Abstract: The invention relates to acetoacetylated lignin resin compositions comprising the reaction product of lignin and an acetoacetate ester. The invention also relates to (meth)acrylated lignin resin compositions comprising the reaction product of lignin and a (meth)acrylic compound. The invention also relates to methods of making the acetoacetylated and (meth)acrylated lignin resin compositions. The invention also relates to curable coating compositions comprising the acetoacetylated and (meth)acrylated lignin resin compositions. The invention also relates to methods of making the curable coating compositions of the invention. The invention also relates to methods of applying curable coating compositions of the invention to substrates. The invention also relates to articles of manufacture comprising a curable coating composition of the invention and a method of making such article.

Abstract: A powder composition suitable for laser sintering for printing a three-dimensional object obtained by pre-heating a raw PEKK to evaporate a liquid solvent in the raw PEKK and the grinding the raw PEKK to form a PEKK powder, the powder composition having a first fraction comprising a polyetherketoneketone (PEKK) powder having a plurality of particles, the plurality of particles having a mean diameter D50 in the range of 30 ?m to 150 ?m. The plurality of particles of the first fraction are substantially non-spherical.

Abstract: A method and apparatus for heat treating powders of semi-crystalline or crystallizable polymers. The apparatus includes a heating device for heating the powder to a temperature that is less than the melting temperature of a highest melting crystalline form of the powder, a vessel containing the powder that is exposed to heat produced by the heating device, and a mechanism for moving the vessel to cause the powder within the vessel to move with respect to the vessel.

Abstract: An apparatus, system and method for additive manufacturing. The apparatus, system and method may include a solution dispenser comprising a carrier having embedded therein particles having a size of about 1-5 microns; a jet suitable to disperse the solution from the dispenser; and a tunable heat filter suitable to burn off the carrier, and make molten the particles, as the solution passes therethrough; wherein an additive manufacturing print build receives the molten particles.

Abstract: A build material for additive manufacturing applications is disclosed. The build material includes a build composition in powder form. The build composition includes a semi-crystalline polymer having a glass transition temperature of at least 60° C. as measured by DSC and a minimum crystallization half-time of greater than 100 minutes as measured by SALS. A semi-crystalline polymer useful in additive manufacturing applications, an additive manufacturing method for producing a three-dimensional object and an additive-manufactured polymer article are also described.

Abstract: A roll-to-roll manufacturing machine suitable for processing and producing polymer films that contain nanostructures, including but not limited to multifunctional polymer films. The machine applies a liquid polymer on a substrate to form a liquid polymer film, at least partially embeds nanostructures into the liquid polymer film, melt casts a layer of a molten polymer on the liquid polymer film to produce a thin polymer film, organizes the nanostructures in a thickness direction of the thin polymer film comprising applying an electric field to the thin polymer film, aligns the nanostructures in the thin polymer film by simultaneously subjecting the thin polymer film to heat and a field that aligns the nanostructures, and solidifies the thin polymer film to freeze the nanostructures along nanocolumns in a thickness direction of a solidified polymer film resulting therefrom.

Abstract: Disclosed is a polymer-metal junction including a polymer composition in contact with a metal substrate, where the polymer composition comprises a polymer component including a PEEK-PEDEK copolymer having a PEEK/PEDEK mole ratio ranging from about 60/40 to about 30/70 and a melting point (Tm) greater than 320° C., and where the polymer composition includes less than 10 wt. % of a sulfur-or-carbonyl-containing solvent, based on the total weight of the polymer composition. Also disclosed are methods of making the polymer-metal junction and articles including the polymer-metal junction.

Abstract: The disclosure relates to the field of lithium-ion batteries, and discloses a polymer composite membrane and a method for preparing same. The disclosure further includes a lithium-ion battery for which the foregoing polymer composite membrane is used. The polymer composite membrane includes a porous base membrane and a heat-resistant fiber layer covering at least one side surface of the porous base membrane, where materials of the heat-resistant fiber layer contain a first polymeric material and a second polymeric material.

