Nitrogen-containing Reactant Patents (Class 524/597)
  • Patent number: 5750597
    Abstract: A thermosetting resin composition which can be used to produce pultruded products with a lustrous surface finish comprises about 60% to about 95% by weight of an uncured, liquid phenolic resin containing about 70-90% solids by weight and about 5 to about 40% of particles of a molding composition comprising an uncured, solid phenolic resin and a suitable filler.
    Type: Grant
    Filed: June 20, 1996
    Date of Patent: May 12, 1998
    Assignee: Plastics Engineering Company
    Inventor: Phillip A. Waitkus
  • Patent number: 5750634
    Abstract: Disclosed is a soluble polycondensation product based on amino-s-triazines with at least two amino groups and forma ehyde, a process for making the product and the use thereof as an additive for an aqueous binding agent suspension.
    Type: Grant
    Filed: March 18, 1996
    Date of Patent: May 12, 1998
    Assignee: SKW Trostberg Aktiengesellschaft
    Inventors: Gerhard Albrecht, Josef Weichmann, Ludwig Eibl, Christian Huber, Alfred Kern
  • Patent number: 5728797
    Abstract: A suspension of finally divided hardened aminoplast or phenoplast resin, particularly melamine-formaldehyde resin, is prepared by mixing an aqueous solution of the resin or its precursors with a water-insoluble stabilizing agent, particularly microcrystalline cellulose; sufficient water is provided to exceed the water tolerance level of the resin and thus form a uniform emulsion or suspension of resin particles in water. Cure of the resin is then advanced such as by heating to form partially or fully cured resin particles of relatively uniform particle size.
    Type: Grant
    Filed: August 18, 1995
    Date of Patent: March 17, 1998
    Assignee: International Paper
    Inventors: Robin D. O'Dell, Jayesh Shah, Alice M. Simon
  • Patent number: 5710239
    Abstract: The present invention relates to a sulfonated water-soluble melamine-formaldehyde resin, to a method of manufacturing the resin, and to insulation products prepared using the resin. The resin is particularly useful for making thermal insulation having low moisture adsorption, high tensile strength and low formaldehyde emissions.
    Type: Grant
    Filed: February 29, 1996
    Date of Patent: January 20, 1998
    Assignee: Georgia-Pacific Resins, Inc.
    Inventor: Kim K. Tutin
  • Patent number: 5684118
    Abstract: A method of scavenging formaldehyde in formaldehyde-based resins using a low mole ratio melamine-urea-formaldehyde resin composition. In addition, a formaldehyde-based resin containing a storage-stable low mole ratio melamine-urea-formaldehyde resin composition as a formaldehyde scavenger.
    Type: Grant
    Filed: March 26, 1996
    Date of Patent: November 4, 1997
    Assignee: Georgia-Pacific Resins, Inc.
    Inventors: Robert A. Breyer, Bill R. Arndell, Semyon Stompel
  • Patent number: 5681917
    Abstract: A low mole ratio melamine-urea-formaldehyde resin useful as a binder for making a variety of products, and a method for making the resin. The melamine-urea-formaldehyde resin thus produced is stable and has low formaldehyde emissions (release).
    Type: Grant
    Filed: March 26, 1996
    Date of Patent: October 28, 1997
    Assignee: Georgia-Pacific Resins, Inc.
    Inventors: Robert A. Breyer, Solona G. Hollis, Joseph J. Jural, deceased
  • Patent number: 5627232
    Abstract: A water-containing composition containing a linear aminoplast-ether copolymer of the formula: ##STR1## where the divalent R.sub.01 contains a divalent alkyleneoxy containing moiety, Amp is the skeletal residue of an aminoplast, R is hydrogen, alkyl containing 1 to about 4 carbon atoms, and acyl containing 1 to about 4 carbon atoms, p is a positive number that is equal to the free valence of Amp minus 2, RO is bonded to alkylene units of Amp, and a is a number greater than 1.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: May 6, 1997
    Assignee: United Catalysts, Inc.
