Conjugated Diene Hydrocarbon Monomer Patents (Class 524/571)
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Patent number: 11680157Abstract: A tire composition is disclosed. The composition comprises a rubber component and based on 100 parts by weight (phr) of the rubber component, 50-200 phr of covered silica, with the covered silica comprising silica core and a first resin covering the silica core, wherein the first resin is not chemically bonded to the silica core. The silica core is covered with the first resin by mixing a slurry comprising silica core with a mixture containing the first resin as a solution, an aqueous dispersion; or a solution by dissolving the first resin in a solvent.Type: GrantFiled: September 24, 2020Date of Patent: June 20, 2023Assignee: Kraton CorporationInventors: Jeremie Pichereau, Wolfgang Pille-Wolf, Joshua Guilliams
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Patent number: 11492426Abstract: A functionalized elastomer comprising the reaction product of a living elastomeric polymer and a polymerization terminator of formula I [R1]n—B—[X—R2]m??I where B is boron; X is oxygen or nitrogen; R1 is independently vinyl, oxiranyl, phenyl, 1-alkenyl of 2 to 8 carbon atoms, alkyl of 1 to 8 carbon atoms including at least one halogen atom, 1-alkenyl of 2 to 8 carbon atoms including at least one halogen or one hydrogen; R2 is independently C1 to C8 alkyl, C8 to C14 aryl; or when m>1 R2 may be taken together to form a substituted or unsubstituted cyclic structure comprising 2 to 16 carbon atoms where the cyclic structure may be heterocyclic or non-heterocyclic; n is 1 or 2, m is 1 or 2, and n+m=3.Type: GrantFiled: August 7, 2020Date of Patent: November 8, 2022Assignee: The Goodyear Tire & Rubber CompanyInventors: Seth Cody Ensign, Robert Alan Woloszynek
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Patent number: 11124589Abstract: The cis-1,4 mer content of conjugated diene mer in polymers can be increased by adding any of a class of morpholine compounds to a catalyst composition that includes a lanthanide metal atom.Type: GrantFiled: October 10, 2015Date of Patent: September 21, 2021Assignee: Bridgestone CorporationInventors: Zengquan Qin, James H. Pawlow, Christine M. Rademacher
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Patent number: 11020915Abstract: A sealing compound comprising an inventive extended sealing gel, a process for producing this sealing compound, the use of sealing gels in sealing compounds, and the use of sealing gel-containing sealing compounds in tyresType: GrantFiled: January 25, 2018Date of Patent: June 1, 2021Assignee: ARLANXEO DEUTSCHLAND GMBHInventors: Jiawen Zhou, Thomas Früh, Torsten Thust
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Patent number: 10971707Abstract: A method for producing a laminated all-solid-state battery 100, including: housing an all-solid-state battery laminate 15, having one or more all-solid-state unit cells, in a casing 20 composed of a laminated film 21, the one or more all-solid-state unit cells obtained by laminating a negative electrode current collector layer having a negative electrode current collector tab 1a, a negative electrode active material layer, a solid electrolyte layer, a positive electrode active material layer and a positive electrode current collector layer having a positive electrode current collector tab 5a in this order, pressing the all-solid-state battery laminate 15 housed in the casing 20 in the direction of lamination from outside the casing 20, injecting a filler into the casing 20 while maintaining pressure, and sealing the casing 20.Type: GrantFiled: January 12, 2018Date of Patent: April 6, 2021Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventor: Kazuhito Kato
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Patent number: 10961374Abstract: A rubber composition based on at least an elastomer matrix is provided. The elastomer matrix comprises a first diene elastomer having a number-average molecular weight, Mn, of greater than or equal to 100 000 g/mol; a functionalized second diene elastomer bearing at the chain end a function capable of reacting with the surface of silica, said functionalized diene elastomer having a number-average molecular weight, Mn, of less than or equal to 80 000 g/mol: and a reinforcing inorganic filler, in an amount ranging from 55 phr to 200 phr. The elastomeric matrix allows good dispersion of the reinforcing inorganic filler. A finished or semi-finished article comprising such a composition, tire tread comprising such a composition, and a tire or semi-finished product comprising such a composition is also provided.Type: GrantFiled: December 21, 2017Date of Patent: March 30, 2021Assignee: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: Séverin Dronet, Laurent Petitjean, Marc Couty, Corentin Pavageau
