N=c=x Containing Reactant Forming A Solid Polymer Or Sicp In The Presence Of A Nonreactant Material (x Is Chalcogen) Patents (Class 524/871)
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Patent number: 6191248Abstract: Thin film metal particulates are removed from FEP sheetstock cheaply and quickly by immersing the coated FEP first in a base and then in an acid. Occasionally, ultrasonic vibration of the FEP may also be required. The particulates are useful as paint pigments when isolated and conversion coated. The FEP is reusable. A preferred binder for carrying the pigments is a two-component system having a tetraketimine and an isocyanate.Type: GrantFiled: December 19, 1997Date of Patent: February 20, 2001Assignee: The Boeing CompanyInventors: Diane C. Rawlings, Larry K. Olli, G. Micheal Granger, Kevin R. Malone
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Patent number: 6100363Abstract: The present invention relates to energy absorbing elastomers having a resilience of no more than 20.0% according to ASTM D2632-92. The energy absorbing elastomers are hydrophobic in nature and have extended gel times thus making them suitable for high volume applications such as coating a large substrate or filling a large void between two substrates.Type: GrantFiled: March 13, 1998Date of Patent: August 8, 2000Assignee: BASF CorporationInventors: Agus Sampara, Cal Peeler, Kerry Bowman, Richard Jewell
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Patent number: 6040381Abstract: The present invention is a continuous process for preparing formulations useful for making filled polymer carpet backings. The present invention particularly incorporates polyisocyanate as a reactive diluent in a continuous process for preparing filled polyurethane polymers. Use of the present invention allows production of carpet backings that incorporate high loadings of filler materials.Type: GrantFiled: March 12, 1999Date of Patent: March 21, 2000Assignee: The Dow Chemical CompanyInventors: James K. Jennings, Randall C. Jenkines, Larry W. Mobley
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Patent number: 5935713Abstract: A composite material resistant to armour piercing bullets consisting of a highly elastic polyurethane matrix into which is embedded aggregate, preferably in the form of rounded pebbles having an average screened size range of from about 20 mm to about 60 mm.Type: GrantFiled: July 14, 1997Date of Patent: August 10, 1999Assignee: Hyperlast LimitedInventor: William Sharples
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Patent number: 5929153Abstract: Disclosed are a vinyl chloride-based polymer-polyurethane composite comprising vinyl chloride-based polymer (1), polyurethane, plasticizer (4), metal salt of higher fatty acid (6) and hydrocarbon-based lubricant (7), the metal of metal salt of higher fatty acid being at least one element selected from a group consisting of magnesium, zinc and lead, which have low hardness and excellent hydrolysis resistance, compression set characteristic and profile extrusion moldability, and a method of producing vinyl chloride-based polymer-polyurethane composite which is produced by means of of heating, melting and mixing not less than 200 parts by weight to not more than 800 parts by weight of polymer polyol (2), isocyanate compound (3) with three or more isocyanate groups in amount of the molar ratio of isocyanate group in isocyanate compound (3) to hydroxyl group in polymer polyol (2) being not less than 0.3 to not more than 0.Type: GrantFiled: December 6, 1995Date of Patent: July 27, 1999Assignee: Tosoh CorporationInventors: Katsuaki Mori, Kazuyuki Okamoto, Yasunobu Adachi
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Patent number: 5922804Abstract: A method for reducing the volatile organic content of coating compositions wherein first, the ketimine of acetone is formed by reacting acetone and a ketimine having the formula ##STR1## wherein n is 1 to 4, R.sub.1 and R.sub.2 may be alkyl aryl, cycloaliphatic or substituted alkyl, aryl, or cycloaliphatic group. R.sub.1 and R.sub.2 may be the same or different, with the proviso that R.sub.1 and R.sub.2 are not both CH.sub.3. R.sub.3 is an aliphatic, aromatic arylaliphatic or cycloaliphatic group, which may also contain O, N, S or Si. The ketimine of acetone is subsequently reacted with at least one isocyanate functional crosslinking resin.Type: GrantFiled: June 28, 1996Date of Patent: July 13, 1999Assignee: BASF CorporationInventors: Bradley M. Richards, Sudhakar Dantiki
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Patent number: 5914299Abstract: An abrasive article is provided that includes at least one binder system formed from a polymeric additive and a thermosetting resin. The polymeric additive includes a polymeric backbone having substituents attached thereto, wherein the substituents include at least one urethane linked nitrogen bonded side chain having about 5 carbon atoms or more and a terminal methyl group and at least one oxygen linked water solubilizing group. An abrasive article that includes the binder system exhibits an increase of workpiece surface abraded in a Woodsanding Normal Force Test as compared to an abrasive article including a binder system formed from a composition containing substantially no polymeric additive.Type: GrantFiled: September 19, 1997Date of Patent: June 22, 1999Assignee: Minnesota Mining and Manufacturing CompanyInventors: Walter L. Harmer, James P. DiZio, Alan R. Kirk
