Five-membered Nitrogen Containing Ring Patents (Class 524/94)
  • Patent number: 6372828
    Abstract: Flame retardant compositions useful as insulation for 150° C.-rated wire and cable applications are provided. The compositions of the invention utilize an ethylene-alkyl acrylate copolymer base resin with a two-component stabilizer package consisting of a zinc salt of a mercaptobenzimidazole and an aromatic secondary amine compound. Also, included to achieve the requisite flame retardance, crosslinkability and physical properties are a brominated flame retardant, antimony trioxide, a hydrated inorganic filler and a chemical crosslinking agent.
    Type: Grant
    Filed: November 8, 1999
    Date of Patent: April 16, 2002
    Assignee: Equistar Chemicals, LP
    Inventor: Lester Y. Lee
  • Patent number: 6368724
    Abstract: A copolyester blend resistant to ultraviolet radiation includes a polyethylene terephthalate based copolyester having 1,4-cyclohexanedimethanol; an effective amount of an ultraviolet radiation absorber selected from the group consisting of benzoxazinones, dimeric benzotriazoles, triazines and mixtures thereof; and from 5 mol % to about 40 mol % isophthalic acid residues present in the copolyester wherein the mole percent is based on 100 mole percent of dicarboxylic acid or equivalents. The copolyester blend is useful in making UV radiation resistant thermoformed articles.
    Type: Grant
    Filed: December 13, 1999
    Date of Patent: April 9, 2002
    Assignee: Eastman Chemical Company
    Inventor: David Richard Fagerburg
  • Patent number: 6365652
    Abstract: This invention relates generally to amido or carbamate substituted trisaryl-1,3,5-triazines and the use thereof to protect against degradation by environmental forces, inclusive of ultraviolet light, actinic radiation, oxidation, moisture, atmospheric pollutants and combinations thereof. The new class of trisaryl-1,3,5-triazines comprises an aryl ring attached to the triazine ring (and preferably an aryl ring containing a hydroxyl group, either free or blocked to form a latent stabilizer, ortho- to the point of attachment to the triazine ring) substituted with a group comprising a bondable amido/carbamate containing group para- to the point of attachment to the triazine ring. These materials may, under the appropriate circumstances, be bonded to formulations comprising coatings, polymers, resins, organic compounds and the like via reaction of the bondable functionality with the materials of the formulation.
    Type: Grant
    Filed: May 3, 2001
    Date of Patent: April 2, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Ram Baboo Gupta, Dennis John Jakiela, Thomas P. Sassi, Gottfried Haacke
  • Patent number: 6355708
    Abstract: The present invention relates to novel bondable trisaryl-1,3,5-triazines containing active (acidic) hydrocarbons and the use thereof as an ultraviolet light absorber. The presently claimed compounds are particularly useful, either alone or in combination with other additives, including other ultraviolet light absorbers and stabilizers, in stabilizing polymers and other materials from degradation by environmental forces such as actinic radiation (ultraviolet light), oxidation, moisture, atmospheric pollutants and combinations thereof.
    Type: Grant
    Filed: April 11, 2001
    Date of Patent: March 12, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Ram Baboo Gupta, Dennis John Jakiela, Gottfried Haacke
  • Publication number: 20020028861
    Abstract: The contents of clear or lightly colored plastic containers or films are protected from ultraviolet radiation by the incorporation of certain UV absorbers of the class of durable benzotriazoles and tris-aryl-s-triazines in the container or film. Contents to be protected include foodstuffs, beverages, pharmaceuticals, cosmetics, personal care products, shampoos and the like.
    Type: Application
    Filed: January 29, 2001
    Publication date: March 7, 2002
    Inventors: Stephen Mark Andrews, Joseph Suhadolnik, Mervin Gale Wood
  • Patent number: 6344506
    Abstract: The invention concerns a white, light-colored tire rubber composition, devoid of carbon black, comprising at least a diene elastomer, a reinforcing white or colored filler, and an anti-photo-oxidizing system, wherein said protective system comprises (A) a 2,2′-methylene-bis-[4-alkyl (C1-C10)-6-alkyl(C1-C12)phenol]; (B) a dialkylthiodipropionate, the alkyl radicals thereof, which may be identical or different, are (C1-C20), radicals; (C) a 2-(2-hydroxyphenyl) benzotriazole; and (D) a “HALS” amine derived from 2,2,6,6-tetramethylpiperidine.