    Inventors: Charles W. Glancy, Alan L. Steinmetz
  • Patent number: 5610263
    Abstract: This invention provides a polymeric vehicle and formulated coating composition which are high in solids and use water to effect viscosities to permit application of such polymeric vehicles and formulated coating compositions with existing commercial application equipment. The polymeric vehicles and formulated coatings include at least one oligoester diol, a carbamate hardener, and in some instances, an additional crosslinking agent. The combination of oligoester diol with carbamate hardener provides a low viscosity coating composition with low to zero VOC content, and provides a coating binder with extremely good film properties.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: March 11, 1997
    Assignee: Eastern Michigan University
    Inventors: Frank N. Jones, Shou-Kuan Fu, Wen Jing, Suru Zhang
  • Patent number: 5599884
    Abstract: Amino resins that contain more free formaldehyde than is desirable for health and/or pollution reasons can be treated with a mixture of diketo reagents (or their nitrogen analogs) and other compounds containing amino moieties to reduce the free formaldehyde content while not diminishing, and in some cases even enhancing, the ability of the resins to function according to their normal uses. The invention is especially useful for melamine-formaldehyde resin dispersions useful to detackify paint.
    Type: Grant
    Filed: May 8, 1995
    Date of Patent: February 4, 1997
    Assignee: Henkel Corporation
    Inventor: Scott J. Beleck
  • Patent number: 5589536
    Abstract: The present invention relates to a glass fiber binding composition comprising an effective binding amount of an aqueous soluble furan resin, 15 to 99 percent by weight water, and an effective amount of a catalyst for curing the furan resin. The invention further pertains to a process of binding glass fibers at junctions of the fibers comprising the steps of providing newly formed glass fibers, applying an effect binding amount of an aqueous soluble furan resin to the junctions of the glass fibers, and curing the resin at the junctions of the glass fibers. Finally, the invention also discloses a glass fiber composition comprising a plurality of glass fibers having a plurality of junctions where two or more fibers meet, and an effective binding amount of an aqueous soluble furan resin comprising 15 to 99% water applied to the junctions of the glass fibers.
    Type: Grant
    Filed: March 13, 1995
    Date of Patent: December 31, 1996
    Assignees: QO Chemicals, Inc., Schuller International, Inc.
    Inventors: Carlo M. Golino, Thomas J. Taylor, William H. Kielmeyer, Leo K. Thiessen, Carl A. Rude
  • Patent number: 5558709
    Abstract: Disclosed is a flow improving agent for binder suspensions containing cement which is composed of a) amino-s-triazine-formaldehyde-sulfite condensation products having a molar ratio of amino-s-triazine:formaldehyde:sulfite of 1:1.3 to 6.0: 0.3 to 1.5 and a low content of free formaldehye as well as b) casein. The flow improving agents have the advantage that the flowability is considerably improved compared to casein (alone) for example and the increased flowability remains constant even over a longer time period.
    Type: Grant
    Filed: August 22, 1995
    Date of Patent: September 24, 1996
    Assignee: SKW Trostberg
    Inventors: Josef Weichmann, Aloisia Stadler, Alfred Kern
  • Patent number: 5476949
    Abstract: Finely divided 1,4-diketopyrrolo[3,4-c]pyrroles of the formula ##STR1## where A and B are each independently of the other a radical of the formula ##STR2## wherein at least 84% by weight of the particles have a Stokes equivalent diameter of .ltoreq.0.25 .mu.m, and mixtures thereof.The substituents R.sub.1 and R.sub.2 are defined in claim 1.These pigments are notable for a very pure hue and outstanding transparency.
    Type: Grant
    Filed: July 21, 1994
    Date of Patent: December 19, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Olof Wallquist, Gary Wooden, Thomas Eichenberger, Ingo Schloder
  • Patent number: 5473043
    Abstract: Moisture-curable urethane resin compositions comprising: (a) a urethane prepolymer having two or more terminal isocyanate groups, (b) a blocked amine compound which is essentially nonreactive with an isocyanate group and generates a primary or a secondary amino group upon contact with water, and (c) an inorganic filler treated with an organic compound, are disclosed. More particularly, the urethane resin compositions comprise a hydrophilic urethane prepolymer having oxyethylene moieties, and a blocked amine compound having two or more oxazolidine rings.
