Organic Nrm Additive Patents (Class 524/583)
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Publication number: 20100059178Abstract: An adhesive and method for hot melt application. The adhesive comprises polyolefin base polymer, from 1 to 10 wt % of at least one functionalized polyolefin, and from 1 to 15 wt % of a wax, based on the total weight of the polyolefin base polymer, functionalized polyolefin and wax, wherein the wax has a weight average molecular weight at least 8% of the weight average molecular weight of the polyolefin base polymer, viscosity at 190° C. of 60 mPa·s or more, and a crystallization temperature greater than the polyolefin base polymer and greater than 100° C., and wherein the adhesive has at least 5% fiber tear at 2° C., at least 50% fiber tear at 25° C., and a characteristic set time of less than 3 seconds.Type: ApplicationFiled: November 11, 2009Publication date: March 11, 2010Inventors: Peijun Jiang, George Rodriguez, Fran A. Shipley, Aspy K. Mehta
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Patent number: 7674869Abstract: A random copolymer having improved mechanical toughness and properties suitable for thin wall thermoforming applications is provided. The random copolymer exhibits the following physical properties: a flexural modulus profile having a 2% flexural modulus of about 168,000 psi, a 1% flexural modulus of about 190,000 psi, and a 0.4% flexural modulus of about 199,000 psi; a melt flow rate of at least about 2.0 g/10 min.; and a haze of less than about 40%. The random copolymer preferably comprises a copolymer of ethylene and propylene, wherein the ethylene content is in the range of from about 0.2% to about 0.8% ethylene by weight of the copolymer. The random copolymer also preferably includes a stabilizer and a clarifying agent such as a sorbitol based clarifier or a nucleator. Various articles of manufacture such as thermoformed containers and packaging may be formed from the random copolymer.Type: GrantFiled: December 7, 2004Date of Patent: March 9, 2010Assignee: Fina Technology, Inc.Inventors: Mike Musgrave, LuAnn Kelly, Peter Selg
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Patent number: 7659336Abstract: A blend of two different compounds may be applied together to form a nucleating agent additive composition. This additive composition is useful as an additive in thermoplastics, polyolefins and/or polymer resins. A blend of a bicyclo[2.2.1]heptane dicarboxylate salt and a dicarboxylate calcium metal salt provide useful and beneficial physical property effects in molded polymeric articles in terms of shrinkage and crystallization temperature of polymer resin compositions.Type: GrantFiled: September 29, 2006Date of Patent: February 9, 2010Assignee: Milliken & CompanyInventors: Weihua Sonya Wolters, Rob Hanssen, Thaneerpandal K. Palanisami, Darin L. Dotson
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Patent number: 7655723Abstract: A polypropylene material is provided having increased radiation resistance compared to solely isotactic polypropylene. The material is formed by utilizing a syndiotactic polypropylene. The isotactic polypropylene may be an isotactic metallocene or Ziegler-Natta catalyzed polypropylene and may include an amount of syndiotactic polypropylene. The material may be used in forming a variety of materials that may undergo exposure to radiation, such as sterilization procedures using radiation. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.Type: GrantFiled: May 2, 2007Date of Patent: February 2, 2010Assignee: Fina Technology, Inc.Inventor: Mike Musgrave
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Patent number: 7652093Abstract: The present invention relates to plasticized polyolefin compositions comprising a polyolefin and a non-functionalized hydrocarbon plasticizer.Type: GrantFiled: April 19, 2006Date of Patent: January 26, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Henry Wu-Hsiang Yang, Wen Li, Bruce R. Lundmark, Chon-Yie Lin, Chia Yung Cheng, Bryan R. Chapman, Petra Eiselt, Galina Ourieva, Manika Varma-Nair, James N. Coffey, Sandra Denise Schregenberger, David J. Lohse, Norman Yang, Jeffrey Theodore Zudock, Robert Jay Wittenbrink
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Patent number: 7652094Abstract: The present invention relates to plasticized polyolefin compositions comprising a polyolefin and a non-functionalized plasticizer; wherein the non-functionalized plasticizer may comprise C6 to C200 paraffins (including branched and normal paraffins) having a pour point of less than ?5° C. In one embodiment, the non-functionalized plasticizer is an isoparaffin comprising C6 to C25 isoparaffins. In another embodiment the non-functionalized plasticizer is a polyalphaolefin comprising C10 to C100 n-paraffins. The polyolefin may be a polypropylene homopolymer, copolymer, impact copolymer, or blends thereof, and may include a plastomer. Non-limiting examples of desirable article of manufacture made from compositions of the invention include films, tubes, pipes, sheets, fibers, woven and nonwoven fabrics, automotive components, furniture, sporting equipment, food storage containers, transparent and semi-transparent articles, toys, tubing and pipes, and medical devices.Type: GrantFiled: May 12, 2006Date of Patent: January 26, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Chon Yie Lin, Chia Yung Cheng, Henry Wu-Hsiang Yang
