Two Or More Nitrogen Rings Patents (Class 524/97)
  • Patent number: 4812499
    Abstract: Compositions of thermoplastic polymers comprising, in mixture, a thermoplastic polymer and a mixture of self-extinguishability-conferring additives, formed by:ammonium phosphate or ammonium polyphosphate: ##STR1## (wherein p is preferably equal to or greater than 50); phosphorus-containing compound definable by means of the general formula: ##STR2## (wherein R.sub.1, R.sub.2 and R.sub.3 have the meaning as indicated in the disclosure).
    Type: Grant
    Filed: March 20, 1986
    Date of Patent: March 14, 1989
    Assignee: Enichem Sintesi S.p.A.
    Inventors: Gioacchino Cipriani, Gianluigi Landoni
  • Patent number: 4797436
    Abstract: The present invention relates to oligomeric tetraalkylpiperidine light stabilizers for polymers, to the preparation thereof from known polyalkyldiazaspirodecanes and epoxides, and to the use thereof for stabilizing polymers against the damaging effect of light, heat and oxygen.
    Type: Grant
    Filed: November 24, 1986
    Date of Patent: January 10, 1989
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Josef Ertl, Helmut Korbanka
  • Patent number: 4771091
    Abstract: Novel diazaspirodecanes of the general formula ##STR1## are prepared from known diazaspirodecane compounds and epoxy compounds or by reacting diazaspirodecane-substituted epoxy compounds with alcohols or amines and are excellent light stabilizers for synthetic polymers.
    Type: Grant
    Filed: November 24, 1986
    Date of Patent: September 13, 1988
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Josef Ertl
  • Patent number: 4757102
    Abstract: Various substituted aminoxy alkylamine derivatives are effective in stabilizing organic materials against oxidative, thermal and actinic degradation, said derivatives being particularly effective as color improvers and process stabilizers in organic materials containing phenolic antioxidants and/or metal salts of fatty acids and/or hindered amine light stabilizers and/or organic phosphorus compounds; and certain of said derivatives as new compounds.
    Type: Grant
    Filed: May 12, 1986
    Date of Patent: July 12, 1988
    Assignee: Ciba-Geigy Corporation
    Inventors: Ramanathan Ravichandran, Stephen D. Pastor, Thomas E. Snead
  • Patent number: 4703073
    Abstract: Alkylated N,N-dibenzylhydroxylamine derivatives are effective in stabilizing polyolefin compositions containing a stabilizer or mixture of stabilizers selected from the group consisting of the phenolic antioxidants, the hindered amine light stabilizers, the alkylated hydroxybenzoate light stabilizers, the ultraviolet light absorbers, the organic phosphorus compounds, the alkaline metal salts of fatty acids and the thiosyner-gists, against degradation upon high temperature extrusion, exposure to the combustion products of natural gas, gamma irradiation or upon storage for extended periods.
    Type: Grant
    Filed: September 15, 1986
    Date of Patent: October 27, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Roland A. E. Winter, Ramanathan Ravichandran, Raymond Seltzer
  • Patent number: 4692486
    Abstract: Low-molecular and high-molecular polyalkylpiperidines are suitable as a synergistic mixture for stabilizing organic material, in particular organic polymers. The compounds are substances known per se. Thus, for example, the mixture of ##STR1## is distinguished by a pronounced synergism.
    Type: Grant
    Filed: July 21, 1986
    Date of Patent: September 8, 1987
    Assignee: Ciba-Geigy Corporation
    Inventor: Francois Gugumus
  • Patent number: 4639478
    Abstract: The present invention relates to 2,3,2',3'-bis-morpholine derivatives corresponding to the formula ##STR1## The present invention also relates to a process for the preparation of these derivatives and to their use as hydrolysis protective agents for synthetic polymers containing ester groups and/or carbonate groups. Preferred synthetic polymers are polyurethanes.
    Type: Grant
    Filed: April 29, 1986
    Date of Patent: January 27, 1987
    Assignee: Bayer Aktiengesellschaft
    Inventors: Peter Haas, James M. Barnes, Wilhelm Goyert
  • Patent number: 4618634
    Abstract: Novel compounds containing piperidine groups, of the general formula ##STR1## in which R.sub.1 is hydrogen, O--, cyanomethyl, C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.12 -alkenyl or -alkynyl, C.sub.7 -C.sub.12 -aralkyl or C.sub.1 -C.sub.12 -acyl, m is an integer from 1 to 12, n is an integer from 1 to 3 and A is an amine radical, are suitable as light stabilizers, heat stabilizers and oxidation stabilizers for synthetic polymers. Processes for their preparation are also described.