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Patent number: 10934382Abstract: The present invention provides a conjugated diene polymer, formulations, and manufacturing methods for the same. The present invention provides a conjugated diene polymer obtained by polymerizing conjugated diene monomers and vinyl aromatic monomers using an initiator by way of an anionic polymerization, the conjugated diene polymer comprising a plurality of blocks having more than 6 consecutive vinyl aromatic units, wherein a vinyl aromatic monomer content of the plurality of blocks having more than 6 consecutive vinyl aromatic units is less than 5 wt % based on a total vinyl aromatic monomer content of the conjugated diene polymer. The present invention also provides formulations for preparing the conjugated diene polymer and the manufacturing methods for the same.Type: GrantFiled: October 8, 2018Date of Patent: March 2, 2021Assignee: TSRC CorporationInventors: Juin-Meng Yu, Chin-Wei Chiou, Kun-Yi Chen, Adel Farhan Halasa
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Patent number: 10793703Abstract: The present invention provides a tire which has at least one member selected from the group consisting of a side reinforcing rubber layer and a bead filler made of a vulcanized rubber composition comprising a natural rubber as a rubber component and having a difference between a dynamic tensile storage modulus E? at 180° C. (A) and a dynamic tensile storage modulus E? at 25° C. (B) {E?(A)?E?(B)} of 2.0 MPa or more, the dynamic tensile storage moduli being measured under conditions of an initial tensile strain of 5%, a dynamic tensile strain of 1%, and a frequency of 52 Hz, and provides the tire excellent in achieving both the riding comfort in normal running and the durability in Run-flat running.Type: GrantFiled: December 10, 2018Date of Patent: October 6, 2020Assignee: BRIDGESTONE CORPORATIONInventors: Motoki Amiya, Chiyo Miyamoto
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Patent number: 10562780Abstract: The present invention relates to methods for removing carbon from a char product that is formed by heating a silica-containing rubber compound in an inert atmosphere or under vacuum. The method includes heating the char product in an oxidising atmosphere to remove the carbon material leaving a silica-containing product. The methods are particularly applicable to vehicle tyre rubber compositions. Silica-containing products obtained by these methods and rubber compositions incorporating such silica-containing products are also aspects of the invention.Type: GrantFiled: April 13, 2015Date of Patent: February 18, 2020Assignee: Avon Polymer Products LTDInventors: Christopher Norris, Martyn Bennett
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Patent number: 10233312Abstract: A modified diene elastomer comprises: at least 55% by weight of entity coupled by a functional group bearing a function of formula —SiOR, in which R is a hydrogen atom or an alkyl radical, and optionally bearing another function capable of interacting with a reinforcing filler, from 5% by weight to 30% by weight of star-branched entity having three elastomeric branches connected to one and the same silicon atom belonging to a functional group bearing or not bearing a function capable of interacting with a reinforcing filler, less than or equal to 15% by weight of entity functionalized at the chain end by a functional group bearing a function —Si(OR)2, in which R is a hydrogen atom or an alkyl radical, and optionally bearing another function capable of interacting with a reinforcing filler, and a content of less than or equal to 15% by weight of non-functional diene elastomer.Type: GrantFiled: July 31, 2014Date of Patent: March 19, 2019Assignees: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE, S.A.Inventors: Charlotte Dire, Jean-Marc Marechal, Margarita Dorato, Mathieu Manceau, Nuno Pacheco
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Patent number: 10207540Abstract: A tire tread formed at least in part from a rubber composition that is based upon a cross-linkable rubber composition that may include between 50 phr and 90 phr of a first highly unsaturated elastomer being middle chain functionalized with an aminoalkoxysilane group and having a Tg of between ?108° C. and ?45° C. and between 10 phr and 50 phr of a second highly unsaturated elastomer being end-chain functionalized with a silanol group and having a Tg of between ?108° C. and ?10° C. The rubber composition may further include between 50 phr and 150 phr of a silica filler and a plasticizing system comprising between 5 phr and 120 phr of a plasticizing resin having a Tg of at least 25° C. and between 0 phr and 60 phr of a plasticizing liquid.Type: GrantFiled: October 27, 2014Date of Patent: February 19, 2019Assignee: Compagnie Generale des Etablissements MichelinInventors: Anthony Derbin Cato, Raymond Stubblefield, Xavier Saintigny, Olivier Piffard
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Patent number: 10004666Abstract: The present invention is directed to a dental composition, and specifically to an improved composition for endodontic instruments useful for filling root canals or sealing.Type: GrantFiled: May 2, 2014Date of Patent: June 26, 2018Assignee: DENTSPLY SIRONA Inc.Inventors: Todd Berger, Kevin Wilkinson, Adam Barantz, Dan Ammon, Xiaoming Jin, Bernard Koltisko