    Type: Grant
    Filed: January 6, 2000
    Date of Patent: February 5, 2002
    Assignee: Compagnie Generale des Etablissements Michelin-Michelin & Cie
    Inventor: Didier Vasseur
  • Publication number: 20020006992
    Abstract: The present invention relates to a synergistic additives mixture for producing calendered polyolefin articles, comprising
    Type: Application
    Filed: February 3, 1999
    Publication date: January 17, 2002
    Inventors: CHRISTIAN WICK, GERHARD PFAHLER, ALEXANDER LICHTBLAU
  • Patent number: 6339117
    Abstract: The present invention relates to polymers whitened with optical brighteners obtained by (a) emulsion polymerization of acrylonitrile with or without a comonomer in the presence or absence of a graftable substrate, and (b) addition of an optical brightener before, during, or after the emulsion polymerization.
    Type: Grant
    Filed: February 28, 2000
    Date of Patent: January 15, 2002
    Assignee: Bayer Aktiengesellschaft
    Inventors: Udo Eckstein, Siegfried Korte, Ulrich Feldhues, Hans-Peter Geiger, Bernhard Hunke, Thomas Roick, Günter Sackmann
  • Publication number: 20020002221
    Abstract: Flame retardant compositions useful as insulation for 150° C.-rated wire and cable applications are provided. The compositions of the invention utilize an ethylene-alkyl acrylate copolymer base resin with a two-component stabilizer package consisting of a zinc salt of a mercaptobenzimidazole and an aromatic secondary amine compound. Also, included to achieve the requisite flame retardance, crosslinkability and physical properties are a brominated flame retardant, antimony trioxide, a hydrated inorganic filler and a chemical crosslinking agent.
    Type: Application
    Filed: November 8, 1999
    Publication date: January 3, 2002
    Inventor: LESTER Y. LEE
  • Patent number: 6312822
    Abstract: A thermoplastic polyolefin composition suitable for use as a coating for a photographic support includes an optical brightener and a polar additive. The polar additive substantially compatibilizes the polar optical brightener with the non-polar polyolefin. A method for adding a polar additive to a polyolefin is also disclosed.
    Type: Grant
    Filed: November 25, 1998
    Date of Patent: November 6, 2001
    Inventors: Gether Irick, Jr., Joe L. Farrar
  • Patent number: 6297314
    Abstract: The invention relates to a coating agent containing a) one or more polyester resins (A); b) one or more polyacrylate resins (B); c) one or more di- and/or polyisocyanates (C) with free or blocked isocyanate groups; d) one or more light stabilizers (L1) based on a UV absorber; e) one or more light stabilizers (L2) based on sterically hindered amines; and f) one or more organic solvents (D). The coating agent is characterized in that 1) the polyester (A) has a hydroxyl number of 80-200 mg KOH/g and an acid number <10mg KOH/g; 2) the polyacrylate resin (B) has a hydroxyl number of 80-200 mg KOH/g and an acid number <20 mg KOH/g; and 3) the light stabilizer (L2) based on sterically hindered amines is functionalized by aminoether.
    Type: Grant
    Filed: January 12, 2000
    Date of Patent: October 2, 2001
    Assignee: BASF Coatings AG
    Inventors: Horst Hintze-Brüning, Patrick Van Ende
  • Publication number: 20010025069
    Abstract: Provided are polypropylene-based films and sheets having good ultraviolet shieldability. While being stored, the films and the sheets are free from additive bleeding, and their outward appearance is kept all the time good. The films and the sheets are formed from a composition comprising 100 parts by weight of a polypropylene-based resin and from 0.
    Type: Application
    Filed: April 24, 2001
    Publication date: September 27, 2001
    Applicant: IDEMITSU PETROCHEMICAL CO., LTD.
    Inventors: Hiroshi Itagaki, Satoshi Tamura, Kouji Satou
  • Patent number: 6291586
    Abstract: An ultraviolet light absorbing material that resists blooming and migration is made up of a polyurethane or polyurea polymer and an amide functional ultraviolet light absorbing compound, wherein the polymer and the amide functional ultraviolet light absorbing compound are hydrogen bonded to one another. Polymeric films that contain a polymeric matrix and the ultraviolet light absorbing material are useful as the top layer in multilayer constructions such as retroreflective sheetings and conformable marking sheets.
    Type: Grant
    Filed: October 31, 1997
    Date of Patent: September 18, 2001
    Assignee: 3M Innovative Properties Company
    Inventors: James E. Lasch, David B. Olson, David M. Burns
  • Patent number: 6277905
    Abstract: This invention relates to a process for improving the toughness of a polymer composition comprising blending: (A) a polyester comprising: (1) terephthalic acid in the amount of 85 to 100 mole % based on the mole percentages of the dicarboxylic acid component equaling a total of 100 mole %. (2) a glycol component comprising from about 60 to 100 mole % 1,4-cyclohexanedimethanol based on the total percentages of the glycol component equaling a total of 100 mole %; (B) one or more rubber impact modifiers; (C) one or more halogenated organic compounds containing at least one imide group having a melting point of greater than 240° C.; and (D) reinforcing fiber.
