Two Or More Nitrogen Rings Patents (Class 524/97)
  • Patent number: 6410045
    Abstract: A drug delivery system for antiglaucomatous medications utilizing a polymeric hydrogel which can absorb an ophthalmic medication which can then be transferred into the ocular fluid of the eye.
    Type: Grant
    Filed: February 19, 2000
    Date of Patent: June 25, 2002
    Inventors: Clyde Lewis Schultz, Janet M. Mint
  • Patent number: 6177491
    Abstract: Compounds of formula (I), wherein n is a number from 2 to 14; R1 is for example C1-C18alkyl or C5-C12cycloalkyl; R2 is for example C2-C12alkylene; A is for example acetyl, (C1-C4alkoxy)carbonyl, (C1-C4alkyl)aminocarbonyl or C1-C4alkyl; B is —OR3, —N(R4(R5) or a group of formula (II); R3, R4 and R5, which are identical or different, are for example hydrogen or C1-C18alkyl, or —N(R4)(R5) is additionally a group of formula (III) with Y being —O—, —CH2—, —CH2CH2— or >N—CH3; X is —O— or >N—R6; R6 is for example hydrogen or C1-C18alkyl; and R is preferably a group of formula (IV); with the proviso that in the individual recurrent units of formula (I), each of the radicals B, R, R1 and R2 has the same or a different meaning. The indicated compounds are useful as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials, in particular synthetic polymers.
    Type: Grant
    Filed: November 18, 1999
    Date of Patent: January 23, 2001
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: James Peter Galbo, Dario Lazzari, Fabrizio Guizzardi
  • Patent number: 6174940
    Abstract: The present invention relates to mixtures comprising the compound I in a proportion of 65-95% by weight, the compound II in a proportion of 5-35% by weight and the compound III in a proportion of 0-10% by weight wherein the substituents are as defined in the description, and to mixtures with other compounds. The mixtures are suitable for stabilizing organic material against the effect of light and heat.
    Type: Grant
    Filed: August 13, 1998
    Date of Patent: January 16, 2001
    Assignee: Clariant GmbH
    Inventors: Thomas St{umlaut over (a)}hrfeldt, Mathias Mehrer, Matthias Z{umlaut over (a)}h, Gerhard Pfahler
  • Patent number: 6107375
    Abstract: A thermoplastic composition featuring an improved resistance to hydrolysis is disclosed. The composition comprises (i) thermoplastic polycarbonate resin (ii) about 0.01 to 3 percent of a compound selected from the group consisting of phosphite and phosphonite and (iii) an additive amount of an oligomer or polymer the structure of which features at least one pendant cyclic iminoether group per molecular chain. The additive amount is that which is sufficient to improve the resistance of the polycarbonate resin to hydrolysis.
    Type: Grant
    Filed: October 8, 1998
    Date of Patent: August 22, 2000
    Assignee: Bayer Corporation
    Inventors: Sivaram Krishnan, James B. Johnson, Donald K. Booher
  • Patent number: 6037395
    Abstract: A conductive material and an oxazoline ring-containing compound or a high-molecular compound obtained by (graft) copolymerization of at least one 2-oxazoline ring-containing compound are added to an aromatic polycarbonate resin and optionally a polyester resin having mainly a skeleton of 1,4 cyclohexanedimethanol origin as a glycol component, thereby obtaining a conductive resin composition significantly improved in strength characteristics and further moisture absorbability without deterioration of heat resistance.
    Type: Grant
    Filed: February 13, 1998
    Date of Patent: March 14, 2000
    Assignee: Riken Vinyl Industry Co., Ltd.
    Inventor: Masaki Enomoto
  • Patent number: 6020406
    Abstract: A synergistic stabilizer mixture comprising a component a) and, for example, a component b), where component a) is at least one compound of the formula I ##STR1## in which R.sub.1 is C.sub.1 -C.sub.10 alkyl, C.sub.5 -C.sub.12 cycloalkyl, C.sub.1 -C.sub.4 alkyl-substituted C.sub.5 -C.sub.12 cycloalkyl, phenyl or C.sub.1 -C.sub.10 alkyl-substituted phenyl,R.sub.2 is C.sub.3 -C.sub.10 alkylene,R.sub.3 is hydrogen, C.sub.1 -C.sub.8 alkyl, O.sup..cndot., --CH.sub.2 CN, C.sub.3 -C.sub.6 alkenyl, C.sub.7 -C.sub.9 phenylalkyl, C.sub.7 -C.sub.9 phenylalkyl which is substituted on the phenyl radical by C.sub.1 -C.sub.4 alkyl; or C.sub.1 -C.sub.8 acyl, andn.sub.1 is a number from 1 to 50,and component b) is, for example, a compound of the formula ##STR2## in which n.sub.2 is a number from 2 to 20.
