With Carbohydrate Reactant, E.g., Starch, Cellulose, Or Sugar, Etc. Patents (Class 524/842)
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Patent number: 9133307Abstract: The present invention relates to a method for producing a modified polymeric sulfur comprising melting thereof in a reactor and mixing with addition of modifiers, wherein 1-35 parts by weight of carbohydrate caramelization products of general formula: wherein R1, R2=H, Glc, Fru, are added to 65-99 parts by weight of molten technical sulfur at constant mixing, the temperature of the mixture is increased to 150-200° C., maintained for 2-4 hours, then the temperature is decreased to 5-25° C. and maintained until solidification of the modified sulfur is complete.Type: GrantFiled: September 19, 2014Date of Patent: September 15, 2015Inventors: Kairat Mirzasalimovich Beketov, Marat Flurovich Faskhutdinov
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Patent number: 7939599Abstract: This invention is a substantially completely biodegradable high starch polymer using completely biodegradable high polymer polyvinyl alcohol [PVOH] that is made to be compatible with starch. The two ingredients are mixed with the optional addition of elasticity enhancer and supplement agent to better the stability and durability of the products. During the mixing and heating process the starch molecular structures are randomized. The randomized starch molecules, the PVOH, the elasticity enhancer and the supplement then under go the process of co-polymerization. The mixture is then extruded, at a temperature that is above the crystallization temperature of the starch molecules, to form the first stage product, the pellets. The pellets can then be extruded into films using a traditional plastic film extruder.Type: GrantFiled: May 17, 2005Date of Patent: May 10, 2011Assignees: Biostarch Technology PTE. Ltd, Beijing Jinbaodi Bio-Environmental Technology LtdInventors: Chun Yang Ding, Yi Hua Zheng, Xian Zhang
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Patent number: 6908983Abstract: The present invention contemplates a process for forming polyaminoamide polymers formed by the reaction of a dibasic acid/ester with excess amounts of an amine; the intermediate polymer resulting therefrom; a process for synthesizing effective, high solids resins resulting from the reaction of intermediate polymers with an epihalohydrin; and the resultant high, solids resin. These resins may be used as wet strength resins in the papermaking industry.Type: GrantFiled: April 1, 2003Date of Patent: June 21, 2005Assignee: Hercules CorporationInventor: William W. Maslanka
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Patent number: 6620880Abstract: An environmentally friendly stable aqueous optionally structured water-resistant architectural coating composition (especially a paint) containing a film-forming binder polymer composed of a starch modified by the presence of carboxylic acid or inorganic carboxylate groups and bonded (probably grafted) to chains of copolymerized mono-ethylenically unsaturated monomers (e.g. “acrylic”, “vinyl” or “styrenic” copolymers) permitting a stable aqueous dispersion of the binder polymer to be made which retains good water-resistance in the dried paint. The modified starch allows paints to be made with less dependence on materials obtained from non-renewable resources whilst retaining a low water-sensitivity.Type: GrantFiled: January 16, 2002Date of Patent: September 16, 2003Assignee: Imperial Chemical Industries PLCInventors: Susan Mary Horley, Stephen Arthur Wheeler
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Publication number: 20020128380Abstract: An environmentally friendly stable aqueous optionally structured water-resistant architectural coating composition (especially a paint) containing a film-forming binder polymer composed of a starch modified by the presence of carboxylic acid or inorganic carboxylate groups and bonded (probably grafted) to chains of copolymerized mono-ethylenically unsaturated monomers (e.g. “acrylic”, “vinyl” or “styrenic” copolymers) permitting a stable aqueous dispersion of the binder polymer to be made which retains good water-resistance in the dried paint. The modified starch allows paints to be made with less dependence on materials obtained from non-renewable resources whilst retaining a low water-sensitivity.Type: ApplicationFiled: January 16, 2002Publication date: September 12, 2002Applicant: Imperial Chemical Industries PLCInventors: Susan Mary Horley, Stephen Arthur Wheeler
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Patent number: 6384132Abstract: An environmentally friendly stable aqueous optionally structured water-resistant architectural coating composition (especially a paint) containing a film-forming binder polymer composed of a starch modified by the presence of carboxylic acid or inorganic carboxylate groups and bonded (probably grafted) to chains of copolymerized mono-ethylenically unsaturated monomers (e.g. “acrylic”, “vinyl” or “styrenic” copolymers) permitting a stable aqueous dispersion of the binder polymer to be made which retains good water-resistance in the dried paint. The modified starch allows paints to be made with less dependence on materials obtained from non-renewable resources while retaining a low water-sensitivity.Type: GrantFiled: April 5, 1999Date of Patent: May 7, 2002Assignee: Imperial Chemical Industries, PlcInventors: Susan Mary Horley, Stephen Arthur Wheeler
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Patent number: 6245882Abstract: Method for the manufacture of a phenolic resin emulsion and/or dispersion, wherein an aldehyde, a phenolic compound and an alkaline catalyst are allowed to react at a temperature of 40-100° C. until a desired degree of condensation is achieved, and the pH of the resin is adjusted to a value below 9 using an acid in the presence of a surface active agent or a mixture thereof at a temperature below 100° C. and a phenolic resin emulsion and/or dispersion is obtained providing a colorless or light-colored glue line or surface when cured.Type: GrantFiled: September 1, 1999Date of Patent: June 12, 2001Assignee: Neste Chemicals OyInventors: Leena Matilainen, Guomin Bian, Claude Ostiguy, Rick Cheng, Matti Satuli, Kari Leskinen, Kwok Tang
