Sulfate, Sulfonate Ester, Sulfonic Acid, Or Salt Thereof Patents (Class 524/745)
  • Patent number: 6013708
    Abstract: Compositions of precipitated cationic polymers containing mixtures of certain salts as well as processes for making and using the same are disclosed.
    Type: Grant
    Filed: October 3, 1996
    Date of Patent: January 11, 2000
    Assignee: Cytec Technology Corp.
    Inventors: Joseph J. Mallon, Raymond S. Farinato, Louis Rosati, John J. Freeman, Jr.
  • Patent number: 5994455
    Abstract: A process for the preparation of polyoxymethylene copolymers, wherein 1,3,5-trioxane is polymerized with generally known comonomers in the presence of a strong protonic acid initiator and in the presence of a formaldehyde dialkyl acetal, and wherein the initiator is dissolved in the formaldehyde dialkyl acetal before admixing to the trioxane and the comonomers.
    Type: Grant
    Filed: September 8, 1998
    Date of Patent: November 30, 1999
    Assignee: Ticonna GmbH
    Inventors: Karl-Friedrich Muck, Horst Roschert, Robert M. Gronner, Satyajit Verma, Michael G. Yearwood
  • Patent number: 5990226
    Abstract: There is provided an aqueous resin composition which does not cause coagulation, can be cured at low temperature, and, by this curing, forms a coating superior in mechanical strength, water resistance, solvent resistance and adhesion to various substrates. The aqueous resin composition of this invention comprises an oxazoline group-containing polymer (A), a carboxyl group-containing polymer (B), and an acidic compound-amine salt catalyst (C). The curing is carried out by a reaction between the oxazoline group-containing polymer (A) and the carboxyl group-containing polymer (B) in the presence of the acidic compound-amine salt catalyst (C).
    Type: Grant
    Filed: January 21, 1993
    Date of Patent: November 23, 1999
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Yoshihiro Arita, Kiyoshi Kawamura, Kenta Kanaida, Satoshi Yamada
  • Patent number: 5986046
    Abstract: An oxidant solution for synthesizing a heat-resistant electroconductive polymer, composed of a solution of a non-protonic organic solvent and an oxidant of the organic compound iron salt expressed by the following formula:Fe.sup.3+O [(X)L--(M)m--(Y.sup.-)n]pH.sup.
    Type: Grant
    Filed: March 9, 1998
    Date of Patent: November 16, 1999
    Assignee: NEC Corporation
    Inventors: Toshihiko Nishiyama, Takashi Fukaumi, Atushi Kobayashi, Masashi Ohi, Yoshihiko Saiki, Kazuaki Fukushima, Tomitaro Hara, Shinji Takeoka, Kimihisa Yamamoto, Eishun Tuchida
  • Patent number: 5973029
    Abstract: Corrosion-resistant latex coatings comprising a diphenyl sulfonate surfactant and a salt of 2-acrylamido-2-methylpropane sulfonic acid.
    Type: Grant
    Filed: October 12, 1993
    Date of Patent: October 26, 1999
    Assignee: The Sherwin-Williams Company
    Inventors: Shui-Jen R. Hsu, Chia-Tien Chen
  • Patent number: 5973061
    Abstract: Aqueous silicone dispersions crosslinkable into elastomeric state by elimination of water therefrom, well adapted for the production of elastomer seals, e.g., for the building industry, include:(A) 100 parts by weight of an oil-in-water emulsion of an .alpha.,.omega.-(dihydroxy)polydiorganosiloxane stabilized with at least one anionic or nonionic surface-active agent, or mixture thereof;(B) 1 to 100 parts by weight of an hydroxylated silicone resin containing, per molecule, at least two different recurring structural units selected from among those of the formulae: R.sub.3 SiO.sub.0.5, R.sub.2 SiO, RSiO.sub.1.5 and SiO.sub.2, wherein the radicals R, which may be identical or different, are vinyl, phenyl or 3,3,3-trifluoropropyl radicals, or linear or branched chain alkyl radicals containing from 1 to 6 carbon atoms, said resin having a hydroxyl group weight content of from 0.1% to 10%;(C) 0 to 250 parts by weight of a nonsiliceous inorganic filler;(D) 0.
    Type: Grant
    Filed: February 28, 1991
    Date of Patent: October 26, 1999
    Assignee: Rhone-Poulenc Chimie
    Inventors: Michel Feder, Jean Ulrich
  • Patent number: 5962623
    Abstract: A continuous process for the preparation of polyacetal copolymers from 1,3,5-trioxane and the comonomers known for this purpose using strong protic acids as an initiator, in which the initiator is added in an amount of 0.01 to 0.6 ppm, based on the total amount of monomers, in finely divided form to the monomer mixture, after the polymerization step the crude polymer is transferred from the polymerization reactor to a mixing unit without further intermediate steps, excess monomer is removed from the crude polymer in the mixing unit or between polymerization reactor and mixing unit by applying reduced pressure and, if desired, generally customary stabilizers, assistants, fillers, reinforcing materials and/or colorants are incorporated into the polymer in the mixing unit.