    Type: Grant
    Filed: May 27, 1997
    Date of Patent: February 1, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Fran.cedilla.ois Gugumus
  • Patent number: 5969014
    Abstract: A use for synergistic additives for polyamides is disclosed by forming a uniform and intimate mixture with polyamide with a component system selected from (I) (II) or (III) (on a weight basis) where(I) is from 0.01% to 1% of a sterically hindered phenyl phosphonite (Ia) with from 0.05% to 5% of a non-hydroxyl substituted oxanilide(Ib) (together 1a+1b), or Ia together with an aromatic di-carbonyl compound containing two hindered amine moieties (together Ia+c). Preferably the weight ratio of Ia to Ib and Ia to Ic is from 1:3 to 1:10, more preferably 1:4, 1:5 or 1:6 and most preferably 1:5; and(II) is from 0.05 to 5% of a non-hydroxyl substituted oxanilide containing at least two hindered amine groups (a) together with from 0.05 to 5% of the aromatic di-carbonyl compound (b), (II a+b),or (III) from 0.01% to 1% of a sterically hindered phenyl phosphonite, from 0.05 to 5% of a non-hydroxyl substituted oxanilide, and from 0.05 to 5% of an aromatic di-carbonyl compound.
    Type: Grant
    Filed: September 23, 1997
    Date of Patent: October 19, 1999
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Joseph R. Webster, Klaus H. Stoll, Jan Malik, Mohamed Sidqi
  • Patent number: 5883163
    Abstract: A light conducting plate for back lighting which comprises a methacrylic copolymer resin comprising 90 to 99.5% by weight of a methyl methacrylate unit and 0.5 to 10% by weight of an alkyl acrylate unit containing 1 to 8 carbon atoms in the alkyl moiety thereof and having a reduced viscosity of 35 to 60 ml/g in chloroform, the chromaticity of said light conducting plate having x and y color coordinates both ranging from 0.01 to 0.001 as obtained according to JIS-Z-8701.
    Type: Grant
    Filed: August 19, 1997
    Date of Patent: March 16, 1999
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventor: Nobuyuki Hosonuma
  • Patent number: 5849820
    Abstract: Thermally stabilized resin compositions are provided which contain one or more cyclic iminoether compounds represented by formula (I), cyclic iminoester compounds represented by formula (II), or both and an amine thermal stabilizer, wherein X is as described herein, and A and B are each, independently, a single bond, substituted or unsubstituted alkylene selected from the group consisting of methylene, ethylene, propylene, butylene, 1-methylethylene, 1,1-dimethylethylene, 1,2-dimethylene, 1-ethylethylene, 1-1-diethylethylene, 1-propylethylene, 1-butylene, 1-hexylethylene, and 1-methyltrimethylene.
    Type: Grant
    Filed: June 26, 1996
    Date of Patent: December 15, 1998
    Assignee: Kolon Industries, Inc.
    Inventors: Kyung Min Kim, Sang Hee Jang, Eun Ha Park
  • Patent number: 5808063
    Abstract: Described are novel photochromic spiro(indoline) fluoranthenoxazine compounds having certain substituents on the 1 and 3 positions of the indoline portion of the compounds and which may be represented by the following graphic formula: ##STR1## Also described are polymeric organic host materials that contain or that are coated with such compounds.
    Type: Grant
    Filed: October 1, 1997
    Date of Patent: September 15, 1998
    Assignee: PPG Industries, Inc.
    Inventor: Anil Kumar
  • Patent number: 5624981
    Abstract: Polyalkylpiperidine-containing acetic acid and 3-aminoacrylic acid derivatives I ##STR1## where R.sup.1 is hydrogen, C.sub.1 - to C.sub.6 -alkyl, formyl, C.sub.2 - to C.sub.6 -alkanoyl, C.sub.1 - to C.sub.12 -alkoxy, C.sub.5 - to C.sub.6 -cycloalkoxy, cyanomethyl, hydroxymethyl, 2-hydroxyethyl or a radical of the formula --CR.sup.3 =CH--CO--OR.sup.4, whereR.sup.3 is hydrogen, C.sub.1 -to C.sub.6 -alkyl or a radical of the formula --CO--OR.sup.4 andR.sup.4 is C.sub.1 - to C.sub.20 -alkyl, C.sub.5 - to C.sub.8 -cycloalkyl, C.sub.7 - to C.sub.18 -aralkyl, phenyl, tolyl or a radical of the formula --(CH.sub.2 CH.sub.2 O).sub.n H or --[CH(CH.sub.3)CH.sub.2 O].sub.n H, where n is a number from 1 to 30,X is O, NH or NR.sup.6, whereR.sup.6 is C.sub.1 - to C.sub.12 -alkyl, andY is hydrogen or a group of the formula =CH--NHR.sup.7 or =CH--NR.sup.6 R.sup.7, whereR.sup.7 is phenyl which can be substituted by one to three C.sub.1 - to C.sub.12 -alkyl, C.sub.1 - to C.sub.
    Type: Grant
    Filed: October 7, 1994
    Date of Patent: April 29, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Martin Holderbaum, Alexander Aumueller, Hubert Trauth
  • Patent number: 5603885
    Abstract: A process for the preparation of plexifilament strands of polyethylene having a ultraviolet stabilizer, in which the polyethylene is dissolved in a non-chlorofluorocarbon solvent, which is pentane, and the ultra-violet stabilizer is selected from Chimassorb 119, Chimassorb 944, and Cyasorb UV 3346.
