N=c=x Reactant Has Ionic Group Attached Thereto, E.g., Carboxyl Sulfonic, Etc. Patents (Class 524/840)
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Patent number: 6897281Abstract: A breathable polyurethane having an upright moisture vapor transmission rate (MVTR) of more than about 500 gms/m2/24 hr comprises: (a) poly(alkylene oxide) side-chain units in an amount comprising about 12 wt. % to about 80 wt. % of said polyurethane, wherein (i) alkylene oxide groups in said poly(alkylene oxide) side-chain units have from 2 to 10 carbon atoms and are unsubstituted, substituted, or both unsubstituted and substituted, (ii) at least about 50 wt. % of said alkylene oxide groups are ethylene oxide, and (iii) said amount of said side-chain units is (i) at least about 30 wt. % when the molecular weight of said side-chain units is less than about 600 grams/mole, (ii) at least about 15 wt. % when the molecular weight of said side-chain units is from about 600 to about 1,000 grams/mole, and at least about 12 wt. % when the molecular weight of said side-chain units is more than about 1,000 grams/mole, and (b) poly(ethylene oxide) main-chain units in an amount comprising less than about 25 wt.Type: GrantFiled: June 19, 2002Date of Patent: May 24, 2005Assignee: Noveon IP Holdings Corp.Inventors: Alexander V. Lubnin, George E. Snow, Ronald D. Varn, Gary A. Anderle
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Patent number: 6881788Abstract: Polyurethane resin water dispersion being good in storage stability and excellent in initial adhesion and resistance to moist heat, and aqueous polyurethane adhesive employing the polyurethane resin water dispersion. The polyurethane resin water dispersion is produced in the manner that polyisocyanate is allowed to react with polycaprolactone polyol comprising polycaprolactone polyol having a number average molecular weight of not less than 3,000 and active-hydrogen-group-containing compound having anionic group, to synthesize isocyanate terminated prepolymer, first, and, then, the isocyanate terminated prepolymer thus produced is allowed to react with polyamine in water. The use of the polyurethane resin water dispersion can produce the aqueous polyurethane adhesive having improved storage stability, initial adhesion and resistance to moist heat.Type: GrantFiled: August 15, 2002Date of Patent: April 19, 2005Assignee: Mitsui Takeda Chemicals, Inc.Inventors: Hyoue Shimizu, Hiroyuki Shiraki
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Patent number: 6881782Abstract: A latex paint composition comprises (a) a polymer having interpolymerized units that comprise units derived from styrene, methyl styrene, vinyl, or combinations thereof and units derived from one or more acrylates, methacrylates, acrylonitrile, or combinations thereof; (b) hiding pigment; (c) non-cellulosic thickener; and (d) a polyfluorourethane additive that is the reaction product of (i) at least one isocyanate reactant, (ii) at least one fluorochemical compound containing at least one Zerewitinoff hydrogen in an amount sufficient to react with about 5% to about 80% of the isocyanate groups, and (iii) at least one non-fluorinated compound; wherein said latex paint composition has a pigment volume concentration of at least 20% and less than its critical pigment volume concentration.Type: GrantFiled: November 6, 2002Date of Patent: April 19, 2005Assignee: 3M Innovative Properties CompanyInventors: Davis H. Crater, Jason T. Petrin
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Patent number: 6875810Abstract: An aqueous dispersion of a polyurethane resin obtainable from compounds including: (A) an organic polyisocyanate; (B) a polyester polyol containing an aromatic metal sulfonate group; (C) an aliphatic polyol being free from aromatic metal sulfonate and having a hydroxyl value of from 10 to 350; and (D) at least one of a polyamine and a polyol each having a molecular weight of 300 or lower, wherein the content of said aliphatic polyol unit (C) amounts to at least 55% by weight based on the solid content of said polyurethane resin. Also disclosed is an aqueous adhesive comprising the polyurethane resin aqueous dispersion.Type: GrantFiled: October 24, 2001Date of Patent: April 5, 2005Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Mitsuru Kitada, Kazuo Kuba, Yutaka Hashimoto
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Patent number: 6870000Abstract: Increased health, safety, and environmental awareness motivated the development of new and improved water curing technology for formulating, manufacturing, and using water curable compositions (also referred to in the art as water induced urethanes). The present invention is based, at least in part, upon the concept of formulating NCO functional resins used in water curable compositions from one or more polyisocyanate constituents that comprise at least one sterically hindered isomer of diphenyl methane diisocyanate (MDI). These isomers have a combination of exceptionally low vapor pressure and suitable moisture reactivity that lead to numerous advantages. Due to their low volatility, these isomers may be substituted for all or a portion of the TDI content of a conventional water induced urethane formulation. Particularly preferred embodiments eliminate any TDI, have 100% solids, are solvent free, and are characterized by essentially zero VOC emissions with respect to isocyanate.Type: GrantFiled: March 31, 2003Date of Patent: March 22, 2005Inventor: Laxmi C. Gupta
