From -n=c=x Reactant Or Blocked N=c=x Reactant (x Is Chalcogen) Patents (Class 524/589)
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Patent number: 8729154Abstract: An object to be achieved by the present invention is to provide a binder for an ink-jet printing ink, the binder being capable of forming a printed image having excellent durability such as rubfastness and alkali resistance without impairing good ejection stability, storage stability, etc. of an ink, and an ink-jet printing ink containing the binder. The present invention relates to a binder for an ink-jet printing ink, the binder containing an aqueous medium (D); and a polyurethane (C) obtained by reacting a polyol (A) containing a vinyl polymer (a1) having two hydroxyl groups at one end and at least one polyol (a2) selected from the group consisting of polyether polyols, polyester polyols, polyester ether polyols, and polycarbonate polyols with a polyisocyanate (B), the polyurethane (C) having a structure derived from the vinyl polymer (a1) in a side chain thereof and being dispersed in the aqueous medium (D), and printed matter.Type: GrantFiled: August 29, 2011Date of Patent: May 20, 2014Assignee: DIC CorporationInventors: Ryuichi Matsuoka, Sadamu Nagahama, Mitsuru Kitada
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Patent number: 8722793Abstract: A polylactic acid resin composition contains (A) a crosslinked polylactic acid resin and (B) a flame retardant additive.Type: GrantFiled: July 22, 2010Date of Patent: May 13, 2014Assignee: Fuji Xerox Co., Ltd.Inventor: Kenji Yao
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Patent number: 8722795Abstract: A dry erase writing surface is formed from a single component, 100% solids polyurethane, ambient cured, dry erase paint composition having at least ninety percent by weight low NCO isocyanate, a cure accelerating catalyst and a defoaming agent. The surface is ready for use in a day. The composition can additionally contain a diluent, vegetable oil or mineral spirits. The coating has a VOC of between 0 and 49 g/l. The coating is initially applied to the surface of the substrate to form a film thickness of 1-3 mils. The whiteboard is characterized as when tested by erasure of the dry erase markers, the marks are virtually invisible after 2500 cycles. The composition can be packaged as a kit with applicators.Type: GrantFiled: April 5, 2012Date of Patent: May 13, 2014Assignee: Exhibit One, Inc.Inventors: Andy W. Anderson, Sr., Michael B. Winchester, Thomas Jeffrey Smythe
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Patent number: 8722792Abstract: A dry erase writing surface is formed from a single component, 100% solids polyurethane, ambient cured, dry erase paint composition having at least ninety percent by weight low NCO isocyanate, a cure accelerating catalyst and a defoaming agent. The surface is ready for use in a day. The composition can additionally contain a diluent, vegetable oil or mineral spirits. The coating has a VOC of between 0 and 49 g/l. The coating is initially applied to the surface of the substrate to form a film thickness of 1-3 mils. The whiteboard is characterized as when tested by erasure of the dry erase markers, the marks are virtually invisible after 2500 cycles. The composition can be packaged as a kit with applicators.Type: GrantFiled: October 17, 2012Date of Patent: May 13, 2014Assignee: Exhibit One, Inc.Inventors: Andy W. Anderson, Sr., Michael B. Winchester, Thomas Jeffrey Smythe
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Patent number: 8719964Abstract: The present invention relates to articles and gloves having a polymer coating on at least a portion of the article or gloves's surface, wherein the polymer coating comprises a polyurethane dispersion made from the reaction product of an isocyanate functional prepolymer, a chain extender, and a chain terminator; and methods for making the same. The articles and gloves of the present invention have improved flexibility, breathability, dexterity and feel, and provide self-sanitizing and self-deodorizing capabilities and improved non-slip grip performance in dry, wet, humid and lubricated conditions.Type: GrantFiled: September 16, 2011Date of Patent: May 13, 2014Assignee: O'Neill LLCInventor: Michael O'Neill
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Patent number: 8716397Abstract: An adhesive composition for use in adhering insulation panels to roofing substrates and roofing membranes to the insulation panels include two components that are mixed prior to application on the roofing substrate. The first component may include a renewable polyol and catalyst. The renewable polyol is selected from any non-petroleum based polyol that is derived from a renewable source. The second component includes isocyanate, and may also include a polyol and a catalyst. The isocyanate and the polyol may each be any non-petroleum based isocyanate or polyol that is derived from a renewable source.Type: GrantFiled: August 17, 2011Date of Patent: May 6, 2014Assignee: ADCO Products, Inc.Inventors: John William Miller, Nicholas John Berard