    Type: Grant
    Filed: September 8, 1998
    Date of Patent: October 5, 1999
    Assignee: Ticona GmbH
    Inventors: Peter Eckardt, Michael Hoffmockel, Karl-Friedrich Muck, Gerhard Reuschel, Satyajit Verma, Michael G. Yearwood
  • Patent number: 5952436
    Abstract: A general approach to making water-resistant polyetherester resins and thermosets is disclosed. In one aspect, an unsaturated polyetherester resin prepared by inserting a carboxylic acid derivative into a polyether is co-cured with a vinyl monomer and a di- or polyisocyanate to give a water-resistant, thermoset that has excellent dimensional stability, flexibility, and strength properties. Processes for making low-viscosity resins that give thermosets with good water resistance are also described. In one process, an unsaturated polyetherester resin intermediate reacts with a mono-functional isocyanate or fatty alcohol to produce an easy-to-formulate, low-viscosity, low-molecular-weight capped resin.
    Type: Grant
    Filed: January 13, 1998
    Date of Patent: September 14, 1999
    Assignee: Arco Chemical Technology, L.P.
    Inventors: Gangfeng Cai, Jeffrey A. Klang, Lau S. Yang
  • Patent number: 5945478
    Abstract: Extrusion rheology of thermoplastic polymer as manifested by surface smoothness is improved by incorporating foam cell nucleating agents into the polymer and extruding the polymer under laminar flow to form unfoamed extrudate.
    Type: Grant
    Filed: June 25, 1997
    Date of Patent: August 31, 1999
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Marlin Dwight Buckmaster, Stuart Karl Randa
  • Patent number: 5936031
    Abstract: A process for preparing polyalkylsilsesquioxane particles comprising:a) dissolving a surfactant in an alkyltrialkoxysilane or its partially hydrolyzed condensate;b) combining the mixture with water; andc) adding a basic material to the mixture to obtain the polyalkyisilsesquioxane particles.
    Type: Grant
    Filed: January 30, 1998
    Date of Patent: August 10, 1999
    Assignee: Eastman Kodak Company
    Inventors: Paul E. Woodgate, Peter J. Makarewicz, Todd C. Zion
  • Patent number: 5905136
    Abstract: The subject is a class of catalyzers to be used in the stage of polycondensation of the synthesis of poly(ethylene terephtalate), consisting of metal and non-metal derivatives in composition with sulfonic acids mixed with titanium compounds so that the final polymer contains a sulfur quantity of 5-60 ppm and a quantity of metals between 2 and 100 ppm.
    Type: Grant
    Filed: June 19, 1997
    Date of Patent: May 18, 1999
    Assignees: Montefibre S.p.A., Inca International S.p.A.
    Inventors: Riccardo Po, Luigi Pelosini
  • Patent number: 5891953
    Abstract: A low-sediment, low-tar, chlorine-free thermal process for preparing oil-soluble polyalkenyl derivatives of monounsaturated C.sub.3 -C.sub.10 monocarboxylic acid producing compounds and monounsaturated C.sub.4 -C.sub.10 dicarboxylic acid producing compounds is disclosed. The process involves reacting the mono- or dicarboxylic acid producing compound with a polyalkene at high temperature and under high inert gas partial pressure in the presence of a sediment-inhibiting amount of hydrocarbyl substituted sulfonic acid. The polyalkenyl derivatives are useful per se as additives in lubricating oils, functional fluids, and fuels and are also useful as intermediates in the preparation of other products (e.g., succinimides) useful as additives in lubricating oils, functional fluids, and fuels.
    Type: Grant
    Filed: January 17, 1997
    Date of Patent: April 6, 1999
    Assignee: Exxon Chemical Patents Inc
    Inventors: Jeremy R. Spencer, Robert W. Russell, Ronald P. Wangner
  • Patent number: 5877252
    Abstract: This invention describes water-based microsphere adhesive formulations to be used in the sheet-to-sheet coating process. These adhesives have proven to have excellent wet-out of a difficult, high-energy surface, good shear stability to allow die-coating or gravure-coating of the adhesive onto an intermediate carrier belt, good elasticity to allow the wet adhesive to cling to the intermediate belt until it is dried (or partially dried), good integrity to allow complete transfer from the intermediate carrier belt onto the final substrate, and repositionable properties in a final product composition.
    Type: Grant
    Filed: May 19, 1997
    Date of Patent: March 2, 1999
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Kim K. Tsujimoto, Mark S. Vogel, Eric Francis Yves Baertich
  • Patent number: 5856401
    Abstract: A method wherein polyesters are prepared under mild conditions by directly condensing hydroxycarboxylic acids or mixtures of polyfunctional alcohols and carboxylic acids in hydrophobic media using heterogeneous catalysts that can form a hydrophilic phase. The systems are inverse emulsions, inverse microemulsions and solid-in-liquid dispersions.
