Organic Nrm Additive Patents (Class 524/583)
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Patent number: 6569926Abstract: A polymer composition comprising a) a thermoplastic polymer, b) a polyfunctional epoxy compound and c) an imidazolidone compound. The invention relates also to a method of improving the gloss of such polymers, to the polymers themselves with improved gloss, and also to the use of polyfunctional epoxy compounds and imidazolidones for improving gloss.Type: GrantFiled: March 8, 2001Date of Patent: May 27, 2003Assignee: Ciba Specialty Chemicals CorporationInventors: Rudolf Pfaendner, Kornelia Malzacher
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Publication number: 20030036592Abstract: Novel polypropylene films are prepared from a composition comprising polypropylene and an N,N—N,N′-bis-alkylene fatty amide having the general structural formula R—CO—NH—(CH2)n—NH—CO—R1 wherein R and R1 are the same or different alkyl or alkenyl groups having about 15 to 21 carbon atoms, n is an integer from 2 to 4 and —CO— is a carbonyl group. Such films are found to have improved utility for gravure printing applications.Type: ApplicationFiled: October 18, 2002Publication date: February 20, 2003Applicant: Applied Extrusion Technologies, Inc.Inventors: Kenneth J. Longmoore, Edward K. Bullock
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Patent number: 6521695Abstract: The present invention is an improved electric insulation composition of a polymer and an additive that reduces water treeing due to electrical aging in water. The polymer additive is a hydrophobic/hydrophilic material with good compatibility with the polymer. The present invention is also a method of preventing electrical breakdown due to the formation of water trees by forming electrical cables with the insulation containing the disclosed anti-treeing additive.Type: GrantFiled: September 24, 1996Date of Patent: February 18, 2003Assignee: Pirelli Cavi S.p.A.Inventors: Franco Peruzzotti, Luca Castellani, Luis Josè Dacal, Valeria Garcia
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Patent number: 6518356Abstract: The invention relates to the addition of dyes to aerobically curable adhesive compositions based on free-radically polymerizable compounds. The dyes serve as user-friendly indicators for monitoring the oxygen intake required to trigger the polymerization. The indicator dyes are especially suitable for aerobically adhesive compositions which contain activator systems for forming peroxides upon contact with air. Suitable dyes and indicators are those whose color change in aqueous solution lies within a pH range from 3.0 to 6.5.Type: GrantFiled: July 24, 2000Date of Patent: February 11, 2003Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Carsten Friese, Georg Knuebel
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Patent number: 6455630Abstract: Polyolefin compositions in powder form suited for metal coating, including (percentage by weight): 1) from 1% to 40% of hollow microspheres; 2) from 60% to 99% of a composition comprising: a) from 25% to 95% of polypropylene, polyethylene or crystalline propylene copolymers or mixtures thereof; b) from 0% to 70% of an elastomeric copolymer; c) from 0.5% to 10% of propylene or polyethylene modified with polar groups; d) from 0% to 10% of titanium dioxide.Type: GrantFiled: November 24, 1997Date of Patent: September 24, 2002Assignee: Basell Poliolefine Italia S.p.A.Inventors: Gian Luigi Rigosi, Roberto Marzola
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Patent number: 6380297Abstract: A method for the preparation of polymer particles comprising the steps of: a) forming an organic phase by dissolving a polymer material in a solvent; b) dispersing the organic phase in an aqueous phase comprising a particulate stabilizer and homogenizing the resultant dispersion, thereby forming spherical particles having a selected particle and uniform particle size distribution; c) following the homogenizing, adding a particle shape-modifying surface active material to the spherical particles; and d) removing the solvent, thereby producing irregularly shaped polymer particles having substantially the same selected particle size and particle size distribution as that of the spherical particles.Type: GrantFiled: August 12, 1999Date of Patent: April 30, 2002Assignee: NexPress Solutions LLCInventors: Todd C. Zion, Dennis E. Smith, Hichang Yoon, Matthew C. Ezenyilimba
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Patent number: 6328912Abstract: A mixture for stabilizing polyolefins containing A) either (A1) at least one compound of the formula in which R1 is for example C1-C10alkyl; R2 is C3-C10alkylene; R3 is for example hydrogen or C1-C8alkyl; and n1 is a number from 2 to 50; or (A2) a product obtainable by reacting a product—obtained by reaction of a polyamine of the formula in which n2′, n2″ and n2′″ are a number from 2 to 12 with cyanuric chloride—with a compound of the formula wherein R4 is for example hydrogen or C1-C12alkyl; and R5 is as defined for R3 and B) magnesium oxide, magnesium hydroxide, C) zinc oxide, zinc hydroxide or an organic salt of zinc or magnesium, or a hydrotalcite; and at least one of C1) an UV absorber or C2) 2 pigment.Type: GrantFiled: July 10, 1997Date of Patent: December 11, 2001Assignee: CIBA Specialty Chemicals Corp.Inventor: François Gugumus