    Type: Grant
    Filed: July 6, 1995
    Date of Patent: February 18, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: David J. McGinty
  • Patent number: 5405958
    Abstract: Described are novel reversible photochromic spiro(indoline) naphthoxazine compounds of improved photocolorability that may be graphically represented by the formula, ##STR1## In preferred embodiments, R.sub.1 is allyl, alkoxyalkyl, and alkyl; each R.sub.2 is alkyl or alkoxy; R.sub.3 and R.sub.4 are alkyl; R.sub.5 is alkoxycarbonyl; and R.sub.6 is hydroxy, alkoxy, or carboxy, e.g., acetoxy. Also described are organic host materials that contain or that are coated with such compounds. Articles such as ophthalmic lenses or other plastic transparencies that incorporate the naphthoxazine compounds or combination thereof with complementary photochromic compounds, e.g., naphthopyran or benzopyran compounds, are also described.
    Type: Grant
    Filed: December 21, 1992
    Date of Patent: April 11, 1995
    Assignee: Transitions Optical, Inc.
    Inventor: Barry VanGemert
  • Patent number: 5403877
    Abstract: This invention relates to salts of triazine derivatives with oxygenated as of phoshporus, having general formula (I): ##STR1## obtained by salification, with an acid containing phosphorus, of polycondensates of 2,4,6-triamino-1,3,5-triazine.The compounds having the general formula (I) are particularly used as flame-resistant additives.
    Type: Grant
    Filed: August 18, 1993
    Date of Patent: April 4, 1995
    Assignee: Ministero Dell'Universita E Della Ricerca Scientifica E. Tecnologica
    Inventors: Roberto Cipolli, Enrico Masarati, Gilberto Nucida, Roberto Oriani, Mario Pirozzi
  • Patent number: 5401797
    Abstract: A highly antioxidant resin composition containing a resin, a solution of a hypophosphite compound in an organic solvent, a heat stabilizer and a hindered amine base weathering stabilizer, which has improved heat stability and weather resistance. The hypophosphite compound is preferably dissolved in a polyvalent alcohol having a molecular weight of not more than 50,000.
    Type: Grant
    Filed: October 23, 1991
    Date of Patent: March 28, 1995
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kozo Kotani, Taiichi Sakaya
  • Patent number: 5389707
    Abstract: Salts of triazinic compounds with phosphorus oxyacids, having the general rmula (I): ##STR1## obtained by salifying oligomeric derivatives of 2,4,6-triamino-1,3,5-triazine with a phosphorus-containing acid.The compounds with general formula (I) find use in particular as flame-retardant additives.
    Type: Grant
    Filed: May 6, 1994
    Date of Patent: February 14, 1995
    Assignee: Ministero Dell'Universita' e Della Ricerca Scientifica e Tecnologica
    Inventors: Roberto Cipolli, Enrico Masarati, Roberto Oriani, Mario Pirozzi, Gilberto Nucida
  • Patent number: 5380815
    Abstract: Condensation compounds obtained by means of the polymerization of polyami compositions essentially constituted by derivatives of 2,4,6-triamino-1,3,5-triazine having the general formula (I): ##STR1## with aldehydes, preferably formaldehyde.
    Type: Grant
    Filed: November 13, 1992
    Date of Patent: January 10, 1995
    Assignee: Ministero Dell `Universita` E Della Ricerca Scientifica E Tecnologica
    Inventors: Roberto Cipolli, Roberto Oriani, Enrico Masarati, Gilberto Nucida
  • Patent number: 5352719
    Abstract: New and novel stabilized polymer compositions and processes for preparing them which employ new and novel carboxylic acid hydrazides bearing a 2,2,6,6-tetra-alkyl-4-piperidine ring and new and novel polymeric compositions stabilized therewith are provided.
    Type: Grant
    Filed: March 12, 1992
    Date of Patent: October 4, 1994
    Assignee: Elf Atochem North America, Inc.
    Inventor: Terry N. Myers
  • Patent number: 5352714
    Abstract: Improved silicone-containing hydrogels are disclosed with enhanced wettability comprising a silicone-containing monomer, hydrophilic monomers, and a relatively non-polar ring-containing monomer able to be converted to a highly polar amino acid upon hydration.
    Type: Grant
    Filed: July 30, 1992
    Date of Patent: October 4, 1994
    Assignee: Bausch & Lomb Incorporated
    Inventors: Yu-Chin Lai, Gary D. Friends, Paul L. Valint, Jr.
  • Patent number: 5331030
    Abstract: Polymeric compositions with good flame self-extinguishing characteristics, ased on thermoplastic polymers or polymers with elastomeric properties, especially olefinic polymers or copolymers, comprising:a) from 90 to 40 parts by weight of a thermoplastic polymer or a polymer with elastomeric properties;b) from 6 to 33 parts by weight of one or more ammonium or amine phosphates and/or phosphonates;c) from 4 to 27 parts by weight of one or more salts of 2,4,6-triamino-1,3,5-triazine derivatives with cyanuric acid, of general formula (I): ##STR1##
    Type: Grant
    Filed: December 1, 1992
    Date of Patent: July 19, 1994
    Assignee: Minstero dell `Universita` e della Ricerca Scientifica e Technologica
    Inventors: Roberto Cipolli, Roberto Oriani, Gilberto Nucida, Enrico Masarati
  • Patent number: 5324834
    Abstract: The present invention relates to novel co-oligomers containing recurring units of the formulae (Ia) and (Ib) ##STR1## which have a number average molecular weight of e.g. from 1,000 to 5,000 and a (Ia):(Ib) ratio of e.g. 1:1, and in which R.sub.1 and R.sub.5 are e.g. N-(2,2,6,6-tetramethyl-4-piperidyl)-n-butylamino, R.sub.2 is e.g. 2,2,6,6-tetramethyl-4-piperidyl, R.sub.3 is e.g. hexamethylene, R.sub.4 is e.g. hydrogen and X is e.g. a group ##STR2## These compounds are particularly suitable for stabilizing organic materials against light, heat and oxidation.
