Abstract: A conjugated diene rubber gel comprising 80-99 weight % of conjugated diene monomer units and 20-1 weight % of aromatic vinyl monomer units and having a swelling index of 16 to 70 as measured in toluene. A rubber vulcanizate made from a rubber composition comprising this conjugated diene rubber gel and a rubber capable of being crosslinked with sulfur exhibits good abrasion resistance and low heat-build up without deterioration of mechanical properties, and thus, is suitable for tire materials. This conjugated diene rubber gel can be produced with high efficiency by emulsion-polymerization of a monomer mixture comprising 50-99.9 weight % of a conjugated diene monomer, 0-30 weight % of an aromatic vinyl monomer, 0-20 weight % of other ethylenically unsaturated monomer and 0.1-20 weight % of a crosslinking monomer.

Abstract: A device for producing disperse mixtures by ultrasound, containing a housing, and a reaction chamber within the housing and at least one sonotrode having a free emitting surface which is directly in effective connection with the reaction chamber and whose end remote from the free emitting surface is coupled to an ultrasonic transducer, wherein the sonotrode is designed as a rod-shaped, axially emitting longitudinal oscillator with the emitting surface corresponding essentially to the surface of the reaction chamber, and wherein the reaction chamber depth which is essentially vertical with respect to the emitting surface is lower than a maximum effective depth of the sonotrode.

Abstract: This invention relates to an asphalt modifier comprising 5˜30 wt. %. of solubilized styrene-butadiene-styrene block copolymer and 70˜95 wt. % of solubilized styrene-butadiene latex, which has an excellent resistance property against plastic deformation, while preventing the occurrence of crack at a low temperature.

Abstract: The invention relates to the use of aqueous polymer dispersions comprising at least one hydrogenated styrene-butadiene copolymer CP, for producing barrier coatings on paper, cardboard, or paperboard.

Abstract: Submicron sized particles of poly(methyl methacrylate) are prepared by a surfactant-free semi-continuous emulsion polymerization process that involves (i) preparing an aqueous phase containing a free radical initiator in water by heating and stirring, (ii) preparing a monomer composition containing at least 80% by weight methyl methacrylate and 1 to 10% by weight of a crosslinking agent, (iii) adding the monomer composition to the aqueous phase to initiate emulsion polymerization of the monomer composition, the adding being done at a rate such that from 0.05% to 5% by weight of the total weight of the monomer composition is added per minute, (iv) continuing heating and stirring following completion of the adding of the monomer composition for an amount of time, and (v) drying and recovering the submicron sized particles of poly(methyl methacrylate). The submicron sized particles of poly(methyl methacrylate are used in forming a coating of carrier particles for a two-component developer composition.

Abstract: This invention is based upon the unexpected discovery that the physical properties of rubber products made with styrene-butadiene rubber can be significantly improved by synthesizing the styrene-butadiene rubber by a process which comprises (1) charging water, a soap system, a free radical generator, 1,3-butadiene monomer and styrene monomer into a first polymerization zone; (2) allowing the 1,3-butadiene monomer and the styrene monomer to copolymerize in the first polymerization zone to a monomer conversion which is within the range of about 15 percent to about 40 percent to produce a low conversion polymerization medium; (3) charging the low conversion polymerization medium into a second polymerization zone; (4) charging an additional quantity of 1,3-butadiene monomer and an additional quantity of styrene monomer into the second polymerization zone; (5) allowing the copolymerization to continue until a monomer conversion of at least about 50 percent is attained to produce the latex of styrene-butadiene rubb

Abstract: A semi-batch process is provided for making a diene rubber latex. The process involves (a) providing an amount of an initial liquid batch composition (containing water, emulsifier and diene monomer), sufficient to occupy from 50 to 80 volume percent of a pressure reaction vessel based on the total volume of the vessel, (b) feeding to the vessel a liquid feed composition containing diene monomer and initiator, (c) providing cooling to the vessel to cool the liquid and vapor therein, and (d) reacting the diene monomer to a final diene monomer conversion level of at least 80 mol percent based on the total moles of diene monomer used in the reaction, and the final liquid volume level in the vessel being at least 80 volume percent based on the total volume of the vessel.