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Patent number: 5907014Abstract: Disclosed is an aromatic diisocyanate prepolymer combined with a dibasic ester, preferably a mixed dialkyl ester of adipic, glutaric and succinic acids, which when used with amine or polyol curatives to make solid, non-foamed elastomeric polyurethane and/or polyurethane/urea products reduces viscosity and improves wettability of the castable polyurethane prepolymer without loss of cured physical properties. This improved wettability of the liquid prepolymer is useful for impregnation of fabrics, preferably polyesters, during the manufacture of a polyurethane coated fabric type belting.Type: GrantFiled: September 30, 1997Date of Patent: May 25, 1999Assignee: Uniroyal Chemical Company, Inc.Inventor: Robert John Quint
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Patent number: 5889065Abstract: This invention relates to pigment preparations containing(a) a pigment,(b) a monohydroxy ether, a polyether polyol, and/or a polyester polyol,(c) a polyisocyanate addition product having an NCO content of <1.0 wt. % and 30 to 95 wt. % of ethylene oxide units arranged within polyether chains and derived from monofunctional alcohols (B) that is prepared at an NCO index of 100 to 600 by reacting(A) a polyisocyanate component having an (average) NCO functionality of 1.7 to 6 and an NCO content of 5 to 65 wt. % with(B) 5 to 100 equivalent %, based on (A), of monohydric poly-ether alcohols having a molecular weight of 150 to 10,000 and an ethylene oxide unit content of 40 to 99.5 wt. %,(C) 0 to 20 equivalent %, based on (A), of a monofunctional isocyanate-reactive compound other than monohydric alcohol (B),(D) 0 to 50 equivalent %, based on (A), of an isocyanate-reactive tertiary amine compound, and(E) 0 to 20 equivalent %, based on (A), of a formative component containing at least two NCO-reactive groups.Type: GrantFiled: September 8, 1997Date of Patent: March 30, 1999Assignee: Bayer AktiengesellschaftInventors: Stephan Kirchmeyer, Michael Kressner, Josef Leitermann, Peter-Roger Nyssen, Christian Wamprecht
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Patent number: 5877243Abstract: Disclosed are coatings and materials that resist bacterial colonization and encrustation for use in medical devices and urological applications. The coating includes acidic chelating components, reactively bound to a hydrophilic polyurethane prepolymer along with noble metal combinations or antibacterials. The acidic and noble metal combinations can also be incorporated as additives during plastic molding of medical devices. A continuous antibacterial surfaces are provided by such coatings and materials.Type: GrantFiled: May 5, 1997Date of Patent: March 2, 1999Assignee: ICET, Inc.Inventor: Shantha Sarangapani
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Patent number: 5847040Abstract: A significantly improved plasticizer-polymer composition embraces a polymer containing a di-, tri- and/or tetra-ethyl-, propyl- and/or butylbiphenyl plasticizer which constitutes the major proportion by weight of any other plasticizing/softening additive, provided that the polymer is not polyvinyl chloride and when the polymer is an elastomer or rubber, or is a polystyrene, said plasticizer is diisopropylbiphenyl and/or triisopropylbiphenyl, and when the polymer is of a plastisol, essentially no ester plasticizing additive is present. As well, a polymer fabrication composition comprises a monomer and/or oligomer component in combination with said plasticizer. A method for preparing the plasticizer-polymer composition and/or the fabrication composition comprises contacting the monomer and/or oligomer component with said plasticizer, mixing to provide a uniform mixture, and carrying out further processing as may be desired so as to optionally prepare the plasticized-polymer composition.Type: GrantFiled: July 22, 1997Date of Patent: December 8, 1998Assignee: Koch Industries, Inc.Inventors: Jack B. Tatman, Gregory R. Hahn, Harold W. Earhart
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Patent number: 5837794Abstract: TDI residue-based urethane-filled isocyanate compositions are produced by reacting a TDI residue satisfying specified criteria with a monofunctional alcohol in amounts such that the equivalent ratio of isocyanate groups to hydroxyl groups is from about 0.9:1 to about 1:0.9. This reaction product is then dissolved in a diisocyanate or polyisocyanate before, during or after reaction of that product with an epoxide having an epoxide equivalent weight of from about 44 to about 400 at a temperature of up to 120.degree. C. These TDI residue-based urethane-filled isocyanate compositions are particularly useful in the production of polyurethanes.Type: GrantFiled: October 27, 1997Date of Patent: November 17, 1998Assignee: Bayer CorporationInventors: William E. Slack, Scott A. Kane, James W. Rosthauser
