Containing Hydroxyl Group Dnrm Patents (Class 524/761)
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Patent number: 9102900Abstract: An inverse dispersion comprising i) at least one cationic polymer obtainable by the polymerization of a) at least one cationic monomer and optionally at least one nonionic monomer (compound A), b) optionally at least one crosslinker (compound B), c) optionally at least one chain transfer agent (compound C), ii) at least one stabilizing agent, wherein the stabilizing agent has one or more hydrophobic chains with more than 30 carbon atoms, iii) at least one non-aqueous carrier.Type: GrantFiled: May 20, 2013Date of Patent: August 11, 2015Assignee: BASF SEInventors: Reinhold J. Leyrer, Ouidad Benlahmar, Volodymyr Boyko, Jules Mikhael, Frank Huelskoetter, Mark Robert Sivik, Travis Kyle Hodgdon, Jichun Shi
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Patent number: 9090736Abstract: A radiation-curable rheological assistant which comprises a compound comprising at least one (meth)acrylate group and at least one urea group of the formula —NH—(CO)—NR1R2 connected thereto wherein R1 and R2 each independently of one another are hydrogen, alkyl, aryl, cycloalkyl or aralkyl, with the proviso that at least one of the radicals is other than hydrogen, a process for preparing the rheological assistant by reacting at least one compound which has at least one isocyanate-reactive group and at least one (meth)acrylate group with at least one di- or polyisocyanate, use of the rheological assistant in radiation-curable coating compositions, such radiation-curable coating compositions, and the use of such radiation-curable coating compositions.Type: GrantFiled: February 17, 2012Date of Patent: July 28, 2015Assignee: BASF SEInventors: Reinhold Schwalm, Erich Beck
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Patent number: 9023943Abstract: The present invention relates to the use of Styrenated Phenol Ethoxylates as surfactants in emulsion polymerization. The present invention further relates to the use of both anionic and nonionic Styrenated Phenol Ethoxylates in emulsion polymerization. Latexes with small average particle and narrow particle size distributions are obtained. Prepared latexes also have low coagulum levels and exhibit excellent mechanical and chemical stability.Type: GrantFiled: November 28, 2011Date of Patent: May 5, 2015Assignee: Ethox Chemicals LLCInventors: Lawrence C. Davis, Edward R. Godwin, Charles V. Hinton, James T. Tanner
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Publication number: 20150050501Abstract: An adhesive system for preparing lignocellulosic composites comprising a) an aqueous primer composition and, b) a polyurethane adhesive composition, wherein said aqueous primer composition comprises: from 0 to 25 wt. %, by weight of the composition, of polyol selected from the group consisting of water soluble polyols, water dispersible polyols, water emulsifiable polyols and mixtures thereof, wherein said polyols have a molecular weight less than 5000 daltons; and, up to 10 wt. %, by weight of the composition, of surfactant selected from the group consisting of water soluble surfactants, water emulsifiable surfactants and mixtures thereof, with the proviso that the aqueous primer composition must comprise at least one of said polyol or a surfactant having hydroxyl functionality and a molecular weight of less than 5000 daltons.Type: ApplicationFiled: August 4, 2014Publication date: February 19, 2015Inventors: Frank Swiezkowski, Peter Dolan, Carlos Amen-Chen, Joseph Gabriel
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Patent number: 8859656Abstract: Emulsions containing acrylic associative thickening agents which, when polymerized in the presence of particular polyglycerols, have a thickening power which is remarkably stable over time.Type: GrantFiled: October 25, 2012Date of Patent: October 14, 2014Assignee: CoatexInventors: Jean-Marc Suau, Denis Ruhlmann
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Patent number: 8822581Abstract: Polystyrene is dispersed into a polyol via a mechanical dispersion process. A stabilizer is present to stabilize the dispersed polymer particles. The stabilizer includes a copolymer of (1) from 10 to 70% by weight of a branched polyol which has a molecular weight of from 4000 to 20,000, from 0.2 to about 1.2 polymerizable ethylenically unsaturated groups per molecule and from about 3 to about 8 hydroxyl groups per molecule with (2) from 30 to 90% by weight of styrene or a mixture of styrene and one or more other low molecular weight monomers.Type: GrantFiled: June 18, 2009Date of Patent: September 2, 2014Assignee: Dow Global Technologies LLCInventors: Hanno R. Van der Wal, Ronald Wevers, Freddy Van Damme, Francois M. Casati, Georges Kanaan, Fernand Pla, Sandrine Hoppe, Bart Noordover, Christian Fonteix