    Type: Grant
    Filed: April 8, 1994
    Date of Patent: December 5, 1995
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Hirohisa Maki, Shigenobu Miyamoto, Ryoji Fujimoto, Toshiki Noda
  • Patent number: 5466734
    Abstract: An aqueous cold seal release varnish comprising the reaction product of a mixture comprising 30-50 parts of a polyamide block copolymer having an acid value of 30-45, 1-5 parts of an amide wax, 10-20 parts of at least one C.sub.1 -C.sub.4 alkanol, 5-10 parts of an amine and 15-55 parts of water. The mixture is dissolved by heating at a temperature of 75.degree.-85.degree. C. for a period of time of not more than 90 minutes to produce a varnish. An aqueous cold seal release lacquer (CSRL) is prepared from the varnish by mixing with a C.sub.1 -C.sub.4 alkanol, water and a surfactant.
    Type: Grant
    Filed: September 13, 1994
    Date of Patent: November 14, 1995
    Assignee: Sun Chemical Corporation
    Inventors: Robert J. Catena, Prasad K. Adhikari
  • Patent number: 5459209
    Abstract: An improved coating composition having one or more polymeric binders dispersed in a liquid medium, wherein the improvement comprises an anti-sag and anti-settling effective amount of oxidized ethylene-carbon monoxide copolymer.
    Type: Grant
    Filed: April 8, 1994
    Date of Patent: October 17, 1995
    Assignee: AlliedSignal Inc.
    Inventor: Michael Jablon
  • Patent number: 5407980
    Abstract: The present invention relates to an adhesive composition for manufacturing plywood for exterior application including:a) 121 parts by weight phenolic resin;b) 5 to 121 parts by weight isocyanate;c) 1 to 40 parts by weight tannin selected from the group consisting of pine, quebracho, mimosa, and combinations thereof;d) 1 to 15 parts by weight paraformaldehyde or formaldehyde solutions in water;e) 5 to 50 parts by weight of water; andf) an amount of filler comprising inorganic and/or organic materials for providing the composition with the desired viscosity.
    Type: Grant
    Filed: November 18, 1992
    Date of Patent: April 18, 1995
    Assignees: Diteco Ltda, Quimicos Coronel S.A.
    Inventors: Antonio Pizzi, Ernst Von Leyser, Cristian Westermeyer
  • Patent number: 5344874
    Abstract: A process for producing a condensed resin dispersion, which comprises subjecting an aldehyde and a compound condensable with the aldehyde, or their precondensate, to a condensation reaction in a dispersion medium consisting essentially of water and/or an organic solvent, to precipitate fine condensed resin particles which hardly settle in said dispersion medium, and then replacing the water and/or the organic solvent by an active hydrogen-containing compound having at least two active hydrogen-containing groups reactive with isocyanate groups.
    Type: Grant
    Filed: July 8, 1991
    Date of Patent: September 6, 1994
    Assignee: Asahi Glass Company Ltd.
    Inventors: Takao Doi, Noriko Itaya, Masami Yamashita, Nobuaki Kunii
  • Patent number: 5334652
    Abstract: The present invention is directed towards liquid coating formulations containing a mixture of a curable polyester or diester resin, an amino crosslinking agent and a pigment wherein the pigment is dispersed in the coating solution at a weight loading level such that the pigment to binder ratio falls within the range of from 1.25 to 1 up to about 5.0 to 1. The polyester or diester resins employed in the coating formulations are such that when formulated with an appropriate crosslinking agent, acid catalyst and pigment within the ranges stated above and properly applied to a substrate and cured, produce coatings having a minimum Knoop hardness of at least about 4 and a flexibility (T-bend test) of less than 6, generally less than about 5, and a MEK rub value of greater than 5, more preferably at least about 15 and most preferably greater than 50.Cured coating compositions prepared in accordance with this invention exhibit all of the attributes considered essential for coil coatings, i.e.
    Type: Grant
    Filed: June 18, 1991
    Date of Patent: August 2, 1994
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: William E. Wellman, Albert I. Yezrielev, Ralph M. Kowalik
  • Patent number: 5332792
    Abstract: An improved coating composition having one or more polymeric binders dispersed in a liquid medium, wherein the improvement comprises an anti-sag and anti-settling effective amount of oxidized ethylene-carbon monoxide copolymer having an acid number as determined by standardized titration of KOH of between about 4 and about 30 and a Brookfield viscosity at a temperature of 140.degree. C. of between about 50 and about 800 centipoises.
    Type: Grant
    Filed: August 19, 1993
    Date of Patent: July 26, 1994
    Assignee: AlliedSignal Inc.
