Diorgano Siloxane Contains Units Of -((r)si(r)-o-)* Where * Is Subscript Two Or More Patents (Class 524/731)
  • Patent number: 7141614
    Abstract: A photosensitive resin composition of the present invention contains a (A) soluble polyimide and a (b) (meth)acrylic compound, the (A) soluble polyimide being soluble in an organic solvent and being synthesized by using an acid dianhydride component and at least one of a diamine component containing a siloxane structure or an aromatic ring structure, and a diamine component having, in its structure, a hydroxyl group a carboxyl group or a carbonyl group, and the (B) (meth)acrylic compound having at least one carbon-carbon double bond, and preferably contains at least one of a (C) photo reaction initiator and a (D) fire retardant. With this arrangement, the photosensitive resin composition of the present invention is capable of having excellent properties. Especially, the photosensitive resin composition of the present invention is so excellently useful that it can be used for electronic parts and the like.
    Type: Grant
    Filed: October 24, 2002
    Date of Patent: November 28, 2006
    Assignee: Kaneka Corporation
    Inventors: Koji Okada, Kaoru Takagahara, Toshio Yamanaka
  • Patent number: 7138179
    Abstract: Disclosed is a method for preparing a biodegradable polymer in the form of uniform powder or spherical particles by dispersion polymerization without a grinding step. The method for preparing a biodegradable polyester includes dispersing a monomer in the presence of a catalyst in a dispersion solvent to form a solid or liquid phase for dispersion polymerization and thereby to yield a biodegradable aliphatic polyester in the form of spherical particles or powder, the monomer comprising a mixture of a first compound (e.g., lactide or glycolide) and a second compound being selected from the group consisting of polyhydric alcohols (e.g., glycerin, erythritol, penterythritol or dipentaerythritol) and carprolactone. The present invention readily prepares a biodegradable polymer having a high molecular weight in the form of uniform powder or spherical particles.
    Type: Grant
    Filed: February 20, 2002
    Date of Patent: November 21, 2006
    Assignee: Chemical & Medical Research Co., Ltd.
    Inventors: Kyeong Ah Kim, Byung Kun Son, Yong Gun Jeon
  • Patent number: 7019069
    Abstract: Resinous composition comprising: (A) 100 weight parts of (R2SiO2/2)w(RSiO3/2)x(SiO4/2)y(O1/2R1)z wherein R is selected from the group consisting of monovalent hydrocarbon groups having 1 to 10 carbon atoms, R1 is selected from the group consisting of the hydrogen atom and saturated hydrocarbon groups having from 1 to 6 carbon atoms, w is a number from 0 to 0.2, x is a number from 0.4 to 0.9, y is a number from 0.1 to 0.6, z is a number from 0.1 to 0.5, and (w+x+y)=1; (B) 20 to 150 weight parts of an alcohol-based solvent; (C) 100 to 1000 weight parts of a solvent selected from the group consisting of hydrocarbon-based solvents and polydimethylsiloxanes described by the formula Me3SiO(Me2SiO)nSiMe3, wherein Me is the methyl group and n has a value of 0 or 1; (D) 1 to 100 weight parts of a coupling agent selected from the group consisting of alkoxysilanes and silane coupling agents; (E) 0.1 to 20 weight parts of a condensation catalyst, and (F) 0.
    Type: Grant
    Filed: February 12, 2001
    Date of Patent: March 28, 2006
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Hideki Kobayashi, Mari Tateishi, Toru Masatomi
  • Patent number: 6989419
    Abstract: Ambient temperature curing coating composition comprising a polysiloxane having the formula: wherein each R1 is selected from the group consisting of alkyl, aryl, and alkoxy groups having up to six carbon atoms, reactive glycidoxy groups, and OSi(OR3)3 groups, wherein each R3 independently has the same meaning as R1, each R2 is selected from the group consisting of hydrogen and alkyl and aryl groups having up to six carbon atoms, and wherein n is selected so that the molecular weight of the polysiloxanes is in the range of from 500 to about 2,000, an alkoxysilyl-functional acrylic polymer, and a curing catalyst. The invention further relates to the preparation of an alkoxysilyl-functional acrylic polymer.
    Type: Grant
    Filed: December 12, 2002
    Date of Patent: January 24, 2006
    Assignee: International Coatings Limited
    Inventor: Steve Alister Nixon
  • Patent number: 6953821
    Abstract: An aqueous dispersion obtained by hydrolysis/condensation and radical polymerization of a mixture containing (A) at least one selected from an organosilane, a hydrolyzate of the organosilane and a condensate of the organosilane, and (B) a radical polymerizable vinyl monomer, in an emulsified state.
    Type: Grant
    Filed: February 16, 2001
    Date of Patent: October 11, 2005
    Assignee: JSR Corporation
    Inventors: Kouji Tamori, Kenji Ishizuki, Hiroshi Shiho
  • Patent number: 6939913
    Abstract: This invention provides a wiring-terminal-connecting adhesive comprising a curing agent capable of generating a free radical upon heating, a radically polymerizable substance and silicone particles, and a wiring-terminal-connecting method and a wiring structure which make use of such an adhesive.
