Nitrogen Ring Is Part Of A Ring System Having Three Or More Rings Fused Or Bridged Together Patents (Class 524/89)
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Patent number: 5708063Abstract: A fulgide or fulgimide compound having a cyclopropyl group as a substituent. The compound has excellent durability which changes reversibly in color from a colorless form to a colored form by the action of light containing ultraviolet rays such as sunlight or the light from a mercury lamp. There are also provided processes for its production, a composition comprising it, and its use.Type: GrantFiled: February 15, 1996Date of Patent: January 13, 1998Assignee: Tokuyama CorporationInventors: Satoshi Imura, Tsuneyoshi Tanizawa, Takashi Kobayakawa
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Patent number: 5698618Abstract: A coating composition is formed from an acid-set coating varnish and a pigment composition. The pigment composition includes a specific organic dyestuff derivative and a specific basic-group-containing resin-type pigment dispersant. The coating composition excels in pigment dispersibility, nonflocculation properties, noncrystallizability and fluidity. When used as a coating, the coating composition has excellent color tone, gloss, hardness, weather resistance, and solvent resistance.Type: GrantFiled: July 18, 1996Date of Patent: December 16, 1997Assignee: Toyo Ink Manufacturing Co., Ltd.Inventors: Takashi Kamikubo, Tadashi Itabashi, Masami Kuwahara
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Patent number: 5597408Abstract: A composition having 1.0-50.0 wt % of a compound having both a structure of organosilane, organosilazane, or organosiloxazane and a structure of a dye compound which has light-absorbing capabilities in a particular wavelength band, 50.0-99.0 wt % of solvent, and optionally 0"10 wt % of a water-soluble polymer, improves adhesion to a photoresist film and anti-reflection characteristics in exposure.Type: GrantFiled: November 30, 1995Date of Patent: January 28, 1997Assignee: Samsung Electronics Co., Ltd.Inventor: Young-joon Choi
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Patent number: 5594089Abstract: Thermomechanical and thermo-oxidative stabilities in heterocycle or heterocycle sulfone resin composites are improved by forming four crosslinks at each addition polymerization site in the backbone of the resin using crosslinking functionalities.Type: GrantFiled: October 21, 1994Date of Patent: January 14, 1997Assignee: The Boeing CompanyInventors: Hyman R. Lubowtiz, Clyde H. Sheppard
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Patent number: 5578665Abstract: The present invention relates to novel piperidine compounds of the formula (I) ##STR1## in which A is e.g. a group of the formula ##STR2## where R.sub.4 is e.g. hydrogen or methyl, X.sub.3 is e.g. --O-- or --NH-- and R.sub.5 ' is e.g. ethylene, propylene or decamethylene, R.sub.1 is e.g. methyl, methoxy, ethoxy or OH, R.sub.2 and R.sub.3 are e.g. methyl, m+n is e.g. a number from 1 to 40, n varies e.g. from zero to 50% of the sum m+n, X.sub.1 is e.g. as defined for R.sub.1 or is a group (CH.sub.3).sub.3 SiO-- and X.sub.2 is e.g. hydrogen, methyl, ethyl, a group (CH.sub.3).sub.3 Si-- or a group ##STR3## and, when m+n is a number from 3 to 10, X.sub.1 and X.sub.2 together also form a direct bond. The compounds of the formula (I) are effective in stabilizing an organic material against thermal, oxidative and light-induced degradation.Type: GrantFiled: March 7, 1995Date of Patent: November 26, 1996Assignee: Ciba-Geigy CorporationInventors: Primo Carrozza, Valerio Borzatta
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Patent number: 5523387Abstract: This invention relates to dyes in salt form which are useful for mass dyeing of synthetic polymers. In particular, this invention relates to ammonium or immonium salt-containing dyes that display good polymer affinity, and the methods for using those dyes to color polymeric substrates.Type: GrantFiled: June 14, 1994Date of Patent: June 4, 1996Assignee: Sandoz Ltd.Inventors: Jurgen Goldmann, Bansi L. Kaul