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Patent number: 9932460Abstract: The present invention provides a rubber composition that can enhance the fuel economy, wet-grip performance, and abrasion resistance in a balanced manner, and a pneumatic tire using this rubber composition. The present invention relates to a rubber composition that contains a rubber component, silica, and a liquid resin having a softening point of ?20 to 20° C., wherein the rubber component contains, based on 100% by mass of the rubber component, not less than 5% by mass of a conjugated diene polymer containing a constituent unit based on a conjugated diene and a constituent unit represented by formula (I) below, at least one terminal of the polymer being modified with a specific compound; and an amount of the silica is 5 to 150 parts by mass per 100 parts by mass of the rubber component.Type: GrantFiled: April 20, 2012Date of Patent: April 3, 2018Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.Inventors: Isamu Tsumori, Kenichi Uesaka, Naoya Omura, Tetsuya Kunisawa, Tatsuhiro Tanaka, Kazuyuki Nishioka
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Patent number: 9845384Abstract: A rubber compound for tyres comprising a cross-linkable unsaturated chain polymer base comprising, in turn, at least a rubber of synthetic origin, a silica-free filler at least partially comprising carbon black, a vulcanization system and a mercapto carboxylic acid.Type: GrantFiled: December 19, 2014Date of Patent: December 19, 2017Assignee: BRIDGESTONE CORPORATIONInventors: Giancarlo Cossu, Gianluca Forte
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Patent number: 9758651Abstract: There is disclosed a vulcanizable rubber composition comprising: (A) a diene based elastomer, (B) from 50 to 150 parts by weight, per 100 parts by weight of elastomer (phr), of silica; (C) from 0.15 to 0.45 phr of a polymeric amine comprising a primary amine functionality; and (D) from 1.5 to 2.5 parts by weight, per 1 part by weight of the polymeric amine, of an aromatic carboxylic acid or aromatic acid anhydride.Type: GrantFiled: August 5, 2014Date of Patent: September 12, 2017Assignee: The Goodyear Tire & Rubber CompanyInventor: Ling Du
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Patent number: 9692015Abstract: An organic light emitting device having a photonic crystal structure and a manufacturing method thereof are provided. The organic light emitting device comprises: a substrate through which light passes; a photonic crystal layer formed on the substrate and having a photonic crystal structure; an intermediate layer formed on the photonic crystal layer and having a large refractive index compared with the photonic crystal layer; a first electrode layer formed on the intermediate layer; a light emitting layer formed on the first electrode layer and emitting light according to current flow; and a second electrode layer formed on the light emitting layer.Type: GrantFiled: January 3, 2012Date of Patent: June 27, 2017Assignee: KOREA INSTITUTE OF MACHINERY & MATERIALSInventors: Jong-Youp Shim, Jun-Ho Jeong, Ki-Don Kim, Dae-Geun Choi, Jun-Hyuk Choi, Eung-Sug Lee, So-Hee Jeon, Jae-R. Youn, Jang-Joo Kim
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Patent number: 9683088Abstract: A process for regenerating sulfur-crosslinked rubber vulcanizates to regenerates, wherein at least one regenerating agent is used in the regeneration. The regenerating agent is selected from the group consisting of dithiophosphoryl polysulfides and/or silanes having a polysulfane group. Regenerates which have been produced by means of the process lead to improved or equal rolling resistance indicators and a lower compression set in vulcanized rubber mixtures compared to regenerates known in the prior art.Type: GrantFiled: March 2, 2015Date of Patent: June 20, 2017Assignee: Continental Reifen Deutschland GmbHInventors: Carla Recker, Lena Mueller, Thomas Voelker
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Patent number: 9475917Abstract: A rubber composition and a method for manufacturing the same are provided. The rubber composition includes a main chain modified conjugated diene based polymer and a stabilizer. A weight ratio of the main chain modified conjugated diene based polymer to the stabilizer is 100:0.2˜2.Type: GrantFiled: December 24, 2013Date of Patent: October 25, 2016Assignee: CHI MEI CORPORATIONInventors: Kuei-Lun Cheng, Kuan-Lin Hsieh, Chih-Cheng Lee
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Patent number: 9428596Abstract: A method of production of modified conjugated diene-based rubber comprising a steps of using, as a polymerization initiator, an alkali metalated aromatic compound which has three or more carbon atoms which are directly bonded to alkali metal atoms and aromatic rings in one molecule so as to polymerize a monomer which contains at least a conjugated diene compound and reacting a compound of the following general formula (I) with an active ends of the obtained polymer is provided. (In the general formula (I), any one of R1 and R10 to R18 is an atom or reactive group which can react with the active ends of said polymer or a hydrocarbon group which includes either of the same, the remaining among R1 and R10 to R18 and R2 to R9 are respectively independently a hydrogen atom, alkyl group, or aryl group, and “j”, “k”, “m”, and “n” are integers of 0 to 100.Type: GrantFiled: December 27, 2012Date of Patent: August 30, 2016Assignee: ZEON CORPORATIONInventors: Takeshi Sugimura, Kazuya Ito
