Abstract: This invention is a composition for polyester fiber for use in reinforcing, the finish composition being characterized by an oil portion containing a lubricant and 3-30 weight % of a melamine compound.

Abstract: Thermosettable prepolymers or resins are prepared by reacting (1) a pyrazine compound containing at least two substituent groups which have a hydrogen atom attached to a carbon atom which is attached to the ring such as tetramethylpyrazine, (2) a material containing at least two aromatic aldehyde groups, and (3) at least one of (a) a nitrogen containing aromatic heterocyclic compound containing at least one hydrogen atom attached to a carbon atom attached to the ring and a polymerizable unsaturated group such as 2-methyl-5-vinylpyridine or (b) an aldehyde containing at least one polymerizable unsaturated group such as 4-isopropenyl-1-cyclohexene-1-carboxaldehyde. These prepolymers or resins are curable to thermoset products having good mechanical and thermal properties by heat and pressure or by homopolymerization or copolymerization with N,N'-bis-imides such as 1,1'-(methylenedi-4,1-phenylene)-bismaleimide. The prepolymers are suitable for preparing composites.

Abstract: An amino-formaldehyde moulding composition is made by compounding togetheran aqueous amino-formaldehyde resin solution to provide 0 to 90 percent by weight of the resin component of the composition, filler to make up 20 to 60 percent by weight of the moulding composition andUF resin which had a low degree of condensation, is solid at room temperature, contains a modifier and makes up 4 to 80 percent by weight of the moulding composition.The moulding compositions themselves are also claimed.

Abstract: Thermoplastic or thermosettable products are prepared by reacting a heterocyclic compound containing at least one nitrogen atom and at least two pendant groups containing a reactive hydrogen atom attached to a carbon atom which is attached to the aromatic heterocyclic ring such as 2,4,6-trimethylpyridine or 2,3,5,6-tetramethylpyrazine with an aldehyde having a hydrogen atom attached to a carbon atom adjacent to the carbonyl group such as phenylacetaldehyde. Also, heat resistant thermoplastic or thermosettable products are prepared by reacting the above product with either a hydroxy aromatic monoaldehyde such as 4-hydroxybenzaldehyde, aromatic dialdehyde such as terephthaldicarboxaldehyde or mixture thereof. Many of these products exhibit bulk conductive properties when doped with a dopant (doping agent) such as antimony pentafluoride.

Abstract: This invention relates to a corrosion inhibiting composition for ferrous metals and its alloys in gas conditioning service using aqueous monoethanolamine to scrub carbon dioxide containing oxygen. The corrosion inhibiting composition includes a thiourea-amine-formaldehyde based polymer and, in the preferred embodiment, also includes a cupric ion producing material.

Abstract: This invention relates to a corrosion inhibiting composition for ferrous metals and its alloys in gas conditioning service using aqueous monoethanolamine to scrub carbon dioxide. The corrosion inhibiting composition includes a thiourea-amine-formaldehyde based polymer and, in the preferred embodiment, also includes a nickel ion producing material.

Abstract: A method for the production of hydroxyalkylmelamine containing resins wherein melamine, formaldehyde and a hydroxyalkylmelamine are reacted under conditions such that a resin is produced which, when incorporated into a decorative laminate, enhances the post-forming thereof, the resin per se, paper sheets containing said resin, a method for the production of laminates and the laminates per se, are disclosed.

Abstract: A radiation shield superior to lead in absorbing/attenuating X-rays and the like made by molding with a resin binder a mixture of powders, namely lead oxide derived from scrap storage batteries, slag derived from electrorefining of aluminum, nickel or chromium as a by-product, and molybdenite. The molded shield may also contain zeolite for gas absorption and a reinforcing core of glass fabric.

Abstract: Thermosettable prepolymers or resins are prepared by reacting a pyrazine containing at least two substituent groups which have a hydrogen atom attached to a carbon atom which is attached to the ring with a material containing at least two aromatic aldehyde groups. These prepolymers or resins are curable to thermoset products having good mechanical and thermal properties. Thermoset polymers having good mechanical and thermal properties are also prepared by homopolymerization in the presence of N,N'-bis-imides or copolymerization of these prepolymers with N,N'-bis-imides. The prepolymers are suitable for preparing composites.

Abstract: In a microencapsulation process which causes hydrophobic core material containing an oil-soluble melamine-formaldehyde precondensate to emulsified in water or in a hydrophilic medium, and to form capsule wall film under conditions for promoting polycondensation, the process which is characterized in that said oil-soluble melamine-formaldehyde precondensate is 40 to 100% in a degree of formaldehyde substitution, 80 to 100% in alkylation degree, and 4 to 11 in hydrophobic degree.

Abstract: This invention is a composition for polyester fiber for use in reinforcing, the finish composition being characterized by an oil portion containing a lubricant and 3-30 weight % of a melamine compound.

