Solid Polymer Derived From Ethylenic Reactants Only, At Least One Of Which Is Propylene Patents (Class 524/70)
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Patent number: 7045570Abstract: The present invention relates to compositions and methods for providing an improved means of modifying asphalt with a polymer. More particularly, this invention provides a solvent system that permits addition of the polymer as a liquid that is preferred over solids addition and handling. The solvent system includes a polymerizable monomer solvent and a rubber or elastomeric polymer.Type: GrantFiled: August 4, 2003Date of Patent: May 16, 2006Assignee: General Electric Co.Inventors: Paul R. Hart, Alan E. Goliaszewski
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Patent number: 6956071Abstract: It has been discovered that certain nitrogen-containing thiols other than mercaptobenzothiazole (MBT) perform equivalently as accelerators in preparing asphalt polymer compositions. Typically, the crosslinker in these compositions is sulfur. Nitrogen-containing thiols containing at least one functional group —N?(SH)— have been found to be useful alternate accelerators along with activators such as zinc oxides. Particular nitrogen-containing thiols include, but are not necessarily limited to, 2-mercaptobenzoxazole (MBO), 2-mercapto-5-methyl-1,3,4-thiadiazole (MMTD), and combinations thereof.Type: GrantFiled: December 20, 2002Date of Patent: October 18, 2005Assignee: Fina Technology, Inc.Inventors: James R. Butler, Bill Lee
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Patent number: 6949593Abstract: Disclosed is a bituminous composition that comprises a bituminous component (A), an elastomer component (B), preferably a block copolymer of a conjugated diene and a monovinylaromatic hydrocarbon, and an additive (C), wherein the additive is a compound of the general formula Ar—R—Ar??(I) wherein each “Ar” independently is a benzene ring or fused aromatic ring system of 6 to 20 carbon atoms, substituted by at least one hydroxyl group, and “R” is an optionally substituted divalent radical comprising 6 to 20 atoms in the backbone and at least one amide and/or ester group in the backbone. These compositions are disclosed to be particularly useful in the preparing and repair of roofing.Type: GrantFiled: September 5, 2003Date of Patent: September 27, 2005Assignee: Kraton Polymers U.S. LLCInventors: Gerardus Wilhelmus Jozef Heimerikx, Erik Adrianus Theunis Trommelen
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Patent number: 6927245Abstract: The present invention provides a dispersing agent that facilitates the delivery of a cross-linking agent to polymer modified asphalt. The present invention further includes a composition comprising a liquid hydrocarbon, the dispersant and cross-linking agent, and methods of preparing the composition and of preparing cross-linked polymer modified asphalt composition.Type: GrantFiled: June 4, 2003Date of Patent: August 9, 2005Assignee: Fina Technology, Inc.Inventors: Paul Buras, James R. Butler
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Patent number: 6872763Abstract: Provided is a vulcanizing agent for vulcanizing bitumen, which vulcanizing agent comprises a sulphur agent and a binder, wherein the vulcanizing agent is in the form of pellets. Further provided is a process for producing a surfacing composition, which process comprises contacting bitumen with an elastomer and the vulcanizing agent of the present invention.Type: GrantFiled: October 24, 2001Date of Patent: March 29, 2005Assignee: ATOFINA Research, S.A.Inventor: Patrizio Andriolo
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Patent number: 6818687Abstract: A polymer modified asphalt is characterized by the addition of a carrier material such as mineral oil. The carrier material is mixed with an activator material and then added to a hot mixture of polymer and asphalt. The activator assists the polymer material in linking with the asphalt while the carrier prevents the formation of gel or lumps within the asphalt. The modified asphalt retains its rheological and solubility characteristics.Type: GrantFiled: March 18, 2003Date of Patent: November 16, 2004Inventor: G. Mohammed Memon
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Patent number: 6790897Abstract: A fluid or semifluid additive composition useful for asphalt paving comprises between about 10% and about 50% crumb rubber, about 10% and about 50% petroleum hydrocarbon having at least about 50% aromatics, between about 10% and about 50% surface active clay, and water, by weight.Type: GrantFiled: September 17, 2003Date of Patent: September 14, 2004Assignee: Flex Products, Inc.Inventors: Michael V. Burris, Bryan B. Burris
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Patent number: 6767939Abstract: The present invention provides a method for preparing an asphalt and thermoplastic elastomer composition. The process comprises heating an asphalt cut in a stirred tank to a temperature sufficient to allow the stirring of the asphalt in the tank. A thermoplastic elastomer or rubber is added to the asphalt while continuing to stir the asphalt. The mixture is stirred at a speed and for a period of time sufficient to increase the distribution of the elastomer into the asphalt. The stirring speed is reduced and the temperature is increased to add crosslinking agents to the tank. Stirring is continued for a period of time sufficient to improve the distribution of the crosslinking agent dispersion in the asphalt. Crosslinking agents include compositions of mercaptobenzothiazole, zinc oxide and elemental sulfur; compositions of mercaptobenzothiazole, zinc oxide, and mixed polythiomorpholine; and compositions of zinc 2-mercaptobenzothiazole and dithiodimorpholine.Type: GrantFiled: May 7, 2002Date of Patent: July 27, 2004Assignee: Fina Technology, Inc.Inventors: James R. Butler, Kevin P. Kelly, Paul Buras
