Derived From Carboxylic Acid Or Derivative Patents (Class 524/5)
  • Patent number: 5922788
    Abstract: A surface coating agent includes a main ingredient compound containing a mixture of white cement and finely ground silica and carbon fibers and a water soluble hardener containing a mixture of a cationic acrylic resin and an anionic acrylic resin.
    Type: Grant
    Filed: February 6, 1997
    Date of Patent: July 13, 1999
    Inventor: Kaneo Gotan
  • Patent number: 5922124
    Abstract: An additive for, a method of adding thereof to uncured mixes for and resulting cured cement-type concreations such as cured embodiments of concrete, marcadam, and roof-top shingles each exhibiting improved heat and freeze-thaw durability resulting from reduced efflorescence and stability against sun ultraviolet light exposure.
    Type: Grant
    Filed: September 12, 1997
    Date of Patent: July 13, 1999
    Inventor: William W. Supplee
  • Patent number: 5919300
    Abstract: Cement dispersing agents for self-compacting concrete of high flowability, comprising a water-soluble N-vinyl copolymer, prepared by copolymerizing (a) an N-vinyl-lactame or -amide with (b) a polyethylene glycol ester of maleic acid containing 6 to 240 moles of oxyethylene groups per molecule and (c) at least one monomer selected from among unsaturated dicarboxylic acids and (d) methallylsulfonic acid. When an aqueous solution of this copolymer is used as an admixture to freshly prepared concrete of even extremely low water-to-cement ratio, a high fluidity, a low decrease in flowability with the progression of time and a lack of segregation over time is attained.
    Type: Grant
    Filed: October 27, 1997
    Date of Patent: July 6, 1999
    Assignee: Sika AG. vorm. Kaspar Winkler & Co.
    Inventors: Theodor A. Burge, Ueli Sulser, Jurg Widmer, Anna Krapf-Huber
  • Patent number: 5919881
    Abstract: Water-soluble vinyl copolymers with number average molecular weight 500-20000, having two specified repetition units at a specified molar ratio and a specified end group can serve as an effective agent for reducing a drop in the fluidity of hydraulic cement compositions.
    Type: Grant
    Filed: June 25, 1997
    Date of Patent: July 6, 1999
    Assignee: Takemoto Yushi Kabushiki Kaisha
    Inventors: Mitsuo Kinoshita, Yoshimasa Miura, Takeshi Arashima, Tomoo Takahashi, Kazuhide Saito
  • Patent number: 5912284
    Abstract: The present invention provides a cement additive its production process and cement composition achieving excellent slump loss prevention capability. As a cement additive, there can be a copolymer (A-1) comprising an unsaturated polyalkylene glycol ether-based monomer (I), maleic acid-based monomer (II) and other monomer (III) copolymerizable with these monomers, the monomer (I)/monomer (II)/monomer (III) weight ratio being 50-99/50-1/0-49 and the weight average molecular weight of the copolymer (A) being 10,000 to 100,000 in terms of polyethylene glycol measured by gel permeation chromatography, or a copolymer (A) with an antifoaming agent (B), wherein the copolymer (A) comprises polyalkylene glycol ether-based units and dicarboxylic acid-based units as repeating units.
    Type: Grant
    Filed: December 17, 1997
    Date of Patent: June 15, 1999
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Tsuyoshi Hirata, Tsutomu Yuasa, Katsuhisa Shiote, Syogo Iwai, Koichiro Nagare
  • Patent number: 5911820
    Abstract: A concrete admixture is provided, which is effective in imparting fluidity to a hydraulic composition such as cement paste, mortar or concrete, particularly in maintaining the fluidity of the composition and which hardly retards the hardening property of the composition. The concrete admixture comprises a copolymer comprising, as structural units, units derived from an ethylenically unsaturated monomer (a) having 25 to 300 moles of C.sub.2 -C.sub.3 oxyalkylene groups per mole of copolymer and units derived from a monomer (b) of an alkyl, alkenyl or hydroxyalkyl ester of an ethylenically unsaturated mono- or di-carboxylic acid.
    Type: Grant
    Filed: February 20, 1998
    Date of Patent: June 15, 1999
    Assignee: Kao Corporation
    Inventors: Haruyuki Satoh, Fujio Yamato, Yoshinao Kono, Sayuri Nakamura
  • Patent number: 5908885
    Abstract: Polysuccinimide and/or polyaspartate, copolymers of succinimide and aspartate and the polymers cross-linked with a diamine are demonstrated to be enhancement agents for the preparation of cementitious materials. The agents may be added to the dry cementitious mixture or the water which is added to form the cementitious material upon hardening. The enhancement agents improve the workability of the wet cementitious mixture, reduce slump loss during mixing, transport, and placement of the wet cementious mixture; and may provide extra strength upon hardening of the cementitious material.