    Type: Grant
    Filed: January 27, 1998
    Date of Patent: January 5, 1999
    Assignee: Saam Associates
    Inventor: John C. Saam
  • Patent number: 5849864
    Abstract: The present invention is addressed a formulation curable in the presence of an amine and containing one or more of a polyol or polymercapto resin, a polyisocyanate cross-linking agent, optionally a organic vehicle, and a tin catalyst complex. The present invention comprises the catalyst complex being formed from a metal catalyst and a complexing sulfonic acid in an equivalent ratio of complexing sulfonic acid to metal catalyst of greater than 2:1. Such curable formulation may be compounded into a coating, an adhesive (including a structural adhesive), a caulk, a foundry binder, or the like. Besides having excellent shelf life, long periods of open time are experienced with the novel catalyzed formulation. However, upon exposure to an amine, the catalyst complex becomes activated and then is effective to catalyze the NCO--OH reaction or the NCO--SH reaction to effect cure of the formulation.
    Type: Grant
    Filed: August 1, 1996
    Date of Patent: December 15, 1998
    Assignee: Ashland Chemical Company
    Inventors: Gary M. Carlson, Laurence G. Dammann
  • Patent number: 5834078
    Abstract: Poly(hydroxyaminoether) ammonium salts are prepared by contacting a poly(hydroxy amino ether) with a protonic acid or an alkyl halide in an amount and under reaction conditions sufficient to form a poly(hydroxy amino ether) ammonium salt having an oxygen transmission rate of less than about 0.5 cm.sup.3 -mil/100 in.sup.2 -atm(O.sub.2)-day.
    Type: Grant
    Filed: August 14, 1997
    Date of Patent: November 10, 1998
    Assignee: The Dow Chemical Company
    Inventors: Michael B. Cavitt, Jerry E. White, John M. Beckerdite, H. Craig Silvis
  • Patent number: 5780558
    Abstract: A low-cost way to modulate the reactivity and acid number of polyetherester thermoset resins is disclosed. "Beginning" and "end" methods for making dicyclopentadiene (DCPD)-modified polyetherester resins are described. The "beginning" method comprises first heating a polyether, DCPD, a diol, an insertion catalyst, and a carboxylic acid derivative to produce a mixture that contains the polyether and a DCPD-diol diester adduct. Increasing the temperature causes insertion of the DCPD-diol diester into the polyether to give a DCPD polyetherester resin. The "end" method reacts a polyetherester resin made by insertion with DCPD to give a DCPD polyetherester resin. Compared with DCPD polyester resins, those of the invention give more flexible thermosets. Compared with unmodified polyetherester resins, the DCPD polyetherester resins offer formulators more control over curing, which eliminates mold distortion and shrinking or cracking of thermoset parts.
    Type: Grant
    Filed: September 25, 1997
    Date of Patent: July 14, 1998
    Assignee: Arco Chemical Technology, L.P.
    Inventors: Jeffrey A. Klang, Lau S. Yang
  • Patent number: 5777025
    Abstract: A low-sediment, low-tar, chlorine-free thermal process for preparing oil-soluble polyalkenyl derivatives of monounsaturated C.sub.4 -C.sub.10 dicarboxylic acid producing compounds is disclosed. The process involves reacting the dicarboxylic acid producing compound with a polyalkene at high temperature and under high inert gas partial pressure in the presence of a sediment-inhibiting amount of hydrocarbyl substituted sulfonic acid. The polyalkenyl derivatives are useful per se as additives in lubricating oils, functional fluids, and fuels and are also useful as intermediates in the preparation of other products (e.g., succinimides) useful as additives in lubricating oils, functional fluids, and fuels.
    Type: Grant
    Filed: February 9, 1996
    Date of Patent: July 7, 1998
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Jeremy R. Spencer, Robert W. Russell, Ronald P. Wangner
  • Patent number: 5760113
    Abstract: A floor polish composition comprising an aqueous emulsion which comprises as a copolymer having an average particle size of from 0.05 to 0.10 .mu.m and having a glass transition temperature of from 30.degree. to 50.degree. C. which is obtainable by polymerization of (A) to (C) described below in the presence of an alkylbenzenesulfonate containing an alkyl group having 10 to 16 carbon atoms in an amount of 0.5 to 2.5 parts by weight per 100 parts by weight of the total amount of (A) to (C):(A): 30 to 50% by weight of an aromatic vinyl compound,(B): 30 to 60% by weight of a (meth)acrylate, and(C): 10 to 20 % by weight of an .alpha., .beta.-ethylenically unsaturated carboxylic acid.
    Type: Grant
    Filed: September 30, 1996
    Date of Patent: June 2, 1998
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Tatsuo Mitsutake, Yuuzi Yoshii
  • Patent number: 5753783
    Abstract: Disclosed is a process which comprises reacting a polymer of the general formula ##STR1## wherein x is an integer of 0 or 1, A is one of several specified groups, such as ##STR2## B is one of several specified groups, such as ##STR3## or mixtures thereof, and n is an integer representing the number of repeating monomer units, with an acetyl halide and dimethoxymethane in the presence of a halogen-containing Lewis acid catalyst and methanol, thereby forming a haloalkylated polymer. In a specific embodiment, the haloalkylated polymer is then reacted further to replace at least some of the haloalkyl groups with photosensitivity-imparting groups. Also disclosed is a process for preparing a thermal ink jet printhead with the aforementioned polymer.
