Adding Nonreactive Material To Chemically Modified Solid Polymer Patents (Class 524/576)
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Patent number: 8420738Abstract: A thermoplastic elastomer composition which has excellent cleanability and is suitable for use as a medical rubber supply. It is characterized by comprising a rubber ingredient dynamically crosslinked with a crosslinking agent and a matrix which comprises a thermoplastic resin and in which the crosslinked rubber ingredient has been dispersed, the crosslinking agent comprising a triazine derivative.Type: GrantFiled: October 2, 2008Date of Patent: April 16, 2013Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Hiroaki Nakano, Hideyuki Okuyama
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Publication number: 20130078574Abstract: A self-assemblable polymer is disclosed, having first and second molecular configurations with the first molecular configuration has a higher Flory Huggins parameter for the self-assemblable polymer than the second molecular configuration, and the self-assemblable polymer is configurable from the first molecular configuration to the second molecular configuration, from the second molecular configuration to the first molecular configuration, or both, by the application of a stimulus. The polymer is of use in a method for providing an ordered, periodically patterned layer of the polymer on a substrate, by ordering and annealing the polymer in its second molecular configuration and setting the polymer when it is in the first molecular configuration.Type: ApplicationFiled: April 20, 2011Publication date: March 28, 2013Applicant: ASML Netherlands B.V.Inventors: Emiel Peeters, Sander Frederik Wuister, Roelof Koole
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Publication number: 20130072625Abstract: A method for preparing a bis(alkoxysilylorgano)dicarboxylate includes reacting a haloorganoalkoxysilane, a dimetal salt of a dicarboxyl functional compound, and a phase transfer catalyst. A quaternary iminium compound of a polyaza, polycycloalkene is useful as the phase transfer catalyst. The product may be a bis(alkoxysilylalkyl)fumarate, which is useful as a coupling agent in rubber compositions for tire applications.Type: ApplicationFiled: December 2, 2011Publication date: March 21, 2013Applicant: Dow Corning CorporationInventors: Michael Backer, John Gohndrone, Don Kleyer, Xiaobing Zhou
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Publication number: 20130060215Abstract: A hot melt adhesive composition includes at least a semi-crystalline copolymer of propylene and a polyethylene wax having a Brookfield viscosity of about 20 cP to 500 cP at 140° C., a density of about 0.95 g/cm3 to 0.99 g/cm3 between 23° C. and 25° C., and a Mettler drop point of about 110° C. to 135° C., wherein the composition is characterized by a effective set time of about 0.1 second to 5 seconds. Articles including the composition and methods of making articles including the composition are described.Type: ApplicationFiled: April 27, 2012Publication date: March 7, 2013Applicant: ADHERENT LABORATORIES, INC.Inventors: Keith C. Knutson, Thomas H. Quinn, William L. Bunnelle
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Publication number: 20130059165Abstract: The instant invention is an adhesion promoter system, and method of producing the same. The adhesion promoter system according to the present invention comprises an aqueous dispersion comprising the melt kneading product of: (a) at least 60 percent by weight of a first functionalized polyolefin, based on the total weight of the solid content; (b) optionally from 0.5 to less than 40 percent by weight of a second functionalized polyolefin, based on the total weight of the solid content, wherein said second functionalized polyolefin comprises homopolymers of propylene or copolymers of propylene with hexene, octene and/or other like alpha-olefins, the homopolymers or copolymers having a single unsaturation, a terminal succinic anhydride moiety, and additional succinic anhydride substitutions on the polypropylene backbone, where the succinic anhydride substitution ranges from about 5 to about 45 weight percent of second functionalized polyolefin; (c) from 0.Type: ApplicationFiled: April 20, 2011Publication date: March 7, 2013Applicant: Dow Global Technologies LLCInventors: David L. Malotky, Sandra Hofmann, Charles F. Diehl, Michael D. Read, Antonio Batistini, H. Craig Silvis, Cristiano Betté
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Publication number: 20130035420Abstract: A coating system comprises a substrate and a cured film disposed on the substrate and formed from a coating composition. The coating composition comprises a solvent component and a resin. The resin comprises a reaction product of a polyolefin and an oligomer or polymer. The polyolefin, different from the oligomer or polymer, has a functional group that is reactive with the oligomer or polymer and the functional group is selected from acrylate, methacrylate, carboxyl, hydroxyl, epoxide, anhydride and isocyanate functional groups. The oligomer or polymer and the polyolefin are at least partially immiscible in solution at ambient temperature. The oligomer or polymer is grafted with the polyolefin to form the resin.Type: ApplicationFiled: February 4, 2011Publication date: February 7, 2013Inventors: Anthony J. Tye, Ali A. Rihan, Jeff Pierce