Abstract: Controlled release polyurea microcapsules can be prepared from a combination of polyisocyanates using emulsion polymerization. Encapsulated catalysts prepared using the polyurea microcapsules can be used to control the cure rate of coatings and sealants.

Abstract: A dental resin composite material is provided that is reduced in darkness of its color tone, and also reduced in burning and color unevenness. Specifically provided are a dental resin composite material including 100 parts by mass of a polyaryletherketone resin, 10 parts by mass to 300 parts by mass of inorganic particles, and 90 ppm or less of an impurity having an aromatic ring, a method of producing the dental resin composite material, and a polyaryletherketone resin for producing a dental resin composite material, to be used for producing the dental resin composite material.

Abstract: The invention relates to a compound comprising at least two —(NH—C?O)— groups and at least two —(C?O)—C?C—R1 groups, wherein R1 represents hydrogen or a group having from 1 to 12 carbon atoms; a curable composition comprising a first unit comprising at least two —(NH—C?O)— groups, a second unit comprising at least two —(C?O)—C?C—R1 groups, and a catalyst; and the use of the composition as an adhesive, coating, casting composition or as sealant.

Abstract: Fibers sized with a coating of amorphous polyetherketoneketone are useful in the preparation of reinforced polymers having improved properties, wherein the amorphous polyetherketoneketone can improve the compatibility of the fibers with the polymeric matrix.

Abstract: Provided is a molding material comprising a composite of 1 to 50 wt % of a continuous reinforcing fiber bundle (A) and 0.1 to 20 wt % of a poly (phenylene ether ether ketone) oligomer (B); and 30 to 98.9 wt % of a thermoplastic resin (C) adhering to the composite, wherein the component (B) has a melting point of not higher than 270° C. Also provided are a method for molding the molding material, a method for producing the molding material, and a method for producing a fiber-reinforced composite material. A molded article having high heat resistance and dynamic properties can be easily produced without impairing the economic efficiency and productivity during the process for producing a molding material. In addition, a fiber-reinforced composite material can be produced with more ease and high productivity.

Abstract: A frame sealant and a sealing method, a display panel and a display device containing the frame sealant. A sealing method for a frame sealant comprises: successively coating a water-borne epoxy resin and a solvent-based epoxy resin or successively coating a solvent-based epoxy resin and a water-borne epoxy resin on a first substrate, aligning and pressing the first substrate and a second substrate; or coating a water-borne epoxy resin on a first substrate, coating a solvent-based epoxy resin on a second substrate, and aligning and pressing the two substrates; a first material by which a nano-scale second material is encapsulated is dispersed in the solvent-based epoxy resin, wherein, the first material is a hydrophilic polymeric material and the second material is one which will undergo an exothermic reaction with water.

Abstract: The present invention relates to branched polymers which contain hydroxyl groups and acrylate groups, to processes for preparing them, and to their use.

Abstract: Processes for increasing the chemical resistance of a surface of a formed article are disclosed. The formed article is produced from a polymeric composition comprising a photoactive additive containing photoactive groups derived from a monofunctional benzophenone. The surface of the formed article is then exposed to ultraviolet light to cause crosslinking of the photoactive additive and produce a crosslinked surface. The crosslinking enhances the chemical resistance of the surface. Various means for controlling the depth of the crosslinking are also discussed.

Abstract: Water-borne cross-linking polymeric compositions and related embodiments, such as methods of making and using the compositions, as well as products formed with said compositions are described. The water-borne composition may comprise one or more polymers formulated from one or more monomers of which at least one is a monomer that yields acetaldehyde as a hydrolysis product, and incorporating cross-linking functionality such as, but not limited to, carbonyl or epoxy functionality, and a blocked cross-linking agent, for example, a hydrazone. Neither the cross-linking functionality nor the acetaldehyde reacts with the blocked cross-linking agent; however, the blocked cross-linking agent is capable of conversion to an alternative form cross-linking agent such as, but not limited to, a hydrazide, to yield a cross-linked polymer. The alternative form cross-linking agent may be formed in an equilibrium reaction including the blocked cross-linking agent.