    Type: Grant
    Filed: November 30, 1999
    Date of Patent: August 21, 2001
    Assignee: Eastman Chemical Company
    Inventor: Gerald Timothy Keep
  • Patent number: 6262151
    Abstract: Benzotriazole UV absorbers which are substituted at the 5-position of the benzo ring by an electron withdrawing group exhibit enhanced durability and very low loss rates when incorporated into automotive coatings. This is particularly the case when the 3-position of the phenyl ring is also substituted by phenyl or phenylalkyl such as &agr;-cumyl. Compounds where the 5-position of the benzo ring are substituted by perfluoroalkyl such as trifluoromethyl are particularly of interest for both their enhanced durability and for their excellent solubility and excellent color properties in some thermoplastic compositions when the phenyl ring is substituted at the 3-position by hydrogen or tert-alkyl.
    Type: Grant
    Filed: July 12, 2000
    Date of Patent: July 17, 2001
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Ramanathan Ravichandran, Joseph Suhadolnik, Mervin G. Wood, Anthony Debellis, Robert E. Detlefsen, Revathi Iyengar, Jean-Pierre Wolf
  • Publication number: 20010007885
    Abstract: An ultraviolet light absorbing material that resists blooming and migration is made up of a polyurethane or polyurea polymer and an amide functional ultraviolet light absorbing compound, wherein the polymer and the amide functional ultraviolet light absorbing compound are hydrogen bonded to one another. Polymeric films that contain a polymeric matrix and the ultraviolet light absorbing material are useful as the top layer in multilayer constructions such as retroreflective sheetings and conformable marking sheets.
    Type: Application
    Filed: October 31, 1997
    Publication date: July 12, 2001
    Inventors: JAMES E. LASCH, DAVID B. OLSON, DAVID M. BURNS
  • Patent number: 6245840
    Abstract: Provided are polypropylene-based films and sheets having good ultraviolet shieldability. While being stored, the films and the sheets are free from additive bleeding, and their outward appearance is kept all the time good. The films and the sheets are formed from a compositions comprising 100 parts by weight of a polypropylene-based resin and from 0.01 to 5 parts by weight of one or more compounds selected from the following (A) to (D): (A) 2-(2-hydroxy-5-t-octylphenyl)benzotriazole, (B) 2-(2H-benzotriazol-2-yl)-6-dodecyl-4-methylphenol, (C) specific triazine compounds, and (D) specific methylene-bisphenols.
    Type: Grant
    Filed: February 16, 1999
    Date of Patent: June 12, 2001
    Assignee: Idemitsu Petrochemical Co. Ltd.
    Inventors: Hiroshi Itagaki, Satoshi Tamura, Kouji Satou
  • Publication number: 20010003030
    Abstract: The present invention provides an over-coating composition comprising a basic compound for coating a photoresist composition to provide a vertical photoresist pattern.
    Type: Application
    Filed: December 1, 2000
    Publication date: June 7, 2001
    Inventors: Jae Chang Jung, Keun Kyu Kong, Cha Won Koh, Jin Soo Kim, Ki Ho Baik
  • Patent number: 6218450
    Abstract: A copolyester blend resistant to ultraviolet radiation includes a polyethylene terephthalate based copolyester having 1,4-cyclohexanedimethanol residues; an effective amount of an ultraviolet radiation absorber selected from the group consisting of benzoxazinones, dimeric benzotriazoles, triazines and mixtures thereof; from about 5 mol % to about 40 mol % isophthalic acid residues in the copolyester, and from 5 mol % to 20 mol % 4,4′-biphenyldicarboxylic acid residues present in the copolyester, wherein the mole percent of the diacid is based on 100 mole percent of dicarboxylic acid or equivalents. The copolyester blend is useful in making UV radiation resistant thermoformed articles.
    Type: Grant
    Filed: December 13, 1999
    Date of Patent: April 17, 2001
    Assignee: Eastman Chemical Company
    Inventor: David Richard Fagerburg
  • Patent number: 6194330
    Abstract: A process for the production of an ultra violet absorbing polymer latex is provided. The inventive process involves the emulsion polymerization of a benzotriazole- or benzophenone-containing monomer with a vinyl functional monomer in the presence of a chain transfer agent, preferably 1-dodecanethiol. The latex provides excellent long-lasting, easy to apply, difficult to remove, ultraviolet absorption properties for many different substrates, most notably fabrics. Different articles and fabrics coated, covered, laminated, and the like, with the inventive latex are also provided.