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Patent number: 8357749Abstract: The instant invention provides an aqueous dispersion, a coating composition, coating layers and coated article made therefrom.Type: GrantFiled: March 2, 2011Date of Patent: January 22, 2013Assignees: Dow Global Technologies LLC, Rohm and HAAS CompanyInventors: David L. Malotky, Bernhard Kainz, Charles F. Diehl, Denise Lindenmuth, Timothy J. Young, John N. Argyropoulos
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Publication number: 20130001832Abstract: A laser-engraveable composition comprises one or more elastomeric rubbers including at least 10 parts of one or more CLCB EPDM elastomeric rubbers, based on parts per hundred of the total weight of elastomeric rubbers (phr). The laser-engraveable composition further comprises 2-30 phr of a near-infrared radiation absorber and either 1-80 phr of an inorganic, non-infrared radiation absorber filler, or a vulcanizing composition that comprises a mixture of at least two peroxides. One first peroxide has a t90 value of 1-6 minutes as measured at 160° C., and a second peroxide has a t90 value of 8-20 minutes as measured at 160° C. This laser-engraveable composition can be used to form various flexographic printing precursors that can be laser-engraved to provide relief images in flexographic printing plates, printing cylinders, or printing sleeves.Type: ApplicationFiled: June 30, 2011Publication date: January 3, 2013Inventors: Ophira Melamed, Ido Gal, Limor Dahan
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Publication number: 20120328940Abstract: Compositions of discrete carbon nanotubes for improved performance lead acid batteries. Further disclosed is a method to form a lead-acid battery with discrete carbon nanotubes.Type: ApplicationFiled: June 21, 2012Publication date: December 27, 2012Applicant: Designed Nanotubes, LLCInventors: Clive P. Bosnyak, Kurt W. Swogger
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Patent number: 8329814Abstract: Briefly described, embodiments of this disclosure include ink formulation and modified pigments. One exemplary modified pigment, among others, includes a pigment A represented by the formula in FIG. 3.Type: GrantFiled: March 22, 2010Date of Patent: December 11, 2012Assignee: Hewlett-Packard Development Company, L.P.Inventors: Zeying Ma, Gregg A. Lane, Yuan Yu, Xiaohe Chen, George M. Sarkisian
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Publication number: 20120296035Abstract: There is provided a ring-opening polymer of cyclopentene wherein a cis ratio of cyclopentene-derived structural units is 30% or more, the weight average molecular weight (Mw) is 100,000 to 1,000,000, and an oxysilyl group is included at an end of the polymer chain. For example, the ring-opening polymer of cyclopentene can be obtained by ring opening polymerization of cyclopentene in the presence of a compound of a transition metal belonging to Group 6 in the Periodic Table, an organoaluminum compound represented by the following general formula (1), and an olefinically unsaturated hydrocarbon containing an oxysilyl group. (R1)3-xAl(OR2)x??(1) (in the general formula (1), R1 and R2 represent a hydrocarbon group having 1 to 20 carbon atoms and x satisfies the requirement 0<x<3.Type: ApplicationFiled: January 14, 2011Publication date: November 22, 2012Applicant: ZEON CORPORATIONInventors: Yasuo Tsunogae, Yoshihisa Takeyama
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Patent number: 8288470Abstract: The invention provides a composition comprising at least one olefin multi-block interpolymer; at least one functionalized olefin-based polymer; and optionally at least one thermoplastic polyurethane. The invention also provides for articles prepared from the inventive compositions and for methods for making the same.Type: GrantFiled: December 21, 2007Date of Patent: October 16, 2012Assignee: Dow Global Technologies LLCInventors: Patricia Ansems, Ashish Batra, Laura Bauerle Weaver, Lawrence J. Effler, H. Craig Silvis, Hamed Lakrout, Laura K. Mergenhagen
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Publication number: 20120231337Abstract: The aqueous paste for an electrochemical cell of the present invention comprises an aqueous dispersion for an electrochemical cell that comprises an olefin copolymer (a); an active material; and a conductive assistant, wherein the olefin copolymer (a) has a weight average molecular weight of not less than 50,000 and is at least one kind selected from a random propylene copolymer (a-1) containing 50% by weight to less than 85% by weight of a structural unit derived from propylene; an acid-modified random propylene copolymer (a-2) obtained by modifying the copolymer (a-1) with an acid; and an ethylene-(meth) acrylic acid copolymer (a-3) containing 5% by weight to less than 25% by weight of a structural unit derived from (meth) acrylic acid.Type: ApplicationFiled: November 18, 2010Publication date: September 13, 2012Inventors: Gen Miyata, Akinori Etoh, Takehito Mitate, Naoto Nishimura, Takahiro Matsuyama, Syumpei Nishinaka
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Publication number: 20120199200Abstract: An edge seal for manufacturing two-pane or multi-pane insulating glass or solar modules includes a sealant and a bonding agent. The sealant contains a polymer modified with special reactive groups and has the following overall composition: olefinic polymers included in an amount from about 10% to about 90% by weight of the total composition; at least one filler included in an amount from about 10% to about 65% by weight of the total composition; at least one inorganic filler that is a thermal and oxidative stabilizer in an amount from about 2% to about 30%; at least one of a desiccant and a water scavenger included in an amount from about 2.5% to about 25% by weight of the total composition; and at least one aging resistor including an anti-oxidant or UV stabilizer included in an amount from about 0% to about 3% by weight of the total composition.Type: ApplicationFiled: October 14, 2010Publication date: August 9, 2012Applicant: ADCP Products, Inc.Inventors: Harald Becker, Heike Brucher, Norbert Schott