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Patent number: 9402391Abstract: The present invention relates to stable, agricultural oil-in-water emulsion compositions.Type: GrantFiled: March 9, 2009Date of Patent: August 2, 2016Assignee: Dow AgroSciences LLCInventors: Wen Xu, Holger Tank
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Patent number: 9139719Abstract: The present invention provides a rubber composition that achieves a well-balanced improvement in fuel economy, wet-grip performance, and abrasion resistance, and a pneumatic tire formed from the rubber composition. The present invention relates to a rubber composition, including a rubber component and silica, wherein the rubber component contains not less than 5% by mass of a conjugated diene polymer, based on 100% by mass of the rubber component, the conjugated diene polymer containing a constituent unit derived from a conjugated diene and a constituent unit represented by the following formula (I): at least one terminal of the conjugated diene polymer being modified by a compound containing a group represented by the following formula (II): and wherein the silica is contained in an amount of 5 to 150 parts by mass per 100 parts by mass of the rubber component.Type: GrantFiled: July 22, 2011Date of Patent: September 22, 2015Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.Inventors: Yuko Hinohara, Kazuyuki Nishioka, Takahiro Mabuchi
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Patent number: 9034980Abstract: A pneumatic tire for a commercial vehicle with a tread, wherein at least the part of the tread which comes into contact with the road contains a sulphur-vulcanized rubber mixture. The sulphur-vulcanized rubber mixture contains 90 to 50 phr (parts by weight, based on 100 parts by weight, of all of the rubbers in the mixture) of natural rubber, 10 to 50 phr of at least one polybutadiene having a glass transition temperature Tg of ?110 to ?65° C. and 5 to 50 phr of at least one aliphatic and/or aromatic hydrocarbon resin having a softening point (ring and ball to ASTM E 28) of 0 to 150° C., and a mean molecular weight Mn of less than 2000 g/mol and a polydispersity D=Mw/Mn of 1 to 5.Type: GrantFiled: April 22, 2013Date of Patent: May 19, 2015Assignee: Continental Reifen Deutschland GmbHInventors: Carla Recker, Philipp Koelle, Thomas Kramer, Christoph Jocher, Thorsten Torbruegge, Fabian Dettmer, Norbert Daldrup
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Patent number: 9034950Abstract: The purpose of the present invention is to provide a rubber composition with which it is possible to produce a tire that retains wear resistance and has excellent frictional force on ice, and a pneumatic tire using the rubber composition. The rubber composition of the present invention is a rubber composition comprising a diene rubber, carbon black and/or a white filler, and a master batch prepared by premixing a non-diene rubber and an organic peroxide, wherein a total content of carbon black and white filler is from 20 to 70 parts by mass per 100 parts by mass of diene rubber and a content of the non-diene rubber in the master batch is from 3 to 30 parts by mass per 100 parts by mass of the diene rubber.Type: GrantFiled: August 19, 2011Date of Patent: May 19, 2015Assignee: The Yokohama Rubber Co., Ltd.Inventors: Satoshi Mihara, Katsunori Shimizu, Keisuke Maejima, Yayoi Akahori
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Patent number: 9022087Abstract: A rubber composition for tire treads is obtained by blending, per 100 parts by mass of a diene rubber, 5 to 150 parts by mass of silica and 0.5 to 20 parts by mass of a silicone oligomer represented by the following siloxane average formula (1): (X)a(Y)b(R1)c(R2)dSiO(4-a-b-c-d)/2 (wherein X is a mercapto group-containing organic group; Y is a hydrolyzable group, R1 is a monovalent hydrocarbon group having from 4 to 10 carbon atoms, R2 is a monovalent hydrocarbon group having from 1 to 3 carbon atoms, 0<a<1, 0<b<3, 0<c<2, 0?d<2, and 0<a+b+c+d<4). The diene rubber contains an aromatic vinyl-conjugated diene copolymer in an amount of at least 50 parts by mass per 100 parts by mass of the diene rubber, the aromatic vinyl-conjugated diene copolymer having an aromatic vinyl content of 20 to 45 mass % and a vinyl bond content in the conjugated diene of 10 to 50%.Type: GrantFiled: August 6, 2012Date of Patent: May 5, 2015Assignee: The Yokohama Rubber Co., Ltd.Inventor: Naoki Kushida
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Patent number: 9010393Abstract: Tyre and rubber composition for tyre, based on at least one isoprene elastomer (for example natural rubber), an inorganic filler as reinforcing filler (for example silica) and a coupling system which provides the bonding between the said reinforcing inorganic filler and the isoprene elastomer, the said coupling system comprising, in combination: as first coupling agent, a silane sulphide compound; as second coupling agent, an at least bifunctional organosilicon compound (for example an organosilane or an organosiloxane) which can be grafted to the elastomer by means of an azodicarbonyl functional group (—CO—N?N—CO—).Type: GrantFiled: May 11, 2006Date of Patent: April 21, 2015Assignee: Michelin Recherche et Technique, S.A.Inventors: Jose Carlos Araujo Da Silva, Nathalie Binde, Pierre Robert, Sebastien Sterin, Anne Veyland
