Aromatic Monomer Patents (Class 524/824)
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Patent number: 11913273Abstract: Motorized door assemblies having a door pivoting about a pivot axis extending across opposing jambs. In one aspect, the assembly includes a motor assembly having a motor, drive gears, slip clutch, and driven shaft connected to the door to pivot it about the pivot axis. The slip clutch includes a clutch plate slideable along the driven shaft, a drive plate driven by the motor via the drive gears, and a clutch spring urging the clutch plate into engagement with the drive plate, where the clutch and drive plates have profiled and counter-profiled faces. In another aspect, a break beam emitter and receiver are mounted to respective ones of the opposing jambs along a beam axis extending parallel to the pivot axis and proximate to an edge of the door opposite the pivot axis. Interruption of a light beam projected therebetween alters operation of a motor assembly.Type: GrantFiled: May 15, 2018Date of Patent: February 27, 2024Assignee: APEX INDUSTRIAL TECHNOLOGIES LLCInventors: Craig Whitaker, Edward Leonard Weaver, II, Scott A. Zieker, Charles Eldon Warner, Ronald G. Knollman
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Patent number: 11597834Abstract: Disclosed herein are a biodegradable polymer microparticle for a filler comprising a core and a shell, wherein the core contains secondary particles including aggregates of a plurality of primary particles, the shell has a raspberry shaped structure, an average particle diameter (D50) of the biodegradable polymer microparticle ranges from 20 to 200 ?m, a manufacturing method thereof, a freeze-dried body including the same, and filler injection including the same.Type: GrantFiled: January 21, 2022Date of Patent: March 7, 2023Assignee: ULTRA V CO., LTD.Inventors: Cheong Cheon Lee, Lia Priscilla, Min Seok Kwak, Jung Woo Han, Jung Ryul Ham, Han Jin Kwon
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Publication number: 20150133604Abstract: Disclosed are latex polymers and an aqueous coating compositions having excellent freeze-thaw stability, open time, stain resistance, low temperature film formation, foam resistance, block resistance, adhesion, water sensitivity and a low-VOC content. The latex polymers and aqueous coating compositions include at least one latex polymer derived from at least one monomer copolymerized or blended with an alkoxylated compound, for example an alkoxylated tristyrylphenol or an alkoxylated tributyiphenol. Also provided is an aqueous coating composition including at least one latex polymer, at least one pigment, water and at least one freeze-thaw additive. Typically, the freeze-thaw additive in an amount greater than about 1.3% by weight of the polymer, typically in an amount greater than about 2% by weight of the polymer, in an amount greater than about 4% by weight of the polymer, in an amount greater than about 7.Type: ApplicationFiled: December 1, 2014Publication date: May 14, 2015Inventors: Zhengang ZONG, Yi-Zhong LI, Jose RUIZ
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Publication number: 20140249270Abstract: Latex emulsions are disclosed which can be used in the formation of coating compositions that are not water sensitive, have good blush resistance and retortability. In some embodiments, the coating compositions are used to coat substrates such as cans and packaging materials for the storage of food and beverages. Coating compositions can be prepared by mixing an ethylenically unsaturated monomer component and a stabilizer comprising a strong acid, in a carrier to form a monomer emulsion, reacting the monomer emulsion with an initiator to form the latex emulsion, and reacting the latex emulsion with a neutralizer. Methods of coating substrates with the coating compositions, and substrates coated with the coating compositions are also disclosed.Type: ApplicationFiled: May 15, 2014Publication date: September 4, 2014Applicant: AKZO NOBEL COATINGS INTERNATIONAL B.V.Inventors: Jude Thomas Rademacher, Gary Charles Pompignano, Willy P. Kulhanek
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Publication number: 20140228477Abstract: A process of preparing a water-based emulsion includes adding a first monomer feed to a reaction vessel in the presence of a first initiator and water to form an acid-functional polymer; neutralizing the acid-functional polymer to form a particulate polymer; and adding a second monomer feed to the reaction vessel in the presence of a second initiator to form an agglomerated polymer; where the process is a one-pot process. The first monomer feed includes a unbranched (meth)acrylate monomer, a (meth)acrylic acid monomer, a branched (meth)acrylate, and a styrenic monomer; the second monomer feed includes a hydrophobic monomer; the water-based emulsion includes the agglomerated polymer; the agglomerated polymer includes the particulate polymer; and the agglomerated polymer having an aggregated drupelet morphology. The agglomerated polymers may be used in high opacity emulsions.Type: ApplicationFiled: August 29, 2012Publication date: August 14, 2014Inventors: Sarav Bharat Jhaveri, Chien L. Hsu