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Patent number: 8790693Abstract: The present invention relates to a process for preparing an aqueous polymer dispersion by free-radical emulsion polymerization of a monomer mixture which comprises N,N-diethylaminoethyl methacrylate, to the polymer dispersion obtainable by this process, and to the use thereof.Type: GrantFiled: August 1, 2008Date of Patent: July 29, 2014Assignee: BASF SEInventors: Maximilian Angel, Karl Kolter, Hartwig Voβ
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Patent number: 8772405Abstract: A polymer polyol (I) is provided that is formed of a polyol (A), polymer particles (B) obtained by polymerization of an ethylenically unsaturated compound (b), and an active-hydrogen-containing compound (d) having an aromatic ring and having a number-average molecular weight of 150 to 2,000, wherein a content of (d) is 1 to 20% on the basis of a weight of (B). The polymer polyol of the present invention contains polymer particles having sufficiently small particle diameters, has a low viscosity, and has excellent handleability. A polyurethane resin obtained by using the polymer polyol of the present invention has excellent mechanical strengths such as elongation at break.Type: GrantFiled: September 25, 2008Date of Patent: July 8, 2014Assignee: Sanyo Chemical Industries, Ltd.Inventors: Takayuki Tsuji, Shigekuni Nakada, Yukiya Kobayashi, Katsuya Uchida
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Publication number: 20140058037Abstract: A polymeric stabilizer is produced by copolymerizing an unsaturated polyether with an unsaturated low molecular weight monomer in a controlled radical polymerization. The polymeric stabilizer is useful for producing polymer polyol products via a mechanical dispersion process or an in situ polymerization process.Type: ApplicationFiled: April 22, 2012Publication date: February 27, 2014Inventors: Lionel Petton, Hanno R. Van der Wal, Freddy Van Damme, Edwin Mes, Fillip E. Du Prez, Sam Verbrugghe, Jean-Paul Masy
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Publication number: 20130324663Abstract: A composition for forming a cast nylon part comprising a base caprolactam mixture and at least one of a first additive comprising acetylene carbon black; a second additive comprising at least one of nonyl phenol ethoxylate, silicon oil, and at least one nonionic surfactant having a viscosity similar to that of nonyl phenol ethoxylate; a third additive comprising silicon dioxide; and a fourth additive comprising intercalated expandable graphite.Type: ApplicationFiled: March 7, 2013Publication date: December 5, 2013Applicant: Advanced Nylons PTY. LTD.Inventor: Wilbur Cook
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Publication number: 20130153830Abstract: Porous materials are fabricated using interpenetrating inorganic-organic composite gels. A mixture or precursor solution including an inorganic gel precursor, an organic polymer gel precursor, and a solvent is treated to form an inorganic wet gel including the organic polymer gel precursor and the solvent. The inorganic wet gel is then treated to form a composite wet gel including an organic polymer network in the body of the inorganic wet gel, producing an interpenetrating inorganic-organic composite gel. The composite wet gel is dried to form a composite material including the organic polymer network and an inorganic network component. The composite material can be treated further to form a porous composite material, a porous polymer or polymer composite, a porous metal oxide, and other porous materials.Type: ApplicationFiled: August 3, 2011Publication date: June 20, 2013Inventors: Dong-Kyun Seo, Alex Volosin
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Publication number: 20130149543Abstract: To provide a water repellent composition which is capable of imparting sufficient water repellency and alcohol repellency to a hydrophobic substrate without significantly decreasing the antistatic property imparted to the hydrophobic substrate by an antistatic agent, and which presents a low environmental impact, its production method, a hydrophobic substrate treating agent composition and an article. A water repellent composition comprising a fluorinated copolymer having structural units based on a monomer (a) having a C1-6 polyfluoroalkyl group, structural units based on a monomer (b) having a C1-6 alkyl group and structural units based on a monomer (c) (halogenated olefin), and a medium, wherein the proportion of the structural units based on the monomer (a) is from 50 to 90 mass % of the structural units (100 mass %) based on all the monomers.Type: ApplicationFiled: February 11, 2013Publication date: June 13, 2013Applicant: Asahi Glass Company, LimitedInventor: Asahi Glass Company, Limited
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Publication number: 20130116368Abstract: Emulsions containing acrylic associative thickening agents which, when polymerized in the presence of particular polyglycerols, have a thickening power which is remarkably stable over time.Type: ApplicationFiled: October 25, 2012Publication date: May 9, 2013Applicant: COATEX S.A.S.Inventor: COATEX S.A.S.