    Type: Grant
    Filed: April 16, 1993
    Date of Patent: June 28, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Valerio Borzatta, Primo Carrozza
  • Patent number: 5298076
    Abstract: A process utilizing carbazole dioxazine crude, having a specific surface area of from 2 to 20 m.sup.2 /g and an average particle size of 0.5 to 20 .mu.m, as a pigment to color high molecular weight organic materials is disclosed. The process is especially useful for producing multicolor effects and camouflage effects and for use in automotive coatings. Compositions containing the carbazole dioxazine crude and a high molecular weight organic material are also disclosed.
    Type: Grant
    Filed: March 23, 1993
    Date of Patent: March 29, 1994
    Assignee: Ciba-Geigy Corporation
    Inventor: Fridolin Babler
  • Patent number: 5268401
    Abstract: The present invention relates to novel piperidine-triazine compounds of the general formula (I) ##STR1## in which R.sub.1 is e.g. hydrogen or methyl, A is e.g. --O--, m is e.g. 3, R.sub.2 is e.g. a group --OR.sub.4 or ##STR2## R.sub.4 is e.g. C.sub.1 -C.sub.4 alkyl, 2,2,6,6-tetramethyl-4-piperidyl or 1,2,2,6,6-pentamethyl-4-piperidyl, R.sub.5 and R.sub.6 which can be identical or different are e.g. C.sub.1 -C.sub.8 alkyl, cyclohexyl, tetrahydrofurfuryl, a group ##STR3## 2,2,6,6-tetramethyl-4-piperidyl or 1,2,2,6,6-pentamethyl-4-piperidyl, or R.sub.5 can also be hydrogen, or ##STR4## is e.g. 4-morpholinyl, n is 1, 2, 3 or 4 and, if n is 1, R.sub.3 is e.g. as defined above for R.sub.2 and, if n is 2, R.sub.3 is e.g. a group --E.sub.1 --R.sub.8 --E.sub.2 -- in which E.sub.1 and E.sub.2 which can be identical or different are e.g. >N-R.sub.12, R.sub.8 is e.g. C.sub.2 -C.sub.6 alkylene, C.sub.8 -C.sub.10 alkylene interrupted by 2 or 3 oxygen atoms or methylenedicyclohexylene and R.sub.12 is e.g.
    Type: Grant
    Filed: April 23, 1991
    Date of Patent: December 7, 1993
    Assignee: Ciba-Geigy Corporation
    Inventor: Roberto Scrima
  • Patent number: 5225463
    Abstract: Self-extinguishing polymeric compositions containing: a) from 90 to 40 parts by weight of a thermoplastic polymer, or a polymer having elastomeric properties and b) 10 to 60 parts by weight of one or more 2,4,6-triamino-1,3,5-triazine compounds salified with an oxygenated acid of phosphorus, wherein at least one of the triamino substituents of the triazine compound are substituted with at least one of the following radicals ##STR1## wherein m=an integer between 2 and 8;p=an integer between 2 and 6;R.sub.8 =H; C.sub.1 -C.sub.8 alkyl; C.sub.2 -C.sub.6 alkenyl; C.sub.q H.sub.2q OR.sub.9 wherein q is an integer between 1 and 4 and R.sub.9 is hydrogen or C.sub.1 -C.sub.4 alkyl; C.sub.6 -C.sub.12 cycloalkyl or alkylcycloalkyl;R' is H; C.sub.1 -C.sub.8 alkyl; C.sub.2 -C.sub.6 alkenyl; C.sub.6 -C.sub.12 cycloalkyl or alkylcycloalkyl; C.sub.1 -C.sub.4 hydroxyalkyl, or ##STR2## is replaced by a heterocyclic radical bound to the alkyl chain through the nitrogen atom.
    Type: Grant
    Filed: April 11, 1991
    Date of Patent: July 6, 1993
    Assignee: Ministero dell'Universita e della Ricerca Scientifica e Tecnologica
    Inventors: Roberto Cipolli, Roberto Oriani, Gilberto Nucida, Mario Pirozzi, Enrico Masarati
  • Patent number: 5180762
    Abstract: The present invention relates to a stabiliser composition for polypropylene, comprising:A) one or more triazine compounds containing groups of the formula (I) in which R is hydrogen, C.sub.1 -C.sub.4 alkyl, O.cndot., OH, C.sub.1 -C.sub.8 alkoxy, C.sub.5 -C.sub.8 cycloalkoxy, C.sub.3 -C.sub.6 alkenyl, C.sub.7 -C.sub.9 phenylalkyl or C.sub.1 -C.sub.8 acyl, andB) one or more oxides and hydroxides of Mg, Ca, Ba, Zn, Al and Sn, preferably Mg and Zn.