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Publication number: 20140213691Abstract: A process of preparing a water-based emulsion includes adding a first monomer feed to a reaction vessel in the presence of a first initiator and water to form an acid-functional polymer; neutralizing the acid-functional polymer to form a particulate polymer; and adding a second monomer feed to the reaction vessel in the presence of a second initiator to form an agglomerated polymer; where the process is a one-pot process. The first monomer feed includes a (meth)acrylate monomer, a (meth)acrylic acid monomer, and a styrenic monomer; the second monomer feed includes a hydrophobic monomer; the water-based emulsion includes the agglomerated polymer; the agglomerated polymer includes the particulate polymer; and the agglomerated polymer having an aggregated drupelet morphology. The agglomerated polymers may be used in high opacity emulsions.Type: ApplicationFiled: August 29, 2012Publication date: July 31, 2014Applicant: BASF SEInventor: Sarav Bharat Jhaveri
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Patent number: 8765860Abstract: An injection molding composition, having a small fluctuation characteristic and a better characteristic, is provided. The above composition is the injection molding composition comprising a ferrite powder which is a collection of ferrite particles, a first binder and a second binder. A weight and a specific surface area of the ferrite powders are represented by Wp and S, and a weight and a density of the first binder and the second binder is represented by Wb1, Wb2, and Db1, Db2. A hypothetical thickness Tb1 of the first binder is 2.0 to 15.0, and a hypothetical thickness Tb2 of the second binder is 16.5 to 32.0. In the composition, it is preferable that coated ferrite particles coating the outer circumference of the ferrite particles with the first binder and the second binder exist.Type: GrantFiled: August 27, 2012Date of Patent: July 1, 2014Assignee: TDK CorporationInventors: Naoto Tsukamoto, Tomohiko Aida, Shinichi Sakano, Yoshihiko Minachi, Masashi Gotoh, Minao Himeno
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Patent number: 8562850Abstract: The present invention relates to an emulsion for vibration damping materials, including an emulsion obtainable by emulsion polymerization of a monomer component, wherein the emulsion is obtainable by emulsion polymerization using an anionic emulsifier and/or a reactive emulsifier, and emulsion particles have an average particle diameter of 100 to 450 nm, and an emulsion for vibration damping materials, comprising acrylic emulsion particles each having a core part and a shell part, wherein the acrylic emulsion particles are obtainable by polymerizing a monomer component including a monomer having a Q value of 0.6 to 1.4 and an e value of ?0.4 to ?1.2.Type: GrantFiled: March 28, 2008Date of Patent: October 22, 2013Assignee: Nippon Shokubai Co., Ltd.Inventors: Yukihiro Miyawaki, Kazutaka Otsuki, Dai Nagaishi, Takahiro Miwa
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Publication number: 20110288232Abstract: Latex emulsions are disclosed which can be used in the formation of coating compositions that are not water sensitive, have good blush resistance and retortability. In some embodiments, the coating compositions are used to coat substrates such as cans and packaging materials for the storage of food and beverages. Coating compositions can be prepared by mixing an ethylenically unsaturated monomer component and a stabilizer comprising a strong acid, in a carrier to form a monomer emulsion, reacting the monomer emulsion with an initiator to form the latex emulsion, and reacting the latex emulsion with a neutralizer. Methods of coating substrates with the coating compositions, and substrates coated with the coating compositions are also disclosed.Type: ApplicationFiled: February 22, 2010Publication date: November 24, 2011Applicant: Akzo Nobel Coatings International B.V.Inventors: Jude Thomas Rademacher, Gary Charles Pompignano, Willy P Kulhanek
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Patent number: 7989544Abstract: Polymer capsules from amphiphilic graft copolymers comprising reactive, hydrophobic polyolefin backbones, and hydrophilic poly(ethylene glycol) (PEG) grafts are produced by self-assembly of the polymers at the oil-water interface, and crosslinking the assembly with bis-cyclooctene PEG derivatives in conjunction with ring-open metathesis polymerization catalysts. The use of the graft copolymer architecture in capsule synthesis provides significant opportunities to tune both the surface properties, in terms of recognition, and the membrane properties, in terms of mechanical strength, encapsulation, and release.Type: GrantFiled: December 13, 2010Date of Patent: August 2, 2011Assignee: University of MassachusettsInventors: Todd S. Emrick, Kurt Breitenkamp
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Publication number: 20110152052Abstract: Described is a recloseable pack having a cold-sealed layer of adhesive which is recloseable after the pack has been opened, the layer of adhesive comprising an emulsion polymer composed to an extent of at least 60% by weight of principal monomers selected from the group consisting of C1 to C20 alkyl (meth)acrylates, vinyl esters of carboxylic acids comprising up to 20 C atoms, vinylaromatics having up to 20 C atoms, ethylenically unsaturated nitriles, vinyl halides, vinyl ethers of alcohols comprising 1 to 10 C atoms, aliphatic hydrocarbons having 2 to 8 C atoms and one or two double bonds, and mixtures of these monomers, the emulsion polymer being preparable by emulsion polymerization of free-radically polymerizable monomers in the presence of at least one protective colloid. Also described are aqueous polymer dispersions suitable for producing the pack of the invention, and polymer films coated with the polymer dispersions.Type: ApplicationFiled: December 15, 2010Publication date: June 23, 2011Applicant: BASF SEInventors: Karl-Heinz SCHUMACHER, Florian Büsch, Dieter Urban, Cornelis Petrus Beyers
