Five-membered Nitrogen Containing Ring Patents (Class 524/94)
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Patent number: 6372828Abstract: Flame retardant compositions useful as insulation for 150° C.-rated wire and cable applications are provided. The compositions of the invention utilize an ethylene-alkyl acrylate copolymer base resin with a two-component stabilizer package consisting of a zinc salt of a mercaptobenzimidazole and an aromatic secondary amine compound. Also, included to achieve the requisite flame retardance, crosslinkability and physical properties are a brominated flame retardant, antimony trioxide, a hydrated inorganic filler and a chemical crosslinking agent.Type: GrantFiled: November 8, 1999Date of Patent: April 16, 2002Assignee: Equistar Chemicals, LPInventor: Lester Y. Lee
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Patent number: 6368724Abstract: A copolyester blend resistant to ultraviolet radiation includes a polyethylene terephthalate based copolyester having 1,4-cyclohexanedimethanol; an effective amount of an ultraviolet radiation absorber selected from the group consisting of benzoxazinones, dimeric benzotriazoles, triazines and mixtures thereof; and from 5 mol % to about 40 mol % isophthalic acid residues present in the copolyester wherein the mole percent is based on 100 mole percent of dicarboxylic acid or equivalents. The copolyester blend is useful in making UV radiation resistant thermoformed articles.Type: GrantFiled: December 13, 1999Date of Patent: April 9, 2002Assignee: Eastman Chemical CompanyInventor: David Richard Fagerburg
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Patent number: 6365652Abstract: This invention relates generally to amido or carbamate substituted trisaryl-1,3,5-triazines and the use thereof to protect against degradation by environmental forces, inclusive of ultraviolet light, actinic radiation, oxidation, moisture, atmospheric pollutants and combinations thereof. The new class of trisaryl-1,3,5-triazines comprises an aryl ring attached to the triazine ring (and preferably an aryl ring containing a hydroxyl group, either free or blocked to form a latent stabilizer, ortho- to the point of attachment to the triazine ring) substituted with a group comprising a bondable amido/carbamate containing group para- to the point of attachment to the triazine ring. These materials may, under the appropriate circumstances, be bonded to formulations comprising coatings, polymers, resins, organic compounds and the like via reaction of the bondable functionality with the materials of the formulation.Type: GrantFiled: May 3, 2001Date of Patent: April 2, 2002Assignee: Ciba Specialty Chemicals CorporationInventors: Ram Baboo Gupta, Dennis John Jakiela, Thomas P. Sassi, Gottfried Haacke
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Patent number: 6355708Abstract: The present invention relates to novel bondable trisaryl-1,3,5-triazines containing active (acidic) hydrocarbons and the use thereof as an ultraviolet light absorber. The presently claimed compounds are particularly useful, either alone or in combination with other additives, including other ultraviolet light absorbers and stabilizers, in stabilizing polymers and other materials from degradation by environmental forces such as actinic radiation (ultraviolet light), oxidation, moisture, atmospheric pollutants and combinations thereof.Type: GrantFiled: April 11, 2001Date of Patent: March 12, 2002Assignee: Ciba Specialty Chemicals CorporationInventors: Ram Baboo Gupta, Dennis John Jakiela, Gottfried Haacke
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Publication number: 20020028861Abstract: The contents of clear or lightly colored plastic containers or films are protected from ultraviolet radiation by the incorporation of certain UV absorbers of the class of durable benzotriazoles and tris-aryl-s-triazines in the container or film. Contents to be protected include foodstuffs, beverages, pharmaceuticals, cosmetics, personal care products, shampoos and the like.Type: ApplicationFiled: January 29, 2001Publication date: March 7, 2002Inventors: Stephen Mark Andrews, Joseph Suhadolnik, Mervin Gale Wood
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Patent number: 6344506Abstract: The invention concerns a white, light-colored tire rubber composition, devoid of carbon black, comprising at least a diene elastomer, a reinforcing white or colored filler, and an anti-photo-oxidizing system, wherein said protective system comprises (A) a 2,2′-methylene-bis-[4-alkyl (C1-C10)-6-alkyl(C1-C12)phenol]; (B) a dialkylthiodipropionate, the alkyl radicals thereof, which may be identical or different, are (C1-C20), radicals; (C) a 2-(2-hydroxyphenyl) benzotriazole; and (D) a “HALS” amine derived from 2,2,6,6-tetramethylpiperidine.Type: GrantFiled: January 6, 2000Date of Patent: February 5, 2002Assignee: Compagnie Generale des Etablissements Michelin-Michelin & CieInventor: Didier Vasseur