    Type: Grant
    Filed: August 28, 1997
    Date of Patent: May 19, 1998
    Assignee: Xerox Corporation
    Inventors: Timothy J. Fuller, Ram S. Narang, Thomas W. Smith, David J. Luca, Raymond K. Crandall
  • Patent number: 5719258
    Abstract: A copolymer of carbon monoxide with an acetylenically unsaturated compound and optionally an olefinically unsaturated compound, on the understanding that the copolymer is not a copolymer of carbon monoxide and exclusively acetylene which contains less than 15%-mole of monomer units originating in carbon monoxide and which is obtainable by copolymerizing the monomers in the presence of a catalyst of titanium tetrabutoxide and triethylaluminium; and a process for copolymerizing an acetylenically unsaturated compound and optionally an olefinically unsaturated compound with carbon monoxide, wherein the monomers are contacted with a catalyst composition based on:(a) a source of palladium, and(b) an anionic phosphorus ligand of the general formula R.sup.1 R.sup.2 P-R.sup.3 -X, wherein R.sup.1 and R.sup.2 independently represent optionally polar substituted hydrocarbyl groups, R.sup.3 is a bivalent bridging group having 2 carbon atoms in the bridge and X is an anionic group.
    Type: Grant
    Filed: March 11, 1996
    Date of Patent: February 17, 1998
    Assignee: Shell Oil Company
    Inventors: Eit Drent, Dennis Humphrey Louis Pello
  • Patent number: 5717057
    Abstract: A method for manufacturing polycarbonate in which an aromatic dihydroxy compound and a carbonic acid diester can be effectively subjected to melt polycondensation using a small amount of a catalyst, making it possible to manufacture polycarbonate having outstanding color matching, outstanding thermal stability, color-matching stability, etc., during molding, and outstanding water resistance is characterized in that when an aromatic dihydroxy compound and a carbonic acid diester are subjected to melt polycondensation in the presence of a catalyst, the catalyst is dissolved or dispersed as a catalyst solution, this catalyst solution is added to the melt polycondensation reaction system, and the aromatic dihydroxy compound and carbonic acid diester are subjected to melt polycondensation.
    Type: Grant
    Filed: December 28, 1995
    Date of Patent: February 10, 1998
    Assignee: General Electric Company
    Inventors: Takeshi Sakashita, Tomoaki Shimoda, Takashi Nagai
  • Patent number: 5696225
    Abstract: A process for making high-performance polyetherester resins and thermosets is disclosed. A polyether polyol reacts with a dicarboxylic acid or anhydride in the presence of an insertion catalyst to produce an acid-terminated polyetherester resin. Reaction of this resin reacts with a primary diol or a diepoxy compound gives a chain-extended polyetherester resin that can be cured with a vinyl monomer to produce a high-performance polyetherester thermoset. Properties of the thermosets rival or exceed those of more expensive high-performance iso and vinyl ester resins.
    Type: Grant
    Filed: February 28, 1996
    Date of Patent: December 9, 1997
    Assignee: ARCO Chemical Technology, L.P.
    Inventors: Gangfeng Cai, Jeffrey A. Klang, Lau S. Yang
  • Patent number: 5688457
    Abstract: Extrusion theology of thermoplastic polymer as manifested by surface smoothness is improved by incorporating foam cell nucleating agents into the polymer and extruding the polymer under laminar flow to form unfoamed extrudate.
    Type: Grant
    Filed: April 10, 1996
    Date of Patent: November 18, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Marlin Dwight Buckmaster, Donald Leonidas Henry, Stuart Karl Randa
  • Patent number: 5688902
    Abstract: Process for the preparation of polyimides or of their polypeptide hydrolysates which are at least 80% biodegradable, by thermal polycondensation of at least one amino acid, optionally followed by hydrolysis, the thermal polycondensation step being carried out in the presence of at least one "acid catalyst" chosen fromsulphuric, nitric, phosphorous, sulphurous, hydrofluoric, silicic and sulphonic acids, organic sulphonic acids containing less than 50 carbon atoms, amino acids bearing a non-carboxyl strong acid function, organic phosphonic acids, organic carboxylic acids having a pK.sub.