    Type: Grant
    Filed: August 25, 2000
    Date of Patent: September 6, 2005
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Motohiro Arifuku, Itsuo Watanabe, Kouji Motomura, Kouji Kobayashi, Yasushi Gotoh, Tohru Fujinawa
  • Patent number: 6881416
    Abstract: Organopolysiloxane gel products having a variety of physical forms and which produce a silky feel when applied to the skin are prepared by reacting an unsaturated organopolysiloxane resin, an Si—H functional organosiloxane crosslinker bearing pendant hydrido functionality, a C4 or higher unsaturated hydrocarbon, and optionally, an unsaturated hydrophile component. Products ranging from viscous liquids, creamy gels, pastes, and soft powders may be obtained. The products are highly useful in formulating cosmetic and pharmaceutical products.
    Type: Grant
    Filed: April 8, 2002
    Date of Patent: April 19, 2005
    Assignee: Wacker Chemical Corporation
    Inventor: Bryan E. Fry
  • Patent number: 6855765
    Abstract: A two-component polyurethane sealant composition is described. The polyurethane sealant of the invention exhibits improved resistance to degradation by heat and hot water. The composition of the invention includes a novel hindered amine antioxidant.
    Type: Grant
    Filed: December 12, 2001
    Date of Patent: February 15, 2005
    Assignee: National University of Singapore
    Inventors: Yit Lin Chew, Suat Hong Goh, Xu Zhou
  • Patent number: 6841616
    Abstract: Halogenated polymers are prepared by a process comprising polymerizing at least one halogen-containing monomer in an aqueous medium containing monomer, radical initiator, and siloxane surfactant. The medium may optionally contain one or more of an antifoulant, a buffering agent and a chain-transfer agent.
    Type: Grant
    Filed: March 28, 2003
    Date of Patent: January 11, 2005
    Assignee: Arkema Inc.
    Inventors: Roice Andrus Wille, Lotfi Hedhli, Mehdi Durali, Sayed Youssef Antoun
  • Patent number: 6841602
    Abstract: A mixture comprising a cross-linkable thermosetting resin precursor and a polyfluoroalkylsiloxane curable to form a composition comprising a cross-linked thermoset resin containing the polyfluoroalkylsiloxane in a gradient concentration through a cross-section thereof.
    Type: Grant
    Filed: October 17, 2001
    Date of Patent: January 11, 2005
    Assignee: RES Development Corporation
    Inventors: Robert E. Sterling, Eugene P. Goldberg
  • Patent number: 6838490
    Abstract: The present invention relates to a novel fully vulcanized powdery silicone rubber, preparation and use thereof. The fully vulcanized powdery silicone rubber is prepared from an latex of organosilicon polymer or copolymer with lower molecular weight via irradiation of high-energy rays. The gel content of the obtained fully vulcanized powdery silicone rubber is at least 60% by weight. The fully vulcanized powdery silicone rubber can be combined with various plastics and is very easy to be dispersed into plastic matrix, and can be used as toughening agent, processing aids or as additives for cosmetics, ink, paint and coatings.
    Type: Grant
    Filed: June 15, 2001
    Date of Patent: January 4, 2005
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry China Petroleum & Chemical Corporation
    Inventors: Xiaohong Zhang, Jinliang Qiao, Genshuan Wei, Jianming Gao, Yiqun Liu, Shijun Zhang, Zhihai Song, Jiuqiang Li, Yicai Zhu
  • Patent number: 6797772
    Abstract: A composition comprises the product obtained by homogeneously blending: (A) 100 parts by weight of a polyorganosiloxane containing at least two alkenyl radicals per molecule, (B) an organohydrogensiloxane containing at least two silicon-bonded hydrogen atoms per molecule in a quantity sufficient to provide from 0.5 to 3 silicon-bonded hydrogen atoms per alkenyl radical of (A), (C) from 50-2000 parts by weight of silver particles pre-treated with an organosilicon compound selected from the group consisting of (i) alkoxy group(s)-containing silanes and (ii) organosiloxanes, (D) a platinum catalyst, (E) up to 20 weight percent based on the weight of (A) of an organosilicon compound containing at least one silicon-bonded alkoxy group per molecule, and (F) from 0.001 to 5 parts by weight per 100 parts by weight of (A) of a cure inhibitor.
    Type: Grant
    Filed: January 18, 2002
    Date of Patent: September 28, 2004
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Kazumi Nakayoshi, Katsutoshi Mine, Rikako Tazawa
  • Patent number: 6784244
    Abstract: The present invention is drawn to an anti-lubricant in the form of a composition that is a viscous fluid, a paste, a gel or even a semi-solid rubber-like material. More specifically, the invention suggests the use as the anti-lubricant of a composition of two or more siloxanes chemically reacted together to form a desirably thick viscous fluid, paste, gel or rubbery solid reaction product, the resultant reaction product being admixed with a more liquid, mobile siloxane that itself has anti-lubricant properties, this more mobile siloxane, which may be either one of the two reacted together or a completely different one, is immobilized—stably dispersed—within the reaction product (and not only provides the required anti-lubricant property but may also be used to modify the final “viscosity” of the composition).
