Ether Compound Dnrm, E.g., Aryl Ether, Dimethylether, Etc. Patents (Class 524/755)
  • Patent number: 11685818
    Abstract: Methods of making fiber reinforced composite articles are described. The methods may include treating fibers with a sizing composition that includes a polymerization compound, and introducing the treated fibers to a pre-polymerized composition. The combination of the treated fibers and pre-polymerized composition may then undergo a temperature adjustment to a polymerization temperature at which the pre-polymerized composition polymerizes into a plastic around the fibers to form the fiber-reinforced composite article. Techniques for introducing the treated fibers to the pre-polymerized composition may include pultrusion, filament winding, reactive injection molding (RIM), structural reactive injection molding (SRIM), resin transfer molding (RTM), vacuum-assisted resin transfer molding (VARTM), long fiber injection (LFI), sheet molding compound (SMC) molding, bulk molding compound (BMC) molding, a spray-up application, and/or a hand lay-up application, among other techniques.
    Type: Grant
    Filed: May 5, 2020
    Date of Patent: June 27, 2023
    Assignee: Johns Manville
    Inventors: Rajappa Tadepalli, Jawed Asrar, Klaus Friedrich Gleich, Kiarash Alavi
  • Patent number: 11518837
    Abstract: The present invention discloses a multi-arm polycarboxylate water reducer and a preparation method thereof, the preparation method includes the following steps: making a phenolic hydroxyl containing rigid compound and p-nitrobenzonitrile subjected to a nucleophilic substitution reaction in a solvent, then subjected to addition with a sodium azide in a solvent and water mixed solution to obtain a tetrazole derivative; making an unsaturated polyether macromonomer subjected to terminal halogenation and react with the prepared tetrazole derivative to obtain a tetrazole-containing multi-arm unsaturated polyether macromonomer; and subjecting the tetrazole-containing multi-arm unsaturated polyether macromonomer, an unsaturated carboxylic acid small monomer and an unsaturated polyether macromonomer to a free radical polymerization reaction under combined action of an initiator, a reducing agent and a molecular weight regulator to obtain the multi-arm polycarboxylate water reducer integrating shrinkage reducing and an
    Type: Grant
    Filed: June 21, 2022
    Date of Patent: December 6, 2022
    Assignees: Jiangsu ARIT New Materials CO., LTD., Chengdu ARIT Times New Material Co., Ltd.
    Inventors: Shanshan Qian, Xu Zhao, Jinying Peng, Tong Lu, Xuechuan Wang, Haojie Qu, Pengcheng Yu, Chunyang Zheng
  • Patent number: 9926662
    Abstract: A water/oil repellent composition which comprises a copolymer (A) comprising from 40 to 95 mass % of monomer (a1) units, from 1 to 60 mass % of monomer (a2) units and from 0 to less than 5 mass % of monomer (a3) units, a copolymer (B) comprising from 40 to 91 mass % of monomer (b1) units, from 2 to 20 mass % of monomer (b2) units, from 5 to 20 mass % of monomer (b3) units, and from 2 to 20 mass % of vinyl chloride (b4) units, and a liquid medium (C), wherein monomers (a1) and (b1) are (Z—Y)nX [Z is a C1-6 polyfluoroalkyl group, etc., Y is a divalent organic group having no fluorine atom, etc., n is 1 or 2, and X is a specific group having a polymerizable unsaturated group], monomers (a2) and (b2) are vinylidene chloride or vinylidene fluoride, and monomers (a3) and (b3) are a (meth)acrylate having a saturated hydrocarbon group having at least 12 carbon atoms.
    Type: Grant
    Filed: April 13, 2016
    Date of Patent: March 27, 2018
    Assignee: Asahi Glass Company, Limited
    Inventors: Minako Shimada, Sho Masuda, Kazunori Sugiyama, Kyoichi Kaneko, Yuichi Oomori, Motonobu Sakakibara, Masahiro Miyazaki, Kazuhiro Kawakami
  • Patent number: 9487689
    Abstract: To provide a fluorinated copolymer comprising, in specific ratios, units derived from F(CF2)6CH2CH2OC(O)C(CH3)?CH2, units derived from vinyl chloride, units derived from vinylidene chloride, units derived from an alkyl (meth)acrylate having a C12-30 alkyl group, and units derived from a monomer having no fluoroalkyl group and having a cross-linkable functional group, wherein units derived from F(CF2)nCH2CH2OC(O)C(CH3)?CH2 (wherein n is an integer of from 1 to 5) are in at most a specific ratio; a process for producing such a fluorinated copolymer; a water repellent composition containing such a fluorinated copolymer; and an article treated with such a water repellent composition.