Abstract: A novel novolac prepared by acid catalyzed condensation between biphenols or bisphenofluorenes and fluorenone is presented. The polymers exhibit excellent oxidative thermal stability and high carbon content, suitable for dielectric, etch stop applications as spin-on material.

Abstract: A resist underlayer film-forming composition for forming a resist underlayer film having both dry etching resistance and heat resistance. A resist underlayer film-forming composition comprising a polymer containing a unit structure of Formula (1): In Formula (1), R3 is a hydrogen atom, and both n1 and n2 are 0. A method for producing a semiconductor device comprising the steps of: forming an underlayer film on a semiconductor substrate using the resist underlayer film-forming composition; forming a hard mask on the underlayer film; further forming a resist film on the hard mask; forming a resist pattern by irradiation with light or electron beams and development; etching the hard mask using the resist pattern; etching the underlayer film using the hard mask patterned; and fabricating the semiconductor substrate using the patterned underlayer film.

Abstract: There is provided a composition for forming a passivation film that satisfies electric insulation, heat-tolerance, solvent-tolerance, and a dry etch back property at the same time.

Abstract: The present disclosure provides injectable synthetic and biodegradable polymeric biomaterials that effectively prevent seroma, a common postoperative complication following ablative and reconstructive surgeries. Provided biomaterials include physically crosslinked hydrogels that are thixotropic, display rapid chain relaxation, are easily extruded through narrow gauge needles, biodegrade into inert products, are well tolerated by soft tissues, and effectively prevent seroma in a radical breast mastectomy animal model.

Abstract: Disclosed are coating compositions that can be one-component, ambient curable, and waterborne. The coating compositions include a polymer that is the reaction product of a polycarbodiimide and a ketocarboxylic acid. Also disclosed are substrates coated with a coating deposited from such compositions, as well as methods for depositing a coating on a substrate, and coated substrates.

Abstract: A polymer colorant including polymer monomer units, and at least one alizarin unit which is incorporated into the polymer and which provides color to the polymer colorant and a process for preparing the polymer colorant. An article or composition containing the polymer colorant. A toner including the polymer colorant, and optionally, one or more ingredients selected from the group consisting of crystalline polyester resins, amorphous polyester resins, colorants, waxes, coagulants, mordants, and mixtures and combinations thereof. A polymer latex including an aqueous dispersion of polymer colorant, wherein the polymer colorant comprises polymer monomer units and at least one alizarin unit which is incorporated into the polymer and which provides color to the polymer colorant; and optionally, a mordant.

Abstract: Disclosed is cross-linking process for cross-linking polymeric chains in a coating composition. In one embodiment the process utilizes a Hantzsch dihydropyridine reaction to form reaction products including cross-linking polymeric resin chains having beta-keto ester functions using a source of aldehyde and a source of ammonia or a primary amine to form a permanent dihydropyridine bond between the beta-keto ester functions. The novel cross-linking reaction can occur at lower temperatures compared to typical cross-linking reactions and can occur in aqueous solutions that have a neutral to mildly alkaline pH of from 6 to 11. The novel cross-linking reaction provides many advantages to performing cross-linking of polymeric chains in coating resins.

Abstract: The present invention is directed to photoactive resins employed in radiation curable compositions and ink. The radiation curable compositions include mono or multi-functional acrylates, an amine and the above-mentioned photoactive resin. Radiation curable inks at least include the components of the radiation curable composition in addition to colorants.

Abstract: A local probe storage array is provided that includes a substrate, and a polymeric layer over the substrate, the polymeric layer comprising a crosslinking agent that has been cured, the crosslinking agent comprising at least three alkyne groups.