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Patent number: 8709544Abstract: The present invention relates to coating compositions for polyurethane coating materials that feature new catalysts.Type: GrantFiled: November 22, 2010Date of Patent: April 29, 2014Assignee: BASF SEInventors: Oliver Neu, Michael Siemer, Ansgar Gereon Altenhoff, Harald Schaefer, Angelika Maria Steinbrecher
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Patent number: 8710170Abstract: A polymer made by reacting a polyisocyanate with a compound having the formula below. R1 is an organic group. R2 is an aliphatic group or oxyaliphatic group. R3 is an aliphatic group. The reaction forms urea groups from the isocyanate groups of the polyisocyanate and the NH groups of the compound.Type: GrantFiled: May 13, 2009Date of Patent: April 29, 2014Assignee: The United States of Americas, as represented by the Secretary of the NavyInventors: Jozef Verborgt, Arthur A Webb
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Patent number: 8697799Abstract: Non-aqueous, liquid coating compositions which contain at least one polyurethane resin B with blocked isocyanate groups and at least one binder C with functional groups reactive towards the blocked isocyanate groups of B, wherein the at least one polyurethane resin B is present as particles having a melting temperature of 40 to 160° C.Type: GrantFiled: December 1, 2006Date of Patent: April 15, 2014Assignee: Axalta Coating Systems IP Co., LLCInventors: Carmen Flosbach, Thomas Grawe
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Patent number: 8686090Abstract: The thermosetting, non-polymeric coating composition includes at least one monomeric material having a plurality of carbamate and/or urea groups, at least one crosslinker reactive with the at least one monomeric material, and a sag control agent that is a crystalline reaction product of an amine and an isocyanate.Type: GrantFiled: December 10, 2003Date of Patent: April 1, 2014Assignee: BASF Coatings GmbHInventors: Marvin L. Green, Swaminathan Ramesh, Walter H. Ohrbom
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Patent number: 8686091Abstract: Water-based coatings having writable-erasable surfaces are provided. The coatings have many desirable attributes. For example, the coatings cure under ambient conditions, have low or no VOC emissions during and upon curing, and have reduced tendency to form ghost images, even after prolonged normal use.Type: GrantFiled: October 4, 2012Date of Patent: April 1, 2014Assignee: IdeaPaint, Inc.Inventors: John Goscha, Martin Douglas Donbrosky, Jr.
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Patent number: 8679589Abstract: The present invention relates to a coating composition comprising (a) at least one hydroxyl-containing compound (A), (b) at least one compound (B) having free and/or blocked isocyanate groups, and (c) at least one catalyst (C) for the crosslinking of silane groups, one or more constituents of the coating composition containing hydrolyzable silane groups, wherein the coating composition contains a water scavenger as further constituent (D).Type: GrantFiled: December 18, 2008Date of Patent: March 25, 2014Assignee: BASF Coatings GmbHInventors: Matthijs Groenewolt, Günter Klein, Andreas Poppe, Simone Hesener, Wilfried Stübbe, Manuela Niemeier, Sabine Holtschulte, Oliver Hilge, Björn Feldmann
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Patent number: 8669323Abstract: The present invention relates to unblocked nano-particle-modified polyisocyanates having increased stability in the NCO content.Type: GrantFiled: May 5, 2009Date of Patent: March 11, 2014Assignee: Bayer MaterialScience AGInventors: Arno Nennemann, Sebastian Dörr, Oliver Pyrlik
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Patent number: 8669300Abstract: The present invention is related to a radiation curable binder, comprising the reaction product of a polyisocyanate having 3 free isocyanate moieties with an acrylate having isocyanate-reactive groups and a component selected from the group consisting of a C12-C22 carboxylic acid having one isocyanate-reactive group or a C12-C22 fatty alcohol. The present invention is furthermore related to a radiation curable printing ink, comprising said binder, at least one diluent, at least one pigment, and optionally additives, as well as to a process of preparing said radiation curable binder. Said binder or said printing ink can be used in offset printing or letterpress printing.Type: GrantFiled: March 19, 2009Date of Patent: March 11, 2014Assignee: Siegwerk Druckfarben AG & Co. KGaAInventors: Gilles Eisele, Thierry Marsille, Gilles Catherin