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Patent number: 8278021Abstract: Disclosed is a method of producing a thin film transistor substrate having high light sensitivity, heat-resistance, impact resistance, and a photosensitive composition used by the same, the method including forming data wires on an insulating substrate, forming an organic insulating film on the data wires by applying a photosensitive composition comprising a terpolymer, where the terpolymer is derived from monomers of an unsaturated carboxylic acid, an unsaturated carboxylic acid anhydride, or a mixture thereof, an unsaturated epoxy group-containing compound, and an olefinic compound.Type: GrantFiled: July 10, 2008Date of Patent: October 2, 2012Assignee: Samsung Electronics Co., Ltd.Inventors: Hoon Kang, Jae-sung Kim, Yang-ho Jung, Hi-kuk Lee
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Publication number: 20120241667Abstract: A binder composition for electrodes with greater binding strength that does not inhibit the formation of a stable electrode interface (SEI) on the surface of an active substance is provided. The binder composition for electrodes includes at least one type of tetracarboxylic acid ester compound, at least one type of diamine compound, and an organic solvent. Furthermore, the organic solvent preferably has a boiling point that is 250° C. or less. In addition, the organic solvent preferably has a highest occupied molecular orbital (HOMO) that is ?10 eV or less.Type: ApplicationFiled: December 8, 2009Publication date: September 27, 2012Applicant: I.S.T. CorporationInventors: Koji Moriuchi, Yasuaki Takeda
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Publication number: 20120101188Abstract: The invention relates to a coating composition comprising: A) at least one thiol-functional compound having at least one thiol group, B) at least one polyisocyanate cross-linking agent with at least one free isocyanate group and C) at least one catalyst compound, said catalyst compound comprising at least one catalyst for the curing reaction between the thiol groups of component A and the free isocyanate groups of component B, and at least one cyclodextrine.Type: ApplicationFiled: April 29, 2010Publication date: April 26, 2012Applicant: E.I DU PONT DE NEMOURS AND COMPANYInventors: Carmen Flosbach, Stefanie Matten, Katharina Dreger
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Publication number: 20110033532Abstract: The present invention relates to a process for preparing an aqueous polymer dispersion by free-radical emulsion polymerization of a monomer mixture which comprises N,N-diethylaminoethyl methacrylate, to the polymer dispersion obtainable by this process, and to the use thereof.Type: ApplicationFiled: August 1, 2008Publication date: February 10, 2011Applicant: BASF SEInventors: Maximilian Angel, Karl Kolter, Hartwig Voss
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Publication number: 20100204401Abstract: Disclosed are aliphatic polyester resins containing 2,2,4,4-tetramethyl-1,3-cyclo-butanediol and solvent borne, thermosetting coating compositions prepared therefrom. The aliphatic polyesters exhibit good hardness and flexibility when formulated into thermosetting coatings compositions.Type: ApplicationFiled: February 6, 2009Publication date: August 12, 2010Applicant: EASTMAN CHEMICAL COMPANYInventors: Stacey James Marsh, Angela Hartley Honeycutt
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Publication number: 20090286931Abstract: An aqueous dispersion is prepared by subjecting (meth)acrylate containing a polyfluoroalkyl group and a polymerizable monomer containing no fluorine atom to an emulsification treatment in the presence of a surfactant and a polypropyleneglycol-based compound having a molecular weight of 250 to 5,000, followed by copolymerization reaction in the presence of a polymerization initiator. The resulting aqueous dispersion, even if prepared from (meth)acrylate copolymer containing mixed perfluoroalkyl groups including perfluoroalkyl groups having 12 or more carbon atoms as polyfluoroalkyl groups, has a distinguished emulsion stability and thus can be effectively used as a water and oil repellent, etc.Type: ApplicationFiled: July 24, 2009Publication date: November 19, 2009Applicant: UNIMATEC CO.,LTD.Inventors: Toshimasa Sagawa, Haruyoshi Tatsu, Masayosi Horiuti
