Solid Polymer From Ethylenic Reactants Only Is Derived From Reactant Containing Halogen Atom Patents (Class 525/104)
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Patent number: 11066570Abstract: The present disclosure refers to an aqueous stain resistant coating composition, comprising, one or more aqueous dispersions of self-crosslinkable polymeric particles; and one or more particulate solids, wherein the polymeric particles have a Tg of 10° C. or less; and wherein the particulate solids comprise a combination of sheet-like particulate solids and sphere-like particulate solids in a weight ratio of 1:1 or more; and wherein the coating composition has a pigment volume concentration of 45% or more; and the coating composition is substantially free of volatile organic compounds.Type: GrantFiled: April 25, 2016Date of Patent: July 20, 2021Inventors: Ronghai Hui, Gang Duan, Rong Xiong, Stephen M. Korenkiewicz, Hui Kou
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Patent number: 11059971Abstract: Provided are a composition, a cured polymer material formed from said composition, a method for forming a thermally conductive material on an article and an article having a thermally conductive material. Said thermally conductive material can be formed on an electronic device, and can be peeled off from said electronic device.Type: GrantFiled: September 29, 2017Date of Patent: July 13, 2021Assignee: Dow Silicones CorporationInventors: Zhihua Liu, Peng Wei, Hexiang Yan, Yi Zhao, Qi Chen, Junmin Zhu
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Patent number: 10889697Abstract: The present invention relates to a polyethylene composition comprising, a base resin (A) comprising a copolymer of ethylene and at least one comonomer selected from alpha-olefins having from three to twelve carbon atoms, wherein the ethylene copolymer comprises a low molecular weight component (A-1) and a high molecular weight component (A-2) with the low molecular weight component (A-1) having a lower weight average molecular weight than the high molecular weight component (A-2), (B) carbon black in an amount of 1.0 to 10 wt % based on the total amount of the polyethylene composition, and (C) optional further additives other than carbon black; wherein the low molecular weight component (A-1) has a melt flow rate MFR2 (190° C., 2.Type: GrantFiled: March 22, 2016Date of Patent: January 12, 2021Assignees: ABU DHABI POLYMERS CO. LTD (BOROUGE) L.L.C., BOREALIS AGInventors: Antti Tynys, Mohana Murali Adhyatma Bhattar, Jarmo Harjuntausta
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Patent number: 10336925Abstract: Semi-crystalline polyester polyols and their use in reactive hot-melt adhesives are disclosed. The polyols comprise recurring units of a C2-C10 aliphatic diol, a C8-C24 aliphatic dicarboxylic acid, and 1 to 20 wt. % of an aromatic dicarboxylic acid source, a polycarbonate, or a combination thereof. The polyols have a hydroxyl number within the range of 14 to 112 mg KOH/g. Reactive hot-melt adhesives from the polyols and composite structures produced using the adhesives are also disclosed. A minor proportion of aromatic dicarboxylic acid, polycarbonate content in the polyester polyol surprisingly improves the properties of reactive hot-melt adhesives when compared with a commercial hot-melt adhesive or an adhesive formulated using an all-aliphatic polyester polyol. The adhesives are useful for bonding a wide variety of substrates, including paper, wood, glass, ceramics, plastics, and metals.Type: GrantFiled: September 6, 2016Date of Patent: July 2, 2019Assignee: RESINATE MATERIALS GROUP, INC.Inventors: Woo-Sung Bae, Kevin Rogers, Michael Christy, Rick Tabor
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Patent number: 10295089Abstract: A multilayer flexible tube includes an inner layer including a melt processable fluoropolymer, wherein the fluoropolymer includes a copolymer of a poly vinylidene fluoride (PVDF) and a hexafluoropropylene (HFP); and an outer layer including a melt processable polymer having a shore hardness less than a shore hardness of the inner layer, wherein the multilayer flexible tube has a maximum storage modulus of at least 300 MegaPascal (MPa) at a temperature of about ?10° C.Type: GrantFiled: April 28, 2017Date of Patent: May 21, 2019Assignee: SAINT-GOBAIN PERFORMANCE PLASTICS CORPORATIONInventors: Wayne Edward Garver, James Ludlow, Gerald H. Ling, Charles S. Golub, Kathryn J. Morris, Mark F. Colton
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Patent number: 9982812Abstract: A multilayer flexible tube includes an inner layer including a melt processable fluoropolymer, wherein the fluoropolymer includes a copolymer of a poly vinylidene fluoride (PVDF) and a hexafluoropropylene (HFP); and an outer layer including a melt processable polymer having a shore hardness less than a shore hardness of the inner layer. Further provided is a method of making the multilayer flexible tube.Type: GrantFiled: March 10, 2015Date of Patent: May 29, 2018Assignee: SAINT-GOBAIN PERFORMANCE PLASTICS CORPORATIONInventors: Wayne Edward Garver, Gerald H. Ling, Charles S. Golub, Kathryn J. Morris, Mark F. Colton