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Patent number: 8669324Abstract: An object of the present invention is to provide a method for producing a binder for inks and for use in producing an inkjet printing ink that has both good ink dischargeability and blend stability. A method for producing a binder for inkjet printing inks, the binder containing a hydrophilic-group-containing urethane resin (A), an acetylene compound (B), and an aqueous medium (C), includes step (1) of allowing Ga polyol (a1) containing a hydrophilic-group-containing polyol to react with a polyisocyanate (a2) in an organic solvent or in the absence of a solvent and feeding the organic solvent as needed to prepare an organic solvent solution [I], step (2) of mixing the organic solvent solution [I] with the acetylene compound (B) and the aqueous medium (C) to prepare a mixture [II], and step (3) of removing the organic solvent contained in the mixture [II].Type: GrantFiled: March 28, 2011Date of Patent: March 11, 2014Assignee: DIC CorporationInventors: Sadamu Nagahama, Mitsuru Kitada, Chisato Kuriyama, Ryuichi Matsuoka
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Patent number: 8664331Abstract: A polyurethane polymer comprising from 35% to 90% (w/w) of a poly (C2-4-alkylene oxide) based on the total weight of the polymer wherein not less than 60% by weight of the poly (C2-4-alkylene oxide) is polyethylene oxide and wherein at least 5% of the poly (C2-4-alkylene oxide) based on the total weight of the polymer is incorporated in lateral chains and which contains 10 to 180 milliequivalents of add groups for each 100 gm polymer when the polyurethane contains from 35 to 45% by weight poly (C2-4-alkylene oxide), e.g. a polymer made by reacting dimethylolpropionic acid, cyclohexane dimethanol, polypropylene glycol (1000), N-methyl pyrrolidone and an ?,?-diydroxy polyethylene glycol obtainable from 2,4-toluene diisocyanate, methoxy polyethylene glycol (750) and diethanolamine.Type: GrantFiled: November 1, 2002Date of Patent: March 4, 2014Assignee: The Lubrizol CorporationInventor: Stuart Nicholas Richards
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Patent number: 8664330Abstract: High green strength reactive hot melt adhesives are prepared using relatively low levels of reactive acrylic, and may be prepared with liquid crystalline or crystalline diols.Type: GrantFiled: April 4, 2003Date of Patent: March 4, 2014Assignee: Henkel US IP LLCInventors: Ju-Ming Hung, Wayne K. Chu, Yue S. Zhang, Ingrid Cole
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Patent number: 8652568Abstract: The instant invention is a coating system, a coating composition, a coating layer, a coated substrate, a method for producing a coating composition, a method for forming a coating layer, a method for making a coated substrate, and a method for healing a coated substrate. The coating system according to the present invention comprises (a) one or more natural oil derived polyols having an average of 3 or more hydroxyl groups per molecule, a number average molecular weight in the range of 300 to 3000 Daltons, a Tg in the range of from less than 0° C.; and (b) one or more polyisocyanates.Type: GrantFiled: September 7, 2011Date of Patent: February 18, 2014Assignee: Dow Global Technologies LLCInventors: Sudhakar Balijepalli, Ray E. Drumright, Sarah T. Eckersley, Brad E. Elwood, Paul Foley, Yanziang Li, Kumar Nanjundiah
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Toluene and styrene derived telomer distributions and brominated flame retardants produced therefrom
Patent number: 8648140Abstract: This invention relates to novel and useful toluene and styrene derived telomer distributions, such distributions being desirable substrates for the preparation of brominated flame retardants.Type: GrantFiled: November 30, 2009Date of Patent: February 11, 2014Assignee: Albemarle CorporationInventors: William J. Layman, Jr., Charles H. Kolich, Arthur G. Mack, Steven A. Anderson, Jonathan P. McCarney, Junzuo Wang -
Patent number: 8648130Abstract: The present invention provides a resin composition which enables to obtain a transparent member having excellent transparency, high refractive index and high strength and an optical component composed of such a transparent member. A resin composition of the present invention comprises a polymerizable compound or a resin component and an organically modified fine particle produced in the presence of a high-temperature high-pressure water as a reaction field, in which an organic material is bonded to the surface of a metal fine particle.Type: GrantFiled: November 28, 2008Date of Patent: February 11, 2014Assignee: Mitsui Chemicals, Inc.Inventors: Akira Hasegawa, Kenichi Goto, Toyoharu Hayashi