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Publication number: 20090101205Abstract: The present invention pertains to a process for preparing a rubber precursor or a rubber composition comprising a modified inorganic oxygen-containing particulate material comprising the steps of: a) preparing a mixture of the modified inorganic oxygen-containing particulate material and a first solvent; and b1) adding the mixture to a rubber precursor comprising at least one polymer and optionally a second solvent; or b2) adding the mixture to a rubber composition comprising at least one monomer of a rubber precursor and optionally a second solvent, and polymerising the monomer(s) to form the rubber precursor; c) optionally cross-linking the rubber precursor in the presence of a cross-linking agent to form a rubber composition; and d) optionally removing the first and/or second solvents before, during or after any of the steps b1), b2), and c). The invention further pertains to rubber compositions comprising rubber and inorganic oxygen-containing particulate material modified with a coupling agent.Type: ApplicationFiled: March 14, 2007Publication date: April 23, 2009Applicant: AKZO Nobel N.V. ,a corporationInventors: Rudolf Anthonius Maria Venderbosch, Elwin Schomaker, Auke Gerardus Talma
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Patent number: 7279523Abstract: A 2-cyanoacrylate-based composition comprises a coloring material that changes color with curing of 2-cyanoacrylate. The composition has good visibility and excellent workability as it is colored before curing, and changes color with curing as it becomes colorless or light-colored after curing, thereby providing bonded, filled or surface treated portions with good appearance.Type: GrantFiled: November 4, 2003Date of Patent: October 9, 2007Assignee: Toagosei Co., Ltd.Inventors: Yushi Ando, Yoshiharu Ohashi
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Patent number: 6989414Abstract: An aqueous emulsion having excellent water resistant property and comprising a copolymer obtainable by polymerizing ethylene and vinyl ester, and a nonionic polyoxyalkylene surface active agent, wherein the nonionic polyoxyalkylene surface active agent comprises 1 to 10 parts by weight of polyoxyalkylene alkyl ether and 0.01 part by weight or less of polyoxyalkylene phenyl ether based on 100 parts by weight of vinyl ester units in the copolymer is provided.Type: GrantFiled: March 14, 2002Date of Patent: January 24, 2006Assignee: Sumitomo Chemical Company, LimitedInventors: Tomoaki Sata, Tatsuo Mitsutake
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Patent number: 6869994Abstract: A carboxyl group-containing polymer composition comprising 100 parts by weight of a carboxyl group-containing polymer (A) prepared by copolymerizing an ?,?-unsaturated carboxylic acid (a) with a compound (b) having at least two ethylenic unsaturated groups; and 0.01 to 20 parts by weight of at least one compound (B) selected from an ester (c) obtained from a polyhydric alcohol and a fatty acid, and an alkylene oxide adduct of an ester (d) obtained from a polyhydric alcohol and a fatty acid. Since the carboxyl group-containing polymer composition is excellent in the solubility in water and gives the aqueous solution excellent thickening property, the polymer composition can be suitably used as a thickener for various aqueous solutions.Type: GrantFiled: June 8, 2000Date of Patent: March 22, 2005Assignee: Sumitomo Seika Chemicals Co., Ltd.Inventors: Masato Fujikake, Shigeki Hamamoto, Tomoki Kawakita, Masatoyo Yoshinaka
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Patent number: 6870001Abstract: An emulsifier mixture comprising an emulsifier I of the formula in which X is O, S, CH2, NH or NR7, one or two of the radicals R1 to R6 are a group SO3?K? and the remainder of R1 to R6 are H or a C1-C18 alkyl group, R7 is a C1-C18 alkyl group and K is a countercation, an emulsifier II of the formula R8—O—(Z?O)n—SO3?K? in which the variables have the following meanings: R8: C1-C18 alkyl Z: CH2—CH2 or n: an integer from 1 to 50 K: a cation, and a nonionic emulsifier III.Type: GrantFiled: April 18, 2002Date of Patent: March 22, 2005Assignee: BASF AktiengesellschaftInventors: Dirk Wulff, Gerhard Auchter
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Patent number: 6602940Abstract: A process for the preparation of an aqueous solution or dispersion containing a cationic polymer, which comprises the steps of: polymerizing a monomer including an N-vinyl-carboxylic acid amide represented by the general formula CH2═CHNHCOR, wherein R represents a hydrogen atom or methyl group, in an aqueous medium in the presence of either or both of a polyethylene glycol and polypropylene glycol; and then modifying the resulting polymer with an acid or base. Furthermore, an aqueous composition containing a cationic polymer, which comprises (A) a modified N-vinylcarboxylic acid amide polymer, (B) either or both of a polyethylene glycol and polypropylene glycol, and (C) water is disclosed.Type: GrantFiled: May 11, 1998Date of Patent: August 5, 2003Assignee: Mitsubishi Chemical CorporationInventors: Shin-ichi Sato, Takahiro Oshida, Takashi Ono, Kiyoji Kuma, Yasuharu Mori, Atsuo Takeuchi