    Type: Grant
    Filed: February 23, 2015
    Date of Patent: November 8, 2016
    Assignee: Asahi Glass Company, Limited
    Inventors: Kyouichi Kaneko, Kazunori Sugiyama, Minako Shimada, Takao Hirono, Reika Fukuda
  • Patent number: 9040625
    Abstract: To provide a water/oil repellent composition which can impart sufficient post-air-drying water/oil repellency to the surface of an article, and which presents a low environmental impact, and an article having its surface treated with the water/oil repellent composition. A water/oil repellent composition comprising a copolymer (A) having structural units based on a monomer (a), structural units based on a monomer (b), structural units based on a monomer (c) and/or structural units based on a monomer (d); and an aqueous medium (B) containing water, and a film-forming assistant (x) and/or a film-forming assistant (y). Monomer (a): a monomer having a C1-6 polyfluoroalkyl group, monomer (b): vinylidene chloride, monomer (c): a monomer, the homopolymer of which has a glass transition temperature of at least 20° C., monomer (d): a monomer having a crosslinkable functional group, film-forming assistant (x): a specific amide solvent, and film-forming assistant (y): a specific glycol solvent.
    Type: Grant
    Filed: October 24, 2013
    Date of Patent: May 26, 2015
    Assignee: ASAHI GLASS COMPANY, LIMITED
    Inventors: Kyouichi Kaneko, Kazunori Sugiyama, Reika Fukuda, Takao Hirono
  • Patent number: 9023943
    Abstract: The present invention relates to the use of Styrenated Phenol Ethoxylates as surfactants in emulsion polymerization. The present invention further relates to the use of both anionic and nonionic Styrenated Phenol Ethoxylates in emulsion polymerization. Latexes with small average particle and narrow particle size distributions are obtained. Prepared latexes also have low coagulum levels and exhibit excellent mechanical and chemical stability.
    Type: Grant
    Filed: November 28, 2011
    Date of Patent: May 5, 2015
    Assignee: Ethox Chemicals LLC
    Inventors: Lawrence C. Davis, Edward R. Godwin, Charles V. Hinton, James T. Tanner
  • Patent number: 9012537
    Abstract: There may be provided a process for producing a polyimide siloxane solution composition having a further improved long-term viscosity stability; and a polyimide siloxane solution composition. In the process for producing the polyimide siloxane solution composition by polymerizing/imidizing a tetracarboxylic acid component and a diamine component consisting of (a) a diaminopolysiloxane, (b) a diamine having a polar group and (c) a diamine other than (a) and (b) in a solvent, the tetracarboxylic acid component and the diamine component excluding (b) the diamine having a polar group are polymerized/imidized to provide a reaction mixture solution, and then (b) the diamine having a polar group is added to the reaction mixture solution last, and the mixture is polymerized/imidized.
    Type: Grant
    Filed: August 17, 2010
    Date of Patent: April 21, 2015
    Assignee: Ube Industries, Ltd.
    Inventors: Susumu Takasaki, Hiroo Yamashita, Seiichirou Takabayashi, Tomoko Hayashida, Mitsuo Yamanaka, Takafumi Hirakawa
  • Patent number: 8962751
    Abstract: A release agent composition, which includes a fluorocopolymer having structural units based on a monomer (a) having a C1-6 polyfluoroalkyl group and structural units based on monomer (b) having a C18-30 alkyl group, and a medium, where the mass ratio of the structural units based on the monomer (a) to the structural units based on the monomer (b) (the structural units based on the monomer (a)/the structural units based on the monomer (b)) is from 1/1 to 1/10.
    Type: Grant
    Filed: August 15, 2012
    Date of Patent: February 24, 2015
    Assignee: Asahi Glass Company, Limited
    Inventors: Hiroaki Inoue, Shuichiro Sugimoto
  • Patent number: 8946313
    Abstract: This invention relates to hybrid polymer polyols. These hybrid polymer polyols comprise the free-radical polymerization product of (A) a base polyol comprising (1) a polymer modified polyol selected from (a) dispersions of polyureas and/or polyhydrazodicarbonamides in a hydroxyl group containing compound and (b) polyisocyanate polyaddition polyols, and (2) optionally, a polyol having a functionality of 2 to 6 and an OH number of from 20 to 500; (B) optionally, a preformed stabilizer; and (C) one or more ethylenically unsaturated monomers, in the presence of (D) a free-radical polymerization initiator, and (E) optionally, a polymer control agent. The present invention also relates to a process for the preparation of these hybrid polymer polyols, foams prepared from these hybrid polymer polyols and to a process for the preparation of these foams.
    Type: Grant
    Filed: December 16, 2011
    Date of Patent: February 3, 2015
    Assignee: Bayer MaterialScience LLC
    Inventors: Rick L. Adkins, Brian L. Neal
  • Publication number: 20150018485
    Abstract: Disclosed herein are compositions and methods for increasing microcapsule dispersion in self-healing paint and coating applications, and more particularly for non-covalent functionalization of polymeric microcapsule shell walls for improved dispersion in polymeric material formulations. Some embodiments are methods of forming a microcapsule dispersion, the methods including providing a polymeric material capable of forming a plurality of microcapsules; initiating polymerization of the polymeric material under reaction conditions sufficient to permit formation of the plurality of microcapsules; and adding an ethoxy-functionalized dispersant to the polymeric material before formation of the plurality of microcapsules is complete, thereby forming the microcapsule dispersion.