    Inventor: Michael Jablon
  • Patent number: 5312862
    Abstract: Methods are presented by which compressed fluids such as carbon dioxide, nitrous oxide, and ethane can be admixed with solvent-borne compositions that contain a high concentration of solid polymer, such as coating compositions, whereby precipitation of the solid polymer can be avoided, thereby preventing plugging of the mixing apparatus.
    Type: Grant
    Filed: December 18, 1992
    Date of Patent: May 17, 1994
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Kenneth A. Nielsen, Jeffrey J. Lear, John N. Argyropoulos, Alex Chia-Huei Kuo
  • Patent number: 5296584
    Abstract: The invention relates to a composition consisting of a melamine solid suspended or dispersed in a resole resin. The method of the invention favors the intermolecular condensation polymerization reaction between phenol and melamine, rather than homopolymerization between phenol molecules or between melamine molecules. This invention reduces formaldehyde emissions by favoring a reaction whose by-product is water rather than formaldehyde. The compositions are useful for bonding glass fiber mats used for thermal and acoustical insulation.
    Type: Grant
    Filed: July 22, 1993
    Date of Patent: March 22, 1994
    Assignee: Borden, Inc.
    Inventor: Wayne R. Walisser
  • Patent number: 5288790
    Abstract: Spherical fine particles of colored resin are provided. The fine particles are of a spherical shape and are superior in heat resistance, solvent resistance, and chemical resistance, and sufficiently satisfactory in durability and coloring, and industrially advantageous. The spherical fine particles of colored resin are made by incorporating an amino resin cured matter and an inorganic pigment into one body, and a ratio of the inorganic pigment against a total amount of the amino resin cured matter and inorganic pigment is in a range of from about 1 to 30% by weight.
    Type: Grant
    Filed: June 25, 1993
    Date of Patent: February 22, 1994
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Saburo Nakahara, Yasuhiro Yamamoto, Yohji Akazawa, Masao Baba, Yoshikuni Mori
  • Patent number: 5258445
    Abstract: Thermoplastic molding compositions and articles comprise immiscible thermoplastic polymer components and reinforcing fibers. The immiscible thermoplastic polymer components and the fibers are blended together under high shear conditions The molding composition generally contains at least two phases and has an extremely smooth and fiber-free surface. Generally, other very good physical properties are obtained such as high heat distortion temperatures, high tensile modulus, high flex modulus, and the like are also very good. A desired blend of thermoplastic components is thermoplastic polyurethane and polyethylene terephthalate with glass fibers A polyethylene terephthalate copolyester blended with an immiscible thermoplastic polymer, preferably polyurethane, and glass fibers produces thermoplastic molding compositions and articles having surprisingly superior impact strength.
    Type: Grant
    Filed: March 6, 1992
    Date of Patent: November 2, 1993
    Assignee: The B. F. Goodrich Company
    Inventors: James M. Sperk, Jr., Biing-lin Lee, James W. Summers, Edward M. Faber, deceased, Hsiungto S. Tseng, Edmond G. Kolycheck
  • Patent number: 5153233
    Abstract: A storage stable or easily redispersible dispersion of melamine, urea or a blend thereof in a polyol, polymer polyol or a blend thereof is produced by the addition of an alkylbenzenesulfonate salt to the dispersion. Foams, polyurethane foams and other polyurethane materials made from storage stable or easily redispersible dispersion of the present invention show improved combustion resistance properties.
    Type: Grant
    Filed: July 15, 1991
    Date of Patent: October 6, 1992
    Inventors: Jose Godoy, Jitka Jenc, Werner A. Lidy
  • Patent number: 5110898
    Abstract: Ths invention relates to an improved method of preparing a solid amino-aldehyde condensation product wherein the solid condensation product precursor solution is fed to the bottom of the reaction vessel.
    Type: Grant
    Filed: October 1, 1990
    Date of Patent: May 5, 1992
    Assignee: Georgia-Pacific Corporation
    Inventor: Richard E. Formaini
  • Patent number: 5102695
    Abstract: Clear, abrasion resistant, tintable coating compositions which are based on siloxane/silica hybrid coating resins and which also contain at least about 3 weight percent and up to about 30 weight percent of a tintability enhancing compound comprising at least one alkylated amine formadehyde compound. These coating compositions are especially useful for providing both abrasion resistance and high levels of tinting.