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Patent number: 8648127Abstract: The disclosure provides for a self decontaminating coating and method. The coating comprises a polyurethane component having a solids content in the range of about 10 weight percent to about 100 weight percent and having at least one volume percent free space, a chemical active, and a biological active. In another disclosed embodiment, a method of reducing the transportation of chemical contaminants and biological contaminants is provided comprising the steps of providing a self decontaminating coating comprising a polyurethane component having a polyurethane component having a solids content in the range of about 10 weight percent to about 100 weight percent and having at least one volume percent free space, a chemical active, and a biological active, and applying the coating to a surface of an aircraft, rotorcraft, vehicle, item of equipment, or architectural structure.Type: GrantFiled: June 2, 2008Date of Patent: February 11, 2014Assignee: The Boeing CompanyInventors: Lynn G. Taylor, Nancy W. Carlson, Adam F. Gross
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Patent number: 8642179Abstract: An insulating varnish includes a polyamide-imide resin including a repeat unit represented by Formula (1) below derived from a synthesis reaction between a resin component (X) and a diisocyanate component (Y). The resin component (X) is derived from a synthesis reaction between a diamine component including aromatic diamines including g a divalent aromatic group (R) including three or more aromatic rings, and an acid component in the presence of an azeotrope solvent. The diisocyanate component (Y) includes a 2,4?-diphenylmethane diisocyanate (Y1) and a 4,4?-diphenylmethane diisocyanate (Y2). In Formula (1), R denotes the divalent aromatic group including three or more aromatic rings, and m and n denote an integer of from 1 to 99.Type: GrantFiled: February 15, 2011Date of Patent: February 4, 2014Assignee: Hitachi Cable, Ltd.Inventors: Shuta Nabeshima, Yuki Honda, Tomiya Abe, Hideyuki Kikuchi, Yasuhiro Funayama
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Patent number: 8633292Abstract: A photochromic composition for making optical materials comprising a polyurethane prepolymer formed by combining an isocyanate and a compound having an active hydrogen containing group, a polysilsequioxane and a photochromic compound. The photochromic composition may also include a monomer that has both an active hydrogen containing group and an unsaturated group. The polysilsesquioxane is incorporated as a copolymer and/or as a polysilsequioxane-chemically modified polyurethane.Type: GrantFiled: March 26, 2009Date of Patent: January 21, 2014Assignee: Signet ArmorliteInventors: Geoffrey Yuxin Hu, Thomas J. Engardio
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Publication number: 20140018458Abstract: A method for producing a polyester polyol is disclosed. The method comprises reacting phthalic anhydride with a diol selected from the group consisting of ethylene glycol, propylene glycol, 1,3-propanediol, 2-meth-1,3-propanediol, neopentyl glycol, 1,6-hexanediol, polyethylene glycols having a number average molecular weight within the range of 200 g/mol to 600 g/mol, and mixtures thereof at a diol to phthalic anhydride molar ratio within the range of 1.1 to 1.6. The resulting o-phthalate polyester polyol has a hydroxyl value in the range of 18 to 400 mg KOH/g, an acid value in the range of 0.2 to 5.0 mg KOH/g, and 1 wt. % or less of cyclic esters.Type: ApplicationFiled: March 7, 2012Publication date: January 16, 2014Applicant: STEPAN COMPANYInventors: Douglas Hillshafer, Andrew Guo
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Publication number: 20140018474Abstract: Provided are a composition for anti-scratch and wear-resistance properties, a method of preparing the same, and its application. The composition has inorganic particles, a dispersant and an organic binding agent. The inorganic particles are spherical and have an average particle size ranging from 10 nanometers to 999 nanometers. The dispersant has an inorganic dispersant and a polymer dispersant. The specific gravity of the inorganic particles and inorganic dispersant are respectively represented by s1 and s2, 0.05<s2/s1<1. The total amount of inorganic particles and inorganic dispersant ranges from 0.5 to 70 parts by weight, the amount of polymer dispersant ranges from 0.1 to 20 parts by weight, and the amount of organic binding agent ranges from 10 to 98 parts by weight. Since the inorganic particles are stably dispersed in the composition, the composition can be applied to coating, paint or composite materials and has improved wear-resistant and anti-scratch properties.Type: ApplicationFiled: December 19, 2012Publication date: January 16, 2014Applicant: ETERNAL CHEMICAL CO., LTD.Inventors: Lang Zhou, Huanzhen Shao, Junwei Hu, Qingzhu Zhou, Hung-Yu Wang