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Patent number: 9587063Abstract: A method of preparing an amiphiphilic co-network comprising preparing a molecularly-bimodal crosslinkable amphiphilic graft by polymerizing a dihydrocarbylacrylamide monomer in the presence of a first asymmetric-telechelic polydihydrocarbylsiloxane monomer mixture and a second asymmetric-telechelic polydihydrocarbylsiloxane monomer mixture where the molar mass ratio between average molar mass of the first asymmetric-telechelic monomer mixture polydihydrocarbylsiloxane and average molar mass of the second asymmetric-telechelic monomer mixture polydihydrocarbylsiloxane is between 1:2 and 1:20; and crosslinking the molecularly-bimodal crosslinkable amphiphilic graft with a siloxane compound that includes at least two Si—H bonds.Type: GrantFiled: June 5, 2014Date of Patent: March 7, 2017Assignee: The University of AkronInventors: Mukerrem Cakmak, Turgut Nugay, Nihan Nugay, Joseph Kennedy
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Patent number: 9394411Abstract: Disclosed herein is a block copolymer comprising a first block derived from a vinyl aromatic monomer; where the vinyl aromatic monomer has at least one alkyl substitution on an aromatic ring; a second block derived from a siloxane monomer; where a chi parameter that measures interactions between the first block and the second block is 0.03 to 0.18 at a temperature of 200° C. Disclosed herein is a method comprising polymerizing a vinyl aromatic monomer to form a first block; and polymerizing a second block onto the first block to form a block copolymer; where the second block is derived by polymerizing a siloxane monomer; and where the block copolymer has a chi parameter of 0.03 to 0.18 at a temperature of 200° C.; where the chi parameter is a measure of interactions between the first block and the second block of the copolymer.Type: GrantFiled: December 23, 2014Date of Patent: July 19, 2016Assignees: DOW GLOBAL TECHNOLOGIES LLC, ROHM AND HAAS ELECTRONIC MATERIALS LLCInventors: Shih-Wei Chang, Jong Keun Park, John W. Kramer, Erin B. Vogel, Phillip D. Hustad, Peter Trefonas, III
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Patent number: 9289371Abstract: An emulsion is obtained from emulsion polymerization of a mixture of (a) 1-50 wt % of a triorganosiloxysilicic acid and (b) 50-99 wt % of an ethylenically unsaturated monomer in the presence of (c) an emulsion stabilizer which is an anionic surfactant, nonionic surfactant or polyvinyl alcohol. The emulsion is used to formulate a cosmetic composition capable of forming, on drying, a film which has water resistance, oil resistance and toughness and is thus effective for preventing makeup deterioration. The cosmetic composition containing the emulsion is useful as eyeliner, mascara, eyebrow color, liquid foundation or milky lotion.Type: GrantFiled: August 25, 2014Date of Patent: March 22, 2016Assignee: NISSAN CHEMICAL INDUSTRY CO., LTD.Inventors: Yukihiro Masuda, Kentaro Watanabe, Akira Yamamoto
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Patent number: 9243166Abstract: Provided are a curable composition and its use. The curable composition has excellent processability, workability and adhesiveness, exhibits excellent light extraction efficiency, crack resistance, hardness, thermal and shock resistance and adhesiveness after curing, has long-lasting durability and reliability even under harsh conditions, and does not cause whitening or surface stickiness. The curable composition can be used as an encapsulant or adhesive material for an optical semiconductor such as an LED.Type: GrantFiled: January 27, 2015Date of Patent: January 26, 2016Assignee: LG CHEM, LTD.Inventors: Min Jin Ko, Jae Ho Jung, Bum Gyu Choi, Dae Ho Kang, Min Kyoun Kim, Byung Kyu Cho
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Patent number: 9187678Abstract: Described herein are release layers formed via solventless extrusion. The release layers include a polyolefin and an alkyl dimethicone. The release layers exhibit tailorable release properties from pressure-sensitive adhesives. The release layers are simple to make and require no post-treatment in order to impart the observed release properties. The release layers are adaptable to multilayer extrusion, blown film formation, and cast film formation techniques.Type: GrantFiled: July 29, 2013Date of Patent: November 17, 2015Assignee: 3M Innovative Properties CompanyInventors: Larry D. Boardman, Jeffrey O. Emslander, Bryan C. Feisel, David S. Hays, David J. Kinning, Richard L. Peloquin, David J. Yarusso
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Patent number: 9018306Abstract: There is provided a curable fluorine-containing polymer composition which is rapidly cured at relatively low temperature by hydrosilylation reaction to form a coating film having not only high hardness and flexibility but also water- and oil-repellency, thereby giving stain-proofing effect for a long period of time, especially maintaining property of removing and wiping-off stain.Type: GrantFiled: June 9, 2008Date of Patent: April 28, 2015Assignees: Dow Corning Corporation, Daikin Industries, Ltd.Inventors: Masayuki Hayashi, Eiji Kitaura, Peter Cheshire Hupfield, Katsuhiko Imoto, Masaru Nagato