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Patent number: 7851543Abstract: Polymer capsules from amphiphilic graft copolymers comprising reactive, hydrophobic polyolefin backbones, and hydrophilic poly(ethylene glycol) (PEG) grafts are produced by self-assembly of the polymers at the oil-water interface, and crosslinking the assembly with bis-cyclooctene PEG derivatives in conjunction with ring-open metathesis polymerization catalysts. The use of the graft copolymer architecture in capsule synthesis provides significant opportunities to tune both the surface properties, in terms of recognition, and the membrane properties, in terms of mechanical strength, encapsulation, and release.Type: GrantFiled: October 6, 2009Date of Patent: December 14, 2010Assignee: University of MassachusettsInventors: Todd S. Emrick, Kurt Breitenkamp
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Patent number: 7713674Abstract: An emulsion polymerization process comprising polymerizing monomer in an emulsion in a reaction vessel at a first temperature to form a resin; cooling the reaction vessel to a second temperature that is above the softening point of the resin yet below the temperature required for significant depolymerization reaction to occur; and adding water to the cooled reaction vessel in an amount sufficient to effect phase inversion with mixing for a sufficient time to form an aqueous latex emulsion in the absence of a surfactant.Type: GrantFiled: September 9, 2005Date of Patent: May 11, 2010Assignee: Xerox CorporationInventors: Allan Kwok-Wai Chen, Milan Maric, Tie Hwee Ng, George Liebermann, Enno Eric Agur, Hadi Khan Mahabadi
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Patent number: 7598313Abstract: Polymer capsules from amphiphilic graft copolymers comprising reactive, hydrophobic polyolefin backbones, and hydrophilic poly(ethylene glycol) (PEG) grafts are produced by self-assembly of the polymers at the oil-water interface, and crosslinking the assembly with bis-cyclooctene PEG derivatives in conjunction with ring-open metathesis polymerization catalysts. The use of the graft copolymer architecture in capsule synthesis provides significant opportunities to tune both the surface properties, in terms of recognition, and the membrane properties, in terms of mechanical strength, encapsulation, and release.Type: GrantFiled: September 3, 2004Date of Patent: October 6, 2009Assignee: University of MassachusettsInventors: Todd S. Emrick, Kurt Breitenkamp
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Publication number: 20090188054Abstract: Aqueous alkenylsuccinic anhydride-containing polymer dispersions which are obtainable by miniemulsion polymerization of hydrophobic monoethylenically unsaturated monomers in the presence of alkenylsuccinic anhydrides, processes for the preparation of such polymer dispersions by polymerizing hydrophobic monomers by a miniemulsion polymerization method in the presence of at least one alkenylsuccinic anhydride and, if appropriate, an alkyldiketene, and use of the resulting aqueous alkenylsuccinic anhydride-containing polymer dispersions as engine and surface sizes for paper and for imparting water repellency to leather, natural and/or synthetic fibers and textiles.Type: ApplicationFiled: January 14, 2005Publication date: July 30, 2009Applicant: BASF AktiengesellschaftInventors: Rainer Dyllick-Brenzinger, Reinhold J. Leyrer, Andreas Brockmeyer, Markus Schmid, Roland Ettl
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Patent number: 7232860Abstract: An aqueous binder dispersion that includes at least one copolymer (P) containing carboxylic acid and/or carboxylate groups. The copolymer (P) includes structural units of carboxyl-free (meth)acrylic esters with a cycloaliphatic structure, and at least 25 mol % of the carboxylic acid groups of the copolymer (P) in the dispersion being present in triethanolamine-neutralized form. The aqueous binder can be used in aqueous coating materials, which can be used to coat a substrate.Type: GrantFiled: August 13, 2003Date of Patent: June 19, 2007Assignee: Bayer MaterialScience AGInventors: Martin Melchiors, Ulrich Freudenberg, Robert Reyer, Raul Pires, Sandra Grosskopf
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Patent number: 7199185Abstract: Reactive polymeric surfactants are disclosed, and their use in processes for preparation of microcapsules, and in stabilising emulsions. The surfactants are random graft polymers or block copolymers which contain both hydrophobic and hydrophilic units and in which the hydrophobic unit includes a hydrophilic cross-linking unit which reacts with (a) a wall forming ingredient in a microencapsulation process, or (b) an ingredient in the disperse phase of an emulsion.Type: GrantFiled: June 10, 2002Date of Patent: April 3, 2007Assignee: Syngenta LimitedInventors: Alexander Mark Heming, Patrick Joseph Mulqueen, Herbert Benson Scher, Ian Malcolm Shirley