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Patent number: 5512376Abstract: A reactive component, which is curable to form a nonpolar polymer containing silicon and carbon atoms, and having a glass transition temperature of at least 20.degree. C., is mixed with an antiplasticizer. The resulting mixture, a curable composition, is cured to form a composition having an increased modulus. The reactive component preferably comprises a polyene having at least two hydrosilation reactive carbon-carbon double bonds (e.g., dicyclopentadiene), and a silicon compound having at least two hydrosilation reactive .ident.SiH groups. Preferably the silicon compound comprising at least one member selected from the group consisting of cyclic polysiloxanes, tetrahedral siloxysilanes, and linear polysiloxanes. Preferably the resulting cured composition is crosslinked, due to at least one member selected from the group consisting of the polyene and the silicon compound having more than two hydrosilation reactive sites. Preferably the curable composition further comprises a hydrosilation catalyst.Type: GrantFiled: June 20, 1994Date of Patent: April 30, 1996Assignee: Hercules IncorporatedInventors: Richard L. Brady, Samuel A. Thompson
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Patent number: 5510403Abstract: A process for dyeing synthetic polyamide comprising applying to the polyamide a compound of formula I or II ##STR1## in which R.sub.2 is hydrogen, trifluoromethyl, halogen, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, cyano, nitro, hydroxyl, amino, C.sub.1-4 alkylamino, di-(C.sub.1-4)alkylamino, phenylamino, N-C.sub.1-4 alkyl-N-phenylamino; benzoylamino, acyl, acyloxy or acylamino,Me is a divalent metal atom;R.sub.1 is 1,2-phenylene, 1,2-, 2,3- or 1,8-naphthalene or 2,2'-diphenylene, the phenylene and naphthalene groups of R.sub.1 being unsubstituted or mono- or di-substituted by R.sub.2a where R.sub.2a has a significance of R.sub.2 other than hydrogen or by 3 or 4 halogen atoms; or in the naphthalene group two adjacent carbon atoms can be bridged by --NH--CO--NH--, --N.dbd.C(CH.sub.3)--NH--, --N.dbd.C(C.sub.6 H.sub.5)--NH--, --CO--N(C.sub.6 H.sub.5)--CO--, --CO--NH--CO--, ##STR2## R.sub.3 is ##STR3## where R is hydrogen or C.sub.1-4 alkyl unsubstituted or substituted by 1 to 4 groups selected from halogen, cyano, C.Type: GrantFiled: January 7, 1991Date of Patent: April 23, 1996Assignee: Sandoz Ltd.Inventor: Bansi L. Kaul
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Patent number: 5484901Abstract: Isoindolineazo pigments of the general formula I ##STR1## where A is the radical of an active-methylene compound or .dbd.S;L is substituted or unsubstituted 1,4-phenylene, 1,3-phenylene or 1,5-naphthylene;K is the radical of a coupling component K--H; and the benzene ring D is optionally substituted,are useful for pigmenting high polymer organic materials.Type: GrantFiled: March 22, 1995Date of Patent: January 16, 1996Assignee: BASF AktiengesellschaftInventors: Michael Krapp, Georg Henning
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Patent number: 5480926Abstract: This invention relates to a photo-stabilized polymer blend comprising:(a) at least one polyethylene terephthalate-based (PET) copolymer comprising 1,4-cyclohexanedimethanol, and(b) an ultraviolet absorber, at least one compound selected from the group consisting of cyclic imino esters.Type: GrantFiled: April 28, 1995Date of Patent: January 2, 1996Assignee: Eastman Chemical CompanyInventors: David R. Fagerburg, Michael E. Donelson
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Patent number: 5475056Abstract: The invention relates to plastisols which prevent a yellowing of top coats applied thereon, to a process for their preparation and to their use. The plastisols based on PVC or methacryl contain, in addition to basic adhesion promoters, aldehydes, ketones, their derivatives, oligomers or mixtures of same.Type: GrantFiled: April 13, 1995Date of Patent: December 12, 1995Assignee: Teroson GmbHInventors: Bernhard Koesters, Xaver Muenz, Manfred Asang
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Patent number: 5473001Abstract: Hindered amine light stabilizers are provided in which the hindered amine is contained in a unit of formula ##STR1## where X is ##STR2## and R.sup.1, R.sup.2, R.sup.3 and A are as defined as in the Summary of the Invention. Unique polymeric and non-polymeric compounds containing this unit are useful as additives for the stabilization of polymeric compositions which are normally subject to thermal, oxidative or actinic light degradation.Type: GrantFiled: April 17, 1995Date of Patent: December 5, 1995Assignee: Elf Atochem North America, Inc.Inventor: Terry N. Myers
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Patent number: 5461151Abstract: A hydroxy group-containing aryl triazine ultraviolet absorber represented by the formula: ##STR1## wherein the R moiety of the OR group is a linear or branched aliphatic alkyl group containing 3 carbon atoms substituted by one or more alkoxy groups of 1 to 12 carbon atoms, said moiety being further substituted by one or more hydroxy groups, andwherein R.sup.19, R.sup.20, R.sup.21, R.sup.22, R.sup.23, R.sup.24 and R.sup.25 are independently selected from the group consisting of hydrogen, hydroxy, alkyl of 1 to 12 carbon atoms, alkoxy of 1 to 12 carbon atoms, sulfonic, halo, carboxy, haloalkyl and acrylamino.Type: GrantFiled: February 18, 1994Date of Patent: October 24, 1995Assignee: Cytec Technology CorporationInventor: Paul S. Waterman