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Publication number: 20150064909Abstract: Provided are: a resin mold material and a resin replica mold material composition for imprinting having a superior mold releasability; a resin mold and a resin replica mold resulting from containing the material composition; and a method for producing them. The resin mold material or resin replica mold material composition for imprinting contains 100 parts by weight of a mold resin or replica mold resin for imprinting and 0.1 to 10 parts by weight of a curable fluoropolymer (A). Preferably, the fluoropolymer (A) has a weight-average molecular weight of 3,000 to 20,000 and results from including as repeating units (a1) an ?-position substituted acrylate having a fluoroalkyl group having 4 to 6 carbon atoms and (a2) and 5 to 120 parts by weight of a high-softening-point monomer exhibiting a glass transition point or softening point of at least 50° C. in the homopolymer state.Type: ApplicationFiled: April 9, 2013Publication date: March 5, 2015Applicant: DAIKIN INDUSTRIES, LTD.Inventors: Tsuneo Yamashita, Masamichi Morita, Yoshiko Kuwajima
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Publication number: 20140220345Abstract: Disclosed is a method of forming a composite micropowder, including mixing 100 parts by weight of fluorine-containing polymer, 10 to 140 parts by weight of silane, catalyst, and water, such that the silane is in-situ polymerized in the fluorine-containing polymer to form a polysiloxane, and the fluorine-containing polymer and the polysiloxane form a composite. The composite is dried, and then physically crushed to form composite micropowder. The total weight of the fluorine-containing polymer and the silane and the weight of the catalyst have a ratio of 100:1 to 100:0.0001. The silane and the water have a molar ratio of 1:0.5 to 1:3. The composite micropowder has a diameter of 0.1 ?m to 15 ?m. The fluorine-containing polymer and the polysiloxane in the composite micropowder have a weight ratio of 95:5 to 60:40.Type: ApplicationFiled: August 29, 2013Publication date: August 7, 2014Applicant: Grand Tek Advanced Material Science Co., Ltd.Inventors: Hseuh-Tso LIN, Shin-Hung CHEN, Dick ZHONG
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Patent number: 8785559Abstract: Methods for fabricating a random graft PS-r-PEO copolymer and its use as a neutral wetting layer in the fabrication of sublithographic, nanoscale arrays of elements including openings and linear microchannels utilizing self-assembling block copolymers, and films and devices formed from these methods are provided. In some embodiments, the films can be used as a template or mask to etch openings in an underlying material layer.Type: GrantFiled: July 3, 2013Date of Patent: July 22, 2014Assignee: Micron Technology, Inc.Inventor: Dan B. Millward
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Patent number: 8785555Abstract: The present invention provides a process for producing an electret which has high thermal stability of retained electric charge and which has excellent charge retention performance. This is accomplished by a process for producing an electret which includes a step of thermally treating a fluorinated polymer and a silane coupling agent, where the fluorinated polymer has an alicyclic structure in its main chain and has a carboxy group or an alkoxycarbonyl group as its terminal group; the silane coupling agent has an amino group; and the weight average molecular weight of the fluorinated polymer is at least 200,000.Type: GrantFiled: July 5, 2011Date of Patent: July 22, 2014Assignee: Asahi Glass Company, LimitedInventor: Kimiaki Kashiwagi
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Patent number: 8710129Abstract: In a polycarbonate resin composition containing a polycarbonate resin and a polycarbosilane compound, the use of the polycarbosilane compound modifies the surface properties of the polycarbonate resin composition without adversely affecting the intrinsic characteristics of the polycarbonate resin, such as transparency, heat resistance, and mechanical properties, e.g., impact resistance. A polycarbonate resin composition containing 100 parts by mass of a polycarbonate resin, 0.001 to 1 part by mass of a metal salt compound, and 0.005 to 5 parts by mass of a polycarbosilane compound has significantly improved flame resistance and high transparency and causes markedly reduced outgassing and mold fouling, without losing impact resistance and heat resistance.Type: GrantFiled: March 15, 2013Date of Patent: April 29, 2014Assignee: Mitsubishi Engineering-Plastics CorporationInventor: Toshiki Monden
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Publication number: 20140104674Abstract: A display medium adapted for an electrophoretic display is provided. The display medium includes at least one particle and a random copolymer bonded with the particle, wherein the random copolymer has a structural unit originated from a first monomer and a second monomer. The first monomer is selected from at least one or a combination of a group of specific compounds consisting of 2-ethylhexyl acrylate, lauryl methacrylate and octadecyl acrylate etc. and the second monomer is selected from at least one kind of a group of specific compounds composed of 2,2,2 trifluoroethyl acrylate, 2,2,3,3 tetrafluoropropyl methacrylate and 1,1,1,3,3,3-hexafluoroisopropyl acrylate. A method of manufacturing the display medium and an electrophoretic display with the display medium are also provided.Type: ApplicationFiled: October 15, 2012Publication date: April 17, 2014Applicant: SIPIX TECHNOLOGY INC.Inventors: Wei-Ho Ting, Ning-Wei Jan, Hui Du, Hong-Mei Zang, Tyau-Jeen Lin, Chun-Hsien Chen