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Patent number: 6759453Abstract: The invention comprises polymers which have been functionalized so as to be able to chemically react with polyamines to form adducts containing at least one or more groups consisting of amino, amido, imino, imido, or imidazloyl. Furthermore, the invention teaches processes to prepare these adducts by solution, melt or in-situ methods. A further embodiment of the invention pertains to the use of polyolefin plastomers or elastomers, elastomeric polyethylene-polypropylene, compositions or interpolymers of styrene-&agr; olefins, which have been chemically modified so that they react with polyamines to confer to asphalt significantly improved desired chemical and physical properties.Type: GrantFiled: October 3, 2001Date of Patent: July 6, 2004Inventors: Murray Jelling, Richard F. Stockel, James Henderson Collins, Mohamed Emam Labib
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Patent number: 6727299Abstract: The present invention relates to a novel aromatic polysulfide and an asphalt composition containing the same, and more particularly, to a novel aromatic polysufide having repeating units of the following formula (I), an asphalt composition, an asphalt paving composition, an adhesion promoter and an UV absorber containing the same: The asphalt paving composition of this invention exhibits excellent adhesiveness to aggregate component and better water resistance, and renders the temperature susceptibility less sensitive, thereby greatly improving durability.Type: GrantFiled: July 25, 2002Date of Patent: April 27, 2004Assignee: Markpro Company, LimitedInventor: Kyung-Sup Shim
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Patent number: 6713539Abstract: A storage-stable modified asphalt composition, which comprises: 50-97.7 parts by weight of a base asphalt, 2.0-20.0 parts by weight of a polymer having double bonds, 0.1-20.0 parts by weight of a compatibilizer, 0.1-10.0 parts by weight of a cross-linking reagent, and 0.1-10.0 parts by weight of a organic polar compound, and the softening point difference of its product determined by the stability test is lower than 2.5° C. The process for preparing said modified asphalt composition is mixing 50-97.7 parts by weight of a base asphalt, 2.0-20.0 parts by weight of a polymer having double bonds, 0.1-20.0 parts by weight of a compatibilizer 0.1-10.0 parts by weight of a cross-linking reagent, and 0.1-10.0 parts by weight of a organic polar compound under certain conditions. The modified asphalt provided by the present invention has good storage-stability. The preparation process provided by the present invention is simple, and there is no need for special apparatus.Type: GrantFiled: August 17, 2001Date of Patent: March 30, 2004Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, SinopecInventors: Shuhua Guo, Weiqi Huang, Jun Long, Baichun Zhang, Zijun Wang, Yucheng She
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Patent number: 6713540Abstract: A process is provided for crosslinking polymer modified asphalt compositions using a combination of a crosslink initiator, crosslink co-agent and crosslinkable polymer, to provide a process that is more reliable and more reproducible and that gives products that have a combination of properties that are superior to conventional sulfur crosslinked compositions.Type: GrantFiled: March 8, 2002Date of Patent: March 30, 2004Assignee: Polimeri Europa Americas, Inc.Inventors: Moises Cisneros Rached, Edward Mazzone, Maria Grazia Cabvaliere
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Patent number: 6653389Abstract: A fluid or semifluid additive composition useful for asphalt paving consists essentially of between about 10% and about 50% crumb rubber, about 10% and about 50% petroleum hydrocarbon having at least 55% aromatics, between about 10% and about 50% surface active clay, and water, by weight.Type: GrantFiled: November 19, 2001Date of Patent: November 25, 2003Assignee: Flex Products, Inc.Inventors: Michael V. Burris, Bryan B. Burris
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Patent number: 6583202Abstract: This invention relates to a roofing or siding membrane comprising a non-woven mat coated with an asphaltic composition containing, in addition to 35-75 wt. % bitumen, a mixture of isotactic and amorphous propylene polymers and between about 0.08 and about 15 wt. % of a functionalized, olefin polymer to provide a non-staining membrane of high tensile strength, low polyolefin content with respect to asphalt, improved compatibility between asphalt and non-functionalized polymers and reduced light end asphalt and polymer exudates. The invention also relates to a method for preparing the membrane.Type: GrantFiled: September 13, 2001Date of Patent: June 24, 2003Assignee: Building Materials Investment CorporationInventors: Louis Lynn Grube, George Manuel Adao, Krishna Venkataswamy
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Patent number: 6569351Abstract: The present invention is directed to a an accelerator-gel additive used to deliver an accelerator such as sulfur, into a system for the production of polymer modified asphalt, vulcanized rubber or similar system. Unlike conventional methods of delivering accelerator into the system, the accelerator-gel additive suspends the accelerator in a gel system thereby preventing the sedimentation of the accelerator during processing. As a result, the polymer and asphalt are processed at lower temperature reducing the production of toxic and flammable gases such as hydrogen sulfide.Type: GrantFiled: March 14, 2000Date of Patent: May 27, 2003Assignee: Ergon, Inc.Inventors: Gaylon L. Baumgardner, Martin R. Burrow, John Dumas, Andrew Menapace, James Smith