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Publication number: 20120196970Abstract: A compatibilizer contains a polymer (A) obtained by reacting a modified olefin-based polymer (a-1) with a polymer (a-2) containing a terminal functional group, wherein the modified olefin-based polymer (a-1) is a polymer modified with from 0.01 to 2 mass % of unsaturated carboxylic acid or a derivative thereof, and the polymer (a-2) is a ring opening polymer or condensation polymer containing a terminal functional group, capable of reacting with the modified olefin-based polymer (a-1), at both ends or one end thereof and has a number average molecular weight from 1,500 to 100,000. This provides an excellent compatibilizer. Particularly, upon melt processing a recovery of a multilayer structure including an EVOH layer and a thermoplastic resin layer, a recycling agent is provided that gives sufficient improvement effects to any of the adhesion of a degraded resin to a screw of a molding machine, the generation of die build-up, the generation of fish eyes, and the decrease in transparency.Type: ApplicationFiled: September 30, 2010Publication date: August 2, 2012Applicant: KURARAY CO., LTD.Inventors: Takeyuki Igarashi, Shinji Tai, Tomoyuki Watanabe
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Publication number: 20120175033Abstract: A rubber composition based on at least a diene elastomer, a reinforcing filler and a crosslinking system, characterized in that it comprises at least 10 to 150 phr of a platy filler and from 0.01 to 0.3 phr of a metal salt. This composition has good processing and mechanical properties, and also improved oxygen impermeability properties over a wide temperature range, from ambient temperatures when the tire is stationary up to the temperatures of the tire when it is running. According to one preferred embodiment, the rubber composition described above can be used in the tire as a protective elastomer layer in at least one part of the tire.Type: ApplicationFiled: March 30, 2010Publication date: July 12, 2012Applicants: Michelin Recherche et Technique S.A., SOCIETE DE TECHNOLOGIE MICHELINInventors: David Lavialle, Jacques Besson
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Publication number: 20120178824Abstract: The present invention relates to the use of esters of polyisobutenesuccinic acid for producing hydrogels, and to the use of such hydrogels for cleaners and care compositions for the home (so-called homecare products), for cosmetics, and also for medical products.Type: ApplicationFiled: January 10, 2012Publication date: July 12, 2012Applicants: Henkel AG & Co. KGaA, BASF SEInventors: Hannah Maria König, Sophia Ebert, Roland Ettl, Ouidad Benlahmar, Marc-Steffen Schiedel, Brigitte Giesen, Petra Plantikow
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Publication number: 20120157579Abstract: Nucleophilic substitution reactions of halogenated polymers and azoles are used to produce derivatives of polyolefins bear pendant azolium ionomers. These uncured ionomers are useful in adhesive, antimicrobial applications, as well as in polymer composites and polymer blends. Furthermore, these azolium ionomers' ion pairs can bear reactive functionality, which provides access to further reactions that were unavailable using previous technology. Advantageously, such reactive ionomer derivatives of polyolefins can be cured by free radical and moisture-curing chemistry that was unaccessible to the halogenated polymer parent material.Type: ApplicationFiled: December 9, 2011Publication date: June 21, 2012Inventors: J. Scott Parent, Ralph A. Whitney
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Patent number: 8202944Abstract: The present invention provides a modified polymer, which is obtained by reacting, with an active metal bonded to a polymer, a modifier represented by the general formula (I) (where X1 to X5 each represent a hydrogen atom or a specific monovalent functional group, and at least one of those is other than a hydrogen atom, R1 to R5 each represent a single bond or a divalent hydrocarbon group having 1 to 18 carbon atoms, and a plurality of aziridine rings may be bonded through any of X1 to X5 and R1 to R5).Type: GrantFiled: December 19, 2005Date of Patent: June 19, 2012Assignee: Bridgestone CorporationInventors: Eiju Suzuki, Tetsuya Omura
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Patent number: 8193275Abstract: Aqueous dispersions including at least one thermoplastic resin; at least one dispersing agent; and water; wherein the dispersion has a pH of less than 12 are disclosed along with dispersions including at least one thermoplastic resin; at least one dispersing agent; and water wherein the dispersion has a volume average particle size of less than about 5 ?m. Some dispersions include less than about 4 percent by weight of the dispersing agent based on the weight of the thermoplastic resin. Other dispersions include at least one propylene-rich alpha-olefin interpolymer; at least one dispersing agent; and water. Methods of making such dispersions are also described.Type: GrantFiled: September 21, 2011Date of Patent: June 5, 2012Assignee: Dow Global Technologies LLCInventors: Brad M. Moncla, Matthew J. Kalinowski, David R. Speth, Charles F. Diehl, Dale C. Schmidt, Kevin D. Maak, Ronald Wevers