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Publication number: 20140018463Abstract: A surface-modified polymer is described, comprising a polymeric material and a self-assembling monolayer covalently bound thereto. The monolayer comprises monoethylene glycolated-OH (MEG-OH); 2-(3-trichlorosilyl-propyloxy)-ethyl-trifluoroacetate (7-OEG or MEG-TFA); 2,2,2-trifluoroethyl-13-trichlorosilyl-tridecanoate (TTTA); OEGylated TTTA (OEG-TTTA); S-(2-(2-(2-(3-trichlorosilyl-propyloxy)-ethoxy)-ethoxy)-ethyl)-benzenethiosulfonate (OEG-TUBTS); or a combination thereof. Methods are described for forming a surface-modified polymer by surface activation, such as with plasma. By utilizing the surface-modified polymer to make medical equipment or devices for contacting biological fluids, a reduction in surface fouling and thrombus formation can result. Advantageously, polymeric equipment or components so modified may have a reduction in unwanted chemical interactions leading to fouling or clotting.Type: ApplicationFiled: July 4, 2013Publication date: January 16, 2014Applicant: ECONOUS SYSTEMS INC.Inventors: Michael THOMPSON, Sonia SHEIKH, Jack Chih-Chieh SHENG, Christophe BLASZYKOWSKI, Kiril FEDOROV
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Patent number: 8598273Abstract: Polymer electrolytes offer increased safety and stability as compared to liquid electrolytes, yet there are a number of new challenges that polymer electrolytes introduce. A polymer electrolyte, as disclosed herein, is a block copolymer that has a block that provides mechanical strength and a novel, ionically-conductive polymer block with a backbone that is both highly flexible and highly conductive with high conductivity pendant chains attached, thus increasing the concentration of lithium coordination sites and improving ionic conductivity. Previous strategies for comb-type conductive polymers have focused on attaching either conductive pendant chains to a flexible non-conductive backbone or conductive pendant groups to a marginally flexible conductive backbone.Type: GrantFiled: February 26, 2010Date of Patent: December 3, 2013Assignee: Seeo, Inc.Inventors: Hany Basam Eitouni, Bing R. Hsieh
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Publication number: 20130261235Abstract: There is disclosed a polycarbonate and polysiloxane block copolymer includes 1 to 50 percent by mass of a siloxane portion derived from a polysiloxane block represented by the following formula (I) and 50 to 99 percent by mass of a carbonate portion derived from a polycarbonate block represented by the following formula (II). There can be provided a novel polycarbonate and polysiloxane block copolymer capable of readily imparting excellent flame retardance, and a flame retardant resin composition.Type: ApplicationFiled: March 8, 2013Publication date: October 3, 2013Applicant: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Masahiko MINEMURA, Mitsuhiro TAKARADA, Masaki TANAKA
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Publication number: 20130253109Abstract: In a polycarbonate resin composition containing a polycarbonate resin and a polycarbosilane compound, the use of the polycarbosilane compound modifies the surface properties of the polycarbonate resin composition without adversely affecting the intrinsic characteristics of the polycarbonate resin, such as transparency, heat resistance, and mechanical properties, e.g., impact resistance. A polycarbonate resin composition containing 100 parts by mass of a polycarbonate resin, 0.001 to 1 part by mass of a metal salt compound, and 0.005 to 5 parts by mass of a polycarbosilane compound has significantly improved flame resistance and high transparency and causes markedly reduced outgassing and mold fouling, without losing impact resistance and heat resistance.Type: ApplicationFiled: March 15, 2013Publication date: September 26, 2013Inventor: Toshiki MONDEN
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Patent number: 8535770Abstract: A pearlescent container comprising about 86% to about 99.99% of a thermoplastic material having a Total Luminous Transmittance value of at least about 80%, about 0.01% to about 5% of a siloxane fluid having a viscosity of no greater than about 1,000,000 cst, wherein said thermoplastic material and said siloxane fluid are immiscible, forms a lamellar structure, and have a Refractive Index difference of at least about 0.1.Type: GrantFiled: November 8, 2012Date of Patent: September 17, 2013Assignee: The Procter & Gamble CompanyInventors: Ping Wang, Liang Yang, John Andrew McDaniel, Gian Armand Juliana DeBelder, Gaoyang Wang
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Publication number: 20130231260Abstract: Reactive polymers bound to a solid support, modified solid supports and reactive polymers are provided. Solid supports comprising the same for use as analytical devices for the detection and/or characterization of analytes, such as biomolecules, are also provided.Type: ApplicationFiled: February 15, 2013Publication date: September 5, 2013Applicant: NVS TECHNOLOGIES, INC.Inventors: Aldrich N. K. Lau, Robert G. Eason, Kristian Scaboo, Brad Taft