    Type: Grant
    Filed: July 1, 1997
    Date of Patent: June 1, 1999
    Assignees: University of South Alabama, MBT Holding AG
    Inventors: C. Steven Sikes, Thomas M. Vickers, Jr., Stephen A. Farrington
  • Patent number: 5883156
    Abstract: An antifouling paint composition comprising a binder resin composition containing a biodegradable resin being obtained by polymerizing a cyclic lactone compound with at least two active hydrogen groups of a compound containing at least two active hydrogen groups in one molecule, and an antifouling additive being mixed with the binder resin composition in a weight ratio of the binder resin composition to the antifouling additive from 1:2 to 7:1, the binder resin composition having a gel fraction of not more than 5% by weight.
    Type: Grant
    Filed: April 4, 1997
    Date of Patent: March 16, 1999
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Koichi Fukuda, Junji Yokoi
  • Patent number: 5880182
    Abstract: An admixture for decreasing the water demand of cementitious compositions such as concrete consists of(a) from 75-25% by weight of a water-reducing agent whose major component is a polycarboxylate; and(b) from 25-75% by weight of at least one saccharide component selected from hydrogenated saccharides and polyhydric alcohol adducts of saccharides.The saccaride component is preferably a hydrogenated polysaccharide with a molecular weight distribution as follows:(i) 70-30% by weight (on total weight of hydrogenated saccharides) have molecular weights in the range 180-300;(ii) 30-70% by weight have molecular weights of from 300 up to 4,000; and(iii) 30% by weight maximum have molecular weights of 4,000 and over.
    Type: Grant
    Filed: February 18, 1997
    Date of Patent: March 9, 1999
    Assignee: MBT Holding AG
    Inventors: Yoshikazu Minomiya, Akira Ohta, Minoru Yaguchi
  • Patent number: 5854318
    Abstract: A cement additive is added to increase flowability of a cement composition and to prevent a slump loss, but those characters are insufficient, or the cement additive becomes ununiform in the cement composition and causes a trouble of the hardening inferiority.Thus, to solve the subjects, the present invention provides a cement additive composed of a crosslinked polymer in which, between main chains having a water-soluble polymer structure of a molecular weight from 500 to 100,000, a bond having as a structural unit at least one group selected from divalent groups as shown in the following formula (I) is formed. ##STR1## ?In the formula (I), R.sup.1 and R.sup.2 independently denote any one of the following. ##STR2## However, R.sup.1 may not be required in a case of that R.sup.2 is the following. ##STR3## Moreover, R and R' independently denote an alkyl group of carbon number of 1 to 5.
    Type: Grant
    Filed: December 5, 1996
    Date of Patent: December 29, 1998
    Assignee: Nippon Shokubai Kagaku Kogyo Co, Ltd.
    Inventors: Hideyuki Tahara, Hiroshi Ito, Yasuhiro Mori, Makoto Mizushima
  • Patent number: 5840114
    Abstract: A high early strength admixture for precast hydraulic cement comprises a calcium salt and a copolymer having a carbon-containing backbone to which are attached cement-anchoring members, such as carboxyl groups, and to which are also attached oxyalkylene pendant groups by linkages selected from the group consisting of amide and imide members. The copolymers used are preferably formed by reacting an acrylic polymer with ammonia or an alkoxylated amine. The calcium salt, preferably calcium nitrite, and the copolymer can be added simultaneously as one admixture, or separately. The invention relates also to methods for enhancing high early strength in concrete, cement, masonry, and mortar mixtures generally, and to precast concrete particarly, and also pertains to such hydraulic mixtures containing the calcium salt and copolymer.
    Type: Grant
    Filed: May 17, 1996
    Date of Patent: November 24, 1998
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Ara Avedis Jeknavorian, Ahmad Arfaei, Neal Steven Berke, David Charles Darwin, Ellis Martin Gartner, Leslie Ann Jardine, James Franklin Lambert, Lawrence Reeder Roberts
  • Patent number: 5834576
    Abstract: A novel acrylic ester which is represented by general formula (2) ##STR1## wherein R.sub.1 and R.sub.2 independently represent a hydrogen atom or an organic residue, R.sub.3 represents an organic residue, n is a positive number among 1 to 3, and m is a positive number among 1 to 100 and which is applicable to various uses, is obtained by reacting an acrylic ester of general formula (3) ##STR2## wherein R.sub.1 represents a hydrogen atom or an organic residue, and R.sub.3 represents an organic residue, with a cyclic ether compound of general formula (4) ##STR3## wherein R.sub.2 represents a hydrogen atom or an organic residue, and n is a positive number among 1 to 3. Moreover, a novel acrylic acid derivative whose use is even wider is obtained by hydrolyzing the acrylic acid derivative.