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Patent number: 6495627Abstract: A conductive composition for a biological electrode is capable of reducing the impedance between the electrode and the skin. A conductive gel composition for a biological electrode which is capable of electrically and physically connecting a living body to an electrode element and is composed of at least the following components: (1) a radical-polymerizable unsaturated compound; (2) a moisturizer serving as a plasticizer and functioning to supplementing and promoting the physiological humidifying function of the horny layer; (3) a polymerization initiator; and (4) a crosslinking agent. This moisturizer serves also as a plasticizer and, furthermore, elevates the moisture content in the horny layer at the application of this composition. The above-mentioned composition may further contain a plasticizer selected from among polyhydric alcohols, amines and ethers.Type: GrantFiled: July 11, 1996Date of Patent: December 17, 2002Assignee: Nihon Kohden CorporationInventors: Shin Suda, Tohru Kurata
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Patent number: 6451892Abstract: A composition for preventing or retarding the formation of gas hydrates during the transport of a fluid comprising water and a hydrocarbon through a conduit. The composition is a homopolymer of vinyl caprolactam, or copolymers thereof, having a low molecular weight in the range of 500 to 2500, which is made in a polymerization solvent, preferably a glycol ether, most preferably 2-butoxyethanol and also including a carrier solvent, preferably monoethylene glycol.Type: GrantFiled: July 13, 1999Date of Patent: September 17, 2002Assignee: ISP Investments Inc.Inventors: Kirill N. Bakeev, Kevin Harris, Carl B. Argo, Michael A. Drzewinski, David E. Graham
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Patent number: 6376588Abstract: Disclosed is a composition useful as a mold release agent, exhibiting viscosities, lubricities and melting points which cover a wide range and fit a variety of types of molding equipment, comprising: a) 5 to 40% by weight one or more water soluble copolymers of ethylene oxide and propylene oxide which are in liquid phase at ambient temperatures; b) 15 to 60% by weight a crystalline polyoxyalkylene having a melting point slightly above ambient; and c) 100 to 5000 ppm of one or more antioxidant additives.Type: GrantFiled: October 15, 1991Date of Patent: April 23, 2002Assignee: Huntsman Petrochemical CorporationInventor: Edward Chung Yit Nieh
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Patent number: 6319978Abstract: The present invention is directed to improved vinyl acetate ethylene pressure sensitive adhesive emulsion polymers. The improvement in the aqueous based, emulsion polymerized pressure sensitive adhesives resides in: a high ethylene content copolymer having a Tg of from −25 to −70° C.; a tensile storage modulus measured at one hertz and at a temperature of −20° C. embraced by the points on a plot of storage modulus and temperature of from 1 times 106 and the points 4 times 109 dynes/cm2 and less that 1 times 107 dynes/cm2 measured at 50° C.Type: GrantFiled: October 1, 1998Date of Patent: November 20, 2001Assignee: Air Products and Chemicals, Inc.Inventors: Christian Leonard Daniels, Chung-Ling Mao, Richard Henry Bott, Menas Spyros Vratsanos
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Publication number: 20010005736Abstract: The disclosed invention relates to isocyanate reactive systems which have an internal mold release agents having improved stability. The isocyanate reactive system includes (1) at least one compound containing a plurality of isocyanate-reactive groups and (2) an internal mold release system comprising (a) a carboxylic acid and (b) a compound selected from the group consisting of a fatty polyester, a fatty acid ester and a fatty amide, and a surfactant selected rom the group consisting of ethoxylated alcohols, propoxylated alcohols or blends thereof.Type: ApplicationFiled: January 22, 2001Publication date: June 28, 2001Inventor: Andreas H. Rothacker
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Patent number: 6103388Abstract: The use of up to about 20 parts by weight of an organic solvent selected from the group consisting of the water soluble polyalkylene glycol ethers in conventional waterborne packaging and converting adhesives provides comparable or better adhesive products with reduced environmental and health related problems.Type: GrantFiled: January 21, 1998Date of Patent: August 15, 2000Assignee: National Starch and Chemical Investment Holding CorporationInventors: Kristina Babcock, Joseph Wieczorek, Jr.