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Publication number: 20010041761Abstract: A polypropylene resin composition comprising 100 parts by weight of a polypropylene resin, 0.001 part by weight or more and less than 0.03 parts by weight of an alkaline earth metal hydroxide and 0.01 part by weight or more and less than 0.5 parts by weight of a phenol antioxidant, a molded product and a film prepared therefrom. The composition is excellent in thermal stability, makes less dirty a processing machine on processing and is less fuming.Type: ApplicationFiled: March 5, 2001Publication date: November 15, 2001Inventors: Yoshiaki Oobayashi, Shigeki Kishiro
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Patent number: 6312631Abstract: A polyolefin composition having enhanced dyeing capabilities containing: (a) a polyolefin; (b) from 0.01 to 10% by weight, based on the weight of the polyolefin in, of a migratable amphiphile, excluding phenolic and sulfur-containing stabilizers and n-octyl phenyl salicylate; and (c) from 0.01 to 1000 ppm of a transition metal, based on the weight of the polyolefin.Type: GrantFiled: January 13, 2000Date of Patent: November 6, 2001Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Norbert Bialas, Paul Birnbrich, Herbert Fischer, Joerg-Dieter Klamann, Raymond Mathis
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Patent number: 6287405Abstract: There is disclosed a method and composition for cosmetically repairing a surface void in polyolefin objects. The method involves inserting a repair composition into the void and then applying heat thereto to fuse the repair composition with a surrounding portion of the polyolefin object. The repair composition is a physical mixture of a thermoplastic powder, a resin binder, and a solvent, having a paste-like consistency. The repair composition may be neutral in color, or may contain a colorant to closely match the underlying object. The heating step can be performed with an open flame or with a heat gun.Type: GrantFiled: February 23, 1999Date of Patent: September 11, 2001Inventors: Michael J. Stevenson, Robert A. Reeves, Matthew Stevenson
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Publication number: 20010018118Abstract: Fiber-reinforced recycled thermoplastic composites and methods for their manufacture are presented. In a preferred embodiment, the thermoplastic composite incorporates a matrix of recycled thermoplastic and a plurality of high modulus fibers, with the recycled thermoplastic including polyethylene, polypropylene, nylon, PET and styrene-butadiene rubber, and the high modulus fibers including glass fibers, natural fibers, carbon fibers, and aramid fibers. Preferably, each of the high modulus fibers have a minimum length of approximately ½ of an inch and a modulus of approximately one million psi.Type: ApplicationFiled: March 2, 2001Publication date: August 30, 2001Inventors: John D. Muzzy, David W. Holty, Douglas C. Eckman, John R. Stoll
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Patent number: 6258885Abstract: A filling compound for electrical and optical equipment in the form of cables, connectors, plugs, etc. and to assemblies thus produced, is provided. Electrical and optical equipment in the form of cables, connectors, plugs, etc. have to be protected against harmful influences penetrating from outside, particularly water, and also against mechanical damage during laying or as a result of exposure to heat. The filling compound is based on a stellate substance, i.e. a substance having a branched molecular structure in which, ideally, 3 or more branches, more particularly polymeric chains, radiate from a single branching point. The filling compound is flexible at very low temperatures but, on the other hand, does not run out, even at extremely high temperatures.Type: GrantFiled: January 13, 1999Date of Patent: July 10, 2001Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Reimar Heucher, Juergen Wichelhaus, Johannes Andres
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Patent number: 6153715Abstract: A propylene resin composition composed of a nucleating agent and a propylene resin having a melt index (MI) of not greater than 1.2 g/10 min and satisfying a relationship between elongational viscosity (.eta..sub..EPSILON.) and melt index (MI) represented by2.0.times.10.sup.5 .times.MI.sup.-0.68 .gtoreq..eta..sub..EPSILON. .gtoreq.1.5.times.10.sup.5 MI .times.MI.sup.-0.68.The composition is endowed with high-rigidity, has excellent drawdown resistance, ensures practical discharge rate during blow-molding at low resin temperature of 220.degree. C. or less, and enables high-productivity production of large-sized blow-molded parts featuring light weight, excellent rigidity, dimensional stability, and heat resistance. Blow-molding of the propylene resin composition provides a blow-molded article which is advantageously used as, particularly, a large-sized automobile part, such as a bumper, a bumper beam, a seat back, an instrument panel, or a like part.Type: GrantFiled: September 17, 1998Date of Patent: November 28, 2000Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Tetsuya Nakamura, Masaya Tsubokawa