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Publication number: 20100004384Abstract: The propylene homopolymers and the polypropylene resin compositions containing the propylene homopolymers according to the present invention give molded articles excellent in vibration fatigue strength and creep properties. The molded articles are therefore suitably used as parts requiring reliability for a long period such as automotive parts and housing parts.Type: ApplicationFiled: January 17, 2008Publication date: January 7, 2010Inventors: Keita Itakura, Toshiyuki Ishii, Rikuo Onishi, Satoshi Hashizume
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Patent number: 7632887Abstract: The present invention relates to plasticized polyolefin compositions comprising a polyolefin and a non-functionalized plasticizer; wherein the non-functionalized plasticizer may comprise C6 to C200 paraffins (including branched and normal paraffins) having a pour point of less than ?5° C. In one embodiment, the non-functionalized plasticizer is an isoparaffin comprising C6 to C25 isoparaffins. In another embodiment the non-functionalized plasticizer is a polyalphaolefin comprising C10 to C100 n-paraffins. The polyolefin may be a polypropylene homopolymer, copolymer, impact copolymer, or blends thereof, and may include a plastomer. Non-limiting examples of desirable article of manufacture made from compositions of the invention include films, tubes, pipes, sheets, fibers, woven and nonwoven fabrics, automotive components, furniture, sporting equipment, food storage containers, transparent and semi-transparent articles, toys, tubing and pipes, and medical devices.Type: GrantFiled: August 4, 2003Date of Patent: December 15, 2009Assignee: ExxonMobil Chemical Patents Inc.Inventors: Chon Yie Lin, Chia Yung Cheng, Henry Wu-Hsiang Yang
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Patent number: 7632888Abstract: A feedstock concentrate material, including a first phase including fibers having a length greater than 5 mm; and a polymeric phase including a first polyolefin having a first melt flow rate; and a second polyolefin having a second melt flow rate. Kits, methods of using and resulting articles including the concentrate are also disclosed.Type: GrantFiled: August 16, 2007Date of Patent: December 15, 2009Assignee: Dow Global Technologies, Inc.Inventors: Jeroen Van Poucke, Herbert Engelen
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Publication number: 20090306281Abstract: Provided are adhesive compositions composed of a polyolefin composition comprising at least about 50 wt. % polypropylene and at least one wax. The polymer compositions have a Dot T-Peel of about 1 Newton or more, a branching index (g?) of 0.95 or less measured at the Mz of the polymer, a molecular weight of 100,000 or less, and the adhesive compositions has a fast set time. The packaging industry desires adhesive compositions having a fast set time, such as those setting in less than five seconds from a molten state at conventional packaging operating temperatures to a solid or quasi solid having favorable Dot T-Peel, set time, and or fiber tear adhesion properties. Polymer based adhesives performing within this window are a favorable alternative to conventional formulated adhesives. The provided adhesive compositions exhibit a favorable balance of properties such as high adhesive strength, wide temperature operating window, and fast set time.Type: ApplicationFiled: May 26, 2009Publication date: December 10, 2009Inventors: Jean M. Tancrede, Christopher L. Curry, David R. Johnsrud, George Rodriguez, Fran A. Shipley
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Patent number: 7622523Abstract: The present invention relates to radiation resistant plasticized polyolefin compositions comprising a polyolefin and a non-functionalized hydrocarbon plasticizer.Type: GrantFiled: February 9, 2005Date of Patent: November 24, 2009Assignee: ExxonMobil Chemical Patents Inc.Inventors: Wen Li, Chon Y. Lin, Bryan R. Chapman, Bruce R. Lundmark, David J. Lohse
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Patent number: 7619026Abstract: The present invention relates to plasticized polyolefin compositions comprising a polyolefin and a non-functionalized hydrocarbon plasticizer.Type: GrantFiled: August 12, 2003Date of Patent: November 17, 2009Assignee: ExxonMobil Chemical Patents Inc.Inventors: Henry Wu-Hsiang Yang, Wen Li, Bruce R. Lundmark, Chon-Yie Lin, Chia Yung Cheng, Bryan R. Chapman, Petra Eiselt, Galina Ourieva, Manika Varma-Nair, James N. Coffey, Sandra Denise Schregenberger, David J. Lohse, Norman Yang, Jeffrey Theodore Zudock, Robert Jay Wittenbrink