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Patent number: 5814675Abstract: The invention provides a process for the preparation of polyurethane microspheres, which comprises of preparing a solution of diol or polyol having a molecular weight in the range of 200-2000, crosslinker and a catalyst selected from amino or organometallic compounds, dispersing this solution in dilute solution of stabilizer which consists of a block copolymer having the general formula ?A!.sub.n-- ?B!.sub.m where A and B are chemically and compositionally dissimilar segments and n and m segments are in between 30-115 and 10-60 units respectively, such that the sum of n and m does not exceed 175 units, in an aliphatic hydrocarbon, adding an isocyanate dropwise to this dispersion, agitating the mixture at high speed of 100-1200 revolutions per minute, a temperature between 30.degree. to 55.degree. C. to permit the formation of polyurethane microspheres, separating these microspheres by filtration, washing with lower aliphatic hydrocarbon and drying the microspheres under vacuum.Type: GrantFiled: March 30, 1998Date of Patent: September 29, 1998Assignee: Council of Scientific & Industrial ResearchInventors: Parshuram Gajanan Shukla, Swaminathan Sivaram
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Patent number: 5756635Abstract: The present invention relates to a process for obtaining PAI fibres by spinning PAI in solution and to the fibres thus obtained. They are obtained by dry or wet spinning into dimethylalkyleneurea followed by removal of the solvent and overdrawing at high temperature. The yarns and fibres obtained are produced from PAI based on tolylene or meta-phenylene diisocyanate, and on an aromatic acid anhydride and/or an aromatic dianhydride, and optionally on one or a number of diacid compounds. They exhibit an outstanding thermomechanical behavior and make it possible to gain access to very low linear densities.Type: GrantFiled: September 27, 1996Date of Patent: May 26, 1998Assignee: Rhone-Poulenc FibresInventors: Philippe Michaud, Marie-Eve Perier, Jean Russo
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Patent number: 5710434Abstract: The invention is directed to a composition of matter useful as a paper impregnant, to the method of its use, and to the products produced by the method. Poly (diphenylmethane diisocyanate) or PMDI has been used in the past as a paper impregnant with or without propylene carbonate as a diluent. These products have generally required pressing under high pressures and at elevated temperatures. It has now been found that triacetin and/or triethyl citrate in usages up to about 20% of PMDI give superior performance in impregnated products. The modified PMDI will cure at essentially ambient conditions in times as short as 1-2 days to insoluble polyureas with low residual amounts of isocyanates and reaction byproducts such as 4,4'-diaminodiphenylmethane. The treated papers can be used in applications of which skins for sandwich panels and high strength corrugated board would be exemplary.Type: GrantFiled: September 19, 1996Date of Patent: January 20, 1998Assignee: Weyerhaeuser CompanyInventors: David W. Park, Frank R. Hunter
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Patent number: 5684083Abstract: A composition is disclosed which includes a urethane resin containing reactive ethylenically unsaturated groups and hydroxyl groups, which is preferably derived by reacting a polyisocyanate and an isocyanate reactive group-containing unsaturated monomer selected from the group consisting of hydroxyalkyl acrylates, hydroxyalkyl methacrylates, hydroxyalkyl acrylamides, hydroxy functional allylic compounds, and mixtures thereof to form an isocyanate group-containing reaction product which is then reacted with an organic polyol wherein the equivalent number of hydroxyl groups is in excess compared with the equivalent number of isocyanate groups. The composition also includes an aminoplast resin for reaction with hydroxyl groups on the urethane resin in an amount of less than about 10% by weight based on solids of the composition which is effective in thin film curing of the composition.Type: GrantFiled: May 22, 1995Date of Patent: November 4, 1997Assignee: PPG Industries, Inc.Inventors: Rodger G. Temple, Henry H. Crum, III, Jonathan T. Martz
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Patent number: 5661216Abstract: A coating composition based on amines, aldimines and isocyanates which forms a polyurea coating or film. These coating compositions are especially useful in the automotive refinish industry due to the cure rate at ambient conditions. The coatings of these compositions can be useful for obtaining low VOC (Volatile Organic Content) levels.Type: GrantFiled: July 31, 1995Date of Patent: August 26, 1997Assignee: BASF CorporationInventors: Thomas J. Laginess, Sudhakar Dantiki, Brian P. Koevenig, Rajnikant P. Shah
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Patent number: 5629402Abstract: This invention relates to coating compositions containing (A) a polyurethane system containing either a polyurethane containing ionic groups and polyethylene oxide units or a precursor thereof prepared from a blocked isocyanate prepolymer and a cross-linking agent and, optionally, (B) organic solvents. This invention further relates to the use of such coating compositions to prepare coatings that are permeable to water vapor.Type: GrantFiled: March 31, 1994Date of Patent: May 13, 1997Assignee: Bayer AktiengesellschaftInventors: Josef Pedain, Detlef-Ingo Schutze, Wilhelm Thoma, Klaus Nachtkamp