    Type: Grant
    Filed: November 14, 1990
    Date of Patent: April 7, 1992
    Assignee: Swedlow, Inc.
    Inventors: Allen M. Guest, Martin W. Preus, William Lewis
  • Patent number: 5084506
    Abstract: A stable, nonaqueous microparticle dispersion of the polymeric reaction product of reactants containing an aminoplast resin and a hydroxyl containing material is characterized in that less than 20 percent of the polymer microparticles have a mean diameter greater than 5 microns, further characterized in that at a total solids content of 60 percent the Brookfield viscosity is less that 1000 centipoise measured at 50 RPM using a number 3 spindle at 25.degree. C., the polymeric reaction product being prepared from reactants which are substantially free of acrylic polymer in a nonaqueous medium which is inert to the reactants.Stable nonaqueous microparticle dispersions characterized as above can also be prepared by the self condensation of an aminoplast resin.
    Type: Grant
    Filed: December 3, 1987
    Date of Patent: January 28, 1992
    Assignee: PPG Industries, Inc.
    Inventors: Dennis L. Faler, Gregory J. McCollum, James B. O'Dwyer, Marvis E. Hartman
  • Patent number: 5047466
    Abstract: Amino resin solutions having an electrical conductivity of <100 .mu.S/cm for impregnating paper are obtainable byA) methylolation of melamine with aqueous formaldehyde in a molar ratio of from 1:2 to 1:5 in the presence of a tertiary organic amine at a pH of from 7 to 12,B) etherification with a molar excess, based on the methylol groups, of a C.sub.1 -C.sub.4 -alcohol in the presence of an unsubstituted or substituted dicarboxylic acid and/or polycarboxylic acid at a pH of from 3 to 6,C) neutralization of the reaction mixture with an inorganic base and removal of the volatile components by distillation, except for a water content of <10% by weight, based on the reaction mixture, andD) addition of a C.sub.1 -C.sub.4 -alcohol to give a solids content of from 40 to 90% by weight, based on the amino resin solution, and removal of insoluble components by filtration.
    Type: Grant
    Filed: February 8, 1990
    Date of Patent: September 10, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Gerd Busse, Jakob Decher, Wolfgang Eisele, Edgar Haeussler, Otto Wittmann
  • Patent number: 5034444
    Abstract: A rheological additive for non-aqueous coating compositions is disclosed. The additive may be the reaction product of an alkoxylated aliphatic nitrogen-containing compound, an aliphatic diamine or mixtures thereof, and an organic polycarboxylic anhydride or acid, an alkanediol polyepoxide ether, or mixtures thereof. The additive provides excellent anti-sag and storage stability properties, particularly for high solids coating compositions, without causing a significant increase in viscosity. Also disclosed are coating compositions containing the additive.
    Type: Grant
    Filed: June 18, 1990
    Date of Patent: July 23, 1991
    Assignee: Rheox, Inc.
    Inventors: Han B. Yun, Alan Smith
  • Patent number: 5034500
    Abstract: Urea-formaldehyde resins, particularly useful for producing particle boards having lower rates of release of formaldehyde are synthesized in several stages including a stage of further condensing a first condensate having a F/U molar ratio of 1.8-2.3 and which was condensed at a pH of between 6 and 8. The further condensing is conducted at a pH of between 6 and 8 until a cloud point with water is reached at 10.degree.-40.degree. C. making it possible to obtain resins which are reactive and stable during storage.
    Type: Grant
    Filed: December 23, 1988
    Date of Patent: July 23, 1991
    Assignee: Norsolor (Orkem Group)
    Inventors: Roger Garrigue, Jack Lalo, Jean-Luc Leclere
  • Patent number: 5030685
    Abstract: A process for producing a condensed resin dispersion, which comprises subjecting an aldehyde and a compound condensable with the aldehyde, or their precondensate, to a condensation reaction in a dispersion medium consisting essentially of water and/or an organic solvent, to precipitate fine condensed resin particles which hardly settle in said dispersion medium, and then replacing the water and/or the organic solvent by an active hydrogen-containing compound having at least two active hydrogen-containing groups reactive with isocyanate groups.