    Type: Application
    Filed: July 11, 2014
    Publication date: January 15, 2015
    Inventors: Gerald O. Wilson, Subramanyam V. Kasisomayajula, Ryan T. Blanchette
  • Patent number: 8933168
    Abstract: There is provided a cyanoacrylate composition comprising: a cyanoacrylate; and a 2-substituted benzothiazole or a derivative thereof wherein the 2-substituent is an alkyl, an alkene, an alkylbenzyl, an alkylamino, an alkoxy, an alkylhydroxy, an ether, a sulfenamide, a thioalkyl or a thioalkoxy group, with the proviso that an amide portion of the sulfenamide does not have a tert butylamino or a morpholine group.
    Type: Grant
    Filed: April 20, 2011
    Date of Patent: January 13, 2015
    Assignee: Henkel IP & Holding GmbH
    Inventors: William Hally, Emer Ward, Patricia A. Hedderman, Deborah A. Moore, Dermot F. Heatley
  • Patent number: 8921482
    Abstract: To provide a water repellent composition which is capable of imparting sufficient water repellency and alcohol repellency to a hydrophobic substrate without significantly decreasing the antistatic property imparted to the hydrophobic substrate by an antistatic agent, and which presents a low environmental impact, its production method, a hydrophobic substrate treating agent composition and an article. A water repellent composition having a fluorinated copolymer having structural units based on a monomer (a) having a C1-6 polyfluoroalkyl group, structural units based on a monomer (b) having a C1-6 alkyl group and structural units based on a monomer (c) (halogenated olefin), and a medium, where the proportion of the structural units based on the monomer (a) is from 50 to 90 mass % of the structural units (100 mass %) based on all the monomers.
    Type: Grant
    Filed: February 11, 2013
    Date of Patent: December 30, 2014
    Assignee: Asahi Glass Company, Limited
    Inventors: Shin Yamane, Shuichiro Sugimoto
  • Patent number: 8901264
    Abstract: To provide a copolymer which can impart sufficient dynamic water repellency, after air-drying water repellency and friction durability to a surface of an article, and which has low impact on the environment, a method for producing the same, a water repellent composition and an article excellent in dynamic water repellency, after air-drying water repellency and friction durability.
    Type: Grant
    Filed: September 9, 2010
    Date of Patent: December 2, 2014
    Assignee: Asahi Glass Company, Limited
    Inventors: Kazunori Sugiyama, Toyomichi Shimada, Nobuyuki Otozawa, Yuuichi Oomori, Minako Shimada
  • Patent number: 8853337
    Abstract: A water- and oil-repellent agent composition having a lower environmental impact to obtain articles having higher water-repellent friction durability and improved texture. The invention also provides an article treated on the surface with the water- and oil-repellent agent composition. The water- and oil-repellent agent composition includes a first fluoropolymer having structural units based on a first monomer and structural units based on a second monomer; a second fluoropolymer (excluding the first fluoropolymer) having structural units based on a third monomer; and an aqueous medium. The first monomer: compound represented by (Z—Y)nX, where Z is a C1-6 polyfluoroalkyl group or the like, Y is a bivalent organic group or the like, n is 1 or 2, and X is a polymerizable unsaturated group. The second monomer: (meth)acrylate having a C18-30 alkyl group but not a polyfluoroalkyl group. The third monomer: a fluoroolefin.
    Type: Grant
    Filed: February 11, 2013
    Date of Patent: October 7, 2014
    Assignee: Asahi Glass Company, Limited
    Inventors: Takao Hirono, Yuuichi Oomori, Minako Shimada
  • Publication number: 20140221567
    Abstract: A method of forming a low gloss, high solids polyurea coating containing very low volatile organic compounds (VOC) in the coating composition. The low volatile content not only makes the coating environmentally friendly but allows it to be applied at variable thickness levels and over a wide variety of environmental conditions. The coating composition is comprised of an isocyanate reactive agent containing a secondary diamine, a polyisocyanate, a gloss reducing agent and a viscosity modifier. The gloss reducing agent is generally pre-mixed into an isocyanate reactive agent containing a secondary diamine and/or polyisocyanate containing the viscosity modifier before mixing the two components together to form a low gloss polyurea coating.
    Type: Application
    Filed: February 4, 2014
    Publication date: August 7, 2014
    Applicant: Air Products And Chemical, Inc.
    Inventors: Shafiq Nisarali Fazel, Jared Denis Bender
  • Patent number: 8796368
    Abstract: A water- and oil-repellent comprising an aqueous dispersion of a fluorine-containing copolymer including as a copolymerization unit (a) a perfluoroalkylalkyl (meth)acrylate represented by the general formula CnF2n+1CmH2mOCOCR?CH2 (wherein R represents hydrogen atom or methyl group; n represents 4, 5, or 6; and m represents 1, 2, 3, or 4), (b) benzyl (meth)acrylate, (c) a fluorine-free polymerizable monomer other than benzyl (meth)acrylate, and (d) a cross-linkable group-containing polymerizable monomer; and a blocked isocyanate added to the aqueous dispersion in a weight ratio of 0.05 to 3.0 to the weight of the solid content of the aqueous dispersion.