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Patent number: 7576146Abstract: Polymeric colored dispersant having the structure A-(B—X)n, where A is an organic chromophore; B is a covalently bonded linking moiety; X is a branched or linear C50-C200 polymeric covalently linked hydrocarbon, and n is an integer from 1 to 4, and low viscosity colorant dispersions containing same having a relative interfacial tension drop of less than about 1.5.Type: GrantFiled: December 5, 2003Date of Patent: August 18, 2009Assignee: Sun Chemical CorporationInventors: Gregory T. Huber, Tatiana N. Romanova, Russel J. Schwartz, Terence R. Chamberlain
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Publication number: 20090192482Abstract: The present invention relates to absorbent articles that include absorbent compositions which exhibit swelling, deswelling, and reswelling behavior. More specifically, absorbent compositions of this invention swell and absorb fluids after exposure to aqueous fluids, deswell and release fluids from the swollen absorbent compositions, and can also reswell and absorb fluids. The swelling-deswelling-reswelling behavior allows enhanced liquid distribution in absorbent composites and absorbent articles.Type: ApplicationFiled: June 30, 2008Publication date: July 30, 2009Inventors: Richard N. Dodge, II, Jian Qin, Scott J. Smith, Gonglu Tian, Yaru Shi
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Publication number: 20090171006Abstract: An object of the present invention is to provide an olefin-based thermoplastic elastomer composition that has both weatherability and flexibility at low temperatures, is excellent in fluidity, and causes no stickiness even in the use at high temperatures; a process oil composition for elastomers that serves as the raw material of the thermoplastic elastomer composition and contributes to the above characteristics; and an oil-extended elastomer containing the process oil composition. The process oil composition for elastomers of the present invention has a property that, when 20 parts by weight of the process oil composition for elastomers are blended with respect to 100 parts by weight of a propylene homopolymer, the melting point of the propylene homopolymer is lowered by 2 to 4.5° C. compared to that of the propylene homopolymer without blending.Type: ApplicationFiled: November 10, 2006Publication date: July 2, 2009Inventors: Yuichi Ito, Hidenari Nakahama, Kotaro Ichino
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Publication number: 20090171001Abstract: The present invention relates to articles made from plasticized polyolefin compositions comprising a polyolefin and a non-functionalized hydrocarbon plasticizer.Type: ApplicationFiled: February 25, 2009Publication date: July 2, 2009Inventors: Chon-Yie Lin, Wen Li, Bryan R. Chapman, Michael B. Kelly, Bruce R. Lundmark, David J. Lohse, Henry Wu-Hsiang Yang, Sandra Denise Schregenbeger
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Publication number: 20090130443Abstract: The present disclosure is directed generally to synthetic organic fiber pellets, methods for making such pellets, and methods of using such pellets for making fiber reinforced polypropylene composite resins. The synthetic organic fiber pellets include at least 80 wt % of a synthetic organic fiber chosen from polyalkylene terephthalates, polyalkylene naphthalates, polyamides, polyolefins, polyacrylonitrile, and combinations thereof, and from 2 to 20 wt % of one or more waxes. The synthetic organic fiber pellets are produced using a pelleting press process.Type: ApplicationFiled: November 14, 2008Publication date: May 21, 2009Inventor: Arnold Lustiger
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Patent number: 7531594Abstract: The present invention relates to articles made from plasticized polyolefin compositions comprising a polyolefin and a non-functionalized hydrocarbon plasticizer.Type: GrantFiled: February 19, 2004Date of Patent: May 12, 2009Assignee: ExxonMobil Chemical Patents Inc.Inventors: Chon-Yie Lin, Wen Li, Bryan R. Chapman, Michael B. Kelly, Bruce R. Lundmark, David J. Lohse, Henry Wu-Hsiang Yang, Sandra Denise Schregenberger
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Patent number: 7521104Abstract: Molding compositions made from a high-molecular-weight propylene polymer with a melt mass-flow rate MFR of from 0.3 to 1 g/10 min, to ISO 1133 at 230° C. and 5 kg, and with a proportion of ? modification crystallites in the range from 2 to 20% by weight. The molding compositions of the invention preferably comprise a quinarcidone pigment as nucleating agent. The high-molecular-weight propylene polymer used preferably comprises a high-molecular-weight propylene copolymer with up to 30% by weight of other copolymerized olefins having up to 10 carbon atoms. One of the uses of the molding compositions of the invention is as materials for pipes.Type: GrantFiled: December 19, 2003Date of Patent: April 21, 2009Assignee: Basell Poliolefine Italia s.r.l.Inventors: Volker Dolle, Thomas Böhm, Herbert Terwyen