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Publication number: 20120083572Abstract: Styrenic (meth)acrylic oligomers that are prepared at lower temperature than conventional solid grade oligomers, or are hydrogenated, contain fewer terminal vinylic unsaturations, when compared to such conventional styrenic (meth)acrylic oligomers prepared by the customary high temperature processes. Styrenic (meth)acrylic oligomers that contain fewer terminal vinylic unsaturations demonstrate improved thermal stability and may provide improved resistance to UV weathering compared to the conventional and non-hydrogenated styrenic (meth)acrylic oligomers.Type: ApplicationFiled: September 30, 2011Publication date: April 5, 2012Inventors: Timothy D. Klots, Rafael Galvan, Jon Debling
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Patent number: 8143344Abstract: The present invention is further directed to a method of producing a particulate composite of silica and elastomer comprising the steps of dispersing a diene based elastomer in a hydrophobic liquid to form an elastomer dispersion; mixing the elastomer dispersion with an aqueous solution of an alkali metal silicate to form a mixture; adding a precipitating agent to the mixture to precipitate a porous silica onto the dispersed elastomer to form a particulate composite of silica and elastomer comprising a porous silica shell at least partially surrounding a core of diene based elastomer; and optionally adding a separating agent to remove the hydrophobic liquid from the particulate composite.Type: GrantFiled: December 3, 2009Date of Patent: March 27, 2012Assignee: The Goodyear Tire & Rubber CompanyInventors: Georges Koster, Wolfgang Lauer
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Publication number: 20110318554Abstract: There is provided a polymer having a high refractive index without forming a complex with inorganic fine particles, being excellent in the solubility in an organic solvent and the coating properties during film formation, and having a high transparency, and further being capable of dispersing optically homogeneously a functional dye such as a nonlinear dye in a high concentration. A hyperbranched polymer containing a thioester group of Formula (1) below [where R1 is a hydrogen atom or a methyl group; Ar1 and Ar2 are independently an aromatic ring group constituted of 5 to 18 ring atoms that is optionally substituted with a C1-6 alkyl group, a C1-6 alkoxy group, a C1-6 alkylthio group, or a halogen atom, the aromatic ring group optionally contains a hetero atom, or is optionally an aromatic ring group formed by two or more fused rings; A? is a structure of Formula (2) or Formula (3) below; and n is the number of repeating unit structures and is an integer of 2 to 100,000].Type: ApplicationFiled: January 27, 2010Publication date: December 29, 2011Applicants: NISSAN CHEMICAL INDUSTRIES, LTD., KYUSHU UNIVERSITYInventors: Hideo Nagashima, Shiyoshi Yokoyama, Shin-ichiro Inoue, Azusa Inoue, Keisuke Kojima
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Patent number: 8058354Abstract: The present invention provides solvent- and water-based primer compositions that include at least one carboxylated polyolefin that has been modified with one or more polyfunctional alcohols. The carboxylated polyolefins are obtained by the reaction of polyolefins with at least one of unsaturated carboxylic esters, unsaturated carboxylic acids, unsaturated carboxylic anhydrides, acrylic monomers, and mixtures thereof. The carboxylated polyolefins are then further modified by reaction with one or more polyfunctional alcohols. These polyfunctional alcohol-modified polyolefins may also contain pendant carboxyl groups, which have the propensity to form hydrophilic salts with amines or inorganic bases, thereby rendering the polyfunctional alcohol-modified polyolefins water-dispersible. These primer compositions are useful for significantly improving the adhesion of paints, adhesives, and inks to various plastic and metal substrates.Type: GrantFiled: June 30, 2003Date of Patent: November 15, 2011Assignee: Eastman Chemical CompanyInventors: Kevin Alan Williams, Robert Lee Eagan, Lisa Kay Templeton, Richard Leon McConnell
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Patent number: 8053512Abstract: A backbone modified polymer comprising the reaction product of an elastomeric polymer and a sulfide modifier represented by Formula 1: AS—Y-Zm (Formula 1), and wherein Y is (C12-C100) aralkyl, (C12-C100) aryl, (C12-C100) alkyl, or (C12-C100) dialkylether (alkyl-O-alkyl), and wherein each may be optionally substituted with (C1-C4alkyl, (C1-C4alkoxy, (C7-C16aryl, (C7-C16 aralkyl, nitrile, amine, NO2, alkoxy, or thioalkyl; S is sulfur; A is hydrogen, —(S)p—R1 or -MR2R3R4; Z is —SH, —S-MR5R6R7, —S—(S)p—R8, —NR9R10, —NR11COR12, —O—CO—R13, —NCO, or —COOR14; M is silicon or tin; N is nitrogen; O is oxygen; m is the number one, two or three; p is the number one, two, three, four or five; R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12, R13 and R14 are the same or different, and are each, independently, selected from hydrogen (H), (C1-C16) alkyl, (C6-C16) aryl, (C7-C16) aralkyl or (C3-C30) tri(hydrocarbyl)silyl, and wherein the hydrocarbyl groups are each independently selected from (C1-C16) alkyl, (C6-C16) aryl, orType: GrantFiled: December 14, 2007Date of Patent: November 8, 2011Assignee: Styron Europe GmbHInventors: Sven K. H. Thiele, Joachim Kiesekamp