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Publication number: 20130216837Abstract: Presently described is a composition comprising at least one first divalent unit comprising a pendant perfluoropolyether or perfluoroalkyl group; at least one second divalent unit comprising a pendant phosphorus-containing acid group; and at least one third unit comprising a terminal or pendant alkoxy silane group. Also described is a coating comprising the composition described herein dissolved or dispersed in a solvent and a method of providing a coated article or surface. Such method is particularly useful for providing corrosion protection to a metallic surface.Type: ApplicationFiled: October 20, 2011Publication date: August 22, 2013Applicant: 3M INNOVATION PROPERTIES COMPANYInventors: Suresh Iyer, David A. Hesselroth, Richard M. Flynn, Karl J. Manske
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Patent number: 8501862Abstract: The invention relates to an extrusion agent comprising: at least one heterogeneous PVDF (A), in other words a copolymer of VDF and at least one comonomer of VDF, comprising by weight at least 50%, advantageously at least 75%, of VDF which has a melting point Tm (expressed in ° C.)>172-549 m, preferably >1.1×(172-549 m), where m denotes the overall molar percentage of comonomer(s); and at least one interface agent (B), which are optionally diluted in a polyolefin (C). The heterogeneous PVDF preferably has a Tm of between 160 and 172° C. Advantageously it is also a VDF-HFP copolymer containing, by weight, from 88% to 92% of VDF and from 8% to 12% of HFP. The extrusion agent is used to reduce or eliminate the surface defects which arise during the extrusion of a thermoplastic resin (D). This resin may be a polyolefin, a styrenic resin, a polyester or a PVC. Optionally it may also be filled, i.e., may contain dispersed organic or inorganic particles.Type: GrantFiled: January 5, 2007Date of Patent: August 6, 2013Assignee: Arkema FranceInventors: Anthony Bonnet, Johann Laffargue, Francois Beaume
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Patent number: 8481604Abstract: The present invention provides a crosslinkable and expandable elastomeric material based on and/or containing siloxane polymer, the process for manufacturing of such material and the use of such material and its blends and composites.Type: GrantFiled: February 1, 2011Date of Patent: July 9, 2013Assignee: Armacell Enterprise GmbHInventors: Jürgen Weidinger, Mark E. Harakal, Joseph Naseri
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Publication number: 20130158197Abstract: Disclosed herein is a curable composition comprising a polyhydroxy curable fluoroelastomer, a polyhydroxy curative, a cure accelerator and an unsaturated metal compound process aid comprising a siloxane having at least one vinyl or allyl group bonded to a silicon atom. Such curable compositions have a lower Mooney viscosity than do similar compositions absent the process aid.Type: ApplicationFiled: November 14, 2012Publication date: June 20, 2013Applicant: E I DU PONT DE NEMOURS AND COMPANYInventor: E I DU PONT DE NEMOURS AND COMPANY
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Patent number: 8440765Abstract: The present invention relates to copolymer compositions for alcohol-selective membranes and methods of selectively separating an alcohol such as ethanol from an aqueous solution using such membranes. The copolymer compositions may be block copolymers of polystyrene-polybutadiene-polystyrene (hereafter “SBS”) having cylindrical morphologies; graft diblock copolymers synthesized by ring-opening metathesis polymerization of two cycloalkene monomers, wherein at least one of the cycloalkene monomers is substituted with one or more polydialkylsiloxane groups; or triblock copolymers comprising a middle block comprising a polymerized cycloalkene monomer and two end groups. The synthesized graft and triblock copolymer compositions may have a spherical, lamellar, cylindrical, double diamond, or gyroid morphologies. The copolymer compositions may contain a structural block that imparts essential mechanical properties to the membrane (e.g., polystyrene) and may also contain an alcohol transporting block (e.g.Type: GrantFiled: March 10, 2011Date of Patent: May 14, 2013Assignee: The Regents of the University of CaliforniaInventors: Nitash P. Balsara, Ashish K. Jha, Liang Chen
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Patent number: 8367771Abstract: A composition for producing an organic insulator is provided which comprises an organic-inorganic hybrid material (as defined). The hybrid material shows high solubility in organic solvents and monomers, and superior adhesion to substrates. In addition, the hybrid material displays a high dielectric constant and a high degree of crosslinking. Based on these advantages, the composition comprising the organic-inorganic hybrid material can be utilized during the fabrication of various electronic devices by a wet process. A method for producing the organic insulator while utilizing the composition also is provided, as well as the resulting organic insulator, and an organic thin film transistor which incorporates the resulting insulating layer.Type: GrantFiled: February 13, 2009Date of Patent: February 5, 2013Assignee: Samsung Electronics Co., Ltd.Inventors: Jung Han Shin, Jae Jun Lee, Chang Ju Kim, Sang Yoon Lee