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Publication number: 20140010858Abstract: The present invention is directed to polymeric compositions comprising a biodegradable copolymer that possesses shape-memory properties and implantable devices (e.g., drug-delivery stents) formed of materials (e.g., a coating) containing such compositions. The polymeric compositions can also contain at least one non-fouling moiety, at least additional biocompatible polymer, at least one biobeneficial material, at least one bioactive agent, or a combination thereof. The polymeric compositions are formulated to possess good mechanical, physical and biological properties. Moreover, implantable devices formed of materials comprising such compositions can be delivered to the treatment site in a conveniently compressed size and then can expand to dimensions appropriate for their medical functions.Type: ApplicationFiled: May 28, 2013Publication date: January 9, 2014Applicant: Abbott Cardiovascular Systems Inc.Inventors: John J. Stankus, O. Mikael Trollsas, Michael H. Ngo
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Publication number: 20140011935Abstract: A polyurethane or polyurea coating composition for use in protecting a leading edge substrate on an airfoil, such as aircraft wings, rotor blades and propeller blades, against liquid or solid particle erosion, the composition made from a polyisocyanate and curing agents, such as polyaspartic esters, aldimines and ketimines, polyamines and polyols or mixtures thereof with optional flatting agent for matte coatings.Type: ApplicationFiled: September 13, 2013Publication date: January 9, 2014Inventor: Shek Hong
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Patent number: 8623950Abstract: The present invention relates to a preparation method of polyurethaneurea elastic fiber, particularly a preparation method of high heat-resistant elastic fiber which retains unique physical properties of elastic fiber under the high temperature process. The polyurethaneurea elastic fiber of the present invention is characteristically prepared without using 1 functional mono-alcohol generally used to regulate the reaction speed and side-reaction during the prepolymer reaction to produce elastic fiber having excellent heat-resistance particularly for the dyeing processing or re-dyeing of polyester but using ethylenediamine alone as a chain extender for the polymerization. To reduce gel formation in polymer after the secondary polymerization and to regulate change of viscosity in the course of process, the ratio of the chain extender amine to the terminal group of prepolymer of the first polymerization is increased.Type: GrantFiled: December 1, 2008Date of Patent: January 7, 2014Assignee: Tae Kwang Ind. Co., Ltd.Inventors: Ickgy Shin, Inrak Jung, Haedong Kim
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Publication number: 20140001676Abstract: The invention relates to a method for manufacturing a mineral fibre-containing composite and the novel mineral fibre-containing element produced by that method.Type: ApplicationFiled: November 9, 2011Publication date: January 2, 2014Applicant: Rockwool International A/SInventors: Kristian Skovgaard Jorgensen, Cor Ghijzen, Martinus Adriana Baets
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Publication number: 20130323511Abstract: An implantable medical device is disclosed. The medical device includes a substrate and a polymer composition including ascorbic acid, the polymer composition disposed on at least a portion of the substrate.Type: ApplicationFiled: April 17, 2013Publication date: December 5, 2013Applicant: Covidien LPInventor: Mbiya Kapiamba
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Patent number: 8592043Abstract: Disclosed herein is a component comprising a substantially homogeneous composition of at least one polymer selected from the group consisting of epoxies, acetals, polyesters, non-ionic rubbers, non-ionic polyurethanes, polyether sulfones, polyether ether ketones, polyether imides, polystyrenes, polyethylene terephthalates, polyamides, polyimides, polyvinylchlorides, polyphenylene oxides, polycarbonates, acrylonitrile-butadiene-styrene terpolymers, silicones, fluropolymers, and polyolefins, a filler, and a metal plating catalyst. A method of making a component also is described comprising obtaining a polymeric material, a liquid, a filler and a metal plating catalyst; combining the metal plating catalyst with the polymeric material, liquid, and filler to form a substantially homogeneous mixture; and evaporating and/or curing the mixture to form a solidified component.Type: GrantFiled: December 21, 2012Date of Patent: November 26, 2013Assignee: Xerox CorporationInventors: Joseph A Swift, Stanley J Wallace, Roger L Bullock