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Publication number: 20020006992Abstract: The present invention relates to a synergistic additives mixture for producing calendered polyolefin articles, comprisingType: ApplicationFiled: February 3, 1999Publication date: January 17, 2002Inventors: CHRISTIAN WICK, GERHARD PFAHLER, ALEXANDER LICHTBLAU
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Patent number: 6339117Abstract: The present invention relates to polymers whitened with optical brighteners obtained by (a) emulsion polymerization of acrylonitrile with or without a comonomer in the presence or absence of a graftable substrate, and (b) addition of an optical brightener before, during, or after the emulsion polymerization.Type: GrantFiled: February 28, 2000Date of Patent: January 15, 2002Assignee: Bayer AktiengesellschaftInventors: Udo Eckstein, Siegfried Korte, Ulrich Feldhues, Hans-Peter Geiger, Bernhard Hunke, Thomas Roick, Günter Sackmann
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Publication number: 20020002221Abstract: Flame retardant compositions useful as insulation for 150° C.-rated wire and cable applications are provided. The compositions of the invention utilize an ethylene-alkyl acrylate copolymer base resin with a two-component stabilizer package consisting of a zinc salt of a mercaptobenzimidazole and an aromatic secondary amine compound. Also, included to achieve the requisite flame retardance, crosslinkability and physical properties are a brominated flame retardant, antimony trioxide, a hydrated inorganic filler and a chemical crosslinking agent.Type: ApplicationFiled: November 8, 1999Publication date: January 3, 2002Inventor: LESTER Y. LEE
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Patent number: 6312822Abstract: A thermoplastic polyolefin composition suitable for use as a coating for a photographic support includes an optical brightener and a polar additive. The polar additive substantially compatibilizes the polar optical brightener with the non-polar polyolefin. A method for adding a polar additive to a polyolefin is also disclosed.Type: GrantFiled: November 25, 1998Date of Patent: November 6, 2001Inventors: Gether Irick, Jr., Joe L. Farrar
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Patent number: 6297314Abstract: The invention relates to a coating agent containing a) one or more polyester resins (A); b) one or more polyacrylate resins (B); c) one or more di- and/or polyisocyanates (C) with free or blocked isocyanate groups; d) one or more light stabilizers (L1) based on a UV absorber; e) one or more light stabilizers (L2) based on sterically hindered amines; and f) one or more organic solvents (D). The coating agent is characterized in that 1) the polyester (A) has a hydroxyl number of 80-200 mg KOH/g and an acid number <10mg KOH/g; 2) the polyacrylate resin (B) has a hydroxyl number of 80-200 mg KOH/g and an acid number <20 mg KOH/g; and 3) the light stabilizer (L2) based on sterically hindered amines is functionalized by aminoether.Type: GrantFiled: January 12, 2000Date of Patent: October 2, 2001Assignee: BASF Coatings AGInventors: Horst Hintze-Brüning, Patrick Van Ende
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Publication number: 20010025069Abstract: Provided are polypropylene-based films and sheets having good ultraviolet shieldability. While being stored, the films and the sheets are free from additive bleeding, and their outward appearance is kept all the time good. The films and the sheets are formed from a composition comprising 100 parts by weight of a polypropylene-based resin and from 0.Type: ApplicationFiled: April 24, 2001Publication date: September 27, 2001Applicant: IDEMITSU PETROCHEMICAL CO., LTD.Inventors: Hiroshi Itagaki, Satoshi Tamura, Kouji Satou
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Patent number: 6291586Abstract: An ultraviolet light absorbing material that resists blooming and migration is made up of a polyurethane or polyurea polymer and an amide functional ultraviolet light absorbing compound, wherein the polymer and the amide functional ultraviolet light absorbing compound are hydrogen bonded to one another. Polymeric films that contain a polymeric matrix and the ultraviolet light absorbing material are useful as the top layer in multilayer constructions such as retroreflective sheetings and conformable marking sheets.Type: GrantFiled: October 31, 1997Date of Patent: September 18, 2001Assignee: 3M Innovative Properties CompanyInventors: James E. Lasch, David B. Olson, David M. Burns
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Patent number: 6277905Abstract: This invention relates to a process for improving the toughness of a polymer composition comprising blending: (A) a polyester comprising: (1) terephthalic acid in the amount of 85 to 100 mole % based on the mole percentages of the dicarboxylic acid component equaling a total of 100 mole %. (2) a glycol component comprising from about 60 to 100 mole % 1,4-cyclohexanedimethanol based on the total percentages of the glycol component equaling a total of 100 mole %; (B) one or more rubber impact modifiers; (C) one or more halogenated organic compounds containing at least one imide group having a melting point of greater than 240° C.; and (D) reinforcing fiber.Type: GrantFiled: November 30, 1999Date of Patent: August 21, 2001Assignee: Eastman Chemical CompanyInventor: Gerald Timothy Keep