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Patent number: 8034868Abstract: A rubber composition obtained by compounding thereinto a rubber component containing 0.5 to 100% by weight of a modified conjugated diene-based polymer having a fullerene bonded thereto in the molecule and having a weight average molecular weight of 50,000 or more excellent processability, superior balance of modulus and heat buildup, excellent cold flowability and superior tan ? balance.Type: GrantFiled: March 18, 2009Date of Patent: October 11, 2011Assignee: The Yokohama Rubber Co., Ltd.Inventors: Makoto Ashiura, Tetsuji Kawazura, Fumito Yatsuyanagi
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Publication number: 20110218298Abstract: High molecular weight disulfide polymers are synthesized in aqueous media by exposing dithiol compounds to a mild oxidizing environment in the presence of a tertiary amine catalyst. The unique oxidizing system polymerizes monomers through the formation of sulfur-sulfur bonds between dithiol compounds. The same oxidizing system may be used to make disulfide-crosslinked gels from compounds containing multiple thiol groups. The oxidizing system is comprised of oxygen at atmospheric concentration and dilute hydrogen peroxide. A filler such as carbon black may be incorporated into the polymer or cross-linked gel during polymerization. A polydisulfide polymer is provided having a weight average molecular weight of greater than about 100,000 g/mol and a polydispersity index of about 2 or less. A tetrathiol composition results from a reaction of a diacrylate with a trithiol.Type: ApplicationFiled: March 4, 2011Publication date: September 8, 2011Applicant: THE UNIVERSITY OF AKRONInventors: Judit E. Puskas, Emily Q. Rosenthal
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Publication number: 20110204281Abstract: The efficient dispersion of carbon nanotubes in various media and methods of using the same in such applications as inks, coatings, and composites and in various electrical and electronic articles are disclosed. A dispersant is used which has the formula P-(U-Y)s where P is a metal or metal-free phthalocyanine, Y is a compatibilizing moiety with a molecular weight between 500 and 5000 g/mol, U is a linking moiety covalently bonding Y to P, and s is an integer between 1 and 4.Type: ApplicationFiled: September 9, 2009Publication date: August 25, 2011Applicant: Sun Chemical CorporationInventor: Jason H. Rouse
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Publication number: 20110201742Abstract: Mixtures of halogenated elastomers and latent curatives are provided that cure when subjected to sufficient heat to decompose the latent curative. Decomposition products include CO2 and N-nucleophiles, which participate in nucleophilic substitution reactions leading to crosslinking of the elastomers. Transparent thermoset products that were free of voids were produced.Type: ApplicationFiled: January 28, 2011Publication date: August 18, 2011Inventors: J. Scott Parent, Ralph A. Whitney
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Publication number: 20110186775Abstract: Carbon nanotube-infused fiber materials containing substantially parallel-aligned, infused carbon nanotubes are described herein. The carbon nanotube-infused fiber materials contain a fiber material and a layer of carbon nanotubes infused to the fiber material, where the infused carbon nanotubes are aligned substantially parallel to the longitudinal axis of the fiber material and at least a portion of the substantially parallel-aligned, infused carbon nanotubes are crosslinked to each other, to the fiber material, or both. Crosslinking can occur through covalent bonding or pi-stacking interactions, for example. The carbon nanotube-infused fiber materials can further contain additional carbon nanotubes that are grown on the layer of substantially parallel-aligned, infused carbon nanotubes. Composite materials containing the carbon nanotube-infused fiber materials and methods for production of the carbon nanotube-infused fiber materials are also described herein.Type: ApplicationFiled: February 1, 2011Publication date: August 4, 2011Applicant: APPLIED NANOSTRUCTURED SOLUTIONS, LLC.Inventors: Tushar K. SHAH, Harry C. Malecki, Brandon K. Malet, Robert D. Hoskins, Jigar M. Patel
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Publication number: 20110160323Abstract: The invention provides a composition comprising an ethylene/?-olefin/non-conjugated diene interpolymer, which has the following properties: an Mz(abs)/Mz(Conv) value greater than 1.35; an Mz(BB)/Mw(abs) value greater than 1.6; and a non-conjugated diene content less than 10 weight percent, based on the total weight of the interpolymer. The invention also provides a process for forming a crosslinked composition, said process comprising: (a) forming a polymeric admixture comprising at least the following: (A) an ethylene/?-olefin/non-conjugated diene copolymer rubber (B) which has the following properties: an Mz(abs)/Mz(Conv) value less than 1.3; an Mz(BB)/Mw(abs) value greater than 1.6, but less than 2.5; and an Mw(abs) value less than 350,000 g/mole; and (B) a coupling amount of (i) at least one poly(sulfonyl azide) or (ii) at least one peroxide; and (b) heating the resulting admixture to a temperature at least the decomposition temperature of the crosslinking agent.Type: ApplicationFiled: September 16, 2009Publication date: June 30, 2011Applicant: Dow Global Technologies LLCInventors: Wenbin Liang, Brian W. Walther, Gary Marchand
