From Aromatic Hydrocarbon Monomer Patents (Class 524/577)
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Patent number: 7235597Abstract: The present invention relates to a styrenic thermoplastic resin composition, and more particularly to a styrenic thermoplastic resin composition comprising a non-halogen flame-retardant having superior flame-retarding properties and impact strength. The present invention provides a flame-retarding styrenic thermoplastic resin composition comprising a) 100 weight parts of a base resin comprising i) 10 to 50 weight parts of a rubber-modified styrenic-containing graft copolymer, ii) 5 to 20 weight parts of phenol novolac resin, and iii) 20 to 70 weight parts of a styrene-containing copolymer; and b) 5 to 20 weight parts of an aromatic phosphate. In addition, the a) base resin may further comprise iv) 10 to 40 weight parts of a thermoplastic polyurethane resin.Type: GrantFiled: September 5, 2002Date of Patent: June 26, 2007Assignee: LG Chem, Ltd.Inventors: Sung-Ho Lee, Chan-Hong Lee, Yong-Yeon Hwang, Ki-Young Nam, Tae-Hak Kim
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Patent number: 7226970Abstract: A resin composition comprising a 2-(1-arylalkylidene) acetic ester and at least one resin selected from a methyl methacrylate resin, a styrene resin and a methyl methacrylate-styrene copolymer resin is provided, wherein the acetic ester is contained in the composition in an amount of from about 0.0005 part by weight to about 0.1 part by weight with respect to 100 parts by weight of the resin. The resin composition is improved in durability without deteriorating the excellent properties of the resin, such as being colorless and transparent.Type: GrantFiled: March 22, 2004Date of Patent: June 5, 2007Assignee: Sumitomo Chemical Company, LimitedInventors: Tomohiro Maekawa, Kenji Manabe
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Patent number: 7192997Abstract: A composition for use in making an encapsulant usable in the encapsulation of a semiconductor chip assembled to a substrate with C4 solder interconnections therebetween, which in turn may form part of an electronic package. The composition comprises a resin, a flexibilizing agent and a filler material.Type: GrantFiled: February 7, 2001Date of Patent: March 20, 2007Assignee: International Business Machines CorporationInventor: Konstantinos I. Papathomas
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Patent number: 7176249Abstract: The invention provides an aqueous ink composition, which comprises at least: 1) an alkali neutralized product of a copolymer containing constituent units of: (i) at least one monomer selected from the group consisting of alkene, styrene, styrene derivatives, vinyl naphthalene, and vinyl naphthalene derivatives; (ii) at least one monomer selected from monomers containing an acidic group that ion dissociate; and (iii) at least one ?,?-ethylenic unsaturated carboxylic acid alkyl ester; 2) a pigment; and 3) an aqueous medium, wherein the alkali neutralized product of the copolymer in the aqueous ink composition forms micelle aggregations with an average diameter being set in the range of 10 nm to 300 nm. A manufacturing method of the aqueous ink composition and an image forming method using the aqueous ink composition are also provided.Type: GrantFiled: March 19, 2003Date of Patent: February 13, 2007Assignee: Fuji Xerox Co., Ltd.Inventors: Eiichi Akutsu, Shigemi Ohtsu, Keishi Shimizu, Kazutoshi Yatsuda, Takeshi Mikami
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Patent number: 7172651Abstract: Pigment suitable for use in coating compositions for inkjet recording media. Surfaces of an inorganic particulate are interacted with a water-soluble polyvalent metal salt in an aqueous medium. The treated particle surfaces have a significant cationic surface charge imparted to them. The salt is a salt of a metal of Group II or Group III of the Periodic Table. Inkjet recording media treated with a coating composition containing the above pigment provide high density, fast-drying, and non-feathering ink images with suitable water fastness, while the coating compositions also offer cost advantages and improved rheology at higher pigment levels over coatings based on silica pigments.Type: GrantFiled: June 17, 2003Date of Patent: February 6, 2007Assignee: J.M. Huber CorporationInventors: Ching-Yih Chen, Ricky L. Giddens, Richard D. Carter
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Patent number: 7153893Abstract: It is an object of the present invention to provide an ink composition with excellent gas resistance, fixability, and bronzing resistance, as well as a recording method and recorded matter in which this ink composition is used. The present invention achieves this object by means of an ink composition in which a pigment is dispersed in a solvent, and a copolymer, which contains structural units originating in an aromatic compound monomer and structural units originating in a C5 or higher diene compound and/or structural units originating in a non-diene compound, is included, wherein the copolymer has a sulfonic acid group, and the proportion of structural units originating in the aromatic compound monomer is 30 to 60 wt % with respect to the weight of the copolymer (100 wt %). In the present invention, styrene, ?-methylstyrene, o-methylstyrene, p-methylstyrene, m-methylstyrene, chlorostyrene, or vinyl benzoate is selected as the above-mentioned aromatic compound monomer.Type: GrantFiled: October 17, 2003Date of Patent: December 26, 2006Assignee: Seiko Epson CorporationInventors: Hiroaki Segawa, Tsuyoshi Sano