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Patent number: 6084010Abstract: The present invention is a hot melt adhesive composition comprising at least one ingredient present in an encapsulated form. The encapsulated ingredient may be any known hot melt adhesive formulation ingredient as well as any hot melt adhesive additive such as antioxidants and fragrances for which there is a desirable change in adhesive properties by isolating such ingredient for a duration of time. The encapsulated ingredient is released from the shell by means of pressure, temperature, diffusion, pH, light, radiation, ultrasound, and combinations thereof. Hot melt adhesive compositions comprising at least one encapsulated ingredient are useful for a variety of novel products including self-supported friction glue sticks, non-tacky pelletized pressure sensitive adhesives, cohesive adhesive systems, hot melt adhesive compositions exhibiting improved thermal stability and odor, as well as for a variety of other adhesive applications.Type: GrantFiled: August 3, 1998Date of Patent: July 4, 2000Assignee: H.B. Fuller Licensing & Financing, Inc.Inventors: John P. Baetzold, Thomas F. Kauffman, Steven L. Scholl, Eugene R. Simmons
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Patent number: 6022905Abstract: The invention provides a composition and method for obtaining both light and dark laser marks of varying shades and intensities on a single plastic article by selectively controlling laser parameters. The invention further provides compositions and methods for obtaining pre-selected one-color and multi-colored designs on plastic articles, by selectively controlling material formulations and laser parameter settings.Type: GrantFiled: May 28, 1999Date of Patent: February 8, 2000Assignee: M.A. HannaColorInventors: Ronald M. Harris, Ke Feng, Alan R. Burgess
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Patent number: 6022924Abstract: A color masterbatch resin composition for a packaging material for a photographic photosensitive material which does not adversely affect photographic properties of the photographic photosensitive material, comprising a light-shielding material in a concentration thrice as much as or more that of the packaging material for a photographic photosensitive material, and a thermoplastic resin of which 50 wt. % or more is the same type as a thermoplastic resin occupying 50 wt. % or more of the total thermoplastic resin composing the packaging material for a photographic photosensitive material, production thereof, a packaging material for a photographic photosensitive material formed of a color masterbatch resin composition, and production thereof.Type: GrantFiled: July 10, 1998Date of Patent: February 8, 2000Assignee: Fuji Photo Film Co., Ltd.Inventors: Mutsuo Akao, Koji Inoue
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Patent number: 6017972Abstract: The invention provides a composition and method for obtaining both light and dark laser marks of varying shades and intensities on a single plastic article by selectively controlling laser parameters. The invention further provides compositions and methods for obtaining pre-selected one-color and multi-colored designs on plastic articles, by selectively controlling material formulations and laser parameter settings.Type: GrantFiled: May 28, 1999Date of Patent: January 25, 2000Assignee: M.A. HannaColorInventors: Ronald M. Harris, Ke Feng, Alan R. Burgess
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Patent number: 5973064Abstract: This invention relates to colored polyester thermoplastics comprised of polymeric colorants having poly(oxyalkylene) moieties and/or anionic dye/quatenary ammonium substantially inorganic salt-free colorant complexes mixed with diluents selected from the group consisting essentially of sorbitan (C.sub.8 -C.sub.22) monoesters, ethoxylated sorbitan (C.sub.8 -C.sub.22) monoesters, mixtures thereof of sorbitan (C.sub.8 -C.sub.22) monoesters and ethoxylated sorbitan (C.sub.8 -C.sub.22) monoesters, ethoxylated nonyl-phenol ethers, ethoxylated dodecylphenol ethers, mixtures thereof of said ethoxylated nonyl-phenol ethers and ethoxylated dodecylphenol ethers, and mixtures of (i) sorbitan (C.sub.8 -C.sub.22) monoesters or ethoxylated sorbitan (C.sub.8 -C.sub.22) monoesters and (ii) ethoxylated nonyl-phenol ethers or ethoxylated dodecylphenol ethers.Type: GrantFiled: July 7, 1998Date of Patent: October 26, 1999Assignee: Miliken Research CorporationInventors: X. Edward Zhao, Todd David Danielson, Eugene Kyle Stephenson, Elizabeth M. Irwin
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Patent number: 5962549Abstract: Composites suitable for use as prostheses for attachment to soft tissues, such as cartilage, tendons, skin, tympanic membrane and gingiva, as well as to cancellous or trabecular bone, are based on combination of a polyolefinic binder with certain bioactive glass materials. The composites bond actively with soft tissues and are readily formulated achieve mechanical properties comparable to those of the soft tissue of interest.Type: GrantFiled: December 9, 1997Date of Patent: October 5, 1999Assignees: University of London, University of Florida Research FoundationInventors: William Bonfield, Min Wang, Larry L. Hench