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Patent number: 8339012Abstract: To provide an electret whose surface potential is improved and an electrostatic induction conversion device comprising the same, an electret is formed by spin-coating a fluorine-containing polymer composition for coating which contains a fluorine-containing polymer having a ring structure in its main chain, a silane coupling agent, an aprotic fluorine-containing solvent, and a fluorine-containing alcohol as a protic fluorine-containing solvent on a copper substrate and baking it.Type: GrantFiled: February 27, 2008Date of Patent: December 25, 2012Assignees: The University of Tokyo, Asahi Glass Co., Ltd.Inventors: Yuji Suzuki, Yoshihiko Sakane
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Patent number: 8293840Abstract: There is provided a coating composition which comprises (A) a synthetic resin having functional group, (B) a stain-proofing component which is a liquid polydialkylsiloxane having functional group or a liquid fluoropolyether having functional group and (C) a curing agent, and the composition is excellent in a stain-proofing property, particularly removability of oily stain, thereby enabling scribbling to be easily wiped off, and is suitable for outdoor coating being excellent in weather resistance and adhesion.Type: GrantFiled: January 8, 2010Date of Patent: October 23, 2012Assignee: Daikin Industries, Ltd.Inventors: Tetsuya Masutani, Katsuhiko Imoto, Masaru Nagato, Susumu Wada, Haruhiko Mohri
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Patent number: 8288475Abstract: A process is disclosed for producing an electret, which includes a step of thermally treating a composition including a fluorinated polymer and a silane coupling agent, where the fluorinated polymer has an alicyclic structure in its main chain and has a carboxy group or an alkoxycarbonyl group as its terminal group. The silane coupling agent has an amino group; and the temperature for the thermal treatment is from 250° C. to 330° C.Type: GrantFiled: July 6, 2011Date of Patent: October 16, 2012Assignee: Asahi Glass Company, LimitedInventor: Kimiaki Kashiwagi
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Publication number: 20120245238Abstract: The invention relates to a composition that has been obtained by the melt-process recycling of one or more multi-layer articles, where the multi-layer articles are composed of at least one melt-processible fluoropolymer layer. The composition of the invention is a compatible blend of the different layers from the multi-layer articles. The other layers of the multi-layer articles are also melt-processible, and include one or more layers chosen from: a) a melt-processible fluoropolymer of a different composition, b) a non-fluoropolymer, and c) a barrier layer. The composition is useful for forming an article in a melt-process operation. The composition may be used by itself, may be blended with other virgin or recycled materials, or may be used at low levels with melt-processible polymers as a process aid.Type: ApplicationFiled: September 23, 2010Publication date: September 27, 2012Applicant: Arkema Inc.Inventors: Saeid Zerafati, Sean M. Stabler, William J. Hartzel
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Patent number: 8242208Abstract: The invention provides a fluoropolymer composition capable of improving the characteristics of the cured material obtained therefrom. A fluoropolymer composition comprising a methylene group-containing fluoropolymer (A) and a hydrosilylation catalyst (B), wherein the methylene group-containing fluoropolymer (A) has methylene group-containing repeating units in the main chain thereof and is capable of hydrosilylation in the presence of the hydrosilylation catalyst (B) and one terminus of the chain is a carbon-carbon double bond or an Si—H group and the other terminus of the chain is an Si—H group or a carbon-carbon double bond.Type: GrantFiled: March 6, 2009Date of Patent: August 14, 2012Assignee: Daikin Industries, Ltd.Inventors: Tatsuya Morikawa, Manabu Fujisawa, Mitsuru Kishine
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Publication number: 20120142865Abstract: The present invention relates to copolymer compositions for alcohol-selective membranes and methods of selectively separating an alcohol such as ethanol from an aqueous solution using such membranes. The copolymer compositions may be block copolymers of polystyrene-polybutadiene-polystyrene (hereafter “SBS”) having cylindrical morphologies; graft diblock copolymers synthesized by ring-opening metathesis polymerization of two cycloalkene monomers, wherein at least one of the cycloalkene monomers is substituted with one or more polydialkylsiloxane groups; or triblock copolymers comprising a middle block comprising a polymerized cycloalkene monomer and two end groups. The synthesized graft and triblock copolymer compositions may have a spherical, lamellar, cylindrical, double diamond, or gyroid morphologies. The copolymer compositions may contain a structural block that imparts essential mechanical properties to the membrane (e.g., polystyrene) and may also contain an alcohol transporting block (e.g.Type: ApplicationFiled: March 10, 2011Publication date: June 7, 2012Applicant: The Regents of the University of CaliforniaInventors: Nitash P. BALSARA, Ashish K. Jha, Liang Chen