    Type: Grant
    Filed: July 31, 1998
    Date of Patent: February 27, 2001
    Assignee: Milliken & Company
    Inventors: Kirkland W. Vogt, Shulong Li
  • Patent number: 6187859
    Abstract: An improved light stable polyether/polyol based aliphatic urethane thermoplastic elastomer prepared from reacting inter alia a polyol having low terminal end unsaturation and an organic diisocyanate. The elastomer is characterized by ultra violet stabilizer being present in a range of 0.25% to 2.0% at a total concentration of 1.0% to 2.0%, an antioxidant being present at a total concentration of 0.10% to 1.0%, and colorants/pigment being present in a total concentration in a range from 1.0% to 2.05% to produce an elastomer capable of withstanding Xenon arc artificial weathering with DE≦3.00 after 2450 kilojoules of exposure.
    Type: Grant
    Filed: October 19, 1998
    Date of Patent: February 13, 2001
    Assignee: Davidson Textron Inc.
    Inventors: William M. Humphrey, Victor E. Gerard
  • Patent number: 6180698
    Abstract: A liquid chemical formulation suitable for making a thin solid polycarbonate film of highly uniform thickness is formed with polycarbonate material, a liquid that dissolves the polycarbonate, and possibly one or more other constituents. The liquid is typically capable of dissolving the polycarbonate to a concentration of at least 1% at 20° C. and 1 atmosphere. The liquid also typically has a boiling point of at least 80° C. at 1 atmosphere. Examples of the liquid include pyridine, a ring-substituted pyridine derivative, pyrrole, a ring-substituted pyrrole derivative, pyrrolidine, a pyrrolidine derivative, and cyclohexanone. In forming the polycarbonate-containing film, a liquid film (36A) of the liquid chemical formulation is formed over a substructure (30). The liquid film is processed to largely remove the liquid and convert the polycarbonate into a solid film (38).
    Type: Grant
    Filed: February 28, 1997
    Date of Patent: January 30, 2001
    Assignees: Candescent Technologies Corporation, Hewlett-Packard Company
    Inventors: John D. Porter, Scott J. Crane, Stephanie J. Oberg, Anthony W. Johnson
  • Patent number: 6166129
    Abstract: The present invention relates to a novel photochromic polyurethane consisting essentially of an isocyanate reactive mixture consisting essentially of: i) from about 40 to about 85% by weight of one or more polyols having a nominal functionality of from 2 to 4 and molecular weights of from 500 to 6000 g/mole; ii) from about 15 to about 60% by weight of one or more diols or triols or mixtures thereof having a functionality of from 2 to 3 and molecular weights of from 62 to 499; b) an aliphatic polyisocyanate having a functionality ranging from about 2 to about 3; and c) a photochromic compound selected from a group consisting of spirooxazines, fulgides, fulgimides, and naphthopyrans, wherein the photochromic compound is present in an amount of 0.01 to 5 parts per hundred parts by weight of the isocyanate reactive mixture.
    Type: Grant
    Filed: October 1, 1999
    Date of Patent: December 26, 2000
    Assignee: Bayer Corporation
    Inventors: James W. Rosthauser, Karl W. Haider, Sivaram Krishnan, James N. Rieck
  • Patent number: 6150440
    Abstract: An ultraviolet light absorbing material that resists blooming and migration is made up of a carboxyl functional polymer and an amide functional ultraviolet light absorbing compound, wherein the carboxyl functional polymer and the amide functional ultraviolet light absorbing compound are hydrogen bonded to one another. Polymeric films that contain a polyolefin and the ultraviolet light absorbing material are useful as the top layer in multilayer constructions such as retroreflective sheetings and conformable marking sheets.
    Type: Grant
    Filed: September 4, 1998
    Date of Patent: November 21, 2000
    Assignee: 3M Innovative Properties Company
    Inventors: David B. Olson, David M. Burns
  • Patent number: 6114419
    Abstract: Fluorinated imides useful for imparting repellency of low surface tension fluids to thermoplastic polymers of formulae ##STR1## wherein R.sub.1 is F(CF.sub.2).sub.x --(CH.sub.2).sub.m, or F(CF.sub.2).sub.x SO.sub.2 N(R.sub.5) (CH.sub.2)p wherein x is from about 4 to about 20, m is from about 2 to about 6, p is from 1 to about 12, and R.sub.5 is an alkyl radical of from 1 to about 4 carbons;R.sub.2 is a linear, branched or cyclic alkylene or poly(oxyalkylene) hydrocarbon group having from about 2 to about 15 carbons;R.sub.3 is selected from the group consisting of F(CF.sub.2).sub.x --(CH.sub.2).sub.m, F(CF.sub.2).sub.x --(CH.sub.2).sub.m --OC(O)--(CH.sub.2).sub.n, and F(CF.sub.2).sub.x SO.sub.2 N(R.sub.5)(CH.sub.2).sub.p OC(O)(CH.sub.2).sub.n wherein x is from about 4 to about 20, m is from about 2 to about 6, n is about 2 to about 12, p is from 1 to about 12, and R.sub.5 is an alkyl radical of from 1 to about 4 carbons;R.sub.4 is an alkyl or alkenyl group of from about 4 to about 20 carbons, andR.sub.
