Two Or More Halogenated Hydrocarbon Monomers Patents (Class 524/835)
  • Publication number: 20140011936
    Abstract: Provided is a polychloroprene latex that shows favorable low-temperature stability without deterioration in the rubber agglutinating property during production of the dip-molded article, a rubber composition, and a dip-molded article, prepared by using the same. Prepared is a polychloroprene latex of a chloroprene copolymer obtained by polymerization of raw monomers at least containing chloroprene and 2,3-dichloro-1,3-butadiene, which is dispersed in water, wherein the 2,3-dichloro-1,3-butadiene content in the raw monomers is controlled to 1 to 30 mass % and the potassium ion content is adjusted to 0.7 to 1.5 parts by mass and the sodium ion content to 0.2 part or less by mass with respect to 100 parts by mass of the solid matter. In addition, a metal oxide: 1 to 10 parts by mass, sulfur: 0.1 to 3 parts by mass, an aging inhibitor: 0.1 to 5 parts by mass and a surfactant: 0.
    Type: Application
    Filed: March 29, 2012
    Publication date: January 9, 2014
    Applicant: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Ikuka Hashimoto, Hiroyuki Yashima, Takeo Mori
  • Patent number: 8541524
    Abstract: Process of controlled free-radical polymerization in aqueous dispersion for the preparation of a block copolymer at least one block of which is a block of a halogenated polymer using molecular iodine and at least one oxidant whose solubility in water is at least 10 g/l for the synthesis of the first block of the block copolymer.
    Type: Grant
    Filed: July 4, 2007
    Date of Patent: September 24, 2013
    Assignee: Solvay (Societe Anonyme)
    Inventors: Christophe Fringant, Yves Vanderveken, Patrick Lacroix-Desmazes, Jeff Tonnar
  • Patent number: 7820747
    Abstract: An aqueous composition that includes (A) a butadiene polymer latex that is prepared by an emulsion polymerization in the presence of a styrene sulfonate stabilizer and (B) a phenolic resin. A preferred aqueous butadiene polymer latex is one that is prepared by emulsion polymerization of at least 60 weight percent dichlorobutadiene monomer (based on the amount of total monomers used to form the butadiene polymer), in the presence of a styrene sulfonate stabilizer.
    Type: Grant
    Filed: October 22, 2007
    Date of Patent: October 26, 2010
    Assignee: Lord Corporation
    Inventors: Helmut W. Kucera, Thomas Rizzo
  • Patent number: 7214740
    Abstract: The present invention is a fluoropolymer comprising a plurality of pendent groups terminating in —CF2SO3X, —CF2SO2F, or combinations thereof, where X is selected from a group consisting of H+ and a monovalent cation, and at least one —CF2Y end group, where Y is selected from a group consisting of a chlorine atom, a bromine atom, an iodine atom, a nitrile group, and an —SO3X group.
    Type: Grant
    Filed: May 3, 2005
    Date of Patent: May 8, 2007
    Assignee: 3M Innovative Properties Company
    Inventors: Kai H. Lochhaas, Klaus Hintzer, Steven J. Hamrock, Michael A. Yandrasits
  • Patent number: 7073201
    Abstract: A two part aqueous adhesive comprising a main agent containing a polychloroprene latex as a main component and a curing agent, the main agent and the curing agent being separated during storing or transporting.
    Type: Grant
    Filed: March 29, 2002
    Date of Patent: July 11, 2006
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Kiyoshi Sunada, Kunio Kaneda, Mikio Yamaguchi
  • Patent number: 6639011
    Abstract: A polymerization process in aqueous emulsion of: (I) one or more fluorinated monomers containing at least one ethylene unsaturation; (II) one or more fluorinated monomers, containing sulphonyl groups —SO2F; said process comprising the use of a surfactant having the formula: Rf—X−M+  wherein X is equal to —COO, —SO3; M is selected from H, NH4, alkaline metal; Rf represents a (per)fluoropolyether chain, preferably having number average molecular weight comprised between about 230 and about 1,800.
    Type: Grant
    Filed: December 20, 2002
    Date of Patent: October 28, 2003
    Assignee: Ausimont S.p.A.
    Inventors: Vincenzo Arcella, Alessandro Ghielmi, Giulio Tommasi
  • Patent number: 6576703
    Abstract: Process for the preparation of a dispersion based on homopolymers/copolymers of tetrafluoroethylene (TFE), said dispersion having a bimodal or multimodal distribution of the particle diameters, wherein the fraction of small particles is in the range 1.5-35% by weight calculated on the dry product; the ratio between the average diameter of the small particles with respect to the average diameter of the dispersion obtained from the polymerization being in the range 0.02-0.6; said process comprising the following essential steps: (a) preparation of an aqueous microemulsion comprising fluorinated surfactants and (per)fluoropolyether oils (PFPE); (b) feeding of the microemulsion into the polymerization reactor; (c) feeding of at least one fluorinated surfactant.