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Patent number: 8580887Abstract: The present invention relates to new, urethane-group-containing polyisocyanates based on aliphatic and/or cycloaliphatic diisocyanates, and to their use.Type: GrantFiled: July 28, 2011Date of Patent: November 12, 2013Assignee: BASF SEInventors: Oihana Elizalde, Frederic Lucas, Angelika Maria Steinbrecher, Lydie Tuchbreiter
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Patent number: 8580901Abstract: An aqueous crosslinkable coating composition that includes a PU polymer and a vinyl polymer bearing carbonyl groups (i.e., a carbonyl-functional vinyl polymer) and/or latex polymer. The composition also preferably includes carbonyl-reactive amine and/or hydrazine functional groups.Type: GrantFiled: December 18, 2008Date of Patent: November 12, 2013Assignee: Valspar Sourcing, Inc.Inventors: T. Howard Killilea, Robert W. Springate
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Publication number: 20130280431Abstract: A coating for an ink jet printhead front face, wherein the coating comprises an oleophobic low adhesion coating having high thermal stability as indicated by less than about 15 percent weight loss when heated to up to 300° C., and wherein a drop of ultra-violet (UV) gel ink or a drop of solid ink exhibits a contact angle of greater than about 50° and sliding angle of less than about 30° with a surface of the coating, wherein the coating maintains the contact angle and sliding angle after the coating has been exposed to a temperature of at least 260° C. for at least 30 minutes.Type: ApplicationFiled: April 19, 2012Publication date: October 24, 2013Applicant: XEROX CORPORATIONInventors: Varun Sambhy, Kock-Yee Law, Hong Zhao, Darren Smith
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Patent number: 8557388Abstract: A polyurethane or polyurea coating for use in protecting a leading edge substrate on an airfoil against liquid or solid particle erosion, the composition made from an isocyanate-terminated prepolymer and curing agents, such as polyaspartic esters, aldimines and ketimines with optional flatting agent for matte coatings.Type: GrantFiled: June 15, 2010Date of Patent: October 15, 2013Assignee: Hontek CorporationInventor: Shek C. Hong
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Patent number: 8552109Abstract: Disclosed is an aqueous polyurethane resin dispersion which comprises a polyurethane resin which is obtained by reacting (A) a polyurethane prepolymer obtained by reacting (a) a polycarbonate polyol having an alicyclic structure in the main chain, (b) an acidic group-containing polyol compound and (d) a polyisocyanate, and (B) a chain-elongating agent, being dispersed in an aqueous medium, a carboxylic acid group content of the above-mentioned (A) polyurethane prepolymer based on a solid component of (A) the polyurethane prepolymer is 2.0 to 13.0% by weight, and a number of a hydroxyl equivalent of a mixture of the above-mentioned (a) polycarbonate polyol having an alicyclic structure in the main chain, the above-mentioned (b) acidic group-containing polyol compound, and, if necessary, (c) a polyol other than (a) and (b) is 70 to 270.Type: GrantFiled: May 28, 2009Date of Patent: October 8, 2013Assignee: Ube Industries, Ltd.Inventors: Taku Nakamura, Masahiro Naiki, Atsushi Morikami, Fumio Adachi, Manabu Takahashi
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Patent number: 8541482Abstract: The present disclosure relates generally to compositions for nail coatings, and particularly, but not by way of limitation, to polymerizable compositions. The disclosure further relates to methods of making a polymerizable, protective and scratch resistant topcoat layer that can be easily removed.Type: GrantFiled: October 5, 2009Date of Patent: September 24, 2013Assignee: Creative Nail Design, Inc.Inventors: Thong Vu, Douglas D. Schoon
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Publication number: 20130243962Abstract: Provided is a coating material comprising a crosslinker component and a catalyst component, the coating material curing at temperatures of 10 to 80° C., to the use of the coating materials to coat a variety of substrates and to coating compositions comprising coating material.Type: ApplicationFiled: March 15, 2013Publication date: September 19, 2013Inventors: Rainer Lomoelder, Andre Raukamp, Sabine Naumann
