Aromatic Monomer Patents (Class 524/824)
  • Patent number: 11913273
    Abstract: Motorized door assemblies having a door pivoting about a pivot axis extending across opposing jambs. In one aspect, the assembly includes a motor assembly having a motor, drive gears, slip clutch, and driven shaft connected to the door to pivot it about the pivot axis. The slip clutch includes a clutch plate slideable along the driven shaft, a drive plate driven by the motor via the drive gears, and a clutch spring urging the clutch plate into engagement with the drive plate, where the clutch and drive plates have profiled and counter-profiled faces. In another aspect, a break beam emitter and receiver are mounted to respective ones of the opposing jambs along a beam axis extending parallel to the pivot axis and proximate to an edge of the door opposite the pivot axis. Interruption of a light beam projected therebetween alters operation of a motor assembly.
    Type: Grant
    Filed: May 15, 2018
    Date of Patent: February 27, 2024
    Assignee: APEX INDUSTRIAL TECHNOLOGIES LLC
    Inventors: Craig Whitaker, Edward Leonard Weaver, II, Scott A. Zieker, Charles Eldon Warner, Ronald G. Knollman
  • Patent number: 11597834
    Abstract: Disclosed herein are a biodegradable polymer microparticle for a filler comprising a core and a shell, wherein the core contains secondary particles including aggregates of a plurality of primary particles, the shell has a raspberry shaped structure, an average particle diameter (D50) of the biodegradable polymer microparticle ranges from 20 to 200 ?m, a manufacturing method thereof, a freeze-dried body including the same, and filler injection including the same.
    Type: Grant
    Filed: January 21, 2022
    Date of Patent: March 7, 2023
    Assignee: ULTRA V CO., LTD.
    Inventors: Cheong Cheon Lee, Lia Priscilla, Min Seok Kwak, Jung Woo Han, Jung Ryul Ham, Han Jin Kwon
  • Publication number: 20150133604
    Abstract: Disclosed are latex polymers and an aqueous coating compositions having excellent freeze-thaw stability, open time, stain resistance, low temperature film formation, foam resistance, block resistance, adhesion, water sensitivity and a low-VOC content. The latex polymers and aqueous coating compositions include at least one latex polymer derived from at least one monomer copolymerized or blended with an alkoxylated compound, for example an alkoxylated tristyrylphenol or an alkoxylated tributyiphenol. Also provided is an aqueous coating composition including at least one latex polymer, at least one pigment, water and at least one freeze-thaw additive. Typically, the freeze-thaw additive in an amount greater than about 1.3% by weight of the polymer, typically in an amount greater than about 2% by weight of the polymer, in an amount greater than about 4% by weight of the polymer, in an amount greater than about 7.
    Type: Application
    Filed: December 1, 2014
    Publication date: May 14, 2015
    Inventors: Zhengang ZONG, Yi-Zhong LI, Jose RUIZ
  • Publication number: 20140249270
    Abstract: Latex emulsions are disclosed which can be used in the formation of coating compositions that are not water sensitive, have good blush resistance and retortability. In some embodiments, the coating compositions are used to coat substrates such as cans and packaging materials for the storage of food and beverages. Coating compositions can be prepared by mixing an ethylenically unsaturated monomer component and a stabilizer comprising a strong acid, in a carrier to form a monomer emulsion, reacting the monomer emulsion with an initiator to form the latex emulsion, and reacting the latex emulsion with a neutralizer. Methods of coating substrates with the coating compositions, and substrates coated with the coating compositions are also disclosed.
    Type: Application
    Filed: May 15, 2014
    Publication date: September 4, 2014
    Applicant: AKZO NOBEL COATINGS INTERNATIONAL B.V.
    Inventors: Jude Thomas Rademacher, Gary Charles Pompignano, Willy P. Kulhanek
  • Publication number: 20140228477
    Abstract: A process of preparing a water-based emulsion includes adding a first monomer feed to a reaction vessel in the presence of a first initiator and water to form an acid-functional polymer; neutralizing the acid-functional polymer to form a particulate polymer; and adding a second monomer feed to the reaction vessel in the presence of a second initiator to form an agglomerated polymer; where the process is a one-pot process. The first monomer feed includes a unbranched (meth)acrylate monomer, a (meth)acrylic acid monomer, a branched (meth)acrylate, and a styrenic monomer; the second monomer feed includes a hydrophobic monomer; the water-based emulsion includes the agglomerated polymer; the agglomerated polymer includes the particulate polymer; and the agglomerated polymer having an aggregated drupelet morphology. The agglomerated polymers may be used in high opacity emulsions.
