Abstract: Dry castable concrete compositions having improved strength and resistance to aggressive chemicals are provided. The compositions comprise water, hydraulic cement, fine and coarse aggregate, and condensed silica fume, wherein the weight ratio of condensed silica fume to hydraulic cement is about 0.10 to 0.25, the water to cement weight ratio is about 0.18 to 0.33, and the mix has a slump of about 1/2 inch or less. Also provided is a method of preparing the dry castable compositions using aqueous condensed silica fume slurries and a method of dry casting the compositions.
Type:
Grant
Filed:
July 31, 1991
Date of Patent:
October 5, 1993
Assignee:
W. R. Grace & Co.-Conn.
Inventors:
Neal S. Berke, Samuel F. Heleba, Mario A. Tamez
Abstract: Provided is a process for producing molded articles having excellent flexural strength, flexibility and dimensional stability, which comprises autoclave-curing at not lower than 100.degree. C. an aqueous composition comprising a hydraulic material (A) and a polyvinyl alcohol (B) powder, said polyvinyl alcohol (B) powder being contained in an amount of 0.1 to 20% by weight based on the weight of said hydraulic material (A).Also provided are molded articles comprising a hydraulic material (A) and a polyvinyl alcohol (B), said polyvinyl alcohol (B) being contained in an amount of 0.1 to 20% by weight based on the weight of said hydraulic material (A), said molded article having a structure comprising said polyvinyl alcohol (B) having once dissolved and then solidified being dispersed therein in the form of islands. These molded articles have excellent flexural strength, flexibility and dimensional stability.
Type:
Grant
Filed:
December 6, 1990
Date of Patent:
November 17, 1992
Assignee:
Kuraray Co., Ltd.
Inventors:
Akio Mizobe, Kenji Saimen, Sotaro Itadani, Ken Yuki
Abstract: A polymer concrete pipe liner is formed from a fluidized, but substantially waterless cement containing mixture applied to the pipe interior. The mixture is composed of inorganic cement particles, a liquid styrene mixture and a minor amount of one or more poly-olefinically unsaturated co-monomers. The mixture substantially excludes acrylonitrile and acrylamide. The co-monomers are preferable selected from a group including trimethylolpropane-trimethacrylate, divinyl benzene, hexadiene, and polyvinylsiloxanes. Mixing the liquid and solid components forms a slurry which is transferred to a pipe interior. Transfer properties can be controlled by particulate gradation, dissolved polymers, and rheology control additives. The pipe is then spun to centrifugally cast the liner. The composition avoids the need for high temperature curing and toxic reactive unsaturates to co-polymerize and cross-link polystyrene.
Abstract: The method for making a low resin content polymer concrete article includes the steps of: supplying a quantity of polymer or monomer resin; adding a non-reactive solvent, vehicle, dispersant or diluent to the resin; supplying the mixture of diluent and resin to a mixing station; supplying filler material to the mixing station; mixing the diluent, resin and filler material at the mixing station; supplying the resultant mixture to an eduction chamber; educing the non-reactive diluent from the eduction chamber; and supplying the resulting mixture with diluent educed to a forming station for shaping and curing.
Abstract: High-quality machine parts, e.g. machine supports, are manufactured of concrete polymer on the basis of methacrylate monomer polymerizing at room temperature and of aggregates. The monomer used has a dynamic viscosity of less than 10 mPas (10 cP) preferably of 1-10 mPas (1-10 cP). The admixed starter system comprises an organic peroxide and an aromatic tertiary amine, the latter being dissolved in methacrylate monomer.
Abstract: A highly stable melamine-formaldehyde condensate solution for use as superplasticizer additives for cement or the like is produced by condensing melamine and formaldehyde in an aqueous medium, sulfonating the melamine-formaldehyde condensate, further condensing and stabilizing the aqueous sulfonated melamine-formaldehyde condensate solution.
Abstract: An aqueous slurry of gypsum plaster is stabilized by an organic, polymeric, hydrophilic stabilizer for more than 30 days without setting.Upon activation with a Lewis acid the slurry becomes hydrated. The plaster form or the hydrated form may be employed to impregnate a substrate to form insulating sheeting. The substrate may be fabric, felt, paper, nonwoven, or sponge.Open-cell, foamed gypsum may be used alone or molded to shaped articles such as bricks for a firewall.
Abstract: Thermally stable water soluble resins are prepared in a multistep process by reacting the waste solids from the mother liquor waste stream of a melamine manufacturing plant with an aldehyde and a sulfonating agent under controlled conditions of pH and temperature. The resin compositions are useful, for example, as superplasticizing agents for concrete admixtures, as mud drilling additives, and in the paper and textile industry. The process not only provides useful resin compositions, but also recovers solid wastes which are considered to be a major contributor to the pollution problems of melamine manufacturing plants.
Type:
Grant
Filed:
August 25, 1986
Date of Patent:
January 10, 1989
Assignee:
Kuwait Institute for Scientific Research
Abstract: An uncured cementitious composition comprising in admixture:(a) at least one hydraulic cement;(b) at least one reactive water-soluble polymer which is capable of providing a viscous solution in water at low addition levels;(c) water in an amount of from 10 to 25 parts by weight of water per 100 parts by weight of the cement; and(d) a water soluble cross-linking agent capable of effecting chemical cross-links between molecules of the said polymer in the presence of the cement and water.