Abstract: Mercaptans are normally used as chain transfer agents in emulsion polymerizations. The mercaptans used in commercial applications are typically complex mixtures of hundreds of similar compounds having boiling points within a narrow range. The chain transfer activity of different mercaptans with such mixtures can vary substantially. To further complicate the situation, the distribution of various mercaptans can also vary substantially between lots of material obtained from commercial sources. Thus, consistent molecular weight control is typically difficult to attain in free radical emulsion polymerizations. This invention is based upon the unexpected discovery that dibenzyltrithiocarbonate will act as a pure compound to effectively and consistently control molecular weight in free radical emulsion polymerizations. The polydispersity of polymers made using dibenzyltrithiocarbonate as a molecular weight regulator is similar to that obtained using conventional mercaptan systems.

Abstract: A method for preparing a polybutadiene latex comprises providing an emulsion polymerization medium by reacting a mixture of water, butadiene monomers, a surfactant, a chain transfer agent, an initiator and an electrolyte, preferably at a temperature of about 60˜80° C., preferably for about 8˜16 hours, and agglomerating the resulting emulsion polymerization medium, preferably at a temperature of about 5˜20° C. higher than the polymerization temperature, preferably for about 4˜12 hours by adding a surfactant and an agglomerating agent to the emulsion polymerization medium in consecutive order.

Abstract: A method of producing silicone-containing aqueous coating compositions excellent in shelf stability of the emulsion and in weather resistance, stain resistance, water resistance and solvent resistance of coatings derived therefrom is provided. The method comprises subjecting an aqueous emulsion prepared in advance by emulsification in an aqueous medium containing a polyalkoxypolysiloxane (A), an unsaturated monomer (B) and an emulsifier (C) so as to attain an oil droplet diameter not more than 1,000 nm to polymerization in the presence of a polymerization initiator (D).

Abstract: A water dispersed primer composition comprising a solution of a halogenated hydrocarbon polymer in organic solvent; and a dispersing agent added to the solution to form a fluid primer to be dispersed in water to provide the water dispersed primer composition. The invention further includes a water based priming adhesive composition comprising an adhesive dispersion of a an adhesive polymer dispersed in water, and a primer mixed with the adhesive dispersion to form the priming adhesive. The primer comprises a solution of a halogenated hydrocarbon polymer in organic solvent and optionally a dispersing agent.

Abstract: Applications of barrier coating mixtures containing in a carrier liquid, (a) an elastomeric (preferably butyl-containing) polymer; (b) a dispersed exfoliated layered filler having an aspect ratio greater than 25; and (c) at least one surfactant, wherein the solids content of the mixture is less than 30% and the ratio of polymer (a) to filler (b) is between 20:1 and 1:1 include coated articles, which are elastomeric, e.g., sports balls and inflatable articles. Methods of manufacturing such coated products are also encompassed.

Abstract: A process for the preparation of resin particles comprising: adding a mixture of at least one free radical reactive monomer continuously to a heated aqueous solution of a water soluble free radical initiator and a water soluble salt to form latex emulsion particles and aggregates thereof; and wherein the rate of continuous addition of said monomer is greater than the rate at which monomer is consumed by polymerization.

Abstract: It is desirable to reduce the amount of volatile organic blowing agent in expandable polystyrene. This may be accomplished by partially polymerizing a mass of styrene and incorporating therein water together with an emulsifier. The partially polymerized mass is then polymerized to a high conversion using conventional suspension techniques. The polymer beads containing water which acts as a blowing agent are recovered.