    Type: Application
    Filed: August 29, 2012
    Publication date: August 14, 2014
    Inventors: Sarav Bharat Jhaveri, Chien L. Hsu
  • Publication number: 20140213691
    Abstract: A process of preparing a water-based emulsion includes adding a first monomer feed to a reaction vessel in the presence of a first initiator and water to form an acid-functional polymer; neutralizing the acid-functional polymer to form a particulate polymer; and adding a second monomer feed to the reaction vessel in the presence of a second initiator to form an agglomerated polymer; where the process is a one-pot process. The first monomer feed includes a (meth)acrylate monomer, a (meth)acrylic acid monomer, and a styrenic monomer; the second monomer feed includes a hydrophobic monomer; the water-based emulsion includes the agglomerated polymer; the agglomerated polymer includes the particulate polymer; and the agglomerated polymer having an aggregated drupelet morphology. The agglomerated polymers may be used in high opacity emulsions.
    Type: Application
    Filed: August 29, 2012
    Publication date: July 31, 2014
    Applicant: BASF SE
    Inventor: Sarav Bharat Jhaveri
  • Patent number: 8765860
    Abstract: An injection molding composition, having a small fluctuation characteristic and a better characteristic, is provided. The above composition is the injection molding composition comprising a ferrite powder which is a collection of ferrite particles, a first binder and a second binder. A weight and a specific surface area of the ferrite powders are represented by Wp and S, and a weight and a density of the first binder and the second binder is represented by Wb1, Wb2, and Db1, Db2. A hypothetical thickness Tb1 of the first binder is 2.0 to 15.0, and a hypothetical thickness Tb2 of the second binder is 16.5 to 32.0. In the composition, it is preferable that coated ferrite particles coating the outer circumference of the ferrite particles with the first binder and the second binder exist.
    Type: Grant
    Filed: August 27, 2012
    Date of Patent: July 1, 2014
    Assignee: TDK Corporation
    Inventors: Naoto Tsukamoto, Tomohiko Aida, Shinichi Sakano, Yoshihiko Minachi, Masashi Gotoh, Minao Himeno
  • Patent number: 8562850
    Abstract: The present invention relates to an emulsion for vibration damping materials, including an emulsion obtainable by emulsion polymerization of a monomer component, wherein the emulsion is obtainable by emulsion polymerization using an anionic emulsifier and/or a reactive emulsifier, and emulsion particles have an average particle diameter of 100 to 450 nm, and an emulsion for vibration damping materials, comprising acrylic emulsion particles each having a core part and a shell part, wherein the acrylic emulsion particles are obtainable by polymerizing a monomer component including a monomer having a Q value of 0.6 to 1.4 and an e value of ?0.4 to ?1.2.
    Type: Grant
    Filed: March 28, 2008
    Date of Patent: October 22, 2013
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Yukihiro Miyawaki, Kazutaka Otsuki, Dai Nagaishi, Takahiro Miwa
  • Publication number: 20110288232
    Abstract: Latex emulsions are disclosed which can be used in the formation of coating compositions that are not water sensitive, have good blush resistance and retortability. In some embodiments, the coating compositions are used to coat substrates such as cans and packaging materials for the storage of food and beverages. Coating compositions can be prepared by mixing an ethylenically unsaturated monomer component and a stabilizer comprising a strong acid, in a carrier to form a monomer emulsion, reacting the monomer emulsion with an initiator to form the latex emulsion, and reacting the latex emulsion with a neutralizer. Methods of coating substrates with the coating compositions, and substrates coated with the coating compositions are also disclosed.
    Type: Application
    Filed: February 22, 2010
    Publication date: November 24, 2011
    Applicant: Akzo Nobel Coatings International B.V.
    Inventors: Jude Thomas Rademacher, Gary Charles Pompignano, Willy P Kulhanek
  • Patent number: 7989544
    Abstract: Polymer capsules from amphiphilic graft copolymers comprising reactive, hydrophobic polyolefin backbones, and hydrophilic poly(ethylene glycol) (PEG) grafts are produced by self-assembly of the polymers at the oil-water interface, and crosslinking the assembly with bis-cyclooctene PEG derivatives in conjunction with ring-open metathesis polymerization catalysts. The use of the graft copolymer architecture in capsule synthesis provides significant opportunities to tune both the surface properties, in terms of recognition, and the membrane properties, in terms of mechanical strength, encapsulation, and release.
    Type: Grant
    Filed: December 13, 2010
    Date of Patent: August 2, 2011
    Assignee: University of Massachusetts
    Inventors: Todd S. Emrick, Kurt Breitenkamp
  • Publication number: 20110152052
    Abstract: Described is a recloseable pack having a cold-sealed layer of adhesive which is recloseable after the pack has been opened, the layer of adhesive comprising an emulsion polymer composed to an extent of at least 60% by weight of principal monomers selected from the group consisting of C1 to C20 alkyl (meth)acrylates, vinyl esters of carboxylic acids comprising up to 20 C atoms, vinylaromatics having up to 20 C atoms, ethylenically unsaturated nitriles, vinyl halides, vinyl ethers of alcohols comprising 1 to 10 C atoms, aliphatic hydrocarbons having 2 to 8 C atoms and one or two double bonds, and mixtures of these monomers, the emulsion polymer being preparable by emulsion polymerization of free-radically polymerizable monomers in the presence of at least one protective colloid. Also described are aqueous polymer dispersions suitable for producing the pack of the invention, and polymer films coated with the polymer dispersions.