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Patent number: 6858668Abstract: This invention relates to a process for the preparation of aqueous emulsions of blocked (poly)isocyanates, this process comprising the steps consisting successively in: a) placing an isocyanate composition containing free isocyanate functions in contact with at least one blocking agent A in the presence of a surfactant B and an aqueous phase, the said isocyanate composition being added gradually to a stock containing at least some of the aqueous phase and at least some of the blocking agent; and optionally, b) subjecting the mixture obtained to a shear (speed gradient) of greater than 1000 s?1, preferably greater than 20,000 s?1 and less than 1,000,000 s?1, preferably less than 200,000 s?1, and c) repeating step b), optionally after step a) has been repeated, until a stable emulsion is obtained whose particles have a Sauter diameter of greater than 0.1 ?m, preferably 0.2 ?m, and less than 5 ?m, preferably less than 2 ?m, and a dispersion width of less than 5 ?m.Type: GrantFiled: August 27, 1998Date of Patent: February 22, 2005Assignee: Rhodia ChimieInventors: Jean-Marie Bernard, Jean-Pierre Corbet, Minou Nabavi, Philippe Galy-Jammou, Denis Revelant
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Patent number: 6855764Abstract: A method for producing self-emulsifiable, aqueous polyurethane resins by a) preparing a premix of polyol component including a least one diol having a molar mass of 500 to 5,000 Dalton, at least one polyhydroxyalkane at least one anionically modifiable dihydroxyalkane-carboxylic acid and 0 to 9 parts by weight of a solvent component in desired ratios; b) reacting a polyisocyanate component the premix from stage a) to give a polyurethane preadduct, c) reacting the polyurethane preadduct from stage b) with either the premix from stage a) or with an anionically modifiable dihydroxyalkanecarboxylic acid to give a polyurethane prepolymer; d) mixing the polyurethane prepolymer from stage c) with a prepared mixture of water, a neutralizing component and an antifoam component; and thereafter or simultaneously reacting the aqueous polyurethane prepolymer from stage d) with a chain-extending component which is diluted with water.Type: GrantFiled: December 7, 2000Date of Patent: February 15, 2005Assignee: SKW Bauchemie GmbHInventors: Alois Maier, Stefan Ingrisch, Alfred Kern
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Patent number: 6846849Abstract: An embodiment of the present invention includes a foam prepared from a resin comprising: one or more saccharides; one or more isocyanates; one or more resin polyols; and water. The foam may be for example polyurethane foam or polycyanurate foam, either flexible or rigid. Another embodiment includes a method for preparing a foam comprising: forming a resin by mixing one or more saccharides with one or more isocyanates and then mixing the one or more saccharides and the one or more isocyanates with water; and admixing one or more foam polyols to the resin. Another embodiment includes a method for manufacturing a foam derived from an isocyanate, comprising replacing all or a portion of the isocyanate with a resin comprising: one or more saccharides; one or more isocyanates; one or more resin polyols; and water. Another embodiment includes an article of manufacture comprising such foam.Type: GrantFiled: January 15, 2003Date of Patent: January 25, 2005Assignee: Temple-Inland Forest Products CorporationInventor: Charles L. Capps
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Patent number: 6835772Abstract: This invention aims to provide a favorable feel coating film having gently soft feel (comfortable feel), a coating composition for forming the coating film, and fine particles of a polymer for incorporation in the coating composition, and concerns with fine particles of lanolin-deposited polyurethane resin obtainable by reacting at least one of polyesters and polyethers with polyisocyanate having at least two isocyanate groups in a poor solvent in the presence of a lanolin derivative; a coating composition comprising (i) at least one binder resin selected from the group consisting of polyester resins and polyether resins, the binder resin having a specific glass transition temperature, a specific number average molecular weight and a specific hydroxyl value, (ii) polyisocyanate having at least two isocyanate groups, (iii) the fine particles of polyurethane resin as described above, and (iv) an organic solvent; and an article coated with the coating composition.Type: GrantFiled: January 25, 2002Date of Patent: December 28, 2004Assignees: Ohashi Chemical Industries Ltd., Toyota Jidosha Kabushiki KaishaInventors: Takashi Kita, Hiroyuki Arimoto, Osamu Shoji, Takayuki Kishimoto, Kenji Kawazu, Mika Kai
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Patent number: 6833425Abstract: The invention relates to fillers for plastics formulations based on polyurethane and the use thereof.Type: GrantFiled: June 13, 2002Date of Patent: December 21, 2004Assignee: 3M ESPE AGInventors: Reinhold Hecht, Bernd Gangnus, Günther Lechner