    Type: Grant
    Filed: June 27, 1996
    Date of Patent: November 18, 1997
    Assignee: Rhone-Poulenc Chimie
    Inventors: Jean-Marie Bernard, Jean-Luc LePage, Arnaud Ponce, Florence Tournilhac
  • Patent number: 5633305
    Abstract: Coating compositions based on waxes, wax-like compounds, drying oils or alkyd resins are improved in their running behavior by the addition of additives which gel at elevated temperature. Other positive properties of the coating compositions, such as for example wetting, penetration (creepage), sprayability, are not adversely affected.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: May 27, 1997
    Assignee: Teroson GmbH
    Inventors: Karl Wesch, Dieter Stamm, Dirk Reitenbach, Winfried Schwittay
  • Patent number: 5629376
    Abstract: Novel polyacrylic acid resins are prepared by polymerizing a monomer selected from the group consisting of H.sub.2 C.dbd.CHCO.sub.2 X, H.sub.2 C.dbd.CR.sup.1 CO.sub.2 X, HR.sup.2 C.dbd.CHCO.sub.2 X, HR.sup.2 C.dbd.CR.sup.1 CO.sub.2 X, HR.sup.2 C.dbd.CHCOX, H.sub.2 C.dbd.CHCOX, H.sub.2 C.dbd.CR.sup.1 COX, HR.sup.2 C.dbd.CR.sup.1 COX, H.sub.2 C.dbd.CHCSO.sub.v X, HR.sup.2 C.dbd.CHCSO.sub.v X, HR.sup.2 C.dbd.CR.sup.1 CSO.sub.v X, H.sub.2 C.dbd.CR.sup.1 CSO.sub.v X, H.sub.2 C.dbd.CHCON(R.sup.3).sub.2, HR.sup.2 C.dbd.CHCON(R.sup.3).sub.2, H.sub.2 C.dbd.CR.sup.1 CON(R.sup.3).sub.2, OR HR.sup.2 C.dbd.CR.sup.1 CON(R.sup.3).sub.2, or a combination thereof, in the presence of at least 10% by weight of reaction components of an aromatic sulfonic acid or its salt, wherein:R.sup.1 and R.sup.2 are independently a substituted or unsubstituted alkyl, alkenyl, aromatic, aralkyl or alkaryl moiety of C.sub.1 to C.sub.20 ;R.sup.
    Type: Grant
    Filed: May 17, 1993
    Date of Patent: May 13, 1997
    Assignee: Peach State Labs, Inc.
    Inventors: R. Richard Sargent, Michael S. Williams, Thomas H. Moss, III, Jeffrey R. Alender
  • Patent number: 5620796
    Abstract: A method of producing an acrylic emulsion adhesive characterized in that a composition comprising 100 parts by weight of a monomeric mixture of alkyl (meth)acrylate, acrylic acid, methacrylic acid and N-vinylpyrrolidone, 0.5-2 parts by weight of a surfactant mixture of an anionic surfactant and a nonionic surfactant, and 0.03 to 0.5 part by weight of a polymerization initiator is subjected to emulsion polymerization reaction. The acrylic emulsion adhesive of this invention is rich in solids, features good adhesion and cohesion as well as high water resistance. Therefore, by coating one side of a transparent support, this adhesive can be used as an adhesive sheet for surface protection.
    Type: Grant
    Filed: April 10, 1995
    Date of Patent: April 15, 1997
    Assignee: Sekisui Kagaku Kogyo Kabushiki Kaisha
    Inventors: Kazuhiro Kawabata, Norio Numata
  • Patent number: 5616645
    Abstract: The present invention relates to a gelled fluoride resin fine particle dispersion for use as a coating, to a method of production thereof, and to a method using this gelled fluoride resin fine dispersion to protect an alkaline inorganic hardened body.The objective of the present invention is to provide an aqueous resin for use as a coating, this aqueous resin being able to form a high performance coating film that is superior in its ability to inhibit the leaching out of the alkaline substance from the alkaline inorganic hardened body, which has excellent weatherability, water resistance, alkaline resistance, and dirt picking resistance.The present invention accomplishes the stated objective through the utilization of gelled fine particles of a fluorine containing resin.The present invention may be used in the coating field.
    Type: Grant
    Filed: July 11, 1994
    Date of Patent: April 1, 1997
    Assignee: Dainippon Ink & Chemicals, Inc.
    Inventors: Shin'ichi Kuwamura, Yoshinobu Deguchi, Tokio Goto, Fumio Yoshino
  • Patent number: 5606008
    Abstract: The purpose of the present invention is to provide a method for manufacturing polycarbonate in which polycarbonate having outstanding color matching, outstanding thermal properties, particularly retention stability during molding, and outstanding water resistance can be effectively and easily manufactured.In the method for manufacturing polycarbonate of the present invention, an aromatic dihydroxy compound and a carbonic acid ester are subjected to melt condensation polymerization in the presence of a catalyst composed of(a) an aliphatic amine with 24-60 carbon atoms, and (b) an alkali metal compound and/or alkaline earth metal compound.The (a) aliphatic amine having 24-60 carbon atoms should preferably be an aliphatic tertiary amine and be used in the amount of 1.times.6.sup.-6 -1.times.10.sup.-1 moles for each mole of the aromatic dihydroxy compound, and the (b) alkali metal compound and/or alkaline earth metal compound should be used in an extremely minute specified amount.
    Type: Grant
    Filed: July 21, 1995
    Date of Patent: February 25, 1997
    Assignee: General Electric Company
    Inventors: Takeshi Sakashita, Tomoaki Shimoda, Takashi Nagai
  • Patent number: 5587449
    Abstract: In the process for the preparation, with simultaneous end group stabilization, of polyacetal copolymers in a homogeneous phase and working up thereof, cyclic formaldehyde oligomers are copolymerized with cyclic acetals in the presence of an initiator in a polymerization reactor and immediately thereafter the initiator is deactivated by addition of basic substances, the unstable chain ends being degraded down to 0.01% to 1% in the presence of residual monomer, the product losing the majority of the residual monomer at the reactor outlet by letting down into a pelletizing device and the residual monomer which remains and the impurities dissolved in the product being removed by extraction with solvents and the product being pelletized, after drying and stabilization.