    Type: Application
    Filed: December 15, 2010
    Publication date: June 23, 2011
    Applicant: BASF SE
    Inventors: Karl-Heinz SCHUMACHER, Florian Büsch, Dieter Urban, Cornelis Petrus Beyers
  • Patent number: 7851543
    Abstract: Polymer capsules from amphiphilic graft copolymers comprising reactive, hydrophobic polyolefin backbones, and hydrophilic poly(ethylene glycol) (PEG) grafts are produced by self-assembly of the polymers at the oil-water interface, and crosslinking the assembly with bis-cyclooctene PEG derivatives in conjunction with ring-open metathesis polymerization catalysts. The use of the graft copolymer architecture in capsule synthesis provides significant opportunities to tune both the surface properties, in terms of recognition, and the membrane properties, in terms of mechanical strength, encapsulation, and release.
    Type: Grant
    Filed: October 6, 2009
    Date of Patent: December 14, 2010
    Assignee: University of Massachusetts
    Inventors: Todd S. Emrick, Kurt Breitenkamp
  • Patent number: 7713674
    Abstract: An emulsion polymerization process comprising polymerizing monomer in an emulsion in a reaction vessel at a first temperature to form a resin; cooling the reaction vessel to a second temperature that is above the softening point of the resin yet below the temperature required for significant depolymerization reaction to occur; and adding water to the cooled reaction vessel in an amount sufficient to effect phase inversion with mixing for a sufficient time to form an aqueous latex emulsion in the absence of a surfactant.
    Type: Grant
    Filed: September 9, 2005
    Date of Patent: May 11, 2010
    Assignee: Xerox Corporation
    Inventors: Allan Kwok-Wai Chen, Milan Maric, Tie Hwee Ng, George Liebermann, Enno Eric Agur, Hadi Khan Mahabadi
  • Patent number: 7598313
    Abstract: Polymer capsules from amphiphilic graft copolymers comprising reactive, hydrophobic polyolefin backbones, and hydrophilic poly(ethylene glycol) (PEG) grafts are produced by self-assembly of the polymers at the oil-water interface, and crosslinking the assembly with bis-cyclooctene PEG derivatives in conjunction with ring-open metathesis polymerization catalysts. The use of the graft copolymer architecture in capsule synthesis provides significant opportunities to tune both the surface properties, in terms of recognition, and the membrane properties, in terms of mechanical strength, encapsulation, and release.
    Type: Grant
    Filed: September 3, 2004
    Date of Patent: October 6, 2009
    Assignee: University of Massachusetts
    Inventors: Todd S. Emrick, Kurt Breitenkamp
  • Publication number: 20090188054
    Abstract: Aqueous alkenylsuccinic anhydride-containing polymer dispersions which are obtainable by miniemulsion polymerization of hydrophobic monoethylenically unsaturated monomers in the presence of alkenylsuccinic anhydrides, processes for the preparation of such polymer dispersions by polymerizing hydrophobic monomers by a miniemulsion polymerization method in the presence of at least one alkenylsuccinic anhydride and, if appropriate, an alkyldiketene, and use of the resulting aqueous alkenylsuccinic anhydride-containing polymer dispersions as engine and surface sizes for paper and for imparting water repellency to leather, natural and/or synthetic fibers and textiles.
    Type: Application
    Filed: January 14, 2005
    Publication date: July 30, 2009
    Applicant: BASF Aktiengesellschaft
    Inventors: Rainer Dyllick-Brenzinger, Reinhold J. Leyrer, Andreas Brockmeyer, Markus Schmid, Roland Ettl
  • Patent number: 7232860
    Abstract: An aqueous binder dispersion that includes at least one copolymer (P) containing carboxylic acid and/or carboxylate groups. The copolymer (P) includes structural units of carboxyl-free (meth)acrylic esters with a cycloaliphatic structure, and at least 25 mol % of the carboxylic acid groups of the copolymer (P) in the dispersion being present in triethanolamine-neutralized form. The aqueous binder can be used in aqueous coating materials, which can be used to coat a substrate.
    Type: Grant
    Filed: August 13, 2003
    Date of Patent: June 19, 2007
    Assignee: Bayer MaterialScience AG
    Inventors: Martin Melchiors, Ulrich Freudenberg, Robert Reyer, Raul Pires, Sandra Grosskopf
  • Patent number: 7199185
    Abstract: Reactive polymeric surfactants are disclosed, and their use in processes for preparation of microcapsules, and in stabilising emulsions. The surfactants are random graft polymers or block copolymers which contain both hydrophobic and hydrophilic units and in which the hydrophobic unit includes a hydrophilic cross-linking unit which reacts with (a) a wall forming ingredient in a microencapsulation process, or (b) an ingredient in the disperse phase of an emulsion.