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Patent number: 5955165Abstract: Containers or other apparatus for viscous materials which allow for enhanced drainage or evacuation of the viscous material with a reduction in the amount of residual material that will remain in the container after evacuation. Compositions for making such containers include hydrophobic or poorly hydrophilic polymers and a polar additive. In the method of making such containers, the composition is made moldable and formed into the shape of the container and then cooled.Type: GrantFiled: April 22, 1997Date of Patent: September 21, 1999Assignee: The Proctor & Gamble CompanyInventors: Pauline C. Zamora, Robert J. Kissner
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Patent number: 5955523Abstract: Disazo chromphores having at least two different poly(oxyalkylene) substituents are linked together by a covalent bond or by an intervening connecting group to form dimers. The preferred poly(oxyalkylene) substituents are straight chain polymers consisting of ethylene oxide and propylene oxide. The disazo colorants are useful for coloring thermoplastic resins such as polypropylene and polyethylene and show improved extraction, migration, clarity and thermal stability characteristics as compared to standard monoazo colorants.Type: GrantFiled: November 7, 1997Date of Patent: September 21, 1999Assignee: Milliken Research CorporationInventors: Eric B. Stephens, Mark E. Ragsdale
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Patent number: 5948152Abstract: This invention relates to liquid complexes of anionic organic dyes with quaternary ammonium compounds which are homogeneous and thus substantially free of unwanted inorganic salts. Of particular interest as quaternary ammonium compounds are those which comprise alkoxylated moieties. Such complexes are formed through ionic bonds formed between the two compounds. The complexes are then removed of substantially all resultant unwanted salt formed from the cations of the dye and the counter ions of the quat so as to obtain an homogeneous liquid colorant which easily disperses within different media and which possess favorable migration and coloring characteristics. This invention also concerns methods of making the aforementioned salt-free anionic dye/quat complexes as well as methods of utilizing such complexes for dyeing thermoplastic and thermoset compositions and the incorporation of such complexes within aqueous and non-aqueous formulations and ink compositions.Type: GrantFiled: April 24, 1998Date of Patent: September 7, 1999Assignee: Milliken & CompanyInventors: Xiaodong Edward Zhao, Kaye Cannon Suddeth, Patrick D. Moore, Raj Batlaw
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Patent number: 5938828Abstract: This invention relates to solid complexes of anionic organic dyes with quaternary ammonium compounds which have average molecular weights of below about 900 which are substantially free from unwanted salts. Of particular interest as quaternary ammonium compounds are those which comprise alkoxylated moieties. Such complexes are formed through ionic bonds formed between the two compounds. The complexes are then removed of substantially all resultant unwanted salt formed from the cations of the dye and the counter-ions of the quat so as to obtain a solid dyeing agent which easily disperses within different media and which possess extremely good non-migration and coloring characteristics. This invention also concerns methods of making the aforementioned salt-free solid anionic dye/quat complexes as well as methods of utilizing such complexes for dyeing thermoplastic, thermoset, and wax compositions.Type: GrantFiled: April 24, 1998Date of Patent: August 17, 1999Assignee: Milliken & CompanyInventors: Xiaodong Edward Zhao, Kaye Cannon Suddeth, Robert L. Mahaffey, Jr.
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Patent number: 5916990Abstract: There are provided a propylene-based polymer characterized in that (1) the xylene-extraction insoluble portion (XI) is 99.0 wt % or greater, (2) the isotactic pentad ratio (IP) is 98.0% or greater as measured by .sup.13 C nuclear magnetic resonance spectroscopy, (3) the isotactic average chain length (N) is 500 or greater, and (4) the total amount of each of the fractions obtained by column separation of the xylene insolubles whose average chain length (N.sub.f) is 800 or greater accounts for 10 wt % or more of the entirety, and a method for its production, as well as a propylene-based polymer composition prepared by combining with this propylene-based polymer at least a nucleating agent in the range of 0.05-15 wt %. In addition, there are provided a polymerization catalyst component allowing the production of such a propylene-based polymer, and a method for its production.Type: GrantFiled: September 7, 1994Date of Patent: June 29, 1999Assignee: Showa Denko K.K.Inventors: Hisayoshi Yanagihara, Kazuyuki Watanabe, Satoshi Iwamoto, Hirotoshi Takahashi, Kazuharu Itoh