Abstract: A textile finishing composition comprising (1) a diluent and (2) a durable press resin composition containing (a) an aminoplast resin and (b) an aldehyde. The textile finishing composition is combined with an acid catalyst and applied to textile materials to impart softness, improved wetting properties and durable press properties.The textile finishing composition is applied at lower than normal dry add-on levels to textile materials to provide textile materials having lower levels of formaldehyde.

Abstract: An essentially linear polyester oligomer having hydroxyl and carboxyl terminal groups for subsequent cure and its production are disclosed. This polyester oligomer is produced by first adducting approximately equimolar amounts of diol carrying two primary hydroxyl groups and a dicarboxylic acid anhydride to form an hydroxy acid. The carboxyl groups of this hydroxy acid are then esterified by reaction with an approximately stoichiometric proportion of diol carrying one primary hydroxyl group and one secondary hydroxyl group, the stoichiometry being based on the total hydroxyl content of the diol and the carboxyl content of the hydroxy acid, to form an hydroxyl-terminated oligomer. This hydroxyl-terminated oligomer is then adducted with a polycarboxylic acid monoanhydride having a carboxyl functionality of at least 3, this monoanhydride being used in an amount of 0.01 to 0.15 equivalents of anhydride per hydroxyl equivalent in the hydroxyl-terminated oligomer.

Abstract: Stoving lacquer coatings containing 0.001 to 30% by weight of one or more organic pigments or polymer-soluble dyes, and 0.001 to 30% by weight, relative to the dry lacquer coating, are suitable for obtaining metallic effects of high purity.

Abstract: An acetal resin composition comprising(A) an acetal resin,(B) at least one member selected from the group consisting of (1) a polyfunctional cyanic acid ester or its prepolymer, (2) a mixture of a polyfunctional cyanic acid ester or its prepolymer with a polyfunctional maleimide or its prepolymer and (3) a pre-copolymer of a polyfunctional cyanic acid ester and a polyfunctional maleimide,(C) an amine-substituted triazine and/or a cyanoguanidine compound, and(D) an inorganic filler other than glass, and/or an organic filler.

Abstract: The invention is a method of reducing formaldehyde emission from wood-based composite boards bonded with aminoplast resins. A salt mixture comprising urea, or one of its analogs, a readily decomposible ammonia liberating compound and, alternatively, a resin catalyst is prepared in a finely granulated form. This is then added to the dried wood particles and blended, preferably prior to the addition of the adhesive binder resin. The salt mixture comprises 12-20 parts of the ammonia liberating compound, 65-88 parts of urea or its analog, and 0-15% of the catalyst. From 6-22.5% by weight of this mixture is used, based on resin solids. Formaldehyde evolution is reduced by 45-80% compared with untreated particleboard without adverse effect on physical properties or press time.

Abstract: Particulate red amorphous phosphorus is stabilized against oxidation and phosphine formation by the use of a combination of titanium dioxide or titanium phosphate and an organic resin, usually an epoxy resin, a melamine-formaldehyde resin or a urea-formaldehyde resin.

Abstract: A phenol-formaldehyde resol to which urea has been added is mixed with a boric acid-hydroxyl-amide component to provide high temperature resistant binder compositions for use in the manufacture of thermally stable bonded mineral fibre insulation structures.

Abstract: A friction material for brake linings is formed using a polystilbazole resin (3-16% by weight) to provide the matrix for the material. The balance of the material is filler material such as steel wool, metal powders, carbon, ceramic powders, and friction modifiers. The lining is produced by mixing the ingredients and hot pressing the mixture at temperatures which promote the flow and cure of the resin, and at pressures which produce a material of suitable density.

Abstract: A highly efficient formaldehyde-free coating composition insolubilizer is prepared by reacting about 3 moles of glyoxal with 1 mole of urea resulting in a formation of a low molecular weight oligomer in a yield of 95-96%. The molar ratio of glyoxal to urea is very critical in obtaining the highest efficiency and is kept within narrow limits. The coating compositions of the present invention possess 2 till 4 times higher wet-rub resistance than the prior art compositions.

Abstract: Disclosed herein a process for producing a microcapsule having an excellent solvent-resistance and a thermal stability, and an extremely minute amount of unreacted formaldehyde, comprising the steps of dispersing a substance to be encapsulated into an aqueous solution containing a water-soluble cationic urea resin, at least one prepolymer selected from the group consisting of a melamine-formaldehyde prepolymer, a urea-formaldehyde prepolymer and a melamine-urea-formaldehyde prepolymer and an anionic surfactant and then, adding an acid-catalyst into the thus obtained aqueous dispersion thereby forming a wall membrane which encapsulates the dispersed microparticle of the substance to be encapsulated by polycondensing the prepolymer and the cationic urea resin followed by cross-linking while causing complex coacervation, and adding a monosaccharide into the aqueous dispersion while adjusting the pH of the aqueous dispersion with the addition of a hydroxide of an alkaline earth metal thereby removing the unreacte

Abstract: Polyurethane foams prepared from the reaction of polyester polyol with organic isocyanate have improved flame retardance and dripping ember retardance by incorporation of an additive comprising (1) halogenated flame retardant, and (2) organic solvent soluble glycoluril-formaldehyde material.