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Patent number: 5418267Abstract: The present invention relates to novel piperidine compounds of the formula (I) ##STR1## in which A is e.g. a group of the formula ##STR2## where R.sub.4 is e.g. hydrogen or methyl, X.sub.3 is e.g. --O-- or --NH-- and R.sub.5' is e.g. ethylene, propylene or decamethylene, R.sub.1 is e.g. methyl, methoxy, ethoxy or OH, R.sub.2 and R.sub.3 are e.g. methyl, m+n is e.g. a number from 1 to 40, n varies e.g. from zero to 50% of the sum m+n, X.sub.1 is e.g. as defined for R.sub.1 or is a group (CH.sub.3).sub.3 SiO-- and X.sub.2 is e.g. hydrogen, methyl, ethyl, a group (CH.sub.3).sub.3 Si-- or a group ##STR3## and, when m+n is a number from 3 to 10, X.sub.1 and X.sub.2 together also form a direct bond. The compounds of the formula (I) are effective in stabilizing an organic material against thermal, oxidative and light-induced degradation.Type: GrantFiled: April 28, 1994Date of Patent: May 23, 1995Assignee: Ciba-Geigy CorporationInventors: Primo Carrozza, Valerio Borzatta
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Patent number: 5405892Abstract: A melt-stable, pigmented thermoplastic molding composition is disclosed. Accordingly, to the composition which contains polycarbonate resin and pigment there is imparted an improved level of melt stability upon the incorporation therewith of an additive amount of a melt stabilizer conforming to ##STR1## where R.sub.1, R.sub.2, R.sub.3 and n are defined. In an additional embodiment the invention relates to a color concentrate containing polycarbonate resin, up to 30% of a pigment and an effective amount of said stabilizer.Type: GrantFiled: June 22, 1994Date of Patent: April 11, 1995Assignee: Miles Inc.Inventors: Sivaram Krishnan, James B. Johnson, Susan H. Bates, Edward M. Anderson
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Patent number: 5397819Abstract: Provided is a method for tagging thermoplastic containers using near infrared fluorescing compounds or copolymerized residues readily capable of detection. Also provided is a method for identifying a thermoplastic container. Also provided are thermoplastic polymer compositions comprised of the near infrared fluorescing compounds or residues and articles comprised of such compositions. Also provided are new compounds useful as near infrared fluorophoric markers in the practice of this invention. The methods, compositions, and compounds of the present invention thus provide a total system useful for marking, for identification purposes, the various classes of thermoplastic wastes, so that they can be identified, sorted, and subsequently recycled.Type: GrantFiled: November 24, 1993Date of Patent: March 14, 1995Assignee: Eastman Chemical CompanyInventors: James J. Krutak, Michael R. Cushman, Clarence A. Coates, William W. Parham, Max A. Weaver, Gabor Patonay
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Patent number: 5376710Abstract: Compounds which comprise at least one group of the formula I or II ##STR1## and at least one polyalkylpiperidine group of the formula III ##STR2## in which R and R.sub.1 to R.sub.6 have the meaning indicated in claim 1, are effective stabilizers for organic materials against damage by light, oxygen and heat.Type: GrantFiled: March 10, 1993Date of Patent: December 27, 1994Assignee: Ciba-Geigy CorporationInventors: Mario Slongo, Jean-Luc Birbaum, Jean Rody, Andreas Valet
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Patent number: 5371122Abstract: A polymer composite contains colorant molecules dispersed therein. The colorant molecules can be dispersed in the polymer or bound to the polymer molecules. When the polymer is a polyamide, the polyamide is in a noncrystalline state due to the inhibition of crystallization imparted by the size and shape of the colorant molecules because the colorant is separated on a molecular level. A high colorant availability is obtained. A method of producing the polymer composite includes the steps of forming a metastable polymer resin layer, applying a film of colorant to the layer, stabilizing the layer, dissolving the stable layer in a solvent, aspirating the solution to remove impurities and aggregates and then removing the solvent. A polymer composition can be produced by mixing the polymer composite with a polymer.Type: GrantFiled: March 24, 1993Date of Patent: December 6, 1994Assignee: Mitsuboshi Belting Ltd.Inventors: Masahito Kawahara, Koichi Sayo, Kazuo Goto, Toru Noguchi, Yoshio Yamaguchi, Shigehito Deki