    Type: Grant
    Filed: February 27, 1985
    Date of Patent: October 21, 1986
    Assignee: Ciba-Geigy S.p.A.
    Inventors: Giuseppe Cantatore, Valerio Borzatta
  • Patent number: 4613636
    Abstract: A peroxide-curable fluoroelastomer composition which can be readily removed from a mold cavity without tearing which comprises a fluoroelastomer whose interpolymerized units consist essentially of units of tetrafluoroethylene, units of perfluoroalkyl perfluorovinyl ether, units of a bromine-containing olefin and, optionally, units of ethylene, and from about 0.05-2 parts per 100 parts fluoroelastomer of an N,N,N',N'-tetrasubstituted 1,8-diaminonaphthalene having the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are independently alkyl groups of 1-6 carbon atoms, phenyl or benzyl, R.sub.1 and R.sub.2 and/or R.sub.3 and R.sub.4 can be joined to form a 5- or 6-membered heterocyclic ring in which a carbon atom can be replaced by an oxygen or a sulfur atom, R.sub.1 and R.sub.3 and/or R.sub.2 and R.sub.
    Type: Grant
    Filed: July 12, 1985
    Date of Patent: September 23, 1986
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Leo Ojakaar
  • Patent number: 4602052
    Abstract: A rubber composition containing carbon black as a reinforcing filler and a quaternary ammonium salt as a coupling agent and a method of making it are disclosed.
    Type: Grant
    Filed: September 17, 1984
    Date of Patent: July 22, 1986
    Assignee: Amoco Corporation
    Inventors: Kenneth E. Weber, Dirk Oberlin
  • Patent number: 4598105
    Abstract: A rubber composition containing carbon black and a second particulate filler of kaolin, metakaolin, talc, pyrophyllite coal, coke, graphite or metal carbonate filler and a method of making it are disclosed.
    Type: Grant
    Filed: September 17, 1984
    Date of Patent: July 1, 1986
    Assignee: Amoco Corporation
    Inventors: Kenneth E. Weber, Dirk Oberlin
  • Patent number: 4555537
    Abstract: Compounds of the formula: ##STR1## are disclosed as light stabilizers for polymers normally subject to degradation by light.
    Type: Grant
    Filed: August 8, 1983
    Date of Patent: November 26, 1985
    Assignee: American Cyanamid Company
    Inventors: Richard Spector, Donald R. Maulding
  • Patent number: 4547537
    Abstract: Compounds of the formula L-T, where L is an unsubstituted or substituted tetrahydro-1,4-oxazine-2-one group and T is a substituted 4-piperidinyl hindered amine moiety, are effective light stabilizers for polyolefins and other organic polymers.
    Type: Grant
    Filed: August 2, 1984
    Date of Patent: October 15, 1985
    Assignee: Ciba-Geigy Corporation
    Inventors: Roger F. Malherbe, Michael H. Ackerman
  • Patent number: 4522735
    Abstract: Amines are reacted with phosphorous trichloride to form N-dichlorophosphinoamines that are then reacted with a bisphenol in about equimolar amounts to provide polyphosphoramidite oligomers. The polyphosphoramidite oligomers are effective as stabilizers for polymers such as polyolefins, and form even more efficient stabilizer combinations with hydroxyphenylalkyleneyl isocyanurates.
    Type: Grant
    Filed: June 17, 1983
    Date of Patent: June 11, 1985
    Assignee: The B. F. Goodrich Company
    Inventor: Dwight W. Chasar
  • Patent number: 4500662
    Abstract: Polysubstituted .alpha.-aminoacetamides of the formula ##STR1## wherein R.sup.1 is tert-alkyl; R.sup.4 is alkyl, phenyl, substituted phenyl, cycloalkyl, piperidinyl, tetraalkylpiperidinyl or an alkylene (.alpha.-aminoacetamide). These compounds are prepared by first reacting an .alpha.-haloacetamide with a base to form an .alpha.-lactam intermediate which in turn is reacted with a primary amine. The compounds are useful as stabilizers of polymeric materials against ultraviolet light degradation.