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Patent number: 7138160Abstract: The use, for the manufacture of paper coating colors, of a copolymer water-soluble in a neutral or alkaline medium as an agent for simultaneously adjusting the water retention of the coating colors and the Brookfield viscosity of the said coating colors; a water-retention agent comprising the copolymer; and coating colors and the coated paper and cardboard thus obtained.Type: GrantFiled: July 10, 2000Date of Patent: November 21, 2006Assignee: Coatex S.A.S.Inventors: Francois Dupont, Henri Grondin, Georges Ravet, Jean-Marc Suau
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Patent number: 6884840Abstract: A process for preparing hot-melt pressure-sensitive adhesives from aqueous dispersions based on polyacrylate, and pressure-sensitively adhesive articles produced therefrom, which comprises producing highly concentrated aqueous dispersions with polymer contents between 68% by weight and 87% by weight of gel-free, molecularly-dispersely meltable polymer particles with an at least bimodal size distribution in size ranges between 0.5 ?m and 1000 ?m Ø.Type: GrantFiled: March 22, 2001Date of Patent: April 26, 2005Assignee: tesa AGInventors: Peter Gleichenhagen, Annemarie Müller
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Patent number: 6844385Abstract: A latex for dip forming which comprises a copolymer prepared by polymerizing 10 to 90% by weight of a conjugated diene monomer, 0.1 to 20% by weight of an ethylenically unsaturated acid monomer and 10 to 89.9% by weight of other ethylenically unsaturated monomer or monomers copolymerizable therewith, wherein the sum of the amount of acid groups bonded to or adsorbed on the surface of the copolymer constituting the latex and the amount of acid groups present in the aqueous phase of the copolymer latex is in the range of 0.1 to 2 meq. in terms of hydrochloric acid, per gram of the copolymer. This latex is dip-formed to give a dip-formed article having no fear of development of a protein allergy, and exhibiting a soft feeling and a high mechanical strength.Type: GrantFiled: June 26, 2000Date of Patent: January 18, 2005Assignee: Zeon CorporationInventors: Katuo Hagiwara, Hisanori Ota
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Patent number: 6790908Abstract: The invention relates to a block copolymer and more especially to a thermoplastic elastomer block copolymer. The block copolymer is a diblock (block A)-(bloc B) copolymer, a triblock (block A)-(block B)-(block A), or a triblock (block A)-(block B)-(block C) copolymer, wherein block A is a stiff block, block B is a soft block, and block C is a stiff block. Block A or Block B comprises repetitive units deriving from segregation monomers.Type: GrantFiled: May 9, 2002Date of Patent: September 14, 2004Assignee: Rhodia Inc.Inventors: Denis Bendejacq, Mathieu Joanicot, Gilda Lizarraga, Virginie Ponsinet
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Publication number: 20040096685Abstract: The present invention relates to pressure sensitive adhesives based on aqueous latex emulsions processes for their preparation and laminates prepared there from. The pressure sensitive adhesives exhibit excellent adhesion in hot water environments and resistance to water-whitening.Type: ApplicationFiled: May 13, 2003Publication date: May 20, 2004Inventors: Raymond Scoot Harvey, Harvey Joseph Richards, Corlyss J. Richards
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Patent number: 6716912Abstract: The present invention comprises a polymeric binder for water-resistant ink jet inks, wherein the binder has an acid component in the range from about 1 to about 10 wt. % of the polymer, a glass transition temperature in the range from about −20° C. to about 25° C., and an average particle diameter in the range from about 250 to about 400 nm and a particle size distribution such that essentially all the particles have a diameter in the range from 130 to 450 nm. The binder comprises monomers selected from the group consisting of acrylates, methacrylates, styrene, substituted styrene, fluoromethacrylates, vinyl acrylates, vinyl acetates, acrylamides, substituted acrylamides, methacrylamides, substituted methacrylamides, or combinations thereof.Type: GrantFiled: November 30, 2000Date of Patent: April 6, 2004Assignee: Rohm and Haas CompanyInventors: Michael Bennett Freeman, Eric Jon Langenmayr, Thomas Glenn Madle
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Patent number: 6710128Abstract: A process is provided to produce an aqueous composition. The process comprises shearing a mixture to produce a mini-emulsion and polymerizing said mini-emulsion in the presence of an initiator to produce the aqueous composition; wherein said mixture comprises at least one tackifier, at least one ethylenically unsaturated monomer, at least one surfactant, and water. The aqueous composition can be utilized to produced various articles including, but not limited to, adhesives, coatings, and laminates.Type: GrantFiled: December 13, 2002Date of Patent: March 23, 2004Assignee: Eastman Chemical CompanyInventors: Bradley James Helmer, Glenn Lewis Shoaf
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Patent number: 6683129Abstract: This invention relates to aqueous emulsions comprising a water-dispersible copolymer which is non-dispersible in aqueous solutions containing 0.5% or more of an inorganic salt, comprising acidic ethylenically unsaturated monomers and ethylenically unsaturated monomers. The acidic ethylenically unsaturated monomers and the ethylenically unsaturated monomers are defined herein. The present invention also pertains to emulsion polymerization methods for making the aqueous emulsions with or without a surfactant.Type: GrantFiled: March 31, 2000Date of Patent: January 27, 2004Assignee: National Starch and Chemical Investment Holding CorporationInventor: Michael W. Eknoian