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Patent number: 6262151Abstract: Benzotriazole UV absorbers which are substituted at the 5-position of the benzo ring by an electron withdrawing group exhibit enhanced durability and very low loss rates when incorporated into automotive coatings. This is particularly the case when the 3-position of the phenyl ring is also substituted by phenyl or phenylalkyl such as &agr;-cumyl. Compounds where the 5-position of the benzo ring are substituted by perfluoroalkyl such as trifluoromethyl are particularly of interest for both their enhanced durability and for their excellent solubility and excellent color properties in some thermoplastic compositions when the phenyl ring is substituted at the 3-position by hydrogen or tert-alkyl.Type: GrantFiled: July 12, 2000Date of Patent: July 17, 2001Assignee: Ciba Specialty Chemicals CorporationInventors: Ramanathan Ravichandran, Joseph Suhadolnik, Mervin G. Wood, Anthony Debellis, Robert E. Detlefsen, Revathi Iyengar, Jean-Pierre Wolf
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Publication number: 20010007885Abstract: An ultraviolet light absorbing material that resists blooming and migration is made up of a polyurethane or polyurea polymer and an amide functional ultraviolet light absorbing compound, wherein the polymer and the amide functional ultraviolet light absorbing compound are hydrogen bonded to one another. Polymeric films that contain a polymeric matrix and the ultraviolet light absorbing material are useful as the top layer in multilayer constructions such as retroreflective sheetings and conformable marking sheets.Type: ApplicationFiled: October 31, 1997Publication date: July 12, 2001Inventors: JAMES E. LASCH, DAVID B. OLSON, DAVID M. BURNS
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Patent number: 6245840Abstract: Provided are polypropylene-based films and sheets having good ultraviolet shieldability. While being stored, the films and the sheets are free from additive bleeding, and their outward appearance is kept all the time good. The films and the sheets are formed from a compositions comprising 100 parts by weight of a polypropylene-based resin and from 0.01 to 5 parts by weight of one or more compounds selected from the following (A) to (D): (A) 2-(2-hydroxy-5-t-octylphenyl)benzotriazole, (B) 2-(2H-benzotriazol-2-yl)-6-dodecyl-4-methylphenol, (C) specific triazine compounds, and (D) specific methylene-bisphenols.Type: GrantFiled: February 16, 1999Date of Patent: June 12, 2001Assignee: Idemitsu Petrochemical Co. Ltd.Inventors: Hiroshi Itagaki, Satoshi Tamura, Kouji Satou
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Publication number: 20010003030Abstract: The present invention provides an over-coating composition comprising a basic compound for coating a photoresist composition to provide a vertical photoresist pattern.Type: ApplicationFiled: December 1, 2000Publication date: June 7, 2001Inventors: Jae Chang Jung, Keun Kyu Kong, Cha Won Koh, Jin Soo Kim, Ki Ho Baik
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Patent number: 6218450Abstract: A copolyester blend resistant to ultraviolet radiation includes a polyethylene terephthalate based copolyester having 1,4-cyclohexanedimethanol residues; an effective amount of an ultraviolet radiation absorber selected from the group consisting of benzoxazinones, dimeric benzotriazoles, triazines and mixtures thereof; from about 5 mol % to about 40 mol % isophthalic acid residues in the copolyester, and from 5 mol % to 20 mol % 4,4′-biphenyldicarboxylic acid residues present in the copolyester, wherein the mole percent of the diacid is based on 100 mole percent of dicarboxylic acid or equivalents. The copolyester blend is useful in making UV radiation resistant thermoformed articles.Type: GrantFiled: December 13, 1999Date of Patent: April 17, 2001Assignee: Eastman Chemical CompanyInventor: David Richard Fagerburg
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Patent number: 6194330Abstract: A process for the production of an ultra violet absorbing polymer latex is provided. The inventive process involves the emulsion polymerization of a benzotriazole- or benzophenone-containing monomer with a vinyl functional monomer in the presence of a chain transfer agent, preferably 1-dodecanethiol. The latex provides excellent long-lasting, easy to apply, difficult to remove, ultraviolet absorption properties for many different substrates, most notably fabrics. Different articles and fabrics coated, covered, laminated, and the like, with the inventive latex are also provided.Type: GrantFiled: July 31, 1998Date of Patent: February 27, 2001Assignee: Milliken & CompanyInventors: Kirkland W. Vogt, Shulong Li