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Patent number: 7094824Abstract: The present invention discloses a rubbery polymer having improved properties, which is comprised of repeat units which are comprised of (a) butyl acrylate, or optionally a mixture of butyl acrylate and 2-ethylhexyl acrylate containing up to about 40 percent 2-ethylhexyl acrylate, (b) at least one member selected from the group consisting of methyl methacrylate, ethyl methacrylate, methyl acrylate, and ethyl acrylate, (c) optionally, about 0% to about 40% of an alkoxy ethyl acrylate or an alkoxy ethyl methacrylate, (d) acrylonitrile, (e) styrene, and (f) a crosslinking agent; wherein about 1% to about 10% of a monomer containing reactive cure sites selected from the group consisting of hydroxyl groups, glycidyl groups, carboxylic acid groups, and unsaturated cure sites is incorporated into the rubbery polymer.Type: GrantFiled: June 3, 2005Date of Patent: August 22, 2006Assignee: Eliokem S.A.S.Inventor: Hung Dang Ngoc
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Patent number: 7091271Abstract: A nanocomposite optical plastic article has a plastic host material with a temperature sensitive optical vector (x) and a core shell nanoparticulate material dispersed into the plastic host material. The core shell nanoparticulate material is characterized by a core defined by a nanoparticulate material which has a temperature sensitive optical vector (x1) and a shell defined by a coating material layer coated onto the core. It is important to the invention that temperature sensitive vector (x1) is directionally opposed to the temperature sensitive optical vector (x) and nshell<nplastic host<ncore.Type: GrantFiled: August 18, 2003Date of Patent: August 15, 2006Assignee: Eastman Kodak CompanyInventors: Robert O. James, Lawrence A. Rowley, Daniel F. Hurley, John Border
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Patent number: 7070865Abstract: A coating composition for the linerboard of corrugated paperboard provides water and grease resistance but is water vapor permeable, and thus permits a different mode of manufacture of corrugated paperboard when aqueous adhesives are employed in the assembly of the linerboards and corrugated medium; in particular the linerboards may be coated with the coating composition prior to assembly of the corrugated paperboard because the water vapor permeable coating permits escape of the water of the aqueous adhesive, during drying of the assembled components of the corrugated paperboard; the coating composition employs a styrene-acrylate copolymer and a C14-C18 fatty acid complex of a metal ion having an oxidation state of at least 3, such as chromium.Type: GrantFiled: January 27, 2003Date of Patent: July 4, 2006Assignee: Le Groupe Recherche I.D. Inc.Inventor: Serge Berube
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Patent number: 7066590Abstract: Combinations of cationic underprinting fluids and anionic ink compositions that together achieve improved color quality and image stability in ink-jet printed images.Type: GrantFiled: April 1, 2004Date of Patent: June 27, 2006Assignee: Hewlett-Packard Development Company, L.P.Inventors: Shirley Lee, Gary W. Byers, Alexey S Kabalnov, Mark H. Kowalski, Amiya K. Chatterjee, Keshava A Prasad, David M. Schut
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Patent number: 7067577Abstract: The present invention relates to a resin composition comprising a resin and apatite, wherein referring to the particulate form of said apatite present in the resin composition thus obtained, the apatite is present in a particulate form having an average diameter or average thickness (d) of not greater than 100 nm and an average aspect ratio (L/D) of not smaller than 5 as defined by the ratio of the average length (L) to said average diameter or average thickness (d).Type: GrantFiled: October 4, 2001Date of Patent: June 27, 2006Assignee: Asahi Kasei Kabushiki KaishaInventors: Masaaki Aramaki, Kenya Sonobe
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Patent number: 7045569Abstract: An optical nanocomposite material has a nanoparticulate filler dispersed in a host plastic material. According to the method of making the nanocomposite material, a predetermined temperature sensitive optical vector, such as refractive index, of the plastic host material and nanoparticulate filler are directionally opposed resulting in a nanocomposite material having significantly improved stability of the refractive index with respect to temperature.Type: GrantFiled: April 5, 2002Date of Patent: May 16, 2006Assignee: Eastman Kodak CompanyInventors: John Border, Michael R. McGovern
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Patent number: 7030175Abstract: Latex particles having a reacttive surfactant covalently bonded to the latex particle surface are provided. The latex particles exhibit shear stability and accurate drop placement on printed media when used in ink jet inks and in high speed ink jet printers. A latex particle is also provided having a reactive surfactant covalently bonded to the surface of the latex particle, where the latex particle has a bulk density from 0.90 g/cm3 to 1.10 g/cm3 and a surface dielectric constant from 2.0 to 3.0. An ink-jet ink is provided that can comprise effective amounts of an ink vehicle, a colorant admixed in the ink vehicle, latex particles dispersed in the ink vehicle, and a reactive surfactant covalently bonded to the surface of the latex particles.Type: GrantFiled: February 6, 2003Date of Patent: April 18, 2006Assignee: Hewlett-Packard Development Company, L.P.Inventors: Kent Vincent, Sivapackia Ganapathiappan