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Patent number: 6683121Abstract: A pigment dispersant including 80-97% by weight, based on the weight of thepigment dispersant, of a first polymer comprising as copolymerized units 15-75% by weight, based on the first polymer weight, ethylenically unsaturated carboxylic acid-functional monomer, the polymer having a Mw from 4,000 to 16,000, and the polymer having a Tg greater than 70° C.; and 3-20% by weight, based on the weight of the pigment dispersant, of a poly(ethylene oxide/propylene oxide) block second polymer having an Mw from 3,000 to 20,000 and an HLB value of 16 to 32 is provided. And the invention relates to a method for dispersing a pigment in an aqueous medium using the pigment dispersant, an aqueous pigment dispersion including the pigment dispersant, and an aqueous ink including the pigment dispersion.Type: GrantFiled: November 20, 2001Date of Patent: January 27, 2004Assignee: Rohm and Haas CompanyInventors: Shang-Jaw Chiou, Scott Lind Egolf, Miao-Hsun Sheng
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Patent number: 6656983Abstract: The invention provides mixed aromatic vinyl-1,3-diene polymers stabilized by a protective colloid and present in the form of aqueous polymer dispersions or polymer powders redispersible in water as adhesives for porous substrates. The polymer dispersions and the polymer powders are obtained by emulsion polymerization of a mixture containing: a) 20 to 80 percent by weight of one or more vinylaromatics; b) 19.9 to 79.9 percent by weight of one or more 1,3-dienes; c) 0.1 to 15 percent by weight of one or more comonomers from the group consisting of N-methylolacrylamide, N-methylolmethacrylamide and the N-(alkoxymethyl)-acrylamides and N-(alkoxymethyl)-methacrylamides with a C1 to C6-alkyl radical. The sum of the above percentages adds up to 100% by weight. Emulsion polymerization is carried out in the presence of one or more protective colloids and without emulsifiers, optionally followed by drying of the resulting aqueous polymer dispersion.Type: GrantFiled: August 1, 2001Date of Patent: December 2, 2003Assignee: Wacker-Chemie GmbHInventors: Theo Mayer, Thomas Kohler, Reinhard Harzschel, Hans-Peter Weitzel, Bernd Schilling
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Patent number: 6593421Abstract: An aqueous composition containing from 1 to 60% by weight of a polymer A) built up from a) from 10 to 50% by weight of a vinylaromatic having up to 20 carbon atoms, b) from 45 to 75% by weight of a nonaromatic hydrocarbon having two conjugated double bonds, c) from 0 to 20% by weight of a water-soluble monomer having a water solubility of at least 100 g per liter of water under standard conditions (21° C. and 1 bar), the water-soluble monomer containing no acid group or acid anhydride group, d) from 0.1 to 4.5% by weight of a monomer containing at least one acid group or acid anhydride group, e) from 0 to 30% by weight of a monomer other than a) to d), and from 40 to 99% by weight of a filler B), the weight data for A) and B) being based on the sum of A) and B).Type: GrantFiled: October 22, 2001Date of Patent: July 15, 2003Assignee: BASF AktiengesellschaftInventors: David Christie, Joachim Pakusch, Eckehardt Wistuba, Horst Seibert, Peter Fickeisen
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Patent number: 6590031Abstract: The present invention relates to pressure sensitive adhesives based on aqueous latex emulsions processes for their preparation and laminates the prepared there from. The pressure sensitive adhesives exhibit excellent adhesion in hot water environments and resistance to water-whitening.Type: GrantFiled: November 13, 2001Date of Patent: July 8, 2003Assignee: Ashland Inc.Inventors: Raymond Scott Harvey, Harvey J. Richards
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Patent number: 6579947Abstract: The invention relates to a hydraulic fracturing fluid comprising an aqueous liquid, and a block copolymer containing at least one water-soluble block and one hydrophobic block and being particularly suited for use in high temperature ranges, greater than 180° C.Type: GrantFiled: February 20, 2001Date of Patent: June 17, 2003Assignee: Rhodia ChimieInventors: Caroline Heitz, Mathieu Joanicot, Robert J. Tillotson
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Patent number: 6566472Abstract: Binder formulations based on aqueous polymer dispersions having a minimum film-forming temperature of below 10° C. and comprising at least one binder polymer P in the form of an aqueous dispersion comprising at least one anionic emulsifier and at least one nonionic emulsifier.Type: GrantFiled: August 17, 2000Date of Patent: May 20, 2003Assignee: BASF AktiengesellschaftInventors: Roland Baumstark, Stefan Kirsch, Rolf Dersch, Johannes Dobbelaar, Michael Melan