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Patent number: 6025426Abstract: Hydrophilic cationic copolymers of acrylamide are prepared as dispersions in a salt media. These polymers have high molecular weights and are readily activated by diluting in water. These polymers are useful flocculants for such applications as sludge dewatering, raw water clarification aids, emulsion breakers and waste water clarification aids.Type: GrantFiled: December 18, 1995Date of Patent: February 15, 2000Assignee: Nalco Chemical CompanyInventor: John R. Hurlock
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Patent number: 5985989Abstract: Substances useful as water reducing and superplasticizer additives for cement compositions are formed by in situ polymerization of one or more ethylenically unsaturated acid monomers such as acrylic acid or maleic anhydride in a reaction medium comprising a polyether such as polypropylene glycol or a copolymer of ethylene oxide and propylene oxide to form a carboxylic acid polymer, followed by reaction of the polyether and carboxylic acid polymer. The composition and properties of the resulting additives may be readily varied as desired through the use of different acid monomers, polyethers, reaction conditions, reagent proportions and the like.Type: GrantFiled: July 9, 1997Date of Patent: November 16, 1999Assignee: ARCO Chemical Technology, LPInventors: Edward T. Shawl, Xinhau Zhou
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Patent number: 5962570Abstract: A process for the preparation of an aqueous solution or dispersion containing a cationic polymer, which comprises the steps of: polymerizing a monomer including an N-vinylcarboxylic acid amide represented by the general formula CH.sub.2 .dbd.CHNHCOR, wherein R represents a hydrogen atom or methyl group, in an aqueous medium in the presence of either or both of a polyethylene glycol and polypropylene glycol; and then modifying the resulting polymer with an acid or base. Furthermore, an aqueous composition containing a cationic polymer, which comprises (A) a modified N-vinylcarboxylic acid amide polymer, (B) either or both of a polyethylene glycol and polypropylene glycol, and (C) water is disclosed.Type: GrantFiled: December 13, 1996Date of Patent: October 5, 1999Assignee: Mitsubishi Chemical CorporationInventors: Shin-ichi Sato, Takahiro Oshida, Takashi Ono, Kiyoji Kuma, Yasuharu Mori, Atsuo Takeuchi
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Patent number: 5939478Abstract: The viscosity of a solvent is modified by thickening the solvent with a silicone latex. A silicone latex having a plurality of crosslinked polysiloxane particles is first prepared by mixing the siloxane polymer, a surfactant, and water; emulsifying the mixture to a gel phase; diluting the emulsion with water; adding a cure package (i.e., a catalyst, a crosslinker, or both, or a self catalytic crosslinker); and then without removing the water from the latex and after the particles of siloxane polymer in the latex have been cured, mixing the latex and solvent to thicken the solvent, forming viscous liquids, gels, and pastes. Water in the latex thickened solvent composition can be stabilized by adding a silicone polyether during mixing of the latex and the solvent.Type: GrantFiled: November 13, 1997Date of Patent: August 17, 1999Assignee: Dow Corning CorporationInventors: James Anderson Beck, Vicky Sue Cobb, Cassie Emelia Cuthbert, Eric Jude Joffre, Virginia Kay O'Neil, Burt Michael Wrolson
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Patent number: 5869570Abstract: A composition including polyalphaolefins that function as drag reducing agents and a process for the preparation of polyalphaolefins that function as drag reducing agents are disclosed. The process includes contacting alphaolefin monomers with catalyst particles in a polymerization mixture that includes a hydrocarbon solvent. The polymerization of the alphaolefin monomers produces polyalphaolefin drag reducing agents having an inherent viscosity of at least 10 dL/g. During polymerization of the polyalphaolcfin monomers, localized micelles compromising high molecular weight polyalphaolefin polymer are formed in micellar zones around the catalyst particles. The polymerization is conducted in the presence of a viscosity reducing agent that includes a substantially hydrophobic dispersant. The viscosity reducing agent is present in an amount sufficient to reduce the viscosity of the reaction mixture and disperse the localized micelles.Type: GrantFiled: March 19, 1996Date of Patent: February 9, 1999Assignee: Energy & Environmental International, L.C.Inventors: Gerald B. Eaton, Michael J. Monahan
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Patent number: 5807609Abstract: At least one compound ##STR1## is added to mineral building materials modified with polymers in order to increase their adhesive power on foams based on polystyrene.Type: GrantFiled: July 26, 1995Date of Patent: September 15, 1998Assignee: BASF AktiengesellschaftInventors: Joachim Pakusch, Maximillian Angel, Andree Dragon, Wilhelm Friedrich Beckerle, Helmut Teichmann