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Patent number: 7018453Abstract: A web offset heatset printing ink composition having less than about 2 wt. % of volatile organic compounds containing an aqueous polymer latex dispersed in an ink base of a resin, a non-volatile plasticizer, and a pigment and method for preparing same.Type: GrantFiled: December 31, 2003Date of Patent: March 28, 2006Assignee: Sun Chemical CorporationInventors: David Klein, Gary F. Dandreaux, Richard R. Durand, Jr., Thierry Frinault, Kenneth Smith
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Patent number: 7014909Abstract: Volatile organic compounds containing carbonyl groups can be released by lithographic printing materials including inks, fountain solutions and printed materials. Volatile organic compounds containing carbonyl groups can also have a serious negative impact on the taste or odor of staple materials such as foodstuffs. The volatile materials can be retained in the lithographic compositions and printed materials can be trapped in the printed materials using an improved reactive technology involving a chemically reactive trap for such volatile carbonyl containing compounds.Type: GrantFiled: February 9, 2004Date of Patent: March 21, 2006Assignees: Graphic Packaging Corporation, Cellresin Technologies, LLCInventors: Boris Vasilyevich Rozynov, William J. Coyle, Willard E. Wood, Neil J. Beaverson
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Patent number: 6984686Abstract: The present invention discloses a rubbery polymer having improved properties, which is comprised of repeat units which are comprised of (a) butyl acrylate, or optionally a mixture of butyl acrylate and 2-ethylhexyl acrylate containing up to about 40 percent 2-ethylhexyl acrylate, (b) at least one member selected from the group consisting of methyl methacrylate, ethyl methacrylate, methyl acrylate, and ethyl acrylate, (c) optionally, about 0% to about 40% of an alkoxy ethyl acrylate or an alkoxy ethyl methacrylate, (d) acrylonitrile, (e) styrene, and (f) a crosslinking agent; wherein about 1% to about 10% of a monomer containing reactive cure sites selected from the group consisting of hydroxyl groups, glycidyl groups, carboxylic acid groups, and unsaturated cure sites is incorporated into the rubbery polymer.Type: GrantFiled: December 18, 2003Date of Patent: January 10, 2006Assignee: Eliokem S.A.S.Inventor: Hung Dang Ngoc
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Patent number: 6953613Abstract: A pigment-based ink jet ink set and image-recording element combination is described, wherein the ink jet image-recording element has a gloss value of at least 5 when measured at 60°, and wherein each ink in the ink set has a normalized differential specular reflectance, N?RS(X), of less than 1.25. N?RS(X) is defined as the maximum value within a set of N?RS(Xn) values in which each N?RS(Xn) is the normalized specular reflectance for a density patch of a printed test image. The printed test image consists of a series of at least eleven density patches printed such that the ink laydown of the patches increases incrementally, from no ink laydown to a maximum level generating a density of at least 1.Type: GrantFiled: November 19, 2002Date of Patent: October 11, 2005Assignee: Eastman Kodak CompanyInventors: Richard C. Reem, Karen J. Klingman
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Patent number: 6894103Abstract: This invention relates to a carbon black modified by a two step process in which carbon black is initially treated with functional monomers by an electropolymerization process to form a functionalized carbon black having an initial polymer attached to, of grafted to, the carbon black following which (A) at least one diene monomer, or (B) living anionic catalysis prepared polymer, is introduced to the functionalized carbon black to continue the polymerization, starting from a living end of the initially formed polymer, and thereby form an extended diene-based polymer. By the addition of the diene monomer or the live anionic polymer to form the associated extended diene-based polymer, it is contemplated that the modified carbon black is rendered more compatible with diene-based elastomers. Such modified carbon black may be used, for example, as reinforcement for component(s) of various articles of manufacture, including tires.Type: GrantFiled: November 22, 2002Date of Patent: May 17, 2005Assignee: The Goodyear Tire & Rubber CompanyInventors: Thierry Florent Edme Materne, Giorgio Agostini
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Patent number: 6890972Abstract: At least one embodiment of the present invention relates to an erasable ink composition particularly useful in a writing instrument for simultaneous the appearance of a graphite pencil. The composition of the present invention comprises a solvent system, a rubber and a pigment. The solvent system used in the present invention comprises an organic ester and a component selected from the group consisting of an optionally substituted cycloalkane, an optionally substituted cycloalkanone, an optionally substituted cycloalkene, or mixtures thereof. A sufficient amount of the solvent system is present so that the erasable ink composition will flow in a writing instrument. Finally, the erasable ink composition optionally includes a plasticizer, a liquid butene, or one or more additives selected from the group consisting of a corrosion inhibitor, a flow enhancing compound, and mixtures thereof.Type: GrantFiled: January 9, 2003Date of Patent: May 10, 2005Assignee: Advance Watch Company, Ltd.Inventors: Barry Rosenbaum, Frances Fesuk