Abstract: A method is described for protection against fire with coating and paint compositions for houses, polymer constructions, industrial installations, and transport vehicles, in which polymeric products produced by processing polystyrene and copolymers to macroreticular structure are introduced with the incorporation of ionic groups at high density, thus acquiring the potential to very strongly absorb water up to 400 times weight endomolecularly. They can be used in paint and general coating compositions as a first surface coating or can be in aqueous paint emulsions as a main coating. Inorganic materials such as lime, gypsum, silicones etc. can also be added. The products in the coating compositions when burned or decomposed in a fire edge release much water and quenches the fire immediately offering complete protection against fire.

Abstract: General purpose inherently tacky acrylic pressure sensitive adhesive polymers formed of alkyl acrylates, vinyl esters, and saturated carboxylic acids, having improved properties, a lower residual monomer content are formed by a sequential emulsion polymerization process in which 40 to 70 percent, typically 45 percent, of the monomers are incrementally added to a reactor as a first charge containing substantially all of the vinyl esters, the balance of the monomers being fed in a second incremental charge.

Abstract: Barrier coating mixtures contain in a carrier liquid, (a) an elastomeric (preferably butyl-containing) polymer; (b) a dispersed exfoliated layered filler having an aspect ratio greater than 25; and (c) at least one surfactant, wherein the solids content of the mixture is less than 30% and the ratio of polymer (a) to filler (b) is between 20:1 and 1:1. Coated articles, which are rigid or flexible and elastomeric, and free-standing films and membranes, which are flexible and elastomeric, are produced using the barrier coating mixtures.

Abstract: A method for preparing a polybutadiene latex comprises providing an emulsion polymerization medium by reacting water, butadiene monomers, a surfactant, a chain transfer agent, an initiator and an electrolyte, preferably at a temperature of about 60.about.80.degree. C., preferably for about 8.about.16 hours, and agglomerating the resulting emulsion polymerization medium, preferably at a temperature of about 5.about.20.degree. C. higher than the polymerization temperature, preferably for about 4.about.12 hours by adding a surfactant and an agglomerating agent to the emulsion polymerization medium in consecutive order. The agglomerating agent is prepared a method comprising a first step of forming agglomerating seeds by batch polymerization of an alkyl acrylate of C.sub.1 .about.C.sub.12, an anionic surfactant and an anionic initiator, a second step of growing the agglomerating agent in semi-batch polymerization by adding an alkyl acrylate of C.sub.1 .about.C.sub.

Abstract: Provided is an erasable ink comprising an emulsion liquid prepared by polymerizing a polymerizable monomer containing a conjugate diene compound in a solvent containing water in the presence of a dye and a surfactant, wherein the polymerizable monomer may contain a vinyl compound as well as a conjugate diene compound, and used are 0.01 to 100 parts by weight of the dye and 0.1 to 30 parts by weight of the surfactant each per 100 parts by weight of the polymerizable monomer.

Abstract: A process for the preparation of resin particles comprising:adding a mixture of at least one free radical reactive monomer continuously to a heated aqueous solution of a water soluble free radical initiator and a water soluble salt to form latex emulsion particles and aggregates thereof; and wherein the rate of continuous addition of said monomer is greater than the rate at which monomer is consumed by polymerization.

Abstract: A composition including polyalphaolefins that function as drag reducing agents and a process for the preparation of polyalphaolefins that function as drag reducing agents are disclosed. The process includes contacting alphaolefin monomers with catalyst particles in a polymerization mixture that includes a hydrocarbon solvent. The polymerization of the alphaolefin monomers produces polyalphaolefin drag reducing agents having an inherent viscosity of at least 10 dL/g. During polymerization of the polyalphaolcfin monomers, localized micelles compromising high molecular weight polyalphaolefin polymer are formed in micellar zones around the catalyst particles. The polymerization is conducted in the presence of a viscosity reducing agent that includes a substantially hydrophobic dispersant. The viscosity reducing agent is present in an amount sufficient to reduce the viscosity of the reaction mixture and disperse the localized micelles.