Abstract: The invention includes a cross-linking composition comprising a cross-linking compound and a cross-linking reaction additive selected from an organic acid and/or an acetate compound, wherein the cross-linking compound has the structure according to formula (IV): wherein the cross-linking reaction additive is capable of reacting with the cross-linking compound to form a reactive oligomer intermediate, which is capable of cross-linking an organic polymer. Also included is an organic polymer composition for use in forming a cross-linked organic polymer, comprising a cross-linking compound of Formula (IV), a cross-linking reaction additive and at least one organic polymer. In one embodiment, the at least one organic polymer has at least one halogen-containing reactive group and is dehalogenated by reacting with an alkali metal compound.

Abstract: Embodiments of the present invention include composite compositions extrusion compounded together comprising a polymer, an amount of nanotubes, and an amount of finely milled carbon fiber having an aspect ratio greater than 1 and less than about 5. The resulting composite materials allow for high carbon loading levels with improved tribological properties including coefficient of friction and wear rates, provides uniform surface resistance with minimal processing sensitivity, retains rheological properties similar to the base resin, and provides isotropic shrink and a reduced coefficient of thermal expansion leading to minimal warp. In general, various articles can be formed that take advantage of the properties of the composite materials incorporating a polymer, carbon nanotubes and finely milled carbon fiber.

Abstract: Photoactive additives, such as cross-linkable polycarbonate resins, are disclosed. The additive is formed from the reaction of a monohydroxybenzophenone, a dihydroxybenzophenone, a diol chain extender, and one or more linker moieties having functional groups that react with the phenolic groups on the other ingredients. If desired, a secondary linker moiety and/or an end-capping agent can be used. When added to a base polymeric resin, the photoactive additive permits crosslinking when exposed to ultraviolet light.

Abstract: Fibers sized with a coating of amorphous polyetherketoneketone are useful in the preparation of reinforced polymers having improved properties, wherein the amorphous polyetherketoneketone can improve the compatibility of the fibers with the polymeric matrix.

Abstract: A resin having a fluorene structure, a relatively high carbon concentration in the resin, a relatively high heat resistance and a relatively high solvent solubility has a structure represented by wherein each of R3 and R4 independently denotes a benzene ring or a naphthalene ring, a carbon atom at the bridgehead of a fluorene backbone or (di)benzofluorene backbone is bonded with a carbon atom of each of other aromatic rings, and a carbon atom of each of aromatic rings of a fluorene backbone or (di)benzofluorene backbone is bonded with a carbon atom at the bridgehead of other fluorene backbone or (di)benzofluorene backbone. The resin can be applied to a wet process. Methods for producing the resin, for forming an underlayer film useful for forming a novel resist, and for pattern forming using the material, and an underlayer film excellent in heat resistance and etching resistance for multilayer resist are described.

Abstract: Polymers comprising polyetheretheretherketone and polyetherdiphenyletherketone and polymers comprising polyetheretheretherketone and polyetheretherethersulphone are described which have advantageous Tn and/or Tg properties.

Abstract: An upright column is packed with particles of a first material so the particles touch one another and a network of voids is defined between the particles. The network will be substantially continuous. A second material is then introduced into the column so the second material penetrates the network and fills the voids. The mixture of first and second materials is then consolidated using heat to melt the first or second material, whilst the other one of the first or second material remains in a solid state and acts as a space holder. Thereafter, the material which acts as the space holder may be removed thereby to leave a substantially continuous porous network defined by the material which was melted. It is found that, by use of the method, a substantially continuous network of the material which is melted can be formed and that the other material can readily be removed and/or is more easily removed compared to if a mixture of first and second materials was formed prior to packing in a column or mould.