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Patent number: 6569925Abstract: The present invention is directed to a an accelerator-gel additive used to deliver an accelerator such as sulfur, into a system for the production of polymer modified asphalt, vulcanized rubber or similar system. Unlike conventional methods of delivering accelerator into the system, the accelerator-gel additive suspends the accelerator in a gel system thereby preventing the sedimentation of the accelerator during processing. As a result, the polymer and asphalt are processed at lower temperature reducing the production of toxic and flammable gases such as hydrogen sulfide.Type: GrantFiled: August 9, 2002Date of Patent: May 27, 2003Assignee: Ergon, IncorporatedInventors: Gaylon L. Baumgardner, Martin R. Burrow, John Dumas, Andrew Menapace, James Smith
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Patent number: 6538060Abstract: Elastomeric polyurethane interpenetrating network compositions are disclosed which are preferably developed by in situ reaction of polyols with different isocyanates and polyisocyanates in a bituminous material, such as, asphalt, coal tar, polymer modified asphalt, oxidized, and unoxidized asphalt. The composition is preferably formed at a temperature between 200° F. and 350° F. The reaction kinetics can be accelerated by including catalysts and curing agents. Bituminous polyurethane interpenetrating network elastomers are suitable for a wide variety of applications including but not limited to roofing, new construction, and wall and foundation waterproofing applications.Type: GrantFiled: June 27, 2001Date of Patent: March 25, 2003Assignee: Urecoats International, Inc.Inventors: Ponswamy Rajalingam, Umarani Rajalingam
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Patent number: 6469075Abstract: The present invention provides a method for preparing an asphalt and thermoplastic elastomer composition. The process comprises heating an asphalt cut in a stirred tank to a temperature sufficient to allow the stirring of the asphalt in the tank. A thermoplastic elastomer or rubber is added to the asphalt while continuing to stir the asphalt. The mixture is stirred at a speed and for a period of time sufficient to increase the distribution of the elastomer into the asphalt. The stirring speed is reduced and the temperature is increased to add crosslinking agents to the tank. Stirring is continued for a period of time sufficient to improve the distribution of the crosslinking agent dispersion in the asphalt. Crosslinking agents comprise zinc 2-mercaptobenzothiole and elemental sulfur in a ratio of zinc 2-mercaptobenzothiazole to sulfur of 2.0/1.0. Useful concentrates are possible using this method while avoiding gel formation.Type: GrantFiled: November 14, 2000Date of Patent: October 22, 2002Assignee: Fina Technology, Inc.Inventors: James R. Butler, Kevin P. Kelly, Karen Scheel
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Patent number: 6429241Abstract: Polymer modified bituminous compositions which are stable against phase separation are provided at greater levels of incorporation of elastomeric polymer having a conjugated diene structure, such as styrene-butadiene rubbers, and/or cross-linking agent, specifically sulfur, by incremental addition of elastomeric polymer and/or cross-linking agent into the bitumen at elevated temperatures of about 150° to about 220° C.Type: GrantFiled: December 2, 1999Date of Patent: August 6, 2002Assignee: Polyphalt LLCInventor: Zhi-Zhong Liang
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Patent number: 6414056Abstract: The present invention relates to novel polymer modified asphalt polyphosphoric and superphosphoric acid treated binder compositions having enhanced high service temperature performance properties and the method of making them and to road paving asphalts containing them.Type: GrantFiled: May 8, 1998Date of Patent: July 2, 2002Assignee: ExxonMobil Research and Engineering CompanyInventors: Olga Puzic, Kenneth Edward Williamson
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Patent number: 6407152Abstract: A process for the preparation of an asphalt and polymer composition in which a minor amount of polymer component is subjected to a crosslinking. An asphalt base material is heated in a mixing chamber at a temperature sufficient to melt the asphalt and allow stirring of the asphalt within the chamber. A thermoplastic elastomer is added to the chamber in an amount not greater than 12 wt. %. While the asphalt elastomer formulation is stirred, a crosslinking agent is added in an amount effective to crosslink the thermoplastic elastomer. The crosslinking agent formulation comprises at least two components. One component is a thiopolymer incorporating organic sulfur prepared by the reaction of 6-tertiary butyl cresol and sulfur dichloride which reacts to produce a reaction product comprising 4,4-thiobis(6-tertiary butyl-m-cresol) and the thiopolymer, followed by subsequent separation of the 4,4-thiobis(6-tertiary-butyl-m-cresol) from the thiopolymer product.Type: GrantFiled: November 28, 2000Date of Patent: June 18, 2002Assignee: Fina Technology, Inc.Inventors: James R. Butler, Kevin P. Kelly
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Publication number: 20020052432Abstract: Bituminous compositions of the bitumen-polymer type, in homogenous phase, contain at least one bitumen base and are prepared from at least one polymer of the thermoplastic polyolefin type. These compositions have a thermoplastic polyolefin content of at least 1% by weight of which the crystallinity rate is greater than or equal to 30%, a melting temperature greater than or equal to 110° C. and a penetrability at 25° C. less than or equal to 300 tenths of a millimeter.Type: ApplicationFiled: November 16, 2001Publication date: May 2, 2002Applicant: TOTAL RAFFINAGE DISTRIBUTION S.A.Inventors: Guy Lemoine, Jacques Nicaud, Jacques Jarrin