    Type: Grant
    Filed: August 8, 2008
    Date of Patent: August 5, 2014
    Assignee: Unimatec Co., Ltd.
    Inventors: Ji-Shan Jin, Sumiko Mouri, Katsuyuki Sato
  • Patent number: 8791218
    Abstract: To provide a water/oil repellent composition which can impart water/oil repellency to a surface of an article without having its texture deteriorated, and has excellent durability against washing and stability, a method for producing such a composition, and an article treated with such a water/oil repellent composition. A water/oil repellent composition which comprises a copolymer having polymerized units derived from monomer (a), polymerized units derived from monomer (b) and polymerized units derived from monomer (c). Here, monomer (a) is a compound represented by the formula: (Z—Y)nX; wherein Z is a C1-6 perfluoroalkyl group or the like; Y is a bivalent organic group or a single bond; n is 1 or 2; and X is a polymerizable unsaturated group; monomer (b) is a (meth)acrylate having no Rf group and having a C12-18 alkyl group; and monomer (c) is monomer (c1) having no Rf group and having a blocked isocyanate group or monomer (c2) having no Rf group and having at least two polymerizable unsaturated groups.
    Type: Grant
    Filed: October 28, 2009
    Date of Patent: July 29, 2014
    Assignee: Asahi Glass Company, Limited
    Inventors: Kazunori Sugiyama, Kyouichi Kaneko, Yuuichi Oomori
  • Patent number: 8779075
    Abstract: The invention relates to the use of aqueous solutions of nonionic surfactants as gel phase free emulsion systems for emulsion polymerization. The nonionic surfactants are chosen from the group (a) of the addition products from 1 to 40 mol ethylene and/or propylene oxide per mol of allyl alcohol, and (b) of the addition products from 1 to 40 mol ethylene and/or propylene oxide per mol of allyl alcohol, wherein the OH-group of said addition products is end-capped in the sense that it is substituted by a group OR, wherein R is an alkyl group with 1 to 20 C-atoms, which can be saturated or unsaturated, straight chained or branched.
    Type: Grant
    Filed: March 13, 2010
    Date of Patent: July 15, 2014
    Assignee: Cognis IP Management GmbH
    Inventors: Markus Scherer, Thomas Schliwka, Katharina Hömberg, Uwe Held, Thomas Mausberg, Ronald Klagge
  • Patent number: 8772405
    Abstract: A polymer polyol (I) is provided that is formed of a polyol (A), polymer particles (B) obtained by polymerization of an ethylenically unsaturated compound (b), and an active-hydrogen-containing compound (d) having an aromatic ring and having a number-average molecular weight of 150 to 2,000, wherein a content of (d) is 1 to 20% on the basis of a weight of (B). The polymer polyol of the present invention contains polymer particles having sufficiently small particle diameters, has a low viscosity, and has excellent handleability. A polyurethane resin obtained by using the polymer polyol of the present invention has excellent mechanical strengths such as elongation at break.
    Type: Grant
    Filed: September 25, 2008
    Date of Patent: July 8, 2014
    Assignee: Sanyo Chemical Industries, Ltd.
    Inventors: Takayuki Tsuji, Shigekuni Nakada, Yukiya Kobayashi, Katsuya Uchida
  • Patent number: 8729183
    Abstract: Aqueous emulsions of high viscosity organopolysiloxanes can be prepared having a very low content of cyclic siloxanes by condensing low molecular weight alkoxy-functional organopolysiloxanes in aqueous emulsion with an alkylphosphate emulsifier and at least one selected polyoxyethylene non-ionic surfactant.
    Type: Grant
    Filed: January 9, 2012
    Date of Patent: May 20, 2014
    Assignee: Wacker Chemie AG
    Inventors: Holger Rautschek, Gerhard Beer
  • Publication number: 20140130693
    Abstract: Disclosed are a resin composition for laser engraving, comprising (Component A) a resin that is a plastomer at 20° C. and contains no ethylenically unsaturated group, and (Component B) a crosslinking agent, a relief printing plate precursor for laser engraving and a process for producing the same using the resin composition, and a relief printing plate and a process for making the same using the resin composition.
    Type: Application
    Filed: January 22, 2014
    Publication date: May 15, 2014
    Applicant: FUJIFILM Corporation
    Inventor: Atsushi SUGASAKI
  • Patent number: 8703864
    Abstract: A water/oil repellent composition which comprises a copolymer having polymerized units derived from monomer (a) and polymerized units derived from monomer (b), wherein the proportion of the polymerized units derived from the monomer (b) is 30 to 80 mol % in the total of the polymerized units derived from the monomer (a) and the polymerized units derived from the monomer (b). Monomer (a) is a compound represented by the formula: (Z—Y)nX; wherein Z is a C1-6 perfluoroalkyl group or the like; Y is a bivalent organic group or the like; n is 1 or 2; and X is a polymerizable unsaturated group; and monomer (b) is a (meth)acrylate having no polyfluoroalkyl group and having an C20-30 alkyl group.