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Publication number: 20020115784Abstract: The invention relates to a process for the preparation of styrene polymers containing water as the sole expanding agent by polymerization of styrene in aqueous suspension in the presence of an amphiphilic organic emulsifier which carries both hydrophilic and hydrophobic groups, or a polar group-containing, water-miscible polymer.Type: ApplicationFiled: December 28, 2001Publication date: August 22, 2002Applicant: BASF AktiengesellschaftInventors: Achim Datko, Peter Dodel, Klaus Hahn
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Patent number: 6437040Abstract: The invention relates to water-soluble block copolymers comprising at least one block of hydrophobic nature and at least one block of hydrophilic nature, the block of hydrophobic nature exhibiting hydrophilic units in an amount of between 33% and 99% by weight with respect to the total weight of the units of the hydrophobic block. These copolymers are preferably diblocks or triblocks and are prepared by a polymerization process referred to as a living or controlled. Control of their hydrophilic-lipophilic balance makes it possible to adjust their solubility in water and their self-association properties. These copolymers can be used in particular as adhesion agents or wetting agents.Type: GrantFiled: February 26, 2001Date of Patent: August 20, 2002Assignee: Rhodia ChimieInventors: Olivier Anthony, Cécile Bonnet-Gonnet, Mathias Destarac, Roya Farhoosh, Mathieu Joanicot, Gilda Lizarraga, Roland Reeb, Jean-Marie Schwob
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Publication number: 20020082374Abstract: A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M comprisingType: ApplicationFiled: September 20, 2001Publication date: June 27, 2002Applicant: BASF AktiengesellschaftInventors: Volker Schaedler, Lambertus Manders, Roland Ettl, Thomas Wirth
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Patent number: 6248815Abstract: The present invention relates to a water based laminating adhesive composition and a method of using thereof. More particularly, the invention relates to a water-based laminating adhesive comprising: a first component comprising at least one aqueous vinyl polymer dispersion (A) comprising the reaction product of i) at least one ethylenically unsaturated monomer; ii) at least one free radical initiator; and iii) optionally, at least one ethylenically unsaturated oligomer; and b) a second component comprising at least one water dispersible polyfunctional aziridine crosslinking agent (B). The adhesive optionally comprises at least one aqueous polyurethane polymer dispersion (C). Improved bonded properties of dry laminated flexible film substrates such as polyolefin, polyester and polyamide, as well as cellophane, metals or paper are obtained.Type: GrantFiled: June 4, 1998Date of Patent: June 19, 2001Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: George A. Papsin, Thomas E. Rolando, Peter A. Voss
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Patent number: 6197879Abstract: A polymer useful as an inorganic pigment dispersant is provided. The polymer is derived from monomers consisting essentially of an ethylenically unsaturated aromatic monomer, an ethylenically unsaturated dicarboxylic acid monomer, and an ethylenically unsaturated monocarboxylic acid monomer. The total amount of said ethylenically unsaturated acid monomers is sufficient to permit said polymer to associate with an inorganic pigment in an aqueous medium in a manner which disperses said inorganic pigment in said aqueous medium to form a stable aqueous dispersion of said inorganic pigment, and the amount of said ethylenically unsaturated aromatic monomer is sufficient to reduce the water sensitivity of a dried coating of a latex paint comprised of said stable aqueous dispersion of said inorganic pigment. A process of preparing a polymer useful as an inorganic pigment dispersant and a method of preparing an inorganic pigment dispersion useful in the preparation of latex paints are also provided.Type: GrantFiled: September 13, 1996Date of Patent: March 6, 2001Assignee: Henkel CorporationInventors: Stephen A. Fischer, Michael S. Wiggins, Bruce Matta, Eric Nowicki
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Patent number: 6190767Abstract: A pressure-sensitive adhesive prepared by emulsifying dispersing a monomer mixture containing at least 50% by weight, based on the total weight of the monomer mixture, of a long-chain alkyl (meth)acrylate with the alkyl having 9 to 13 carbon atoms in an aqueous surfactant solution to bring the monomer mixture to fine particles having an average diameter of not more than 2.0 &mgr;m and polymerizing the monomer mixture in the presence of a water-soluble polymerization initiator can provide a pressure-sensitive adhesive which possesses excellent moisture resistance, water resistance, weather resistance, and adhesion to a nonpolar adherend, such as a polyolefin plastic, and, at the same time, well-balanced tackiness properties.Type: GrantFiled: February 9, 1998Date of Patent: February 20, 2001Assignee: Toyo Ink Manufacturing Co., Ltd.Inventors: Yoshinobu Ishikawa, Hiroaki Kitayama, Masaki Nomura