    Type: Grant
    Filed: July 22, 1991
    Date of Patent: January 19, 1993
    Assignee: Ciba-Geigy Corporation
    Inventor: Paola Canova
  • Patent number: 5173357
    Abstract: Polyester film has a thickness of between 10 to 500 .mu.m and exhibits excellent tear strength retention against thermal history conditions. The film is prepared from a resin composition which includes 100 parts by weight of a polyester consisting essentially of alkylene terephthalate groups as the main recurring units in the polymer chain and between 0.1 to 5 parts by weight of a bisoxazoline compound incorporated thereinto. The film is usefully employed as a sterilizing bag or as a food-packaging material and can be laminated to anther sheet of film or to paper.
    Type: Grant
    Filed: May 29, 1991
    Date of Patent: December 22, 1992
    Assignee: Polyplastics Co., Ltd.
    Inventors: Toshio Nakane, Yukihiko Kageyama, Kenji Hijikata
  • Patent number: 5149723
    Abstract: This invention relates to polyacetal compositions that are stabilized against ultraviolet light and heat degradation due to the inclusion therein of a mixed hindered amine light stabilizer (HALS) system, wherein each HALS of the system contains a hindered amine that is of tertiary functionality.
    Type: Grant
    Filed: March 22, 1991
    Date of Patent: September 22, 1992
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Richard A. Hayes
  • Patent number: 5147911
    Abstract: Compounds of formula I ##STR1## wherein n is 2-4, R.sub.1 is alkyl, cycloalkyl, phenylalkyl, phenyl or a radical of formula II ##STR2## R.sub.2, R.sub.3 and R.sub.4 are independently hydrogen, alkyl, cycloalkyl, phenylalkyl or aryl, or R.sub.3 and R.sub.4 together are alkyl, R.sub.5 and R.sub.6 are independently hydrogen, alkyl, cycloalkyl or phenylalkyl, R.sub.7 is hydrogen, alkyl or a group of the formula --(CH.sub.2).sub.k COOR.sub.8, where k is 0-2 and R.sub.8 is hydrogen or alkyl, and T is an n-valent hydrocarbon radical which may be interrupted by heteroatoms, are useful stabilizers for substrates subject to the deleterious effects of oxygen, heat and/or actinic radiation.
    Type: Grant
    Filed: September 23, 1991
    Date of Patent: September 15, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Peter Hofmann, Paul A. Odorisio, Glen T. Cunkle, Don Sabrsula
  • Patent number: 5147910
    Abstract: Substituted 3H-1,3,2-oxazaphospholidines of formula I ##STR1## where R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are independently hydrogen, alkyl, cycloalkyl, phenylalkyl or aryl, n is 1 to 4 and T is an n-valent aliphatic or aromatic hydrocarbon radical are effective in stabilizing organic materials against the deleterious effects of oxygen, heat and/or actinic radiation.
    Type: Grant
    Filed: September 23, 1991
    Date of Patent: September 15, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Paul A. Odorisio, James L. Hyun, Sai P. Shum, Raymond Seltzer
  • Patent number: 5147909
    Abstract: Substituted 1,3,2-benzoxazaphospholidines of formula I ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are independently hydrogen, alkyl, cycloalkyl, phenylalkyl or aryl, n is 1 to 4, and T is an n-valent aliphatic or aromatic hydrocarbon radical are effective in stabilizing organic materials against the deleterious effects of oxygen, heat and actinic radiation.
    Type: Grant
    Filed: September 23, 1991
    Date of Patent: September 15, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Paul A. Odorisio, Stephen D. Pastor, James L. Hyun
  • Patent number: 5139885
    Abstract: A resin composition, being useful for coating on electric wire, comprises an aromatic polyester, a halogenated compound such as diol, diglycidyl and dicarboxylic acid and a di-heterocyclic compound.
    Type: Grant
    Filed: March 20, 1990
    Date of Patent: August 18, 1992
    Assignee: Polyplastics Co., Ltd.
    Inventors: Toshio Nakane, Yukihiko Kageyama, Hiroaki Konuma, Kenji Hijikata
  • Patent number: 5124379
    Abstract: Polymeric compositions endowed with high self-extinguishing characteristics hen exposed to a flame, based on thermoplastic polymers or polymers endowed with elastomeric properties, in particular olefinic polymers or copolymers, comprising:(a) from 89 to 45 parts by weight of a thermoplastic polymer, or of a polymer endowed with elastomeric properties;(b) from 8 to 30 parts by weight of one or more ammonium or amine phosphates(s) and/or phosphonate(s);(c) from 3 to 25 parts by weight of one or more compound(s) derivatives of 2,4,6-triamino-1,3,5-triazine, having the general formula (I): ##STR1## wherein at least one of the radicals from R to R.sub.5 is: ##STR2## wherein: n=an integer comprised within the range of from 2 to 8;m=an integer comprised within the range of from 2 to 6;R.sub.6 =H; (C.sub.1 -C.sub.8)-alkyl; (C.sub.2 -C.sub.6)-alkenyl; --C.sub.p H.sub.2p --O--R.sub.8, wherein p is an integer comprised within the range of from 1 to 4 and R.sub.8 is either H or a (C.sub.1 -C.sub.4)-alkyl; (C.sub.6 -C.