    Type: Grant
    Filed: September 30, 2009
    Date of Patent: April 22, 2014
    Assignee: Asahi Glass Company, Limited
    Inventors: Minako Shimada, Kazunori Sugiyama, Yuuichi Oomori
  • Patent number: 8637589
    Abstract: In one aspect, the invention relates to silicone prepolymer compositions comprising a silicone prepolymer and a solvent. A soluble silicone prepolymer can be provided having increased average silicon content, thereby attaining a desired oxygen permeability. A solvent can be provided with a desired balance between hydrophilicity and hydrophobicity by selection and modification of the solvent molecular structure, resulting in molded polymer films and articles that exhibit minimal or nonexistent eye irritation and exhibit highly transparent products. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.
    Type: Grant
    Filed: December 7, 2010
    Date of Patent: January 28, 2014
    Assignees: Johnson & Johnson Vision Care, Inc., Toray Industries
    Inventors: Kazuhiko Fujisawa, Mitsuru Yokota, Masataka Nakamura
  • Patent number: 8637613
    Abstract: The invention relates to highly transparent organofunctional silicone copolymers, being self-dispersible in water without emulsifiers or protective colloid, being obtained by radically initiated solution polymerization of a) one or more ethylenically unsaturated organomonomers, and b) one or more siliconmacromeres, characterized in that c) one or more water soluble comonomeres are copolymerized in an organic solvent or solvent mixture.
    Type: Grant
    Filed: August 7, 2007
    Date of Patent: January 28, 2014
    Assignee: Wacker Chemie AG
    Inventor: Abdulmajid Hashemzadeh
  • Patent number: 8580888
    Abstract: Two part cyanoacrylate/cationically curable adhesive systems are provided, which contain vinyl ethers.
    Type: Grant
    Filed: August 23, 2012
    Date of Patent: November 12, 2013
    Assignee: Henkel Ireland Limited
    Inventors: Raymond P. Tully, Barry N. Burns, Emer Ward, Mark Loane, Rachel M. Hersee
  • Publication number: 20130153830
    Abstract: Porous materials are fabricated using interpenetrating inorganic-organic composite gels. A mixture or precursor solution including an inorganic gel precursor, an organic polymer gel precursor, and a solvent is treated to form an inorganic wet gel including the organic polymer gel precursor and the solvent. The inorganic wet gel is then treated to form a composite wet gel including an organic polymer network in the body of the inorganic wet gel, producing an interpenetrating inorganic-organic composite gel. The composite wet gel is dried to form a composite material including the organic polymer network and an inorganic network component. The composite material can be treated further to form a porous composite material, a porous polymer or polymer composite, a porous metal oxide, and other porous materials.
    Type: Application
    Filed: August 3, 2011
    Publication date: June 20, 2013
    Inventors: Dong-Kyun Seo, Alex Volosin
  • Patent number: 8461251
    Abstract: A method for producing a fluoroolefin copolymer solution, gives the copolymer solution good storage stability and suppressed coloration. The method for producing a fluoroolefin copolymer solution includes subjecting at least one fluoroolefin and at least one monomer other than the fluoroolefin to a solution polymerization in an organic solvent in the presence of potassium carbonate and hydrotalcite.
    Type: Grant
    Filed: July 20, 2011
    Date of Patent: June 11, 2013
    Assignee: Asahi Glass Company, Limited
    Inventors: Yuji Hara, Kiyoshi Kasahara, Shou Masuda
  • Patent number: 8299170
    Abstract: The present invention discloses a reactivity-based self-stratifying coating composition. The coating composition can include a polyol, silsesquioxane, a polyester polyol, and a crosslinker that form a mixture within a solvent. The polyol can be selected from a fluorinated polyether, a fluoroethylene-alkyl vinyl ether and/or a combination thereof. The silsesquioxane can be an epoxy functional silsesquioxane having a formula of (R)6(C6H11O2)2(SiO1.5)8 where R can be selected from hydrogen, methyl, ethyl, propyl, butyl, pentyl, hexyl, cyclopentyl, cyclohexyl, benzyl, phenyl, and isomers thereof. In some instances, the epoxy functional silsesquioxane can be a di-epoxy silsesquioxane.
    Type: Grant
    Filed: October 6, 2010
    Date of Patent: October 30, 2012
    Assignees: Toyota Motor Engineering & Manufacturing North America, Inc., Eastern Michigan University
    Inventors: Cynthia G. Templeman, Jamil Baghdachi, Punthip Talapatcharoenkit
  • Patent number: 8278021
    Abstract: Disclosed is a method of producing a thin film transistor substrate having high light sensitivity, heat-resistance, impact resistance, and a photosensitive composition used by the same, the method including forming data wires on an insulating substrate, forming an organic insulating film on the data wires by applying a photosensitive composition comprising a terpolymer, where the terpolymer is derived from monomers of an unsaturated carboxylic acid, an unsaturated carboxylic acid anhydride, or a mixture thereof, an unsaturated epoxy group-containing compound, and an olefinic compound.