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Patent number: 6380284Abstract: The invention concerns the continuous production of asphalts modified by the addition of polymers and reacted with sulfur. The binders produced by said methods can contain very high amounts of polymers, also combined with secondary materials such as: rubber, various plastics, and waste lubricants. This type of binder, which cannot be obtained by discontinuous batch technology, is produced by the continuous mixing of several asphalt components through a static mixer. Said binders provide very high-performance asphalts and agents for regenerating old asphalts contained in waste road materials, in the process of hot recycling of coated materials. They are also used for producing novel emulsions of highly modified binders, with multiple applications and in particular for cold recycling. This novel method, by regenerating old asphalt contained in waste coated materials, represents a means for waste conversion and for limiting the use of asphalt and road-surfacing aggregates.Type: GrantFiled: May 15, 2000Date of Patent: April 30, 2002Inventor: Emile Lopez
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Patent number: 6359033Abstract: A paving composition comprises a mixture of about 90 to 99.5 wt. % of an asphaltic material and about 0.5 to 10 wt. % of solid particles each encapsulated with a cross-linked polymer, the encapsulated particles being uniformly dispersed in the asphaltic material. The encapsulated particles have a particle-to-polymer weight ratio so as to provide a density match between the encapsulated particles and the asphaltic material. The paving composition according to the invention has a higher complex viscosity at high temperatures (60° C.) and is more ductile at low temperatures (−15° C.) in comparison with the base asphaltic material. Moreover, the composition is completely stable at elevated temperatures (160° C.) or during long periods of storage.Type: GrantFiled: July 17, 2000Date of Patent: March 19, 2002Assignee: Universite Laval, Cite UniversitaireInventors: Abdellatif Ait-Kadi, Ali Akbar Yousefi
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Patent number: 6310122Abstract: The present invention provides a method for preparing an asphalt and thermoplastic elastomer composition. The process comprises heating an asphalt cut in a stirred tank to a temperature sufficient to allow the stirring of the asphalt in the tank. A thermoplastic elastomer or rubber is added to the asphalt while continuing to stir the asphalt. The mixture is stirred at a speed and for a period of time sufficient to increase the distribution of the elastomer into the asphalt. The stirring speed is reduced and the temperature is increased to add an oil dispersion or aqueous emulsion of crosslinking agents to the tank. Stirring is continued for a period of time sufficient to improve the distribution of the crosslinking agent dispersion in the asphalt.Type: GrantFiled: September 3, 1999Date of Patent: October 30, 2001Assignee: Fina Technology, Inc.Inventors: James R. Butler, Kevin P. Kelly
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Patent number: 6284820Abstract: The present invention relates to bituminous compositions, particularly suitable for paving and building waterproofing, comprising a bitumen and a copolymer of ethylene with propylene and/or other alpha-olefins and optionally with smaller proportion of a diene or polyene. The copolymer is besides characterized by a very low crystallinity, intrinsic viscosity higher than 1.5 dl/g and by a content of propylene units or of the alpha-olefin in form of triads comprised between 4 and 50% of the propylene or of the alpha-olefin, with at least 70% of said triads having isotactic structure.Type: GrantFiled: July 24, 1997Date of Patent: September 4, 2001Assignee: Montell Technology company BVInventors: Vittorio Braga, Emilio Martini, Maurizio Galimberti, Enrico Albizzati
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Publication number: 20010018475Abstract: A thermoplastic elastomer composition for calender-molding obtained by dynamically heat-treating a mixture comprising 40 to 95% by weight of (A) an oil-extended olefin copolymer rubber containing 100 parts by weight of an olefin copolymer rubber having a Mooney viscosity (ML1+4100° C.) of 120 to 350 and 20 to 150 parts by weight of mineral oil softening agent and 60 to 5% by weight of (B) a polypropylene resin, a process for producing a calendered sheet from the composition and a sheet obtained by the process.Type: ApplicationFiled: February 1, 2001Publication date: August 30, 2001Inventors: Takeshi Tominaga, Nobuhiro Natsuyama, Hironobu Shigematsu, Tatsuo Hamanaka, Makoto Makino
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Patent number: 6218449Abstract: The invention provides a method comprising contacting, between 100° C. and 230° C. and under agitation, an elastomer, a functionalising agent and optionally, a peroxide compound. The functionalising agent is a thiolcarboxylic acid polyester or a reaction product of a thiolcarboxylic acid or ester with ethylene sulphide. The functionalised elastomer can also be pre-formed, then incorporated into the bitumen. The resulting compositions are usable directly or after dilution, for forming bituminous binders to produce surfacing, coating and waterproofing materials.Type: GrantFiled: April 12, 1999Date of Patent: April 17, 2001Assignee: Elf Antar FranceInventors: Jean-Pascal Planche, Paul Maldonado, Bernard Neff, Thierry Senninger, Annie Zins, St{overscore (e)}phane Drouilhet