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Patent number: 5369140Abstract: A radiation curable composition contains as light stabiliser a UV absorber of formula I ##STR1## wherein R is hydrogen or C.sub.1 -C.sub.18 alkyl, R.sub.1 and R.sub.2 are each independently of the other H, OH, C.sub.1 -C.sub.12 alkyl, halogen or halomethyl,R.sub.3 and R.sub.4 are each independently of the other H, OH, C.sub.1 -C.sub.12 alkyl, C.sub.1 -C.sub.18 alkoxy or halogen, andR.sub.5 and R.sub.6 are each independently of the other H, C.sub.1 -C.sub.12 alkyl or halogen. These UV absorbers are substantially non-yellowing.Type: GrantFiled: May 3, 1991Date of Patent: November 29, 1994Assignee: Ciba-Geigy CorporationInventors: Andreas Valet, Manfred Kohler
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Patent number: 5354513Abstract: Disclosed is a polarizing film comprising a hydrophobic polymer containing a dichroic organic colorant in an oriented state which is characterized in that the dichroic organic colorant is substantially insoluble in water, organic solvents and liquid crystals and the dichroic ratio of the colorant is not less than 7 when it is measured with the film obtained by blending the colorant intimately with polyethylene terephthalate, melting the resulting blend and forming it into a film. This polarizing film has exceptionally excellent moisture resistance and thermal resistance.Type: GrantFiled: October 13, 1993Date of Patent: October 11, 1994Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Katsuji Nakamura, Junichi Fujio, Shin Hosonuma, Masakatsu Nakatsuka, Tsutomu Nishizawa
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Patent number: 5350786Abstract: Stabilizers for organic polymers, consisting of one or more compounds of the classis of the sterically hindered amines (HALS) are directly added to the reaction mixture during the (co)polymerization of the .alpha.-olefins or of their mixtures with other unsaturated monomers.The so-obtained polymeric compositions result perfectly stabilized and show a thermo- and photo-oxidative resistance higher than that of the same polymeric compositions to which the same stabilizers are added by a traditional route.Type: GrantFiled: March 4, 1993Date of Patent: September 27, 1994Assignee: Enichem Synthesis S.p.A.Inventors: Silvestro Costanzi, Damiano Gussoni, Luciano Pallini
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Patent number: 5340910Abstract: Provided is an improved process for the synthesis of 1-cyano-3H-dibenz[f,ij] isoquinoline-2,7-dione compounds, and process exhibiting improvements in quality of products, safety, fewer environmental concerns and economics when compared to presently known processes. The compounds are useful as colorants for polyesters, and selected compounds and when combined with small quantities of certain red colorants are particularly efficacious as blue toners for polyesters.Type: GrantFiled: June 21, 1993Date of Patent: August 23, 1994Assignee: Eastman Chemical CompanyInventors: Kim S. Chamberlin, Wayne P. Pruett, Max A. Weaver, Samuel D. Hilbert, Donna R. Quillen, Preston K. Salyer
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Patent number: 5330686Abstract: Described is a photochromic composition which is a polymerizate of acrylate monomer(s), a crosslinking amount of anhydrous acrylic anhydride and/or anhydrous methacrylate anhydride and a photochromic amount of pyrido benzoxazine. Depending on the amount of crosslinking agents and the other components selected to form the polymerizate, the polymerizate will exhibit improved temperature stability with regard to photocolorability and/or prevention of activation in sunlight.Type: GrantFiled: August 19, 1992Date of Patent: July 19, 1994Assignee: PPG Industries, Inc.Inventors: Robert A. Smith, Barry Van Gemert
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Patent number: 5322868Abstract: o-Hydroxyphenyl-s-triazines of formula I ##STR1## wherein n is 1 or 2 and R.sub.1 to R.sub.7 are as defined in claim 7, are good light stabilizers for coating compositions which contain a basic curing catalyst. In contradistinction to other UV absorbers, they do not cause discolorations in the presence of such catalysts.Type: GrantFiled: February 28, 1992Date of Patent: June 21, 1994Assignee: Ciba-Geigy CorporationInventors: Andreas Valet, Godwin Berner