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Publication number: 20090082521Abstract: Provided is a water dispersible polyolefin resin composition which is capable of forming a coating film having a smooth solidified surface when applied onto a substrate and which has excellent storage stability. The water dispersible polyolefin resin composition contains (C) a surfactant, (D) a water-soluble polymeric compound and (E) a water-insoluble organic solvent in amounts of 0.01 to 1.00 part by mass, 0.01 to 1.00 part by mass and 2 to 200 parts by mass, respectively, per 100 parts by mass of a combination of 5 to 70% by mass of (A) a poly(1-butene) resin having (i) a mesopentad fraction [mmmm] of 20 to 80 mole % and (ii) a weight average molecular weight (Mw) measured by gel permeation chromatography (GPC) of 10,000 to 1,000,000 or 5 to 70% by mass of (A?) polypropylene resin having (i) a mesopentad fraction [mmmm] of 20 to 60 mole % and (ii) an intrinsic viscosity [?] measured at 135° C. in tetralin of 0.1 to 15 dl/g with 95 to 30% by mass of (B) water.Type: ApplicationFiled: March 22, 2006Publication date: March 26, 2009Applicant: Idemitsu Kosan Co., Ltd.Inventors: Masami Kanamaru, Yutaka Minami
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Patent number: 7501462Abstract: Clarified polyolefins such as polypropylene are used widely to make polymer articles, containers, and the like. Such articles may be manufactured by the injection of molten polymer into a mold or forming device in manufacturing processes at high rates. A clarified composition is provided to achieve optimized clarity and organoleptic performance at lower processing temperatures and/or within a polypropylene resin having a higher melt flow rate.Type: GrantFiled: February 28, 2008Date of Patent: March 10, 2009Assignee: Milliken & CompanyInventors: Jiannong Xu, Xiaodong Edward Zhao, Jiang Li, Kemper David Lake, Jr.
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Patent number: 7494947Abstract: The polypropylene-based thermoplastic fibers are uniform in cross-section, not having any degraded surface skin, and they are heat-weldable at a pressure at a temperature which is lower than the melting temperature, by virtue of internal heating due to the effect of said pressure. They are made of a first constituent with high crystallinity and at least one second constituent, compatible with the first constituent, and of crystallinity that is lower than that of the first constituent. They have a quantity of primary oxidation inhibitor lying in the range 350 ppm to 1000 ppm. Such fibers are made by spinning under conditions that avoid molecular degradation by thermal oxidation at the periphery of the fibers, in particular with cooling that is rapid immediately on leaving the extrusion head. The non-woven fabric obtained by heat-bonding such fibers is characterized by weld points that are in the form of a polymer laminate that is uniform and transparent.Type: GrantFiled: November 5, 2002Date of Patent: February 24, 2009Assignee: ALBISInventor: Galliano Boscolo
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Patent number: 7482402Abstract: The present invention is directed generally to fiber reinforced polypropylene compositions, and the beneficial mechanical properties imparted by such compositions. The fiber reinforced polypropylene compositions include at least 25 wt % polypropylene based polymer, from 5 to 60 wt % organic fiber, and from 0 to 60 wt % inorganic filler. Lubricant may also be optionally incorporated into the composition. Articles molded from these fiber reinforced polypropylene compositions have a flexural modulus of at least 300,000 psi, and exhibit ductility during instrumented impact testing. The fiber reinforced polypropylene compositions of the present invention are particularly suitable for making molded articles including, but not limited to household appliances, automotive parts, and boat hulls.Type: GrantFiled: December 13, 2005Date of Patent: January 27, 2009Assignee: Exxonmobil Research and Engineering CompanyInventors: Arnold Lustiger, Jeffrey Valentage, Walter T. Matuszek
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Publication number: 20090012213Abstract: A composition for making a composite plastics material, comprising a polymer, wood fibre and microsilica. The microsilica, i.e., silica fume, is added for the purpose of reducing the water absorption while maintaining, or improving, the flame retardancy, mechanical performance and processibility of the material. The intended polymers for the composite materials are polyethylene (PE), polyvinylchloride (PVC), polypropylene (PP) or polyethylene terephthalate (PET). The composites can be shaped through extrusion or heat-moulding.Type: ApplicationFiled: February 27, 2006Publication date: January 8, 2009Applicant: ELKEM ASInventors: Gerd Schmaucks, Jan Olaf Roszinski
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Publication number: 20080306194Abstract: The present invention relates to a new type of polyolefin based hot-melt adhesive and methods for their production. More particularly, it relates to a new type of hot-melt adhesive comprising propylene co-polymers and possessing a favorable balance of cohesive strength, adhesion properties, and processibility, which render them especially well-suited for some hot-melt adhesive applications, for example, as elastic attachment adhesives.Type: ApplicationFiled: May 9, 2005Publication date: December 11, 2008Applicant: Huntsman Polymers CorporationInventors: Lixin Sun, Enrico L. Buenacosa, Jim Haselman