    Type: Grant
    Filed: November 22, 1999
    Date of Patent: August 31, 2004
    Assignee: Ball Burnishing Machine Tools Limited
    Inventor: Geoffrey Robert Linzell
  • Patent number: 6777493
    Abstract: A radial end-modified styrene-conjugated diene block copolymer having a general formula 1. The copolymer is obtained by synthesizing a styrene-conjugated diene block copolymer by way of copolymerization using an organic lithium initiator in the presence of a nonpolar solvent and then coupling the anionic active end of the resulting copolymer with a polyfunctional polysiloxane: (PS-PD)3Si—CH2CH2—[SiO(CH3)2—]nSi(CH3)2R  Formula 1 wherein, PS is polystyrene, PD is polydiene such as polyisoprene or polyisoprene-polybutadiene, R is hydroxy group or -(PD-PS), and n is an integer of 1 to 100. The block copolymer based adhesives have low melt viscosity and excellent adhesive strength.
    Type: Grant
    Filed: October 30, 2002
    Date of Patent: August 17, 2004
    Assignee: Korea Kumho Petro Chemical Co., Ltd.
    Inventors: Young Hoon Ko, Sun Woo Cheen
  • Patent number: 6749771
    Abstract: Compounds for use in the preparation of polymerizable liquid crystalline mixtures, liquid crystalline polymers and optical devices prepared from such mixtures and polymers. The compounds include novel compounds comprising an organosiloxane portion and a portion having a structure that is compatible with a mesogenic molecular architecture.
    Type: Grant
    Filed: January 12, 2001
    Date of Patent: June 15, 2004
    Assignee: Rolic AG
    Inventors: Zoubair Cherkaoui, Carsten Benecke
  • Patent number: 6743868
    Abstract: A method for making thermoplastic elastomeric compositions is disclosed wherein a polyamide, a silicone base, a stabilizer, and optional compatibilizer are first mixed, then a hydrosilation catalyst and subsequently an organohydrido silicon compound are added, and the silicone base is dynamically vulcanized.
    Type: Grant
    Filed: July 18, 2002
    Date of Patent: June 1, 2004
    Assignee: Dow Corning Corporation
    Inventors: Frances Marie Fournier, Richard Leroy Rabe
  • Patent number: 6743854
    Abstract: Ambient temperature curing coating composition comprising a polysiloxane having the formula: wherein each R1 is selected from the group consisting of alkyl, aryl, and alkoxy groups having up to six carbon atoms, reactive glycidoxy groups, and OSi(OR3)3 groups, wherein each R3 independently has the same meaning as R1, each R2 is selected from the group consisting of hydrogen and alkyl and aryl groups having up to six carbon atoms, and wherein n is selected so that the molecular weight of the polysiloxanes is in the range of from 500 to about 2,000, a glycidyl-functional acrylic polymer, and a hardener. The composition can be used as a protective coating for large structures such as ships, bridges, buildings, industrial plants, or oil rigs.
    Type: Grant
    Filed: January 12, 2001
    Date of Patent: June 1, 2004
    Assignee: International Coatings Limited
    Inventors: Keith Yeats, Steve Alister Nixon
  • Patent number: 6737458
    Abstract: The invention relates to silicone compositions which can be crosslinked to give elastomers and which comprises the constituents (A) from 20 to 99% by weight of polyorganosiloxane containing at least two alkenyl groups per molecule and having a viscosity at 25° C. of from 0.1 to 500,000 Pa.s, (B) from 1 to 80% by weight of non-reinforcing filler having a mean particle size of from 0.1 to 200 &mgr;m and a specific surface area of <100 m2/g, (C) a crosslinking component comprising (C1) an organic peroxide, or (C2) an organosilicon compound containing at least two SiH functions per molecule in combination with a hydrosilylation catalyst, and (D) a nitrogen compound which is selected from amino, ammonium and amido compounds and nitrogen-containing organosilicon compounds. The compositions exhibit improved thermal stability and resistance to oil at elevated temperatures.
    Type: Grant
    Filed: January 8, 2003
    Date of Patent: May 18, 2004
    Assignee: Wacker-Chemie GmbH
    Inventors: Christof Woerner, Richard Birneder
  • Patent number: 6649704
    Abstract: A method for preparing a thermoplastic elastomer is disclosed, said method comprising (I) mixing (A) a rheologically stable polyamide resin having a melting point or glass transition temperature of 25° C. to 275° C.