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Patent number: 6214908Abstract: A composition comprising a binder and a residue wherein the residue comprises a blend of polypropylene, styrene butadiene rubber and calcium carbonate. The residue is a novel material derived as a coproduct from the medium-pressure depolymerization of nylon 6 carpet. The compositions are useful as road asphalt, asphalt roof membranes, molding compounds, and plastic lumber such as palisades and spacers.Type: GrantFiled: July 19, 1999Date of Patent: April 10, 2001Assignee: AlliedSignal Inc.Inventors: Kwok Wai Lem, Alan Letton, Thomas Paul John Izod, Francis Stephen Lupton, William Brian Bedwell
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Patent number: 6191217Abstract: The present invention teaches a method for enabling the formation of a high damping, soft polymer gel. The method includes: reacting a poly(alkyl vinylether-co-maleimide) polymer with a maleated polyalkylene and an alkyl diamine under substantially dry conditions sufficient to form a polyalkylene grafted poly(alkyl vinylether-co-maleimide) polymer product; and, dispersing the polyalkylene grafted poly(alkyl vinylether-co-maleimide) polymer product with an extender oil sufficient to form the gel. The present invention also contemplates a polymer gel composition, a polymer composition and an article manufactured from the polymer gel composition.Type: GrantFiled: November 17, 1998Date of Patent: February 20, 2001Assignee: Bridgestone CorporationInventors: Xiaorong Wang, Victor J. Foltz, Terrence E. Hogan
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Patent number: 6180697Abstract: The present invention provides a method for preparing an asphalt and thermoplastic elastomer composition. The process comprises heating an asphalt cut in a stirred tank to a temperature sufficient to allow the stirring of the asphalt in the tank. A thermoplastic elastomer or rubber is added to the asphalt while continuing to stir the asphalt. The mixture is stirred at a speed and for a period of time sufficient to increase the distribution of the elastomer into the asphalt. The stirring speed is reduced and the temperature is increased to add an oil dispersion of crosslinking agents to the tank. Stirring is continued for a period of time sufficient to improve the distribution of the crosslinking agent dispersion in the asphalt.Type: GrantFiled: September 4, 1999Date of Patent: January 30, 2001Assignee: Fina Technology, Inc.Inventors: Kevin P. Kelly, James R. Butler
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Patent number: 6156827Abstract: Bituminous compositions of the bitumen-polymer type, in homogenous phase, contain at least one bitumen base and are prepared from at least one polymer of the thermoplastic polyolefin type. These compositions have a thermoplastic polyolefin content of at least 1% by weight of which the crystallinity rate is greater than or equal to 30%, a melting temperature greater than or equal to 110.degree. C. and a penetrability at 25.degree. C. less than or equal to 300 tenths of a millimeter.Type: GrantFiled: February 17, 1999Date of Patent: December 5, 2000Assignees: Total Raffinage Distribution S.A., Institut Francais du PetroleInventors: Guy Lemoine, Jacques Nicaud, Jacques Jarrin
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Patent number: 6130276Abstract: In a method of melting asphalt in a vessel, the molten asphalt normally emitting fumes, 0.2 weight percent to 6 weight percent of a polymer is added to the asphalt to reduce the visual opacity of the fumes by at least 25% over the same asphalt without the polymer. In another embodiment, the total emissions of benzene soluble suspended particulates is reduced by at least 15% over the same asphalt without the polymer. Preferably, the added polymer has a melt flow index of from 15 grams/10 minutes to 95 grams/10 minutes, and the added polymer reduces the visual opacity of the fumes by forming a skim on the upper surface of the molten asphalt.Type: GrantFiled: March 12, 1999Date of Patent: October 10, 2000Assignee: Owens Corning Fiberglas Technology, Inc.Inventors: Donn Roy Vermilion, Michael Richard Franzen, Richard T. Janicki, David Charles Trumbore, Jay W. Keating, Jorge Alberto Marzari
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Patent number: 6107373Abstract: A consumable container is molded from a composition comprising 40 to 90 weight % of an asphalt and 10 to 60 weight % of a polymer material, which advantageously can include a first polymer such as PP that imparts heat resistance and a second polymer such as EVA that imparts toughness and impact resistance. This molded asphalt/polymer material preferably has an unnotched Izod impact strength of at least 2 joules. The container is consumable--it can be melted along with roofing asphalt held in the container without adversely affecting the properties of the asphalt and without requiring undue mixing. The composition also can be used to reduce fumes normally emitted from a kettle of molten asphalt, e.g., as measured by a reduction of the visual opacity of the fumes by at least 25%, a reduction of the hydrocarbon emissions of the fumes by at least 20%, or a reduction of the total suspended particulates emissions of the fumes by at least 15%. The container may be used, e.g.Type: GrantFiled: September 30, 1997Date of Patent: August 22, 2000Assignee: Owens Corning Fiberglas Technology, Inc.Inventors: Richard T. Janicki, Donn R. Vermilion, Kevin P. Gallagher, Frederick H. Ponn, Michael R. Franzen, Jorge A. Marzari, Jay W. Keating, David C. Trumbore, Steven G. Harris, Edward Mirra, Jr.