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Patent number: 6187859Abstract: An improved light stable polyether/polyol based aliphatic urethane thermoplastic elastomer prepared from reacting inter alia a polyol having low terminal end unsaturation and an organic diisocyanate. The elastomer is characterized by ultra violet stabilizer being present in a range of 0.25% to 2.0% at a total concentration of 1.0% to 2.0%, an antioxidant being present at a total concentration of 0.10% to 1.0%, and colorants/pigment being present in a total concentration in a range from 1.0% to 2.05% to produce an elastomer capable of withstanding Xenon arc artificial weathering with DE≦3.00 after 2450 kilojoules of exposure.Type: GrantFiled: October 19, 1998Date of Patent: February 13, 2001Assignee: Davidson Textron Inc.Inventors: William M. Humphrey, Victor E. Gerard
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Patent number: 6180698Abstract: A liquid chemical formulation suitable for making a thin solid polycarbonate film of highly uniform thickness is formed with polycarbonate material, a liquid that dissolves the polycarbonate, and possibly one or more other constituents. The liquid is typically capable of dissolving the polycarbonate to a concentration of at least 1% at 20° C. and 1 atmosphere. The liquid also typically has a boiling point of at least 80° C. at 1 atmosphere. Examples of the liquid include pyridine, a ring-substituted pyridine derivative, pyrrole, a ring-substituted pyrrole derivative, pyrrolidine, a pyrrolidine derivative, and cyclohexanone. In forming the polycarbonate-containing film, a liquid film (36A) of the liquid chemical formulation is formed over a substructure (30). The liquid film is processed to largely remove the liquid and convert the polycarbonate into a solid film (38).Type: GrantFiled: February 28, 1997Date of Patent: January 30, 2001Assignees: Candescent Technologies Corporation, Hewlett-Packard CompanyInventors: John D. Porter, Scott J. Crane, Stephanie J. Oberg, Anthony W. Johnson
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Patent number: 6166129Abstract: The present invention relates to a novel photochromic polyurethane consisting essentially of an isocyanate reactive mixture consisting essentially of: i) from about 40 to about 85% by weight of one or more polyols having a nominal functionality of from 2 to 4 and molecular weights of from 500 to 6000 g/mole; ii) from about 15 to about 60% by weight of one or more diols or triols or mixtures thereof having a functionality of from 2 to 3 and molecular weights of from 62 to 499; b) an aliphatic polyisocyanate having a functionality ranging from about 2 to about 3; and c) a photochromic compound selected from a group consisting of spirooxazines, fulgides, fulgimides, and naphthopyrans, wherein the photochromic compound is present in an amount of 0.01 to 5 parts per hundred parts by weight of the isocyanate reactive mixture.Type: GrantFiled: October 1, 1999Date of Patent: December 26, 2000Assignee: Bayer CorporationInventors: James W. Rosthauser, Karl W. Haider, Sivaram Krishnan, James N. Rieck
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Patent number: 6150440Abstract: An ultraviolet light absorbing material that resists blooming and migration is made up of a carboxyl functional polymer and an amide functional ultraviolet light absorbing compound, wherein the carboxyl functional polymer and the amide functional ultraviolet light absorbing compound are hydrogen bonded to one another. Polymeric films that contain a polyolefin and the ultraviolet light absorbing material are useful as the top layer in multilayer constructions such as retroreflective sheetings and conformable marking sheets.Type: GrantFiled: September 4, 1998Date of Patent: November 21, 2000Assignee: 3M Innovative Properties CompanyInventors: David B. Olson, David M. Burns
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Patent number: 6114419Abstract: Fluorinated imides useful for imparting repellency of low surface tension fluids to thermoplastic polymers of formulae ##STR1## wherein R.sub.1 is F(CF.sub.2).sub.x --(CH.sub.2).sub.m, or F(CF.sub.2).sub.x SO.sub.2 N(R.sub.5) (CH.sub.2)p wherein x is from about 4 to about 20, m is from about 2 to about 6, p is from 1 to about 12, and R.sub.5 is an alkyl radical of from 1 to about 4 carbons;R.sub.2 is a linear, branched or cyclic alkylene or poly(oxyalkylene) hydrocarbon group having from about 2 to about 15 carbons;R.sub.3 is selected from the group consisting of F(CF.sub.2).sub.x --(CH.sub.2).sub.m, F(CF.sub.2).sub.x --(CH.sub.2).sub.m --OC(O)--(CH.sub.2).sub.n, and F(CF.sub.2).sub.x SO.sub.2 N(R.sub.5)(CH.sub.2).sub.p OC(O)(CH.sub.2).sub.n wherein x is from about 4 to about 20, m is from about 2 to about 6, n is about 2 to about 12, p is from 1 to about 12, and R.sub.5 is an alkyl radical of from 1 to about 4 carbons;R.sub.4 is an alkyl or alkenyl group of from about 4 to about 20 carbons, andR.sub.Type: GrantFiled: April 7, 1998Date of Patent: September 5, 2000Assignee: E. I. du Pont de Nemours and CompanyInventors: Theodor Arthur Liss, Kimberly Gheysen Raiford, Edward James Greenwood