    Type: Grant
    Filed: February 27, 1996
    Date of Patent: November 10, 1998
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Hideaki Nagano, Koichi Nakagawa, Keiji Yurugi, Mitsuaki Makino, Tsuyoshi Hirata, Koichiro Nagare, Yuichi Kita
  • Patent number: 5820670
    Abstract: The present invention provides resilient cement compositions and methods which are particularly useful in the construction and repair of oil and gas wells. The cement compositions have improved mechanical properties including elasticity and ductility.
    Type: Grant
    Filed: June 3, 1997
    Date of Patent: October 13, 1998
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Jiten Chatterji, Bobby J. King, Patty L. Onan, David D. Onan
  • Patent number: 5814146
    Abstract: The invention concerns a MDF cement material showing better impact strength meant as an increase in the breaking total energy, by fibers addition.
    Type: Grant
    Filed: December 31, 1996
    Date of Patent: September 29, 1998
    Assignee: Italcementi S.P.A.
    Inventors: Rosa Di Maggio, Marcello Franchini, Gianluca Guerrini, Claudio Migliaresi, Stefano Poli
  • Patent number: 5807970
    Abstract: Formulations including a high density polyester and a density reducing component. The formulations are useful for facilitating the separation of blood serum or plasma from the cellular portion of blood in blood collection applications.
    Type: Grant
    Filed: April 29, 1997
    Date of Patent: September 15, 1998
    Assignee: Becton, Dickinson and Company
    Inventor: Rhyta S. Rounds
  • Patent number: 5807609
    Abstract: At least one compound ##STR1## is added to mineral building materials modified with polymers in order to increase their adhesive power on foams based on polystyrene.
    Type: Grant
    Filed: July 26, 1995
    Date of Patent: September 15, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Joachim Pakusch, Maximillian Angel, Andree Dragon, Wilhelm Friedrich Beckerle, Helmut Teichmann
  • Patent number: 5779786
    Abstract: A process for the production of a ready-mixed setting-type joint compound includes the use of calcium sulfate hemihydrate, water, and a set-retarding agent. The retarder includes a polymer composition including acrylic acid and acrylamide monomer units, for example a copolymer (or a mixture of copolymers) of acrylic acid and acrylamide or a blend of a homopolymer of acrylic acid and a homopolymer of acrylamide. The joint compound can be combined with an accelerator including a metallic salt. The joint compound of the invention can be formulated either as a lightweight joint compound or as a conventional weight joint compound. The joint compounds provide short setting times, reduced shrinkage, reduced preparation time, and beneficial application properties.
    Type: Grant
    Filed: March 4, 1997
    Date of Patent: July 14, 1998
    Assignee: National Gypsum Company
    Inventor: Jashbhai M. Patel
  • Patent number: 5763508
    Abstract: Dispersion powders including (a) a polymer of vinyl ester, vinyl ester/ethylene, (meth)acrylate or styrene/acrylate homo- and copolymers, (b) 1 to 25% by weight, based on the total weight of the polymer, of a protective colloid, (c) 0.1 to 10% by weight, based on the total weight of the polymer, of at least one saturated carboxylic acid ester of the formula C.sub.n H.sub.(2n+1) COOC.sub.m H.sub.(2m+1) where n=5 to 22 and m=1 to 8, and (d) 0 to 20% by weight, based on the total weight of the polymer, of anticaking agent, are useful, for example, as modifying agents in mortar and concrete for increasing the flexural tensile strength, compressive strength, and/or adhesive strength thereof.
    Type: Grant
    Filed: August 22, 1996
    Date of Patent: June 9, 1998
    Assignee: Clariant GmbH
    Inventors: Stefan Hess, Michael Schottler, Ludwig Schmitz
  • Patent number: 5753365
    Abstract: A rubber composition includes a rubber component and particulates of a crystalline syndiotactic-1,2-polybutadiene resin dispersed therein. The particulates have an average particle diameter of 1 to 500 .mu.m, and the melting point of the crystalline syndiotactic-1,2-polybutadiene resin is not less than 110.degree. C. The compounding ratio of the resin is 5 to 60 parts by weight relative to 100 parts by weight of the rubber component. The rubber composition is useful for tires, other rubber articles, etc. With respect to tires in particular, a pneumatic tire includes a rubber composition used for a tread, wherein the rubber composition includes a rubber component and particulates of crystalline syndiotactic-1,2-polybutadiene resin. The matrix portion of the tread rubber other than the above particulates is preferably a foamed rubber.
    Type: Grant
    Filed: February 5, 1996
    Date of Patent: May 19, 1998
    Assignees: Bridgestone Corporation, Ube Industries, Ltd.