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Patent number: 5773513Abstract: A waterborne coating composition comprising 5-70 weight percent solids of a curing agent and 30-95 weight percent solids of a hydroxy functional acrylic copolymer further comprising 20-70 weight percent of a vinyl aromatic, 0-40 weight percent of a hydroxy functional monomer, 0-70 weight percent of other polymerizable compounds, and 10-80 weight percent of a reaction product of a monoepoxyester and an unsaturated acid functional monomer wherein the copolymer is prepared via skew feed polymerization having a plurality of feed streams charged to a reactor and one feed stream contains 5-60 weight percent of the unsaturated acid functional monomer, 40-95 weight percent of the reaction product of a monoepoxyester and an unsaturated acid functional monomer, and 0-55 weight percent of the other polymerizable compounds.Type: GrantFiled: April 4, 1996Date of Patent: June 30, 1998Assignee: E. I. du Pont de Nemours and CompanyInventors: Jozef Huybrechts, Kerstin Stranimaier
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Patent number: 5698627Abstract: A novel additive for papermaking is disclosed. The additive comprises an aqueous solution of a copolymer obtained by reacting (a) an acrylamide, (b) a vinyl monomer which is copolymerizable with component (a) and has a cationic group, (c) at least one of vinyl monomers which are copolymerizable with component (a) and (b) and have 2, 3 or 4 carboxyl groups in a molecule thereof and/or a salt thereof, optionally (e) a nonionic monomer which is copolymerizable with components (a), (b) and (c) if desired, and (d) a cross-linking compound, in the presence of (f) at least one of ethylene glycol, diethylene glycol, diethanolamine and glycerin.This novel additive for papermaking is able to achieve excellent freeness and retention in the process of papermaking and provides paper with increased strength.Type: GrantFiled: March 29, 1996Date of Patent: December 16, 1997Assignee: Japan PMC CorporationInventors: Tadayoshi Oguni, Satoshi Takizawa, Kiyoshi Iwai
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Patent number: 5698629Abstract: A process for the preparation of a water-in-oil type polymer emulsion which comprises polymerizing an acrylamide-containing monomer in a water-in-oil type emulsion. The acrylamide is prepared by hydrating acrylonitrile in the presence of a catalytic amount of nitrilehydratase.Type: GrantFiled: August 16, 1996Date of Patent: December 16, 1997Assignee: Nitto Chemical Industry Co., Ltd.Inventors: Susumu Seki, Wataru Fujii
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Patent number: 5616645Abstract: The present invention relates to a gelled fluoride resin fine particle dispersion for use as a coating, to a method of production thereof, and to a method using this gelled fluoride resin fine dispersion to protect an alkaline inorganic hardened body.The objective of the present invention is to provide an aqueous resin for use as a coating, this aqueous resin being able to form a high performance coating film that is superior in its ability to inhibit the leaching out of the alkaline substance from the alkaline inorganic hardened body, which has excellent weatherability, water resistance, alkaline resistance, and dirt picking resistance.The present invention accomplishes the stated objective through the utilization of gelled fine particles of a fluorine containing resin.The present invention may be used in the coating field.Type: GrantFiled: July 11, 1994Date of Patent: April 1, 1997Assignee: Dainippon Ink & Chemicals, Inc.Inventors: Shin'ichi Kuwamura, Yoshinobu Deguchi, Tokio Goto, Fumio Yoshino
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Patent number: 5594066Abstract: Stable, agglomerate-free, low-viscosity graft copolymer dispersions are prepared by the radical polymerization of 25 to 65% by weight of ethylenically unsaturated monomers in the presence of a base polyol, a macromer, a low-molecular weight regulator and, optionally, an organic solvent. The dispersions of this process are suitable as a polyol component for the production of polyurethane plastics by the isocyanate addition process.Type: GrantFiled: August 23, 1995Date of Patent: January 14, 1997Assignee: Bayer AktiengesellschaftInventors: Torsten Heinemann, Manfred Dietrich, Gundolf Jacobs, Mark Kratz, Josef Sanders, Uwe Scholz, Helmut Woynar
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Patent number: 5539022Abstract: Water-dilutable dispersions of acrylate copolymers having a hydroxyl number of from 40 to 200 mg KOH/g and an acid number of from 15 to 50 mg of KOH/g, obtained by free-radical copolymerization ofa) from 5 to 40 parts by weight of at least one glycidyl ester of an .alpha.-branched aliphatic saturated monocarboxylic acid,b) from 0 to 30 parts by weight of at least one diester of an .alpha.,.beta.-olefinically unsaturated dicarboxylic acid,c) from 0 to 70 parts by weight of at least one vinyl aromatic hydrocarbon, the molar quantity of component c) always being greater than or equal to the molar quantity of component b),d) from 0 to 60 parts by weight of an alkyl ester of an .alpha.,.beta.-olefinically unsaturated carboxylic acid,e) from 2 to 40 parts by weight of at least one .alpha.,.beta.-olefinically unsaturated carboxylic acid, the molar quantity of component e) always being greater than the molar quantity of component a),f) from 5 to 40 parts by weight of at least one hydroxyalkyl ester of an .alpha.,.Type: GrantFiled: April 4, 1994Date of Patent: July 23, 1996Assignee: Hoechst AktiengesellschaftInventors: Holger Schmidt, Tanja R. Brueck, Uwe Kubillus, Harald Oswald, Petra Schaub, Andrea Travers-Hemmer
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Patent number: 5494957Abstract: A polymer polyol is prepared by polymerizing one or more ethylenically unsaturated monomers in a polyol. A high molecular weight stabilizer having polymerizable ethylenic unsaturation and a low hydroxyl functionality is used, which leads to improved dispersion stability at reduced stabilizer level.Type: GrantFiled: August 17, 1994Date of Patent: February 27, 1996Assignee: The Dow Chemical CompanyInventors: Douglas R. Moore, Keith R. Plowman, Paul L. Neill