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Patent number: 6825268Abstract: Polyurethane or polyurethane polymer hybrid dispersions, with reduced hydrophilicity and methods for preparing and using them are disclosed.Type: GrantFiled: November 26, 2002Date of Patent: November 30, 2004Assignee: SKW Bauwerkstoffe Deutschland GmbHInventors: Alois Maier, Norbert Steidl, Alfred Kern, Franz Wolfertstetter, Gerhard Reusmann, Frank Reichel
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Patent number: 6822042Abstract: A novel resin for binding composite lignocellulosic, cellulosic and non-cellulosic products is disclosed. The resin is comprised of one or more isocyanates, one or more saccharides, one or more polyols, and water. Preferaby, the saccharide is a polysaccharide comprised of corn syrup. Preferably, the isocyanate is a polyisocyanate and the polyol is an ethylene glycol. Also disclosed are methods for preparing and applying the resin as well as the products prepared from the resin.Type: GrantFiled: October 24, 2002Date of Patent: November 23, 2004Assignee: Temple-Inland Forest Products CorporationInventor: Charles L. Capps
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Patent number: 6822038Abstract: An aqueous coating material comprising A) at least one polyester that is water-soluble or water-dispersible, B) at least one polyurethane acrylate that is water-soluble or water-dispersible, C) at least one amino resin that is itself water-soluble or water-dispersible or is water-soluble or water-dispersible in the presence of the polyester and the polyurethane acrylate, D) at least one of a color pigment, an effect pigment, a color and effect pigment, and a filler, and E) optionally at least one polyisocyanate. Also, processes for preparing and using the aqueous coating material.Type: GrantFiled: February 26, 2002Date of Patent: November 23, 2004Assignee: BASF Coatings ACInventors: Lutz-Werner Gross, Ludwig Moorkamp, Heinz-Ulrich Grumpe, Ulrich Poth
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Patent number: 6822012Abstract: This invention relates generally to water resistant peelable protective and decorative clear or pigmented coating compositions and, more specifically, to aqueous and solvent based, polymeric coating compositions which form a protective and/or decorative coating and is removably adheres to a variety of substrates, including automotive paints, metals, glass, vinyl, plastics, concrete, natural and synthetic elastomers, and ceramics. The coatings can be either a flat film on the substrate, or a three-dimensional expandable foamy coating, and can be readily peeled off from the substrate as a whole piece. The coatings may be formulated for temporary or long-term protection depending upon the application. The peelable coatings can be applied as a paint, paste, film, or expandable foam cord whereby the expansion of the foam can be controlled by the formulation and applicator.Type: GrantFiled: October 20, 2000Date of Patent: November 23, 2004Assignee: Ashland IncInventors: Richard J. Baumgart, Michael A. Dituro, Frances E. Lockwood, Zhiqiang Zhang, Daniel J. Dotson
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Patent number: 6815494Abstract: Aqueous coating material comprising (A) water-dispersible hydroxy-functional binder component containing urethane groups, (B) water-dispersible binder component containing urethane groups and blocked isocyanate groups, (C) water-dispersible amino resin, and optionally (D) water-dispersible hydroxy-functional polyester, the binder component (B) being preparable by (B1) preparing a polyurethane prepolymer containing isocyanate groups from at least one polyol and at least one polyisocyanate, (B2) reacting the polyurethane prepolymer (B1) containing isocyanate groups with a chain extender to give a hydroxyl-containing chain-extended polyurethane prepolymer, (B3) reacting the hydroxyl-containing chain-extended polyurethane prepolymer (B2) with at least one polyisocyanate to give a further polyurethane prepolymer containing isocyanate groups, and (B4) blocking some or all of the isocyanate groups of the chain-extended polyurethane prepolymer (B3) containing isocyanate groups with a blocking agent to give a polyuretType: GrantFiled: March 25, 2003Date of Patent: November 9, 2004Assignee: BASF Coatings AGInventors: Georg Wigger, Ulrike Röckrath, Bärbel Wiatr, Marita Schilling, Ralf Stein
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Patent number: 6809149Abstract: Functionalized silicas with 3-methacryloxypropylsilyl and/or glycidyloxypropylsilyl groups on the surface are prepared by mixing the silicas with the silane and heat-treating the mixture. The silicas are employed, for example, in solvent-containing coatings.Type: GrantFiled: October 19, 2001Date of Patent: October 26, 2004Assignee: Degussa AGInventors: Jürgen Meyer, Manfred Ettlinger, Stephanie Frahn, Dieter Kerner
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Patent number: 6797770Abstract: A coating composition capable of forming an alkali-soluble lubricating film, which contains as main components an aqueous polyurethane composition (A) and a lubricating functionality-providing agent (B) at 1-30 wt % with respect to the solid content of the aqueous polyurethane composition, having excellent press moldability and scratch resistance, as well as lubricating surface treated metal articles with excellent press moldability and scratch resistance, that are coated with the coating composition to a dry film thickness of 0.5-5 &mgr;m. The coating composition preferably further contains as a main component silica particles (C) in an amount of 1-30 wt % with respect to the solid content of the aqueous polyurethane composition.Type: GrantFiled: October 31, 2001Date of Patent: September 28, 2004Assignees: Nippon Steel Corporation, Mitsui Takeda Chemicals, INCInventors: Yoichiro Mori, Makoto Yamasaki, Masahiro Fuda, Ryosuke Wake, Tsutomu Tawa, Chikako Kouda, Fumiaki Hirata