    Type: Grant
    Filed: June 10, 2002
    Date of Patent: April 3, 2007
    Assignee: Syngenta Limited
    Inventors: Alexander Mark Heming, Patrick Joseph Mulqueen, Herbert Benson Scher, Ian Malcolm Shirley
  • Patent number: 7138160
    Abstract: The use, for the manufacture of paper coating colors, of a copolymer water-soluble in a neutral or alkaline medium as an agent for simultaneously adjusting the water retention of the coating colors and the Brookfield viscosity of the said coating colors; a water-retention agent comprising the copolymer; and coating colors and the coated paper and cardboard thus obtained.
    Type: Grant
    Filed: July 10, 2000
    Date of Patent: November 21, 2006
    Assignee: Coatex S.A.S.
    Inventors: Francois Dupont, Henri Grondin, Georges Ravet, Jean-Marc Suau
  • Patent number: 6884840
    Abstract: A process for preparing hot-melt pressure-sensitive adhesives from aqueous dispersions based on polyacrylate, and pressure-sensitively adhesive articles produced therefrom, which comprises producing highly concentrated aqueous dispersions with polymer contents between 68% by weight and 87% by weight of gel-free, molecularly-dispersely meltable polymer particles with an at least bimodal size distribution in size ranges between 0.5 ?m and 1000 ?m Ø.
    Type: Grant
    Filed: March 22, 2001
    Date of Patent: April 26, 2005
    Assignee: tesa AG
    Inventors: Peter Gleichenhagen, Annemarie Müller
  • Patent number: 6844385
    Abstract: A latex for dip forming which comprises a copolymer prepared by polymerizing 10 to 90% by weight of a conjugated diene monomer, 0.1 to 20% by weight of an ethylenically unsaturated acid monomer and 10 to 89.9% by weight of other ethylenically unsaturated monomer or monomers copolymerizable therewith, wherein the sum of the amount of acid groups bonded to or adsorbed on the surface of the copolymer constituting the latex and the amount of acid groups present in the aqueous phase of the copolymer latex is in the range of 0.1 to 2 meq. in terms of hydrochloric acid, per gram of the copolymer. This latex is dip-formed to give a dip-formed article having no fear of development of a protein allergy, and exhibiting a soft feeling and a high mechanical strength.
    Type: Grant
    Filed: June 26, 2000
    Date of Patent: January 18, 2005
    Assignee: Zeon Corporation
    Inventors: Katuo Hagiwara, Hisanori Ota
  • Patent number: 6790908
    Abstract: The invention relates to a block copolymer and more especially to a thermoplastic elastomer block copolymer. The block copolymer is a diblock (block A)-(bloc B) copolymer, a triblock (block A)-(block B)-(block A), or a triblock (block A)-(block B)-(block C) copolymer, wherein block A is a stiff block, block B is a soft block, and block C is a stiff block. Block A or Block B comprises repetitive units deriving from segregation monomers.
    Type: Grant
    Filed: May 9, 2002
    Date of Patent: September 14, 2004
    Assignee: Rhodia Inc.
    Inventors: Denis Bendejacq, Mathieu Joanicot, Gilda Lizarraga, Virginie Ponsinet
  • Publication number: 20040096685
    Abstract: The present invention relates to pressure sensitive adhesives based on aqueous latex emulsions processes for their preparation and laminates prepared there from. The pressure sensitive adhesives exhibit excellent adhesion in hot water environments and resistance to water-whitening.
    Type: Application
    Filed: May 13, 2003
    Publication date: May 20, 2004
    Inventors: Raymond Scoot Harvey, Harvey Joseph Richards, Corlyss J. Richards
  • Patent number: 6716912
    Abstract: The present invention comprises a polymeric binder for water-resistant ink jet inks, wherein the binder has an acid component in the range from about 1 to about 10 wt. % of the polymer, a glass transition temperature in the range from about −20° C. to about 25° C., and an average particle diameter in the range from about 250 to about 400 nm and a particle size distribution such that essentially all the particles have a diameter in the range from 130 to 450 nm. The binder comprises monomers selected from the group consisting of acrylates, methacrylates, styrene, substituted styrene, fluoromethacrylates, vinyl acrylates, vinyl acetates, acrylamides, substituted acrylamides, methacrylamides, substituted methacrylamides, or combinations thereof.
    Type: Grant
    Filed: November 30, 2000
    Date of Patent: April 6, 2004
    Assignee: Rohm and Haas Company
    Inventors: Michael Bennett Freeman, Eric Jon Langenmayr, Thomas Glenn Madle
  • Patent number: 6710128
    Abstract: A process is provided to produce an aqueous composition. The process comprises shearing a mixture to produce a mini-emulsion and polymerizing said mini-emulsion in the presence of an initiator to produce the aqueous composition; wherein said mixture comprises at least one tackifier, at least one ethylenically unsaturated monomer, at least one surfactant, and water. The aqueous composition can be utilized to produced various articles including, but not limited to, adhesives, coatings, and laminates.