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Patent number: 5605721Abstract: The present invention is directed to an underlayment composition for an artificial playing surface comprised of a butadiene rubber, such as polybutadiene or styrene-butadiene that is commercially available as recycled polycord tires that have been granulized. An inorganic-base moisture-retaining agent such as vermiculite or perlite is also included in the composition in addition to a binder comprised of a mixture of isocyanate polyurethane and an inorganic acid. The present invention also provides a method of making the present composition. The method comprises the steps of mixing thoroughly granulized particles of butadiene rubber in a mixing container, mixing an inorganic-based moisture-retaining component with the butadiene rubber, mixing an acid having a pH .ltoreq.3 with the butadiene rubber and the inorganic-based moisture-retaining component, and mixing an isocyanate polyurethane with the butadiene rubber, the inorganic-based moisture-retaining component and the acid.Type: GrantFiled: June 7, 1995Date of Patent: February 25, 1997Inventor: Joseph W. Di Geronimo
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Patent number: 5580922Abstract: The invention is directed to a composition of matter useful as a paper impregnant, to the method of its use, and to the products produced by the method. Poly (diphenylmethane diisocyanate) or PMDI has been used in the past as a paper impregnant with or without propylene carbonate as a diluent. These products have generally required pressing under high pressures and at elevated temperatures. It has now been found that triacetin and/or triethyl citrate in usages up to about 20% of PMDI give superior performance in impregnated products. The modified PMDI will cure at essentially ambient conditions in times as short as 1-2 days to insoluble polyureas with low residual amounts of isocyanates and reaction byproducts such as 4,4'-diaminodiphenylmethane. The treated papers can be used in applications of which skins for sandwich panels and high strength corrugated board would be exemplary.Type: GrantFiled: June 6, 1995Date of Patent: December 3, 1996Assignee: Weyerhaeuser CompanyInventors: David W. Park, Frank R. Hunter
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Patent number: 5578675Abstract: Improved basecoat--clearcoat paint coating compositions which may be ambient cured are disclosed. The coating compositions comprise:1) a hydroxyl functional coreactant,2) at least one anhydride functional coreactant and,3) a carbodiimide compound.The improved compositions cure at a rate especially useful as refinish paint compositions.Type: GrantFiled: December 27, 1994Date of Patent: November 26, 1996Assignee: BASF CorporationInventors: Patrick J. Mormile, Rajnikant P. Shah, Anthony J. Tye
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Patent number: 5574083Abstract: Disclosed are certain aromatic polycarbodiimides. Also disclosed is the use of an aromatic polycarbodiimide containing only aromatic carbodiimide groups as a cross-linker for a coating binder polymer bearing carboxyl groups.Type: GrantFiled: April 29, 1994Date of Patent: November 12, 1996Assignee: Rohm and Haas CompanyInventors: Ward T. Brown, James C. Day
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Patent number: 5538547Abstract: A process for impregnating wood and wood products wherein the wood is treated with a composition comprising;(A) a salt of an organic or inorganic acid and an organopolysiloxane which contains SiC-bonded radicals with basic nitrogen in amounts of at least 0.5% by weight of basic nitrogen, based on the weight of this organopolysiloxane,(B) a water-repellent active compound which is not solid at 20.degree. C. under 1020 hPa, with the proviso that the water-repellent active compound can also be an organosilicon compound which is solid at 20.degree. C. under 1020 hPa and dissolves under these conditions to the extent of more than 50 parts by weight in 100 parts by weight of (A), if appropriate mixed with an organosilicon compound containing basic nitrogen in amounts of 0% to 0.5% by weight, based on the weight of this organosilicon compound, and/or silicic acid esters, and(c) water.Wood and wood products treated with the composition described above exhibit substantially reduced water absorption.Type: GrantFiled: April 19, 1994Date of Patent: July 23, 1996Assignee: Wacker-Chemie GmbHInventors: Dieter Gerhardinger, Hans Mayer, Guenther Kolleritsch
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Patent number: 5539037Abstract: An alkali metal salt additive in very low concentration in spandex (e.g., 0.02-0.25%) increases the heat set efficiency of spandex. The anion of the salt is a carboxylate having 1 to 10 carbon atoms or thiocyanate.Type: GrantFiled: September 30, 1993Date of Patent: July 23, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventor: Tahir Iqbal