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Patent number: 6787596Abstract: A solvent-free polyurethane-polymer hybrid dispersion having a high solids content of polymer or formulation constituents is described, which is obtainable by a) the multistage preparation of a polyurethane base dispersion and b) by the subsequent preparation of a polyurethane-polymer hybrid dispersion. This polyurethane-polymer hybrid dispersion not only is distinguished by complete freedom from solvents and high solids contents in combination with low viscosity and a technically simple preparation process but also has excellent mechanical properties and, owing to the low hydrophilicity, high water resistance.Type: GrantFiled: April 11, 2002Date of Patent: September 7, 2004Assignee: SKW Bauchemie GmbHInventors: Alois Maier, Stefan Ingrisch, Herbert Winkelmann, Franz Wolfertstetter, Alfred Kern, Werner Temme, Ralph Bergs
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Patent number: 6787599Abstract: A two-component water paint system that allows reliable formation of essentially bubble-free paint films having a thickness of at least 120 &mgr;m. The water paint system comprises an aqueous emulsion of a hydroxy-functional alkyd resin wherein the hydroxy-functional alkyd resin can be obtained from an oleic or fatty acid component, a polyvalent alcohol, a polyether polyol having a molecular weight of 400 to 8,000, a monobasic carboxylic acid and a polycarboxylic acid or the anhydride thereof.Type: GrantFiled: January 22, 2001Date of Patent: September 7, 2004Assignee: Ashland-Südchemie-Kernfest GmbHInventors: Peter Kuhlmann, Reinhard Winter
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Patent number: 6787190Abstract: This invention provides a water based paint composition containing polyurethane resin which is formed by urethanation reaction of polyisocyanate compound with polyalkylene glycol and a further reaction of so formed isocyanate-containing prepolymer with a monohydric alcohol having at least 5 carbons, and water-soluble organic solvent having boiling point not higher than 150° C.; and provides also a process for forming multi-layered coating, which comprises applying onto a metallic object cationic electropaint, above-described water based paint composition, water based intermediate coating and top coating, by the order stated.Type: GrantFiled: May 23, 2002Date of Patent: September 7, 2004Assignee: Kansai Paint Co., Ltd.Inventor: Takanobu Iizuka
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Patent number: 6787627Abstract: The invention relates to water-dilutable polyurethanes containing structural units derived from 3,4-epoxy-1-butene and also to aqueous dispersions comprising these polyurethanes, to a process for preparing them and to use as aqueous oxidatively drying and/or UV-crosslinking coating compositions.Type: GrantFiled: February 18, 2003Date of Patent: September 7, 2004Assignee: Bayer AktiengesellschaftInventors: Martin Melchiors, Jan Weikard, Rolf Gertzmann, Helmut Greiving, Ulrich Freudenberg
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Patent number: 6784243Abstract: The invention relates to polyurethane-polyurea dispersions, also called PU dispersion, which contain aralkylamine-blocked isocyanate groups, and to their preparation and use. This blocking agent ahs a significantly lower deblocking temperature as compared with the prior art. Coatings produced from this dispersion have high hydrolysis resistances. The arylamine-blocked isocyanate groups are composed of polyisocyanates, polymeric polyols having average molar weights of 400 to 6000, at least one blocking agent, and either or both of nonionically hydrophilicizing compounds or compounds having at least one ionic or potentially ionic group.Type: GrantFiled: June 10, 2003Date of Patent: August 31, 2004Assignee: Bayer AktiengesellschaftInventors: Thorsten Rische, Karin Naujoks, Thomas Feller, Christoph Gürtler, Jan Mazanek
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Patent number: 6784242Abstract: A polyurethane binder with a low content of readily volatile isocyanate-functional monomer is provided by a process of (a) reacting a first at least difunctional isocyanate and a first polyol component at an NCO:OH ratio less than 2 wherein the first at least difunctional isocyanate has an NCO group with a slower rate of reaction with the OH groups than a second NCO group to produce a reaction product containing free OH groups and reacting the reaction product with a second polyol and a second at least difunctional isocyanate wherein the second at least difunctional isocyanate has isocyanate groups with a more rapid rate of reaction with the OH groups than the predominent percentage of isocyanate groups present in the reaction product.Type: GrantFiled: May 6, 2002Date of Patent: August 31, 2004Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Achim Huebener, Guenter Henke, Andreas Bauer