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Patent number: 6875804Abstract: The syndiotactic polystirene resin composition according to the present invention is superior in compatibility between a syndiotactic polystyrene and a rubber component and mechanical properties such as impact strength, in which a syndiotactic polystyrene-maleic anhydride (sPS-MA) and a hydrogenated styrene/butadiene/styrene-maleic anhydride (SEBS-MA) are employed as compatibilizers and a diamine compound is added as a coupling agent. The compatibilizers and coupling agents improve polarity of both the syndiotactic polystyrene and the rubber component and impact strength of the syndiotactic polystyrene composition.Type: GrantFiled: December 18, 2000Date of Patent: April 5, 2005Assignee: Samsung Atofina Co., Inc.Inventors: Xuequan Zhang, Jae Gon Lim
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Patent number: 6875809Abstract: Volatile organic compounds containing carbonyl groups can be released by lithographic printing materials including inks, fountain solutions and printed materials. Volatile organic compounds containing carbonyl groups can also have a serious negative impact on the taste or odor of staple materials such as foodstuffs. The volatile materials can be retained in the lithographic compositions and printed materials can be trapped in the printed materials using an improved reactive technology involving a chemically reactive trap for such volatile carbonyl containing compounds.Type: GrantFiled: May 25, 2001Date of Patent: April 5, 2005Assignees: Cellresin Technologies, LLC, Graphic Packaging International, Inc.Inventors: Boris Vasilyevich Rozynov, William J. Coyle, Willard E. Wood, Neil J. Beaverson
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Patent number: 6875798Abstract: There is provided a water based ink capable of decolorizing or discoloring written or printed letters or images through an organic solvent or heating, which is used for a writing instrument such as roller balls, makers, etc., printing inks, ink jets and the like. The water based ink comprises a colorant consisting of spherical fine grains colored by a color former, the spherical fine grains consisting of at least one member selected from polyolefins and other polymers containing, as a constitutional unit, at least one monomer selected from the group consisting of acrylonitrile, styrene, acrylic acid, methacrylic acid, methyl acrylate and methyl methacrylate.Type: GrantFiled: October 23, 2001Date of Patent: April 5, 2005Assignee: Zebra Co., Ltd.Inventors: Satoru Yui, Naoki Sakurai, Koichi Ito
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Patent number: 6872773Abstract: A readily water-redispersible and water-wettable polymer powder is prepared by spray-drying of an aqueous dispersion of polymer particles with admixing of a hydrophilic and of a hydrophobic antiblocking agent.Type: GrantFiled: April 2, 2004Date of Patent: March 29, 2005Assignee: BASF AktiengesellschaftInventors: Joachim Pakusch, Ines Pietsch, Hans-Jürgen Denu, Heinrich Sack, Bernd Reck
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Patent number: 6867255Abstract: A nanocomposite made with an inorganic layered material and a star-shaped polystyrene that can be blended with normal linear polystyrene is disclosed. The inorganic layered material can have an exfoliated structure, substantially exfoliated, or intercalated structure. The exfoliated structure can result in significantly improved physical properties, even with only a very low content of clay. The invention is also directed to a process that can be used to make the compositions of the present invention. In one embodiment, a physical mixture of clay and star polymer is prepared and then the mixture is heated for several hours, preferably under high-shear mixing, to increase the rate of exfoliation, after which mostly inexpensive commodity linear polystyrene polymer completes the composition.Type: GrantFiled: October 3, 2003Date of Patent: March 15, 2005Assignee: Eastman Kodak CompanyInventors: Douglas R. Robello, Nori Yamaguchi, Thomas N. Blanton, Craig L. Barnes
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Patent number: 6852821Abstract: Aqueous primary dispersions and coating materials comprising dispersed and/or emulsified, solid and/or liquid polymer particles and/or dispersed solid core-shell particles having a diameter?500 nm preparable by controlled free-radical microemulsion or miniemulsion polymerization of A) at least one olefinically unsaturated monomer and B) at least one olefinically unsaturated monomer which is different than the olefinically unsaturated monomer (A) and has the general formula I: R1R2C?CR3R4 (I), in which the radicals R1, R2, R3 and R4 independently of one another are hydrogen atoms or substituted or unsubstituted alkyl, cycloalkyl, alkylcycloalkyl, cycloalkylalkyl, aryl, alkylaryl, cycloalkylaryl, arylalkyl or arylcycloalkyl radicals, with the proviso that at least two of the variables R1, R2, R3 and R4 are substituted or unsubstituted aryl, arylalkyl or arylcycloalkyl radicals, especially substituted or unsubstituted aryl radicals; and also their use.Type: GrantFiled: November 8, 2000Date of Patent: February 8, 2005Assignee: BASF Coatings AGInventors: Maximilian Bendix, Wolfgang Bremser, David Christie