    Type: Grant
    Filed: December 13, 2002
    Date of Patent: March 23, 2004
    Assignee: Eastman Chemical Company
    Inventors: Bradley James Helmer, Glenn Lewis Shoaf
  • Patent number: 6683129
    Abstract: This invention relates to aqueous emulsions comprising a water-dispersible copolymer which is non-dispersible in aqueous solutions containing 0.5% or more of an inorganic salt, comprising acidic ethylenically unsaturated monomers and ethylenically unsaturated monomers. The acidic ethylenically unsaturated monomers and the ethylenically unsaturated monomers are defined herein. The present invention also pertains to emulsion polymerization methods for making the aqueous emulsions with or without a surfactant.
    Type: Grant
    Filed: March 31, 2000
    Date of Patent: January 27, 2004
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventor: Michael W. Eknoian
  • Patent number: 6683121
    Abstract: A pigment dispersant including 80-97% by weight, based on the weight of thepigment dispersant, of a first polymer comprising as copolymerized units 15-75% by weight, based on the first polymer weight, ethylenically unsaturated carboxylic acid-functional monomer, the polymer having a Mw from 4,000 to 16,000, and the polymer having a Tg greater than 70° C.; and 3-20% by weight, based on the weight of the pigment dispersant, of a poly(ethylene oxide/propylene oxide) block second polymer having an Mw from 3,000 to 20,000 and an HLB value of 16 to 32 is provided. And the invention relates to a method for dispersing a pigment in an aqueous medium using the pigment dispersant, an aqueous pigment dispersion including the pigment dispersant, and an aqueous ink including the pigment dispersion.
    Type: Grant
    Filed: November 20, 2001
    Date of Patent: January 27, 2004
    Assignee: Rohm and Haas Company
    Inventors: Shang-Jaw Chiou, Scott Lind Egolf, Miao-Hsun Sheng
  • Patent number: 6656983
    Abstract: The invention provides mixed aromatic vinyl-1,3-diene polymers stabilized by a protective colloid and present in the form of aqueous polymer dispersions or polymer powders redispersible in water as adhesives for porous substrates. The polymer dispersions and the polymer powders are obtained by emulsion polymerization of a mixture containing: a) 20 to 80 percent by weight of one or more vinylaromatics; b) 19.9 to 79.9 percent by weight of one or more 1,3-dienes; c) 0.1 to 15 percent by weight of one or more comonomers from the group consisting of N-methylolacrylamide, N-methylolmethacrylamide and the N-(alkoxymethyl)-acrylamides and N-(alkoxymethyl)-methacrylamides with a C1 to C6-alkyl radical. The sum of the above percentages adds up to 100% by weight. Emulsion polymerization is carried out in the presence of one or more protective colloids and without emulsifiers, optionally followed by drying of the resulting aqueous polymer dispersion.
    Type: Grant
    Filed: August 1, 2001
    Date of Patent: December 2, 2003
    Assignee: Wacker-Chemie GmbH
    Inventors: Theo Mayer, Thomas Kohler, Reinhard Harzschel, Hans-Peter Weitzel, Bernd Schilling
  • Patent number: 6593421
    Abstract: An aqueous composition containing from 1 to 60% by weight of a polymer A) built up from a) from 10 to 50% by weight of a vinylaromatic having up to 20 carbon atoms, b) from 45 to 75% by weight of a nonaromatic hydrocarbon having two conjugated double bonds, c) from 0 to 20% by weight of a water-soluble monomer having a water solubility of at least 100 g per liter of water under standard conditions (21° C. and 1 bar), the water-soluble monomer containing no acid group or acid anhydride group, d) from 0.1 to 4.5% by weight of a monomer containing at least one acid group or acid anhydride group, e) from 0 to 30% by weight of a monomer other than a) to d), and from 40 to 99% by weight of a filler B), the weight data for A) and B) being based on the sum of A) and B).
    Type: Grant
    Filed: October 22, 2001
    Date of Patent: July 15, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: David Christie, Joachim Pakusch, Eckehardt Wistuba, Horst Seibert, Peter Fickeisen
  • Patent number: 6590031
    Abstract: The present invention relates to pressure sensitive adhesives based on aqueous latex emulsions processes for their preparation and laminates the prepared there from. The pressure sensitive adhesives exhibit excellent adhesion in hot water environments and resistance to water-whitening.
    Type: Grant
    Filed: November 13, 2001
    Date of Patent: July 8, 2003
    Assignee: Ashland Inc.
    Inventors: Raymond Scott Harvey, Harvey J. Richards
  • Patent number: 6579947
    Abstract: The invention relates to a hydraulic fracturing fluid comprising an aqueous liquid, and a block copolymer containing at least one water-soluble block and one hydrophobic block and being particularly suited for use in high temperature ranges, greater than 180° C.
    Type: Grant
    Filed: February 20, 2001
    Date of Patent: June 17, 2003
    Assignee: Rhodia Chimie
    Inventors: Caroline Heitz, Mathieu Joanicot, Robert J. Tillotson
  • Patent number: 6566472
    Abstract: Binder formulations based on aqueous polymer dispersions having a minimum film-forming temperature of below 10° C. and comprising at least one binder polymer P in the form of an aqueous dispersion comprising at least one anionic emulsifier and at least one nonionic emulsifier.