    Type: Grant
    Filed: September 28, 1989
    Date of Patent: July 9, 1991
    Assignee: Asahi Glass Company, Ltd.
    Inventors: Takao Doi, Noriko Itaya, Masami Yamashita, Nobuaki Kunii
  • Patent number: 5003034
    Abstract: Coating compositions comprise a clear, homogeneous binder mixture of polyether or polyester polymer, an amine-formaldehyde condensate resin, and an organic solvent; the mixture being miscible with water to application viscosity. The coating composition typically contains suspended solid particulates, including pigments and metal flakes.
    Type: Grant
    Filed: January 4, 1990
    Date of Patent: March 26, 1991
    Assignee: Bee Chemical Company
    Inventors: Richard E. Jarzombek, Raymond J. Moeller, Jr., Merrill L. Pruitt
  • Patent number: 4997905
    Abstract: The preparation of aminoplastic resins containing melamine, having very low rates of formaldehyde emission, and being particularly useful for the production of particle boards. In a second stage of the process for preparing the resin, additional NH.sub.2 (melamine and urea) is added to a conventional condensate solution at an increased pH between 6 and 9 so as to lower the F/NH.sub.2 molar ratio to between 0.5 and 0.9. Urea is added in a third stage to obtain an F/NH.sub.2 of between 0.30 and 0.50, with the optional addition of borax.
    Type: Grant
    Filed: December 23, 1988
    Date of Patent: March 5, 1991
    Assignee: Norsolor (Orkem Group)
    Inventors: Bernard Druet, Daniel Hopin
  • Patent number: 4963613
    Abstract: An adhesive composition comprising:a polymer latex containing a copolymer which comprises(a) 40 to 80% by weight of a conjugated diene monomer and(b) 0.5 to 30% by weight of a cyanated vinyl monomer,(c) 5 to 35% by weight of vinylpyridine and(d) not more than 53% by weight of an aromatic vinyl monomer; anda resorcin-formalin resin, which composition can adhere various fibers to rubbers.
    Type: Grant
    Filed: July 7, 1989
    Date of Patent: October 16, 1990
    Assignee: Sumitomo Naugatuck Co., Ltd.
    Inventors: Yasushi Toyoda, Saburo Mishiba
  • Patent number: 4962182
    Abstract: Curing aminoplastic resins containing urea and melamine by adding as the curing catalyst, a triazinone derivative.
    Type: Grant
    Filed: December 23, 1988
    Date of Patent: October 9, 1990
    Assignee: Norsolor (Orkem Group)
    Inventors: Roger Garrigue, Jack Lalo
  • Patent number: 4960856
    Abstract: This invention relates to an aqueous solution of water soluble urea-formaldehyde precondensate having a formaldehyde-to-urea (F/U) molar ratio of between about 1.20:1.0 and 1.70:1.0 and to a method for making the precondensate solution by reacting urea and formaldehyde in the presence of acid catalyst in aqueous solution having a pH between about 3.5 and 4.25; then, in neutral to slightly basic solution.
    Type: Grant
    Filed: November 28, 1988
    Date of Patent: October 2, 1990
    Assignee: Georgia-Pacific Corporation
    Inventor: Richard Formaini
  • Patent number: 4959406
    Abstract: Plastic containing small amounts of titanium dioxide and, if appropriate, carbon black and an additive which reduces the tracking resistance, for the production of laser-writable mouldings.
    Type: Grant
    Filed: February 6, 1989
    Date of Patent: September 25, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventors: Eckard Foltin, Hans-Werner Depcik, Karl Huff, Alfred Pischtschan, Mehmet C. Yesildag, Reiner Erkelenz
  • Patent number: 4948828
    Abstract: A spider for a gassing current limiting fuse made of an asbestos free material is disclosed. The spider material produces an arc quenching gas and water upon erosion by an arc. The material includes the following proportions of ingredients: 50-80% Al.sub.2 O.sub.3.3H.sub.2 O; 8-22% Wollastonite (CaSiO.sub.3); and 10-25% melamine formaldehyde resin.
    Type: Grant
    Filed: January 31, 1989
    Date of Patent: August 14, 1990
    Assignee: Cooper Industries, Inc.