    Type: Grant
    Filed: October 26, 2001
    Date of Patent: November 18, 2003
    Assignee: Dow Corning Corporation
    Inventors: Christopher Michael Brewer, Igor Chorvath, Frances Marie Fournier, Michael Kang-Jen Lee, Dawei Li, Robert Leo Oldinski, Lenin James Petroff, Richard Leroy Rabe, David Joseph Romenesko, Yongjun Lee, Koji Nakanishi
  • Patent number: 6646092
    Abstract: The invention presents a method for manufacturing an amphoteric urethane resin, improving at least one of the performance of cosmetics including this amphoteric urethane resin and the storage stability of the urethane resin.
    Type: Grant
    Filed: June 26, 2002
    Date of Patent: November 11, 2003
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Tomohiro Hashimoto, Takeshi Baba, Seiji Asaoka, Tetsuo Sakurai
  • Publication number: 20030198824
    Abstract: A photocurable composition, including (a) a cationically curable monomer; (b) a radically curable monomer; (c) reactive particles comprising a crosslinked polysiloxane core and a shell of reactive groups on an outer surface of the core, wherein the reactive groups comprise epoxy groups, ethylenically unsaturated groups, or hydroxy groups; (d) a radical photoinitiator; and (e) a cationic photoinitiator. A method of making a 3-D object from such a composition. A 3-D object made by the method.
    Type: Application
    Filed: April 19, 2002
    Publication date: October 23, 2003
    Inventors: John W. Fong, David L. Johnson
  • Patent number: 6608126
    Abstract: Silicone liquid crystals, silicone vesicles, and silicone gels are formed by combining (i) an amine functional silicone or an organic amine compound, (ii) an organic epoxide containing at least two epoxy groups or an epoxy functional silicone containing at least two epoxy groups, and (iii) a fluid such as water, a silicone fluid other than a silicone used in (i) and (ii), and a polar organic compound or nonpolar organic compound other than organic compounds used in (i) and (ii) in which the polar and nonpolar organic compound are present at a concentration to provide a level of solids less than 40 percent by weight based on the weight of (i)-(iii). These silicone liquid crystals, silicone vesicles, and silicone gels are useful in personal care for preparing various skin, hair, and underarm products.
    Type: Grant
    Filed: April 11, 2001
    Date of Patent: August 19, 2003
    Assignee: Dow Corning Corporation
    Inventors: Michael Salvatore Ferritto, Zuchen Lin, William James Schulz, Jr.
  • Patent number: 6573321
    Abstract: An anti-contamination coating composition is obtained by mixing a tetraalkoxysilane condensate having an average condensation degree of 4 to 20 and has an alkyl group having 1 to 2 carbon atoms and an alkyl group having 3 to 10 carbon atoms, or an alkyl group having 1 to 3 carbon atoms and an alkyl group having 4 to 12 carbon atoms, the alkyl group having 3 to 10 carbon atoms or 4 to 12 carbon atoms present in the amount of 5 to 50% by equivalent based on all alkyl groups in the condensate, with a polyurethane resin, an acrylic copolymer resin or a silicone-acrylic copolymer resin in the amount of 1.0 to 40.0 parts by weight in term of SiO2 relative to 100 parts by weight of the polyol compound. The addition of a hydrophilic alkoxysilane having a poly alkylene oxide chain compound is also suitable.
    Type: Grant
    Filed: July 23, 2001
    Date of Patent: June 3, 2003
    Assignee: Sk Kaken Co., Ltd.
    Inventors: Hidehito Karuga, Shigeto Kamimura, Hiroshi Nakai, Hisashi Suzuki, Tadahiko Ikeuchi, Kenichi Ishigaki, Kensuke Kurimoto, Takanori Nakashoya
  • Patent number: 6547563
    Abstract: A method which comprises using silicone rubber as a material for dental tissue conditioner.
    Type: Grant
    Filed: September 17, 1999
    Date of Patent: April 15, 2003
    Assignee: Tokuyama Corporation
    Inventors: Yasuhiro Hosoi, Osamu Iwamoto, Takaaki Imakura
  • Publication number: 20030045626
    Abstract: An aqueous dispersion obtained by hydrolysis/condensation and radical polymerization of a mixture containing (A) at least one selected from an organosilane, a hydrolyzate of the organosilane and a condensate of the organosilane, and (B) a radical polymerizable vinyl monomer, in an emulsified state.
    Type: Application
    Filed: October 16, 2001
    Publication date: March 6, 2003
    Inventors: Kouji Tamori, Kenji Ishizuki, Hiroshi Shiho
  • Patent number: 6528121
    Abstract: An aqueous treatment agent for wiping paper is capable of rendering tissue paper, toilet paper, and other types of wiping paper dry to the touch, highly smooth, nonsticky, and extremely soft while suppressing the slippery or wet feel thereof. The aqueous treatment agent comprises a water dispersion of a silicone rubber powder with an average particle diameter of 0.1 to 500 micrometers, a silicone oil, a surfactant, and water.