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Patent number: 6066687Abstract: An acrylic fiber exhibiting improved brightness and proccessability is disclosed. The fiber includes a synergistic combination of a delustrant and an optical brightener and is specifically useful in the manufacture of "terry" knitted athletic socks.Type: GrantFiled: June 24, 1994Date of Patent: May 23, 2000Assignee: Solutia Inc.Inventors: Gary Joseph Capone, Henry Gook Chin
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Patent number: 6040356Abstract: This invention relates to a durable gravure ink composed of a pigment with high weather resistance, a pigment with high alkali resistance, and a binder with high weather resistance and high alkali resistance, and a technique for producing a decorative material using this ink. According to this invention, a decorative material having a pattern layer excellent in both of weather resistance and alkali resistance is provided.Type: GrantFiled: May 11, 1998Date of Patent: March 21, 2000Assignee: Dai Nippon Printing Co., Ltd.Inventors: Masahiro Kanki, Mutsuhiro Kawano, Takashi Matano
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Patent number: 6040366Abstract: The compression set of elastomeric silicone compositions, addition cured injection moldable compositions, is reduced by the incorporation of nitrogen compounds wherein the nitrogen possesses at least one organic substituent and the nitrogen is tetravalent wherein the nitrogen is cationic. The adhesion of such compositions to thermoset or thermoplastic polymer substrates is improved by the addition of bis(trimethoxysilylpropyl)fumarate and a disilanol that may or may not contain alkenyl groups. The lubricity of such compositions is improved by the addition of compounds selected from the group consisting of diorganosiloxanes such as polydimethylsiloxanes, phenyl containing siloxanes such as copolymers of diphenylsiloxane with diorganosiloxanes and copolymers of methylphenylsiloxane with diorganosiloxanes, fluorosilicones such as silicones containing trifluoropropyl substituted siloxanes, polydimethylsiloxanes, aliphatic and aromatic hydrocarbons that are liquid between 0.degree. C. and 100.degree. C.Type: GrantFiled: February 27, 1998Date of Patent: March 21, 2000Assignee: General Electric CompanyInventors: Frank S. Burkus, II, Edward M. Jeram, Slawomir Rubinsztajn
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Patent number: 6025433Abstract: To offer thermosetting paint compositions resistant to yellowing to brass, which give paint films of excellent resistance to yellowing due to brass, low-temperature curability, weather resistance, resistance to yellowing after stoving, acid resistance, scratch resistance, solvent resistance, adhesion and appearance. Thermosetting paint compositions, which are thermosetting paint compositions which are resistant to yellowing due to brass, characterized in that the paint-film-forming components include (A) a compound which has per molecule at least 2 functional groups which can react with an isocyanate group, at 49.6-90 wt %, (B) a blocked isocyanate which has par molecule at least 2 isocyanate groups blocked by an azole blocking agent, at 9.6-50 wt %, (C) an ultraviolet absorber and/or free radical scavenger, at 0.2-5 wt %, (D) an organotin compound at 0.1-3 wt %, and (E) an amino resin at 0.1-30 wt %.Type: GrantFiled: July 21, 1998Date of Patent: February 15, 2000Assignee: BASF Coatings AGInventors: Kishio Shibatoh, Souichi Mori, Yasuhiro Monma
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Patent number: 5998520Abstract: A thermoplastic molding composition is disclosed comprising (A) at least one resinous component selected from the group consisting of (i) a homogeneous blend of polycarbonate resin and polycaprolactone and (ii) a copoly(carbonate-lactone) copolymer, and (B) at least one compound selected from a group consisting of benzopyrans, naphthopyrans, spirobenzopyrans, spironaphthopyrans, spirobenzoxazines, spironaphthoxazines, fulgides and fulgimides. The composition which contains the photochromic compound at an amount of 0.01 to 1.0 parts per hundred parts of weight of said (A) exhibits good photochromic properties.Type: GrantFiled: July 2, 1997Date of Patent: December 7, 1999Assignee: Bayer CorporationInventors: Sivaram Krishnan, Robert A. Pyles, James B. Johnson, Michael P. Jenkins, Timothy J. Pike