    Inventors: Yoshiyuki Morimoto, Koji Yamauchi, Seiichiro Iwafune, Tatsuro Hamada, Masanori Aoyama, Eiji Yamanaka, Koichi Nagakura, Koji Ishiguchi
  • Patent number: 5753036
    Abstract: Mortar formulations comprising a hydraulic cement and a PVOH stabilized acrylic latex or a spray dried redispersible powder made from the PVOH stabilized acrylic latex are disclosed. These include formulations suitable for use as tile mortars, patching mortars, EIFS base coats and grouts. An acrylic latex that, when formulated with hydraulic cement, has performance advantages over other latex resins in mortar, patch and exterior insulation and finishing systems. The spray dried, redispersible acrylic emulsion polymer that, when formulated with hydraulic cement, has comparable or better performance than a liquid latex in mortars and patches.
    Type: Grant
    Filed: April 21, 1997
    Date of Patent: May 19, 1998
    Assignee: Air Products and Chemicals, Inc.
    Inventors: E. Chris Hornaman, Christopher Thomas Hable, Randall Paul Bright, Richard Henry Bott
  • Patent number: 5753744
    Abstract: An improved hydraulic cement and resultant hydraulic cement composition which has an alkyl terminated alkoxy amine derivative of maleic acid based polymer or copolymer uniformly distributed therein.
    Type: Grant
    Filed: June 13, 1996
    Date of Patent: May 19, 1998
    Assignee: W.R. Grace & Co.-Conn.
    Inventors: David Charles Darwin, Ellis Martin Gartner, Ahmad Arfaei, Xiaojia Zhang
  • Patent number: 5749963
    Abstract: The hardenable mortar composition consists of a bonding agent component including a hydraulic bonding agent, such as cement, gypsum or mortar, and a paste-forming agent consisting of a liquid solvent inert with respect to the hydraulic bonding agent, and an aqueous component kept separate from the bonding agent component until the two components are mixed to form a hardened mortar composition. The aqueous component includes water and a hydrophobic adsorbent or absorbent. The hydrophobic adsorbent or absorbent is included in the aqueous component to avoid the emergence of the paste-forming agent, which is at the very least unsightly, when the aqueous component is mixed with the bonding agent component. The hydrophobic adsorbent or absorbent binds the paste-forming agent which would otherwise escape during mixing and remains as an inert additive in the setting mortar composition, without reducing the hardness thereof.
    Type: Grant
    Filed: February 13, 1997
    Date of Patent: May 12, 1998
    Assignee: fischerwerke, Artur Fischer GmbH & Co. KG
    Inventors: Norbert Arnold, Willi Haug, Stefan Lind
  • Patent number: 5741844
    Abstract: A coating composition giving a fresco-like appearance when mixed with a cement based plaster comprises a latex polymer binder, acrylic polymer binder, or two acrylic polymer cross-linking binders, particulate matter and chemical agents. The plaster composition preferably comprises 35 to 45 percent by weight cement based plaster; 50 to 60 percent by weight coating composition, 2 to 8 percent by weight colorant. A method for preparing a the plaster composition and a plaster wall, ceiling, or other surface comprised of the plaster composition applied to an appropriate wall, ceiling, or surface is also disclosed.
    Type: Grant
    Filed: May 2, 1997
    Date of Patent: April 21, 1998
    Assignee: Warren J. Nass
    Inventors: Warren John Nass, Kurt Gutfreund, Eli S. Freeman
  • Patent number: 5739190
    Abstract: A process for the preparation of a stable water-in-oil emulsion of a hydrolyzed polymer of an N-vinyl amide of the formula ##STR1## in which R and R.sup.1 denote H or C.sub.1 -C.sub.6 alkyl, by the polymerization of a compound of the formula I alone or in admixture with another ethylenically unsaturated monomer in the presence of a polymerization initiator and emulsifier in the form of a water-in-oil emulsion, to form a water-in-oil polymeric emulsion, followed by hydrolysis of the polymer in the form of the water-in-oil polymeric emulsion in the presence of an acid or base and from 1 to 30 wt %, based on the polymer, of an emulsifier, the emulsifier used being a mixture of(a) from 5 to 95 wt % of a block or graft copolymer of the structure (A-B)m, (A)-B or (B)-A, in which in each case(a) from 5 to 95 wt % of a block or graft copolymer of the structure (A-B).sub.m, (A).sub.n B or (B).sub.
    Type: Grant
    Filed: November 21, 1996
    Date of Patent: April 14, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Heinrich Hartmann, Karl-Heinrich Schneider, Walter Denzinger, Claudia Nilz, Dietmar Monch
  • Patent number: 5739179
    Abstract: Aqueous emulsions of grafted polymer compositions are provided. The grafted component of these compositions has two or more polymeric substituents. The aqueous emulsions of grafted polymer compositions are particularly useful as cement modifiers.