    Inventors: Stephen P. Johnson, Stephen P. Hassler
  • Patent number: 4920199
    Abstract: Coating compositions comprise a clear, homogeneous binder mixture of polyether or polyester polymer, an amine-formaldehyde condensate resin, and an organic solvent; the mixture being miscible with water to application viscosity. The coating composition typically contains suspended solid particulates, including pigments and metal flakes.
    Type: Grant
    Filed: November 10, 1988
    Date of Patent: April 24, 1990
    Assignee: Bee Chemical Company
    Inventors: Richard E. Jarzombek, Raymond J. Moeller, Jr., Merrill L. Pruitt
  • Patent number: 4870129
    Abstract: An adhesive consisting substantially of an aqueous solution or dispersion of a polyurethane containing chemically incorporated carboxylate and/or sulphonate groups is prepared from a mixture of at least two (cyclo)-aliphatic diisocyanate and selected polyester diols based on (i) adipic acid and (ii) tetramethylenediol, hexamethylenediol or mixtures of these diols. The use of such aqueous solutions for the formation of bonds on any substrates, in particular on leather, plastics, rubber materials and/or polyvinyl chloride containing plasticizer, with the same material or with other materials is disclosed.
    Type: Grant
    Filed: August 19, 1987
    Date of Patent: September 26, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wolfgang Henning, Rudolf Hombach, Walter Meckel, Manfred Dollhausen
  • Patent number: 4843126
    Abstract: Aminoplast compositions are cured using a sulfur and phosphorus containing catalyst.
    Type: Grant
    Filed: December 30, 1987
    Date of Patent: June 27, 1989
    Assignee: The Lubrizol Corporation
    Inventor: Robert E. Quinn
  • Patent number: 4789703
    Abstract: Pelletized thermoplastic polymers or resins containing (--CONH--) groups such as the nylons can readily be brominated or chlorinated in organic solvents to convert the (--NH--) units to (--NBr--) or (--NCl--) units and to form solutions of the N-brominated or N-chlorinated thermoplastic polymers or resins. These N-brominated or N-chlorinated thermoplastic polymer solutions can be coated on a cellular or solid rubbery hydrocarbon polymer substrate, such as an EPDM rubber in the form of a weatherstrip or glass run channel, dried and irradiated with ultraviolet light or heated at a temperature and for a period of time sufficient to reform the amide (--CONH--) groups and to provide the rubbery substrate with an adherent and abrasion resistant coating which also exhibits reduced ice adhesion and coefficient of friction.
    Type: Grant
    Filed: May 22, 1987
    Date of Patent: December 6, 1988
    Assignee: GenCorp Inc.
    Inventors: Hubert J. Fabris, Earl G. Melby, Kohji Y. Chihara, Harry W. Cocain
  • Patent number: 4767807
    Abstract: A coloring agent for the dope-dyeing viscose rayon, comprising minute spherical cured particles of an amino resin produced from formaldehyde and at least one amino compound selected from the group consisting of benzoguanamine, melamine, and urea and colored with a dye, a viscose composition containing the coloring agent, a viscose rayon obtained by spinning the composition, and a method for manufacture thereof.
    Type: Grant
    Filed: August 18, 1986
    Date of Patent: August 30, 1988
    Assignee: Nippon Shokubai Kagaku Kogyo Co. Ltd.
    Inventors: Iwao Fujikawa, Mitsuo Kushino, Yasuhiro Yamamoto
  • Patent number: 4732787
    Abstract: A hard, abrasion resistant varnish, for coating the surfaces of solid substrates, comprises a solution in a mixture of solvents:a--4 to 90% by weight, in relation to the total of constituents (a), (b) and (c), of a colloidal silica,b--9 to 95% by weight, in relation to the total of constituents (a), (b) and (c), of the product of hydrolysis and partial condensation of at least one trialkoxysilane;c--1 to 87% by weight, in relation to the total of constituents (a), (b) and (c), of the product of hydrolysis and partial condensation of at least one epoxidized trialkoxysilane;d--0.5 to 9% by weight, in relation to the total of constituents (a), (b) and (c), and (d), of a soluble melamine-formaldehyde and urea-formaldehyde resin.The varnish can optionally contain an acid hardener and secondary adjuvants such as dyes, film tension agents and agents for protection from light.The varnish in contact with the solid substrate to be coated is hardened by heating at about 120.degree. for a time not exceeding 2 hours.