    Type: Grant
    Filed: April 6, 2001
    Date of Patent: March 4, 2003
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Isao Ona, Masaru Ozaki, Kazuo Kobayashi, Yoshitsugu Morita
  • Patent number: 6528590
    Abstract: The present invention relates to an aqueous copolymer dispersion consisting essentially of A) an aqueous dispersion of a copolymer having a solids content of from 20 to 65% by weight, said copolymer being composed of various monomers and the weight fractions of the various monomers being chosen within the stated limits such that a synthetic resin composed of these monomers alone would have a glass transition temperature in the range from −50 to 35° C., B) from 0 to 10% by weight, based on the copolymer A, of benzophenone, acetophenone, one or more acetophenone derivatives or benzophenone derivatives without an ethylenically unsaturated group, or a mixture thereof, C) from 0.3 to 10% by weight, based on the copolymer A, of emulsifiers, and D) from 0 to 5% by weight, based on the copolymer A, of protective colloids; to a process for its preparation and to its use.
    Type: Grant
    Filed: October 5, 2001
    Date of Patent: March 4, 2003
    Assignee: Clariant GmbH
    Inventors: Dierk Beyer, Volker Renisch, Rolf Kuropka, Susana Maria De Almeida Carvalho
  • Patent number: 6512072
    Abstract: A formulation for depositing a film on a substrate comprising 5 to79.9 wt. % of an alkylene trialkoxy terminated polysiloxane; 0.01 to 5 wt. % of a catalyst; 20 to 94.99 to wt % of a volatile diluent, and, optionally, 0.01 to 5 wt. % of an alkoxysilane and 0.1 to 25 wt % of a filler. The formulations are especially valuable for forming films to be used in personal care or healthcare applications.
    Type: Grant
    Filed: June 12, 2000
    Date of Patent: January 28, 2003
    Assignee: Dow Corning Corporation
    Inventors: David Clayton Gantner, Keith Alan LaChance, Bartley Dean Maxon, Katherine Lynn Ulman, Debra Jo Nagy Zellner
  • Patent number: 6472076
    Abstract: There is provided an array of alkyl substituted silsesquioxane thin film precursors having a structure wherein alkyl groups are bonded to the silicon atoms of a silsesquioxane cage. The alkyl groups may be the same as, or different than the other alkyl groups. In a first aspect, the present invention provides a composition comprising a vaporized material having the formula [R—SiO1.5]x[H—SiO1.5]y, wherein x+y=n, n is an integer between 2 and 30, x is an integer between 1 and n and y is a whole number between 0 and n. R is a C1 to C100 alkyl group. Also provided are films made from these precursors and objects comprising these films.
    Type: Grant
    Filed: October 18, 1999
    Date of Patent: October 29, 2002
    Assignee: Honeywell International Inc.
    Inventor: Nigel P. Hacker
  • Patent number: 6465552
    Abstract: Thermoplastic elastomers are disclosed which are prepared by; (I) mixing, (A) a thermoplastic resin comprising more than 50 percent by volume of a polyamide or a polyester resin, (B) a silicone base comprising; (B′) 100 parts by weight of a diorganopolysiloxane gum having a plasticity of at least 30 and having an average of at least 2 alkenyl groups per molecule and (B″) 5 to 200 parts by weight of a reinforcing filler, wherein the weight ratio of said silicone base to said polyamide or polyester resin is from 35:65 to 85:15, (C) a compatibilizer, (D) a radical initiator, present in an amount sufficient to cure said diorganopolysiloxane gum, and optionally (E) a stabilizer, (II) dynamically vulcanizing said diorganopolysiloxanes gum, wherein at least one property of the thermoplastic elastomer selected from tensile strength or elongation is at least 25% greater than the respective property for a corresponding simple blend wherein said diorganopolysiloxane is not cured and said thermopla
    Type: Grant
    Filed: May 1, 2001
    Date of Patent: October 15, 2002
    Assignee: Dow Corning Corporation
    Inventors: Igor Chorvath, Frances Marie Fournier, Christopher James Julien, Michael Kang-Jen Lee, Dawei Li, Jun Liao, Robert Leo Oldinski, Richard Leroy Rabe, David Joseph Romenesko, Thomas John Tangney, Yongjun Lee, Koji Nakanishi
  • Patent number: 6461597
    Abstract: A cosmetic consists of a cosmetic raw material in the form of an emulsion of silicone or organic oil containing crosslinked particles mixed with other cosmetic raw materials. Its touch on fingers and skin is good, spreading and feel during use are good, and it can also prevent unruly hair, stray hair, and tangling of hair, so hair can easily be arranged. It imparts a fresh, dry feeling without any stickiness. The cosmetic raw material consists of the silicone or organic oil emulsion containing crosslinked particles with a mean particle diameter of 0.05 to 100 &mgr;m. Crosslinking is obtained by an hydrosilylation of liquid crosslinkable compositions consisting of (A) organic compounds with at least two aliphatic unsaturated bonds per molecule, (B) silicon containing organic compounds with at least two hydrogen atoms bonded to silicon atoms in each molecule, and (C) hydrosilylation reaction catalysts.