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Patent number: 6852777Abstract: A water-based ink for inkjet printing comprising a water dispersion of vinyl polymer particles prepared by containing a pigment in a vinyl polymer prepared by copolymerizing a monomer mixture comprising (a) a salt-forming group-containing monomer, (b) a macromer, and (c) a monomer copolymerizable with the salt-forming group-containing monomer and the macromer; and a process for preparing a water-based ink for inkjet printing comprising a water dispersion of vinyl polymer particles prepared by containing a pigment in a vinyl polymer, comprising dissolving in an organic solvent a vinyl polymer prepared by copolymerizing a monomer mixture comprising (a) a salt-forming group-containing monomer, (b) a macromer, and (c) a monomer copolymerizable with the salt-forming group-containing monomer and the macromer; adding a pigment to the resulting solution; pre-kneading the mixture; thereafter adding a neutralizing agent and water and kneading the mixture, to give an oil-in-water dispersion; and distilling off the organType: GrantFiled: December 28, 1999Date of Patent: February 8, 2005Assignee: Kao CorporationInventors: Yukihiro Nakano, Isao Tsuru, Kohji Azuma, Michitaka Sawada, Takehiro Tsutsumi
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Patent number: 6843939Abstract: This invention relates to an UV stabilizing additive composition comprising an ortho-hydroxy triazine compound, a hindered hydroxybenzoate compound and optionally a hindered amine compound. This additive composition may be used to stabilize materials from UV radiation. This invention also contemplates a method of stabilizing a material by contacting the material with the UV stabilizing additive composition.Type: GrantFiled: December 10, 2002Date of Patent: January 18, 2005Assignee: Cytec Technology Corp.Inventors: Joseph A. Stretanski, Brent M. Sanders
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Patent number: 6841595Abstract: Process for the preparation of protective colloid-stabilized, emulsifier-free, aqueous dispersions based on at least two monomers selected from vinylaromatics, 1,3-dienes and/or (meth)acrylates, in the presence of assistants and, if required, further comonomers in an amount of from 0.1% by weight to 20% by weight, based on the total amount of monomers, wherein at least 10% by weight of the total amount of water are added to the reaction vessel only after the monomers have been added to the reaction vessel and the conversion is at least 40%, based on 100% of the monomers.Type: GrantFiled: July 3, 2002Date of Patent: January 11, 2005Assignee: PolymerLatex GmbH & Co. KGInventors: Davide Brizzolara, Herbert Vorholt
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Patent number: 6818692Abstract: This invention pertains to rubber cement compositions containing a rubber elastomer, a tackifier, and an organic solvent that is not a hazardous air pollutant (HAP). This invention also includes the method of making this rubber cement composition and of using this adhesive to bond to surfaces together.Type: GrantFiled: September 4, 2002Date of Patent: November 16, 2004Assignee: W. W. Henry CompanyInventors: John W. Bulluck, Holly McKee
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Patent number: 6800682Abstract: A gluing, sealing and coating compound based on a styrene copolymer is characterized in that the styrene copolymer mainly contains styrene and in that it contains an aromatic compound-free polyalkylene oxide and/or its fatty derivative. These non-toxic plastcizers are easily tolerated and increase stickiness, elasticity and stretchability. These compounds are therefore suitable as binders for producing glues, coatings and sealing compounds.Type: GrantFiled: December 15, 1997Date of Patent: October 5, 2004Assignee: Henkel Kommanditgesellschaft auf Aktien (Henkel KGaA)Inventors: Udo Windhoevel, Hartmut Urbath, Helmuth Loth, Wolfgang Klauck, Johann Klein, Kai Boege
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Patent number: 6797769Abstract: An electrodepositing solution for low-potential electrodeposition is disclosed which is used in an electrodeposition method and a photoelectrodeposition method and which can improve the film formability under the application of a low voltage, suppress the elution of metal ions and stably form by deposition an electrodeposition film having a uniform thickness, a uniform color density and a smooth surface. The electrodepositing solution permits an electrodeposition film of an electrodeposition material to be formed by deposition on a conductive material upon application of a voltage between the conductive material and a counter electrode. The electrodeposition material contains an electropositive polymer material which contains, as at least one component thereof, a copolymer consisting of a hydrophobic monomer, a hydrophilic monomer and a plastic monomer.Type: GrantFiled: September 20, 2001Date of Patent: September 28, 2004Assignee: Fuji Xerox Co., Ltd.Inventors: Eiichi Akutsu, Yasunari Nishikata, Shigemi Ohtsu, Keishi Shimizu, Kazutoshi Yatsuda
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Patent number: 6797745Abstract: Disclosed is an ink composition comprising (a) a styrene polymer or terpene polymer hardening component, (b) a nonpolymeric aromatic viscosity modifier, (c) a colorant, (d) an optional nonpolymeric aromatic ink vehicle, (e) an optional colorant dispersing agent, (f) an optional conductivity enhancing agent, (g) an optional antioxidant, and (h) an optional UV absorber.Type: GrantFiled: September 23, 1999Date of Patent: September 28, 2004Assignee: Xerox CorporationInventor: Shadi L. Malhotra