    Type: Grant
    Filed: July 10, 2008
    Date of Patent: October 2, 2012
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Hoon Kang, Jae-sung Kim, Yang-ho Jung, Hi-kuk Lee
  • Publication number: 20120157574
    Abstract: There may be provided a process for producing a polyimide siloxane solution composition having a further improved long-term viscosity stability; and a polyimide siloxane solution composition. In the process for producing the polyimide siloxane solution composition by polymerizing/imidizing a tetracarboxylic acid component and a diamine component consisting of (a) a diaminopolysiloxane, (b) a diamine having a polar group and (c) a diamine other than (a) and (b) in a solvent, the tetracarboxylic acid component and the diamine component excluding (b) the diamine having a polar group are polymerized/imidized to provide a reaction mixture solution, and then (b) the diamine having a polar group is added to the reaction mixture solution last, and the mixture is polymerized/imidized.
    Type: Application
    Filed: August 17, 2010
    Publication date: June 21, 2012
    Applicant: UBE INDUSTRIES, LTD.
    Inventors: Susumu Takasaki, Hiroo Yamashita, Selichirou Takabayashi, Tomoko Hayashida, Mitsuo Yamanaka, Takafumi Hirakawa
  • Publication number: 20120052257
    Abstract: An ink composition for inkjet recording including: a urethane oligomer or polymer that has at least one group selected from the group consisting of groups represented by following Formulae (1) to (3) at one or more side chains of the oligomer or polymer; and an organic solvent.
    Type: Application
    Filed: July 29, 2011
    Publication date: March 1, 2012
    Applicant: FUJIFILM CORPORATION
    Inventor: Hirokazu KYOTA
  • Publication number: 20120040179
    Abstract: The embodiments of the invention are directed to coatings and their uses. More particularly, the embodiments of the invention are directed to coating compositions that include silane-based precursors that are used to form coatings through a sol-gel process. The coatings so formed are characterized by anti-reflective, abrasion resistant, and anti-soiling properties. The coatings also have extended weatherability to heat, humidity, and protection against ambient corrosives. The coatings formed from the compositions described herein have wide application, including, for example, use as coatings on the outer glass of solar cells.
    Type: Application
    Filed: July 18, 2011
    Publication date: February 16, 2012
    Inventor: Bakul Champaklal Dave
  • Publication number: 20120027708
    Abstract: This invention relates to the polymerization of organopolysiloxanes to form organopolysiloxanes of increased molecular weight and to the organopolysiloxane compositions thus produced. The organopolysiloxane is in admixture with a molten wax during the polymerization, thereby forming a blend of the wax with an organopolysiloxane of increased molecular weight. After the polymerisation reaction is completed, the reaction product can be cooled below the solidification temperature of the wax, for example down to room temperature. This yield a paste-like solid blend which is a very intimate dispersion of wax in organopolysiloxane or vice versa. The dispersion is surprisingly stable.
    Type: Application
    Filed: March 30, 2010
    Publication date: February 2, 2012
    Inventors: Beatrice Durand, Giada Tonet, Annelise Girboux, Delphine Davio, Andreas Stammer
  • Publication number: 20120029131
    Abstract: The invention relates to the use of aqueous solutions of nonionic surfactants as gel phase free emulator systems for the emulsion polymerization, wherein said nonionic surfactants are chosen from the group (a) of the addition products from 1 to 40 mol ethylene and/or propylene oxide per mol of allyl alcohol, and (b) of the addition products from 1 to 40 mol ethylene and/or propylene oxide per mol of allyl alcohol, wherein the OH-group of said addition products is end-capped in the sense that it is substituted by a group OR, wherein R is an alkyl group with 1 to 20 C-atoms, which can be saturated or unsaturated, straight chained or branched.
    Type: Application
    Filed: March 13, 2010
    Publication date: February 2, 2012
    Applicant: Cognis IP Management GmbH
    Inventors: Markus Scherer, Thomas Schliwka, Katharina Hömberg, Uwe Held, Thomas Mausberg, Ronald Klagge
  • Patent number: 8067513
    Abstract: The present invention relates to the use of Styrenated Phenol Ethoxylates as surfactants in emulsion polymerization. The present invention further relates to the use of both anionic and nonionic Styrenated Phenol Ethoxylates in emulsion polymerization. Latexes with small average particle and narrow particle size distributions are obtained. Prepared latexes also have low coagulum levels and exhibit excellent mechanical and chemical stability.
    Type: Grant
    Filed: August 11, 2008
    Date of Patent: November 29, 2011
    Assignee: Ethox Chemicals LLC
    Inventors: Lawrence C. Davis, Edward R. Godwin, Charles V. Hinton, James T. Tanner
  • Publication number: 20110275753
    Abstract: To provide a method for producing a fluoroolefin copolymer solution, whereby good storage stability of the copolymer solution is obtainable, and coloration of the solution can be suppressed, and a method for producing a coating composition. A method for producing a fluoroolefin copolymer solution, which comprises subjecting at least one fluoroolefin (a) and at least one monomer (b) other than the fluoroolefin (a) to a solution polymerization in an organic solvent in the presence of potassium carbonate and hydrotalcite.