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Patent number: 5912292Abstract: A mono-axially oriented polypropylene film with sodium benzoate as a nucleating agent results in reduced shrinkage and increase stretchability. The sodium benzoate ranges up to 1000 ppm. The polypropylene used in making the film preferably has an isotacticity exceeding 97% as determined by C.sup.13 -NMR spectroscopy. The film preferably has a thicknesses of about 0.5 mil to 5.0 mil and, more preferably, about 1.0 mil to 3.0 mil. The sodium benzoate preferably has a purity of 99% and a particle size of from about 1 micron to about 3 microns.Type: GrantFiled: February 10, 1993Date of Patent: June 15, 1999Assignee: Fina Technology, Inc.Inventor: Likuo Sun
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Patent number: 5902849Abstract: A filling compound for electrical and optical equipment in the form of cables, connectors, plugs etc. and to assemblies thus produced, is provided. Electrical and optical equipment in the form of cables, connectors, plugs etc. have to be protected against harmful influences penetrating from outside, particularly water, and also against mechanical damage during laying or as a result of exposure to heat. The filling compound is based on a stellate substance, i.e. a substance having a branched molecular structure in which, ideally, 3 or more branches, more particularly polymeric chains, radiate from a single branching point. The filling compound is flexible at very low temperatures but, on the other hand, does not run out, even at extremely high temperatures.Type: GrantFiled: November 12, 1996Date of Patent: May 11, 1999Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Reimar Heucher, Juergen Wichelhaus, Johannes Andres
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Patent number: 5820970Abstract: Polypropylene films which have cavities distributed in the film and on the surfaces are suitable for writing or printing and have a low density. The films have surface qualities of each side of surface within .+-.2.times.10.sup.-6 inch of the average depth of the cavities, .+-.2% of the average of the gloss at 45.degree. angle and .+-.0.02 of the average of coefficient of friction. Such a film is obtained by passing the molded film from the calender through a set of heating rolls at temperatures revealed in this invention before entering the stretching system. The obtained polypropylene film has superior printability, low density and high stiffness, and thus is suitable for use as a paper substitute.Type: GrantFiled: June 2, 1997Date of Patent: October 13, 1998Assignee: Inteplast CorporationInventor: Hwang-Wen Huang
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Patent number: 5750645Abstract: A process which combines a calender with a stretching system and a set of heating rolls is provided in this invention to produce films of polypropylene resin of wide thickness range. The polypropylene films which have cavities distributed in the film and on the surfaces are suitable for writing or printing and have a low density. The films have surface qualities of each side of surface within .+-.2.times.10.sup.-6 inch of the average depth of the cavities, .+-.2% of the average of the gloss at 45.degree. angle and .+-.0.02 of the average of coefficient of friction. Such a film is obtained by passing the molded film from the calender through a set of heating rolls at temperatures revealed in this invention before entering the stretching system. The obtained polypropylene film has superior printability, low density and high stiffness, and thus is suitable for use as a paper substitute.Type: GrantFiled: May 10, 1996Date of Patent: May 12, 1998Assignee: Inteplast CorporationInventor: Hwang-Wen Huang
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Patent number: 5728753Abstract: Composites suitable for use as prostheses for attachment to soft tissues, such as cartilage, tendons, skin, tympanic membrane and gingiva, as well as to cancellous or trabecular bone, are based on combination of a polyolefinic binder with certain bioactive glass materials. The composites bond actively with soft tissues and are readily formulated achieve mechanical properties comparable to those of the soft tissue of interest.Type: GrantFiled: November 9, 1995Date of Patent: March 17, 1998Assignees: University of London, University of FloridaInventors: William Bonfield, Min Wang, Larry L. Hench
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Patent number: 5721322Abstract: The specification discloses a method and additive for increasing the surface activity of non-polar polymeric materials, and a non-polar polymeric material exhibiting increased surface activity. The invention employs an additive of the formulaA-B-A.sup.1wherein each of the A and A.sup.1 blocks which may be the same or different has a number molecular weight in the range of from about 200 to about 1000 daltons and is selected from the group substituted and unsubstituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, aryl and alkylaryl units derived from one or more esters, organic acids, organic halides or organic acid halides, and units derived from alkyl or aryl isocyanates or ester-amides. The B-block is a polyepichlorohydrin unit derived from a polyepichlorohydrin polyol having at least two terminal hydroxyl groups and having an average molecular weight in the range of from about 400 to about 4000 daltons.Type: GrantFiled: January 24, 1997Date of Patent: February 24, 1998Assignee: Arizona Chemical CompanyInventors: Xinya Lu, Eric S. Gardiner