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Patent number: 5314936Abstract: The invention relates to an aqueous polymer dispersion which may optionally contain mineral additives and/or pigments and which essentially consists of a mixture ofA) a 20% to 65% w/w aqueous dispersion of a copolymer of(a) an olefinically unsaturated compound containing one or more carboxyl groups and/or amide groups, and(b) at least two monomers selected from the group consisting of acrylates and methacrylates and vinylaromatic compounds, andB) from 0.1 to 5% w/w, based on the weight of the copolymer contained in component (A), of at least one aromatic ketone of the general formula (I) ##STR1## in which R stands for an alkyl or aryl radical and R.sup.1 stands for an aryl radical containing from 1 to 3 radicals of the formula --O--C(O)--O-- attached to one or more oxaalkylene groups.Such polymer dispersions are suitable for the manufacture of paints and coating systems.Type: GrantFiled: February 12, 1992Date of Patent: May 24, 1994Assignee: BASF AktiengesellschaftInventors: Manfred Schwartz, Reinhard Baecher, Bernhard Dotzauer, Eckehardt Wistuba, Andreas Boettcher
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Patent number: 5312851Abstract: A light-resistant wholly aromatic polyamide resin composition comprises a light-resisting agent blended to a wholly aromatic polyamide resin and comprising at least one naphthalene ring structure-containing compound of the formula (I): ##STR1## wherein Ar.sub.1, Ar.sub.2, Ar.sub.3 =a divalent organic group, X=an amide bond group (--CONH), Y=an amide bond group or an imide bond group ##STR2## A and B=a monovalent organic group when Y=an amide bond group, or =a divalent organic group when Y=an imide bond group, n=1 to 10, and at least one of Ar.sub.1, Ar.sub.2, Ar.sub.3, A and B has a naphthalene ring structure.Type: GrantFiled: December 29, 1992Date of Patent: May 17, 1994Assignee: Teijin LimitedInventors: Toshitsugu Matsuki, Tsutomu Kiriyama, Toshihiro Santa
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Patent number: 5312568Abstract: Process for the manufacture of a polarizing film by drawing a polymer film containing a dichroic dye at a temperature above the glass transition temperature of the polymer, the polymer film consisting mainly of a semicrystalline polyolefine and being drawn at a temperature below the crystalline melting point of the polyolefine, the dye being present in liquid form at that drawing temperature, and a polarizing dye-containing polyolefine film having a dichroic ratio of at least 15.Type: GrantFiled: August 6, 1993Date of Patent: May 17, 1994Assignee: DSM N.V.Inventor: Cornelis W. M. Bastiaansen
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Patent number: 5286418Abstract: Disclosed is a polarizing film comprising a hydrophobic polymer containing a dichroic organic colorant in an oriented state which is characterized in that the dichroic organic colorant is substantially insoluble in water, organic solvents and liquid crystals and the dichroic ratio of the colorant is not less than 7 when it is measured with the film obtained by blending the colorant intimately with polyethylene terephthalate, melting the resulting blend and forming it into a film. This polarizing film has exceptionally excellent moisture resistance and thermal resistance.Type: GrantFiled: July 3, 1991Date of Patent: February 15, 1994Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Katsuji Nakamura, Junichi Fujio, Shin Hosonuma, Masakatsu Nakatsuka, Tsutomu Nishizawa
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Patent number: 5268394Abstract: The invention relates to the use of an acridans of Structure (I) as a stabilizer, preferably combined with hindered amine, phenolic, and phosphite stabilizers for stabilizing polyether polyols for polyurethane flexible foams and as stabilizers for the polyglycols, heat transfer fluids, lubricating additives.Type: GrantFiled: February 9, 1993Date of Patent: December 7, 1993Assignee: Uniroyal Chemical Company, Inc.Inventors: Edward L. Wheeler, Lawrence B. Barry, Mark C. Richardson
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Patent number: 5258208Abstract: Process for the manufacture of a polarizing film by drawing a polymer film containing a dichroic dye at a temperature above the glass transition temperature of the polymer, the polymer film consisting mainly of a semi-crystalline polyolefine and being drawn at a temperature below the crystalline melting point of the polyolefine, the dye being present in liquid form at that drawing temperature, and a polarizing dye-containing polyolefine film having a dichroic ratio of at least 15.Type: GrantFiled: June 11, 1992Date of Patent: November 2, 1993Assignee: DSM N.V.Inventor: Cornelis W. M. Bastiaansen