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Patent number: 6776287Abstract: Water-soluble films suitable for water-dissolvable packaging comprising a polyurethane polymer having defined amounts of poly(ethylene oxide) (and optionally poly(propylene oxide)) groups and acid (preferably carboxyl) groups at least 50% neutralised with a base, at least a proportion of which is of the non-volatile type, the polyurethane being made by chain extension of a urethane prepolymer. Also water-soluble packaging (sachets, capsules, bags) made from the films and their use in packaging various materials, and a process for the production of aqueous polyurethane solutions which may be used for making such films.Type: GrantFiled: November 22, 2000Date of Patent: August 17, 2004Assignee: Aquasol LimitedInventors: David Charles Hinde, Gerardus Cornelis Overbeek, John Christopher Padget, Phillip Cheshire, Terence Yeates, Yvonne Wilhelmina Smak
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Patent number: 6774177Abstract: An electrically conductive hydroprimer for plastics comprising I) at least one component comprising at least one aqueous polyurethane dispersion and at least one electrically conductive pigment; and II) at least one component comprising at least one polyisocyanate, wherein at least one of the components I and II comprise at least one aromatic solvent. Also, the use of the hydroprimer for producing multi-coat color and/or effect paint systems for plastic components and plastic components coated with the multi-coat paint systems.Type: GrantFiled: March 28, 2002Date of Patent: August 10, 2004Assignee: BASF Coatings AGInventor: Guido Wilke
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Patent number: 6770702Abstract: Polymer obtainable by a multistage polymerization process which involves conducting, in a first step, an aqueous-phase polymerization of at least one ethylenically monofunctional compound alone or together with at least one ethylenically difunctional or poly-functional compound together in the presence of a polyesterpolyol, polyurethane and/or polyacrylate; and, in a subsequent step, a reaction of the resulting product with at least one ethylenically monofunctional compound alone or together with at least one ethylenically difunctional or polyfunctional compound; followed by a reaction of the resulting product with a crosslinker; and its use.Type: GrantFiled: April 16, 2002Date of Patent: August 3, 2004Assignee: PPG Industries Lacke GmbHInventors: Horst Muller, Hans-Dieter Hille
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Patent number: 6770271Abstract: The present invention relates to polyurethanes and a process for preparing them. These polyester polyurethanes contain units corresponding to the following formulae (I) and (II): The polyester polyurethanes according to the present invention form pseudolatices and may be utilized as film-forming resin in cosmetic compositions.Type: GrantFiled: February 23, 2000Date of Patent: August 3, 2004Assignee: L'OrealInventors: Jean Mondet, Bertrand Lion, Nathalie Mougin, Bertrand Piot, Valérie de La Poterie
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Patent number: 6767958Abstract: The present invention relates to a modified polyisocyanate which is the reaction product of a polyisocyanate with 2-(cyclohexylamino)-ethanesulfonic acid and/or 3-(cyclohexylamino)-propanesulfonic acid, to a process for preparing these modified polyisocyanates, to coating compositions containing these modified polyisocyanates and to coated substrates prepared from these coating compositions.Type: GrantFiled: November 14, 2002Date of Patent: July 27, 2004Assignee: Bayer AktiengesellschaftInventors: Hans-Josef Laas, Reinhard Halpaap
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Patent number: 6767954Abstract: Latently crosslinking aqueous polyurethane dispersions contain I) a disperse phase (P.I) containing Ia) a polyurethane (Ia) which, in addition to hydrophilic groups which produce water dispersibility, carries carbodiimide groups and substantially no carboxyl groups or Ib) a physical mixture of Ibi) a polyurethane (Ibi) which carries hydrophilic groups which produce water dispersibility and carries substantially no carbodiimide or carboxyl groups, and Ibii) a carbodiimide (Ibii) which carries substantially no hydrophilic groups which produce water dispersibility, and II) a disperse phase (P.II) containing another polymer (II) which carries substantially no carbodiimide groups and is substantially derived from II.1) from 30 to 99.Type: GrantFiled: April 2, 2002Date of Patent: July 27, 2004Assignee: BASF AktiengesellschaftInventors: Bernd Meyer-Roscher, Andre Burghardt, Ulrike Licht