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Patent number: 5426136Abstract: Particulate amorphous silica, surfactant, monomer, and an aqueous solvent are brought into mutual contact so that as equilibrium is approached the concentration of the surfactant in the liquid phase is below, at, or slightly above the critical micelle concentration; the monomer is then polymerized to form polymeric film associated with at least a portion of the surface of the particulate amorphous silica, the polymeric film being (i) homopolymer of an aliphatic monomer or (ii) copolymer of at least two different monomers.Type: GrantFiled: March 24, 1993Date of Patent: June 20, 1995Assignee: PPG Industries, Inc.Inventors: Walter H. Waddell, Larry R. Evans, Jeffrey H. Harwell, John H. O'Haver
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Patent number: 5424122Abstract: The invention relates to a neutral nonionic latex comprising:(a) about 5 to about 70 weight percent of a nonionic polymer comprising polymerized free-radically polymerizable nonionic monomer, based upon the total weight of the neutral nonionic latex, wherein the free radically polymerizable nonionic monomer comprises:(i) about 90 to about 99 percent by weight of nonionic alkyl acrylate monomer; and(ii) about 1 to about 10 percent by weight of nonionic amide monomer; wherein the weight percentages of (i) and (ii) are based upon the total weight of (i) plus (ii);(b) about 30 to about 95 weight percent of an aqueous phase, based upon the total weight of the neutral nonionic latex; and(c) about 2 to about 10 weight percent of a nonionic emulsifier based upon the total weight of the nonionic polymer plus the nonionic emulsifier;wherein particles of the nonionic polymer are stabilized by the nonionic emulsifier and dispersed within the aqueous phase.Type: GrantFiled: December 9, 1991Date of Patent: June 13, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: Michael D. Crandall, Robert L. Nelson
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Patent number: 5399604Abstract: An epoxy group-containing thermosetting resin composition comprising (A) a copolymer obtained from (a) at least one member selected from an unsaturated carboxylic acid and an unsaturated carboxylic acid anhydride, (b) an epoxy group-containing unsaturated compound, (c) a monoolefin unsaturated compound, and optionally (d) a conjugated diolefin unsaturated compound, and (B) an organic solvent for dissolving the above copolymer. There is also provided another epoxy-group containing thermosetting resin composition which contains the above component (A), (C) a polymerizable compound having at least one ethylenically unsaturated double bond, and (D) a photopolymerization initiator. These epoxy-group containing thermosetting resin compositions are excellent in storage stability.Type: GrantFiled: July 21, 1993Date of Patent: March 21, 1995Assignee: Japan Synthetic Rubber Co., Ltd.Inventors: Kimiyasu Sano, Masayuki Endo, Atsufumi Shimada, Yasuaki Yokoyama, Nobuo Bessho
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Patent number: 5349021Abstract: A thermosetting printing ink composition comprising a functional copolymer of a thermosettable polyester and a polysiloxane, a pigment, a crosslinking agent and a curing catalyst which may be a strong acid or a metal salt thereof. The composition desirably also includes a reactive diluent such as a glycol, glycol ether or alcohol. The compositions are especially useful for imprinting metal containers such as beer and soda cans.Type: GrantFiled: June 2, 1993Date of Patent: September 20, 1994Assignee: Sun Chemical CorporationInventors: John M. Rooney, Narendra M. Patel, Albert A. Kveglis, Robert J. Catena, Leonard Di Leo, Selcuk Avci
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Patent number: 5342865Abstract: A solvent system contains methoxy acetone, water and, optionally, an oxygen-containing solvent other than methoxy acetone, such as a propylene glycol monoether or diether. The solvent system is a useful solvent for a curing agent for an epoxy resin, a curing catalyst and/or a cure inhibitor. A solution of the curing agent, the curing catalyst and/or the cure inhibitor in the solvent system can be mixed with an epoxy resin, optionally dissolved in a solvent, for producing a one-component epoxy resin composition.Type: GrantFiled: April 20, 1993Date of Patent: August 30, 1994Assignee: The Dow Chemical CompanyInventors: Jan J. Zwinselman, John P. Everett, Karin Wanzl-Dacho
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Patent number: 5324774Abstract: High concentration-low viscosity polymer-polyols are prepared by polymerizing mixtures of acrylonitrile and styrene in polyols, which are free of any polymerizable carbon-carbon double bond, in the presence of alkyl-substituted tertiary mines. Without use, as a dispersion stabilizer, of organic compounds which have a polymerizable carbon-carbon double bond and terminal hydroxyl groups, there can be obtained polymer-polyols which have a concentration of the polymer of 33-60 wt % and a glass transition temperature of the polymer of 90.degree.-120.degree. C.Type: GrantFiled: October 14, 1992Date of Patent: June 28, 1994Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Ariko Nishikawa, Tamotsu Kunihiro, Tsukuru Izukawa, Kiyotsugu Asai