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Patent number: 6147165Abstract: Inherently tacky, pressure-sensitive adhesive compositions useful in marking film applications are provided. The compositions comprise polymer particles prepared by emulsion polymerization of at least one monomer mixture. The monomer mixture comprises at least one alkyl acrylate, the alkyl group of which has from about 4 to 12 carbon atoms, preferably in an amount of from about 73% to 90% by weight, at least one unsaturated carboxylic acid containing from about 3 to 5 carbon atoms, preferably in an amount of from about 2% to 12% by weight, and at least one hard monomer, preferably present in an amount of from about 5% to 15% by weight. The particles have a mean diameter of about 300 nm or less, as determined by laser light scattering. Preferably the hard monomer comprises a styrenic monomer, more preferably both a styrenic monomer and an alkyl methacrylate. In some embodiments, the compositions are prepared by sequential polymerization of the first and second monomer charges.Type: GrantFiled: March 9, 1998Date of Patent: November 14, 2000Assignee: Avery Dennison CorporationInventors: Ivan S. P. Lee, Graham Yeadon, Paul Keller
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Patent number: 6111009Abstract: Flexographic or other printed paper is deinked by a process which comprises pulping in the presence of an emulsion of crosslinked, insoluble, ionisable and swellable polymer particles. The emulsion preferably provides a viscosity (at 3%) in the ionised state of below 50,000 cps (Brookfiled RVT) and is novel.Type: GrantFiled: September 18, 1997Date of Patent: August 29, 2000Assignee: Ciba Specialty Chemicals Water Treatments LimitedInventors: John Oliver Stockwell, Timothy Guy Bingham, Howard Roger Dungworth
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Patent number: 5912293Abstract: The invention provides an aqueous polymer dispersion in which the copolymer is formed from70 to 90% by weight alkyl methacrylate provided by 0 to 30% by weight C.sub.1-3 alkyl methacrylate and 50 to 90% by weight C.sub.4-12 alkyl methacrylate;5 to 20% by weight styrene or alkyl styrene;2 to 10% by weight water soluble ethylenically unsaturated monomer;0.5 to 4% polyethylenically unsaturated monomer; and0 to 4% carbonyl containing ethylenically unsaturated monomer. The dispersion of the invention is particularly suitable for incorporation into compositions for coating on wood.Type: GrantFiled: October 28, 1997Date of Patent: June 15, 1999Assignee: Allied Colloids LimitedInventors: John Robert Stockwell, John Mark Plonka
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Patent number: 5912294Abstract: Aqueous polymer emulsions are obtained by polymerizing a mixture of hydrophobic and hydrophilic ethylenically unsaturated monomers by the free radical aqueous emulsion polymerization method and using, as the dispersing medium, a mixture of water and an organic solvent which is not completely soluble in water, the amount of solvent accounting for more than 20% by weight of the total amount of monomers to be polymerized.Type: GrantFiled: April 2, 1996Date of Patent: June 15, 1999Assignee: BASF AktiengesellschaftInventor: Christian Schade
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Patent number: 5902852Abstract: It has been determined that rubbery terpolymers of a conjugated diolefin monomer, a vinyl aromatic monomer, and N-(isobutoxymethyl) acrylamide (IBMA) can be used to modify asphalt cement to greatly enhance the resistance to shoving, rutting, and low temperature cracking of asphalt concretes made therewith. These rubbery polymers have a Mooney viscosity which is within the range of about 35 to about 80. It has further been determined that these rubbery terpolymers are compatible with virtually all types of asphalt. It is particularly preferred for the rubbery polymers of this invention to also contain repeat units which are derived from hydroxypropyl methacrylate (HPMA).Type: GrantFiled: October 21, 1997Date of Patent: May 11, 1999Assignee: The Goodyear Tire & Rubber CompanyInventors: Gerald Owen Schulz, Daniel Frederick Klemmensen
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Patent number: 5886076Abstract: A polymer comprising styrene or substituted-styrene and carboxylated monomer is prepared by a solution polymerization process, comprising first a polymerization step, followed by a neutralization step, and then a distillation step. The polymers have relatively low molecular weights, generally below about 10,000, and can have higher styrene content than has hither been possible. The polymers are found to have good soil release properties and so to be particularly useful in cleaning compositions for fabric or hard surface cleaning.Type: GrantFiled: December 4, 1996Date of Patent: March 23, 1999Assignee: National Starch and Chemical Investment Holding CoporationInventors: Paul T. Kimpton, Robert W. Hodgetts
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Patent number: 5859123Abstract: The present invention relates to a water-based fluorine-containing emulsion. This emulsion contains a fluorine-containing copolymer in a disperse phase thereof This copolymer is prepared by copolymerizing: (A) a fluoroolefin, (B) an organosilicon compound containing an olefinic unsaturated bond and an alkoxysilyl group, (C) an unsaturated carboxylic acid represented by a general formula of CH.sub.2 .dbd.CH--(CH.sub.2).sub.n --COOH where n is an integer of from 3 to 15, and (D) at least one other copolymerizable monomer. A paint prepared from the emulsion is superior in storage stability and mechanical stability, although this paint belongs to a one-package paint. A coated film formed by applying the paint is superior in water resistance in its early stages, stain resistance, and weather resistance.Type: GrantFiled: November 15, 1996Date of Patent: January 12, 1999Assignee: Central Glass Company, LimitedInventors: Satoru Kobayashi, Kazuhiko Maeda, Yoshi Hirashima, Seiji Hasegawa, Kentaro Tsutsumi