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Patent number: 9006310Abstract: A method includes: mixing a polymer cement and a filler to form a solution masterbatch; optionally drying the solution masterbatch to form a crumb polymer composition; mixing a low viscosity polymeric or oligomeric liquid into the solution masterbatch or crumb polymer composition; and intermeshing mixing the solution masterbatch or crumb polymer composition.Type: GrantFiled: December 28, 2012Date of Patent: April 14, 2015Assignee: Bridgestone CorporationInventors: Mark W. Smale, Zhong-Ren Chen
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Patent number: 9000088Abstract: This invention relates to hydrolysable silanes useful in the modification of elastomers, and as coupling agents for diene elastomer compositions containing a filler. In particular the invention relates to novel hydrolysable silanes containing a piperazine ring and an ether or thioether linkage.Type: GrantFiled: December 7, 2012Date of Patent: April 7, 2015Assignee: Dow Corning CorporationInventors: Michael Wolfgang Backer, Thomas Chaussee, Damien Deheunynck, Sebastien Grofils
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Patent number: 8993675Abstract: An alkali metal-reacted aromatic compound which has three or more carbon atoms which are directly bonded to alkali metal atoms and aromatic rings in one molecule is used as a polymerization initiator to polymerize a monomer mixture which is contains at least one conjugated diene compound to thereby produce a radial conjugated diene polymer. Further, active ends of the polymer having active ends which is obtained by this method is made to react with a modifier which can react with the active ends to thereby produce an end-modified radial conjugated diene polymer. According to the present invention, it is possible to provide a method of production of the radial conjugated diene polymer which gives a high degree of freedom of polymer design and easy control of the polymer structure.Type: GrantFiled: May 11, 2010Date of Patent: March 31, 2015Assignee: Zeon CorporationInventors: Shigetaka Hayano, Takeshi Sugimura, Yasuhisa Tsukahara
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Patent number: 8993683Abstract: A method for preparing a functionalized polymer, the method comprising the steps, of: (i) polymerizing monomers to form a reactive polymer, and (ii) reacting the reactive polymer with a lactone or thiolactone that contains a protected amino group.Type: GrantFiled: August 31, 2012Date of Patent: March 31, 2015Assignee: Bridgestone CorporationInventors: Steven Luo, Zengquan Qin
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Publication number: 20150080526Abstract: A process for the preparation of branched polybutadiene having a high content of 1,4-cis units which comprises polymerizing butadiene in the presence of at least one organic solvent, and in the presence of: a) a catalytic system prepared in situ including: (a1) at least one neodymium carboxylate, (a2) at least one alkyl compound of aluminum, (A3) at least one alkyl compound of aluminum containing at least one halogen atom, and b) at least one organic ester containing at least one halogen atom. Said branched polybutadiene having a high content of 1,4-cis units, depending on the branching degree and molecular weight distribution, can be advantageously used in various applications ranging from the modification of plastic materials [production, for example, of high impact polystyrene (HIPS)] to the production of tyres, in particular the production of treads and/or of sidewalls of tyres.Type: ApplicationFiled: April 24, 2013Publication date: March 19, 2015Inventors: Andrea Vallieri, Marianna Zinna, Costantino Perretta
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Publication number: 20150080525Abstract: Provided is a rubber composition including a rubber component. The rubber component contains at least a polymer that is a synthesized polyisoprene or an isoprene copolymer and that has 20% or less gel fraction.Type: ApplicationFiled: March 6, 2013Publication date: March 19, 2015Applicant: BRIDGESTONE CORPORATIONInventors: Junko Matsushita, Shojiro Kaita, Satoru Tamaki
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Patent number: 8981000Abstract: A polymer has at least the following characteristics: (a) a block styrene content containing 4 to 6 styrene units from about 27 to about 50 weight percent based on total styrene content in the polymer; (b) a vinyl content from about 30 to about 80 weight percent based on total amount of polymerized 1,3-butadiene; and (c) a styrene content from about 40 to about 70 weight percent based on total weight of polymer. Processes for the polymerization of such a polymer, compositions containing such a polymer, and articles containing at least one component formed from such a composition are described.Type: GrantFiled: March 1, 2012Date of Patent: March 17, 2015Assignee: Styron Europe GmbHInventors: Evemarie Hamann, Silvia Valenti, Karin Schmiedel