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Patent number: 8158723Abstract: The invention relates to a moisture cross-linkable composition usable as an adhesive or sealant which is very easy to use and exhibits excellent bonding performance. The composition is obtained by mixing 100 parts by weight of an organic polymer (A) with moisture cross-linkable reactive silane terminal functions and 1 to 70 parts by weight of an organic polymer (B) miscible at ambient temperature with polymer (A), selected from among polyesters, polyethers, polyurethanes, polyacrylates, polyethylenediimines, polycarbonates, polyureas or polyamides.Type: GrantFiled: December 2, 2004Date of Patent: April 17, 2012Assignee: Bostik, S.A.Inventors: Virginie Lucet, Jacqueline Carrard, André Mayer
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Patent number: 8119249Abstract: A silicone resin composition is provided, which includes polysiloxane including (PSA1), (PSA2), (PSB) and (PSC), and a hydrosilylating catalyst, wherein a weight ratio between (PSA2) and (PSA1) (w2/w1) is 0.03-0.Type: GrantFiled: December 19, 2008Date of Patent: February 21, 2012Assignee: Kabushiki Kaisha ToshibaInventors: Shinji Murai, Koji Asakawa
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Patent number: 8076003Abstract: A coating composition including a compound having a first molecular group or a first combination of atoms, the first molecular group or the first combination of atoms capable of bonding to an oxidizable metal or a metal oxide, and a second molecular group or a second combination of atoms, the second molecular group or the second combination of atoms capable of interacting with a precursor of a polymer so the compound and the polymer are bound together.Type: GrantFiled: September 26, 2008Date of Patent: December 13, 2011Assignee: Infineon Technologies AGInventors: Manfred Mengel, Joachim Mahler
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Patent number: 8013064Abstract: To provide an elastomer composition that can be easily prevented from being blocking to a substrate. A perfluoroelastomer composition comprising (A) a perfluoroelastomer and (B) a fluorosilane compound.Type: GrantFiled: April 11, 2008Date of Patent: September 6, 2011Assignee: 3M Innovative Properties CompanyInventors: Katsuhiko Nakazato, Tatsuo Fukushi
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Patent number: 7989547Abstract: Polyhydroxy curable fluoroelastomer compositions contain at least one process aid that is an aminosilicone having only a single primary amine group per polysiloxane molecule.Type: GrantFiled: May 28, 2009Date of Patent: August 2, 2011Assignee: DuPont Performances Elastomers LLC.Inventor: Steven R. Oriani
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Patent number: 7976951Abstract: A laminate includes a backing material coated with an adhesive composition. The adhesive composition includes a silylated polyurethane obtained from the silylation of a polyurethane prepolymer derived from the reaction of polybutadiene polyol and polyisocyanate; and an additional adhesive component.Type: GrantFiled: May 15, 2009Date of Patent: July 12, 2011Assignee: Momentive Performance Materials Inc.Inventors: Roy M. Griswold, Robert L. Frye, Mark J. Bisaillon
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Patent number: 7964667Abstract: An elastomer blend is made by admixing fluoroelastomer and fluorinated silicone polymer (with optional filler and/or conductive particulate) into a polymeric admixture in weight ratios to provide a low vaporous hydrocarbon permeation rate and high thermal strain value in thermally robust elastomer cured from the blend. The blend is of especial use for making gaskets for use in high stress conditions at elevated operating temperatures.Type: GrantFiled: March 4, 2008Date of Patent: June 21, 2011Assignee: Freudenberg-NOK General PartnershipInventors: Francis Joseph Walker, Paul J. Hochgesang
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Publication number: 20110040024Abstract: A nanoparticle includes a chain oligomer section having a hydrophilic group and fluoroalkyl groups respectively at its opposite terminals, a three-dimensional silica network section, and an organic chain having fluorine or silicon, and is represented by the following formula (2): where R? is independent H or independent alkyl group; X is the hydrophilic group and is selected from the group consisting of an OH group, an NCO group, an NH2 group, an NHR group (where R is alkyl group) and a COY group (where Y is a hydrophilic group); RF is the fluoroalkyl group having a carbon number of 2 to 10 and a molecular weight of 119 to 1000; 3D-SN is the three-dimensional silica network section; B is selected from the group consisting of an O, O?C—O, NH—C?O and NR—C?O (where R is alkyl group); E is O, O?C—O, NH—C?O or NR—C?O (where R is alkyl group); L is (CH2O)l—[Si(CH3)2O]k—(CH2O)l-?, (CF2)j-? or (CF2O)h-? where ? is COY group (where Y is hydrophilic group), NCO group, NH2 group, NHR group (R is alkyl group), R grouType: ApplicationFiled: October 22, 2010Publication date: February 17, 2011Inventors: Hideaki YAEGASHI, Shoko Kano, Masahiko Yamanaka, Kentarou Watanabe, Hiroshi Yokohama, Hideo Sawada