    Type: Grant
    Filed: September 29, 1982
    Date of Patent: February 19, 1985
    Assignee: The B. F. Goodrich Company
    Inventor: John T. Lai
  • Patent number: 4499219
    Abstract: Moulding compositions based on thermoplastic polyesters can be effectively protected against thermal degradation, if they contain, as a first stabilizer, a polyepoxide compound and, as a second stabilizer, a bisoxazoline or a dicarboxylic acid imide or amide.
    Type: Grant
    Filed: November 21, 1983
    Date of Patent: February 12, 1985
    Assignee: Ciba-Geigy Corporation
    Inventors: Lothar Buxbaum, Franz Breitenfellner, Thomas Kainmuller
  • Patent number: 4491643
    Abstract: Bis(2,2,6,6-tetramethylpiperidyl-1,3,5-triazinyl)-spirodiamines and spiroglycol ethers are provided, having the formula: ##STR1##
    Type: Grant
    Filed: January 9, 1984
    Date of Patent: January 1, 1985
    Assignee: Adeka Argus Chemical Co., Ltd.
    Inventors: Motonobu Minagawa, Yutaka Nakahara, Toshihiro Shibata, Etsuo Tobita
  • Patent number: 4461861
    Abstract: Compounds of the formula: ##STR1## wherein at least one of the groups contains a 4-piperidinyl moiety are disclosed as light stabilizers for polymers.
    Type: Grant
    Filed: June 6, 1983
    Date of Patent: July 24, 1984
    Assignee: American Cyanamid Company
    Inventors: Frank F. Loffelman, Thomas E. Brady
  • Patent number: 4433085
    Abstract: A triazolidine-3,5-dione/formaldehyde/amine condensate is disclosed of the formula ##STR1## in which wherein the terms R.sup.1, R.sup.2 and R.sup.5 are defined hereinafter in the specificationa process for the preparation of such condensate by reaction of a triazolidine-3,5-dione with formaldehyde and a suitable nitrogen compound and the use of the condensate as a flame-proofing agent for thermoplastics, especially polyamide and as an auxiliary for modifying polymeric substances.
    Type: Grant
    Filed: June 29, 1981
    Date of Patent: February 21, 1984
    Assignee: Bayer Aktiengesellschaft
    Inventors: Ludwig Rottmaier, Rudolf Merten
  • Patent number: 4417013
    Abstract: A solid pigment composition comprises an intimate mixture of a pigment and a copolymer of an alkyl or cycloalkyl methacrylate ester and a lesser amount of an aminoalkyl methacrylate ester. The compositions are compatible with a wide range of substrates such as paints, printing inks and bulk polymers.
    Type: Grant
    Filed: January 18, 1982
    Date of Patent: November 22, 1983
    Assignee: Sandoz Ltd.
    Inventor: Johann Schuster
  • Patent number: 4386177
    Abstract: Oligomers prepared from alkoxycarbonylalkyleneamino halotriazines and diamines are useful as light stabilizers for polymers subject to ultraviolet radiation degradation.
    Type: Grant
    Filed: July 20, 1981
    Date of Patent: May 31, 1983
    Assignee: American Cyanamid Company
    Inventor: Frank F. Loffelman
  • Patent number: 4367304
    Abstract: Compounds of the formula I, II, III or IV ##STR1## wherein X is halogen, OH, --OR.sup.1, --OOCR.sup.2, --OOC--R.sup.4 --COOR.sup.3 or --N(R.sup.5)(R.sup.6), or the two X groups together form a group --O--R.sup.9 --O-- or --OOC--R.sup.9 --COO--, Y has one of the meanings given for X, or it is --NHR.sup.5, --NHNH.sub.2 or --NHNH-phenyl, Z has one of the meanings given for X, or is --SR, and R, R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.9 and R' are organic radicals having the meanings defined hereinbelow, are thermal stabilizers for chlorine-containing thermoplastics particularly for PVC. Their effect can be further intensified by the addition of co-stabilizers.
    Type: Grant
    Filed: November 4, 1980
    Date of Patent: January 4, 1983
    Assignee: Ciba-Geigy Corporation
    Inventors: Klaus-Peter Michaelis, Wolfgang Wehner, Holger Andreas, Horst Muller
  • Patent number: 4331586
    Abstract: Oligomers of the formula ##STR1## which contain at least one piperidinyl moiety in the repeating unit are useful as light stabilizers for polymers.
    Type: Grant
    Filed: July 20, 1981
    Date of Patent: May 25, 1982
    Assignee: American Cyanamid Company
    Inventor: William B. Hardy