    Type: Grant
    Filed: February 22, 2001
    Date of Patent: June 10, 2003
    Assignee: Ausimont S.p.A.
    Inventors: Valery Kapeliouchko, Enrico Marchese
  • Patent number: 5985993
    Abstract: A method for preparing a polybutadiene latex comprises providing an emulsion polymerization medium by reacting water, butadiene monomers, a surfactant, a chain transfer agent, an initiator and an electrolyte, preferably at a temperature of about 60.about.80.degree. C., preferably for about 8.about.16 hours, and agglomerating the resulting emulsion polymerization medium, preferably at a temperature of about 5.about.20.degree. C. higher than the polymerization temperature, preferably for about 4.about.12 hours by adding a surfactant and an agglomerating agent to the emulsion polymerization medium in consecutive order. The agglomerating agent is prepared a method comprising a first step of forming agglomerating seeds by batch polymerization of an alkyl acrylate of C.sub.1 .about.C.sub.12, an anionic surfactant and an anionic initiator, a second step of growing the agglomerating agent in semi-batch polymerization by adding an alkyl acrylate of C.sub.1 .about.C.sub.
    Type: Grant
    Filed: December 30, 1996
    Date of Patent: November 16, 1999
    Assignee: Cheil Industries, Inc.
    Inventors: Byeong-do Lee, Dong-un Jin
  • Patent number: 5532300
    Abstract: A specific class of water-borne, water redispersible laminating adhesives is disclosed which is desirable for bonding nonwoven substrates to themselves or to other substrates. The adhesives provide improved bond strength and improved water redispersibility when compared to laminating adhesives currently used for the same purpose. Furthermore, the novel adhesives are much less sensitive to the presence of significant levels of plasticizer than are laminating adhesives currently used, which exhibit reduced water redispersibility when such plasticizers are present in significant amounts. The novel laminating adhesives contain an aqueous styrene/acrylic polymer dispersion prepared by radical-initiated emulsion polymerization of unsaturated monomers in the presence of starch degradation products having a weight average molecular weight range of from about 2500 to 25000 and which are obtainable by hydrolysis in the aqueous phase.
    Type: Grant
    Filed: August 12, 1994
    Date of Patent: July 2, 1996
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Timothy C. Koubek, Paul P. Puletti, Joseph Wieczorek, Jr.
  • Patent number: 5438096
    Abstract: Improved flame retardant polymer latices are disclosed which comprise copolymers of ring-halogenated aromatic monomer units and alkyl acrylate/methacrylate monomer units, and which may additionally include at least one other monomer. In a first embodiment, the latices include ring-brominated aromatic monomer units and alkyl acrylate and/or alkyl methacrylate monomer units. In a second embodiment, the latices include these first two types of monomer units and further include third monomer units from unsaturated esters of saturated carboxylic acids, halogen-free aromatic monomers or unsaturated carboxylic or dicarboxylic acid monomers. In a third embodiment, the latices include four monomer units, namely ring-brominated aromatic monomer units, alkyl acrylate/methacrylate monomer units, halogen-free aromatic monomer units and unsaturated carboxylic or dicarboxylic acid monomer units.
    Type: Grant
    Filed: May 16, 1994
    Date of Patent: August 1, 1995
    Assignee: Great Lakes Chemical Corporation
    Inventors: Jin-liang Wang, Nicolai A. Favstritsky, Richard S. Rose
  • Patent number: 5358998
    Abstract: Aqueous polymer dispersions containing polymers obtainable by free-radical polymerization of unsaturated monomers, and sugared starch, and the use thereof.
    Type: Grant
    Filed: October 7, 1992
    Date of Patent: October 25, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Kurt Wendel, Thomas Schwerzel, Guenter Hirsch
  • Patent number: 5326557
    Abstract: Moisturizing compositions for a human skin which contain oxyethylene function organosilanes. When used in skin care applications, these compounds exhibit humectant properties. The oxyethylene functional organosilane is a compound having the formula RSiR'.sub.3 in which R is the radical --O(CH.sub.2 CH.sub.2 O).sub.x R"; R' is an R group or an alkyl radical having one to six carbon atoms; R" is a radical such as hydrogen; an alkyl group of one to six carbon atoms; and an aryl group; and x is an integer having a value of six to thirty.
    Type: Grant
    Filed: April 6, 1993
    Date of Patent: July 5, 1994
    Assignee: Dow Corning Corporation
    Inventors: David A. Glover, Gary E. LeGrow, Linda M. Madore, Regina M. Malczweski