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Patent number: 5686515Abstract: A process for manufacture of articles comprised of polyethylene terephthalate wherein the PET is colored with a composition comprised of a wax dispersant, ethylene copolymer, and a colorant. In a preferred embodiment, the wax dispersant is a maleated polyethylene wax. In an alternative embodiment, the wax dispersant is a low molecular weight polyethylene wax and the composition further includes linear low density polyethylene. A preferred ethylene copolymer is ethylene-(meth)acrylic acid.Type: GrantFiled: November 13, 1995Date of Patent: November 11, 1997Assignee: The M.A. Hanna CompanyInventors: Tracy L. Phillips, Ronald M. Harris, Alan R. Burgess, Judy A. Johnston
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Patent number: 5627226Abstract: A composite is provided having improved toughness without reduction in stiffness comprising a polymer matrix having fibers embedded therein wherein the polymer of the matrix is substantially beta polypropylene or a beta polypropylene-olefin copolymer. The composite is made by combining a nucleating agent with a polymer composition selected from the group consisting of alpha polypropylene, an alpha polypropylene-olefin copolymer, alpha polypropylene containing fibers therein and an alpha polypropylene-olefin copolymer having fibers therein, and when the polymer is polypropylene or polypropylene-olefin copolymer, also independently adding fiber to the polymer or copolymer and thereafter inducing nucleation whereby a composite of improved stiffness with no reduction in toughness is formed.Type: GrantFiled: November 3, 1995Date of Patent: May 6, 1997Assignee: Exxon Research & Engineering CompanyInventors: Arnold Lustiger, Cary N. Marzinsky, Yann Devorest
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Patent number: 5573840Abstract: The invention provides a polymeric insulating material having a high dielectric breakdown voltage. The material comprises polypropylene which has been obtained in a yield of at least 300,000 g/g-Ti based on titanium in a catalyst upon polymerization, contains ash in an amount not greater than 40 ppm by weight when analyzed by completely burning the polypropylene in air, said ash containing titanium in an amount not greater than 1 ppm by weight based on the weight of the polypropylene, and also contains chlorine in an amount not greater than 2 ppm by weight and boiling n-heptane soluble matter in an amount not smaller than 1 wt. % but not greater than 10 wt. %. To further improve the dielectric breakdown voltage an inorganic oxide or hydroxide free of particles of 10 .mu.m and greater in diameter and having an average particle size not greater than 1 .mu.Type: GrantFiled: May 26, 1995Date of Patent: November 12, 1996Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Takeo Inoue, Shigeru Kimura, Tutomu Iwatani, Takayuki Yamada, Yukio Ishii, Ryuichi Sugimoto
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Patent number: 5514743Abstract: Reinforced, flame-resistant thermoplastic composition consisting of: (A) a polymeric matrix consisting of an olefinic or styrene (co)polymer; (B) a quantity which is sufficient to give flame resistance properties, of an intumescent flame-retarding agent consisting of a mixture of (i) a compound containing nitrogen, insoluble in water, consisting of an oligomer or polymer of a derivative of 1,3,5-triazine and (ii) an ammonium phosphate, and (C) from 5 to 50% by weight with respect to the total composition of a phosphorite having a phosphorous content, expressed as BPL (Bone Phosphate of Lime) of more than 40% by weight.Type: GrantFiled: June 13, 1995Date of Patent: May 7, 1996Assignee: Enichem S.p.A.Inventors: Roberto Pernice, Michele Checchin, Alessandro Moro, Roberto Pippa
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Patent number: 5508330Abstract: An improvement in barrier properties of films and molded articles containing an organic polymer is achieved by incorporation therein of fluorochemicals, fluoropolymers or mixtures thereof, wherein said fluorochemicals or fluoropolymers contain greater than 40% fluorine by weight and exhibit less than 20% weight loss at 165.degree. C., as measured by thermogravimetric analysis at 20.degree. C. per minute in air. The films and molded articles in accordance with the present invention exhibit improved vapor and chemical barrier properties.Type: GrantFiled: November 3, 1994Date of Patent: April 16, 1996Assignee: Ciba-Geigy CorporationInventors: Gregory R. Coughlin, Robert A. Falk