    Type: Grant
    Filed: May 13, 1986
    Date of Patent: March 22, 1988
    Assignee: Societe la Celliose S.A.
    Inventors: Alain Vantillard, Joel Pellenc, Claude Verne
  • Patent number: 4731262
    Abstract: Painting of an article formed of a synthetic resin, e.g. an automobile bumper formed of polyurethane resin, is accomplished by simplified operations and at reduced cost by using a paint of a desired color containing 5-40 wt % of an aprotic polar solvent, preferbly N-methyl-2-pyrrolidone. The paint is applied directly to a cleaned surface of the plastic article, followed by usual drying and baking. Application of a usual primer is omitted since the paint containing an adequate amount of aprotic polar solvent is excellent in adhesion to plastic surfaces. The obtained paint film is comparable to an ordinary top coat paint film formed on a primer layer in appearance, whether resistance and chemical resistance. When a two-toned paint coat is wished, another paint not containing any aprotic polar solvent is applied onto a selected area of the initially formed paint film, followed by drying and baking.
    Type: Grant
    Filed: June 2, 1986
    Date of Patent: March 15, 1988
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Masashi Ohno, Takashi Toyama, Kiminori Ishii
  • Patent number: 4707508
    Abstract: Concentrated aqueous solutions of sulfo-containing melamine-formaldehyde condensates containing hydantoin derivatives to prolong their shelf life.These melamine-formaldehyde condensates are predominantly used as additives in inorganic binders to improve their flow and strength properties.
    Type: Grant
    Filed: September 30, 1986
    Date of Patent: November 17, 1987
    Assignee: Chemie Linz Aktiengesellschaft
    Inventors: Stefan Pieh, Johann Krammer
  • Patent number: 4672083
    Abstract: The formaldehyde emission in the thermoplastic processing of antioxidant containing oxymethylene copolymer molding compositions is reduced considerably if these molding compositions additionally contain on the surface or homogeneously mixed in a specifically defined formaldehyde binding material which contains in the molecule at least two 4,6-diamino-1,3,5-triazin-2-yl groups. In this way there are avoided deposits on the die and odor annoyance.
    Type: Grant
    Filed: May 21, 1986
    Date of Patent: June 9, 1987
    Assignee: Degussa AG
    Inventors: Herbert Amann, Gerhard Morlock, Egbert Schola
  • Patent number: 4663239
    Abstract: A fire retardant composition in a stable liquid form comprises the reaction product of an aqueous aldehyde, preferably formaldehyde, solution, at least one alcohol solvent, an alkanolamine, an organic catalyst, ammonium hydroxide, urea and an aqueous phosphoric acid solution. The aldehyde and urea are included in an approximately 1:1 weight ratio. A method of forming the reaction product comprises adding urea to a mixture of aldehyde, alcohol, alkanolamine, organic catalyst and ammonium hydroxide, and heating the resultant mixture to at least 150.degree. F.
    Type: Grant
    Filed: February 10, 1986
    Date of Patent: May 5, 1987
    Inventor: Glenn A. Pearson
  • Patent number: 4642264
    Abstract: The object of the present invention are new thermoset resins having quickened curing, a process for their preparation, and their applications. The resins according to the invention consist, at least in part, of the products resulting from the polycondensation of one or more pyridine derivatives containing at least two methyl groups in the 2, 4 or 6 positions, with one or more aromatic dialdehydes, and the addition of one or more additives consisting of phenol compounds. These resins are used to the fabrication of composite materials.
    Type: Grant
    Filed: August 23, 1984
    Date of Patent: February 10, 1987
    Assignees: Societe Nationale des Poudres et Explosifs, Office National d'Etudes et de Recherches Aerospatiales
    Inventors: Marcel Ropars, Bertrand Bloch
  • Patent number: RE33853
    Abstract: A pigment paste comprising a pigment and as a pigment dispersing agent, a compound having a basic structure represented by the following formula ##STR1## wherein R.sub.1 represents a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group, and R.sub.2 represents a residue of a diol or polyol, or a mixture of said pigment dispersing agent and an organic solvent, said pigment being dispersed in said pigment dispersing agent or in said mixture.
    Type: Grant
    Filed: December 18, 1989
    Date of Patent: March 24, 1992
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Noboru Okoshi, Masatoshi Motomura, Mitsuru Ohtsubo, Takenori Ikeda