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Patent number: 8978721Abstract: A heat-expandable rubber layer is provided to an inner all of a pneumatic tire when the tire is in an uncured state. The rubber layer is expanded when the tire is in a vulcanized state. Once expanded, the rubber layer is capable of reducing rolling noises of the tire. The rubber layer includes an elastomer composition based on at least an elastomer, e.g., natural rubber or butyl rubber; a reinforcing filler, e.g., silica and/or carbon black; between 10 and 80 phr of a blowing agent, e.g., an azodicarbonamide compound; and between 10 and 50 phr of a hot-melt compound with a melting point between 70° C. and 150° C., e.g., urea. The combination of the blowing agent and the hot-melt compound, at recommended high contents, makes it possible to very greatly reduce an expansion ratio and therefore a thickness of the rubber layer once the pneumatic tire is vulcanized, without affecting noise absorption properties provided by the blowing agent.Type: GrantFiled: October 25, 2010Date of Patent: March 17, 2015Assignees: Compagnie Generale des Etablissements Michelin, Michelin Recherche et Technique S.A.Inventors: Mitsue Tanaka, Salvatore Pagano
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Patent number: 8980392Abstract: The use of a functionalized organosilicon compound as a coupling agent between an inorganic filler and an elastomer in an elastomer composition including an isoprene elastomer and a reinforcing inorganic filler is disclosed. The compound is selected among functionalized organosilicon compounds including at least one double bond C?C or C?N, and not including any C?C—C?O bonds or N?N bonds, and reacting with the isoprene units according to an electrocyclic reaction, in particular according to a standard cycloaddition reaction [2+1], [2+2], [3+2] or a Diels-Alder reaction [4+2] or an ene-synthesis reaction other than an ene-synthesis reaction between an isoprene unit and a C?C—C?O or N?N function. Also described, are elastomer composition(s) obtained and items manufactured using such compositions.Type: GrantFiled: June 2, 2010Date of Patent: March 17, 2015Assignee: Rhodia OperationsInventors: Laurent Guy, Virginie Pevere, Thierry Vidal
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Patent number: 8980982Abstract: A plastic packaging component is provided that is formed of a resin containing an electromagnetic spectrally detectable additive mixed with the resin. The resin formed into a plastic packaging component of an aerosol package lid, an aerosol spray button, an aerosol spray tube, a trigger sprayer, an integrated lid-sprayer, a grease cartridge, a grease cap, plastic fiber toweling, a packaging strap, a pail lid, a jar cap, or a brush. A process for detecting a displaced packaging component in an organic production stream is provided that includes adding to a resin an electromagnetically detectable additive intermixed with the resin and forming the additive loaded resin into the plastic packaging component. The production stream is then scanned for the detectable signal of the additive. Upon detecting the additive, an alarm signal is provided that the production stream contains the displaced packaging component.Type: GrantFiled: February 14, 2012Date of Patent: March 17, 2015Assignee: Illinois Tool Works, Inc.Inventors: Robert H. Martin, William A. Price, II, John Gregory Bruce, Darylnn Phillips Jordan, Craig Martin Stearns
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Publication number: 20150059606Abstract: An object of the present invention is to provide a relief printing plate precursor for laser engraving that is excellent in rinsing properties for engraving residue and engraving sensitivity and can give a sharp engraved shape. Disclosed is a relief printing plate precursor for laser engraving comprising a relief-forming layer formed of a resin composition for laser engraving, or a crosslinked relief-forming layer obtained by crosslinking the relief-forming layer formed of the resin composition for laser engraving, wherein the resin composition for laser engraving comprises a binder polymer as Component A, and carbon black of which pH is higher than 6 and an average particle size when being dispersed into water is equal to or less than 500 nm as Component B.Type: ApplicationFiled: August 28, 2014Publication date: March 5, 2015Applicant: FUJIFILM CORPORATIONInventor: Yuichi YASUHARA
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Patent number: 8962744Abstract: The present invention provides a random copolymer that is used for manufacturing a tire having excellent rollability and wear resistance and that includes randomly arranged monomer units of a conjugated diene compound and of a non-conjugated olefin, a rubber composition containing the random copolymer, a cross-linked rubber composition obtained by crosslinking the rubber composition, and a tire manufactured by using the rubber composition or the cross-linked rubber composition. A copolymer of a conjugated diene compound and a non-conjugated olefin, including a random copolymer having randomly arranged monomer units of the conjugated diene compound and of the non-conjugated olefin, and containing, by more than 30 mol %, a unit derived from the conjugated diene compound.Type: GrantFiled: February 2, 2012Date of Patent: February 24, 2015Assignee: Bridgestone CorporationInventors: Yasuo Horikawa, Shojiro Kaita, Olivier Tardif, Junko Matsushita