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Publication number: 20130231412Abstract: Among other things, the present disclosure provides compositions and methods for an elastomeric cross-linked polyester material. Such an elastomeric cross-linked polyester material, in some embodiments, comprises a plurality of polymeric units of the general formula (-A-B—)p, wherein p is an integer greater than 1; and a plurality of urethane cross-links each of which covalently links two polymeric units to one another, which two linked polymeric unit each had at least one free hydroxyl or amino group prior to formation of the crosslink.Type: ApplicationFiled: August 26, 2012Publication date: September 5, 2013Inventors: Robert S. Langer, Jeffrey M. Karp, Maria Jose Maio Nunes-Pereira, Ben Ouyang, Lino Da Silva Ferreira, Debanjan Sarkar
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Publication number: 20130231441Abstract: The present invention provides coating compositions with excellent curing performance. Curing can occur very rapidly for excellent cycle time, yet with minimal (if any) foaming. A preferred catalyst system helps to provide excellent initial and follow through cure through the entirety of the coating thickness, even with respect to in-mold coating (IMC) applications. Preferred aspects of the invention provide a composition having zero, or nearly zero, emissions of volatile organic compounds (VOC) when applied and cured.Type: ApplicationFiled: March 29, 2013Publication date: September 5, 2013Applicant: Valspar Sourcing, Inc.Inventors: Brian A. Robertson, Ranjit R. Pachha
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Patent number: 8519050Abstract: A resin precursor composition includes an isocyanate component, a first polyol having a molecular weight of between approximately 600 and 800 and an OH index of between approximately 200 and 300 mgOH/g, and a second polyol having a molecular weight of between approximately 100 and 300 and an OH index of between approximately 800 and 1,200 mgOH/g.Type: GrantFiled: November 8, 2010Date of Patent: August 27, 2013Assignee: Milgard Manufacturing IncorporatedInventors: Randall J. Brown, Semen Kharchenko, Harry D. Coffee, Icheng Huang
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Publication number: 20130209729Abstract: The present invention relates to an improved composition comprising a blend of diisocyanates of Formula (II) derived from their corresponding dianiino alkyl esters obtained from soy protein source, wherein R is an alkyl and n is 1-4, and methods of making and using such compositions as construction material resin binders, in particular, wood resin binders and/or adhesives.Type: ApplicationFiled: August 16, 2011Publication date: August 15, 2013Applicant: INVENTURE RENEWABLES, INC.Inventors: Mark G. Tegen, William Rusty Sutterlin
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Patent number: 8507616Abstract: A pigmented adhesive, halo-free heat transfer label is created when adhesive properties are incorporated into colored inks used to print graphics on labels for items such as apparel. The resulting label has a halo-free graphic applied thereto that eliminates the need for a separate application of adhesive to the label. A pigmented adhesive composition for use with heat transfer type labels includes a hydroxyl-functional polyurethane dispersion, one or more polyurethane dispersions different from the hydroxyl-functional polyurethane dispersion, a blocked cross-linking agent, a catalyst for the blocked cross-linking agent, a pigment dispersion, and an adhesive powder, which are combined prior to the formation of a graphic created using the combined mixture, on the release layer of a substrate.Type: GrantFiled: April 27, 2011Date of Patent: August 13, 2013Assignee: Illinois Tool Works Inc.Inventors: Weide Victor Yang, Alan C. Grotefend, Michael B. Colella
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Patent number: 8507585Abstract: A non-aqueous pigment ink comprising a pigment, a non-aqueous solvent, and non-aqueous resin dispersion microparticles having a pigment dispersion capability, wherein the non-aqueous resin dispersion microparticles are an acrylic polymer comprising an alkyl (meth)acrylate unit having an alkyl group of 12 or more carbon atoms and a (meth)acrylate unit having a urethane group. The acrylic polymer is a copolymer of a monomer mixture comprising an alkyl (meth)acrylate (A) having an alkyl group of 12 or more carbon atoms and a reactive (meth)acrylate (B) having a functional group capable of reacting with an amino group, wherein the urethane group is introduced by a reaction between the functional group capable of reacting with an amino group, an amino alcohol and a polyvalent isocyanate compound, and the mass ratio within the acrylic polymer between the copolymer portion and the introduced urethane group portions is within a range from 60:40 to 99:1.Type: GrantFiled: April 8, 2009Date of Patent: August 13, 2013Assignee: Riso Kagaku CorporationInventors: Tetsuo Hosoya, Hiroshi Hayashi, Yoshifumi Watanabe, Kazuyuki Ando, Marie Morinaga