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Patent number: 5521247Abstract: Aqueous coating agent including a water-dilutable mixture of binding agents ofI. 50 to 88 wt. % of a neutralised water-soluble reaction product including(A) 10 to 80 wt. % of a polyurethane resin with an acid number of 70 to 160, at least one terminal blocked isocyanate group devoid of free hydroxyl groups and fatty acid residues with more than 12 C-atoms and with a limiting viscosity number of 6.5 to 12.0 ml/g, measured in DMF at 20.degree. C., and(B) 20 to 90 wt. % of a polyester resin with an OH-number of 50 to 500, an acid number of less than 20, a limiting viscosity number of 8.0 to 13.0 ml/g, measured in DMF at 20.degree. C., with the reaction product having a limiting viscosity number of 13.5 to 18.0 ml/g measured in DMF at 20.degree. C.II. 10 to 40 wt. % of one or several blocked polyisocyanates not capable of being diluted with water, andIII. 2 to 30 wt. % of at least one amine resin by way of additional cross-linking agent.Type: GrantFiled: December 29, 1993Date of Patent: May 28, 1996Assignee: Herberts G.m.b.HInventors: Klaus Dobler, Michael Georgiadis, Wolfgang Goldner, Knut Graf
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Patent number: 5514722Abstract: The present invention is directed to an underlayment composition for an artificial playing surface comprised of a butadiene rubber, such as polybutadiene or styrene-butadiene that is commercially available as recycled polycord tires that have been granulized. An inorganic-base moisture-retaining agent such as vermiculite or perlite is also included in the composition in addition to a binder comprised of a mixture of isocyanate polyurethane and an inorganic acid. The present invention also provides a method of making the present composition. The method comprises the steps of mixing thoroughly granulized particles of butadiene rubber in a mixing container, mixing an inorganic-based moisture-retaining component with the butadiene rubber, mixing an acid having a pH.ltoreq.3 with the butadiene rubber and the inorganic-based moisture-retaining component, and mixing an isocyanate polyurethane with the butadiene rubber, the inorganic-based moisture-retaining component and the acid.Type: GrantFiled: August 12, 1994Date of Patent: May 7, 1996Assignee: Presidential Sports Systems, Inc.Inventor: Joseph W. Di Geronimo
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Patent number: 5508111Abstract: A polyurethane adhesive formed from (I) an NCO terminated prepolymer with excess of NCO and talc, and (II) a polyol, a urethane catalyst, talc and a minor amount of certain aryl or aromatic polyamines exhibits good sag and thixotropic properties and, also, exhibits good lap shear strength when cured between treatment-free substrates.Type: GrantFiled: March 5, 1993Date of Patent: April 16, 1996Assignee: GenCorpInventor: Arden E. Schmucker
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Patent number: 5506328Abstract: This invention relates to a process for coating a substrate comprising contacting the substrate with a low volatile organics, moisture curable, two-component coating composition comprising an admixture of an A-side and a B-side, said A-side comprising an aliphatic polyisocyanate having an isocyanate index relative to the number of isocyanate-reactive groups in said coating composition of at least about 200, preferably at least about 300, more preferably at least about 500, said B-side comprising a tertiary amine catalyst and optionally an isocyanate-reactive compound selected from the group consisting of monoahls, polyols, imines, oxazolidines, and combinations thereof, said coating composition optionally containing a solvent in an amount of less than about 45%, based upon the weight of the polyisocyanate in said coating composition, said coating composition having a viscosity as measured by ZAHN cup 2 of less than about 200 seconds, said composition being essentially free of any volatile mono- and di-isocyanType: GrantFiled: May 24, 1993Date of Patent: April 9, 1996Assignee: Olin CorporationInventors: Kiran B. Chandalia, Michael J. Morgan, James M. O'Connor, Stephen L. Goldstein
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Patent number: 5489664Abstract: Crosslinkable liquid composition based on organic isocyanates and epoxy compounds, comprising the following components:(A) an organic polyisocyanate;(B) a polyepoxide or mixture of a polyepoxide and a monoepoxide; and(C) a catalyst constituted by at least one cyanoderivative containing a quaternary nitrogen atom,which composition can be polymerized at temperatures of 40.degree. C. or higher, by a process comprising exposure thereof to a non-ionizing electromagnetic radiation having a frequency comprised in the microwave range of frequencies, to obtain a solid material endowed with an excellent combination of physical, chemical and mechanical properties.Type: GrantFiled: November 4, 1994Date of Patent: February 6, 1996Assignees: Enichem S.p.A., Eniricerche S.p.A.Inventors: Fabrizio Parodi, Renata Gerbelli, Mark De Meuse