Type:
Grant
Filed:
October 14, 1986
Date of Patent:
October 18, 1988
Assignee:
Redland Technology Limited
Inventors:
Howard A. Barker, Eric A. Rirsch, John Maxfield
Abstract: A composition for artificial marble which comprises a polymer composition in which an inorganic substance and an organic polymer are firmly bound in one body and a vinyl compound, said polymer composition being obtained by polymerizing a polymerizable vinyl monomer, in the presence of at least one monomer selected from the group consisting of carboxylic acid monomer, sulfonic acid monomer, and sulfonate monomer, in an aqueous polymerization system containing an inorganic substance dispersed therein; and a processs for producing artificial marble from said composition by cast polymerization with the addition of a polymerization initiator.
Abstract: High-quality machine parts, e.g. machine supports, are manufactured of concrete polymer on the basis of methacrylate monomer polymerizing at room temperature and of aggregates. The monomer used has a dynamic viscosity of less than 10 mPas 10cP, preferably of 1-10 mPas 10cP. The admixed starter system comprises an organic peroxide and an aromatic tertiary amine, the latter being dissolved in the methacrylate monomer.
Abstract: A light-weight high-strength plastic concrete is obtained by mixing a nonionic surface active agent having a hydrophilic-lipophilic balance of 3 to 6, a vinyl monomer, and a cement slurry with stirring to form a W/O type emulsion, thereafter polymerizing the vinyl monomer and hardening the cement in the W/O type emulsion simultaneously.The plastic concrete obtained by the aforesaid process has a smooth surface and the appearance thereof is almost same as that of an ordinary cement concrete. The plastic concrete is also excellent in workability such as cutting, scraping riveting, etc.
Abstract: Highly concentrated aqueous solutions of low viscosity of melamine/aldehyde resins are obtained by reacting to a precondensate in a first step melamine and an aldehyde in an alkaline medium and in the presence of water together with at least one compound (I), selected from the group, consisting of an alkali sulfite, an alkaline earth sulfite, an amino sulfonic acid, an amino carboxylic acid, a hydroxycarboxylic acid, a hydroxycarboxylic acid lactone, and a polyhydroxy carboxylic acid lactone, reacting then the thus obtained mixture in a second step with at least one compound (II), selected from the group, consisting of an amino carboxylic acid, a carboxylic acid, a hydroxy carboxylic acid, a hydroxy carboxylic acid lactone, a sulfamic acid, an amino sulfonic acid, a polyhydroxy carboxylic acid and a polyhydroxy carboxylic acid lactone, and then making alkaline the obtained resin solution by adding at least one basic compound (III).
Type:
Grant
Filed:
December 14, 1983
Date of Patent:
February 26, 1985
Assignee:
Sika AG, vorm. Kaspar Winkler & Co.
Inventors:
Theodor A. Burge, Jurg Widmer, Theodor Meyer, Ulrich Sulser
Abstract: This invention is concerned with a polymer concrete composition, which is a two-component composition useful with many bases including metal. Component A, the aggregate composition, is broadly composed of silica, silica flour, portland cement, and acrylamide, whereas Component B, which is primarily vinyl and acrylyl reactive monomers, is a liquid system. A preferred formulation emphasizing the major necessary components is as follows:______________________________________ Component A: Silica sand 60-77 wt. % Silica flour 5-10 wt. % Portland cement 15-25 wt. % Acrylamide 1-5 wt. % Component B: Styrene 50-60 wt. % Trimethylolpropane 35-40 wt. % trimethacrylate ______________________________________and necessary initiators, accelerators, and surfactants.
Type:
Grant
Filed:
May 29, 1984
Date of Patent:
February 19, 1985
Assignee:
The United States of America as represented by the United States Department of Energy
Abstract: Polyester resins are produced by chemically reacting a broken-down alkali metal lignin-cellulose polymer, a substituted organic hydroxy compound and a polycarboxylic acid compound and/or a polycarboxylic acid anhydride. Polyester resins may be used as molding powder, as coating agents and to produce polyurethane foams.
Abstract: Polymerable organic compounds and an epoxide compound are emulsified with aqueous alkali metal silicate solutions then polymerized with a catalyst such as a peroxide type catalyst thereby producing an alkali metal silicate organic plastic which may be used as an adhesive, as molding powder or reacted with an organic diisocyanide to produce polyurethane silicate resins and foams.
Abstract: Polymerable organic compounds are emulsified with aqueous alkali metal silicate solutions then polymerized with a catalyst such as a peroxide type catalyst thereby producing an alkali metal silicate organic plastic which may be used as an adhesive or as molding powder.
Abstract: Compositions which are hardenable in the presence of water to form a poly(carboxylate) cement contain a metal salt which accelerates the setting of the composition.
Type:
Grant
Filed:
September 17, 1979
Date of Patent:
June 29, 1982
Assignee:
National Research Development Corporation
Abstract: Polymerable organic compounds and an epoxide compound are emulsified with aqueous alkali metal silicate solutions then polymerized with a catalyst such as a peroxide type catalyst thereby producing an alkali metal silicate organic plastic which may be used as an adhesive, as molding powder or reacted with an organic diisocyanide to produce polyurethane silicate resins and foams.
Abstract: Polymerable organic compounds are emulsified with aqueous alkali metal silicate solutions then polymerized with a catalyst such as a peroxide type catalyst thereby producing an alkali metal silicate organic plastic which may be used as an adhesive or as molding powder.
Abstract: Poly (polyisocyanate-polyol-alkali metal silicate) solid or foamed products are produced by mixing a dry granular alkali metal silicate with a polyol while heating to form an emulsion which is then reacted with an organic polyisocyanate.