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Patent number: 5476709Abstract: The invention provides a polymeric insulating material having a high dielectric breakdown voltage. The material comprises polypropylene which has been obtained in a yield of at least 300,000 g/g-Ti based on titanium in a catalyst upon polymerization, contains ash in an amount not greater than 40 ppm by weight when analyzed by completely burning the polypropylene in air, said ash containing titanium in an amount not greater than 1 ppm by weight based on the weight of the polypropylene, and also contains chlorine in an amount not greater than 2 ppm by weight and boiling n-heptane soluble matter in an amount not smaller than 1 wt. % but not greater than 10 wt. %. According to the invention, it is possible to further improve the dielectric breakdown voltage by adding to the polypropylene an inorganic oxide or hydroxide free of particles of 10 .mu.m and greater in diameter and having an average particle size not greater than 1 .mu.Type: GrantFiled: June 8, 1993Date of Patent: December 19, 1995Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Takeo Inoue, Shigeru Kimura, Tutomu Iwatani, Takayuki Yamada, Yukio Ishii, Ryuichi Sugimoto
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Patent number: 5464898Abstract: A cast resin suspensions comprising:(A) 40 to 80% by weight of an inorganic filler,(B) 60 to 20% by weight of a liquid polymerizable organic monomer, and(C) 0 to 5 parts by weight based on the sum of (A) and (B) of a polymerizable organosilicon component as coupling agent,wherein inorganic filler (A) is a mixture of at least two filler particle fractions having different median particle sizes, wherein the size ratio of the average particle sizes of the large and small filler particles ranges from 10:1 to 2:1 and wherein the weight ratio of the contents of large and small filler particles is from 4:1 to 1:4.Type: GrantFiled: September 19, 1994Date of Patent: November 7, 1995Assignee: Roehm GmbH Chemische FabrikInventors: Guenther Ittmann, Manfred Krieg
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Patent number: 5420185Abstract: A bow-tie tree resistant electrical insulating composition comprises 100 parts by weight of at least one polymer selected from polyolefins and ethylene copolymers, 0.005-1.0 part by weight of a metal salt of a fatty acid containing a hydroxyl group in the molecule, and 0.005-1.0 part by weight of a fatty acid or a derivative thereof.Type: GrantFiled: September 14, 1994Date of Patent: May 30, 1995Assignee: Hitachi Cable Ltd.Inventors: Kiyoshi Watanabe, Takanori Yamazaki, Hideki Yagyu, Mamoru Kanaoka, Katsutoshi Hanawa, Chuki Ikeda
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Patent number: 5415827Abstract: For the purpose of improving the quality and especially the mechanical properties of single- or multi-ply sheets with at least one ply, consisting at least in part of thermoplastically processable starch, the sheets are stretched monoaxially or biaxially after they have been produced.Type: GrantFiled: October 16, 1992Date of Patent: May 16, 1995Assignee: Ivan TomkaInventors: Ivan Tomka, Joachim Meissner, Rico Menard
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Patent number: 5414028Abstract: Carbohydrate substituted dibenzo[d,f][1,3,2]dioxaphosphepin compounds of formula I ##STR1## where A is a carbohydrate residue are effective stabilizers for polymers processed at elevated temperatures and subject to thermal or oxidative degradation.Type: GrantFiled: February 17, 1994Date of Patent: May 9, 1995Assignee: Ciba-Geigy CorporationInventors: Stephen D. Pastor, Joseph E. Babiarz
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Patent number: 5376716Abstract: A radiation resistant resin suitable for the manufacture of, for example, disposable medical supplies comprises a semicrystalline polypropylene or propylene-ethylene and from 1500 to 5000 ppm triallyl trimellitate. The resin exhibits substantially no increase in melt flow rate after irradiation to a dosage of up to 5 Mrads, and may contain up to about 5% by weight of a polybutylene and/or up to about 3000 ppm of a sorbital based clarifying agent.Type: GrantFiled: August 31, 1992Date of Patent: December 27, 1994Assignee: Rexene Products CompanyInventors: Kasinath Nayak, George C. Allen, Roger Merrill
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Patent number: 5356962Abstract: Carbohydrate substituted dibenzo[d,g][1,3,2]dioxaphosphocin compounds of formula I ##STR1## where A is a carbohydrate residue are effective stabilizers for polymers processed at elevated temperatures and subject to thermal or oxidative degradation.Type: GrantFiled: February 17, 1994Date of Patent: October 18, 1994Assignee: Ciba-Geigy CorporationInventors: Stephen D. Pastor, Joseph E. Babiarz
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Patent number: 5328951Abstract: A method is disclosed for increasing the surface energy of a surface of an organic polymeric material, particularly polyolefins. The method is comprised of blending from about 99.5% to about 90.0% by weight of the polymeric material with from about 0.5% to about 10.0% by weight of an amphiphile having the formula:RA(CHR.sup.2 [CH.sub.2 ].sub.n A.sup.1).sub.m R.sup.1where R and R.sup.1 are selected from the group consisting of the alkyl, aryl, alkylaryl, acyl and arylacyl derivatives of an aliphatic or aliphatic/aromatic mono-acid with a molecular weight of from about 150 to about 500 daltons, A and A.sup.1 are polar atoms or groups, R.sup.2 is selected from the group consisting of H, CH.sub.3 and C.sub.2 H.sub.5, n is from 0 to 3 and m is from 2 to 20.Type: GrantFiled: July 1, 1993Date of Patent: July 12, 1994Assignee: Arizona Chemical CompanyInventor: Eric S. Gardiner