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Patent number: 5455294Abstract: The present invention concerns a new, unconventional, mold-binding, water solidified polyurethane cast to be used in orthopedic departments for the correction of deformities, fixation of fractured limbs and joints, and mollification of affected parts, as well as the method of its preparation. The chief constituent, a polyurethane prepolymer, contains a stabilizer that can prolong appreciably the storage period of the cast material, maleic anhydride, and a mixed catalyst for control of hardening time, bis(2-morpholinoethoxy)ethane and anhydrous potassium carbonate.Type: GrantFiled: August 13, 1993Date of Patent: October 3, 1995Assignees: Wang Jian Zhang, Li Hai ShengInventor: Li H. Sheng
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Patent number: 5428104Abstract: Polyol compositions comprising a polyol, an insoluble fluorinated compound and a surfactant composition which is the reaction product of a stoichiometric excess of a polyisocyanate and a polyalkylene glycol monoalkyl ether of formula R--A--OH, wherein R is C.sub.1-25 alkyl and A is a polypropylenoxy chain, optionally containing up to 25% polyethylenoxy units, having a total length of from 4 to 39 units.Type: GrantFiled: November 22, 1993Date of Patent: June 27, 1995Assignee: Imperial Chemical Industries PLCInventors: Martin Barker, Karen Van Der Sande
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Patent number: 5424350Abstract: A water-permeable and fire-resistant film and the preparing method thereof is disclosed. The water-permeable and fire-resistant film comprises polyurethane resin; a first fire-resistant agent; a second fire-resistant agent, an inorganic fire-resistant agent and an additive agent. The first fire-resistant agent used is selected from the group consisting of paraffine chlorinated, decabromodiphenyI oxide, hexachloro benzene, hexabromo benzene, pentabromo ethyl benzene, pentabromo diphenyl oxide and octabromo diphenyl ether. The second fire-resistant agent used is selected from the group consisting of Sb2O3 and Sb2OS. The surface of the film produced is smooth.Type: GrantFiled: December 2, 1994Date of Patent: June 13, 1995Assignee: China Textile InstituteInventors: Shin-Chuan Yao, Jong-Fu Wu, Kun-Lin Cheng, Chiu-Hsiung Tsai, Farn-Ping Koong, Kun-Lung Chuang, Shu-Lan Yao, Chin-Liu Liu
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Patent number: 5419923Abstract: A method for manufacturing tracing paper, comprising coating a plastic film with a coating material. The coating material comprises a solvent system, adhesives, writable inorganic pigments and surfactants. The solvent system contains 50-80% by weight of aliphatic solvent and 20-50% by weight of aromatic solvent. The coating material includes 20-60% by weight of solid components. The inorganic pigments are in an amount of 30-60% based on the weight of the solid components of the coating material.Type: GrantFiled: February 16, 1994Date of Patent: May 30, 1995Assignee: Shinkong Synthetic Fiber Corp.Inventors: Jeremiah Chen, C. C. Chang
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Patent number: 5391681Abstract: Curable compositions based on epoxy resins or a mixture of epoxy resins and polyisocyanates and containing at least one compound of formula I: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7, R.sub.8 and R.sub.9 are each independently of one another hydrogen, alkyl, aryl, arylalkyl or halogen, and R.sub.2 together with R.sub.3 and R.sub.5 together with R.sub.6 and R.sub.8 together with R.sub.9 may each also represent a fused benzene ring.The compositions have high reactivity and at the same time good storage stability.Type: GrantFiled: May 27, 1993Date of Patent: February 21, 1995Assignee: Ciba-Geigy CorporationInventors: Andreas Muhlebach, Peter Flury
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Patent number: 5391614Abstract: This invention relates to a process for coating a substrate which comprises contacting the substrate with a low volatility organic (so-called "low VOC") coating composition having a viscosity as measured by ZAHN cup 2 of less than about 200 seconds and consisting essentially of at least one polyisocyanate prepolymer which is the reaction product of a polyisocyanate with an active hydrogen-containing compound selected from the group consisting of monoahls, polyols, imines, oxazolidines, and combinations thereof, a solvent in an amount of between 0% and 45% by weight based upon the amount of said polyisocyanate in said composition, and a tertiary amine catalyst, said composition being essentially free of any volatile mono- and di-isocyanates, and said composition being moisture curable upon exposure to atmospheric moisture. Also claimed is the coating composition itself.Type: GrantFiled: July 14, 1994Date of Patent: February 21, 1995Assignee: Olin CorporationInventors: Kiran B. Chandalia, Michael J. Morgan, Michael M. Martinez, James M. O'Connor, Stephen P. Noe
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Patent number: 5387644Abstract: A hardenable monomer composition useful for flooring composition, grouts, mortars and the like comprises a mixture of crosslinkable acrylic monomer, carbon black and/or polyester- or polyether-methane oligomer having at least two polymerizable double bonds and a paraffin oil.The monomer is preferably of the formula I ##STR1## and there is preferably present other monomers, particularly hydroxypropyl methacrylate.Type: GrantFiled: December 14, 1993Date of Patent: February 7, 1995Assignee: Sandoz Ltd.Inventor: Karoly Discho