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Publication number: 20080275180Abstract: A polypropylene material is provided having increased radiation resistance compared to solely isotactic polypropylene. The material is formed by utilizing a syndiotactic polypropylene. The isotactic polypropylene may be an isotactic metallocene or Ziegler-Natta catalyzed polypropylene and may include an amount of syndiotactic polypropylene. The material may be used in forming a variety of materials that may undergo exposure to radiation, such as sterilization procedures using radiation. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.Type: ApplicationFiled: May 2, 2007Publication date: November 6, 2008Applicant: FINA TECHNOLOGY, INC.Inventor: Mike Musgrave
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Patent number: 7442742Abstract: A masterbatch composition is provided that includes a colorant, a thermoplastic carrier, a metallocene polymer processing aid, and optionally an additive. Also provided is a method for making a masterbatch composition and a method for making a colorized polymer.Type: GrantFiled: April 4, 2007Date of Patent: October 28, 2008Assignee: Carolina Color CorporationInventors: Jeffrey S. Smink, Ronald M. Harris, Robert R. Powers, Andrew J. Schwartz, Rick D. Martz
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Patent number: 7351758Abstract: Clarified polyolefins such as polypropylene are used widely to make polymer articles, containers, and the like. Such articles may be manufactured by the injection of molten polymer into a mold or forming device in manufacturing processes at high rates. A clarified composition is provided to achieve optimized clarity and organoleptic performance at lower processing temperatures and/or within a polypropylene resin having a higher melt flow rate.Type: GrantFiled: May 24, 2005Date of Patent: April 1, 2008Assignee: Milliken & CompanyInventors: Jiannong Xu, Xiaodong Edward Zhao, Jiang Li, Kemper David Lake, Jr.
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Publication number: 20080004384Abstract: Compositions comprising hexahydrophthalate (HHPA) metal salts may be useful as nucleating agents in polyolefins. Masterbatch compositions containing such salts and silica and/or hydrotalcite are particularly useful in reducing haze and improving properties of manufactured polyolefin articles or film. Such compositions may be dispersed effectively and efficiently into resin during manufacturing operations in the form of a masterbatch, thereby providing excellent polymer crystallization temperatures, improved polymer physical properties, improved dimensional stability, and improved transparency.Type: ApplicationFiled: July 3, 2006Publication date: January 3, 2008Inventors: Weihua Sonya Wolters, Kemper David Lake
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Patent number: 7291669Abstract: Polyolefin compositions comprising a particular hindered phenolic antioxidant selected from the group consisting of tris(3,5-di-tert-butyl-4-hydroxybenzyl)isocyanurate, 1,3,5-tris-(3,5-di -tert-butyl-4-hydroxybenzyl)-2,4,6-trimethylbenzene and the calcium salt of the monoethyl ester of 3,5-di-tert-butyl-4-hydroxybenzylphosphonic acid, an oligomeric sterically hindered amine light stabilizer, a hydroxylamine stabilizer or trialkylamine N-oxide stabilizer, and, optionally, an organic phosphorus stabilizer, are effectively stabilized against degradation upon melt processing, long term heat aging, and exposure to combustion products of natural gas.Type: GrantFiled: March 14, 2005Date of Patent: November 6, 2007Assignee: Ciba Specialty Chemicals CorporationInventors: James H. Botkin, Urs L. Stadler
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Patent number: 7244777Abstract: The present invention provides nucleated polyolefins using shellac based nucleating agents wherein the nucleated polyolefins obtained have improved crystallization temperature (Tc) and smaller spherulitic size and hence improved transparency characteristics.Type: GrantFiled: March 26, 2004Date of Patent: July 17, 2007Assignee: Council of Scientific and Industrial ResearchInventors: Subhash Pundlik Vernekar, Ramesh Chellaswamy, Swaminathan Sivaram
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Patent number: 7208536Abstract: The present invention provides a propylene resin composition having excellent anti-scratch characteristic. Specifically, provided is a polyolefin resin composition comprising a high crystalline polypropylene resin, a rubber component, an inorganic filler and an aluminosiloxane masterbatch, with excellent damage resistance such as anti-scratch characteristic thereby giving very low surface damage, excellent heat resistance, good rigidity and impact properties and injection moldability, for car interior or exterior parts.Type: GrantFiled: February 17, 2006Date of Patent: April 24, 2007Assignee: Samsung Total Petrochemicals Co., Ltd.Inventors: Jae Gon Lim, Young Sung Yoo, Jae Whan Cho, Man Saeng Her