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Patent number: 6765057Abstract: The invention relates to a process for the preparation of an aqueous dispersion of an anionic polyurethane in which initially a tertiary aminofunctional acrylic monomer is used as neutralizing agent for pendant carboxylic acid groups in dispersions of a polyurethane or a polyurethane/polyacrylate, whereafter the unsaturated monomers undergo in situ an addition polymerisation, optionally together with other unsaturated monomer. In the process the isocyanate terminated prepolymer may be reacted with 0-100% of a stoichiometric amount of a hydroxy functional unsaturated monomer before the dispersion in water. The tertiary amine functional usaturated monomer is preset in a ratio to the anionic residues to be neutralized in the polyurethane prepolymer from 0.3 to 2 and preferably from 0.7 to 1.5. Furthermore the amount of carboxylic acid functions in the isocyanate functional polyurethane prepolymer is from 1 to 15% and preferably from 2 to 10%.Type: GrantFiled: August 28, 2001Date of Patent: July 20, 2004Assignee: Stahl International B.V.Inventors: Josep Oller Chirivella, Mario Jimenez Martinez, Montserrat Pous Brutau
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Patent number: 6765056Abstract: The aqueous-based cross-linkable binder composition comprising (A) an aqueous dispersion of an aldehyde-functional polyurethane having a number average molecular weight of more than 1,000 and an average aldehyde functionality of ≧2, which polyurethane comprises ionic and/or non-ionic dispersing groups, and (B) a low-molecular weight aldehyde-reactive cross-linker selected from the group of low-molecular weight polyamines and low-molecular weight compounds comprising at least one group of one of the formulae E1—CHR1—E2 and H—C—(E1E2E3), wherein —E1, —E2 and —E3 are independently chosen from electron-withdrawing groups such as —P(═O)—O—, —CO—, —CN, —SO2—, —NO2 and wherein R1 has the meaning of hydrogen or a hydrocarbon radical having 1 to 10 carbon atoms.Type: GrantFiled: August 13, 2001Date of Patent: July 20, 2004Assignee: Akzo Nobel N.V.Inventors: Klaus Hobel, Josephus Christiaan Van Oorschot, Keimpe Jan Van Den Berg
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Patent number: 6762241Abstract: The invention relates to polyurethane solutions with alkoxysilane structural units, processes for the preparation of polyurethane solutions containing alkoxysilane structural units and the use of polyurethane solutions containing alkoxysilane structural units.Type: GrantFiled: September 21, 2001Date of Patent: July 13, 2004Assignee: Bayer AktiengesellschaftInventors: Harald Blum, Detlef-Ingo Schütze
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Patent number: 6750286Abstract: A polyurethane which has a number average molecular weight Mn of from 3,000 to 50,000 and an acid number of from 10 to 35 and is preparable by reacting (a1) at least one polyesterpolyol having a number average molecular weight Mn of from 1,000 to 4,000, an acid number of from 0 to 15, and an OH number of from 35 to 150, based on acyclic aliphatic and cycloaliphatic dicarboxylic acids, (a2) a mixture of at least one diol and one triol, (a3) at least one compound containing at least two isocyanate-reactive functional groups and at least one functional group capable of forming anions, and (a4) a mixture of at least one, acyclic aliphatic and at least one cycloaliphatic diisocyanate, to give an isocyanato-containing prepolymer that is then chain extended with a polyfunctional amine or amino alcohol and, if desired, is neutralized.Type: GrantFiled: June 26, 2001Date of Patent: June 15, 2004Assignee: BASF Coatings AGInventors: Stephan Schwarte, Michael Hartung
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Patent number: 6747088Abstract: UV- and heat-curable aqueous polyurethane dispersions comprise compounds attached via polyisocyanates and containing UV-polymerizable C═C double bonds, aliphatic diols incorporated by way of isocyanates and having a molecular weight of less than 500 g/mol, compounds attached via isocyanates and containing carboxylic acid or sulfonic acid groups and/or salts thereof, free hydroxyl groups, and compounds containing blocked isocyanate groups. They are suitable for coating heat-stable substrates such as metal substrates and may be used with advantage for automotive clearcoats.Type: GrantFiled: March 29, 2002Date of Patent: June 8, 2004Assignee: BASF AktiengesellschaftInventors: Reinhold Schwalm, Wolfgang Paulus, Uwe Meisenburg, Erich Beck, Bernd Bruchmann, Wolfgang Schrof, Frank Völlinger
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Patent number: 6743844Abstract: An aqueous dispersed polymeric composition for preparing the spill resistant carpet backing is provided. The aqueous dispersed polymeric composition of the present invention comprises an aqueous dispersed polymeric material, an inorganic filler, and a hydrophobic compound selected from the group consisting of a hydrophobic acid, a salt of a hydrophobic acid, and mixtures thereof. Alternatively, the inorganic filler is pretreated with the hydrophobic compound. Also, a kit and a method for preparing a spill resistant carpet backing from the aqueous dispersed polymeric composition is provided.Type: GrantFiled: February 8, 2001Date of Patent: June 1, 2004Assignee: Dow Global Technologies Inc.Inventors: Rick L. Tabor, Rhonda R. Suarez, Randall C. Jenkines