    Type: Grant
    Filed: November 7, 2000
    Date of Patent: October 8, 2002
    Assignee: Dow Corning Toray Silicone Co., LTD.
    Inventors: Yoshitsugu Morita, Kazuo Kobayashi, Ozaki Masaru
  • Patent number: 6437042
    Abstract: A suspension containing crosslinked silicone particles with a lower mean particle diameter and a better dispersion in certain organic resins is prepared by emulsifying a condensation crosslinkable silicone composition containing (A) an organopolysiloxane having at least two silanol groups per molecule and (B) a crosslinker, but no (C) condensation catalyst, in water using a surfactant. A tin (II) salt of an organic acid with no more than ten carbon atoms is then emulsified in water with a surfactant, and added as the component (C) to the emulsion of condensation crosslinkable silicone composition. This crosslinks the emulsion of condensation crosslinkable silicone composition.
    Type: Grant
    Filed: January 3, 2001
    Date of Patent: August 20, 2002
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Kazuo Kobayashi, Yoshitsugu Morita, Ken Tanaka
  • Publication number: 20020074086
    Abstract: To prepare an adhesive which has excellent heat resistance, suppresses the formation of bubbles during curing and is free from such a defect as opacity caused by the bubbles.
    Type: Application
    Filed: September 27, 2001
    Publication date: June 20, 2002
    Inventors: Koichiro Nakamura, Masahiro Hori, Hiroaki Yamamoto
  • Publication number: 20020072564
    Abstract: The invention herein provides a silicone polymer emulsion comprising: a) a silicone polymer; and b) a surfactant; and a liquid continuous phase comprising a diol, wherein the diol comprises from about 25 to about 100% by weight of the continuous phase. Further provided is a method of making a condensation polymer/ silicone polymer blend comprising the steps of: a) preparing a silicone polymer emulsion comprising a silicone polymer in a liquid continuous phase; b) introducing the silicone polymer emulsion into a condensation polymerization reaction medium prior to or during the condensation polymerization reaction, wherein the condensation polymerization reaction medium comprises (1) a diacid, di-isocyanate, dialkyl carbonate, diaryl carbonate, dihalo carbonate or a mixture thereof, wherein the continuous phase, the condensation polymerization reaction medium or both comprises a diol component; and c) polymerizing the diol and component b(1) thereby forming a condensation polymer/silicone polymer blend.
    Type: Application
    Filed: November 29, 2001
    Publication date: June 13, 2002
    Applicant: Eastman Chemical Company
    Inventors: David Logan Murray, Allan Scott Jones, Wesley R. Hale
  • Patent number: 6403105
    Abstract: A condensation curable coating composition comprises the following and any reaction product thereof: (A) a room temperature vulcanizable polyorganosiloxane composition; and (B) a marine foul release-enhancing proportion of at least one organic compatible silicone fluid free from silanol groups and being capable of blooming to the surface of a cured product of component A.
    Type: Grant
    Filed: October 25, 2000
    Date of Patent: June 11, 2002
    Assignee: General Electric Company
    Inventor: Judith Stein
  • Patent number: 6403711
    Abstract: A high elongation, low 100% modulus composition comprises a copolymer dispersed in a continuous phase polysiloxane. The copolymer is made from high amounts of at least a monomer which is capable of forming a low Tg polymer and relatively low amounts of at least a monomer which is capable of forming a high Tg polymer. The monomer forming the low Tg polymer can be an alkyl acrylate whereas the monomers forming the high Tg polymer can be a vinyl ester, an acrylonitrile or derivatives thereof, a vinyl substituted aromatic such as styrene, an alkyl methacrylate, and the like. The composition has good adhesion to substrates as well as good viscosity aging, and can be utilized in caulks or sealants.
    Type: Grant
    Filed: January 10, 2000
    Date of Patent: June 11, 2002
    Assignee: Noveon IP Holdings Corp.
    Inventors: Wei-Yeih Yang, Melvin Dale Beers, Ta-Min Feng
  • Patent number: 6399700
    Abstract: Synthetic comb copolymers which elicit controlled cellular response, methods of applying these polymers to various surfaces, and methods of using the polymers for modifying biomaterial surfaces, in tissue engineering applications and as drug delivery devices are provided. The comb copolymers are comprised of hydrophobic polymer backbones and hydrophilic, non-cell binding side chains which can be end-capped with cell-signaling ligands that guide cellular response. By mixing non-cell binding combs with ligand-bearing combs, the surface concentration and spatial distribution of one or more types of ligands, including adhesion peptides and growth factors, can be tuned on a surface to achieve desired cellular response. In one embodiment, the combs are used as stabilizing agents for dispersion polymerization of latexes. The comb-stabilized latexes can be applied to substrates by standard coating operations to create a bioregulating surface, or used as drug delivery agents.