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Publication number: 20110133134Abstract: Compositions comprising graphene sheets, at least one olefin polymer, and at least one crosslinking agent and crosslinked compositions comprising graphene sheets and at least one olefin polymer. A method of making a crosslinked composition comprising graphene sheets and at least one olefin polymer, coatings comprising the compositions, and a method of coating a surface with the compositions are disclosed.Type: ApplicationFiled: June 9, 2010Publication date: June 9, 2011Applicant: VORBECK MATERIALS CORP.Inventors: Vipin Varma, Dan Scheffer
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Patent number: 7947776Abstract: An aqueous dispersions including (A) at least one ethylene-based polyolefin forming a dispersed polymer phase; (B) at least one dispersing agent; and (C) water; wherein the dispersion has a pH of less than 12; and wherein the dispersed polymer phase has a volume average particle size of less than about 5 microns. In other aspects, an article or a substrate including a coating, wherein the coating was obtained from an aqueous dispersion comprising (A) at least one of an ethylene-based polyolefin and a propylene-based polyolefin; (B) at least one dispersing agent; and (C) water; wherein the dispersion had a pH of less than 12.Type: GrantFiled: May 10, 2007Date of Patent: May 24, 2011Assignee: Dow Global Technologies LLCInventors: Brad M. Moncla, Matthew J. Kalinowski, David R. Speth, Charles F. Diehl, Dale C. Schmidt, Kevin D. Maak, Wenbin Liang, Gary M. Strandburg
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Publication number: 20110118394Abstract: An aqueous solution coating composition comprising an autoxidisable polyvinyl polymer having ?20% of fatty acid residue by weight of polymer; Tg from ?60 to +15° C.; acid value of 15 to 75 mg KOH/g, Mw from 2500 to 100000 g/mol; polydispersity ?30, said composition having ?25% co-solvent by weight of solids, ?30% solids by weight of composition; said composition when in the form of a coating having a telegraphing value defined as the difference in gloss at a 20° angle of between a film cast on rough PVC and a film cast on smooth PVC of 10 gloss units.Type: ApplicationFiled: March 31, 2009Publication date: May 19, 2011Inventors: Ilse Van Casteren, Gerardus Cornelis Overbeek, Ronald Tennebroek, Tijs Nabuurs, Richard George Coogan
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Patent number: 7935755Abstract: A method for forming a heat sealable coating on a substrate, wherein the substrate is formed from at least one oriented polymer is shown. The method includes depositing an aqueous polymer dispersion on the substrate, wherein the aqueous polymer dispersion includes (A) at least one thermoplastic resin; (B) at least one dispersing agent; and (C) water; wherein the dispersion has a pH of less than 12, and drying the dispersion to form a first layer.Type: GrantFiled: June 15, 2010Date of Patent: May 3, 2011Assignee: Dow Global Technologies LLCInventors: Brad M. Moncla, Sarah T. Eckersley, Ralph G. Czerepinksi, Charles F. Diehl, Matthew J. Kalinowski, Dale C. Schmidt
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Patent number: 7825182Abstract: This invention relates to nanocomposites comprising organo-clay and at least one stabilization functionalized thermoplastic polyolefin. Preferably the stabilization functionalized thermoplastic polyolefin is represented by the formula: T-(R1G)n wherein T represents the thermoplastic polyolefin Each R1 is a bridging group, preferably independently selected from the group consisting of C1 to C20 aliphatic; C1 to C20 aromatic; substituted C1 to C20 aliphatic; substituted C1 to C20 aromatic; C1 to C20 aliphatic ester; C1 to C20 aliphatic ether; C1 to C20 aliphatic amide; C1 to C20 aliphatic imide; n is the number of stabilization functional/bridging groups bound to T and may be from 1-300; and G is selected from one or more of phenols, ketones, hindered amines, substituted phenols, substituted ketones, substituted hindered amines, or combinations thereof.Type: GrantFiled: April 1, 2008Date of Patent: November 2, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Caiguo Gong, Alan J. Oshinski, Beverly J. Poole, Jerry W. Ball, Thomas W. Sykes
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Patent number: 7803865Abstract: Aqueous dispersions including at least one thermoplastic resin; at least one dispersing agent; and water; wherein the dispersion has a pH of less than 12 are disclosed along with dispersions including at least one thermoplastic resin; at least one dispersing agent; and water wherein the dispersion has a volume average particle size of less than about 5 ?m. Some dispersions include less than about 4 percent by weight of the dispersing agent based on the weight of the thermoplastic resin. Other dispersions include at least one propylene-rich alpha-olefin interpolymer; at least one dispersing agent; and water. Methods of making such dispersions are also described.Type: GrantFiled: August 25, 2004Date of Patent: September 28, 2010Assignee: Dow Global Technologies Inc.Inventors: Brad M. Moncla, Matthew J. Kalinowski, Dave Speth, Charles Diehl, Dale Schmidt, Kevin D. Maak, Ronald Wevers