Abstract: Water recovered from the polymerization of vinyl monomers can be treated to remove or deactivate chain transfer agents present in the water allowing resuse in polymerization processes. The water recovered from a vinyl polymerization reaction is contacted with a cation exchange resin in the hydrogen form prior to recycle, or may be acidified and then contacted with an anion exchange resin in the hydroxide form.

Abstract: Latices based on conjugated dienes are produced using emulsion polymerization by introducing the monomers to be polymerized into the initially introduced seed latex in the presence of a free-radical forming activator and an emulsifier in such a manner that the ratio of the monomer polymerization rate to the monomer feed rate is less than 0.7:1 and by performing polymerization up to a monomer conversion of .gtoreq.95% at temperatures of 10 to 85.degree. C., wherein the addition of the emulsifier is controlled in such a manner that the final particle size (TG.sub.L) of the latex to be produced is governed by the following equation:TG.sub.L =TG.sub.S .times.(m.sub.L /D.sub.L).sup.1/3 (m.sub.S /D.sub.S).sup.1/3,in whichD.sub.L =density of the latex particles in the latex to be producedD.sub.S =density of the particles of the seed usedm.sub.L =mass of the latex particles in the latex to be producedm.sub.S =mass of the particles of the seed usedTG.sub.L =particle size of the latex to be producedTG.sub.

Abstract: The invention relates to the use of macrocyclic metal complexes that consist of a complexing agent of formula I and at least one metal ion of an element of atomic numbers 21-29, 42, 44 or 57-70 ##STR1## in which n, R.sup.1, R.sup.2, R.sup.3 and A are as set forth in the specification, are useful as temperature sensors.

Abstract: A process for producing a polymer toner comprises the steps of pouring a polymerizable monomer composition containing at least a polymerizable monomer and a colorant, but containing no oil-soluble polymerization initiator into an aqueous dispersion medium containing a dispersing agent; adding an oil-soluble polymerization initiator to the polymerizable monomer composition while stirring the composition to form primary droplets thereof, thereby bringing the droplets of the polymerizable monomer composition into contact with droplets of the oil-soluble polymerization initiator to form droplets of a polymerizable monomer composition containing the oil-soluble polymerization initiator; further continuing the stirring to form secondary droplets having desired droplet sizes; and then conducting suspension polymerization of the polymerizable monomer composition.

Abstract: A process for preparing a copolymer latex comprising emulsion polymerizing an aliphatic conjugated diene monomer and other monomer copolymerizable therewith in the presence of a cyclic unsaturated hydrocarbon having one unsaturated bond in a ring, in which, preferably a monomer mixture which does not contain the aliphatic conjugated diene monomer is added after the addition of a monomer mixture containing the aliphatic conjugated diene monomer, or a part of a chain transfer agent is added after the addition of the monomers. This copolymer latex is useful as an adhesive composition, a paper coating composition, an adhesive composition for back-sizing carpets, an adhesive composition for rock fiber materials, a paper coating composition for gravure printing, and a color developing composition for a pressure sensitive copying paper.

Abstract: An aqueous reaction mixture having a pH of 4.5 to 5.5 of a methyl terminated siloxane emulsified polymer, a methyl triethoxysilane, a mixture of nonyl and octyl phenol derivative surfactants, fluorinated alkyl ester surfactant and synthetic ethoxylated amine surfactants, a silanol terminated polydimethylsiloxane hydroxyl terminated polybutadiene and ethanol. The reaction mixture is coated on a mold core surface and cured with heat to form a mold release surface that can be used in excess of twelve times prior to recoating.