Abstract: The invention relates to a protective device (1) for the laser machining of holes (3) in at least one component (2) by means of a laser beam (5), wherein the protective device (1) is positionable in the beam direction downstream of the beam-exit-side end (8) of a hole (3) to be machined in the component wall (10), in order to protect an adjoining rear space having a component wall (11), opposite the hole (3), of the component (2) from the incident laser beam. The protective device (1) according to the invention is formed from a composite made of a matrix composed of polyether ether ketone plastics material and fibres embedded therein, wherein the fibres are embedded such that, with respect to their particular fibre extending direction, they extend in a criss-cross manner in the plastics material and are distributed at approximately the same density in the volume of the plastics material of the protective device (1).

Abstract: A phenolic self-crosslinking polymer whose self-crosslinking reaction at a heating step is performed without additives for hardening the polymer, and a composition of resist-underlayer-film containing the same, are disclosed.

Abstract: A process for the production of a particle composition containing, at least one resin and at least one pigment is described, said process comprising the following steps: •extrusion of a mixture containing said at least one resin and said at least one pigment without induced heating; •subsequent extrusion, with induced heating, of the mixture obtained from the preceding extrusion; •granulation of the mixture thus obtained. With the abovementioned process it is possible to obtain a composition having granules with an average diameter less than 2 microns and a greater homogeneity than the known processes.

Abstract: Provided is an ink composition capable of forming images having excellent water resistance, excellent solvent resistance and excellent adhesiveness to base materials, the ink composition including (Component A) a polymer containing a repeating unit (a1) having at least one of an aromatic ketone structure and an aliphatic 1,2-diketone structure, a repeating unit (a2) having at least one of a tertiary amine structure and a thiol structure, and a repeating unit (a3) having an ethylenically unsaturated double bond, and (Component B) a coloring material.

Abstract: Disclosed herein are compositions including a cross-linked polycarbonate. The cross-linked polycarbonate may be derived from a polycarbonate having about 0.5 mol % to about 5 mol % endcap groups derived from a monohydroxybenzophenone. A plaque including the composition can achieve a UL94 5VA rating. Also disclosed herein are articles including the compositions, methods of using the compositions, and processes for preparing the compositions.

Abstract: Processes for increasing the chemical resistance of a surface of a formed article are disclosed. The formed article is produced from a polymeric composition comprising a photoactive additive containing photoactive groups derived from a monofunctional benzophenone. The surface of the formed article is then exposed to ultraviolet light to cause crosslinking of the photoactive additive and produce a crosslinked surface. The crosslinking enhances the chemical resistance of the surface. Various means for controlling the depth of the crosslinking are also discussed.

Abstract: Disclosed herein are compositions including a cross-linked polycarbonate. The cross-linked polycarbonate may be derived from a polycarbonate having about 0.5 mol % to about 5 mol % endcap groups derived from a monohydroxybenzophenone. A plaque including the composition can achieve a UL94 5VA rating. Also disclosed herein are articles including the compositions, methods of using the compositions, and processes for preparing the compositions.

Abstract: Provided is a molding material comprising a composite of 1 to 50 wt % of a continuous reinforcing fiber bundle (A) and 0.1 to 20 wt % of a poly(phenylene ether ether ketone) oligomer (B); and 30 to 98.9 wt % of a thermoplastic resin (C) adhering to the composite, wherein the component (B) has a melting point of not higher than 270° C. Also provided are a method for molding the molding material, a method for producing the molding material, and a method for producing a fiber-reinforced composite material. A molded article having high heat resistance and dynamic properties can be easily produced without impairing the economic efficiency and productivity during the process for producing a molding material. In addition, a fiber-reinforced composite material can be produced with more ease and high productivity.

Abstract: Reactive extrusion can be used in a continuous, solvent-less preparation of imide oligomers involving two competing reactions among three ingredients, the first reaction between a dianhydride and a diamine and the second reaction between an endcap and the diamine. The imide oligomer can form a composite via conventional production methods or via formation of a film from imide oligomer re-melted in an extruder before being impregnated into tape or fabric.

Abstract: Embodiments of the present disclosure provide polymer compositions, methods of making polymer compositions, structures having the polymer composition covalently bonded to the surface of the structure, methods of attaching the polymer to the surface of the structure, methods of decreasing the amount of virus on a structure, methods of killing or reducing the amount of virus on a surface, and the like.