    Type: Grant
    Filed: April 7, 1998
    Date of Patent: September 5, 2000
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Theodor Arthur Liss, Kimberly Gheysen Raiford, Edward James Greenwood
  • Patent number: 6066687
    Abstract: An acrylic fiber exhibiting improved brightness and proccessability is disclosed. The fiber includes a synergistic combination of a delustrant and an optical brightener and is specifically useful in the manufacture of "terry" knitted athletic socks.
    Type: Grant
    Filed: June 24, 1994
    Date of Patent: May 23, 2000
    Assignee: Solutia Inc.
    Inventors: Gary Joseph Capone, Henry Gook Chin
  • Patent number: 6040356
    Abstract: This invention relates to a durable gravure ink composed of a pigment with high weather resistance, a pigment with high alkali resistance, and a binder with high weather resistance and high alkali resistance, and a technique for producing a decorative material using this ink. According to this invention, a decorative material having a pattern layer excellent in both of weather resistance and alkali resistance is provided.
    Type: Grant
    Filed: May 11, 1998
    Date of Patent: March 21, 2000
    Assignee: Dai Nippon Printing Co., Ltd.
    Inventors: Masahiro Kanki, Mutsuhiro Kawano, Takashi Matano
  • Patent number: 6040366
    Abstract: The compression set of elastomeric silicone compositions, addition cured injection moldable compositions, is reduced by the incorporation of nitrogen compounds wherein the nitrogen possesses at least one organic substituent and the nitrogen is tetravalent wherein the nitrogen is cationic. The adhesion of such compositions to thermoset or thermoplastic polymer substrates is improved by the addition of bis(trimethoxysilylpropyl)fumarate and a disilanol that may or may not contain alkenyl groups. The lubricity of such compositions is improved by the addition of compounds selected from the group consisting of diorganosiloxanes such as polydimethylsiloxanes, phenyl containing siloxanes such as copolymers of diphenylsiloxane with diorganosiloxanes and copolymers of methylphenylsiloxane with diorganosiloxanes, fluorosilicones such as silicones containing trifluoropropyl substituted siloxanes, polydimethylsiloxanes, aliphatic and aromatic hydrocarbons that are liquid between 0.degree. C. and 100.degree. C.
    Type: Grant
    Filed: February 27, 1998
    Date of Patent: March 21, 2000
    Assignee: General Electric Company
    Inventors: Frank S. Burkus, II, Edward M. Jeram, Slawomir Rubinsztajn
  • Patent number: 6025433
    Abstract: To offer thermosetting paint compositions resistant to yellowing to brass, which give paint films of excellent resistance to yellowing due to brass, low-temperature curability, weather resistance, resistance to yellowing after stoving, acid resistance, scratch resistance, solvent resistance, adhesion and appearance. Thermosetting paint compositions, which are thermosetting paint compositions which are resistant to yellowing due to brass, characterized in that the paint-film-forming components include (A) a compound which has per molecule at least 2 functional groups which can react with an isocyanate group, at 49.6-90 wt %, (B) a blocked isocyanate which has par molecule at least 2 isocyanate groups blocked by an azole blocking agent, at 9.6-50 wt %, (C) an ultraviolet absorber and/or free radical scavenger, at 0.2-5 wt %, (D) an organotin compound at 0.1-3 wt %, and (E) an amino resin at 0.1-30 wt %.
    Type: Grant
    Filed: July 21, 1998
    Date of Patent: February 15, 2000
    Assignee: BASF Coatings AG
    Inventors: Kishio Shibatoh, Souichi Mori, Yasuhiro Monma
  • Patent number: 5998520
    Abstract: A thermoplastic molding composition is disclosed comprising (A) at least one resinous component selected from the group consisting of (i) a homogeneous blend of polycarbonate resin and polycaprolactone and (ii) a copoly(carbonate-lactone) copolymer, and (B) at least one compound selected from a group consisting of benzopyrans, naphthopyrans, spirobenzopyrans, spironaphthopyrans, spirobenzoxazines, spironaphthoxazines, fulgides and fulgimides. The composition which contains the photochromic compound at an amount of 0.01 to 1.0 parts per hundred parts of weight of said (A) exhibits good photochromic properties.
    Type: Grant
    Filed: July 2, 1997
    Date of Patent: December 7, 1999
    Assignee: Bayer Corporation
    Inventors: Sivaram Krishnan, Robert A. Pyles, James B. Johnson, Michael P. Jenkins, Timothy J. Pike
  • Patent number: 5977220
    Abstract: A process to reduce the compression set of elastomeric silicone compositions, addition cured injection moldable compositions or millable compositions, comprises the incorporation of nitrogen compounds wherein the nitrogen possesses at least one organic substituent and the nitrogen is tetravalent wherein the nitrogen is cationic.