Abstract: This invention discloses a process for preparing a latex of styrene-butadiene rubber which comprises (1) charging water, a soap system, a free radical generator, 1,3-butadiene monomer, and styrene monomer into a first polymerization zone; (2) allowing the 1,3-butadiene monomer and the styrene monomer to copolymerize in the first polymerization zone to a monomer conversion which is within the range of about 15% to about 40% to produce a low conversion polymerization medium; (3) charging the low conversion polymerization medium into a second polymerization zone; (4) charging an additional quantity of 1,3-butadiene monomer and an additional quantity of styrene monomer into the second polymerization zone; (5) allowing the copolymerization to continue until a monomer conversion of at least about 50% is attained to produce the latex of styrene-butadiene rubber. This technique can also be utilized to synthesize polybutadiene latex or nitrile rubber latex by emulsion polymerization with low levels of soap.

Abstract: A method of producing a high solids adhesive is provided wherein a buffered latex emulsion, such as, for example, styrene butadiene latex emulsion buffered to a pH of 11.0 using caustic agents, is combined with a non-emulsified mixture of dissolving process oils and tackifying resins and mineral fillers. The resultant adhesive has a solids content greater than previously achieved in the industry and has exceptional adhesive characteristics such as increased bond strength, improved durability, better aging, faster drying, improved water resistance and improved freeze resistance. High solids content is achieved by taking advantage of the excess emulsifiers in the latex emulsion and adding the remaining constituent components directly to the stabilized latex emulsion.

Abstract: A process for producing an anti-slip article by preparing an aqueous dispersion containing a copolymer of styrene and a diene in a ratio by weight of from 20:80 to 80:20, and applying the aqueous dispersion onto a non-water-absorbing article.

Abstract: A specific class of water-borne, water redispersible laminating adhesives is disclosed which is desirable for bonding nonwoven substrates to themselves or to other substrates. The adhesives provide improved bond strength and improved water redispersibility when compared to laminating adhesives currently used for the same purpose. Furthermore, the novel adhesives are much less sensitive to the presence of significant levels of plasticizer than are laminating adhesives currently used, which exhibit reduced water redispersibility when such plasticizers are present in significant amounts. The novel laminating adhesives contain an aqueous styrene/acrylic polymer dispersion prepared by radical-initiated emulsion polymerization of unsaturated monomers in the presence of starch degradation products having a weight average molecular weight range of from about 2500 to 25000 and which are obtainable by hydrolysis in the aqueous phase.

Abstract: Aqueous polymer dispersions containing polymers obtainable by free-radical polymerization of unsaturated monomers, and sugared starch, and the use thereof.

Abstract: Dispersions of hydrophobic substance e.s. resin emulsions, usually having a relatively low average particle size can be continuously and speedily prepared by feed a hydrophobic substance in the liquid state into at least two static mixers, arranged in a series. The resin is introduced at a temperature above 50 degrees C. but below its degradation temperature of hydrophobic substance and water under pressure is introduced into the first mixer. The mixture of resin and water is passed to another mixer maintained at a temperature lower than that prevailing in the first mixer and below the boiling point of water. Optionally aqueous solution of surfactant under pressure instead of water is introduced into the first mixer and optionally aqueous surfactant is introduced into the second mixer.

Abstract: Odorless, aqueous copolymer dispersions are produced by emulsion copolymerizing a comonomer recipe which comprises at least 60% by weight of styrene and/or butadiene and/or an acrylic ester and/or a vinyl nitrile, and, optionally, up to 40% by weight of at least one other copolymerizable comonomer, in an aqueous medium of copolymerization, in the presence of an alkoxy, aryloxy, acyloxy or acylamino substituted diphenyl disulfide chain transfer agent.