Abstract: A composition forming coated films having an excellent chipping resistance, containing:A. at least one polyester resin derived from (1) at least one acid component selected from the group consisting of dibasic acids and derivatives thereof and (2) at least one alcohol component selected from the group consisting of polyhydric alcohols and derivatives thereof; andB. at least one aminoplast resin having a number-average molecular weight of 800 to 1400,The polyester resin containing at least 20% by weight of the acid component being an aliphatic dibasic acid having 4 to 10 carbon atoms and at least 20% by weight of the alcohol component being a dihydric alcohol having 2 to 6 carbon atoms, the polyester resin having a number-average molecular weight of 2000 to 4000, a hydroxyl number of 30 to 75 and an acid number of 5 to 15.The weight ratio of the polyester resin to the aminoplast resin is 60/40 to 95/5.

Abstract: A coating composition comprises(A) an alkyl ether methylolmelamine in which a part or whole of methylol groups of methylolmelamine are converted into alkyl ether methylol groups;(B) a polyhydric alcohol having 2 or more hydroxyl groups; and(C) a dispersion of colloidal silica which can be condensed each other for the two or three components; and(D) a solvent.

Abstract: Polyurethane foams prepared from the reaction of polyester polyol with organic isocyanate have improved flame retardance and dripping ember retardance by incorporation of an additive comprising (1) halogenated flame retardant, and (2) water or alcohol soluble urea-formaldehyde resin.

Abstract: A heat resistant resin produced by reacting (A) a polyamideimide resin with (B) an alcohol component and (C) an acid component with heating is soluble in a cresol type solvent and gives coatings excellent in heat resistance, thermal shock resistance, wear resistance, resistance to hydrolysis, etc., suitable for enamelled wire.

Abstract: A process for dyeing high-molecular organic material in the bulk characterized by the use of a 1,4-diketo-pyrrolo[3,4-c]-pyrrole of the formula ##STR1## wherein R.sub.1 and R.sub.2 are isocyclic or heterocyclic aromatic radicals, preferably unsubstituted or substituted phenyl or naphthyl radicals.The dyeings obtained, for example in plastics, fibres, lacquers and printings, are distinguished by very high coloring strength, high saturation, good dispersibility, good fastness to cross-lacquering, migration, heat, light and weather, and also by a high gloss and a good IR-remission behavior.

Abstract: A process for preparing a urea-formaldehyde base resin having a F/U molar ratio of 1.0:1-1.2:1, that is hydrolytically stable, which comprises adjusting a formaldehyde solution to a pH of 0.5-2.5, slowly charging urea to said formaldehyde solution while maintaining the temperature at 40.degree.-70.degree. C., neutralizing the reaction mixture after obtaining a Gardner viscosity in the range of T+-V+, then adding the final charge of urea and permitting equilibration.

Abstract: A process for bonding lignocellulosic material under heat and pressure, where the bonded lignocellulosic material is characterized by a low emission of formaldehyde, which comprises applying a binder to said lignocellulosic material, said binder comprising a urea-formaldehyde base resin having a ratio of formaldehyde to urea of 1.0:1-1.2:1, said base resin having essentially no free formaldehyde and said base resin when cured containing substantially more methylene groups than methylene ether groups, consolidating said lignocellulosic material and curing the binder.

Abstract: Aminoplastic resin dispersions which are stable to sedimentation are obtained by condensation of aldehydes with aminoplastic resin formers in an aqueous medium, in the presence of water-soluble compounds of the formulaR--X--(A--O).sub.m --B--NHCONH--Y].sub.nhaving the substituent meanings mentioned in the description. The condensation is preferably carried out in the presence of dyestuffs or optical brighteners which have groups capable of condensation. The dispersions obtained thereby are particularly suitable for whitening the coating compositions used in the paper industry, and for coating paper, wood, films and textile materials.

Abstract: A formaldehyde-free adhesive system for the manufacture of particleboard comprises the reaction product of a cyclic urea and glyoxal in an equivalent ratio of about 1.1-1.5:1.

Abstract: A process for pigmenting organic material of high molecular weight, which comprises the use of a compound of the formula ##STR1## in which X is a meta- or para-positioned fluorine, chlorine or bromine atom. The yellow to scarlet colorations obtained are distinguished by excellent fastness to light and atmospheric influences.