    Type: Grant
    Filed: December 29, 1997
    Date of Patent: November 2, 1999
    Assignee: General Electric Company
    Inventors: Frank S. Burkus, II, Edward M. Jeram, Slawomir Rubinsztajn
  • Patent number: 5972248
    Abstract: The present invention relates to novel stabilizers of the formula (I) ##STR1## in which the substituents have the meaning defined in the description. These novel stabilizers are particularly suitable for stabilizing organic material, such as plastics, oils, paints and coatings, against degradation by light, radiation, heat and oxygen.
    Type: Grant
    Filed: October 7, 1997
    Date of Patent: October 26, 1999
    Assignee: Clariant GmbH
    Inventors: Thomas Stahrfeldt, Josef Wiedemann, Matthias Zah
  • Patent number: 5973126
    Abstract: A monoazo compound synthesized using 2-hydroxynaphthalene-3,6-dicarboxylic acid (or salt thereof), an amide, an ureide or an ester thereof as a coupler is novel, and is superior in water resistance, chemical resistance and solvent resistance. The present invention provides such a novel azo compound and a process for producing the same.
    Type: Grant
    Filed: May 20, 1998
    Date of Patent: October 26, 1999
    Assignee: Kabushiki Kaisha Ueno Seiyaku Oyo Kenkyujo
    Inventors: Ryuzo Ueno, Masaya Kitayama, Kenji Minami, Hiroyuki Wakamori
  • Patent number: 5942571
    Abstract: A liquid silicone rubber composition for use in high-voltage eletrical insulating parts comprising (A) a polyorganosiloxane containing alkenyl groups, (B) fumed silica, (C) a polyorganohydridosiloxane, (D) a platinum type catalyst, (E) finely powdered aluminum hydroxide, and (F) a powdered metal compound selected from the group consisting of powdered zinc oxidc, powdered zinc borate, and powdered magnesium hydroxide and a method for manufacturing such a composition.
    Type: Grant
    Filed: January 28, 1998
    Date of Patent: August 24, 1999
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Akito Nakamura, Yasumichi Shigehisa, Yuichi Tsuji
  • Patent number: 5939493
    Abstract: A rubber composition comprising 100 parts by weight of a rubber component which comprises at least one type of rubber selected from the group consisting of natural rubber and diene synthetic rubbers, 0.1 to 10 parts by weight of at least one type of metal dithiophosphate represented by the following general formula, optionally 15 to 85 parts by weight of a reinforcing inorganic filler, and optionally a specific tertiary amine compound in an amount of 0.5 to 15% by weight of the amount of the reinforcing inorganic filler is provided.General formula ##STR1## wherein R.sup.1 and R.sup.3 each independently represents an alkyl group or a cycloalkyl group, M represents an antimony atom, a zinc atom, a copper atom, or an iron atom, and n represents a valency of M.The rubber composition of the present invention exhibits excellent resistance to heat or resistance to heat aging (particularly excellent resistance to hardening and excellent fracture properties).
    Type: Grant
    Filed: December 24, 1997
    Date of Patent: August 17, 1999
    Assignee: Bridgestone Corporation
    Inventor: Masahiro Hojo
  • Patent number: 5936054
    Abstract: An addition-crosslinkable silicone rubber composition comprising the constituents(I) an alkenyl-functional polyorganosiloxane(II) a SiH-functional crosslinker(III) a hydrosilylation catalyst and(IV) at least one 1H-benzotriazole-5-carboxylic acid derivative selected from a group consisting of 1H-benzotriazole-5-carboxylic acid esters and 1H-benzotriazole-5-carboxylic acid amides.
    Type: Grant
    Filed: June 10, 1997
    Date of Patent: August 10, 1999
    Assignee: Wacker-Chemie GmbH
    Inventors: Frank Achenbach, Christof Worner, Brigitte Ostermeier, Georg Eberl, Jelica Gegic
  • Patent number: 5936016
    Abstract: The present invention relates to photochromic compounds of spiro?indoline?2,3'!-naphthoxazine! structure, characterized in that they contain, in the 6' position, a group R.sub.6 chosen from the following groups: cyano and phenylsulfonyl linked via the sulfur atom to carbon 6', and methods of using such compounds.
    Type: Grant
    Filed: January 29, 1997
    Date of Patent: August 10, 1999
    Assignee: Essilor International Compagnie Generale D'Optique
    Inventors: Pierre Lareginie, Vladimir Lokshin, Andre Samat, Robert Guglielmetti, Elena Zaballos Garcia
  • Patent number: 5925150
    Abstract: A black colorant composition useful for coloring polyurethanes is provided having a red benzothiazole azo colorant which, when combined with a complementary blue and yellow colorant, exhibits low flairing.