    Type: Application
    Filed: July 20, 2011
    Publication date: November 10, 2011
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Yuji HARA, Kiyoshi Kasahara, Shou Masuda
  • Publication number: 20110272183
    Abstract: An object of the invention is to provide carboxyl group-containing polyurethanes that have small curing warpage and can give cured products having excellent electrical insulating properties and flexibility, curable compositions that contain the carboxyl group-containing polyurethane and can give cured products having good electrical insulating properties, cured products obtained from the compositions, flexible circuit boards covered with the cured products, and processes for manufacturing flexible circuit boards. The carboxyl group-containing polyurethane is obtainable from materials including a (poly)carbonate polyol (a), a polyisocyanate (b) and a carboxyl group-containing polyol (c). The (poly) carbonate polyol includes an organic residue derived from a dimer diol and an organic residue derived from a polyol having a C10-20 alicyclic structure.
    Type: Application
    Filed: January 20, 2010
    Publication date: November 10, 2011
    Applicant: SHOWA DENKO K.K.
    Inventors: Kazuhiko Ooga, Ritsuko Azuma, Atsushi Umino
  • Publication number: 20110240541
    Abstract: A monolith for liquid chromatography is disclosed that involves a reaction product of; a (1) crosslinker having at least three adjacent groups, selected from ethylene oxide, polyethylene oxide, and mixtures thereof, and two or more pendent vinyl groups, and (2) monomer having the formula, CH2?CR—Y—Z, where R is H or CH3, where Z is a functional group selected to impart a desired interaction property to the monolith, and where Y is nothing, or any group that will not materially affect or compete with the function of the functional group (Z) in the monolith, or the reactivity of vinyl groups in the crosslinker or monomer.
    Type: Application
    Filed: April 6, 2010
    Publication date: October 6, 2011
    Inventors: Binghe Gu, Milton L. Lee
  • Publication number: 20110196092
    Abstract: There is provided a cyanoacrylate composition comprising: a cyanoacrylate; and a 2-substituted benzothiazole or a derivative thereof wherein the 2-substituent is an alkyl, an alkene, an alkylbenzyl, an alkylamino, an alkoxy, an alkylhydroxy, an ether, a sulfenamide, a thioalkyl or a thioalkoxy group, with the proviso that an amide portion of the sulfenamide does not have a tert butylamino or a morpholine group.
    Type: Application
    Filed: April 20, 2011
    Publication date: August 11, 2011
    Applicant: Loctite (R&D) Limited
    Inventors: William Hally, Emer Ward, Patricia A. Hedderman, Deborah A. Moore, Dermot F. Heatley
  • Patent number: 7893118
    Abstract: Solid and liquid compositions containing particles of highly fluorinated ion-exchange polymer having sulfonate functional groups with an ion exchange ratio of less than about 33. The compositions contain at least about 25% by weight of polymer particles having a particle size of about 2 nm to about 30 nm.
    Type: Grant
    Filed: March 22, 2010
    Date of Patent: February 22, 2011
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Dennis Edward Curtin, Edward George Howard, Jr.
  • Patent number: 7884151
    Abstract: The manufacturing process of a material of nanocomposites of the resin includes providing a nano-clay platelets liquid; adding a modification agent into the nano-clay platelets liquid, then stirring in a first time in a first temperature for making a cake product; taking the cake product heated in a second temperature and then crumbling the cake product for making a first powder; moving the water out of the first powder for making a second powder; adding a resin into the second powder, then stirring and baking for making the material of nanocomposites of the resin.
    Type: Grant
    Filed: August 8, 2008
    Date of Patent: February 8, 2011
    Assignee: CPC Corporation, Taiwan
    Inventors: Jiang-Jen Lin, Chih-Wei Chiu, Ing-Nan Jan
  • Patent number: 7847001
    Abstract: A fluoropolymer liquid composition including a fluoropolymer liquid (A) which includes a liquid medium and a crosslinkable functional group-containing crosslinkable fluoropolymer. The fluoropolymer liquid (A) is a fluoropolymer liquid dispersion (AD) having, dispersed in a liquid dispersion medium, particles of a crosslinkable fluoropolymer (PD) containing acid/acid salt groups or organic groups capable of undergoing hydrolysis and thus being converted to carboxyl groups, or a fluoropolymer solution (AS) having, dissolved in a fluorosolvent or an alcohol/water mixed solvent, a crosslinkable fluoropolymer (PS) containing acid/acid salt groups or acid/acid salt groups precursors. Further, the crosslinkable functional group is a cyano group, —I or —Br.
    Type: Grant
    Filed: December 2, 2009
    Date of Patent: December 7, 2010
    Assignee: Daikin Industries, Ltd.
    Inventors: Takuya Arase, Masayoshi Tatemoto
  • Patent number: 7714028
    Abstract: Solid and liquid compositions containing particles of highly fluorinated ion-exchange polymer having sulfonate functional groups with an ion exchange ratio of less than about 33. The compositions contain at least about 25% by weight of polymer particles having a particle size of about 2 nm to about 30 nm.