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Patent number: 7192998Abstract: A process for producing olefin polymers, which comprises the steps of polymerizing an olefin monomer in a polymerization zone in the presence of a catalyst comprising a transition metal compound to form an olefin polymer, and adding at the end of or downstream from the polymerization zone a composition having a weight averaged molecular weight of at least 100 and containing a group R, a cation Y, an anionic group —C(R1)2—X?, and optionally a group —C(R1)2—X—H, the composition having a relative the composition having a relative mole fraction n of cations Y and a relative mole fraction m of group —C(R1)2—X—H, wherein 0<n?1, 0??m<1, and n+m=1. Use of such m=1. Use of such a composition for rendering inert undesired quantities of acidic compounds or halogen-containing compounds present in an olefin polymer by mixing the olefin polymer intimately with the additive composition.Type: GrantFiled: December 13, 2002Date of Patent: March 20, 2007Assignee: Dow Global Technologies Inc.Inventors: Pascal E. R. E. J. Lakeman, Johan A. Thoen
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Patent number: 7192909Abstract: The invention relates to the use of polyolefin waxes as external lubricants and release agents for plastics. Said polyolefin waxes are produced by using metallocene catalysts, whereby the polyolefin waxes are homopolymerizates of ethylene or are copolymerizates of ethylene with one or more 1-olefins, and linear or branched, substituted or non-substituted olefins having 3–18 C atoms are used as 1-olefins. The processable plastic mixtures produced in this manner have a distinctively longer tack-free time and exhibit an improved behavior with regard to mold release.Type: GrantFiled: March 14, 2001Date of Patent: March 20, 2007Assignee: Clariant Produkte (Deutschland) GmbHInventors: Eric Richter, Harald Kiesel
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Patent number: 7078450Abstract: Concentrates (also known as masterbatches) of certain bicyclic dicarboxylate salt thermoplastic nucleating additives in order to facilitate use thereof in typical thermoplastic manufacturing procedures are provided. Such nucleating additives have been found to impart high peak crystallization temperatures to thermoplastics (such as polypropylene, as one example); however, when combined in masterbatch form in the past such a nucleation property was sacrificed due to unforeseen problems associated with polymer-containing concentrates (i.e., pellets, for example) of such additives. Thus, improvements in masterbatching of these bicyclic dicarboxylate salt thermoplastic nucleators has been accomplished to the level necessary to allow for concentrate use with concomitant effective nucleation effects at the same level (if not in excess thereof) of the utilization of such a nucleator added in powder form.Type: GrantFiled: November 7, 2003Date of Patent: July 18, 2006Assignee: Milliken & CompanyInventors: Kemper David Lake, Jr., Bhavesh Chandrakant Gandhi
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Patent number: 7049361Abstract: The polyolefin [A] has a weight average molecular chain length of 2850 nm or longer and a density ?1 (g/cm3), the polyolefin wax [B] has a weight average molecular weight of 700–6000 and a density ?2 (g/cm3), the polyolefin and the polyolefin wax are incorporated at [A]/[B]=90/10–50/50 (ratio by weight), and the densities ?1 and ?2 satisfy the following conditions: 0.92??1?0.94, 0.91??2?0.93, ?0.03?(?1??2)?0.03.Type: GrantFiled: March 11, 2002Date of Patent: May 23, 2006Assignee: Sumitomo Chemical Company, LimitedInventors: Atsuhiro Takata, Ryuma Kuroda, Satoshi Hanada, Takeshi Yamada
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Patent number: 7041742Abstract: The present invention provides impact modified thermoplastic olefin (“TPO”) compositions that exhibit both stiffness and toughness. TPO compositions according to the invention include a polyolefin homopolymer resin such as polypropylene, from about 17% by weight to about 30% by weight of a rubbery copolymer comprising at least one alpha olefin, and from about 1.0% to about 8.0% by weight of a nonionic surfactant, which acts as an impact modifying fluid. The preferred nonionic surfactant for use in the invention is an ethoxylated sorbitan fatty acid ester such as ethoxylated sorbitan trioleate (“ESTO”).Type: GrantFiled: September 22, 2003Date of Patent: May 9, 2006Assignee: Ferro CorporationInventors: Ann M. Panek, Anna C. Andrews, Haleh Ayrom-Keuchel, Paul J. DeFranco, Robert J. Opalko
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Patent number: 7019055Abstract: A polymer of polyvinyl chloride, polyvinylidene chloride, polycarbonate, polyethylene, polypropylene, polyimide, polyester, or polyvinyl acetate contains about 0.005 to about 10 phr of a stabilizer to prevent discoloration due to oxidation, particularly gamma radiation.Type: GrantFiled: January 17, 2001Date of Patent: March 28, 2006Inventor: Qi Wang
