improves the interaction of the carbon black with the rubber as measured by a decrease in the tan delta at 60° C. while substantially maintaining the tan delta at 0° C.Type: GrantFiled: October 29, 2002Date of Patent: September 21, 2004Assignee: The Lubrizol CorporationInventors: James D. Burrington, Benny R. Richardson, Joseph W. Pialet, Ann E. Wykoff, Roger L. Sowerby, Kenneth W. Lee, Ralph E. Kornbrekke, Ghebrehiwet N. Ghebremeskel, Kirk E. Davis
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Patent number: 6723764Abstract: A process for preparing an enlarged latex, which comprises (1) causing (a) an anionic surfactant and (b) at least one surfactant selected from the group consisting of a cationic surfactant and an amphoteric surfactant to exist in a latex, (2) adding, as an aggregating and enlarging agent, at least one selected from the group consisting of (i) an inorganic acid, (ii) an organic acid, (iii) a substance which forms an acid in water, (iv) a combination of at least two substances which are reacted with each other to form an acid, and (v) a substance which forms an acid by exposure to active rays to the latex in the presence of these surfactants, and (3) causing the acid derived from the aggregating and enlarging agent to act on the latex, thereby enlarging the particle diameter of the latex, an enlarged latex obtained by the preparation process, a graft copolymer obtained by polymerizing a polymerizable monomer with the enlarged latex, and a resin composition comprising the graft copolymer and a thermoplastic resiType: GrantFiled: May 30, 2002Date of Patent: April 20, 2004Assignee: Rohm and Haas CompanyInventor: Hiroshi Sakabe
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Patent number: 6696518Abstract: The present invention relates to a process for hydrogenating ethylenically unsaturated double bonds in polymers P by reacting an aqueous dispersion of at least one polymer P with hydrogen in the presence of at least one hydrogenation catalyst comprising at least one transition metal selected from rhodium and/or ruthenium and at least one nonionic phosphorus compound capable of forming a coordinative compound with the transition metal, which comprises incorporating the hydrogenation catalyst into the aqueous dispersion of the polymer P without adding a solvent. The present invention also relates to the aqueous dispersions of the hydrogenated polymers P obtainable by this process and to coating compositions comprising such dispersions.Type: GrantFiled: November 27, 2001Date of Patent: February 24, 2004Assignee: BASF AktiengesellschaftInventors: Rolf Dersch, Heiko Maas, Volker Schädler
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Patent number: 6369151Abstract: The present invention provides a rubber composition for tire tread having compatibility between low fuel consumption and abrasion resistance, especially abrasion resistance under severe condition. The rubber composition for tire tread is obtained by adding carbon black containing silica as 10 to 55 parts by weight based on a rubber component of 100 parts by weight and silica coupling agent of 2 to 8% by weight based on the carbon black containing silica.Type: GrantFiled: October 20, 1999Date of Patent: April 9, 2002Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Yoichi Mizuno, Mamoru Uchida
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Publication number: 20020010258Abstract: The present invention relates to the preparation of silica reinforced rubber compositions and to articles of manufacture which contain at least one component comprised thereof Such article of manufacture may be a tire. The silica reinforced rubber composition comprises at least one elastomer, silica, and an organo-metal additive of least one of organo-tin, organo-titanium, and/or organo-zirconium compound, preferably to an exclusion of additional additives to the rubber composition which will readily react with hydroxyl groups (e.g. silanol groups) on the surface of the silica to create an alcohol such as, for example, alkylsilane, alkoxysilane, and bis-(3-alkoxysilylalkyl) polysulfide compounds. Such organo-metal compound may have a valance of four and in the case of the organo-tin compound may have a valance of four or two, preferably four.Type: ApplicationFiled: April 19, 2001Publication date: January 24, 2002Inventors: Daniel Edward Bowen, Eric Sean Castner
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Patent number: 6316486Abstract: The present invention relates to new compounds of the formula (I) in which X represents halogen, Y represents halogen or alkyl and Z represents halogen or alkyl, with the proviso that always one of the radicals Y and Z represents halogen while the other represents alkyl, and Het represents one of the groups in which A, B, D and G have the meanings given in the description, to a plurality of processes for their preparation and to their use as pesticides and herbicides.Type: GrantFiled: October 31, 1997Date of Patent: November 13, 2001Assignee: Bayer AktiengesellschaftInventors: Folker Lieb, Hermann Hagemann, Arno Widdig, Michael Ruther, Reiner Fischer, Thomas Bretschneider, Christoph Erdelen, Ulrike Wachendorff-Neumann, Peter Dahmen, Markus Dollinger, Hans-Joachim Santel, Alan Graff, Wolfram Andersch, Norbert Mencke, Andreas Turberg
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Patent number: 6313205Abstract: The invention concerns a rubber sulfur-vulcanizable composition designed for manufacturing tire treads, comprising at least a diene elastomer, a white filler as reinforcing filler and as coupling agent (white filler/elastomer) a multifunctionalized polyorganosiloxane comprising per molecule: a) at least a first siloxyl unit bearing, on the silicon atom, at least one linear or branched C1-C15 alkoxyl radical; and b) at least a second siloxyl unit bearing, on the silicon atom, at least one radical of general formula Z—SH, Z being a linear or branched divalent hydracarbon, comprising preferebly 2 to 30 carbons.Type: GrantFiled: January 10, 2000Date of Patent: November 6, 2001Assignee: Compagnie Generale des Etablissements Michelin-Michelin & CieInventors: Frédéric Chiron, Claude Laforet, Jean-Luc Mangeret
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Patent number: 6197875Abstract: A particulate silica which has been treated with a polymer oil jelly.Type: GrantFiled: March 19, 1999Date of Patent: March 6, 2001Assignee: Rhodia LimitedInventors: Ian Malcolm Mackinnon, Douglas Martin Butcher
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Patent number: 6020441Abstract: Polymers containing ethylenically unsaturated double bonds are hydroformylated by reacting aqueous dispersions of the polymers with hydrogen and carbon monoxide in the presence of suitable hydroformylation catalysts.Also provided are the polymer dispersions obtainable by this process and the hydroformylated polymers themselves.Type: GrantFiled: May 12, 1997Date of Patent: February 1, 2000Assignee: BASF AktiengesellschaftInventors: Edgar Zeller, Hartmann F. Leube, Bernhard Schlarb, Heinz-Josef Kneuper, Michael Roper
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Patent number: 6004677Abstract: There is provided a process for producing polydienes, such as polybutadiene and polyisoprene, in a gas phase fluidized bed reactor using a pre-activated nickel catalyst which is highly active for cost effective production of these dienes in gas phase.Type: GrantFiled: August 8, 1997Date of Patent: December 21, 1999Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Kevin Joseph Cann, Maria Angelica Apecetche, Minghui Zhang
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Patent number: 5859120Abstract: Carbon blacks containing silicon and a process for manufacturing them. The carbon blacks containing silicon are suitable as reinforcing carbon blacks for rubber mixtures and give the latter viscoelastic properties such as reduced rolling resistance in tires. At the same time, the wet traction is even improved in the process.Type: GrantFiled: March 25, 1997Date of Patent: January 12, 1999Assignee: Degussa AktiengesellschaftInventors: Alfons Karl, Burkhard Freund, Karl Vogel