    Type: Grant
    Filed: February 27, 2008
    Date of Patent: May 11, 2010
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Dennis Edward Curtin, Edward George Howard
  • Publication number: 20100087597
    Abstract: To provide a water/oil repellent composition which can give water/oil repellency to a surface of an article and has excellent durability (wash durability and heavy-rain durability), a method for producing such a composition, and an article which has water/oil repellency and is less susceptible to deterioration of water/oil repellency when it is washed or in heavy rain. A water/oil repellent composition which comprises a copolymer having polymerized units derived from monomer (a) and polymerized units derived from monomer (b), wherein the proportion of the polymerized units derived from the monomer (b) is 30 to 80 mol % in the total of the polymerized units derived from the monomer (a) and the polymerized units derived from the monomer (b).
    Type: Application
    Filed: September 30, 2009
    Publication date: April 8, 2010
    Applicant: ASAHI GLASS COMPANY., LTD.
    Inventors: Minako Shimada, Kazunori Sugiyama, Yuuichi Oomori
  • Patent number: 7691934
    Abstract: The invention is directed to a method of making ultra high molecular weight diallyldialkyl ammonium salt homopolymers, compositions thereof and use of compositions as a fixative in papermaking.
    Type: Grant
    Filed: October 19, 2006
    Date of Patent: April 6, 2010
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Zhiqiang Song, George William Schriver, Holger Reinicke
  • Publication number: 20100022697
    Abstract: The invention relates to a process for microencapsulation of phase change materials based on free radicals polymerization comprising: a) the preparation of i) a solution with, at least, a hydrophilic liquid and a stabilizer (continuous phase) and ii) a solution with, at least, a phase change material, a free radical initiator and a polymerizable material (discontinuous phase); b) the preparation of an emulsion by dispersing the discontinuous phase in the continuous phase under vigorous stirring; and c) the polymerization of monomers until the phase change material becomes microencapsulated. This process is simple and effective and avoids the use of hazardous compounds. The invention also relates to microcapsules obtainable by said process and to the use thereof in the thermal protection and storage of heat.
    Type: Application
    Filed: March 23, 2006
    Publication date: January 28, 2010
    Applicant: UNVERSIDAD DE CASTILLA-LA MANCHA
    Inventors: Juan Francisco Rodriguez Romero, Maria Luz Sanchez Silva, Paula Sanchez Paredes, Antonio De Lucas Martinez, Martha Liliana Torres Barreto
  • Patent number: 7541407
    Abstract: A method for incorporating a UV light absorbing compound into a polyester prepared using direct esterification of reactants selected from a dicarboxylic acid and a diol. The method comprises reacting the reactants in an esterifying reactor under conditions sufficient to form an esterified product including at least one of an ester, an oligomer, or mixture having an ester and a mixture of low molecular weight polyester; polymerizing the esterified product in a polycondensation reactor to form a polyester; and adding the UV absorbing compound to the esterified products when at least 50% of the carboxy groups initially present in the reactants have been esterified to obtain a yield of UV absorbing compound incorporated into the polyester of greater than 25%. Articles utilizing the UV protected polyester prepared by the method of the invention are additionally disclosed.
    Type: Grant
    Filed: May 27, 2004
    Date of Patent: June 2, 2009
    Assignee: Eastman Chemical Company
    Inventors: Perry Michael Murdaugh, Sr., Earl Edmondson Howell, Jr., Cory Lee Wells, Max Allen Weaver, Jason Clay Pearson
  • Patent number: 7514526
    Abstract: The present invention discloses a process for the preparation of a stabilized polyester that is low in the generation of aldehydes which comprises reacting one or more diacids with one or more diols in an esterification process, and/or one or more diesters with one or more diols in a transesterification process in the presence of an effective amount of a stabilizer selected from the group consisting of (a) a polyhydric alcohol which is for example poly(ethylene-co-vinyl alcohol), poly(styrene-co-allyl alcohol), maltitol, isomalt, sorbitol, xylitol, sucrose, mucic acid dibutylester, mucic acid di(phenyl-1-ethyl)ester, pentaerythritol or dipentaerythritol; (b) a compound of the formula II which is for example di-iso-octyl-phosphinic acid; (c) a sterically hindered amine which is for example Tinuvin 123 or Tinuvin 622; (d) a polyacrylamide, an anionic acrylic polymer or a cationic acrylamide copolymer; or (e) a hydroxylamine and/or a nitrone.
    Type: Grant
    Filed: February 7, 2006
    Date of Patent: April 7, 2009
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Dirk Simon, Dario Lazzari, Stephen Mark Andrews, Heinz Herbst
  • Publication number: 20080306210
    Abstract: The invention relates to new compositions having good binder properties, wetting properties and dispersing properties not only for virtually foam-free aqueous pigment preparations but also for solvent-borne and solvent-free pigment preparations with very good heat stability and weathering stability.
    Type: Application
    Filed: November 6, 2006
    Publication date: December 11, 2008
    Inventors: Patrick Glockner, Evelyn Albrecht, Andreas Wenning
  • Publication number: 20080214732
    Abstract: Aromatic sulfonimide ionene polymers useful as membranes in electrochemical cells are prepared.
    Type: Application
    Filed: October 1, 2007
    Publication date: September 4, 2008
    Inventor: Mark F. TEASLEY