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Patent number: 8962743Abstract: The present invention provides a copolymer of a conjugated diene compound and a non-conjugated olefin, in which the conjugated diene unit has cis-1,4 bonds and the non-conjugated olefin contains many ethylene structures. In a copolymer of a conjugated diene compound and an unconjugated olefin other than the conjugated diene compound, the conjugated diene unit has a cis-1,4 bond content of 50% or more and the unconjugated olefin is contained in an amount of 20 mol % or more.Type: GrantFiled: July 27, 2011Date of Patent: February 24, 2015Assignee: Bridgestone CorporationInventors: Shojiro Kaita, Olivier Tardif, Yasuo Horikawa, Hideki Kitano
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Patent number: 8952101Abstract: For a tire excellent in strength, low-heat buildup property, wet grip property, and driveability, and a rubber composition and a conjugated diene rubber for the tire, a conjugated diene rubber of the present invention includes 5 wt % or more of a structure that 3 or more conjugated diene polymer chains are bound via a denaturing agent, obtained by reaction of each chain and the agent, each chain being that at least one of terminals is an isoprene block having 70 wt % or more of an isoprene monomer unit, and the other is an active terminal, the agent having, per molecule, at least one of an epoxy group(s) and a hydrocarbyloxysilyl group(s), and being that a total number of the epoxy group(s) and hydrocarbyloxy groups in the hydrocarbyloxysilyl group(s) per molecule is 3 or more.Type: GrantFiled: February 22, 2011Date of Patent: February 10, 2015Assignee: Zeon CorporationInventors: Tatsuo Sasajima, Takeshi Karato, Takeshi Sugimura
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Publication number: 20150018481Abstract: The invention relates to preparation of rubber reinforced with at least one of graphene and carbon nanotubes with specialized coupling agent and tire with component thereof.Type: ApplicationFiled: July 15, 2013Publication date: January 15, 2015Applicant: The Goodyear Tire & Rubber CompanyInventors: Ralf Mruk, Annette Lechtenboehmer, Klaus Unseld, Claude Ernest Felix Boes, Frederic Gerard Auguste Siffer, Ling Du, Robert Fokko Roskamp, Leena Nebhani
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Publication number: 20150011701Abstract: The polymer of the present invention is a synthesized polyisoprene or an isoprene copolymer. The polymer has a number average molecular weight (Mn) of 1.5 million or more when measured by using gel permeation chromatography (GPC).Type: ApplicationFiled: March 6, 2013Publication date: January 8, 2015Applicant: BRIDGESTONE CORPORATIONInventors: Junko Matsushita, Shojiro Kaita, Satoru Tamaki
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Patent number: 8927644Abstract: A polymer having at least the following characteristics: (a) a block styrene content with more than 4 consecutive styrene units from about 40 to about 70 weight percent based on total styrene content in the polymer; (b) a vinyl content from about 25 to about 80 weight percent based on total amount of polymerized 1,3-diene; (c) a styrene content from about 20 to about 75 weight percent based on total weight of polymer; and (d) a molecular weight distribution (Mw/Mn) of 1.5 or less.Type: GrantFiled: June 22, 2012Date of Patent: January 6, 2015Assignee: Styron Europe GmbHInventors: Evemarie Hamann, Silvia Valenti, Gabriele Holtz
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Patent number: 8921468Abstract: A rubber composition for a tire includes a rubber component containing at least one of a natural rubber and an epoxidized natural rubber, silica and a natural based wax, wherein the silica is contained in an amount of 10 parts by mass or more based on 100 parts by mass of the rubber component and the natural based wax is contained in an amount of 1.2% by mass or more and 2% by mass or less based on the total mass of the rubber composition for a tire, and to a tread, a side wall, a clinch and a tire using the rubber composition.Type: GrantFiled: March 14, 2008Date of Patent: December 30, 2014Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Tomoaki Hirayama, Takao Wada, Noboru Wakabayashi, Keiji Ikeda
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Publication number: 20140371385Abstract: The present invention relates to a method for recycling scrap rubber comprising the steps of pyrolyzing scrap rubber to obtain a char material and milling the thus obtained char material. The present invention also relates to carbon black powders and carbon black pellets obtained by the method according to the invention. Moreover, the present invention relates to the use of said carbon black powder and to compositions comprising said carbon black powders.Type: ApplicationFiled: December 21, 2012Publication date: December 18, 2014Inventors: Arnoldus Henricus Adrianus Verberne, Jan Anne Jonkman, Christopher Michael Twigg