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Patent number: 6743374Abstract: A self-emulsifiable polyisocyanate with high functionality, having the average number of functional groups in 4.3 or more and a viscosity of 8,000 mPa·s (at 25° C.) or less, which is obtained by subjecting a modified polyisocyanate containing allophanate bonds and a poly(oxyalkylene)glycol monoalkyl ether (e) having oxyethylene bonds in a total amount of 30 mole % or more in its molecule to a urethanization reaction, said modified polyisocyanate being obtained by reacting a polyol (a) having the average number of functional groups in an amount of 2 or more with an organic polyisocyanate (b) in the presence of an allophanate-forming catalyst (c) comprising a zirconium carboxylate; and a process for producing the same.Type: GrantFiled: July 31, 2002Date of Patent: June 1, 2004Assignee: Nippon Polyurethane Industry Co., Ltd.Inventors: Motomu Kita, Mitsushige Ikemoto, Toshiaki Sasahara
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Patent number: 6720385Abstract: Disclosed are stable aqueous polyurethane latexes prepared from prepolymer formulations including a polyisocyanate component and polyol component, wherein from 5 to 40 percent of the weight of the polyol component is ethylene oxide in the form of ethylene oxide applied as an end cap onto a propylene oxide or higher oxyalkylene polyoxyalkylene polyol, and no more than 45 percent of the weight of polyol component is ethylene oxide. These latexes are prepared without the use of organic solvents.Type: GrantFiled: April 30, 2002Date of Patent: April 13, 2004Assignee: The Dow Chemical CompanyInventors: Rick L. Tabor, Douglas R. Moore, James J. Jakubowski, Wayne R. Willkomm, Ruben Solis
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Patent number: 6720384Abstract: A coating composition consisting of at least four components, comprising a component (I) comprising at least one oligomeric or polymeric resin containing functional groups which react with isocyanate groups, as binder (A), a component (II) comprising at least one polyisocyanate as crosslinking agent (F), a component (III) which comprises water and is substantially free from acrylate copolymers (A) dispersed or dissolved therein, and a finely divided solid component (IV) which comprises at least one water-soluble or -dispersible finely divided solid acrylate copolymer (A); and also a process for producing a coating from a coating composition consisting of at least four components, which involves (1) mixing at least one component (I) with at least one component (II), to give the mixture (I/II); (2) mixing at least one component (III) with at least one finely divided solid component (IV), to give the mixture (III/IV); and then either (3) dispersing and/or dissolving the mixture (I/II) in the mixture (III/IV) orType: GrantFiled: November 7, 2001Date of Patent: April 13, 2004Assignee: BASF Coatings ACInventors: Bernd Mayer, Heinz-Peter Rink
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Patent number: 6716910Abstract: The invention relates to aqueous and/or water-dilutable polyisocyanate crosslinkers blocked with diisopropylamine, to their preparation and use in one-component baking lacquers, for example as fillers in automotive lacquering.Type: GrantFiled: July 10, 2002Date of Patent: April 6, 2004Assignee: Bayer AktiengesellschaftInventors: Eberhard König, Jan Mazanek, Heino Müller, Joachim Petzoldt
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Patent number: 6716909Abstract: The present invention provides a water-borne coating composition excellent in smoothness and film appearance. A water-borne coating composition comprising: an emulsion resin obtained by emulsion polymerization of an &agr;,&bgr;-ethylenically unsaturated monomer mixture and a urethane compound represented by the general formula (1) or (2): wherein the content of said urethane compound is 0.01 to 20% by weight on the solid basis relative to the resin solid in the coating composition. A method of forming a multilayer coating film comprising: applying a water-borne base coating to an article to be coated and then applying a clear coating thereonto, followed by curing by heating, wherein said water-borne base coating is the above-mentioned water-borne coating composition.Type: GrantFiled: September 4, 2001Date of Patent: April 6, 2004Assignee: Nippon Paint Co., Ltd.Inventors: Tsuyoshi Harakawa, Masaru Murayama, Shinnji Seo, Naohiro Tsuji
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Patent number: 6716913Abstract: The present invention is directed to carboxyl-containing monomers for use in preparing a polyurethane polymers, the carboxyl-containing monomers being the reaction product of a low molecular weight polyol compound and an acid anhydride in the presence of 5-500 ppm phosphoric acid, the carboxyl-containing monomer having a viscosity in the range of 3,000 to 100,000 centipoise, and having oligomer content of less than about 30 mg KOH/g. The present invention is also directed to methods of making the above carboxyl-containing monomers, as well as prepolymers and urethane polymers containing the above carboxyl-containing monomers.Type: GrantFiled: November 27, 2000Date of Patent: April 6, 2004Assignee: Arch Chemicals, Inc.Inventors: Indulis Gruzins, Donald Farrell McElheney, Robert C. Hire, Jerry Douglas Necessary