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Patent number: 5250592Abstract: Compositions comprising an organic material liable to thermal, oxidative and/or actinic degradation and at least one compound of the formula (I) ##STR1## are described in which R is hydrogen, C.sub.1 -C.sub.18 alkyl, C.sub.1 -C.sub.18 alkoxy, halogen, nitro, phenyl-C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.18 alkanoyl, benzoyl, (C.sub.1 -C.sub.6 alkyl)benzoyl, C.sub.2 -C.sub.18 alkenoyl, --N(R.sub.7)(R.sub.7a), --OH or --CO-A, R.sub.1 has the same possibilities of meaning as R, R.sub.2 is hydrogen or C.sub.1 -C.sub.4 alkyl and R.sub.3 is hydrogen or halogen, A is hydroxyl, C.sub.1 -C.sub.18 alkoxy, C.sub.5 -C.sub.12 cycloalkoxy, benzyloxy or benzyloxy substituted by C.sub.1 -C.sub.4 alkyl and/or halogen, --N(R.sub.7)(R.sub.7a), --NH--NH--R.sub.8 or leads to di-, tri- or tetrameric ring systems containing rings of the formula I via a bridging member, and in which R.sub.5 and R.sub.Type: GrantFiled: December 23, 1992Date of Patent: October 5, 1993Assignee: Ciba-Geigy CorporationInventor: Peter Nesvadba
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Patent number: 5246989Abstract: A photochromic compound of the present invention is a spiroxazine compound represented by the following formula: ##STR1## wherein R.sup.1 to R.sup.3 represent a monovalent organic group such as alkyl group, Y represents a fused heterocyclic aromatic hydrocarbon group or an unsaturated heterocyclic group if R.sup.1 and R.sup.2 are both methyl groups, and represents an aromatic hydrocarbon group or unsaturated heterocyclic group if R.sup.1 and R.sup.2 are other than the above mentioned. This compound shows an excellent photochromic characteristics even at high temperatures not less than ambient temperature.Type: GrantFiled: March 28, 1991Date of Patent: September 21, 1993Assignee: Tokuyama Soda Kabishiki KaishaInventors: Kayo Iwamoto, Takashi Tanaka, Satoshi Imura, Seiji Okazaki, Shinsuke Tanaka
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Patent number: 5229442Abstract: Stabilizing compositions for organic polymers, composed of mixtures of at least one liquid phenolic antioxidant and at least one aminic antioxidant, subjected to thermal treatment, are characterized by their stabilizing capacity which is considerably higher than that of either single components or of corresponding untreated mixtures.These stabilizing compositions can be used in all field where the single components of the mixtures are generally used and, preferably, in the stabilization of organic polymers normally subject to deterioration due to oxidation processes.Type: GrantFiled: March 6, 1992Date of Patent: July 20, 1993Assignee: Enichem Synthesis S.p.A.Inventors: Fabio Broussard, Carlo Busetto
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Patent number: 5213733Abstract: Synthetic textiles containing a photochromic pigment. The pigments are prepared by encapsulating a photochromic pigment in a thermoplastic polymer having a high melt flow index, mixed with a primary thermoplastic resin, and extruded at a temperature of less than 250.degree. C. through a spinnerette having a diameter of at least 0.3 ml.Type: GrantFiled: June 3, 1991Date of Patent: May 25, 1993Assignee: Industrial Technology Research InstituteInventors: Yean-Rong Hwu, Chi-Chung Bai, Li-Chang Tao, Der-Guey Luo, Andrew T. Hu
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Patent number: 5162091Abstract: Polyester fibers produced by adding a compound of the following general formula (1), (2) or (3) to a polyester (a) comprising ethylene terephthalate as the main recurring unit and melt-spinning the resulting composition: ##STR1## which can be easily spun and have an excellent hand.Type: GrantFiled: April 2, 1991Date of Patent: November 10, 1992Assignee: Kao CorporationInventors: Yasuo Ishii, Tsutomu Tanaka, Nobuyuki Suzuki, Shigetoshi Suzue
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Patent number: 5162407Abstract: A sealant composition especially useful for porous materials such as wood, concrete and mansonry is provided comprising: (a) a silanol-terminated polysiloxane having a molecular weight greater than about 2000; (b) a multifunctional silane having functional groups which condense with silanol groups in the presence of atmospheric moisture at room temperature to form a cross-linked polymer; and (c) a nonaqueous volatile solvent which is non-reactive with components (a) and (b).The sealant composition renders said materials waterproof by coating and filling in the pores of said material with cured silicone rubber product.In a preferred embodiment the composition also contains a metal-containing curing catalyst and a volatile or subliming chelating agent in an amount sufficient to prevent cure of the composition in the storage container prior to or during use.The composition may also comprise adhesion agents, surfactants and pigments.Type: GrantFiled: March 6, 1991Date of Patent: November 10, 1992Assignee: Investors Diversified Capital, Inc.Inventor: Ronald L. Turner