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Patent number: 5977220Abstract: A process to reduce the compression set of elastomeric silicone compositions, addition cured injection moldable compositions or millable compositions, comprises the incorporation of nitrogen compounds wherein the nitrogen possesses at least one organic substituent and the nitrogen is tetravalent wherein the nitrogen is cationic.Type: GrantFiled: December 29, 1997Date of Patent: November 2, 1999Assignee: General Electric CompanyInventors: Frank S. Burkus, II, Edward M. Jeram, Slawomir Rubinsztajn
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Patent number: 5972248Abstract: The present invention relates to novel stabilizers of the formula (I) ##STR1## in which the substituents have the meaning defined in the description. These novel stabilizers are particularly suitable for stabilizing organic material, such as plastics, oils, paints and coatings, against degradation by light, radiation, heat and oxygen.Type: GrantFiled: October 7, 1997Date of Patent: October 26, 1999Assignee: Clariant GmbHInventors: Thomas Stahrfeldt, Josef Wiedemann, Matthias Zah
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Patent number: 5973126Abstract: A monoazo compound synthesized using 2-hydroxynaphthalene-3,6-dicarboxylic acid (or salt thereof), an amide, an ureide or an ester thereof as a coupler is novel, and is superior in water resistance, chemical resistance and solvent resistance. The present invention provides such a novel azo compound and a process for producing the same.Type: GrantFiled: May 20, 1998Date of Patent: October 26, 1999Assignee: Kabushiki Kaisha Ueno Seiyaku Oyo KenkyujoInventors: Ryuzo Ueno, Masaya Kitayama, Kenji Minami, Hiroyuki Wakamori
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Patent number: 5942571Abstract: A liquid silicone rubber composition for use in high-voltage eletrical insulating parts comprising (A) a polyorganosiloxane containing alkenyl groups, (B) fumed silica, (C) a polyorganohydridosiloxane, (D) a platinum type catalyst, (E) finely powdered aluminum hydroxide, and (F) a powdered metal compound selected from the group consisting of powdered zinc oxidc, powdered zinc borate, and powdered magnesium hydroxide and a method for manufacturing such a composition.Type: GrantFiled: January 28, 1998Date of Patent: August 24, 1999Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Akito Nakamura, Yasumichi Shigehisa, Yuichi Tsuji
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Patent number: 5939493Abstract: A rubber composition comprising 100 parts by weight of a rubber component which comprises at least one type of rubber selected from the group consisting of natural rubber and diene synthetic rubbers, 0.1 to 10 parts by weight of at least one type of metal dithiophosphate represented by the following general formula, optionally 15 to 85 parts by weight of a reinforcing inorganic filler, and optionally a specific tertiary amine compound in an amount of 0.5 to 15% by weight of the amount of the reinforcing inorganic filler is provided.General formula ##STR1## wherein R.sup.1 and R.sup.3 each independently represents an alkyl group or a cycloalkyl group, M represents an antimony atom, a zinc atom, a copper atom, or an iron atom, and n represents a valency of M.The rubber composition of the present invention exhibits excellent resistance to heat or resistance to heat aging (particularly excellent resistance to hardening and excellent fracture properties).Type: GrantFiled: December 24, 1997Date of Patent: August 17, 1999Assignee: Bridgestone CorporationInventor: Masahiro Hojo
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Patent number: 5936054Abstract: An addition-crosslinkable silicone rubber composition comprising the constituents(I) an alkenyl-functional polyorganosiloxane(II) a SiH-functional crosslinker(III) a hydrosilylation catalyst and(IV) at least one 1H-benzotriazole-5-carboxylic acid derivative selected from a group consisting of 1H-benzotriazole-5-carboxylic acid esters and 1H-benzotriazole-5-carboxylic acid amides.Type: GrantFiled: June 10, 1997Date of Patent: August 10, 1999Assignee: Wacker-Chemie GmbHInventors: Frank Achenbach, Christof Worner, Brigitte Ostermeier, Georg Eberl, Jelica Gegic
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Patent number: 5936016Abstract: The present invention relates to photochromic compounds of spiro?indoline?2,3'!-naphthoxazine! structure, characterized in that they contain, in the 6' position, a group R.sub.6 chosen from the following groups: cyano and phenylsulfonyl linked via the sulfur atom to carbon 6', and methods of using such compounds.Type: GrantFiled: January 29, 1997Date of Patent: August 10, 1999Assignee: Essilor International Compagnie Generale D'OptiqueInventors: Pierre Lareginie, Vladimir Lokshin, Andre Samat, Robert Guglielmetti, Elena Zaballos Garcia
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Patent number: 5925150Abstract: A black colorant composition useful for coloring polyurethanes is provided having a red benzothiazole azo colorant which, when combined with a complementary blue and yellow colorant, exhibits low flairing.Type: GrantFiled: August 20, 1997Date of Patent: July 20, 1999Assignee: Milliken & CompanyInventors: Mark Edward Ragsdale, David Jesse Moody, Eric B. Stephens