    Type: Grant
    Filed: March 26, 2001
    Date of Patent: June 4, 2002
    Assignee: Massachusetts Institute of Technology
    Inventors: Anne M. Mayes, Linda G. Griffith, Darrell J. Irvine, Pallab Banerjee, Terry D. Johnson
  • Publication number: 20020061365
    Abstract: The invention relates to aqueous emulsions, a process for the preparation and the use thereof.
    Type: Application
    Filed: July 9, 1997
    Publication date: May 23, 2002
    Inventors: WOLFGANG GRAPE, RUDI STRACKE, FRANK ZILLMER, ARMAND DE MONTIGNY
  • Patent number: 6387520
    Abstract: A solvent-free liquid silicone rubber composition comprising (A) an organopolysiloxane containing at least two alkenyl groups, (B) an organohydrogenpolysiloxane having at least two hydrogen atoms each attached to a silicon atom, (C) wet silica having a BET specific surface area of 150-250 m2/g, a mean particle size of 0.01-20 &mgr;m, and a sodium ion content of up to 0.35 wt % Na2O, (D) an adhesive agent, and (E) a platinum group catalyst is useful for coating onto air bag base fabric to form a thin film having good infiltration, strong adhesion and minimized surface tack.
    Type: Grant
    Filed: August 24, 2000
    Date of Patent: May 14, 2002
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Hironao Fujiki, Yoshifumi Inoue, Yoshifumi Harada, Takeshi Miyao, Masayuki Ikeno
  • Publication number: 20020052442
    Abstract: Process for preparing non-aqueous dispersions, wherein a liquid prepolymer is emulsified in a non-aqueous liquid, the droplet size of the emulsion is adjusted to 0.1 to 30 &mgr;m and the droplet size distribution U90 is adjusted to less than 2 by means of a jet disperser, and the droplets are cured by a chemical reaction.
    Type: Application
    Filed: April 30, 1999
    Publication date: May 2, 2002
    Inventors: ECKHARD WENDT, ROBERT BLOODWORTH, MARKUS MECHTEL, BERND KLINKSIEK, OLAF HALLE
  • Patent number: 6372860
    Abstract: In a silicone rubber composition comprising an organopolysiloxane as a base polymer, 0.1-50 parts by weight of a modified silicone fluid having a melting point of up to 100° C. and a refractive index difference of 0.01-0.05 from the base polymer is blended per 100 parts by weight of the composition. The composition is cast and cured to form a mother mold which maintains parting properties over a long term.
    Type: Grant
    Filed: April 5, 2000
    Date of Patent: April 16, 2002
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Kei Miyoshi, Kouichi Tanaka
  • Patent number: 6365670
    Abstract: Organopolysiloxane gels containing gel-bound hydrophillic groups are prepared by reacting a hydrosilylatable unsaturated organopolysiloxane resin, a crosslinker bearing Si—H bound hydrogen, and a hydrosilylatable unsaturated hydrophile, in the presence of an effective amount of a hydrosilylation catalyst, at least a portion of the reaction taking place in the presence of at least 60 weight percent of an oleaginous composition containing at least 50 weight percent low viscosity organopolysiloxane. When sheared, the crosslinked organosiloxane compositions form a stable, preferably incompatible gel which may be used in turn to form a stable emulsion with large amounts of ordinarily incompatible hydrophillic liquids. The emulsions thus formed are suitable for use in a wide variety of cosmetic products.
    Type: Grant
    Filed: March 10, 2000
    Date of Patent: April 2, 2002
    Assignee: Wacker Silicones Corporation
    Inventor: Bryan E. Fry
  • Patent number: 6362288
    Abstract: A method for preparing a thermoplastic elastomer is disclosed, said method comprising (I) mixing (A) a rheologically stable polyamide resin having a melting point or glass transition temperature of 25° C. to 275° C.
    Type: Grant
    Filed: July 26, 2000
    Date of Patent: March 26, 2002
    Assignee: Dow Corning Corporation
    Inventors: Christopher Michael Brewer, Igor Chorvath, Michael K. Lee, Yongjun Lee, Dawei Li, Koji Nakanishi, Robert Leo Oldinski, Lenin James Petroff, Richard L. Rabe, David Joseph Romenesko
  • Publication number: 20020035200
    Abstract: The invention provides a method of making an amide-type polymer/silicone polymer blend comprising the steps of preparing a silicone polymer emulsion comprising a silicone polymer dispersed in a liquid continuous phase; introducing the silicone polymer emulsion into an amide-type polymerization reaction medium prior to or during the reaction, wherein the reaction medium comprises 1) a diacid component and a diamine component, an oligomer of a diacid and a diamine component, or a mixture thereof, and polymerizing the components of b)1, thereby providing an amide-type polymer/silicone polymer blend. A amide-type polymer/silicone polymer blends are also provided.