Abstract: Pigmented coating solutions are disclosed which deposit coatings possessing improved resistance to ultraviolet radiation-induced auto-oxidation. These solutions contain organic solvent, including aromatic hydrocarbon solvent, having dissolved therein an aromatic hydrocarbon-soluble, normally liquid, polysulfide or polydisulfide derivative having terminal -SH groups which have been reacted with a monofunctional reactant providing a C.sub.1 -C.sub.22 alkyl terminal group to provide an essentially nonreactive derivative. The solvent also has dissolved therein a polar polymeric binder (preferably thermosetting) which degrades by a photo-oxidative mechanism and which has only limited compatibility with the derivative. The pigment protects the bulk of a deposited coating, and the limited compatibility causes a heated film of the coating solution to stratify as the solvent evaporates to concentrate the derivative at the surface of the cured coating to protect the same.

Abstract: A composition for producing surface layers on wood or other substrates is formed from diatomite, expanded perlite, chopped glass fibers and a thermosettable resin mixed in specified amounts to provide a flowable mixture. When applied to the substrate as a layer about 1 to 2 cms. thick and the resin component has cured, a tough, impact-resistant, watertight surface is created on the substrate. The new compositions and surfacing methods are particuarly useful for refinishing the hulls of wooden boats.

Abstract: Process of binding aggregates by mixing aggregates with resin binder and vacuum-activated catalyst, applying a partial vacuum to the mixture to activate the catalyst, and curing the binder.

Abstract: A coating composition of polymers of a vinyl oxazoline drying oil ester which esters are made by a process which reacts drying oil fatty acids with tris (hydroxy methyl) amino methane to form an intermediate which is further reacted at about 175.degree.-190.degree. C. with a formaldehyde/alcohol solution to form the vinyl oxazoline drying oil ester; the improvement used with this process is the use of at least 3 moles of formaldehyde to one mole of intermediate and about 1-5% by weight, based on the weight of the intermediate, of methanol and adding after the reaction with formaldehyde about 5-25% by weight, based on the weight of the ester solution, of an alcohol, a ketone or a mixture of an alcohol and a ketone; the coating composition are aqueous and contain sufficient ammonia or amine to provide a pH of about 7.5-9.5.

Abstract: Formaldehyde suppression is accomplished in urea formaldehyde foamed insulation by adding, prior to the foaming, a small but effective amount of a formaldehyde off-gassing suppressant, which is calcium metasilicate.

Abstract: There is disclosed a solid and water-insoluble condensation product of N,N'-ethyleneurea with formaldehyde, having the structure ##STR1## wherein n is an integer from 20 to 60 with a mean value of 41, and having an average number molecular weight M.sub.n ranging from 2000 to 6000. Said product, when added to a polymer in combination with an ammonium phosphate, results in the production of articles which are resistant to heat and to thermo-oxidation.

Abstract: Binder Compositions comprising a solution of furan foundry binders in an alkylated aromatic hydrocarbon solvent result in a more cost efficient binder. The cost efficiency is achieved without significant loss of physical properties of the foundry cores and molds which are formed using the binder. In instances the binder compositions of this invention exhibit improved physical properties.

Abstract: Partially etherified melamine-formaldehyde resins having a melamine:formaldehyde molar ratio of 1:(1.25 to 1) can be prepared by a condensation reaction under neutral or weakly alkaline conditions if the condensation reaction is carried out in the presence of a glycol monoether of the general formula IR(OCH.sub.2 CH.sub.2).sub.n OH (I)wherein R denotes alkyl having 1 to 4 C atoms and n denotes a number from 1 to 5. The partially etherified melamine-formaldehyde resins are suitable for the production of compression moulding compositions having a high flow and minimal processing shrinkage and after-shrinkage.

Abstract: A high solids pigmented coating composition is prepared from a curing agent and an ester diol binder which is a mixture of(a) 20-80 mole % of a compound having the general formula: ##STR1## where R.sub.1 represents the group formed by abstraction of the two carboxyl groups from a cycloaliphatic and/or aromatic dicarboxylic acid having 8 to 20 carbon atoms and R.sub.2 and R.sub.3 may be the same or different and represent groups formed by abstraction of the two hydroxyl groups from a divalent alcohol having 2 to .[.12.]. .Iadd.6 .Iaddend.carbon atoms, and m is a number of 1 - 3, and(b) 80-20 mole % of a compound having the general formula: ##STR2## where R.sub.4 represents the group formed by abstraction of the two carboxyl groups from an aliphatic dicarboxylic acid having 2 to 12 carbon atoms, and R.sub.5 and R.sub.6 may be the same or different and represent groups formed by abstraction of the two hydroxyl groups from a divalent alcohol having 2 to .[.12.]. .Iadd.6 .Iaddend.