    Type: Grant
    Filed: August 17, 2000
    Date of Patent: May 20, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Roland Baumstark, Stefan Kirsch, Rolf Dersch, Johannes Dobbelaar, Michael Melan
  • Publication number: 20020115784
    Abstract: The invention relates to a process for the preparation of styrene polymers containing water as the sole expanding agent by polymerization of styrene in aqueous suspension in the presence of an amphiphilic organic emulsifier which carries both hydrophilic and hydrophobic groups, or a polar group-containing, water-miscible polymer.
    Type: Application
    Filed: December 28, 2001
    Publication date: August 22, 2002
    Applicant: BASF Aktiengesellschaft
    Inventors: Achim Datko, Peter Dodel, Klaus Hahn
  • Patent number: 6437040
    Abstract: The invention relates to water-soluble block copolymers comprising at least one block of hydrophobic nature and at least one block of hydrophilic nature, the block of hydrophobic nature exhibiting hydrophilic units in an amount of between 33% and 99% by weight with respect to the total weight of the units of the hydrophobic block. These copolymers are preferably diblocks or triblocks and are prepared by a polymerization process referred to as a living or controlled. Control of their hydrophilic-lipophilic balance makes it possible to adjust their solubility in water and their self-association properties. These copolymers can be used in particular as adhesion agents or wetting agents.
    Type: Grant
    Filed: February 26, 2001
    Date of Patent: August 20, 2002
    Assignee: Rhodia Chimie
    Inventors: Olivier Anthony, Cécile Bonnet-Gonnet, Mathias Destarac, Roya Farhoosh, Mathieu Joanicot, Gilda Lizarraga, Roland Reeb, Jean-Marie Schwob
  • Publication number: 20020082374
    Abstract: A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M comprising
    Type: Application
    Filed: September 20, 2001
    Publication date: June 27, 2002
    Applicant: BASF Aktiengesellschaft
    Inventors: Volker Schaedler, Lambertus Manders, Roland Ettl, Thomas Wirth
  • Patent number: 6248815
    Abstract: The present invention relates to a water based laminating adhesive composition and a method of using thereof. More particularly, the invention relates to a water-based laminating adhesive comprising: a first component comprising at least one aqueous vinyl polymer dispersion (A) comprising the reaction product of i) at least one ethylenically unsaturated monomer; ii) at least one free radical initiator; and iii) optionally, at least one ethylenically unsaturated oligomer; and b) a second component comprising at least one water dispersible polyfunctional aziridine crosslinking agent (B). The adhesive optionally comprises at least one aqueous polyurethane polymer dispersion (C). Improved bonded properties of dry laminated flexible film substrates such as polyolefin, polyester and polyamide, as well as cellophane, metals or paper are obtained.
    Type: Grant
    Filed: June 4, 1998
    Date of Patent: June 19, 2001
    Assignee: H. B. Fuller Licensing & Financing, Inc.
    Inventors: George A. Papsin, Thomas E. Rolando, Peter A. Voss
  • Patent number: 6197879
    Abstract: A polymer useful as an inorganic pigment dispersant is provided. The polymer is derived from monomers consisting essentially of an ethylenically unsaturated aromatic monomer, an ethylenically unsaturated dicarboxylic acid monomer, and an ethylenically unsaturated monocarboxylic acid monomer. The total amount of said ethylenically unsaturated acid monomers is sufficient to permit said polymer to associate with an inorganic pigment in an aqueous medium in a manner which disperses said inorganic pigment in said aqueous medium to form a stable aqueous dispersion of said inorganic pigment, and the amount of said ethylenically unsaturated aromatic monomer is sufficient to reduce the water sensitivity of a dried coating of a latex paint comprised of said stable aqueous dispersion of said inorganic pigment. A process of preparing a polymer useful as an inorganic pigment dispersant and a method of preparing an inorganic pigment dispersion useful in the preparation of latex paints are also provided.
    Type: Grant
    Filed: September 13, 1996
    Date of Patent: March 6, 2001
    Assignee: Henkel Corporation
    Inventors: Stephen A. Fischer, Michael S. Wiggins, Bruce Matta, Eric Nowicki
  • Patent number: 6190767
    Abstract: A pressure-sensitive adhesive prepared by emulsifying dispersing a monomer mixture containing at least 50% by weight, based on the total weight of the monomer mixture, of a long-chain alkyl (meth)acrylate with the alkyl having 9 to 13 carbon atoms in an aqueous surfactant solution to bring the monomer mixture to fine particles having an average diameter of not more than 2.0 &mgr;m and polymerizing the monomer mixture in the presence of a water-soluble polymerization initiator can provide a pressure-sensitive adhesive which possesses excellent moisture resistance, water resistance, weather resistance, and adhesion to a nonpolar adherend, such as a polyolefin plastic, and, at the same time, well-balanced tackiness properties.
    Type: Grant
    Filed: February 9, 1998
    Date of Patent: February 20, 2001
    Assignee: Toyo Ink Manufacturing Co., Ltd.