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Patent number: 6713522Abstract: This invention relates generally to water resistant peelable protective and decorative clear or pigmented foam coating compositions and, more specifically, to aqueous and solvent based, polymeric coating compositions which form a protective and/or decorative coating and is removably adheres to a variety of substrates, including automotive paints, metals, glass, vinyl, plastics, concrete, natural and synthetic elastomers, and ceramics. The coatings present a three-dimensional expandable foamy coating, and can be readily peeled off from the substrate as a whole piece. The coatings may be formulated for temporary or long-term protection depending upon the application. The peelable coatings can be applied as a paint, paste, film, or expandable foam cord whereby the expansion of the foam can be controlled by the formulation and applicator.Type: GrantFiled: March 23, 2001Date of Patent: March 30, 2004Assignee: Ashland Inc.Inventors: Zhiqiang Zhang, Richard J. Baumgart, Michael A. Dituro, Frances E. Lockwood, Daniel J. Dotson, Wen-Chen Su
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Patent number: 6713554Abstract: The present invention relates to a composition comprising a component (A) containing, an aqueous alkali silicate solution and a primary amino-alcohol as a catalyst, and a component (B) containing a polyisocyanate. The present invention further relates to organo-mineral products which can be obtained by the transformation of polyisocyanates and aqueous alkali silicate solutions in the presence of a primary amino-alcohol as a catalyst. The organo-mineral products can be used as building, coating, sealing or insulating materials, or as a cement or adhesive.Type: GrantFiled: August 30, 2002Date of Patent: March 30, 2004Assignee: Fosroc International LimitedInventor: Harald Bode
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Patent number: 6713556Abstract: The invention relates to particular mixtures of polyisocyanates which are blocked with 3,5-dimethylpyrazole, and to the use thereof as crosslinking component in single-component stoving lacquers, especially automotive clear lacquers.Type: GrantFiled: November 1, 2002Date of Patent: March 30, 2004Assignee: Bayer AktiengesellschaftInventors: Eberhard König, Reinhard Halpaap, Thomas Klimmasch, Hans-Ulrich Meier-Westhues, Harald Mertes, Joachim Schüll, Bernd Steinhilber
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Patent number: 6713551Abstract: The present inventors provides polyol-containing resin compositions for coatings which can give cured coating films having high hardness and at the same time high solid compositions to meet the recent resources saving and/or environmental protection requirements, and curable coating compositions having high reactivity at curing, giving the coating film with good appearance and the coatings with prolonged pot life. The invention is directed to a resin composition for coatings comprising a polyol (A1) or (A2), a polyether polyol (B) and a solvent (C), wherein the polyol (A1) comprises a hydroxyl-containing polymerizable unsaturated monomer and a ring structure-containing polymerizable unsaturated monomer as essential components and the polyol (A2) comprises a hydroxyl-containing polymerizable unsaturated monomer and a linear branched structure-containing polymerizable unsaturated monomer as essential components.Type: GrantFiled: July 18, 2001Date of Patent: March 30, 2004Assignee: Nippon Shokubai Co., Ltd.Inventors: Kunio Takahashi, Naoki Kodama, Masaya Yoshida
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Patent number: 6710120Abstract: The invention relates to aqueous polyurethane dispersions based on fatty acid dialkanolamides, to a process for preparing them and to use as coating compositions.Type: GrantFiled: March 31, 2003Date of Patent: March 23, 2004Assignee: Bayer AktiengesellschaftInventors: Rolf Gertzmann, Christoph Irle, Jan Weikard, Rolf Roschu, Erhard Lühmann
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Patent number: 6686416Abstract: Disclosed is a storage-stable, essentially aqueous one component dispersion, of a deactivated isocyanate and a isocyanate-reactive polymer which cross-links at low temperatures.Type: GrantFiled: September 24, 2001Date of Patent: February 3, 2004Assignee: Jowat Lobers und Frank GmbH & Co. KGInventors: Dieter Guse, Theodor Hippold, Christian Terfloth
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Patent number: 6686415Abstract: A one-component dispersion comprising deactivated isocyanates which cross-links already at low temperatures (lower than 70° C.).Type: GrantFiled: November 7, 2000Date of Patent: February 3, 2004Assignee: Jowat Lobers und Frank GmbH & Co. KGInventors: Christian Terfloth, Dieter Guse, Theodor Hippold
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Patent number: 6683131Abstract: A water-based liquid treatment composition for metal surfaces comprises water, (A) dissolved, dispersed, or both dissolved and dispersed urethane resin, acrylic resin; or both urethane and acrylic resins; (B) dissolved, dispersed, or both dissolved and dispersed curing agent molecules; (C) dispersed silica powder; (D) dispersed oxidized polyethylene wax with an average particle size of 0.01 to 0.Type: GrantFiled: November 28, 2001Date of Patent: January 27, 2004Inventors: Yasuhiro Kinoshita, Keiichi Ueno, Takashi Koyama
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Patent number: H2113Abstract: A process for the preparation of an ink which comprises mixing an ink vehicle, a colorant and a polyurethane resin emulsion.Type: GrantFiled: August 16, 1999Date of Patent: January 4, 2005Assignee: Xerox CorporationInventors: Garland J. Nichols, Chieh-Min Cheng, Min-Hong Fu, Elizabeth A. Kneisel