Abstract: The subject invention relates to a process for treating an emulsion of a crosslinked elastomeric polymer containing residual hydrazine to obtain a latex of soluble elastomeric polymer having a reduced concentration of residual hydrazine therein, said process comprising the addition of ozone to said emulsion in an amount and under conditions which are sufficient for the ozone to react with the crosslinked elastomeric polymer and the residual hydrazine to produce a latex of soluble elastomeric polymer having a reduced level of residual hydrazine therein. The process of the present invention also improves the color of latex by removing color-bodies, such as benzoquinone, which may be present in the original latex.
Type:
Grant
Filed:
February 22, 1990
Date of Patent:
August 13, 1991
Assignee:
The Goodyear Tire & Rubber Company/Olin Corp.
Abstract: Aqueous dispersions of copolymers having a glass transition temperature of not more than -45.degree. C. and a K value greater than 80 consist of not less than 80% by weight of acrylates of alkanols of 8 to 12 carbon atoms, from 1 to 4% by weight of .alpha.,.beta.- monoolefinically unsaturated carboxylic acids and/or their amide derivatives and from 0.1 to 3% by weight of .alpha.-methylstyrene, and are used for the production of self-adhesive structures having good tack at as low as -40.degree. C.
Type:
Grant
Filed:
December 30, 1987
Date of Patent:
February 6, 1990
Assignee:
BASF Aktiengesellschaft
Inventors:
Juergen Vietmeier, Peter Pfoehler, Gundo Brauch, Wolfgang Druschke, Albrecht Zosel
Abstract: The present invention is based upon the discovery that a styrene-butadiene composition contatining about 0.1 to 10 weight % of a monoester of maleic acid or fumaric acid provides improved bonding strength. In addition, small amounts of a functional monomer can also be included.
Type:
Grant
Filed:
July 18, 1988
Date of Patent:
October 24, 1989
Assignee:
Reichhold Chemicals, Inc.
Inventors:
Cronin Rebecca L. Durney, Rutherford W. Scott, James F. Campbell
Abstract: Process for the preparation of aqueous solutions of hydrolysed styrene/acrylonitrile copolymers, the carboxyl groups of which are entirely or partly present as NH.sub.4 and/or alkali metal salt, characterized in that(a) 40-90% by weight of acrylonitrile,(b) 10-60% by weight of styrene and0-20% by weight of further monomer which can be hydrolysed by alkaliare subjected to suspension or emulsion polymerization, the aqueous dispersion or emulsion is subsequently hydrolysed at 90.degree.-220.degree. C. in the presence of alkali metals and/or alkaline earth metals, and, if appropriate, the copolymer solution is treated with hydrogen peroxide wherein a part of the styrene may be replaced by a further monomer which cannot be hydrolysed by alkali.
Type:
Grant
Filed:
July 12, 1988
Date of Patent:
May 23, 1989
Assignee:
Wolff Walsrode AG
Inventors:
Lutz Hoppe, Helmut Huhn, Werner Karstens, Eugen Reinhardt
Abstract: Surface treating water-absorbent resins with a polyquaternary amine substantially increases both the rate of water absorption and the quantity of water absorbed and retained by the resin. In addition to improved water absorbing properties, the surface-treated resins maintain the necessary "dry feel" required for most applications.
Type:
Grant
Filed:
April 25, 1988
Date of Patent:
April 25, 1989
Assignee:
American Colloid Company
Inventors:
William Alexander, Mark Anderson, Barbara R. Regan
Abstract: An aqueous dispersion of a vinyl copolymer resin is prepared by polymerizing 1 to 15 parts by weight of a polyoxyethylene-containing hydrophilic polymerizable vinyl monomer of which polyoxyethylene moiety has an average molecular weight of 2,000 to 10,000, 99 to 85 parts by weight of at least one specific polymerizable vinyl monomer and 0 to 5 parts by weight of alpha, beta-unsaturated carboxylic acids, salts thereof or anhydrides thereof in an organic solvent, and dispersing the resulting vinyl copolymer resin solution in water.
Abstract: A copolymer latex is produced by the emulsion polymerization of 20 to 50% by weight of a conjugated diolefin, 15 to 50% by weight of an aromatic vinyl compound, 0 to 25% by weight of a vinyl cyanide, 5 to 40% by weight of an alkyl ester of an unsaturated carboxylic acid, and 0.5 to 10% by weight of an ethylenically unsaturated acid. First, a monomeric mixture composed of the entire aromatic vinyl compound, the entire vinyl cyanide, at least a part of the conjugated diolefin and at least a part of the ethylenically unsaturated acid, and optionally at least a part of the alkyl ester of an unsaturated carboxylic acid, the amount of the monomeric mixture being 55 to 95% by weight based on the weight of all the monomers used in the process, is polymerized in emulsion. Then, the remainder of the monomers which amounts to 5 to 45% by weight of the weight of all the monomers is added to the above polymerization system and the mixture is polymerized in emulsion.
Abstract: Stable amphoteric latices based on conjugated dienes formed by preparing an amphoteric aqueous dispersion of particles by reacting at least one unsaturated nitrogen compound capable of being hydrolyzed in an acid or alkaline medium with an aqueous emulsion reaction medium, containing cationic species, and polymerizing, in the aqueous dispersion, without prior neutralization of the dispersion, at least one conjugated diene or a mixture of conjugated dienes and at least one non-ionic monomer in the presence of an initiator selected from the group consisting of an uncharged initiator and a cationic-charge-generating initiator.
Abstract: An aqueous emulsion comprising a polymeric resin prepared by polymerizing (a) at least one amino acid of either one of the formula: ##STR1## and the formula: ##STR2## with (b) at least one other polymerizable monomer in an aqueous medium, the component (a) and at least a portion of the component (b) being introduced separately into the reaction system.
Abstract: A sizing composition and method of preparing sized glass fiber strand is provided to produce sized glass fiber strand that has reduced tackiness. The sizing composition has a low molecular weight liquid polymer selected from the group consisting of styrene-butadiene copolymer, acrylonitrile-butadiene copolymer or hydroxy or carboxy derivatives of said copolymers, epoxy resins, polyester resins, or polyurethane resins that are free radically curable; and a free radical precurser selected from the group consisting of peroxides, hydroperoxides in an amount in the range of about 0.2 to 5 parts per hundred parts of liquid polymer in said sizing composition; or the said liquid polymer that can be treated with radiation to produce an equivalent amount of free radicals.
Abstract: Aqueous dispersions containing from 30% to 70% by weight of cross-linkable copolymers based on esters of (meth)acrylic acid comprising esters of (meth)acrylic acid and/or styrene, and other ethylenically-unsaturated compounds copolymerizable therewith and from 1% to 15% by weight based on the total weight of the copolymer, of allyl esters of .alpha.-hydroxycarboxylic acids. These dispersions can be used as a base of stoving enamels, which can be hardened to obtain coats of great surface hardness and great flexibility on metals.
Type:
Grant
Filed:
June 11, 1980
Date of Patent:
June 22, 1982
Assignee:
Wacker-Chemie GmbH
Inventors:
Klaus Marquardt, Herbert Eck, Werner Bathelt