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Patent number: 5356716Abstract: The present invention relates to waterproofing sealer compositions that protect various types of porous substrates from deterioration due to water absorption and thus extend their useful lives. Example of porous substrate are concrete, brick, masonry, ceramics, stones, cloth, wood and the like. These waterbased compositions comprise alkali metalalkylsiliconates, alkali silicates, polymers, diluents and additives.These sealer compositions do not change appearance and character of the substrate surface.Type: GrantFiled: September 4, 1992Date of Patent: October 18, 1994Inventor: Pratim R. Patel
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Patent number: 5331044Abstract: The present invention deals with low temperature impact resistant, easily flowing, thermoplastic polyurethane elastomer compositions, comprising:A) 5-95 parts by weight of at least one thermoplastic polyurethane elastomer (A) having a Shore A hardness less hah 95; andB) 95-5 parts by weight of at least one thermoplastic polyurethane elastomer (B) having a Shore A hardness greater than 98, whereby the parts by weight of (A) and (B) total 100 parts by weight; andC) 0-60 weight percent based on the weight of (A) and (B) of a reinforcing filler.The products are prepared by melting together polyurethane elastomers (A) and (B) at temperatures of from 140.degree.-250.degree. C., preferably in an extruder, and are most preferred for the preparation of ski boots and injection molded articles for motor vehicles.Type: GrantFiled: February 7, 1990Date of Patent: July 19, 1994Assignee: BASF AktiengesellschaftInventors: Deitrich Lausberg, Rolf Steinberger, Walter Heckmann, Harald Schulz
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Patent number: 5328954Abstract: Disclosed is an encrustation and bacterial-resistant coating for use on medical devices and in other medical-related applications. The coating includes a reaction product formed by the covalent linkage of a hydrophilic polyurethane prepolymer and aminopolycarboxylic acid. A urease inhibitor and/or an antibacterial agent may also be added to the coating.Type: GrantFiled: April 16, 1993Date of Patent: July 12, 1994Assignee: ICET, Inc.Inventor: Shantha Sarangapani
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Patent number: 5324773Abstract: Products made using the RIM process where the reaction mixture contains an acidic release agent have improved green strength when the reaction mixture also contains a peralkylated polyalkylene polyamine.Type: GrantFiled: December 1, 1993Date of Patent: June 28, 1994Assignee: Miles Inc.Inventors: Robson Mafoti, David D. Steppan, Michael F. Hurley, Albert Magnotta
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Patent number: 5319008Abstract: A moisture-curable, substantially solvent-free and anhydrous blend of a bituminous material such as asphalt and a liquid prepolymer is disclosed, which blend when cured, results in an elastomer having excellent adhesion to surfaces exposed outdoors. The stability of the blend derives from asphalt being microdispersed in a dispersed phase within a continuous phase of the liquid prepolymer so that particles of asphalt are in the size range from 0.5 .mu.m to 100 .mu.m. The asphalt is treated to react all functional groups it may have because they may react with a functional group of the liquid prepolymer. The prepolymer is a polyurethane, a terpolymer of ethylene-propylene-diene, or a silicone. The microdispersion is stably maintained by a compatibilizer having opposed substantially polar and non-polar terminal portions, present in an amount in the range from 0.01 to 5 parts per 100 parts of the blend. The compatibilizer is chosen from (A) an ester of a C.sub.2 -C.sub.Type: GrantFiled: March 27, 1992Date of Patent: June 7, 1994Assignee: Tremco, Inc.Inventor: Ronald J. Janoski
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Patent number: 5314983Abstract: Mixtures of polyisocyanates and epoxides are cured by microwave irradiation, optionally with microwave or thermal post-curing to produce cured polymer articles having good chemical, electrical and mechanical properties.Type: GrantFiled: November 9, 1992Date of Patent: May 24, 1994Assignee: Enichem S.p.A.Inventors: Mark T. DeMeuse, Fabrizio Parodi
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Patent number: 5302660Abstract: The invention relates to a process for the production of low-gel spinning solutions-surprisingly stable in their solution viscosity-of segmented polyurethane urea elastomers in highly polar solvents, such as dimethyl formamide or dimethyl acetamide, characterized by the use of multistage jet reactor, and to a multistage jet reactor.Type: GrantFiled: July 7, 1993Date of Patent: April 12, 1994Assignee: Bayer AktiengesellschaftInventors: Bernd Klinksiek, Rolf-Volker Meyer, Beatrix Frauendorf, Klaus Rall, Wolfgang 35e,uml/a/ cker, Hans-Joachim Wollweber, Helmut Ohse, Wolfram Wagner