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Patent number: 5789527Abstract: Provided are a polyester resin for use in a toner binder which is excellent in terms of offset resistance and low-temperature fixability, which keeps triboelectric charge stability even in an environment of a high temperature and a high humidity, which has excellent durability, and which is used in a toner that gives vivid image characteristics, a process for producing the same, and a toner using the same. The polyester resin for use in the toner binder is formed by linking at least a part of the crosslinked low-molecular polyesters through a dicarboxylic acid used as a linking agent.Type: GrantFiled: June 5, 1996Date of Patent: August 4, 1998Assignees: Tomoegawa Paper Co., Ltd., Unitika, Ltd.Inventors: Kikumi Nakamichi, Kouta Tanahashi, Tomoko Kubota, Naomi Sasaki, Hideki Kurebayashi, Haruo Okutani, Kazue Nakadera
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Patent number: 5789511Abstract: A polymer comprising styrene or substituted-styrene and carboxylated monomer is prepared by a solution polymerization process, comprising first a polymerization step, followed by a neutralization step, and then a distillation step. The polymers have relatively low molecular weights, generally below about 10,000, and can have higher styrene content than has hither been possible. The polymers are found to have good soil release properties and so to be particularly useful in cleaning compositions for fabric or hard surface cleaning.Type: GrantFiled: March 26, 1997Date of Patent: August 4, 1998Assignee: National Starch and Chemical Investment Holding CorporationInventors: Paul T. Kimpton, Robert W. Hodgetts
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Patent number: 5756574Abstract: A process for the preparation of an aqueous polymer emulsion, in which an aqueous emulsion of a polymer which contains at least one chemically bonded monomer having at least one ethylenically unsaturated group is produced in a manner known per se so that the total content of free monomers having at least one ethylenically unsaturated double bond, ie. monomers of this type which are not chemically bonded, in the aqueous polymer emulsion is from >0 to .ltoreq.1% by weight, based on the polymer content of the aqueous polymer emulsion, and this residual monomer content is then reduced by the action of a free radical redox initiator system comprising at least one oxidizing agent and at least one reducing agent, wherein the redox initiator system comprises, as the reducing agent, one which is present, in aqueous solution, in at least two tautomeric forms in equilibrium with one another (for example aminoiminomethanesulfinic acid and/or the salts thereof).Type: GrantFiled: April 3, 1997Date of Patent: May 26, 1998Assignee: BASF AktiengesellschaftInventors: Roland Baumstark, Robert Rupaner
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Patent number: 5650473Abstract: A polymer comprising styrene or substituted-styrene and carboxylated monomer is prepared by a solution polymerization process, comprising first a polymerization step, followed by a neutralization step, and then a distillation step. The polymers have relatively low molecular weights, generally below about 10,000, and can have higher styrene content than has hither been possible. The polymers are found to have good soil release properties and so to be particularly useful in cleaning compositions for fabric or hard surface cleaning.Type: GrantFiled: July 21, 1995Date of Patent: July 22, 1997Assignee: National Starch and Chemical Investment Holding CorporationInventors: Paul T. Kimpton, Robert W. Hodgetts
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Patent number: 5532300Abstract: A specific class of water-borne, water redispersible laminating adhesives is disclosed which is desirable for bonding nonwoven substrates to themselves or to other substrates. The adhesives provide improved bond strength and improved water redispersibility when compared to laminating adhesives currently used for the same purpose. Furthermore, the novel adhesives are much less sensitive to the presence of significant levels of plasticizer than are laminating adhesives currently used, which exhibit reduced water redispersibility when such plasticizers are present in significant amounts. The novel laminating adhesives contain an aqueous styrene/acrylic polymer dispersion prepared by radical-initiated emulsion polymerization of unsaturated monomers in the presence of starch degradation products having a weight average molecular weight range of from about 2500 to 25000 and which are obtainable by hydrolysis in the aqueous phase.Type: GrantFiled: August 12, 1994Date of Patent: July 2, 1996Assignee: National Starch and Chemical Investment Holding CorporationInventors: Timothy C. Koubek, Paul P. Puletti, Joseph Wieczorek, Jr.
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Patent number: RE36884Abstract: Mannich (alk)acrylamide microparticles are produced at high solids contents without a significant increase in bulk viscosity by inverse microemulsion polymerization and provide superior dewatering characteristics.Type: GrantFiled: September 12, 1997Date of Patent: September 26, 2000Assignee: Cytec Technology Corp.Inventors: Joseph J. Kozakiewicz, Sun-Yi Huang