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Patent number: 5919847Abstract: A composition comprising a blend of a thermoplastic resin and at least one compound or oligomer which is ##STR1## wherein R.sub.f is a perfluorinated moiety which may contain one or more catenary ether oxygen atoms, Q is a linking group selected from alkylene groups having 1 or 2 carbon atoms, sulfonamido groups or combinations thereof, R is an alkyl group, R.sup.1 is a perfluoroalkyl group, R.sup.2 is an alkyl group which may be straight chain or branched and n is a number of from 2 to 40.Type: GrantFiled: December 2, 1997Date of Patent: July 6, 1999Assignee: Minnesota Mining and Manufacturing CompanyInventors: Alan D. Rousseau, Marvin E. Jones, Seyed A. Angadjivand
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Patent number: 5916937Abstract: A heat cured fluorosilicone rubber exhibiting improved compression set comprises N,N'-meta-phenylenedimaleimide.Type: GrantFiled: September 30, 1997Date of Patent: June 29, 1999Assignee: General Electric CompanyInventor: Edwin R. Evans
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Patent number: 5912287Abstract: A silicone rubber composition comprising(A) polyorganosiloxane described by average formula R.sub.a SiO.sub.(4-a)/2, where R denotes substituted and unsubstituted monovalent hydrocarbon groups and a is a number from 1.95 to 2.05 and having at least 2 silicon-bonded alkenyl groups in each molecule;(B) microparticulate silica;(C) the reaction mixture of(a) a platinum compound and(b) an organosilicon compound described by general formula ##STR1## where R.sup.1, R.sup.2, and R.sup.3 represent C.sub.1 to C.sub.10 monovalent hydrocarbon groups and a is 1, 2, or 3;(D) curing agent, and optionally(E) triazole compound.Type: GrantFiled: July 17, 1997Date of Patent: June 15, 1999Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Takao Matsushita, Osamu Takuman
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Patent number: 5883163Abstract: A light conducting plate for back lighting which comprises a methacrylic copolymer resin comprising 90 to 99.5% by weight of a methyl methacrylate unit and 0.5 to 10% by weight of an alkyl acrylate unit containing 1 to 8 carbon atoms in the alkyl moiety thereof and having a reduced viscosity of 35 to 60 ml/g in chloroform, the chromaticity of said light conducting plate having x and y color coordinates both ranging from 0.01 to 0.001 as obtained according to JIS-Z-8701.Type: GrantFiled: August 19, 1997Date of Patent: March 16, 1999Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventor: Nobuyuki Hosonuma
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Patent number: 5880199Abstract: A liquid silicone rubber composition that prior to its cure has a suitable fluidity and excellent moldability and that cures into a highly flame retardant silicone rubber molding with excellent electrical properties. The liquid silicone rubber composition comprises(A) polyorganosiloxane,(B) microparticulate silica,(C) aluminum hydroxide powder,(D) zinc carbonate powder,(E) polyorganohydrogensiloxane,(F) benzotriazole,(G) the reaction mixture of(a) a platinum compound and(b) 3,5-dimethyl-1-hexyn-3-ol, and(H) hydrosilylation reaction catalyst.Type: GrantFiled: May 22, 1997Date of Patent: March 9, 1999Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Takao Matsushita, Yasumichi Shigehisa, Yuichi Tsuji
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Patent number: 5863599Abstract: The present invention provides a film for application to a surface of a material capable of transmitting heat and/or light. The film comprises: a solvent comprising at least one volatile organic compound in an amount sufficient to maintain flowability of the film after exposure to air and for a time sufficient to apply the film to the surface, whereupon the solvent evaporates and dries the film; a polymer in an amount sufficient to reversibly bind the film to the surface; and, an ultraviolet absorbent material in an amount sufficient to reduce transmission of said energy through said material. The film may be applied and removed upon demand by the user.Type: GrantFiled: January 8, 1997Date of Patent: January 26, 1999Inventor: Chel Wing Lew