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Patent number: 6069194Abstract: A method and apparatus for packaging a low-fuming meltable asphalt composition which includes the introduction of pellets comprising one or more polymeric materials into molten asphalt flowed into a conventional container or carton.Type: GrantFiled: December 12, 1997Date of Patent: May 30, 2000Assignee: Owens Corning Fiberglass Technology, Inc.Inventors: Michael R. Franzen, Donn R. Vermilion, David C. Trumbore, Richard T. Janicki, Jeffrey W. Smith, Jay W. Keating, Jorge A. Marzari, Thomas C. Bitsky, Ron S. Bliss
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Patent number: 6060542Abstract: The invention provides a process for preparing a bitumen composition comprising blowing a mixture with an oxygen-containing gas which mixture comprises a bitumen having a penetration of less than 300 dmm (as measured by ASTM D 5 at 25.degree. C.), a thermoplastic rubber which is present in an amount of less than 10% w, and a bitumen blowing catalyst which is present in an amount of more than 0.5% w and up to 3% w, both based on total mixture; and bitumen compositions obtainable by such process.Type: GrantFiled: May 5, 1998Date of Patent: May 9, 2000Assignee: Shell Oil CompanyInventors: Gerrit Van Gooswilligen, Michael Christopher Phillips, Koen Steernberg
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Patent number: 6057390Abstract: A method is provided for improving high temperature performance grade properties of asphalt which comprises i) heating an asphalt cement to 200 to 500.degree. F. (93 to 260.degree. C.), ii) adding 1 to 10 wt. % crosslinkable polymer, e.g., styrene-butadiene-styrene triblock copolymer based on weight of said asphalt cement, iii) adding a useful temperature index (UTI) improving amount of dioxime(s) of 1,4-benzoquinone and its derivatives and optionally, free radical initiator, e.g., organic peroxide, and iv) mixing the resulting blend, thereby providing a paving asphalt having a greater useful temperature index (UTI) than a corresponding blend to which no dioxime is added. The invention further relates to asphalt compositions thus made and paving compositions containing these asphalt compositions.Type: GrantFiled: June 15, 1999Date of Patent: May 2, 2000Assignees: Ashland Inc., Marathon Ashland Petroleum LLCInventors: Roman Loza, Laurence G. Dammann, Roger E. Hayner, Patricia K. Doolin
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Patent number: 6046260Abstract: A zinc oxide dispersion for use in rubber compounds having at least 40, preferably 74-92, weight percent zinc oxide powder and at least five weight percent of a binder selected from the group consisting of asphalt and terpene tackifiers. The dispersion also preferably includes at least 0.5 weight percent stearifying agent such as stearic acid.Type: GrantFiled: January 13, 1998Date of Patent: April 4, 2000Assignee: Flow Polymers, Inc.Inventor: James W. Hoover
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Patent number: 6020404Abstract: Bitumen/polymer compositions are provided containing a bitumen or a mixture of bitumens and, reckoned by weight of bitumen, 0.3% to 20% of at least one primary polymer selected among certain elastomers and plastomers and 0.01% to 12% of at least one olefinic polymer bearing epoxy or COOH groupings. The compositions are useful, directly or after dilution, to form bitumen/polymer binders for carrying out road surfacing, for coated materials or waterproof coatings.Type: GrantFiled: January 7, 1998Date of Patent: February 1, 2000Assignee: Elf Antar France Tour Elf-2 Place de la CoupoleInventors: Jean-Pascal Planche, Patrick Turello, Claude Lacour
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Patent number: 6011095Abstract: Bitumen/polymer compositions are produced by contacting, between 100.degree. C. and 230.degree. C., under agitation, one bitumen or a mixture of bitumens with at least one olefinic polymer bearing epoxy or COOH groupings, then by incorporating in the product, an acid additive while the whole mixture is agitated at a range between 100.degree. C. and 230.degree. C. for at least 10 minutes. The product, which is subjected to treatment by the acid additive may still contain one or several additional polymers, for instance of the elastomer type cross-linkable with sulphur, and even be subjected to sulphur cross-linking before treatment. The bitumen/polymer compositions are useful directly or after dilution, to form binders for carrying out surfacing operations.Type: GrantFiled: April 20, 1998Date of Patent: January 4, 2000Assignee: ELF Antar FranceInventors: Jean-Pascal Planche, Patrick Turello, Claude Lacour