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Publication number: 20140350173Abstract: The present invention provides a method for producing a rubber composition provided by compounding a rubber component (A) comprising at least one selected from natural rubbers and synthetic diene rubbers, a filler containing an inorganic filler (B), a silane coupling agent (C), and at least one vulcanization accelerator (D) selected from specific compounds, wherein the rubber composition is kneaded in a plurality of stages and wherein, in the first stage (X) of kneading, a portion (A?) of the rubber component (A), all or a portion of the inorganic filler (B), all or a portion of the silane coupling agent (C), and all or a portion of the vulcanization accelerator (D) are added and kneaded, and in or after the second stage of kneading, the residual portion (A?) of the rubber component (A) is added and kneaded, and the method for producing a rubber composition enables production of a rubber composition capable of suitably having a low-heat-generation property by further improving the coupling function activity oType: ApplicationFiled: December 21, 2012Publication date: November 27, 2014Applicant: BRIDGESTONE CORPORATIONInventor: Shigeaki Matsuo
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Publication number: 20140350174Abstract: The present invention relates to a method for producing a rubber composition obtained by compounding a rubber component (A) containing at least one kind selected from natural rubber and synthetic diene rubber, a filler containing an inorganic filler (B), a silane coupling agent (C), and thiourea, the method comprising kneading the rubber composition in plural stages, the rubber component (A), the whole or a part of the inorganic filler (B), the whole or a part of the silane coupling agent (C), and the thiourea being kneaded in the first stage of kneading, and thus provides a method for producing a rubber composition excellent in low-heat-generation property through enhancement of the reactivity between the coupling agent and the rubber component.Type: ApplicationFiled: December 21, 2012Publication date: November 27, 2014Applicant: BRIDGESTONE CORPORATIONInventors: Noriaki Yukimura, Satoshi Horie, Takumi Toda
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Patent number: 8877831Abstract: Methods and compositions are provided that relate to weighted elastomers. The weighted elastomers may comprise an elastomer and a weighting agent attached to an outer surface of the elastomer. An embodiment includes a method of cementing that comprises providing a cement composition containing cement, water, and a weighted elastomer. In addition, the cement composition may be introduced into a subterranean formation and allowed to set therein.Type: GrantFiled: March 12, 2012Date of Patent: November 4, 2014Assignee: Halliburton Energy Services, Inc.Inventors: Craig W. Roddy, Jeffery D. Karcher, Rickey L. Morgan, D. Chad Brenneis
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Publication number: 20140308488Abstract: A composition containing adhesive agent including an adhesive agent component used for manufacturing a recorded material in which a face opposing to an image forming face of a recording medium, which has an image formed by an inkjet method, is bonded, includes polyisoprene as the adhesive agent component. At least a part of the polyisoprene is included in a state of particles.Type: ApplicationFiled: March 31, 2014Publication date: October 16, 2014Applicant: SEIKO EPSON CORPORATIONInventors: Kiyohiko TAKEMOTO, Masaru HOSHINO
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Publication number: 20140303319Abstract: The present invention relates to a conjugated diene based polymer comprising a monomer unit derived from at least one conjugated diene selected from 1,3-butadiene and isoprene and a monomer unit derived from a compound represented by Formula (1): wherein n represents an integer of 0 to 5; R11, R12 and R13 each independently represent an alkyl group having 1 to 10 carbon atoms.Type: ApplicationFiled: April 7, 2014Publication date: October 9, 2014Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventor: Mana FUJII
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Patent number: 8852739Abstract: The invention relates to a carbon black with a CTAB surface area of from 20 to 49 m2/g, with a COAN greater than 90 ml/(100 g), and with a sum of OAN and COAN greater than 235 ml/(100 g). The carbon black is produced in a furnace reactor, where from 20 to 55% by weight of the feedstock used for the carbon black are introduced radially through a nozzle within the first third of the reaction zone, and the remaining amount of the feedstock used for the carbon black is introduced through a nozzle upstream at least one further point into the reactor. The carbon black can be used in rubber mixtures.Type: GrantFiled: February 22, 2011Date of Patent: October 7, 2014Assignee: Evonik Carbon Black GmbHInventors: Arndt-Peter Schinkel, Michael Stanyschöfsky, Conny Vogler, Joachim Fröhlich, Bernhard Schwaiger, Thomas Pelster