    Type: Grant
    Filed: July 3, 1990
    Date of Patent: June 23, 1992
    Assignee: Presidenza del Consiglio dei Ministri Ufficio del Ministro per il Coordinamento delle Iniziative per la Ricerca Scientifica e Tecnologica
    Inventors: Roberto Cipolli, Roberto Oriani, Gilberto Nucida, Mario Pirozzi, Enrico Masarati
  • Patent number: 5116891
    Abstract: Flame-resistant polymeric compositions, preferably olefinic polymers and/or copolymers, containing 8 to 45% by weight of a flameproofing system. This flameproofing system comprises at least one phosphorus component and a monomeric triazinylpiperazine. The phosphours component is a free-flowing, pulverulent, sparingly water-soluble ammonium polyphosphate, while the triazinylpiperazine used is a pulverulent bistriazinylpiperazine.
    Type: Grant
    Filed: January 18, 1991
    Date of Patent: May 26, 1992
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Werner Eberspach, Daniel Scharf, Manfred Lysek
  • Patent number: 5079284
    Abstract: A polymer such as polyester is modified with reaction with a modifier of a compound having the formula: ##STR1## in which X is halogen, Y.sub.1 and Y.sub.2 are a three- to eight-membered ring, Z is a divalent organic group and n is 1 or more.
    Type: Grant
    Filed: February 8, 1990
    Date of Patent: January 7, 1992
    Assignee: Polyplastics Co., Ltd.
    Inventors: Toshio Nakane, Yukihiko Kageyama, Kenji Hijikata
  • Patent number: 5063262
    Abstract: Costabilizers which are copolymers of oxazolines and bisoxazolines enhance the stabilizing properties of primary stabilizers such as polyoxazolines and zinc compounds in chloride-containing thermoplastic molding compositions, preferably based on polymers of vinyl chloride.
    Type: Grant
    Filed: September 26, 1990
    Date of Patent: November 5, 1991
    Assignee: Huels Aktiengesellschaft
    Inventor: Thomas Hildebrand
  • Patent number: 5049603
    Abstract: The polyester comopsition is improved in properties at low and high temperatures and is prepared by mixing 100 parts by weight of a mixture comprising (A) 60 to 99 parts by weight of a crystalline thermoplastic polyester resin and (B) 1 to 40 parts by weight of a polyester elastomer with (C) 0.01 to 5 parts by weight of a bisoxazoline compound, (D) 0.01 to 5 parts by weight of a phosphorus compound represented by the general formula: ##STR1## wherein R.sub.1 and R.sub.2 may be the same or different from each other and are each a group selected from among alkyl, substituted alkyl, aryl, substituted aryl and alkoxy groups, and (E) 0.01 to 5 parts by weight of one or more antioxidants selected from among thio ether compounds and hindered phenol compounds.
    Type: Grant
    Filed: April 20, 1990
    Date of Patent: September 17, 1991
    Assignee: Polyplastics Co., Ltd.
    Inventor: Mitsuhiro Mochizuki
  • Patent number: 5049602
    Abstract: Costabilizers which are composed of pyrroles and/or dihydropyridines and/or copolymers of oxazolines and bisoxazolines and/or polyols enhance the stabilizing effect of primary stabilizers such as polyoxazolines and zinc compounds in thermoplastic molding compositions, such as those based on polymers of vinyl chloride.
    Type: Grant
    Filed: September 26, 1990
    Date of Patent: September 17, 1991
    Assignee: Huels Aktiengesellschaft
    Inventor: Thomas Hildebrand
  • Patent number: 5039722
    Abstract: The new compounds of formula (I) ##STR1## in which R.sub.1 is e.g. hydrogen or methyl, R.sub.2 is e.g. a group --OR.sub.5 or ##STR2## in which R.sub.5 is e.g. 2,2,6,6-tetramethyl-4-piperidyl or 1,2,2,6,6-pentamethyl-4-piperidyl, R.sub.6 and R.sub.7 which are identical or different are e.g. C.sub.1 -C.sub.8 alkyl, tetrahydrofurfuryl, 2,2,6,6-tetramethyl-4-piperidyl or 1,2,2,6,6-pentamethyl-4-piperidyl, or R.sub.6 is also hydrogen, or the group ##STR3## is e.g. 4-morpholinyl, R.sub.3 and R.sub.4 which are identical or different are e.g. hydrogen, methyl, 2,2,6,6-tetramethyl-4-piperidyl or 1,2,2,6,6-pentamethyl-4-piperidyl, m and n are e.g. 3, and X is e.g. --O-- or ##STR4## where R.sub.9 is C.sub.1 -C.sub.8 alkyl, tetrahydrofurfuryl, 2,2,6,6-tetramethyl-4-piperidyl or 1,2,2,6,6-pentamethyl-4-piperidyl, are effective as light stabilizer, heat stabilizers and oxidation stabilizers for organic materials, in particular synthetic polymers.
    Type: Grant
    Filed: December 21, 1989
    Date of Patent: August 13, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Giuseppe Cantatore, Valerio Borzatta
  • Patent number: 5039723
    Abstract: A synthetic resin composition stabilized particularly against the deterioration caused by the action of heat and light, which comprises 100 parts by weight of a synthetic resin, 0.001 to 10 parts by weight of a cyclic phosphite compound represented by the following general formula (I) and 0.001 to 10 parts by weight of a hindered amine compound having a group represented by the following general formula (II) in its molecule: ##STR1## wherein R.sub.1 stands for a tert-butyl or tert-amyl group; R.sub.2 stands for a C.sub.1.about.9 alkyl group; R.sub.3 stands for a hydrogen atom or a C.sub.1.about.4 alkyl group and R.sub.4 stands for a C.sub.1.about.30 alkyl group.