    Type: Grant
    Filed: August 31, 1995
    Date of Patent: December 24, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Dietrich Fleischer, Michael Hoffmockel, Karl-Friedrich Muck, Gunter Sextro
  • Patent number: 5561025
    Abstract: A process for the preparation of polymer latex particles which comprises the emulsion polymerization of a mixture of monomer, polar comonomer, water, surfactant, initiator, and a water phase termination agent, and wherein the water phase termination agent is selected from the group consisting of butanethiol, pentanethiol, hexanethiol, heptanethiol, octanethiol, and carbon tetrabromide (CBr.sub.4).
    Type: Grant
    Filed: July 3, 1995
    Date of Patent: October 1, 1996
    Assignee: Xerox Corporation
    Inventors: Francisco E. Torres, Raj D. Patel, Michael A. Hopper, Grazyna E. Kmiecik-Lawrynowicz
  • Patent number: 5534038
    Abstract: Disclosed are processes for tinting hydrogel materials, such as contact lenses, by dissolving a leuco sulfate ester of a vat dye in an compatible monomer solution, adding an oxidizing initiator to the monomer solution, and oxidizing and polymerizing the monomer solution and dye in the same solution. In one aspect, the oxidation and polymerization are conducted simultaneously whereas in another embodiment, the oxidation of the soluble leuco sulfate ester of a vat dye to the insoluble vat dye and polymerization are conducted sequentially in the same reaction medium.
    Type: Grant
    Filed: May 19, 1995
    Date of Patent: July 9, 1996
    Assignee: Pilkington Barnes Hind, Inc.
    Inventor: John M. Evans
  • Patent number: 5520834
    Abstract: Soluble polyacetals containing acetaldehyde acetal units are obtainable by cationically initiated addition polymerization of(a) compounds containing at least 3 hydroxyl groups, and(b) divinyl ethers containing terminal vinyl ether groups, or mixtures of such divinyl ethers and monovinyl ethers, in the presence or absence of(c) dihydroxy compounds and/or monohydroxy compounds, and are useful as admixture in phosphate-reduced and phosphate-free detergents and cleaners and as dispersant for finely divided minerals.
    Type: Grant
    Filed: March 20, 1995
    Date of Patent: May 28, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Heinrich Hartmann, Johannes Perner, Hans-Ulrich Jaeger, Paul Diessel, Richard Baur, Volker Schwendemann
  • Patent number: 5496921
    Abstract: Polycarbonates are prepared by inducing the melt polycondensation of an aromatic dihydroxy compound and a diester carbonate in the presence of alkali metal compounds and/or alkaline earth metal compound droxy and adding to the polycarbonate which is the reaction product thereof: a sulfonic acid compound having the formula ##STR1## in an amount of 0.05-10 ppm, based on the polycarbonate, an epoxy compound in an amount of 1-2000 ppm, based on the polycarbonate and a phosphorus compound in an amount of 10-1000 ppm, based on the polycarbonate.
    Type: Grant
    Filed: October 24, 1994
    Date of Patent: March 5, 1996
    Assignee: GE Plastics Japan
    Inventors: Takeshi Sakashita, Tomoaki Shimoda
  • Patent number: 5416157
    Abstract: Provided is a process useful for making acrylic polymers of methacrylic acid having improved shear stability. The process provides polymers useful as enteric coatings for medicaments having improved coating efficiency of pharmaceutical forms. Also provided are medicaments in solid form coated with said polymers.
    Type: Grant
    Filed: September 9, 1993
    Date of Patent: May 16, 1995
    Assignee: Eastman Chemical Company
    Inventors: Robert G. Chen, Nancy M. Clipse
  • Patent number: 5401801
    Abstract: There is disclosed a novel silicone emulsion useful as a mold coating in aluminum die casting operations. The silicone emulsion of the invention comprises an aqueous dispersion of an organopolysiloxane of a particular general formula in combination with an alkyl diphenyl ether disulfate salt. The novel silicone emulsion of the invention exhibits stability even when diluted tens of times and subjected to mechanical shear. When applied to a heated mold surface, water is driven from the silicone emulsion and there is formed a oil film. The oil film allows for easy release of the cast part. Furthermore, the film exhibits good paintability and lubricity under extreme pressure.
    Type: Grant
    Filed: April 6, 1993
    Date of Patent: March 28, 1995
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Tsutomu Naganawa, Isao Ona
  • Patent number: 5380790
    Abstract: Provided is a process useful for preparing acrylic polymers of methacrylic acid and ethyl acrylate. The process provides polymers useful as enteric coatings for medicaments in solid form, said coatings having improved effectiveness, reproducibility and coating efficiency. Also provided are medicaments in solid form coated with such polymers.