Abstract: A process is described for the production of an aqueous polymer dispersion by polymerization of ethylenically unsaturated compounds by means of free-radical initiators in the presence of starch and/or starch derivatives and optional further conventional adjuvants, and which the dispersions are coagulate-free, have a low viscosity, and a small particle size, said process comprising polymerizing an ethylenically unsaturated diene monomer or mixture of monomers consisting of20 to 100% by weight of a diene,0 to 80% by weight of a vinyl-aromatic monomer,0 to 50% by weight of an ethylenically unsaturated monomerin the presence of an aqueous solution or dispersion of dextrins containing 10 parts to 200 parts by weight dextrins, which are optionally chemically modified, wherein the content of said dextrins having a molecular weight in excess of 5000 is at least 50% by weight and the content of dextrins having a molecular weight in excess of 100,000 is not in excess of 5% by weight of the dextrin component.

Abstract: A process for preparing a dispersion of a filler e.g., melamine, urea or borax in a dispersion or graft polymer polyol is provided. The process comprises (1) dispersing the filler in a suitable basestock (e.g., a polyether polyol) and (2) thereafter using this as the basestock for preparing the dispersion or graft polymer polyol.The polymer which is prepared in dispersed form in the second step may be for example (1) the reaction product of a polyamine, hydrazine or hydrazide and an isocyanate (PHD polymer) or (2) the reaction product of an olamine and an isocyanate (PIPA polymer). Alternatively styrene and acrylonitrile can be graft polymerised in the basestock in step (2). The new dispersion or graft polymer polyols containing dispersed filler are useful in the manufacture of fire resistant polyurethane foam for e.g., furniture applications.

Abstract: There is described a process for the production of pigment/plastic premixes characterized by homogeneous distribution of pigment in a polymer matrix. The invention is based on the polymerization of olefins carried out by means of a process using Ziegler catalyst. Significantly the polymerization occurs on the surface of the pigment particles, after the prior activation of the pigment particles.

Abstract: A process for the preparation of polymers which comprises forming an aqueous phase comprised of water and a surfactant; adding to the aqueous phase monomers; subsequently initiating polymerization of the monomers; thereafter adding a stabilizing component; and completing the polymerization.

Abstract: The subject invention relates to a process for treating an emulsion of a crosslinked elastomeric polymer containing residual hydrazine to obtain a latex of soluble elastomeric polymer having a reduced concentration of residual hydrazine therein, said process comprising the addition of ozone to said emulsion in an amount and under conditions which are sufficient for the ozone to react with the crosslinked elastomeric polymer and the residual hydrazine to produce a latex of soluble elastomeric polymer having a reduced level of residual hydrazine therein. The process of the present invention also improves the color of latex by removing color-bodies, such as benzoquinone, which may be present in the original latex.

Abstract: An aqueous mold release agent for the production of molded polyurethane articles, especially polyurethane soft foam articles, is provided which contains as substance effecting mold release at least a portion of one or more unsaturated oligomeric or polymeric hydrocarbons having molecular weights of at least 500 and iodine values of at least 60, preferably in combination with one or more foam stabilizers suited for polyurethane systems.

Abstract: Method and apparatus for forming emulsions, a term used to include microemulsions. The leading edges of a plurality of sheets of an emulsion-forming liquid mixture are forced under pressure to impinge in a low-pressure turbulent zone of the liquid. The apparatus comprises a plurality of nozzles having elongated orifices to eject under pressure sheets of the emulsion-forming liquid and being arranged to effect impingement of the sheets along a common liquid jet interaction front. Inasmuch as the method and apparatus permit the formulation of emulsions without the use of any emulsifiers, there is provided a new class of emulsions, namely those essentially free of any emulsifying agents. The emulsions formed have a wide range of applications.

Abstract: This invention reveals a technique for preparing syndiotactic 1,2-polybutadiene latex. It more specifically discloses a process for synthesizing syndiotactic 1,2-polybutadiene latex by polymerizing 1,3-butadiene in an aqueous medium in the presence of (1) at least one emulsifier, (2) a catalyst emulsion composition which is prepared by a microfluidization or microemulsification process, and (3) at least one member selected from the group consisting of carbon disulfide and phenyl isothiocyanate. Such syndiotactic 1,2-polybutadiene latices can be utilized in preparing blends of syndiotactic 1,2-polybutadiene with rubbers which are prepared by emulsion polymerization.