Abstract: The invention provides a resin component used within a memory disk drive device and a highly reliable memory disk drive device using the resin component, the resin component having excellent flame resistance and minimal outgas. A resin component used inside a memory disk drive device (1), the resin component being an insulating bushing for protecting a lead of a motor (2) when the lead is connected to a circuit board; a carriage (4) being molded integrally with a coil for driving a swing arm (3) provided with a pickup head (3a) for reading or writing information on a memory disk on a distal end thereof, and the carriage adapted for balancing the weight of the swing arm (3); or a ramp (5) for retracting the pickup head (3a) when the memory disk stops. The resin component is a resin article molded from an amorphous resin, a crystalline resin, or a liquid crystal polymer resin, the molded resin article having 30 ppm or less outgas when measured by a prescribed method.

Abstract: The invention describes powders for use in the production of spatial structures, i.e. molded bodies, using layer build-up methods, as well as methods for their efficient production. The powders have the special feature that they have good flow behavior, for one thing, and at the same time, have such a composition that the molded body that can be produced with the powder, using rapid prototyping, has significantly improved mechanical and/or thermal properties. According to a particularly advantageous embodiment, the powder has a first component that is present in the form of essentially spherical powder particles, which is formed by a matrix material, and at least one further component in the form of stiffening and/or reinforcing fibers, which are preferably embedded in the matrix material.

Abstract: Modified polyphenol binder compositions and methods for making and using same are provided. In at least one specific embodiment, the binder composition can include at least one unsaturated monomer and at least one polyphenolic compound. The polyphenolic compound can include a lignin, a tannin, a novolac resin, a modified phenol formaldehyde resin, bis-phenol A, humic acid, or any mixture thereof.

Abstract: A method of manufacturing a film or membrane includes: (a) dissolving at least one polymer comprising a poly(aryl ketone) in at least one solvent to form a dope; (b) depositing the dope on a substrate to form a coated substrate at appropriate conditions; and (c) drying the coated substrate to form the film or membrane. The dope may also include additional polymers or fillers, such as carbon nanotubes.

Abstract: A polyaryletherketone polymeric material, for example polyetheretherketone and composite materials comprising said polymeric material are described. The polymeric material has a melt viscosity (MV) in the range 0.05 to 0.12 kNsm?2, preferably in the range 0.085 to 0.095 kNsm?2.

Abstract: Technologies are generally described for a system and method effective to prepare a flame retardant. In one example, a method may include copolymerizing a mixture of monomers. The mixture of monomers may include at least one dicarboxylic acid monomer, at least one diamine monomer, and at least one monomer having the formula (I) wherein R1 is hydroxyl, halogen, alkoxy, or aryloxy; wherein R2 is hydroxyl, halogen, alkoxy, or aryloxy; wherein R3 is H or -L-R5; wherein R4 is H or L-R5; wherein if R3 is H, then R4 is L-R5; wherein L is alkyl, cycloalkyl, aryl, heteroaryl, or —(R6-O—R7)n-; wherein R6 is alkyl, cycloalkyl, aryl, or heteroaryl, wherein R7 is alkyl, cycloalkyl, aryl, or heteroaryl, wherein n is an integer from 1 to 12; wherein R5 is a flame retarding moiety comprising P, N, halogen, or B; and wherein q is an integer from 1 to 12.

Abstract: The invention relates to novel benzo[1,2-b:4,5-b?]dithiophene-2,6-diyl-alt-thieno[3,4-b]thiazole-4,6-diyl polymers, methods for their preparation and monomers used therein, blends, mixtures and formulations containing them, the use of the polymers, blends, mixtures and formulations as semiconductor in organic electronic (OE) devices, especially in organic photovoltaic (OPV) devices, and to OE and OPV devices comprising these polymers, blends, mixtures or formulations.