    Type: Grant
    Filed: July 19, 1996
    Date of Patent: April 14, 1998
    Assignee: Rohm and Haas Company
    Inventors: Shang Jaw Chiou, Miao-Hsun Li Sheng
  • Patent number: 5736160
    Abstract: An improved method or process and device for treating and healing a bone void is disclosed, and in particular a method employing a surfactant for efficiently incorporating a biologically active agent into the interstices (voids or pores) of a porous hydrophobic biodegradable material wherein the biologically active agent is deposited on the internal surfaces defining the voids or pores of the biodegradable material. The biodegradable body or device, now containing surfactant and a biologically active agent in the body itself as well as on the external surfaces and the internal surfaces defining the voids or pores, is then applied into the bone void or cavity.
    Type: Grant
    Filed: April 26, 1996
    Date of Patent: April 7, 1998
    Assignee: THM Biomedical, Inc.
    Inventors: Timothy Ringeisen, John H. Brekke
  • Patent number: 5728207
    Abstract: The present invention is directed to an imidized polycarboxylic acid polymer useful as a cement admixture, to improved cement compositions containing said polymer and to a process of forming the same.
    Type: Grant
    Filed: July 3, 1996
    Date of Patent: March 17, 1998
    Assignee: W.R. Grace & Co.-Conn.
    Inventors: Ahmad Arfaei, David Charles Darwin, Ellis Martin Gartner, Byong-Wa Chun, Hideo Koyata, Lawrence Lu Kuo
  • Patent number: 5725657
    Abstract: The present invention is directed to a polyoxyalkylene ammonium salt of an imidized polycarboxylic acid polymer cement admixture, storage stable aqueous solutions of said polymer, and to improved cement compositions containing said polymer.
    Type: Grant
    Filed: March 24, 1996
    Date of Patent: March 10, 1998
    Inventors: David Charles Darwin, Ellis Martin Gartner
  • Patent number: 5725654
    Abstract: There is provided a cement composition having improved fluidity comprising cement and an addition copolymer of (a) an adduct of a polyether polyol and an ethylenically unsaturated isocyanate with (b) an ethylenically unsaturated carboxylic acid.
    Type: Grant
    Filed: June 6, 1997
    Date of Patent: March 10, 1998
    Assignee: Arco Chemical Technology, L.P.
    Inventors: Edward T. Shawl, Xinhau Zhou, Kenneth G. McDaniel
  • Patent number: 5723516
    Abstract: A granular material is presented comprising inorganic particles coated with an organometallic polymeric binder, the organometallic polymeric binder comprising the reaction product of water with at least one component of a binder precursor composition. The binder precursor composition is selected from the group consisting of 1) a first composition comprising an inert organic polymer and a hydrolyzable liquid organometallic solvent; 2) a second composition comprising a water reactive organic polymer dissolved in an inert organic solvent; and 3) a third composition comprising the water reactive organic polymer dissolved in the hydrolyzable liquid organometallic solvent.
    Type: Grant
    Filed: November 22, 1996
    Date of Patent: March 3, 1998
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: W. Stuart Bigham, Dean M. Moren
  • Patent number: 5720807
    Abstract: A hydraulic composition comprising a water-soluble polymer in the form of a polyalkylene oxide derivative having a hydroxyl number of at most 50 KCH-mg/g in terms of terminal hydroxyl groups rendered hydrophobic, a surfactant having a weight-average molecular weight of at most 5,000, a superplasticizer, and a hydraulic powder, which can be endowed with high flowability, aggregate segregation resistance, and strength to remarkably improve the method of using concrete and the method of placing concrete and to thereby greatly enhance the far-reaching effect of eliminating noise pollution particularly in the production of concrete products and streamlining the production of the concrete products.
    Type: Grant
    Filed: August 22, 1996
    Date of Patent: February 24, 1998
    Assignee: Kao Corporation
    Inventors: Tatsuo Izumi, Hotaka Yamamuro, Shin Murahara, Akira Kurara
  • Patent number: 5707445
    Abstract: An admixture for concrete comprising, as an essential component, a copolymer prepared by copolymerizing (a) a polyalkylene glycol monoester monomer having 110 to 300 mols of an oxyalkylene group(s) each having 2 to 3 carbon atoms, with (b) at least one monomer selected from among acrylic monomers, unsaturated dicarboxylic monomers and allylsulfonic monomers. When this admixture is used in preparing concrete, the resulting concrete composition undergoes little change in the slump for a lengthened time, so that the quality of the concrete composition can be easily controlled.