    Type: Grant
    Filed: July 31, 1989
    Date of Patent: August 13, 1991
    Assignee: Adeka Argus Chemical Co., Ltd.
    Inventors: Tohru Haruna, Kazunori Nishikawa
  • Patent number: 5019611
    Abstract: There is disclosed compounds having, within their structural formulae, a trivalent moiety: ##STR1## which exhibit antiozonant activity when added to rubber compositions at antiozonant effective levels and which exhibit synergistic antiozonant activity when used with conventional antiozonants in rubber compositions. There is also disclosed novel compounds which can be used as antiozonants.
    Type: Grant
    Filed: January 15, 1987
    Date of Patent: May 28, 1991
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Kevin L. Rollick, James G. Gillick, Joseph A. Kuczkowski
  • Patent number: 4997938
    Abstract: The novel compounds of the formula (I) ##STR1## in which R.sub.1 is di(C.sub.1 -C.sub.4 -alkyl)amino, C.sub.1 -C.sub.4 -alkoxy, a 5-membered to 7-membered nitrogen containing heterocyclic group with the nitrogen atom bonded to the triazine ring, or a group of the formula (II), ##STR2## R.sub.2 and R.sub.4 which are identical or different are C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, benzyl or 1,2,2,6,6-pentamethyl-4-piperidyl, n is 2 or 3 and, if n is 2, R.sub.3 is a group ##STR3## with R.sub.5 and R.sub.7, which are identical or different, being hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, benzyl or 1,2,2,6,6-pentamethyl-4-piperidyl and R.sub.6 being C.sub.2 -C.sub.12 -alkylene, cyclohexylene, cyclohexylenedimethylene or methylenedicyclohexylene, or R.sub.3 is the divalent radical of a 6-membered to 7-membered heterocyclic compound with two nitrogen atoms which are each bonded to a triazine ring, or, if n is 3, R.sub.3 is a group ##STR4## with R.sub.8 and R.sub.
    Type: Grant
    Filed: December 8, 1989
    Date of Patent: March 5, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Giuseppe Cantatore, Valerio Borzatta, Franca Masina
  • Patent number: 4992493
    Abstract: The compounds of the formula (I) ##STR1## in which R.sub.1 is C.sub.1 -C.sub.8 -alkyloxy, allyloxy, allylamino, di(C.sub.1 -C.sub.4 -alkyl)-amino, diallylamino, a 5-membered to 7-membered nitrogen containing heterocyclic group with the nitrogen atom linked to the triazine ring, or a group of the formula (II), ##STR2## R.sub.2 is hydrogen, O, OH, NO, CH.sub.2 CN, C.sub.1 -C.sub.8 -alkyl, allyl, benzyl, C.sub.1 -C.sub.8 -acyl, C.sub.1 -C.sub.18 -alkyloxy, C.sub.5 -C.sub.12 -cycloalkyloxy or OH-monosubstituted C.sub.2 -C.sub.4 -alkyl, R.sub.3 and R.sub.5 independently are hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl, C.sub.7 -C.sub.9 -phenylalkyl, tetrahydrofurfuryl, C.sub.2 -C.sub.4 -alkyl monosubstituted by OH, by C.sub.1 -C.sub.4 -alkyloxy or by di(C.sub.1 -C.sub.4 -alkyl)amino, or a group of the formula (III) ##STR3## with R.sub.2 as defined above, R.sub.4 is hydrogen, C.sub.1 -C.sub.
    Type: Grant
    Filed: September 6, 1989
    Date of Patent: February 12, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Giuseppe Cantatore, Valerio Borzatta, Franca Masina
  • Patent number: 4966931
    Abstract: The present invention disclosed herein is connected with a polypropylene resin composition giving off no corrosive and poisonous gases, having excellent moldability, providing molded articles with excellent mechanical strength and high flame retardance. The composition of the present invention is composed of predetermined amounts of a polypropylene resin, a polyethylene resin, polyammonium phosphate or polyammonium phosphate modified by melamine resin and a 1,3,5-triazine derivative. This composition may additionally contain a predetermined amount of one or more of specific thiophosphites and may further contain a predetermined amount of an olefinic synthetic rubber or elastomer and a crosslinking agent.
    Type: Grant
    Filed: January 19, 1989
    Date of Patent: October 30, 1990
    Assignee: Chisso Corporation
    Inventors: Shinichi Akitaya, Toru Fukazawa, Yutaka Nozokido, Nobuchika Tabata
  • Patent number: 4954541
    Abstract: A resin composition, being useful for coating on electric wire, comprises an aromatic polyester, a halogenated compound such as diol, diglycidyl and dicarboxylic acid and a di-heterocyclic compound.
    Type: Grant
    Filed: November 15, 1988
    Date of Patent: September 4, 1990
    Assignee: Polyplastics Co., Ltd.