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Patent number: 5990206Abstract: Preparation of an asphalt composition using an asphalt modifier composition comprising at least one member selected from the group consisting of rubber-base modifiers and resin-base modifiers and a phosphorus compound permits the modifier to be satisfactorily dissolved in asphalt. Further, when paving is conducted by using a composition for paving prepared with such the asphalt composition, the adhesion of asphalt to an aggregate is high, and the resultant pavement has markedly improved in rutting resistance and wearing resistance. Therefore, such the pavement has a prolonged service life.Type: GrantFiled: November 13, 1997Date of Patent: November 23, 1999Assignee: Kao CorporationInventors: Shingo Tanaka, Takayuki Ikenaga
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Patent number: 5959007Abstract: Stable rubberized bitumen concentrates are prepared by initially forming a mass comprising bitumen and crumb rubber particles in an amount of at least about 15 wt % of the mass with the crumb rubber being swollen in-situ, and applying shear and temperature conditions to the mass to dissociate the vulcanizate network of the rubber particles and to incorporate the digested vulcanizate into the bitumen. The stable rubberized bitumen concentrate is stable against sedimentation of rubber particles both following storage of the concentrate at about 320.degree. F. for 48 hours and dilution to a lower concentration in the ASTM solubility test.Type: GrantFiled: November 20, 1997Date of Patent: September 28, 1999Assignee: Polyphalt L.L.C.Inventor: Zhi-Zhong Liang
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Patent number: 5948827Abstract: A rubber composition obtained by recycling scrap material and adapted for use as raw material for manufacturing products for building, automobile accessory, and footwear industries possibly as a replacement for wood, zinc sheet, fiber cement, plastic and any other rigid or semirigid material. The composition includes from about 66% to about 77% of particles of ground tires having a size between about 18 and about 30 microns, from about 15% to about 22% of particles of ground plastic material having a size between about 18 and about 30 microns, and from about 8% to about 12% of a solution of acid with toluene or methyl isobutyl ketone. The acid may be lactic acid, phosphoric acid or formic acid. The percentage of acid in the solution by volume is from about 12% to about 50% and the percentages of toluene or methyl isobutyl ketone in the solution by volume is from about 50% to about 88%.Type: GrantFiled: January 13, 1997Date of Patent: September 7, 1999Inventors: Joaquin Lupo, Luis Jacinto Tre
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Patent number: 5840109Abstract: Mixtures containing bitumen and at least one polymer selected from (A) an essentially atactic propylene homopolymer, (B) an amorphous propylene copolymer with a C.sub.4 -C.sub.10 .alpha.-olefin, and (C) an amorphous propylene copolymer with ethylene; the polymers (A) and (B) having the following characteristics:intrinsic viscosity (.eta.): greater than 1 dl/g;% (r)-% (m)>0, where % (r) is the percentage of the syndiotactic dyads, and % (m) is the percentage of the isotactic dyads;less than 2% of the CH.sub.2 groups are contained in the (CH.sub.2).sub.n sequences where n.gtoreq.2; andBernoulli index (B)=1.+-.0.2;the copolymer (C) having the following characteristics:the quantity of propylene in the copolymer (%P), expressed in mole percentage, and the EPE/(EPE+PPE+PPP) triad ratio satisfy the following equation:0.01 % P+EPE/(EPE+PPE+PPP).gtoreq.1;and less than 2% of the CH.sub.2 groups are contained in the (CH.sub.2).sub.n sequences where n is an even number.Type: GrantFiled: February 21, 1997Date of Patent: November 24, 1998Assignee: Montell North America Inc.Inventors: Vittorio Braga, Franco Sartori
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Patent number: 5756565Abstract: Non-gellable, high temperature storage-stable bitumen/polymer compositions are provided and which are produced by stirring a sulphur-cross-linkable elastomer, an antigelling adjuvant and a sulphur-donating coupling agent into a bitumen or bitumen mixture at 100.degree.-230.degree. C. The antigelling adjuvant has the formula R--X wherein R is a C.sub.2-50 monovalent organic radical and X is a carboxylic acid, sulfonic acid or phosphoric acid group. The bitumen-polymer compositions may be used directly or in diluted form in a bitumen or bitumen mixture to form bitumen/polymer binders for producing road surfaces, coating materials or sealing materials.Type: GrantFiled: November 13, 1995Date of Patent: May 26, 1998Assignee: Elf Antar FranceInventors: Laurent Germanaud, Jean-Pascal Planche, Trung Kiet Phung