    Inventors: Yoshinobu Ishikawa, Hiroaki Kitayama, Masaki Nomura
  • Patent number: 6147165
    Abstract: Inherently tacky, pressure-sensitive adhesive compositions useful in marking film applications are provided. The compositions comprise polymer particles prepared by emulsion polymerization of at least one monomer mixture. The monomer mixture comprises at least one alkyl acrylate, the alkyl group of which has from about 4 to 12 carbon atoms, preferably in an amount of from about 73% to 90% by weight, at least one unsaturated carboxylic acid containing from about 3 to 5 carbon atoms, preferably in an amount of from about 2% to 12% by weight, and at least one hard monomer, preferably present in an amount of from about 5% to 15% by weight. The particles have a mean diameter of about 300 nm or less, as determined by laser light scattering. Preferably the hard monomer comprises a styrenic monomer, more preferably both a styrenic monomer and an alkyl methacrylate. In some embodiments, the compositions are prepared by sequential polymerization of the first and second monomer charges.
    Type: Grant
    Filed: March 9, 1998
    Date of Patent: November 14, 2000
    Assignee: Avery Dennison Corporation
    Inventors: Ivan S. P. Lee, Graham Yeadon, Paul Keller
  • Patent number: 6111009
    Abstract: Flexographic or other printed paper is deinked by a process which comprises pulping in the presence of an emulsion of crosslinked, insoluble, ionisable and swellable polymer particles. The emulsion preferably provides a viscosity (at 3%) in the ionised state of below 50,000 cps (Brookfiled RVT) and is novel.
    Type: Grant
    Filed: September 18, 1997
    Date of Patent: August 29, 2000
    Assignee: Ciba Specialty Chemicals Water Treatments Limited
    Inventors: John Oliver Stockwell, Timothy Guy Bingham, Howard Roger Dungworth
  • Patent number: 5912294
    Abstract: Aqueous polymer emulsions are obtained by polymerizing a mixture of hydrophobic and hydrophilic ethylenically unsaturated monomers by the free radical aqueous emulsion polymerization method and using, as the dispersing medium, a mixture of water and an organic solvent which is not completely soluble in water, the amount of solvent accounting for more than 20% by weight of the total amount of monomers to be polymerized.
    Type: Grant
    Filed: April 2, 1996
    Date of Patent: June 15, 1999
    Assignee: BASF Aktiengesellschaft
    Inventor: Christian Schade
  • Patent number: 5912293
    Abstract: The invention provides an aqueous polymer dispersion in which the copolymer is formed from70 to 90% by weight alkyl methacrylate provided by 0 to 30% by weight C.sub.1-3 alkyl methacrylate and 50 to 90% by weight C.sub.4-12 alkyl methacrylate;5 to 20% by weight styrene or alkyl styrene;2 to 10% by weight water soluble ethylenically unsaturated monomer;0.5 to 4% polyethylenically unsaturated monomer; and0 to 4% carbonyl containing ethylenically unsaturated monomer. The dispersion of the invention is particularly suitable for incorporation into compositions for coating on wood.
    Type: Grant
    Filed: October 28, 1997
    Date of Patent: June 15, 1999
    Assignee: Allied Colloids Limited
    Inventors: John Robert Stockwell, John Mark Plonka
  • Patent number: 5902852
    Abstract: It has been determined that rubbery terpolymers of a conjugated diolefin monomer, a vinyl aromatic monomer, and N-(isobutoxymethyl) acrylamide (IBMA) can be used to modify asphalt cement to greatly enhance the resistance to shoving, rutting, and low temperature cracking of asphalt concretes made therewith. These rubbery polymers have a Mooney viscosity which is within the range of about 35 to about 80. It has further been determined that these rubbery terpolymers are compatible with virtually all types of asphalt. It is particularly preferred for the rubbery polymers of this invention to also contain repeat units which are derived from hydroxypropyl methacrylate (HPMA).
    Type: Grant
    Filed: October 21, 1997
    Date of Patent: May 11, 1999
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Gerald Owen Schulz, Daniel Frederick Klemmensen
  • Patent number: 5886076
    Abstract: A polymer comprising styrene or substituted-styrene and carboxylated monomer is prepared by a solution polymerization process, comprising first a polymerization step, followed by a neutralization step, and then a distillation step. The polymers have relatively low molecular weights, generally below about 10,000, and can have higher styrene content than has hither been possible. The polymers are found to have good soil release properties and so to be particularly useful in cleaning compositions for fabric or hard surface cleaning.
    Type: Grant
    Filed: December 4, 1996
    Date of Patent: March 23, 1999
    Assignee: National Starch and Chemical Investment Holding Coporation
    Inventors: Paul T. Kimpton, Robert W. Hodgetts
  • Patent number: 5859123
    Abstract: The present invention relates to a water-based fluorine-containing emulsion. This emulsion contains a fluorine-containing copolymer in a disperse phase thereof This copolymer is prepared by copolymerizing: (A) a fluoroolefin, (B) an organosilicon compound containing an olefinic unsaturated bond and an alkoxysilyl group, (C) an unsaturated carboxylic acid represented by a general formula of CH.sub.2 .dbd.CH--(CH.sub.2).sub.n --COOH where n is an integer of from 3 to 15, and (D) at least one other copolymerizable monomer. A paint prepared from the emulsion is superior in storage stability and mechanical stability, although this paint belongs to a one-package paint. A coated film formed by applying the paint is superior in water resistance in its early stages, stain resistance, and weather resistance.