Abstract: Process for the preparation of polymer dispersions with particle diameters of 50 to 1000 nm, wherein there are employed, as emulsifiers for the emulsion polymerization citric acid derivatives of the general formula (I) ##STR1## in which, independently of one another, R.sub.1, R.sub.2 and R.sub.3 denote C.sub.6 -C.sub.20 -alkyl, (including cycloalkyl) hydrogen, sodium, potassium, lithium or ammonium andR.sub.4 denotes hydrogen or acetyl,with the proviso that at least one of the radicals R.sub.1 to R.sub.3 denotes alkyl, and as initiators water-soluble agents which form free radicals or redox systems with at least one water-soluble component.

Abstract: A method for forming shaped hydrogel articles such as soft contact lenses wherein hydrophilic monomers are mixed with an inert diluent prior to polymerization, and the diluent is replaced with water following the polymerization. Diluents yielding optically clear hydrogels with good mechanical properties are selected on the basis of their viscosity and their Hanson cohesion parameters relative to the cohesion parameters of the polymeric component of the hydrogel.

Abstract: Disclosed is an improved process for affecting preparation of resin particles by a bead polymerization reaction which for example comprises (1) providing a solution mixture of water, suspension agent, and surfactant; (2) adding thereto while stirring a monomer component, a low molecular weight wax, and a polymerization initiator; (3) affecting polymerization of the monomer by heating the resulting solution at a temperature of from about 90 degrees Centigrade to about 120 degrees Centigrade; and (4) separating the resulting polymer from the reaction mixture.

Abstract: Beads comprising a polymeric matrix containing a releasable lipophilic compound are made by precipitating the compound from solution within the matrix. Beads may be made by forming a homogeneous blend of the compound in lipophilic polymerizable material and subjecting the blend to bead polymerization while the blend is dispersed as beads in an aqueous medium containing hydrophilic polymerization stabilizer. The lipophilic compound may be a behenyl ester wax inhibitor or other reagent useful downhole or for other purposes and preferably has a relatively high melting point. The polymerizable material preferably dissolves the lipophilic compound and may include acrylic acid, methacrylic acid or other hydrophilic polymerizable material.

Abstract: A latex for immunoserological tests containing polystyrene and/or polystyrene derivative particles which are prepared by polymerizing styrene and/or styrene derivatives in the absence of emulsifying agents, said particles having uniform diameters and a specific gravity of 1.05 or more.

Abstract: Disclosed is an improved process for affecting preparation of resin particles by a bead polymerization reaction which for example comprises (1) providing a solution mixture of water, suspension agent, and surfactant; (2) adding thereto while stirring a monomer component, a low molecular weight wax, and a polymerization initiator; (3) affecting polymerization of the monomer by heating the resulting solution at a temperature of from about 90 degrees Centigrade to about 120 degrees Centigrade; and (4) separating the resulting polymer from the reaction mixture.

Abstract: Residual monomer may be removed from a polymeric emulsion by subjecting it to pressure and temperature conditions so that the ambient vapor pressure is less than the vapor pressure in the emulsion and concurrently and continuously during the treatment adding a free radical initiator.

Abstract: A method and composition are provided for preparing elastomeric polymers containing a particulate rubber filler which are useful to provide relatively thick membranes for flooring, decking, roofing or other purposes and which permit the molding of a wide variety of rubber-like goods. The composition comprises a polyol, an organic polyisocyanate, an alkaline carbon dioxide absorbent and a water carrier in amounts sufficient to form a non-foaming pourable, trowelable or sprayable composition, includes rubber particles to provide increased resiliency, economy and density, and cures internally to provide a polyurethane elastomer coating. A prepolymer may be prepared as a separate component having an extended shelf life and adapted for ultimate combination with an aqueous rubber slurry in order to facilitate simple on site mixing of the composition.