    Type: Grant
    Filed: August 20, 1997
    Date of Patent: July 20, 1999
    Assignee: Milliken & Company
    Inventors: Mark Edward Ragsdale, David Jesse Moody, Eric B. Stephens
  • Patent number: 5919847
    Abstract: A composition comprising a blend of a thermoplastic resin and at least one compound or oligomer which is ##STR1## wherein R.sub.f is a perfluorinated moiety which may contain one or more catenary ether oxygen atoms, Q is a linking group selected from alkylene groups having 1 or 2 carbon atoms, sulfonamido groups or combinations thereof, R is an alkyl group, R.sup.1 is a perfluoroalkyl group, R.sup.2 is an alkyl group which may be straight chain or branched and n is a number of from 2 to 40.
    Type: Grant
    Filed: December 2, 1997
    Date of Patent: July 6, 1999
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Alan D. Rousseau, Marvin E. Jones, Seyed A. Angadjivand
  • Patent number: 5916937
    Abstract: A heat cured fluorosilicone rubber exhibiting improved compression set comprises N,N'-meta-phenylenedimaleimide.
    Type: Grant
    Filed: September 30, 1997
    Date of Patent: June 29, 1999
    Assignee: General Electric Company
    Inventor: Edwin R. Evans
  • Patent number: 5912287
    Abstract: A silicone rubber composition comprising(A) polyorganosiloxane described by average formula R.sub.a SiO.sub.(4-a)/2, where R denotes substituted and unsubstituted monovalent hydrocarbon groups and a is a number from 1.95 to 2.05 and having at least 2 silicon-bonded alkenyl groups in each molecule;(B) microparticulate silica;(C) the reaction mixture of(a) a platinum compound and(b) an organosilicon compound described by general formula ##STR1## where R.sup.1, R.sup.2, and R.sup.3 represent C.sub.1 to C.sub.10 monovalent hydrocarbon groups and a is 1, 2, or 3;(D) curing agent, and optionally(E) triazole compound.
    Type: Grant
    Filed: July 17, 1997
    Date of Patent: June 15, 1999
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Takao Matsushita, Osamu Takuman
  • Patent number: 5883163
    Abstract: A light conducting plate for back lighting which comprises a methacrylic copolymer resin comprising 90 to 99.5% by weight of a methyl methacrylate unit and 0.5 to 10% by weight of an alkyl acrylate unit containing 1 to 8 carbon atoms in the alkyl moiety thereof and having a reduced viscosity of 35 to 60 ml/g in chloroform, the chromaticity of said light conducting plate having x and y color coordinates both ranging from 0.01 to 0.001 as obtained according to JIS-Z-8701.
    Type: Grant
    Filed: August 19, 1997
    Date of Patent: March 16, 1999
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventor: Nobuyuki Hosonuma
  • Patent number: 5880199
    Abstract: A liquid silicone rubber composition that prior to its cure has a suitable fluidity and excellent moldability and that cures into a highly flame retardant silicone rubber molding with excellent electrical properties. The liquid silicone rubber composition comprises(A) polyorganosiloxane,(B) microparticulate silica,(C) aluminum hydroxide powder,(D) zinc carbonate powder,(E) polyorganohydrogensiloxane,(F) benzotriazole,(G) the reaction mixture of(a) a platinum compound and(b) 3,5-dimethyl-1-hexyn-3-ol, and(H) hydrosilylation reaction catalyst.
    Type: Grant
    Filed: May 22, 1997
    Date of Patent: March 9, 1999
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Takao Matsushita, Yasumichi Shigehisa, Yuichi Tsuji
  • Patent number: 5863599
    Abstract: The present invention provides a film for application to a surface of a material capable of transmitting heat and/or light. The film comprises: a solvent comprising at least one volatile organic compound in an amount sufficient to maintain flowability of the film after exposure to air and for a time sufficient to apply the film to the surface, whereupon the solvent evaporates and dries the film; a polymer in an amount sufficient to reversibly bind the film to the surface; and, an ultraviolet absorbent material in an amount sufficient to reduce transmission of said energy through said material. The film may be applied and removed upon demand by the user.