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Patent number: 5319012Abstract: A method for the nucleation of polyolefins containing residual polymerization catalyst by blending the polyolefins with at least one aliphatic dicarboxylic acid containing from about 4 to about 21 carbon atoms and at least one aliphatic monocarboxylic acid containing from about 8 to about 24 carbon atoms in a weight ratio between about 4:1 and about 1:4. Also a composition comprising at least one aliphatic dicarboxylic acid containing from about 4 to about 21 carbon atoms and at least one aliphatic monocarboxylic acid containing from about 8 to about 24 carbon atoms. The polyolefin product of the nucleation can be molded into shaped articles.Type: GrantFiled: July 15, 1992Date of Patent: June 7, 1994Assignee: Witco CorporationInventors: James J. Ward, Thomas E. Breuer
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Patent number: 5310889Abstract: Carbohydrate substituted dibenzo[d,f][1,3,2]dioxaphosphepin compounds of formula I ##STR1## where A is a carbohydrate residue are effective stabilizers for polymers processed at elevated temperatures and subject to thermal or oxidative degradation.Type: GrantFiled: July 22, 1992Date of Patent: May 10, 1994Assignee: Ciba-Geigy CorporationInventors: Stephen D. Pastor, Joseph E. Babiarz
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Patent number: 5310890Abstract: Carbohydrate substituted dibenzo[d,g][1,3,2]dioxaphosphocin compounds of formula I ##STR1## where A is a carbohydrate residue are effective stabilizers for polymers processed at elevated temperatures and subject to thermal or oxidative degradation.Type: GrantFiled: July 22, 1992Date of Patent: May 10, 1994Assignee: Ciba-Geigy CorporationInventors: Stephen D. Pastor, Joseph E. Babiarz
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Patent number: 5300549Abstract: A method for the nucleation of polyolefins containing residual polymerization catalyst by blending the polyolefins with at least one aliphatic dicarboxylic acid containing from about 4 to about 21 carbon atoms and at least one aliphatic monocarboxylic acid containing from about 8 to about 24 carbon atoms in a weight ratio between about 4:1 and about 1:4. Also a composition comprising at least one aliphatic dicarboxylic acid containing from about 4 to about 21 carbon atoms and at least one aliphatic monocarboxylic acid containing from about 8 to about 24 carbon atoms. The polyolefin product of the nucleation can be molded into shaped articles.Type: GrantFiled: April 11, 1991Date of Patent: April 5, 1994Assignee: Witco CorporationInventors: James J. Ward, Thomas E. Breuer
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Patent number: 5274020Abstract: Far infra-red ray radiating materials in which organic metal compounds or organic silicon compounds are used as radiating materials are disclosed. Examples of organic metal compounds which may be used in this invention are alkyl metal ester, alkyl metal chelate, alkyl metal acylate, metal chelated ester, metal alcoholate, and zirconium tetraacetylacetonate. Examples of organic silicon compounds which may be used in this invention are dimethyl dispoxy silan, and methyl triethoxy silan. The far infra-red radiating material manufactured by using the above compounds make it possible to express transparent color and have increased surface brightness, adhesive strength, and heat resistance, without lowering its standard of radiation rate in comparison with known radiating materials manufactured by using inorganic compounds.Type: GrantFiled: September 6, 1991Date of Patent: December 28, 1993Assignee: Samwoo Far Infra-Red Ray Co., Ltd.Inventor: Young Joon Kweon
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Patent number: 5272196Abstract: A method is disclosed for increasing the surface energy of a surface of an organic polymeric material, particularly polyolefins. The method is comprised of blending from about 99.5% to about 90.0% by weight of the polymeric material with from about 0.5% to about 10.0% by weight of an amphiphile having the formula:RA(CHR.sup.2 [CH.sub.2 ].sub.n A.sup.1).sub.m R.sup.1where R and R.sup.1 are selected from the group consisting of the alkyl, aryl, alkylaryl, acyl and arylacyl derivatives of an aliphatic or aliphatic/aromatic mono-acid with a molecular weight of from about 150 to about 500 daltons, A and A.sup.1 are polar atoms or groups, R.sup.2 is selected from the group consisting of H, CH.sub.3 and C.sub.2 H.sub.5, n is from 0 to 3 and m is from 2 to 20.Type: GrantFiled: March 24, 1993Date of Patent: December 21, 1993Assignee: Arizona Chemical CompanyInventor: Eric S. Gardiner
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Patent number: 5244962Abstract: There are provided pressure-sensitive adhesives which comprise free radical cured mixtures of at least one crosslinkable olefin polymer and at least one tackifying organic additive, preferably a hydrogenated additive, which is substantially nonresponsive to action of free radicals and present in an amount sufficient to tackify the cured mixture of polymer and additive.Type: GrantFiled: August 14, 1991Date of Patent: September 14, 1993Assignee: Avery Dennison CorporationInventors: Sebastian S. Plamthottam, Roger H. Mann, John O. Landers