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Patent number: 7763676Abstract: A method for forming a heat sealable coating on a substrate, wherein the substrate is formed from at least one oriented polymer is shown. The method includes depositing an aqueous polymer dispersion on the substrate, wherein the aqueous polymer dispersion includes (A) at least one thermoplastic resin; (B) at least one dispersing agent; and (C) water; wherein the dispersion has a pH of less than 12, and drying the dispersion to form a first layer.Type: GrantFiled: February 28, 2005Date of Patent: July 27, 2010Assignee: Dow Global Technologies Inc.Inventors: Brad Maurice Moncla, Sarah T. Eckersley, Ralph G. Czerepinski, Charles F. Diehl, Matthew James Kalinowski, Dale C. Schmidt
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Publication number: 20100160522Abstract: Chemically crosslinked polycyclooctene having excellent shape recovery properties is prepared by ring-opening metathesis polymerization of cis-cyclooctene followed by chemical crosslinking. The crosslinked polycyclooctene can be shaped, the shape memorized, a new shape imparted with the original shape being recoverable by suitable temperature adjustment. The dependence of shape memory characteristics on degree of crosslinking was established. In addition to polycyclooctene, blends thereof with other materials such as SBR, EVA, polyurethane rubbers, and inorganic fillers can be utilized to provide chemically crosslinked products having excellent and tailored shape memory properties.Type: ApplicationFiled: March 5, 2010Publication date: June 24, 2010Inventors: Patrick T. Mather, Changdeng Liu, Seung B. Chun, E. Bryan Coughlin
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Publication number: 20100152371Abstract: In method of making an organic solution of a chlorinated polyolefin that produces a storage-stable solution, a chlorinated polyolefin resin is dissolved in a hydrocarbon solvent that is predominantly aliphatic hydrocarbon, aromatic hydrocarbons other than toluene and xylene, or mixtures of these at a temperature of from 118 to 125° C., particularly at 120 to 122° C., held at the temperature for an adequate time for complete dissolution, particularly for at least about ninety minutes, then cooled and a cosolvent is added at a temperature below the boiling point of the cosolvent but at a temperature at which the chlorinated polyolefin solution is still clear or has little haziness, particularly at about 50 to 75° C. The solution may then be cooled, if needed, to a storage or use temperature. The solution has from about 60 to about 90 percent by weight of the mixture of the hydrocarbon solvent and cosolvent and from about 10 to about 40 percent by weight of chlorinated polyolefin resin. The solution has 0.Type: ApplicationFiled: February 22, 2010Publication date: June 17, 2010Inventors: Gregory G. Menovcik, William H. Merritt
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Patent number: 7737218Abstract: Provided is a method comprising reacting the anionic living end of a polymer with a compound selected from the group consisting of tin halides and silicon halides to produced a polymer with a homolytically cleavable group containing a Sn—C bond or a Si—C bond. An engineered plastic may then be produced by adding the polymer containing a homolytically cleavable group containing a Sn—C bond or a Si—C bond to a solvent comprising at least one vinyl monomer; (b) optionally adding at least one additional inert solvent; (c) optionally adding additives selected from the group consisting of extender oils, modifiers, and antioxidants; and (d) initiating polymerization of the at least one vinyl monomer by the use of an initiator and/or heat, wherein a free radical is produced from the polymer containing a homolytically cleavable group containing a Sn—C bond or a Si—C bond.Type: GrantFiled: December 29, 2006Date of Patent: June 15, 2010Assignee: Bridgestone CorporationInventors: James E. Hall, David F. Lawson
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Publication number: 20100113672Abstract: An object is to provide a fire retardant material capable of being molded by an injection molding machine and free from deterioration of the physical properties and a molded body formed of the fire retardant material. A fire retardant includes a degraded polypropylene resin obtained by melt kneading a polypropylene resin and an organic peroxide, wherein a weight average molecular weight of the degraded polypropylene is from 50,000 to 200,000; and an inorganic filler, wherein a mass ratio of the polypropylene to the inorganic filler is from 95/5 to 10/90.Type: ApplicationFiled: October 20, 2009Publication date: May 6, 2010Applicant: TOYODA GOSEI CO., LTD.Inventor: Hiroyuki Nakagawa
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Publication number: 20100076102Abstract: The invention relates to a composite comprising a thermosetting resin with a hardness of at least 55 Shore D, wherein the resin essentially consists of an ethylene ?-olefin copolymer with a density of less than 880 kg/m3, which resin is crosslinked to a degree such that the volume swelling measured in decaline after 64 hours at 23° C. is less than 50% by volume on the composite and the composite contains at least 40% by volume of a reinforcing filler, wherein the vol % of the filler is related to the volume of the resin. The composite according to the invention is an excellent isolator when at least 100 phr cork are present in the composite. A composite according to the invention can be made by crosslinking of the copolymer in the presence of a high amount of peroxide in the presence of at least 40% by volume on the resin of a filler.Type: ApplicationFiled: September 10, 2007Publication date: March 25, 2010Applicant: DSM IP ASSETS B.V.Inventors: Herman Gerard Dikland, Jagdish Ramanlal Patel, Christopher Michael Twigg