    Type: Grant
    Filed: November 15, 1996
    Date of Patent: January 12, 1999
    Assignee: Central Glass Company, Limited
    Inventors: Satoru Kobayashi, Kazuhiko Maeda, Yoshi Hirashima, Seiji Hasegawa, Kentaro Tsutsumi
  • Patent number: 5789527
    Abstract: Provided are a polyester resin for use in a toner binder which is excellent in terms of offset resistance and low-temperature fixability, which keeps triboelectric charge stability even in an environment of a high temperature and a high humidity, which has excellent durability, and which is used in a toner that gives vivid image characteristics, a process for producing the same, and a toner using the same. The polyester resin for use in the toner binder is formed by linking at least a part of the crosslinked low-molecular polyesters through a dicarboxylic acid used as a linking agent.
    Type: Grant
    Filed: June 5, 1996
    Date of Patent: August 4, 1998
    Assignees: Tomoegawa Paper Co., Ltd., Unitika, Ltd.
    Inventors: Kikumi Nakamichi, Kouta Tanahashi, Tomoko Kubota, Naomi Sasaki, Hideki Kurebayashi, Haruo Okutani, Kazue Nakadera
  • Patent number: 5789511
    Abstract: A polymer comprising styrene or substituted-styrene and carboxylated monomer is prepared by a solution polymerization process, comprising first a polymerization step, followed by a neutralization step, and then a distillation step. The polymers have relatively low molecular weights, generally below about 10,000, and can have higher styrene content than has hither been possible. The polymers are found to have good soil release properties and so to be particularly useful in cleaning compositions for fabric or hard surface cleaning.
    Type: Grant
    Filed: March 26, 1997
    Date of Patent: August 4, 1998
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Paul T. Kimpton, Robert W. Hodgetts
  • Patent number: 5756574
    Abstract: A process for the preparation of an aqueous polymer emulsion, in which an aqueous emulsion of a polymer which contains at least one chemically bonded monomer having at least one ethylenically unsaturated group is produced in a manner known per se so that the total content of free monomers having at least one ethylenically unsaturated double bond, ie. monomers of this type which are not chemically bonded, in the aqueous polymer emulsion is from >0 to .ltoreq.1% by weight, based on the polymer content of the aqueous polymer emulsion, and this residual monomer content is then reduced by the action of a free radical redox initiator system comprising at least one oxidizing agent and at least one reducing agent, wherein the redox initiator system comprises, as the reducing agent, one which is present, in aqueous solution, in at least two tautomeric forms in equilibrium with one another (for example aminoiminomethanesulfinic acid and/or the salts thereof).
    Type: Grant
    Filed: April 3, 1997
    Date of Patent: May 26, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Roland Baumstark, Robert Rupaner
  • Patent number: 5650473
    Abstract: A polymer comprising styrene or substituted-styrene and carboxylated monomer is prepared by a solution polymerization process, comprising first a polymerization step, followed by a neutralization step, and then a distillation step. The polymers have relatively low molecular weights, generally below about 10,000, and can have higher styrene content than has hither been possible. The polymers are found to have good soil release properties and so to be particularly useful in cleaning compositions for fabric or hard surface cleaning.
    Type: Grant
    Filed: July 21, 1995
    Date of Patent: July 22, 1997
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Paul T. Kimpton, Robert W. Hodgetts
  • Patent number: 5532300
    Abstract: A specific class of water-borne, water redispersible laminating adhesives is disclosed which is desirable for bonding nonwoven substrates to themselves or to other substrates. The adhesives provide improved bond strength and improved water redispersibility when compared to laminating adhesives currently used for the same purpose. Furthermore, the novel adhesives are much less sensitive to the presence of significant levels of plasticizer than are laminating adhesives currently used, which exhibit reduced water redispersibility when such plasticizers are present in significant amounts. The novel laminating adhesives contain an aqueous styrene/acrylic polymer dispersion prepared by radical-initiated emulsion polymerization of unsaturated monomers in the presence of starch degradation products having a weight average molecular weight range of from about 2500 to 25000 and which are obtainable by hydrolysis in the aqueous phase.
    Type: Grant
    Filed: August 12, 1994
    Date of Patent: July 2, 1996
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Timothy C. Koubek, Paul P. Puletti, Joseph Wieczorek, Jr.
  • Patent number: RE36884
    Abstract: Mannich (alk)acrylamide microparticles are produced at high solids contents without a significant increase in bulk viscosity by inverse microemulsion polymerization and provide superior dewatering characteristics.
    Type: Grant
    Filed: September 12, 1997
    Date of Patent: September 26, 2000
    Assignee: Cytec Technology Corp.
    Inventors: Joseph J. Kozakiewicz, Sun-Yi Huang