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Patent number: 6995202Abstract: Concentrates (also known as masterbatches) of certain bicyclic dicarboxylate salt thermoplastic nucleating additives in order to facilitate use thereof in typical thermoplastic manufacturing procedures are provided. Such nucleating additives have been found to impart high peak crystallization temperatures to thermoplastics (such as polypropylene, as one example); however, when combined in masterbatch form in the past such a nucleation property was sacrificed to a certain extent due to unforeseen problems associated with polymer-containing concentrates (i.e., pellets, for example) of such additives. Thus, improvements in masterbatching of these bicyclic dicarboxylate salt thermoplastic nucleators have been accomplished to the level necessary to allow for concentrate use with concomitant effective nucleation effects at the same level (if not in excess thereof) of the utilization of such a nucleator mixed prior to melt-compounding with a target or resin or added directly into a molten resin (i.e.Type: GrantFiled: November 7, 2003Date of Patent: February 7, 2006Assignee: Milliken & CompanyInventors: Kemper David Lake, Jr., Bhavesh Chandrakant Gandhi
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Patent number: 6992128Abstract: The invention relates to a method for enhancing the fraction of ?-crystal modification in polypropylene by compounding nanocrystalline substances. A ?-fraction of 50–100% is achieved with said method. The compounds are characterized by improved mechanical properties. The nanocrystalline powders can be directly compounded and compatibilized with surface-active substances in the PP matrix for better dispersion.Type: GrantFiled: May 12, 2003Date of Patent: January 31, 2006Assignee: Treofan Germany GmbH & Co. KGInventors: Detlef Busch, Petra Häde, Bertram Schmitz
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Patent number: 6894093Abstract: The present invention describes plastic materials and food additives that are free or substantially free from endocrine disruptive chemicals. The plastic materials may be used in products which are exposed to individuals in which endocrine disruptive activity is particularly disadvantageous, such as baby bottles, baby toys, food containers, medical containers, animal cages and medical products. The food additives may be used in food products that are ingested by individuals in which endocrine disruptive activity is particularly disadvantageous, such as newborns or the physically infirm. The present invention also describes a series of assays which, when performed in combination, provide a novel method for determining the presence of endocrine disruptive activity.Type: GrantFiled: May 10, 2002Date of Patent: May 17, 2005Inventor: George D. Bittner
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Patent number: 6879861Abstract: A novel polymeric electrically insulating material that includes a linked voltage stabilizing agent. Also provided are methods of making the novel material and articles and devices that incorporate the novel material, particularly implantable medical devices.Type: GrantFiled: December 21, 2000Date of Patent: April 12, 2005Assignee: Medtronic, Inc.Inventors: Michael E. Benz, Mark A. Tapsak, Angela Pratt, Randall V. Sparer
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Patent number: 6855756Abstract: The present invention relates to a soft polypropylene resin having a melt index falling in a specific range, prepared by melting and kneading a substantial propylene homopolymer or a propylene copolymer composition each having specific properties in the presence of a radical-generating agent. According to the present invention, capable of being provided at a good productivity is a soft polypropylene resin which is useful as an alternative for a polyvinyl chloride resin in the fields of films, sheets, construction materials and the like and which is excellent in fluidity.Type: GrantFiled: October 19, 2001Date of Patent: February 15, 2005Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Shinichi Yukimasa, Masato Kijima
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Patent number: 6843939Abstract: This invention relates to an UV stabilizing additive composition comprising an ortho-hydroxy triazine compound, a hindered hydroxybenzoate compound and optionally a hindered amine compound. This additive composition may be used to stabilize materials from UV radiation. This invention also contemplates a method of stabilizing a material by contacting the material with the UV stabilizing additive composition.Type: GrantFiled: December 10, 2002Date of Patent: January 18, 2005Assignee: Cytec Technology Corp.Inventors: Joseph A. Stretanski, Brent M. Sanders
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Patent number: 6838568Abstract: Plastic additives which are useful as nucleating agents and which are especially useful for improving the optical properties of polymeric materials are provided. More particularly, this invention relates to certain alkyl (or alkoxy) substituted fluoro-benzylidene sorbitol acetals and polymer compositions thereof which may be utilized within, as merely examples, food or cosmetic containers and packaging. These inventive fluorinated and alkylated benzylidene sorbitol acetals are also useful as gelling agents for water and organic solvents, particularly those used in the preparation of antiperspirant gel sticks.Type: GrantFiled: September 13, 2002Date of Patent: January 4, 2005Assignee: Milliken & CompanyInventors: John D. Anderson, Nathan A. Mehl