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Patent number: 5750598Abstract: The bitumen/polymer composition comprises a bitumen, an elastomeric polymer vulcanisable with sulphur in an amount of 0.5 to 20% by weight of the bitumen, a sulphur-donating vulcanising agent, a vulcanisation accelerator and a viscosity-reducing agent chosen from water and hydrocarbon oils. The vulcanisation accelerator present in the composition consists of one or more vulcanisation accelerators active at temperatures below 100.degree. C., and the viscosity-reducing agent is used in an amount suitable for rendering the composition liquid at temperatures below 100.degree. C.Type: GrantFiled: March 6, 1995Date of Patent: May 12, 1998Assignee: Eli FranceInventors: Dennis Krivohlavek, Gayle King, Jean-Pascal Planche
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Patent number: 5744524Abstract: An asphaltic compound according to the invention includes from about 70 to about 45 parts by weight of asphalt; from about 15 to about 25 parts by weight of a polymer modifier for said asphalt; from about 15 to about 25 parts by weight of a filler; and, from about 0.1 to about 5 parts by weight of a dispersing agent. The dispersing agent can be selected from the group consisting of stearic acid, tri(dioctyl) pyrophosphate titanate, tri(dioctyl) pyrophosphate-O, neoalkoxy tridodecylbenzenesulfonyl titanate, lecithin, aluminum stearate, maleic anhydride-modified ethylene/alpha-olefin copolymer, maleic anhydride grafted propylene-ethylene copolymer, ethoxylated alcohol, and mixtures thereof.Type: GrantFiled: March 13, 1997Date of Patent: April 28, 1998Assignee: Bridgestone/Firestone, Inc.Inventors: Eraj D. Manandhar, Arthur M. Usmani
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Patent number: 5733645Abstract: Disclosed is a process for producing non-blocking slats of normally tacky amorphous propylene copolymers. The process entails coextruding the normally tacky amorphous propylene copolymer with a low viscosity polyolefin such as a polyethylene wax forming a core of amorphous propylene copolymer covered with a sheath of polyethylene wax. The coextruded article is cooled, cut (while exposing less than 40 percent of the core) and then coated with a non-tacky powder; thereby, forming non-blocking slats. Disclosed is also a novel amorphous propylene copolymer composition containing no more than 90 weight percent propylene and up to 70 weight percent of an alpha olefin comonomer having a needle penetration greater than 70 to less than 100 dmm at 23.degree. C. and a Brookfield Thermosel Viscosity below 1000 cP at 190.degree. C.Type: GrantFiled: August 5, 1996Date of Patent: March 31, 1998Inventor: Marc Stacey Somers
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Patent number: 5703148Abstract: An asphalt-polymer composition containing:a) at least 25 to 97 wt % of an asphalt,b) at least 1 to 25 wt % of a polymer, andc) at least 2 to 50 wt % of aromatic compound(s),whereinthe aromatic compound(s) is present in an amount greater than 2 wt %,the at least one aromatic compound(s) and the polymer are present in amounts such that the ratio of amount present of aromatic compound to amount present of polymer is from 0.5 to 10, andthe composition has a FRAASS point of less than or equal to -13.degree. C. and a storage stability defined by a".DELTA. ring-and-ball" and a ".DELTA. penetrability" of less than or equal to 5. Also a process for preparing such asphalt-polymer composition including mixing the asphalt, the polymer and the aromatic compound at a temperature from 190.degree. to 300.degree. C. for a period of time preferably exceeding 30 minutes. The asphalt-polymer composition can be used as a road asphalt, emulsion or surface coating.Type: GrantFiled: March 16, 1995Date of Patent: December 30, 1997Assignee: Total Raffinage Distribution S.A.Inventors: Yannick Jolivet, Michel Malot, Didier Jamois
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Patent number: 5672642Abstract: The invention is a process for the preparation of storage stable asphalt-polymer blends, comprising:a. contacting sulfur with asphalt; andb. contacting a polymer with the sulfur-asphalt mixture under conditions such that a compatible and homogeneous polymer-asphalt blend is formed.The process of the invention allows the preparation of compatible asphalt-polymer blends that are more stable while utilizing a more cost efficient, faster process and still maintaining the desired physical properties of good weatherability and creep resistance.Type: GrantFiled: February 29, 1996Date of Patent: September 30, 1997Assignee: The Dow Chemical CompanyInventor: William A. Gros