    Type: Grant
    Filed: June 13, 1996
    Date of Patent: January 13, 1998
    Assignee: Kao Corporation
    Inventors: Fujio Yamato, Shuichi Fujita, Yoshiaki Tanisho, Kazushige Kitagawa, Haruyuki Satoh
  • Patent number: 5705553
    Abstract: Copolymers containing carboxyl groups in aqueous dispersion form or redispersible powder form and their water-soluble salts, based on ethylenically unsaturated and copolymerizable monomers, the macro-molecules of which contain at least 24% by weight of monomer units carrying carboxyl groups prepared, by emulsion copolymerization initiated by free radicals in the presence of polyvinyl alcohol (PVA) or polyvinylpyrrolidone (PVP) dissolved in the aqueous phase and isolation of the copolymers in aqueous dispersion form, and optionally subsequent removal of water by spray drying to obtain redispersible copolymer powders and processes for their preparation and their use as thickeners in aqueous formulations which copolymers, by conversion into their water-soluble salt forms, are useful as thickening agents having a surprisingly advantageous rheology-modifying action in aqueous systems.
    Type: Grant
    Filed: November 13, 1995
    Date of Patent: January 6, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Rolf Kuropka
  • Patent number: 5702828
    Abstract: The invention provides a process for water-proofing gypsum materials which comprises adding, to a pulverulent gypsum plaster composition containing from 10 to 90% by weight of gypsum based on the total weight of the composition, a mixture ofa) from 1.0 to 15% by weight, based on the total weight of the composition, of one or more dispersion powders redispersible in water and based on vinyl acetate copolymers with ethylene and/or vinyl esters of C.sub.5 -C.sub.15 -monocarboxylic acids, styrene copolymers with acrylic esters of alcohols having from 1 to 18 carbon atoms, vinyl chloride copolymers with ethylene and/or vinyl esters of C.sub.2 -C.sub.15 monocarboxylic acids, andb) from 0.05 to 5.0% by weight, based on the total weight of the composition, of one or more thixotropic additives from the group consisting of polyacrylic acids and their salts, smectites, bentonites, carboxymethylcelluloses and melamine-formaldehyde condensates.
    Type: Grant
    Filed: February 22, 1996
    Date of Patent: December 30, 1997
    Assignee: Wacker-Chemie GmbH
    Inventors: Klaus Adler, Erwin Gubisch, Alois Sommerauer
  • Patent number: 5700557
    Abstract: A composition for producing an unsaturated polyester is provided. The composition comprises an unsaturated polyester resin; cement; sand; bleaching agent; and curing agent.
    Type: Grant
    Filed: December 5, 1996
    Date of Patent: December 23, 1997
    Inventor: Li-Ching Lin
  • Patent number: 5696185
    Abstract: Aqueous dispersions of polymers which have a high glass transition temperature and a low average molecular weight and contain a specific amount of methacrylic acid as polymerized units are suitable, in liquid or dried form, as additives for improving the flow behavior of cement-containing mineral building materials having binding properties.
    Type: Grant
    Filed: July 17, 1996
    Date of Patent: December 9, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Wilhelm Friedrich Beckerle, Rolf Petri, Bernhard Dotzauer, Manfred Schwartz, Maximilian Angel
  • Patent number: 5688844
    Abstract: The present invention provides resilient cement compositions and methods which are particularly useful in the construction and repair of oil and gas wells. The cement compositions have improved mechanical properties including elasticity and ductility and are basically comprised of cementitious material, an aqueous rubber latex and a latex stabilizer.
    Type: Grant
    Filed: July 1, 1996
    Date of Patent: November 18, 1997
    Assignee: Halliburton Company
    Inventors: Jiten Chatterji, Bobby J. King, Patty L. Totten, David D. Onan
  • Patent number: 5683616
    Abstract: This invention relates to a process for preparing ceramic-like materials with specific properties by binding an inorganic filler in the form of a dry composition with a grain size of up to 25 .mu.m containing in the volume ratio 1:0.-1.52 a waste phosphogypsum and magnetite or glass-forming oxides, with an unsaturated polyester resin in an amount of 46-220 volume parts per 100 volume parts of the filler. The use of magnetite makes it poisible to prepare materials with magnetic properties, while glass-foming oxides enable preparing materials effective to absorb an X-radiation of 45-55 keV and a hard radiation of 0.6-125 MeV. When an expanding agent is added to the raw composition according to this invention, an expanded material is obtained, having completely closed pores, particularly useful in the building industry.
    Type: Grant
    Filed: December 18, 1995
    Date of Patent: November 4, 1997
    Inventors: Marceli Cyrkiewicz, Erwin Herling, Jacek Kleszczewski
  • Patent number: 5679731
    Abstract: A low density, antimigratory cement composition includes cement, water and between about 0.5 to about 2.5 gallons per sack of cement of an additive wherein the additive is a copolymer of an impermeability agent and a gelling agent wherein said impermeability agent is a vinyl acetate-containing material and wherein said gelling agent is a vinyl ester which is compatible with said impermeability agent, whereby said cement composition in slurry form is thixotropic and resistant to gas migration.