    Type: Grant
    Filed: January 8, 1997
    Date of Patent: January 26, 1999
    Inventor: Chel Wing Lew
  • Patent number: 5837757
    Abstract: Disclosed are non-bromine, flame-retardant polycarbonate resin compositions having increased reflectance and improved light shieldability, light fastness and moldability while still having good mechanical properties such as flame retardancy and impact resistance, and light reflectors as produced by molding the compositions. One type of the composition comprises (A) a polycarbonate resin and (B) a titanium oxide powder in a ratio by weight of from 70/30 to 90/10, and contains (C) a stilbene-bisbenzoxazole derivative in an amount of from 1 to 1000 ppm by weight and optionally (D) a non-halogen phosphate compound in an amount of from 0.05 to 1.00% by weight in term of phosphorus element, relative to the total weight of the component (A) and the component (B). The other type of the composition comprises (A) from 99.9 to 70% by weight of a polycarbonate resin and (B) from 0.1 to 30% by weight of a titanium oxide powder, and contains (D) a non-halogen phosphate compound in an amount of from 0.05 to 1.
    Type: Grant
    Filed: June 3, 1997
    Date of Patent: November 17, 1998
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Akio Nodera, Hiroshi Itagaki
  • Patent number: 5789470
    Abstract: The invention relates to stabilized recycled plastics, which can be obtained from domestic, commercial and industrial waste or valuable material collections, comprising a macrocyclic compounds containing a radical of formula (I) or (II), in the macrocycle or in a side group of the macrocycle, where the macrocycle comprises at least 8 atoms and in which the substituents R, independently of one another, are methyl, ethyl or propyl, or two radicals R on the same carbon atom are, together, a pentamethylene radical, and a is the number 0, 1 or 2. The invention also relates to a process for the stabilization of recycled plastics and to the use of the above macrocyclic compounds as stabilizer.
    Type: Grant
    Filed: March 20, 1997
    Date of Patent: August 4, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Heinz Herbst, Kurt Hoffmann, Franca Masina, Rudolf Pfaendner, Franciszek Sitek
  • Patent number: 5756256
    Abstract: A planarizing technique comprising: coating a topography overlying a substrate with a planarizing resist layer; softbaking the planarizing resist layer in the presence of a silicon-containing vapor or liquid; coating the planarizing resist layer with an imaging resist layer; softbaking the imaging resist; selectively exposing the imaging resist layer to light; developing the imaging resist layer; and etching the planarizing layer. The planarizing layer may comprise novolacs and other organic polymers used conventionally in lithographic processes. The planarizing layer may further comprise any organic acid moiety that is compatible with the solvent used to dissolve the resin. In particular, the acid moiety is indole-3-carboxylic acid. In another aspect, the invention comprises a silylated planarizing resist.
    Type: Grant
    Filed: January 16, 1997
    Date of Patent: May 26, 1998
    Assignees: Sharp Microelectronics Technology, Inc., Sharp Kabushiki Kaisha
    Inventors: Tatsuo Nakato, David A. Vidusek
  • Patent number: 5744615
    Abstract: Disclosed is a process for producing an ultra-white N,N'-ethylene-bis(tetrabromophthalimide) product useful as a flame retardant. Also disclosed is a flame retardant composition predominantly comprised of N,N'-ethylene-bis(tetrabromophthalimide) and having unprecedented color and high purity.
    Type: Grant
    Filed: January 19, 1996
    Date of Patent: April 28, 1998
    Assignee: Great Lakes Chemical
    Inventors: Brian Tarbit, Brian Adger, Paul Willett
  • Patent number: 5741837
    Abstract: A syndiotactic polystyrene composition is improved which exhibits improved crystallization rate. The improved syndiotactic polystyrene composition contains (a) a syndiotactic polystyrene; and (b) a nucleating agent which is selected from the group consisting of two types of compounds represented by the following formulas, respectively: ##STR1## In Formulas I and II, the radicals R.sub.1 and R.sub.2, which can be the same of different, are C.sub.1 to C.sub.5 alkyl groups, X is a halogen group, preferably a bromide group, and n is an integer from 1 to 5. In the present invention, the nucleating agent is provided at 0.01 to 5 part, by weight, per 100 parts, also by weight, of the syndiotactic polystyrene resin. An example of Formula I compound is 2-hydroxybenimidiazole, and an example of the Formula II compound is bis(phenylbromide) methane.
    Type: Grant
    Filed: March 27, 1997
    Date of Patent: April 21, 1998
    Assignee: Industrial Technology Research Institute
    Inventors: Chung-Jen Wu, Chien-Ming Chen, Hsien-Ming Chen, Hurng-Rern Lee
  • Patent number: 5723543
    Abstract: A thermoplastic elastomer composition is provided. The composition comprises a hydrogenated elastomeric block copolymer having at least two resinous endblocks of polymerized monovinyl aromatic compound and an elastomeric midblock of polymerized conjugated diene, a midblock plasticizer, and an ethylene-acrylate copolymer or terpolymer. The thermoplastic elastomer exhibits improved overmolding adhesion to polar matrices over compositions not containing the ethylene-acrylate polymer.
    Type: Grant
    Filed: September 26, 1996
    Date of Patent: March 3, 1998
    Assignee: Shell Oil Company
    Inventor: Michael John Modic