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Publication number: 20090326145Abstract: The invention describes a process for reducing the surface energy of organic materials such as for example increasing the oil and water repellency and stain release of organic materials, which comprises treating the organic material with at least a compound of the formula I wherein the general symbols are as defined in claim 1; especially wherein at least one of the radicals R2, R3 or R4 is —CH(R11)—S(O)p—R12; R11 is hydrogen, C1-C8alkyl, unsubstituted or with C1-C4alkyl substituted phenyl; R12 is a monovalent perfluorinated alkyl or alkenyl, linear or branched organic radical having four to twenty fully fluorinated carbon atoms, and p is 0, 1 or 2.Type: ApplicationFiled: June 4, 2007Publication date: December 31, 2009Inventors: Michèle Gerster, Manuel Mihalic
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Publication number: 20090299000Abstract: The present invention relates to a peroxide curable rubber compound comprising a peroxide curative and a high multiolefin halobutyl ionomer prepared by reacting a halogenated butyl polymer having a high mol percent of multiolefin with at least one nitrogen and/or phosphorus based nucleophile. The resulting high multiolefin halobutyl ionomer comprises from about 2 to 10 mol % multiolefin. The present invention is also directed to a shaped article comprising the rubber compound.Type: ApplicationFiled: August 16, 2006Publication date: December 3, 2009Inventors: Rui Resendes, Janice Nicole Hickey
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Publication number: 20090227730Abstract: The instant invention discloses a process for preventing contact discoloration of substrates coming into contact with elastomers and stabilizing elastomers to prevent oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation, which comprises incorporating into the elastomers, or applying to these, at least a compound of the formula (I) wherein R1 is C1-C12alkyl, R2 is C1-C12alkyl, or R1 and R2 together with the carbon atom to which they are attached form an unsubstituted or with C1-C4alkyl substituted C5-C12cycloalkyl ring; R3 is hydrogen or —CH2—S(O)m—R5, R4 and R5 independently of each other are unsubstituted or with cyano substituted C5-C18-alkyl; C7-C9phenylalkyl, unsubstituted or with halogen, hydroxyl, cyano or C1-C4alkyl substituted phenyl or naphthyl; benzothiazolyl or —R6—CO2—R7, R6 is C1-C18alkylene, R7 is C1-C18alkyl, and m is 0, 1 or 2.Type: ApplicationFiled: October 2, 2006Publication date: September 10, 2009Applicant: Ciba CorporationInventors: Michèle Gerster, Hans-Rudolf Meier, Gerrit Knobloch, Pierre Rota-Graziosi
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Patent number: 7534839Abstract: Anionically-polymerized living polymers are sequentially functionalized with certain agents X? and Y?. A method of preparing a functionalized polymer comprising the steps of reacting the polymer with a functionalizing agent X?, and then further reacting the polymer with a functionalizing agent Y?.Type: GrantFiled: June 9, 2004Date of Patent: May 19, 2009Assignee: Bridgestone CorporationInventors: David F. Lawson, Christine Rademacher, Christopher Robertson
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Publication number: 20090076215Abstract: Integral polymer grids, such as geogrids, are made by stretching and orienting a polypropylene starting sheet material having a defined pattern of holes or depressions in which the polypropylene is at least 50%, and preferably up to about 80%, beta crystals caused by adding a beta nucleating agent to the polypropylene, preferably in concentrations between about 10 ppm to about 100 ppm. Such beta nucleated polypropylene grids exhibit increased yield and break tensile strengths, increased 2% and 5% tensile strengths, increased modulus characteristics, increased torsional stiffness, increased impact strength, and increased grid junction strength. Methods for manufacturing the beta nucleated polypropylene mesh grids are disclosed, along with applications for stabilizing particulate material in civil engineering structures, and the like.Type: ApplicationFiled: April 4, 2008Publication date: March 19, 2009Inventors: William Shelton, John Pocher
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Publication number: 20090075078Abstract: An acid-modified polyolefin-based resin for glass fiber treatment having: (1) an amount of components extractable with boiling methyl ethyl ketone of 8 mass % or less; (2) a number average molecular weight (Mn), measured by gel permeation chromatography (GPC), of 6,000 to 48,000; and (3) an amount of an acid which has been added, measured by Fourier transform infrared spectroscopy, of 0.1 to 12 mass %.Type: ApplicationFiled: October 20, 2005Publication date: March 19, 2009Applicant: PRIME POLYMER CO., LTD.Inventors: Koki Yano, Rikuo Onishi
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Publication number: 20080262147Abstract: A modified butyl rubber composition containing a modified butyl rubber obtained by a modification reaction of a compound (a) having a nitroxide-free radical, stable in the presence of oxygen at an ordinary temperature, in the molecule thereof and a radical initiator (b) and at least two kinds of bi- or more-functional radical polymerizable monomers (c).Type: ApplicationFiled: April 16, 2008Publication date: October 23, 2008Applicant: The Yokohama Rubber Co., Ltd.Inventors: Makoto Ashiura, Tetsuji Kawazura