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Publication number: 20130203934Abstract: A polyurea coating composition comprising the reaction product of: an isocyanate-functional component (A) comprising: a) an aliphatic isocyanate functional material; and b) a cycloaliphatic isocyanate functional material; and an isocyanate-reactive component (B) comprising at least one polyaspartic acid ester component.Type: ApplicationFiled: April 5, 2011Publication date: August 8, 2013Applicant: Bayer MaterialScience LLCInventors: Kurt E. Best, John P. Forsythe, Joseph R. Kleer, Michael K. Jeffries
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Patent number: 8500947Abstract: The present disclosure provides compositions having reduced viscosity which may be used as adhesives or tissue sealants, and includes methods for speeding the cure rate of such compositions.Type: GrantFiled: October 27, 2008Date of Patent: August 6, 2013Assignee: Covidien LPInventor: Ferass Abuzaina
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Patent number: 8501867Abstract: The mixture of the invention comprises at least one cycloaliphatic polyisocyanate and at least one solvent comprising an ester function and an ether function. An aqueous emulsion can be obtained from this mixture which also comprises a compound bearing a function with a mobile hydrogen, selected from primary or secondary hydroxyl functions, phenol functions, primary and/or secondary amino functions, carboxylic functions and a thiol function or a compound containing precursor functions capable of freeing hydroxyl functions. The emulsion can be used for the manufacture of coatings on a substrate of cement, of wood or especially of leather, and also for the manufacture of adhesives.Type: GrantFiled: April 29, 2008Date of Patent: August 6, 2013Assignee: Vencorex FranceInventors: Philippe Barbeau, Philippe Olier, Johannes Schwarz
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Patent number: 8497013Abstract: A primer-less coating composition for facestock comprises: a binder being a water-dispersible polymer; an ethylenically unsaturated compound which is aqueous-dispersible and miscible with or bonded to said water-dispersible polymer, wherein said ethylenically unsaturated compound is able to form a covalent bond with an ink; and a crosslinker, wherein said crosslinker is suitable for binding the coating to the facestock. The coating composition may be applied to a substrate to form a printable film. A printed film in accordance with the invention may be used in a label, for example for use on a container such as a bottle.Type: GrantFiled: November 2, 2011Date of Patent: July 30, 2013Assignee: Innovia Films LimitedInventors: Alastair Hugh Servante, Simon James Read
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Patent number: 8497316Abstract: It concerns a crosslinkable and foaming polyester-polyurethane resin moulding composition, comprising: an A component, comprising: A1) at least one poly-functional isocyanate compound, and A2) at least one free radical polymerization initiator a B component, comprising by weight: B1) 100 parts of at least one polyol resin comprising: —B11) 50 to 80 parts of at least one ethylenically unsaturated polyester polyol—B 12) 20 to 50 parts of at least one ethylenically unsaturated monomer, with, B11), being the reaction product of: a) an acid component comprising: a1) at least one ethylenically unsaturated diacid, and a2) at least one saturated diacid with a1/a2 molar ratio so varying to have an unsaturation content in B11) from 0.25/1 to 5/1, and, b) a diol component in excess with respect to component a) B2) from 0.01 to 1.Type: GrantFiled: September 29, 2008Date of Patent: July 30, 2013Assignee: CCP Composites UK LtdInventors: Paul Darby, Phil Dean
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Patent number: 8492458Abstract: A solvent borne polyurethane composition with a polymodal molecular weight distribution comprising: i) 10 to 90 wt % of at least a polyurethane A with a Mw in the range of from 4,000 up to 25,000 g/mol, ii) 90 to 10 wt % of at least a polyurethane B with a Mw in the range of from 25,000 to 100,000 g/mol and iii) a liquid medium.Type: GrantFiled: June 25, 2012Date of Patent: July 23, 2013Assignee: DSM IP Assets B.V.Inventors: Ester Parra Pastor, Joan Tiana Ruiz, Urs Jürgen Frieden Hugel