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Patent number: 5837757Abstract: Disclosed are non-bromine, flame-retardant polycarbonate resin compositions having increased reflectance and improved light shieldability, light fastness and moldability while still having good mechanical properties such as flame retardancy and impact resistance, and light reflectors as produced by molding the compositions. One type of the composition comprises (A) a polycarbonate resin and (B) a titanium oxide powder in a ratio by weight of from 70/30 to 90/10, and contains (C) a stilbene-bisbenzoxazole derivative in an amount of from 1 to 1000 ppm by weight and optionally (D) a non-halogen phosphate compound in an amount of from 0.05 to 1.00% by weight in term of phosphorus element, relative to the total weight of the component (A) and the component (B). The other type of the composition comprises (A) from 99.9 to 70% by weight of a polycarbonate resin and (B) from 0.1 to 30% by weight of a titanium oxide powder, and contains (D) a non-halogen phosphate compound in an amount of from 0.05 to 1.Type: GrantFiled: June 3, 1997Date of Patent: November 17, 1998Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Akio Nodera, Hiroshi Itagaki
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Patent number: 5789470Abstract: The invention relates to stabilized recycled plastics, which can be obtained from domestic, commercial and industrial waste or valuable material collections, comprising a macrocyclic compounds containing a radical of formula (I) or (II), in the macrocycle or in a side group of the macrocycle, where the macrocycle comprises at least 8 atoms and in which the substituents R, independently of one another, are methyl, ethyl or propyl, or two radicals R on the same carbon atom are, together, a pentamethylene radical, and a is the number 0, 1 or 2. The invention also relates to a process for the stabilization of recycled plastics and to the use of the above macrocyclic compounds as stabilizer.Type: GrantFiled: March 20, 1997Date of Patent: August 4, 1998Assignee: Ciba Specialty Chemicals CorporationInventors: Heinz Herbst, Kurt Hoffmann, Franca Masina, Rudolf Pfaendner, Franciszek Sitek
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Patent number: 5756256Abstract: A planarizing technique comprising: coating a topography overlying a substrate with a planarizing resist layer; softbaking the planarizing resist layer in the presence of a silicon-containing vapor or liquid; coating the planarizing resist layer with an imaging resist layer; softbaking the imaging resist; selectively exposing the imaging resist layer to light; developing the imaging resist layer; and etching the planarizing layer. The planarizing layer may comprise novolacs and other organic polymers used conventionally in lithographic processes. The planarizing layer may further comprise any organic acid moiety that is compatible with the solvent used to dissolve the resin. In particular, the acid moiety is indole-3-carboxylic acid. In another aspect, the invention comprises a silylated planarizing resist.Type: GrantFiled: January 16, 1997Date of Patent: May 26, 1998Assignees: Sharp Microelectronics Technology, Inc., Sharp Kabushiki KaishaInventors: Tatsuo Nakato, David A. Vidusek
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Patent number: 5744615Abstract: Disclosed is a process for producing an ultra-white N,N'-ethylene-bis(tetrabromophthalimide) product useful as a flame retardant. Also disclosed is a flame retardant composition predominantly comprised of N,N'-ethylene-bis(tetrabromophthalimide) and having unprecedented color and high purity.Type: GrantFiled: January 19, 1996Date of Patent: April 28, 1998Assignee: Great Lakes ChemicalInventors: Brian Tarbit, Brian Adger, Paul Willett
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Patent number: 5741837Abstract: A syndiotactic polystyrene composition is improved which exhibits improved crystallization rate. The improved syndiotactic polystyrene composition contains (a) a syndiotactic polystyrene; and (b) a nucleating agent which is selected from the group consisting of two types of compounds represented by the following formulas, respectively: ##STR1## In Formulas I and II, the radicals R.sub.1 and R.sub.2, which can be the same of different, are C.sub.1 to C.sub.5 alkyl groups, X is a halogen group, preferably a bromide group, and n is an integer from 1 to 5. In the present invention, the nucleating agent is provided at 0.01 to 5 part, by weight, per 100 parts, also by weight, of the syndiotactic polystyrene resin. An example of Formula I compound is 2-hydroxybenimidiazole, and an example of the Formula II compound is bis(phenylbromide) methane.Type: GrantFiled: March 27, 1997Date of Patent: April 21, 1998Assignee: Industrial Technology Research InstituteInventors: Chung-Jen Wu, Chien-Ming Chen, Hsien-Ming Chen, Hurng-Rern Lee
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Patent number: 5723543Abstract: A thermoplastic elastomer composition is provided. The composition comprises a hydrogenated elastomeric block copolymer having at least two resinous endblocks of polymerized monovinyl aromatic compound and an elastomeric midblock of polymerized conjugated diene, a midblock plasticizer, and an ethylene-acrylate copolymer or terpolymer. The thermoplastic elastomer exhibits improved overmolding adhesion to polar matrices over compositions not containing the ethylene-acrylate polymer.Type: GrantFiled: September 26, 1996Date of Patent: March 3, 1998Assignee: Shell Oil CompanyInventor: Michael John Modic