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Patent number: 6790909Abstract: The invention relates to a process for preparing a reaction product (RP) which is functionalized by groups containing halogen or sulfonyl chloride by reaction of at least one free-radically polymerizable monomer, at least one compound of the formula (I), at least one free-radical initiator and at least one free-radically polymerizable monomer containing halogen or sulfonyl chloride groups under free-radical conditions, and to a reaction product (RP) which can be prepared by the process of the present invention and to the use of the reaction product (RP) as macroinitiator for the preparation of graft copolymers. Furthermore the invention relates to a process for preparing graft copolymers by reaction of the reaction product (RP) with at least one suitable monomer and to graft copolymers which can be prepared by the process of the present invention and also to the use of the graft copolymers of the present invention.Type: GrantFiled: July 14, 2003Date of Patent: September 14, 2004Assignee: BASF AktiengesellschaftInventors: Yvonne Heischkel, Nicolas Stöckel, Philipp Wieland, Marcus Schäfer, Oskar Nuyken
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Publication number: 20040171743Abstract: Novel compositions and methods of using those compositions to form metal oxide films or coatings are provided. The compositions comprise an organometallic oligomer and an organic polymer or oligomer dispersed or dissolved in a solvent system. The compositions have long shelf lives and can be prepared by easy and reliable preparation procedures. The compositions can be cured to cause conversion of the composition into films of metal oxide interdispersed with organic polymer or oligomer. The cured films have high refractive indices, high optical clarities, and good mechanical stabilities at film thicknesses of greater than about 1 &mgr;m.Type: ApplicationFiled: January 15, 2004Publication date: September 2, 2004Applicant: Terry Brewer, Ph.D.Inventors: Tony D. Flaim, Yubao Wang, Ramil-Marcelo L. Mercado
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Patent number: 6784225Abstract: An improved enhancer formulation for use in forming precision molded articles from a furnace process is disclosed wherein an organometallic zirconia coupling agent is used in conjunction with a polymer in solvent to inhibit the bleed-through of infiltrant metal in a finished part formed in a single-step furnace process.Type: GrantFiled: November 9, 2001Date of Patent: August 31, 2004Assignee: 3D Systems, Inc.Inventor: Kris Alan Schmidt
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Patent number: 6774161Abstract: Particulate materials are cold molded by preheating a binder and the material to be bound to a temperature of from 160 to 240° C., and then press molding at a temperature less than 80° C. and at a pressure of from 1 to 120 bar to give a molding, wherein the binder contains a polymer powder or aqueous polymer dispersion thereof, the polymer having a glass transition temperature Tg greater than 80° C. and a complex viscosity less than 15,000 Pa·s at 190° C., and derived from one or more comonomer units from the group of vinyl esters of optionally branched C1-18 alkylcarboxylic acids, (meth)acrylic esters of optionally branched C1-15 alcohols, dienes, olefins, vinylaromatics, and vinyl halides. The moldings exhibit excellent properties including resistance to sagging at elevated temperatures, and are recyclable.Type: GrantFiled: January 30, 2003Date of Patent: August 10, 2004Assignee: Wacker Polymer Systems GmbH & Co. KGInventors: Abdulmajid Hashemzadeh, Klaus Kohlhammer, Thomas Lehmann, Peter Weiler
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Patent number: 6770706Abstract: An aqueous polymer adhesive is provided containing styrene polymers or styrene copolymers with alkyl acrylate acid/or alkyl methacrylates and a thickener system containing an inorganic thickener and an aqueous dispersion of an acrylic acid/acrylamide copolymer which can be partially replaced by a dispersion of a (co)polymer containing acrylate residues, a dispersion of a (co)polymer containing acrylic acid residues and methacrylic acid residues and polyarethanes. The adhesive has a high initial strength and can be in layers up to 30 mm thick.Type: GrantFiled: October 1, 2002Date of Patent: August 3, 2004Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Anke Lewin, Wolfgang Klauck, Gaby Schilling, Martin Majolo
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Patent number: 6762240Abstract: A latex emulsion that includes crosslinked polymeric microparticles dispersed in an aqueous continuous phase. The microparticles are prepared from a monomer mix of a crosslinking monomer, a monomer having hydrophilic functional groups, and one or more other monomers. Also disclosed is a thermosetting composition that includes a first reactant that has reactive functional groups; a curing agent that has at least two functional groups reactive with the functional groups of the first reactant; and the latex emulsion of crosslinked polymeric microparticles dispersed in an aqueous continuous phase. The thermosetting composition may be used to coat a substrate. The coating may be a multi-layer composite coating that includes a base coat layer deposited from a pigmented film-forming base coat composition containing the thermosetting composition; and a substantially pigment free top coat layer deposited over a portion of the base coat layer from a substantially pigment free top coat composition.Type: GrantFiled: April 19, 2002Date of Patent: July 13, 2004Assignee: PPG Industries Ohio, Inc.Inventors: Shanti Swarup, Brian Endlich, M. Frank Haley, Charles M. Kania, Kurt G. Olson, Edward S. Pagac, Kaliappa G. Ragunathan