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Patent number: 6222006Abstract: An aqueous formulation of a high solid content fully functional thermosettable wet strength resin designed for use in the manufacture of paper products is disclosed. The wet strength resin is the product of reaction of an epihalohydrin and an end-capped polyaminamide polymer. The thermosetting wet strength resins are useful in the manufacture of improved absorbent paper products such as bathroom tissues, facial tissues, napkins, towels, and paperboard products such as dairy cartons and bag paper.Type: GrantFiled: August 5, 1998Date of Patent: April 24, 2001Assignee: Fort James CorporationInventors: Bruce Jerome Kokko, Elroy Wayne Post
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Patent number: 5948387Abstract: Novel contrast media for use in ultrasonic imaging are described. Such contrast media may be comprised of an aqueous solution of one or more biocompatible polymers, wherein said biocompatible polymers are coated with and/or in admixture with at least one silicon containing compound. Alternatively, the contrast media may be comprised of an aqueous solution of one or more biocompatible synthetic polymers, or an aqueous solution of cellulose. The contrast media may be employed, if desired, with anti-gas agents and/or suspending agents.Type: GrantFiled: May 9, 1997Date of Patent: September 7, 1999Assignee: Imarx Pharmaceutical Corp.Inventors: Evan C. Unger, Guanli Wu
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Patent number: 5776604Abstract: The invention provides a lithographic printable plastic film. A plastic film is coated with a coating formulation which allows lithographic printing on plastic films. The coating composition comprises an acrylic binder, specifically a blend of acrylic polymer and ethylene-acrylic acid copolymer, at least one particulate filler, specifically silica, calcium carbonate, clay, talc, titanium dioxide and mixtures thereof, a surfactant and, optionally, an ultraviolet stabilizer. The coating composition is applied to a plastic film for lithographic printing.Type: GrantFiled: January 4, 1996Date of Patent: July 7, 1998Assignee: Mobil Oil CorporationInventors: Pang-Chia Lu, Gordon Musclow, Robert Michael Sheppard
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Patent number: 5484843Abstract: Self-reversible, stable, water-in-oil dispersions, miscible with water, constituted by an oil phase, an aqueous phase and at least two emulsifying agents of which at least one is of water-in-oil type, and at least one is of oil-in-water type, which contain 20 to 50% by weight of a mixture constituted by a hydrosoluble anionic polymer belonging to the group of carboxymethylcelluloses (C), and by a cross-linked, synthetic anionic polymer, insoluble in water but water-swellable (P), based on acrylic acid (AA), partially salified with an alkali metal (M), optionally copolymerized with 2-acrylamido 2-methyl propanesulphonate of the alkali metal M (AMPSM), cross-linked with a diethylenic carboxylic acid and in which the molar ratio of the salified acid functions to the total number of free or salified acid functions is comprised between about 0.6 and about 0.9, the ratio by weight C/P+C being comprised between 0.01 and 0.4, preparation process and use for obtaining a printing paste.Type: GrantFiled: September 29, 1994Date of Patent: January 16, 1996Assignee: Societe Francaise HoechstInventors: Paul Mallo, Isabelle Fietier, Ulrich Karsunky
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Patent number: 5017642Abstract: An aqueous solution of a cationic thermosetting resin containing a very small amount of organic halogen compounds is prepared by adjusting a reaction temperature in a reaction of polyamidopolyamine with epihalohydrin and a molar ratio of the polyamidopolyamine and epihalohydrin.Type: GrantFiled: December 21, 1989Date of Patent: May 21, 1991Assignee: Sumitomo Chemical Company, LimitedInventors: Toshiyuki Hasegawa, Hisao Takagishi, Hiroshi Horiuchi
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Patent number: 4963597Abstract: An aqueous gel composition is formed from xanthan gum crosslinked with ions of a transitional metal, resorcinol, and formaldehyde. The gel which initially forms is injected into a formation where it selectively enters pores in a more permeable zone. Once in the more permeable zone, the gel reheals and forms a shear and thermally stable gel. This gel can be used in high temperature formations in addition to those formations having a pH of from about 3.0 to about 10. After the shear and thermally stable gel has formed, a steam-flooding, water-flooding, or a carbon dioxide oil recovery process is commenced in a zone of lesser permeability.Type: GrantFiled: January 22, 1990Date of Patent: October 16, 1990Assignee: Mobil Oil CorporationInventor: Paul Shu
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Patent number: 4391642Abstract: A binder composition in aqueous solution, suitable for use in the production of foundry sand moulds and cores is obtained by mixing(i) an alkali silicate(ii) a substantially water soluble carbohydrate selected from monosaccharides, disaccharides, polysaccharides and derivatives thereof and(iii) a phenolic compound selected from monohydric phenols, dihydric phenols, trihydric phenols, phenols of polynuclear hydrocarbons and phenolic acids, which is miscible with or soluble in an aqueous solution of an alkali metal silicate.The composition may also contain an oxyanion such as a borate which is capable of forming a water soluble complex with the carbohydrate.A mixture of phenolic compounds, such as a mixture consisting predominantly of isomers of di- and trihydroxy diphenyl obtained in the distillation of crude resorcinol, may be used.The preferred carbohydrate is a stabilized starch hydrolysate whose reducing power has been removed by a process such as hydrogenation.Type: GrantFiled: October 27, 1980Date of Patent: July 5, 1983Assignee: Foseco International LimitedInventors: John Stevenson, Alan Cross, John G. Anderson