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Patent number: 5155148Abstract: The present invention relates to polymerizable esters containing derivatives from p-hydroxydiphenylamine which are useful in the stabilization of oxidizable organic materials such as rubber, oils and the like.Type: GrantFiled: April 26, 1991Date of Patent: October 13, 1992Assignee: The Goodyear Tire & Rubber CompanyInventors: Dane K. Parker, Budd H. Sturm
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Patent number: 5100940Abstract: Phenolic N-(amido)imides are provided which are useful as antioxidant stabilizers for organic materials, including a large variety of synthetic polymers, typically subject to thermooxidative degradation. The antioxidant effectiveness of the phenolic N-(amido)imide stabilizers is enhanced by the deactivating potential of the amido-imide moiety towards metals or metal ions that frequently contaminate polymer compositions and serve to catalyze thermal degradation.Type: GrantFiled: August 20, 1991Date of Patent: March 31, 1992Assignee: Atochem North America, Inc.Inventor: Jerome Wicher
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Patent number: 5087658Abstract: A heat-resistant resin paste consisting essentially of a first organic liquid (A.sub.1), a second organic liquid (A.sub.2), a heat-resistant resin (B) which is soluble in an organic liquid mixture consisting essentially of the first organic liquid (A.sub.1) and the second organic liquid (A.sub.2), and fine particles of a heat-resistant resin (C) which are soluble in the first organic liquid (A.sub.1), but insoluble in the second organic liquid (A.sub.2). The first organic liquid (A.sub.1), the second organic liquid (A.sub.2), and the heat-resistant resin (B) are brought into a solution in which the fine particles of a heat-resistant resin (C) are dispersed. The heat-resistant resin paste may be suitably used for screen process printing to provide integrated circuit devices with insulator layers or surface protecting layers. The heat-resistant resin paste is suitable for forming insulator layers or surface protecting layers in integrated circuit devices by employing screen process printing.Type: GrantFiled: December 18, 1989Date of Patent: February 11, 1992Assignee: Hitachi Chemical Company, Ltd.Inventors: Hiroshi Nishizawa, Kenji Suzuki, Yoshiyuki Mukoyama, Tohru Kikuchi, Hidetaka Sato
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Patent number: 5079299Abstract: This invention provides a mold release composition copmrising (1) a compound or a polymer having at least one of perfluoroalkyl groups having 4 to 20 carbon atoms and perfluoroalkenyl groups having 4 to 20 carbon atoms, and (2) a ladder polymer of organosilsesquioxane.Type: GrantFiled: July 16, 1989Date of Patent: January 7, 1992Assignee: Daikin Industries, Ltd.Inventors: Iwao Hisamoto, Masayoshi Shinjyo, Seiji Takubo, Yasuko Katakura
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Patent number: 5066541Abstract: High thermal stabilities are achievable in linear or multidimensional sulfone, solvent resistant oligomers by incorporating oxazole, thiazole, or imidazole linkages into the oligomer backbone. Blended oligomers of crosslinking oligomers and noncrosslinking compatible polymers are also described. The oligomers include residues of four-functional compounds of the formula: ##STR1## (or isomers thereof) wherein M=--CO--, --S--, --O--, --SO.sub.2 -- or --(CF.sub.3).sub.2 C--; andY=--OH, --SH, or --NH.sub.2.In an improved method, the reactants are condensed at or below ambient temperature in the presence of pyridine in a suitable solvent such as N,N'-dimethylacetamide (DMAC).Type: GrantFiled: December 16, 1988Date of Patent: November 19, 1991Assignee: The Boeing CompanyInventors: Hyman R. Lubowitz, Clyde H. Sheppard, Ronald R. Stephenson
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Patent number: 5059356Abstract: Disclosed is a polarizing film comprising a hydrophobic polymer containing a dichroic organic colorant in an oriented state which is characterized in that the dichroic organic colorant is substantially insoluble in water, organic solvents and liquid crystals and the dichroic ratio of the colorant is not less than 7 when it is measured with the film obtained by blending the colorant intimately with polyethylene terephthalate, melting the resulting blend and forming it into a film. This polarizing film has exceptionally excellent moisture resistance and thermal resistance.Type: GrantFiled: September 6, 1990Date of Patent: October 22, 1991Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Katsuji Nakamura, Junichi Fujio, Shin Hosonuma, Masakatsu Nakatsuka, Tsutomu Nishizawa