    Type: Grant
    Filed: September 9, 1993
    Date of Patent: January 10, 1995
    Assignee: Eastman Chemical Company
    Inventors: Robert G. Chen, Stephen H. Wu
  • Patent number: 5380789
    Abstract: A catalyst selected from a perfluorosulfonic acid and an anhydride thereof enables a non-conjugated drying oil to react with a phenol to form a phenol-added vegetable oil without causing hydrolysis of the non-conjugated drying oil. The phenol-added vegetable oil is allowed to react with an aldehyde to form a vegetable oil-modified phenolic resin. A laminate produced by impregnating paper with the vegetable oil-modified phenolic resin and laminating and molding the impregnated paper is excellent in low temperature punching quality and electrical properties and is free from low molecular weight components oozing out the surface of the laminate.
    Type: Grant
    Filed: August 10, 1993
    Date of Patent: January 10, 1995
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Ken Nanaumi, Takeshi Horiuchi, Masahiro Nomoto, Mitsuhiro Inoue
  • Patent number: 5371170
    Abstract: Polycarbonates are prepared by inducing the melt polycondensation of an aromatic dihydroxy compound and a diester carbonate in the presence of alkali metal compounds and/or alkaline earth metal compound droxy and adding to the polycarbonate which is the reaction product thereof: a sulfonic acid compound having the formula ##STR1## in an amount to 0.05-10 ppm, based on the polycarbonate, and also an epoxy compound in an amount of 1-2000 ppm, based on the polycarbonate.
    Type: Grant
    Filed: February 23, 1994
    Date of Patent: December 6, 1994
    Assignee: GE Plastics Japan
    Inventors: Takeshi Sakashita, Tomoaki Shimoda
  • Patent number: 5322886
    Abstract: Polychloroprene latexes, well suited for the production of adhesives, are prepared by (co)polymerizing chloroprene, in aqueous emulsion, in the presence of a free-radical initiator and at least one emulsifying agent, said aqueous emulsion further comprising (a) at least one non-carboxylic ionic surfactant and (b) at least two nonionic surfactants, the HLB values thereof differing by at least 3 units.
    Type: Grant
    Filed: May 13, 1991
    Date of Patent: June 21, 1994
    Assignee: Distugil
    Inventor: Francois Sauterey
  • Patent number: 5306801
    Abstract: The present invention relates to a polycarbonate production method. More specifically, it relates to a polycarbonate production method that is capable of preparing polycarbonates which have excellent residence stability such as hue stability and heat stability at the time of molding, and which have particularly outstanding water resistance.
    Type: Grant
    Filed: June 24, 1992
    Date of Patent: April 26, 1994
    Assignee: GE Plastics Japan, Ltd.
    Inventors: Takeshi Sakashita, Tomoaki Shimoda
  • Patent number: 5302670
    Abstract: The present invention relates to plastics that can be obtained by reacting unsaturated and/or hydroxyl-group-containing fatty acids or their esters or mixtures of various such fatty acids and esters with bifunctional ester-forming and/or amide-forming compounds and, if necessary, subsequently converting ethylenic double bonds, to give difatty acid diamides, difatty acid diesters, difatty acid amide esters, monofatty acid amide amines or monofatty acid amide alcohols as monomer components which contain at least two reactive groups suited for linkage to give polymers, in particular ethylenic double bonds, hydroxyl groups, epoxy groups or amino groups, and by linking the said compounds in the known way via a second group of bifunctional compounds that are capable of reacting with these free reactive groups to give the desired plastics.
    Type: Grant
    Filed: February 28, 1991
    Date of Patent: April 12, 1994
    Assignee: Battelle-Institut e.V.
    Inventors: Rainer Frische, Jurgen Volkheimer, Klaus Wollmann, Herrmann Schomann, Judith Schneider, Alexander Ach, Renate Gross-Lannert, Bernd Best
  • Patent number: 5288794
    Abstract: A cyanoacrylate monomer adhesive formulation which has improved thermal properties resulting from the inclusion in the formulation of an effective amount for enhancing the thermal resistance of the cured polymer of a mono, poly or hetero aromatic compound characterized by at least three substitutions on an aromatic ring thereof, two or more of said substitutions being electron withdrawing groups selected from the group consisting of NO.sub.2, CN, CF.sub.3, NR.sup.1.sub.3.sup.+, SR.sup.1.sub.2.sup.+, C(.dbd.O)R.sup.1, C(.dbd.O)OR.sup.1, NO, CCl.sub.3, SO.sub.2, S(.dbd.O), SO.sub.3, SO.sub.2 R.sup.1, SO.sub.2 OR.sup.1 and F, one or more of said substitutions being leaving groups selected from the group consisting of F, Br, Cl, I, NO.sub.2, CN, SOR.sup.1, SO.sub.2 R.sup.1 and SO.sub.2 OR.sup.1, and R.sup.1 is an optionally substituted hydrocarbon group. Example such compounds have the formula: ##STR1## where L is the leaving group and the W groups are the electron withdrawing groups.
    Type: Grant
    Filed: October 23, 1992
    Date of Patent: February 22, 1994
    Assignee: Loctite Corporation
    Inventor: Shabbir Attarwala
  • Patent number: 5288840
    Abstract: A polyoxymethylene copolymer excellent in stability and mechanical properties which is comprised of oxymethylene units and oxyalkylene units and has a molecular weight of 10,000 to 200,000. The proportion of oxyalkylene units to oxymethylene units is 0.07 to 0.5% by mole and the ratio of the absorbance of terminal formate groups to that of methylene groups determined by infrared spectrophotometry is not more than 0.025. A process for producing the copolymer is also disclosed.