    Inventors: Toshio Nakane, Yukihiko Kageyama, Hiroaki Konuma, Kenji Hijikata
  • Patent number: 4918122
    Abstract: The invention provides a composition comprising a resin processable at temperatures upto 160.degree. C. having incorporated therein a flame retardant amount of a salt formed by reaction between dimethyl methyl phosphonate, monomethyl methyl phosphonate or methyl phosphonic acid, and a compound of the general formula (I) ##STR1## in which X is 0 or S; R.sup.1 is H, alkyl with 1 to 4 carbon atoms, alkenyl of up to 4 carbon atoms, CN, CONH.sub.2 or NH.sub.2, R.sup.2 is H, alkyl with 1 to 4 carbon atoms or alkenyl of up to 4 carbon atoms or R.sup.1 and R.sup.2 together with the nitrogen atom to which they are attached form a heterocyclic ring of up to 6 carbon atoms which may optionally contain another hetero atom and R is H, an alkyl group with 1 to 8 carbon atoms, an aryl group with 6 to 10 carbon atoms, a cycloalkyl group with 5 to 12 carbon atoms or a heterocyclic group with up to 9 ring carbon atoms, or, together with R.sup.1 forms an alkylene chain of 3 to 10 carbon atoms, or R is a group NHR.sup.
    Type: Grant
    Filed: July 15, 1987
    Date of Patent: April 17, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Richard J. Dellar, Norman Richardson, deceased, Brian G. Clubley
  • Patent number: 4906678
    Abstract: Compounds of the formula (I) ##STR1## wherein R.sub.1 and R.sub.5 are independently hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl or a group of the formula (II), ##STR2## R.sub.2, R.sub.3 and R.sub.4 are independently C.sub.2 -C.sub.12 -alkylene, R is a group of the formula (III) ##STR3## wherein R.sub.6 is C.sub.2 -C.sub.8 -dialkylamino, C.sub.1 -C.sub.4 -alkoxy, a 5-membered to 7-membered heterocyclic group containing a nitrogen atom which is attached to the triazine residue or a group of the formula (IV), ##STR4## R.sub.7 and R.sub.8 are independently C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, benzyl or a group of the formula (II), subject to the proviso that both, R.sub.1 and R.sub.5 are different from hydrogen, if R is a group ##STR5## are useful as light stabilizers, heat stabilizers and/or oxidation stabilizers for organic materials, in particular synthetic polymers.
    Type: Grant
    Filed: October 31, 1988
    Date of Patent: March 6, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Giuseppe Cantatore, Francois Gugumus
  • Patent number: 4889881
    Abstract: An ethylene-.alpha.-olefin vulcanized rubber composition with excellent weather resistance and high transparency which is formed by vulcanizing with an organic peroxide an unvulcanized rubber composition comprising an ethylene-.alpha.-olefin rubber containing no metal oxide nor metal carbonate.
    Type: Grant
    Filed: August 9, 1988
    Date of Patent: December 26, 1989
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Hiroyoshi Takao, Yoshio Tanimoto, Kiyosi Ikeda
  • Patent number: 4883870
    Abstract: The compounds of the formula (I) ##STR1## in which R.sub.1 is C.sub.1 -C.sub.8 -alkyloxy, allyloxy, allylamino, di(C.sub.1 -C.sub.4 -alkyl)amino, diallylamino, a 5-membered to 7-membered nitrogen containing heterocyclic group with the nitrogen atom linked to the triazine ring, or a group of the formula (II), ##STR2## R.sub.2 is hydrogen, O.sup.., OH, NO, CH.sub.2 CN, C.sub.1 -C.sub.8 -alkyl, allyl, benzyl, C.sub.1 -C.sub.8 -acyl, C.sub.1 -C.sub.18 -alkyloxy, C.sub.5 -C.sub.12 -cycloalkyloxy or OH-monosubstituted C.sub.2 -C.sub.4 -alkyl, R.sub.3 and R.sub.5 independently are hydrogen, C.sub.1 -C.sub.12 -alkyl,* monosubstituted by OH, by C.sub.1 -C.sub.4 -alkyloxy or by di(C.sub.1 -C.sub.4 -alkyl)amino, or a group of the formula (III) ##STR3## with R.sub.2 as defined above, R.sub.4 is hydrogen, C.sub.1 -C.sub.12 -alkyl or cyclohexyl and n is an integer from 2 to 6, are useful as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials, in particular synthetic polymers. * C.sub.5 -C.
    Type: Grant
    Filed: July 11, 1988
    Date of Patent: November 28, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Giuseppe Cantatore, Valerio Borzatta, Franca Masina
  • Patent number: 4863981
    Abstract: The present invention relates to a stabilizer system containing two high-molecular polyalkylpiperidines, the use thereof for stabilizing organic material and the organic material which has been protected by means of the stabilizer system mentioned against degradation induced by light.
    Type: Grant
    Filed: June 19, 1987
    Date of Patent: September 5, 1989
    Assignee: Ciba-Geigy Corporation
    Inventor: Francois Gugumus
  • Patent number: 4812501
    Abstract: 1,3,2-oxazaphospholidine derivatives of the formula ##STR1## are effective in stabilizing organic materials against oxidative, thermal and actinic degradation, said derivatives being particularly effective as color improvers and process stabilizers in organic materials containing phenolic antioxidants.
    Type: Grant
    Filed: March 16, 1988
    Date of Patent: March 14, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Paul A. Odorisio, Stephen D. Pastor, James L. Hyun