    Type: Grant
    Filed: September 21, 1995
    Date of Patent: October 21, 1997
    Assignee: Intevep, S.A.
    Inventor: Wilfredo Rodriguez
  • Patent number: 5674929
    Abstract: The interlayer adhesion and final strength of cementitious compositions which are applied in consecutive layers are improved by the incorporation in the compositions of an admixture which is a combination of a waterproofing agent and a water retention agent. The invention is particularly applicable to sprayed concrete.
    Type: Grant
    Filed: September 6, 1994
    Date of Patent: October 7, 1997
    Assignee: MBT Holding AG
    Inventor: Tom Melbye
  • Patent number: 5668195
    Abstract: A random copolymer corresponding to Formula I in free acid or salt form having the following types and numbers of monomer units; ##STR1## wherein A is selected from the moities (i) and (ii);--CR.sub.1 R.sub.2 --CR.sub.3 R.sub.4 -- (i)wherein R.sub.1 and R.sub.3 are selected from substituted benzene, C.sub.1-8 alkyl, C.sub.2-8 alkenyl, C.sub.2-8 alkylcarbonyl, C.sub.1-8 alkoxy, carboxyl and hydrogen, or R.sub.1 and R.sub.3 can together with R.sub.2 and/or R.sub.4 form a ring; and R.sub.2 and R.sub.4 are selected from hydrogen and C.sub.1-4 alkyl; and ##STR2## wherein R.sub.1 and R.sub.3 are as for (i) and R.sub.7, R.sub.8, R.sub.9 and R.sub.10 are individually selected from hydrogen and C.sub.1-6 alkyl, or R.sub.1 and R.sub.3 together with R.sub.7 and/or R.sub.8, R.sub.9 and R.sub.10 form a continuous C.sub.
    Type: Grant
    Filed: July 26, 1996
    Date of Patent: September 16, 1997
    Assignee: MBT Holding AG
    Inventor: Bernhard Leikauf
  • Patent number: 5665842
    Abstract: A random copolymer corresponding to Formula I in free acid or salt form having the following types and numbers of monomer units; ##STR1## wherein A is selected from the moieties (i) and (ii);--CR.sub.1 R.sub.2 --CR.sub.3 R.sub.4 -- (i)wherein R.sub.1 and R.sub.3 are selected from substituted benzene, C.sub.1-8 alkyl, C.sub.2-8 alkenyl, C.sub.2-8 alkylcarbonyl, C.sub.1-8 alkoxy, carboxyl and hydrogen, or R.sub.1 and R.sub.3 can together with R.sub.2 and/or R.sub.4 form a ring; and R.sub.2 and R.sub.4 are selected from hydrogen and C.sub.1-4 alkyl; and ##STR2## wherein R.sub.1 and R.sub.3 are as for (i) and R.sub.7, R.sub.8, R.sub.9 and R.sub.10 are individually selected from hydrogen and C.sub.1-6 alkyl, or R.sub.1 and R.sub.3 together with R.sub.7 and/or R.sub.8, R.sub.9 and R.sub.10 form a continuous C.sub.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: September 9, 1997
    Assignee: MBT Holding AG
    Inventor: Bernhard Leikauf
  • Patent number: 5663285
    Abstract: Formulations including a high density polyester and a density reducing component. The formulations are useful for facilitating the separation of blood serum or plasma from the cellular portion of blood in blood collection applications.
    Type: Grant
    Filed: August 16, 1996
    Date of Patent: September 2, 1997
    Assignee: Becton Dickinson and Company
    Inventor: Rhyta S. Rounds
  • Patent number: 5661211
    Abstract: A patching compound for patching holes in drywall, cement, and the like, includes well known drywall mud material, water, and various other ingredients such as calcium carbonate, gypsum, perlite, mica, talc, clay, starch, cement, and a preservative, such as sorbic acid or a product sold as boroguard ZB. The various ingredients are mixed with water to provide a relatively soft and pliable filler compound. Silicone caulking may also be used for moisture retention, if desired. The compound is place in a dispenser for dispensing, and the dispenser may either be a relatively small dispenser for household use or a relatively large dispenser for commercial and industrial use. For the household use, the dispenser preferably includes a housing having an asymmetrical configuration in which is disposed a piston. The piston moves within the cylinder and is prevented from rotating by the asymmetrical configuration of the cylinder. Rotation of a threaded rod causes the piston to move the compound, as desired.