    Type: Grant
    Filed: June 2, 1992
    Date of Patent: February 22, 1994
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Hirohisa Morishita, Kazuhiko Matsuzaki
  • Patent number: 5286566
    Abstract: An electrically conductive polyurethane elastomer obtained by the reaction of a polytetramethylene ether glycol having the formula HO[(CH.sub.2).sub.4 O].sub.x H where x is from 8 to 41 and from about 20 to about 95 parts by weight per 100 parts by weight of said glycol of at least one diisocyanate, a sufficient amount of chain extender and cross linking agents to provide a crosslinked elastomer and an amount of an asymmetric ionic quarternary ammonium salt having the formula: ##STR1## where R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are C.sub.n H.sub.2n+1 and 1.ltoreq.n.ltoreq.25 sufficient to provide a D.C. volume resistivity of from about 10.sup.7 to about 10.sup.11 ohm cm. In a preferred embodiment the asymmetric ionic quarternary ammonium salt is hexadecyl ethyl dimethyl ammonium ethyl sulfate.
    Type: Grant
    Filed: August 31, 1993
    Date of Patent: February 15, 1994
    Assignee: Xerox Corporation
    Inventors: Edward L. Schlueter, Jr., Henry L. Manuel, James F. Smith, Thomas C. Parker, Robert M. Ferguson
  • Patent number: 5281657
    Abstract: A process for preparing organopolysiloxane hydrosols by mixing an organosilicon compound with water, which comprises mixing a silane of the formulaR.sub.a Si(OR.sup.1).sub.4-a (I)where a is 0, 1, 2 or 3, R can be the same or different and is a hydrogen atom or a monovalent organic radical, R.sup.1 can be the same or different and is a monovalent organic radical, and/or a partial hydrolysis product thereof and, optionally, an organodisiloxane of the formulaR.sup.2.sub.3 Si-O-SiR.sup.2.sub.3 (II)where R.sup.2 can be the same or different and is the same as R, with water in the presence of an emulsifier at a temperature below 15.degree. C.
    Type: Grant
    Filed: August 16, 1993
    Date of Patent: January 25, 1994
    Assignee: Wacker-Chemie GmbH
    Inventors: Konrad Mautner, Bernward Deubzer, Helmut Oswaldbauer, Hilmar Sinner
  • Patent number: 5281650
    Abstract: The invention relates to a method of preparing sintered shapes, comprising the steps of: (1) forming a green body from a mixture comprising (A) at least one inorganic powder with (B) at least one polymer derived from (a) at least two sulfo monomers or (b) a combination of (i) a sulfo monomer with (ii) at least one monomer selected from acrylic compounds, acrylonitriles, vinyl lactams and vinyl pyrrolidones and maleic acids, anhydrides or salts, provided the mixture is substantially free of polysaccharide; (2) sintering the body. Inorganic shapes made from the compositions of the present invention have relatively high fired densities; small uniform grain sizes; and relatively low porosity. The sulfo polymers of the present invention help disperse the inorganic powder. These polymers improve deagglomeration of the inorganic powder and also help prevent reagglomeration of the powder. The polymers provide divalent ion stability for systems using water containing divalent ions, such as hard water.
    Type: Grant
    Filed: November 22, 1991
    Date of Patent: January 25, 1994
    Assignee: The Lubrizol Corporation
    Inventors: W. Michael Burk, Robert E. Quinn
  • Patent number: 5264486
    Abstract: 2-component polyurethane sealants for the direct glazing of motor vehicles, comprising (A) a pasty polyurethane component containing a polyurethane prepolymer having free isocyanate groups, and a curing agent, and (B) a pasty solvent-containing component, where component (A) contains at least one latent, solvent-activatable curing agent which can be activated by means of solvents, and component (B) contains a polar, aprotic solvent and water reversibly bonded to a carrier substance which liberates the water in a delayed manner after components (A) and (B) have been mixed.
    Type: Grant
    Filed: December 4, 1991
    Date of Patent: November 23, 1993
    Assignee: Bostik, Inc.
    Inventor: Gerhard Piestert
  • Patent number: 5238992
    Abstract: A process for preparing solid polymer blends and composites of controlled porosity in microemulsions containing both hydrophilic and hydrophobic phases. The microemulsions are prepared with surfactant systems that may include a cosolvent as a part thereof, together with a hydrophilic monomer, or monomers, dissolved in the hydrophilic phase of the microemulsion, and a hydrophobic monomer, or monomers, dissolved in the hydrophobic phase. Polymerization of the monomers thus present is carried out to provide highly uniform dispersions of the resulting polymers in each other. The invention allows for the control of the morphology of the blends, the improvement in compatability of otherwise incompatible polymers, and improvements in the processability of the polymers due to enhanced thermal and mechanical properties.
    Type: Grant
    Filed: August 26, 1992
    Date of Patent: August 24, 1993
    Assignee: Edison Polymer Innovation Corporation
    Inventor: Syed Outubuddin