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Patent number: 5043372Abstract: N,N'-hydrocarbylenebis[N-(2,2,6,6-tetraalkyl-4-piperidinyl)amic acid hydrazides] and their derivatives are useful for stabilizing polymeric systems which are subject to degradation and/or discoloration upon exposure to heat and/or light. The novel compounds contain at least two hindered amine light stabilizing groups and two hydrazide or hydrazide derivative thermal oxidative stabilizing groups.The novel compounds are excellent light stabilizers for polyolefins, have low volatility and are not readily lost from polymeric systems via volatilization, migration or extraction.Type: GrantFiled: December 22, 1989Date of Patent: August 27, 1991Assignee: Atochem North America, Inc.Inventor: Ronald E. MacLeay
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Patent number: 5004759Abstract: Macrocyclic polyaminotriazines containing tetramethylpiperidine side groups are suitable for use as stabilisers, in particular against degradation by UV light, for polyphenylene ethers. They have the advantage that they do not impair, or impair only to an insignificant degree, the dimensional stability under heat of these polymers.Type: GrantFiled: June 28, 1988Date of Patent: April 2, 1991Assignee: Ciba-Geigy CorporationInventors: Francis Mutterer, Kurt Berger
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Patent number: 5001171Abstract: It now has been found that uncured modified rubber compositions comprising mixtures of elastomers and a reinforcing filler can be prepared having improved properties.Type: GrantFiled: October 21, 1988Date of Patent: March 19, 1991Assignee: Bridgestone/Firestone, Inc.Inventors: Georg G. Bohm, Daniel F. Graves
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Patent number: 4965302Abstract: Disclosed herein is a thermoplastic polyester molded article comprising a thermoplastic polyester and at least one of the specified diimide compounds, the latter being blended in an amount effective for ultraviolet screening. The polyester molded article and a composition for producing it according to this invention is capable of screening ultraviolet rays not only in the short wavelength region but also in the long wavelength region and has uniform dispersion stability and thermal stability. The molded articles of the present invention are free of undesired coloration and deposition of extraneous matter.Type: GrantFiled: March 23, 1989Date of Patent: October 23, 1990Assignee: Mitsubishi Kasei CorporationInventors: Takuji Hirahara, Takashi Nakamura, Yoshiko Kumeno, Takayuki Ohta, Tetsuo Kasai
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Patent number: 4962156Abstract: Disclosed is A water- and oil-repellent composition comprising (A) at least one species selected from the group consisting of a homopolymer and a copolymer of perfluoroalkyl group-containing acrylate, a homopolymer and a copolymer of methacrylate, a copolymer of the same and a monomer copolymerizable therewith and a perfluoroalkyl group-containing urethane compound, and (B) a ladder polymer of organosilsesquioxane.Type: GrantFiled: August 15, 1989Date of Patent: October 9, 1990Assignee: Daikin Industries, Ltd.Inventors: Masayoshi Shinjo, Sumiko Okamoto, Yasuko Katakura, Seiji Takubo
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Patent number: 4954542Abstract: Tetrahalophthalate esters are disclosed herein as flame retardant processing aids for polybutylene terephthalate (PBT) resins.Type: GrantFiled: March 25, 1988Date of Patent: September 4, 1990Assignee: Pennwalt CorporationInventors: Joseph M. Bohen, Ronald F. Lovenguth
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Patent number: 4948669Abstract: Wire insulation and cable jacketing compositions comprise blends of ethylene copolymers and propylene polymers.Type: GrantFiled: January 25, 1989Date of Patent: August 14, 1990Assignee: E. I. du Pont de Nemours and CompanyInventor: Loic P. Rolland
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Patent number: 4940802Abstract: A 4,4'-bis(phthalimido)diphenyl sulfone compound having the formula: ##STR1## wherein X is a halogen atom, k=0 to 4, l=0 to 4, m=0 to 4 and n=0 to 4, provided k+l+m+n>1.Type: GrantFiled: December 8, 1988Date of Patent: July 10, 1990Assignee: Tosoh CorporationInventors: Takao Matsuba, Masashige Kubo, Takumi Kagawa, Kiyotaka Oyama, Koji Kawabata