    Type: Grant
    Filed: November 30, 1995
    Date of Patent: August 26, 1997
    Inventor: Ronald L. Todd
  • Patent number: 5660626
    Abstract: A shrinkage-reducing dispersing agent for use in cementitious compositions such as concrete and mortar comprising a graft polymer which is a polycarboxylic acid or a salt thereof, having side chains derived from at least one species selected from (a) oligoalkyleneglycol and/or polyalcohol and (b) polyalkylene glycols or derivatives thereof.
    Type: Grant
    Filed: January 31, 1996
    Date of Patent: August 26, 1997
    Inventors: Akira Ohta, Tomomi Sugiyama, Yoshio Tanaka
  • Patent number: 5661206
    Abstract: An admixture for modifying the fluidity of a cementitious mixture comprises a cement-dispersing agent which is an aqueous solution of polymer, in which solution an oxyalkylene-based defoaming agent is dissolved or dispersed in particles of no greater that 20 .mu.M diameter. The polymer is preferably a polymer which comprises units derived from unsaturated carboxylic acid monomer and the polymer is preferably prepared in the presence of the defoaming agent. Particular addition copolymers give particularly good results. The admixture permits good control of the fluidity of cementitious compositions and has extended shelf life.
    Type: Grant
    Filed: December 21, 1995
    Date of Patent: August 26, 1997
    Assignees: MBT Holding AG, Nippon Shokubai Co., Ltd.
    Inventors: Yoshio Tanaka, Akira Ohta, Hideyuki Tahara, Tsuyoshi Hirata
  • Patent number: 5653797
    Abstract: A process for the production of a ready-mixed setting-type joint compound includes the use of calcium sulfate hemihydrate, water, and a set-retarding agent. The retarder includes a polymer composition including acrylic acid and acrylamide monomer units, for example a copolymer (or a mixture of copolymers) of acrylic acid and acrylamide or a blend of a homopolymer of acrylic acid and a homopolymer of acrylamide. The joint compound can be combined with an accelerator including a metallic salt. The joint compound of the invention can be formulated either as a lightweight joint compound or as a conventional weight joint compound. The joint compounds provide short setting times, reduced shrinkage, reduced preparation time, and beneficial application properties.
    Type: Grant
    Filed: April 26, 1996
    Date of Patent: August 5, 1997
    Assignee: National Gypsum Company
    Inventor: Jashbhai M. Patel
  • Patent number: 5651817
    Abstract: When a cement dispersant comprising a polymer which is obtained by co-condensating monomers comprising monomer (A) and monomer (B) with formaldehyde, or a salt obtained by neutralizing the polymer, wherein the monomer (A) is an aromatic compound having, on the average, 1 to 300 mol per molecule of at least one member selected from the group consisting of oxyethylene group and oxypropylene group, and the monomer (B) is an aromatic compound having a carboxyl group; or another cement dispersant comprising a polymer which is obtained by co-condensating monomers comprising the above-described monomer (A), the above-described monomer (B) and monomer (C) which is an aromatic compound having a sulfonic acid group with formaldehyde, or a salt obtained by neutralizing the polymer is used as one component of a hydraulic composition, the fluidity of the hydraulic composition is maintained for a long time. Therefore, no trouble on transportation is caused during the force feeding of the hydraulic composition with a pump.
    Type: Grant
    Filed: December 14, 1995
    Date of Patent: July 29, 1997
    Assignee: Kao Corporation
    Inventors: Fuzio Yamato, Haruyuki Satoh
  • Patent number: 5643978
    Abstract: The present invention is directed to an imidized polycarboxylic acid polymer useful as a cement admixture, to improved cement compositions containing said polymer and to a process of forming the same.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: July 1, 1997
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: David Charles Darwin, Ellis Martin Gartner, Byong-Wa Chun, Hideo Koyata, Lawrence Lu Kuo
  • Patent number: 5634966
    Abstract: Mixed anodic/cathodic corrosion inhibitors for use in hydraulic cement, comprising a) a first component consisting of an amount of alkali or alkaline earth metal nitrite sufficient to inhibit anodic corrosion; and b) a second component comprising an agent that acts to increases the anodic corrosion performance of the first component; wherein said first and second components are present in a weight ratio of from about 1:0.1 to 1:1. Optionally an EO/PO superplasticizer can be incorporated where the weight ratio of the first component, i.e., nitrite, to EO/PO superplasticizer is from about 1:0.005 to 1:0.25, with the surprising benefit of increased protection against cathodic corrosion without harming the level of anodic corrosion inhibition.
    Type: Grant
    Filed: July 19, 1995
    Date of Patent: June 3, 1997
    Assignee: W.R. Grace & Co.-Conn.
    Inventors: Neal S. Berke, Maria C. Hicks