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Patent number: 5286831Abstract: The present invention directed to an at least substantially pore-free polyurethane prepared by reacting at least one polyisocyanate and a component containing a partial carboxylic acid ester which is the reaction product of a carboxylic acid and an at least trihydric alcohol in quantities such that at least one of the hydroxyl groups of said alcohol is not esterified.Type: GrantFiled: November 9, 1989Date of Patent: February 15, 1994Assignee: Bayer AktiengesellschaftInventors: Bernhard Hess, Klaus Prater, Heinrich Heine, Joachim Franke, Hans-Dieter Jakob
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Patent number: 5286566Abstract: An electrically conductive polyurethane elastomer obtained by the reaction of a polytetramethylene ether glycol having the formula HO[(CH.sub.2).sub.4 O].sub.x H where x is from 8 to 41 and from about 20 to about 95 parts by weight per 100 parts by weight of said glycol of at least one diisocyanate, a sufficient amount of chain extender and cross linking agents to provide a crosslinked elastomer and an amount of an asymmetric ionic quarternary ammonium salt having the formula: ##STR1## where R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are C.sub.n H.sub.2n+1 and 1.ltoreq.n.ltoreq.25 sufficient to provide a D.C. volume resistivity of from about 10.sup.7 to about 10.sup.11 ohm cm. In a preferred embodiment the asymmetric ionic quarternary ammonium salt is hexadecyl ethyl dimethyl ammonium ethyl sulfate.Type: GrantFiled: August 31, 1993Date of Patent: February 15, 1994Assignee: Xerox CorporationInventors: Edward L. Schlueter, Jr., Henry L. Manuel, James F. Smith, Thomas C. Parker, Robert M. Ferguson
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Patent number: 5278223Abstract: The invention relates to optionally solventless two-component polyurethane surfacers containing finely divided fillers in a high pigment volume concentration based on a polyfunctional isocyanate component (B) and a polyol component (A) which is liquid at room temperature and which consists of mixture components containing isocyanate-reactive hydroxyl groups with an at least predominant content of branched-chain polyols (A1) containing ester and ether groups, which contains at least a proportion of the finely divided fillers and, optionally, the additives and which, for application, is mixed with the isocyanate component (B) and applied as a mixture which can still be processed by shaping.Type: GrantFiled: March 27, 1992Date of Patent: January 11, 1994Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Bernhard Gruenewaelder, Bernhard Parent, Hermann Kluth, Juergen Wegner, Werner Haller
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Patent number: 5256729Abstract: A composition and method for consolidating proppant or gravel for propping fractures about, or for gravel packs for sand control in, wells in subterranean formations characterized by an improvement in which there is used a combination of reactants, including a capped diisocyanate that will produce polyurethane and coat the catalyst in situ. Also disclosed are specific examples of satisfactory frac fluids, diluents and catalysts for both a specially designed one-pass system and, preferably, a two-pass system of putting and consolidating the proppant in a fracture.Type: GrantFiled: January 22, 1993Date of Patent: October 26, 1993Assignee: Atlantic Richfield CompanyInventors: Helmuth Kutta, Robin Wiser-Halladay
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Patent number: 5247001Abstract: The invention relates to composite conducting polymers.It comprises producing a composite polymer comprising a base polymer formed from a normal polyurethane in which a conducting polymer formed from doped polypyrrole is dissolved.It enables a conducting polypolymer to be obtained, the mechanical characteristics of which are very substantially those of a normal polyurethane.Type: GrantFiled: December 24, 1991Date of Patent: September 21, 1993Assignee: Thomson-CSFInventor: Olivier Lacour
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Patent number: 5229453Abstract: A hydrophilic polyurethane prepolymer in a compatible, water-miscible solvent or solvent blend having a solids content of greater than about 10 and less than about 50 percent prepolymer in organic solvent that reacts with water at about a 1:1 ratio by volume to produce an excellent gel for use in sealing water containing structures and soil stabilization. In the cure process, the compositions of the present invention expand less than 50%, and preferably less than 30%.Type: GrantFiled: June 4, 1991Date of Patent: July 20, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventor: Gary P. Roberts
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Patent number: 5221783Abstract: A polyurethane filleting composition which has production of electronic assemblies. The filleting composition is a self-curing polyurethane mixture which has a low dielectric constant, good thermal conductivity, and relatively long working life. The composition is a four part mixture containing:(a) a diisocyanate having the formulaOCN--[CH.sub.2 ]n--NCOwhere n=1 to 6;(b) a polyol having the formula ##STR1## where m=1 to 10; (c) a filler/curing promoter additive; and(d) a viscosity control additive.Type: GrantFiled: April 28, 1989Date of Patent: June 22, 1993Assignee: Hughes Aircraft CompanyInventors: Mel V. Huynh, Ludmila H. Kram