    Type: Application
    Filed: September 20, 2001
    Publication date: March 21, 2002
    Applicant: Eastman Chemical Company
    Inventors: Allan Scott Jones, William R. Darnell, David Logan Murray, Wesley R. Hale
  • Patent number: 6355724
    Abstract: The present invention relates to improved and novel silicone gel compositions comprising at least one low molecular weight volatile organosilicone fluid and at least one elastomer-like silicone composition as matrix. The improved silicone gels of the invention can readily and easily be spread on the skin and possess a desirable dull appearance during application. The silicone films which result after the gel has remained on the skin about 15 to 20 minutes after application, are smooth, slippery, non-tacky and non-shiny with a low detectable residue thereof. Silicone gels applied in alkylsiloxanes exhibit significant improvements over those applied in permethylcyclosiloxanes or in other known media or by known methods.
    Type: Grant
    Filed: December 6, 2000
    Date of Patent: March 12, 2002
    Assignee: Clariant LSM (Florida), Inc.
    Inventors: Gary E. LeGrow, W. Leonard Terry
  • Patent number: 6352780
    Abstract: The present invention relates to a polymeric coating composition for application onto glass substrates for anti-reflective properties. The coating is provided via chemical grafting that involves the use of monomers and/or prepolymers, catalyst, and graft initiator and when applied onto the surface of the glass substrate forms a polymeric film chemically bonded to the glass with excellent adhesion. This coating can reduce the reflectance of the coated glass surface to as close to zero as possible, thus maximizing transmittance and providing resistance to abrasion, water/chemical attack, and UV degradation.
    Type: Grant
    Filed: February 22, 2000
    Date of Patent: March 5, 2002
    Assignee: AFG Industries, Inc.
    Inventors: Mohan L. Sanduja, Carl Horowitz, Abraham Thomas, Paul Thottathil
  • Patent number: 6353052
    Abstract: The invention provides a method of making an amide-type polymer/silicone polymer blend comprising the steps of preparing a silicone polymer emulsion comprising a silicone polymer dispersed in a liquid continuous phase; introducing the silicone polymer emulsion into an amide-type polymerization reaction medium prior to or during the reaction, wherein the reaction medium comprises 1) a diacid component and a diamine component, an oligomer of a diacid and a diamine component, or a mixture thereof; and polymerizing the components of b)1, thereby providing an amide-type polymer/silicone polymer blend. A amide-type polymer/silicone polymer blends are also provided.
    Type: Grant
    Filed: March 2, 2000
    Date of Patent: March 5, 2002
    Assignee: Eastman Chemical Company
    Inventors: Allan Scott Jones, William R. Darnell, David Logan Murray, Wesley R. Hale
  • Patent number: 6348557
    Abstract: The invention relates to crosslinkable materials based on organopolysiloxanes. Said materials are characterized in that in addition to organopolysiloxanes they contain at least one low-molecular organosilicon compound with 2 to 17 silicon atoms comprising units of the formula (I) R1aR2b(OR3)cSiO4−(a+b+c)/2, R1, R2, R3, a, b and c having the meaning given in claim 1 provided that low-molecular organosilicon compounds comprising units of the formula (I) where b is 0 have at least one unit of the formula (I) in which a is 0 or 1, and at least one unit of the formula (I) in which a is 3.
    Type: Grant
    Filed: December 23, 1998
    Date of Patent: February 19, 2002
    Assignee: Wacker-Chemie GmbH
    Inventors: Herbert Barthel, August Altenbuchner, Johann Schuster, Mario Heinemann, Lutz Eismann, Otto Rothenaicher
  • Publication number: 20020016409
    Abstract: In one aspect, the invention provides a method of making a nylon 6/silicone polymer blend comprising the steps of preparing a silicone polymer emulsion comprising a silicone polymer dispersed in a liquid continuous phase; introducing the silicone polymer emulsion into a nylon 6 ring opening reaction either prior to or during the nylon 6 ring opening reaction medium wherein the reaction medium comprises caprolactam; and opening the ring and reacting the caprolactam, thereby providing a nylon 6/silicone polymer emulsion blend. Nylon 6/silicone polymer blends are also provided by the invention herein.
    Type: Application
    Filed: October 3, 2001
    Publication date: February 7, 2002
    Applicant: Eastman Chemical Company
    Inventors: Wesley R. Hale, David Logan Murray, Allan Scott Jones
  • Patent number: RE38928
    Abstract: A biaxially stretched polyester film for forming a container, characterized by being formed of a polyester substantially consisting of an ethylene terephthalate unit and an ethylene naphthalate unit, the refractive index in the direction of thickness of the film being 1.5 or greater. This film is not only excellent in the formability during formation into cans or the like, but has excellent properties in taste property, particularly, the taste property after the retorting, and may be suitably used for containers produced by forming process and, particularly, for metallic cans.
    Type: Grant
    Filed: May 15, 1997
    Date of Patent: January 3, 2006
    Assignee: Toray Industries, Inc.
    Inventors: Masahiro Kimura, Kohzo Takahashi, Hiroji Kojima, Koichi Abe