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Patent number: 6759455Abstract: This invention discloses a resin which is particularly useful in making paraffinic solvent based paints, said resin being comprised of repeat units which are derived from (a) about 5 to about 60 weight percent tertiary-butyl cyclohexyl methacrylate, (b) 0 to about 40 weight percent vinyl aromatic monomers, (c) about 20 to about 80 weight percent alkyl methacrylate monomers, and (d) about 1 to about 30 weight percent alkyl acrylate monomers. These resins exhibit good hardness and excellent resistance to ultraviolet light. More importantly, coatings made with these resins are highly resistant to yellowing and discoloration on exposure to ultra-violet light over long periods of time.Type: GrantFiled: February 13, 2001Date of Patent: July 6, 2004Inventor: Serge Magnet
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Publication number: 20040106725Abstract: A polystyrene seed latex composition is provided having a total emulsion polymer content of from 0.2 to 2.0 weight percent and a particle diameter less than 150 Å. The seed latex is produced on a continuous basis by feeding to a continuous stirred reactor an emulsion stream and initiator stream. The feed streams are mixed in the stirred reactor at room temperature to produce the seed latex. Preferably, the initiator stream comprises a sodium formaldehyde sulfoxylate reducing agent. The amount of initiator charged into the continuous seed reactor is sufficient to complete both the seed and a subsequent continuous latex polymerization reaction.Type: ApplicationFiled: May 8, 2001Publication date: June 3, 2004Applicant: BASF AGInventors: Jonathan P. Antonucci, Michael A. Taylor, Koichi Takamura, Robert Racz
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Patent number: 6743835Abstract: The invention relates to a process for preparing nondusting free-flowing pigment concentrates with removal of the water from pigment suspensions comprising polymers and dispersants in a fluidized bed drier. The resulting bead-form pigment concentrates are nondusting and readily free-flowing. The invention further embraces the use of pigment concentrates prepared in this way for coloring plastics and polymers.Type: GrantFiled: December 5, 2001Date of Patent: June 1, 2004Assignee: Goldschmidt AGInventors: Werner Schäfer, Manfred Scheiba, Stefan Stadtmüller, Markus Weimann, Karlheinz Rümpler, Ulrich Walter
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Patent number: 6737468Abstract: The use of a copolymer (A) preparable by free-radical polymerization of a) at least one olefinically unsaturated monomer and b) at least one olefinically unsaturated monomer different than the olefinically unsaturated monomer (a) and of the general formula I R1R2C=CR3R4 (I), in which the radicals R1, R2, R3 and R4 each independently of one another are hydrogen atoms or substituted or unsubstituted alkyl, cycloalkyl, alkylcycloalkyl, cycloalkylalkyl, aryl, alkylaryl, cycloalkylaryl, arylalkyl or arylcycloalkyl radicals, with the proviso that at least two of the variables R1, R2, R3 and R4 are substituted or unsubstituted aryl, arylalkyl or arylcycloalkyl radicals, especially substituted or unsubstituted aryl radicals, in an aqueous medium, in a basecoat material used to produce color and/or effect basecoats BL and multicoat color and/or effect coating systems ML.Type: GrantFiled: January 11, 2002Date of Patent: May 18, 2004Assignee: BASF Coatings AGInventor: Wolfgang Bremser
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Patent number: 6727316Abstract: The use of a copolymer (A) preparable by free-radical polymerization of a) at least one olefinically unsaturated monomer and b) at least one olefinically unsaturated monomer different than the olefinically unsaturated monomer (a) and of the general formula I R1R2C═CR3R4 (I), in which the radicals R1, R2, R3 and R4 each independently of one another are hydrogen atoms or substituted or unsubstituted alkyl, cycloalkyl, alkylcycloalkyl, cycloalkylalkyl, aryl, alkylaryl, cycloalkylaryl, arylalkyl or arylcycloalkyl radicals, with the proviso that at least two of the variables R1, R2, R3 and R4 are substituted or unsubstituted aryl, arylalkyl or arylcycloalkyl radicals, especially substituted or unsubstituted aryl radicals; in an aqueous medium, in a coating material used to produce surfacer coats and antistonechip primer coats.Type: GrantFiled: December 13, 2001Date of Patent: April 27, 2004Assignee: BASF Coatings AGInventor: Wolfgang Bremser
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Patent number: 6723772Abstract: The present invention provides a resin composition comprising 100 parts by weight of a methyl methacrylate resin or styrene resin, about 0.1 to about 20 parts by weight of a light diffusing agent, about 0.0005 to about 0.1 parts by weight of an ultraviolet absorber selected from the group consisting of 2-(1-arylalkylidene) malonates and oxalanilides, and about 0.0001 to about 0.01 parts by weight of a phosphor. This resin composition is used as a material of a light diffusing member showing excellent light diffusible transmittance, having excellent durability and manifesting suppressed yellowing of transmitted light. Further, a laminated plate obtained using this resin composition is suitably used as a lighting cover, light diffusing plate for liquid crystal displays, illumination sign board or the like for which light transmittance and light diffusing property are required and durability is desired.Type: GrantFiled: July 9, 2002Date of Patent: April 20, 2004Assignee: Sumitomo Chemical Company, LimitedInventor: Tomohiro Maekawa