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Patent number: 6780799Abstract: The present invention is directed to surface functionalized fabrics, particularly those based on non-woven polypropylene, wherein the functional groups are capable of binding antimicrobial agents through ionic conjugation to control their release and prolong their antimicrobial activity. The invention also deals with Nylon 6 fabric that is complexed with iodine to control its release and to achieve prolonged antimicrobial activities. Similarly, polypropylene and cellulosic fabrics grafted with N-vinylpyrrolidone are disclosed. The N-vinylpyrrolidone can also complex with iodine to control its release and provide antimicrobial activity over desired periods of time.Type: GrantFiled: June 3, 2003Date of Patent: August 24, 2004Assignee: Poly-Med, Inc.Inventor: Shalaby W. Shalaby
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Patent number: 6756450Abstract: A chlorine-free polyolefin-based plastisol or organosol and method for producing the same, where the plastisol or organosol includes: (a) a finely-dispersed polyolefin in (b) 60 to 800 parts by weight (based on 100 parts by weight polyolefin) of a dispersion medium containing monomers which are capable of polyaddition or are polymerizable and copolymerizable, and/or oligomers and/or prepolymers and optionally, liquid softeners; (c) an initiator system suitable for the desired polyaddition and/or polymerization; and optionally (d) up to 700 parts by weight inert fillers and other additives and auxiliary substances. The chlorine-free plastisol or organosol is storage-resistant at room temperature and gelates at high temperatures. The inventive plastisols or organosols are suitable for many applications and represent an advantageous alternative to the plastisols currently in use, e.g. PVC-based plastisols, since they guarantee a number of different combinations of properties.Type: GrantFiled: May 5, 2003Date of Patent: June 29, 2004Inventor: Slaweyko Marinow
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Patent number: 6727317Abstract: Unique transparent plastic (preferably though not necessarily polypropylene) articles that can be tailored to become opaque when exposed to a sufficiently high temperature and which returns to substantially the same transparency level upon cooling are provided. Such formulations include polymeric constituents that exhibit melting temperatures well below that for the majority clarified polypropylene, and thus which appear to become amorphous upon exposure to temperatures above such a lower melting temperature, thereby affecting the crystalline formation of the clarified polypropylene to the extent that opacity dominates the appearance thereof. Such lower melting temperature polymeric constituents include species such as low melt flow (up to 10) metallocene polyethylene and/or low density polyethylene, both of which exhibit melting temperatures of from about 60 to about 100° C., well below the typical polypropylene melting temperatures of roughly about 150° C.Type: GrantFiled: January 25, 2002Date of Patent: April 27, 2004Assignee: Milliken & CompanyInventors: Jenci Kurja, Stephane Berghmans
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Publication number: 20030187130Abstract: Process for the production of an alpha olefin polymer and a process for the treatment of the alpha olefin polymer. A polymerization feed containing an alpha olefin, such as propylene, is supplied to the reactor to produce a thermoplastic polymer product involving a homopolymer or a copolymer. A product stream containing the polymer is withdrawn from the polymerization reactor and the polymer product is recovered from the product stream. The polymer product is then processed to produce the polymer product in a granular or pelletized form. A hindered amine light stabilizer is oxidized with an oxidizing agent under conditions to convert at least a portion of the amine groups to nitroxyl groups. The oxidized hindered amine light stabilizer is then supplied to the polymer product prior to heating and processing of the polymer product.Type: ApplicationFiled: March 28, 2002Publication date: October 2, 2003Inventor: Lisa K. Albe
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Publication number: 20030105194Abstract: Flame retardant polyolefin pre-expanded particles made of a resin composition comprising a polyolefin resin and a sterically hindered amine ether flame retardant, which can be molded with good moldability to give in-mold foamed articles which have an excellent flame resistance and do not generate harmful gas at the time of burning.Type: ApplicationFiled: December 3, 2001Publication date: June 5, 2003Applicant: KANEKA CORPORATIONInventors: John Bready Stuart, Steven Charles Skarke, Tetsuya Ogita, Takema Yamaguchi, Tomonori Iwamoto