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Publication number: 20040069184Abstract: A marking composition is disclosed for placing a temporarily visible mark on a surface. The composition includes a paint base and a pigmented colorant. The pigmented colorant is dispersed within the paint base, and has characteristics that cause the mark to progressively become substantially invisible upon exposure to UV light. Additives, such as UV absorbers and anti-oxidants may be included to alter the rate at which the mark becomes invisible. The pigmented colorant may be a dispersion of dyed melamine-toluenesulfonamide-formaldehyde polymer in a mixture of alkyl based resins and aliphatic hydrocarbons. The colorant may be about 2 to 30 parts by weight of the composition. In one embodiment, the pigmented colorant is a Special Fugitive Colorant, with a color selected from the group consisting of: Special Fugitive Yellow Dispersion, No. 121M6669; Special Fugitive Orange Dispersion, No. 121M6665; Special Fugitive Red Dispersion, No. 121M6850; Special Fugitive Red Dispersion; No.Type: ApplicationFiled: September 17, 2003Publication date: April 15, 2004Inventors: Neil S. Fox, Christopher P. Finke
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Patent number: 6710118Abstract: An aqueous polymer dispersion whose polymer, present in disperse distribution, is composed in free-radically polymerized form of from 20 to 65% by weight of at least one vinylaromatic monomer (monomers A), from 30 to 75% by weight of at least one monomer having two conjugated, ethylenically unsaturated double bonds (monomers B), and from 0.5 to 10% by weight of at least one other monomer, C, selected from the group consisting of &agr;,&bgr;-monoethyienically unsaturated mono- and dicarboxylic acids and amide or ester derivatives thereof and whose alkali metal ion content GA, based on the mass of the dispersed polymer, is ≧0.5% by weight, the pH of the aqueous dispersion medium being adjusted to a value below 6.Type: GrantFiled: November 6, 2002Date of Patent: March 23, 2004Assignee: BASF AktiengesellschaftInventors: Markus Koppers, Marco Schmidt, Thomas Anselmann, Jürgen Schmidt-Thümmes, Mike Zott, Eckehardt Wistuba
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Publication number: 20040039127Abstract: An electronic device for high frequency signals having a small dielectric loss and high efficiency is provided which has a low dielectric loss tangent resin composition for coping with high frequency signals as an insulating layer.Type: ApplicationFiled: May 9, 2003Publication date: February 26, 2004Inventors: Satoru Amou, Akira Nagai, Shinji Yamada, Takao Ishikawa, Akio Takahashi
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Patent number: 6693146Abstract: Self crosslinking aqueous polymer dispersions containing hard and soft copolymers containing polymerized units of a conjugated diene, a vinyl aromatic compound, an organic carboxylic acid and/or anhydride, and at least one crosslinker may be included in consolidated nonwoven constructions. The consolidated nonwoven construction is useful as a base material such as a bituminized roofing mat.Type: GrantFiled: January 2, 2003Date of Patent: February 17, 2004Assignee: Polymerlatex GmbH & Co. KG.Inventors: Gunther Mueller, Helmut Daum, Willibald Scheda
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Patent number: 6689433Abstract: Ink-receiving print media products capable of producing high quality printed images which are light-fast, humid-fast, have low coalescence (graininess) levels, and are characterized by other beneficial attributes. The print media products have at least one ink-receiving layer supported by a substrate. The ink-receiving layer includes a binder blend designed to achieve the aforementioned goals, namely, gelatin, a poly(vinyl alcohol-polyethylene oxide) copolymer, and a poly((styrene)-(n-butyl acrylate)-(methyl methacrylate)-(2-(tert-butylamino) ethyl methacrylate)) copolymer. One or more optional pigments and/or additional binders can also be included within the ink-receiving layer. The ink-receiving layer may optionally be employed in combination with one or more additional material layers thereover or thereunder which can contain, for example, one or more pigments and/or binders.Type: GrantFiled: May 6, 2002Date of Patent: February 10, 2004Assignee: Hewlett-Packard Development Company, L.P.Inventors: Bor-Jiunn Niu, Stefan Schuttel, Meinrad Schaer
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Patent number: 6683126Abstract: The present invention provides a coating composition for producing difficult-to-wet surfaces, comprising i) at least one finely divided powder whose particles have a hydrophobic surface and a porous structure characterized by a BET surface area (determined in accordance with DIN 66131) of at least 1 m2/g, and ii) at least one film-forming binder characterized by a surface tension <50 mN/m, the weight ratio of powder to binder being at least 1:4. It also provides a process for producing difficult-to-wet surfaces, and provides for the use of the coating compositions for producing surfaces having a self-cleaning effect and for reducing the flow resistance for liquids in pipes.Type: GrantFiled: April 25, 2001Date of Patent: January 27, 2004Assignee: BASF AktiengesellschaftInventors: Harald Keller, Ingolf Kühn, Ekkehard Jahns, Christian Lach, Stephan Hüffer, Thilo Krebs, Yi Thomann, Thomas Frechen