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Patent number: 7868089Abstract: The invention provides a thermoplastic polymer composition which has both excellent heat resistance and chemical resistance, and also has flexibility and excellent processability. The present invention is a thermoplastic polymer composition comprising a fluororesin (A) and non-fluorine-containing cured rubber (B), wherein the fluororesin (A) comprises a fluorine-containing ethylenic polymer (a), and the non-fluorine-containing cured rubber (B) is at least one kind of rubber (b) which is at least partially crosslinked.Type: GrantFiled: May 16, 2005Date of Patent: January 11, 2011Assignee: Daikin Industries Ltd.Inventors: Haruhisa Masuda, Tsuyoshi Ono
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Patent number: 7851529Abstract: Provided are a polycarbonate resin composition which does not contain halogen and phosphorus as a flame retardant component and which is excellent in a fluidity while maintaining a flame resistance, a heat resistance and an impact resistance and a molded article thereof.Type: GrantFiled: November 26, 2007Date of Patent: December 14, 2010Assignee: Idemitsu Kosan Co., Ltd.Inventors: Kenichi Mitsuhashi, Akio Nodera, Hiroshi Kawato, Toshio Isozaki
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Publication number: 20100298487Abstract: The invention relates to an extrusion agent comprising: at least one heterogeneous PVDF (A), in other words a copolymer of VDF and at least one comonomer of VDF, comprising by weight at least 50%, advantageously at least 75%, of VDF which has a melting point Tm (expressed in ° C.)>172-549 m, preferably >1.1×(172-549 m), where m denotes the overall molar percentage of comonomer(s); and at least one interface agent (B), which are optionally diluted in a polyolefin (C). The heterogeneous PVDF preferably has a Tm of between 160 and 172° C. Advantageously it is also a VDF-HFP copolymer containing, by weight, from 88% to 92% of VDF and from 8% to 12% of HFP. The extrusion agent is used to reduce or eliminate the surface defects which arise during the extrusion of a thermoplastic resin (D). This resin may be a polyolefin, a styrenic resin, a polyester or a PVC. Optionally it may also be filled, i.e., may contain dispersed organic or inorganic particles.Type: ApplicationFiled: January 5, 2007Publication date: November 25, 2010Applicant: Arkema FranceInventors: Anthony Bonnet, Johann Laffargue, Francois Beaume
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Patent number: 7829617Abstract: There is provided an aromatic polycarbonate resin composition having excellent flame retardancy, mechanical properties and fluidity and affording a thin-walled molded article. The aromatic polycarbonate resin composition includes a resin component containing (A) 90 to 99.5% by mass of an aromatic polycarbonate resin and (B) 10 to 0.5% by mass of a polyorganosiloxane-containing graft copolymer, and, compounded in 100 parts by mass of the resin component, (C) 0.1 to 5 parts by mass of a bisphenol type epoxy compound and (D) 0.05 to 2 parts by mass of polytetrafluoroethylene capable of forming fibrils, wherein the polyorganosiloxane-containing graft copolymer in the resin composition has a dispersion average particle diameter of 0.1 to 1.0 ?m. The molded article has a section with a thickness of 1 mm or less and is obtainable by molding the aromatic polycarbonate resin composition.Type: GrantFiled: March 28, 2006Date of Patent: November 9, 2010Assignee: Idemitsu Kosan Co., Ltd.Inventors: Akio Nodera, Yusuke Hayata
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Patent number: 7807752Abstract: There is provided a coating composition which comprises (A) a synthetic resin having functional group, (B) a stain-proofing component which is a liquid polydialkylsiloxane having functional group or a liquid fluoropolyether having functional group and (C) a curing agent, and the composition is excellent in a stain-proofing property, particularly removability of oily stain, thereby enabling scribbling to be easily wiped off, and is suitable for outdoor coating being excellent in weather resistance and adhesion.Type: GrantFiled: January 22, 2004Date of Patent: October 5, 2010Assignee: Daikin Industries, Ltd.Inventors: Tetsuya Masutani, Katsuhiko Imoto, Masaru Nagato, Susumu Wada, Haruhiko Mohri
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Publication number: 20100233371Abstract: Disclosed is a polytetrafluoroethylene coating agent having low friction and high wear resistance, obtained by dispersing nanodiamond powder in a polar organic solvent, stirring the nanodiamond dispersion solution and a silane coupling agent, and stirring the silane-treated dispersion solution and an oily polytetrafluoroethylene coating solution, in which the silane coupling agent has at least one organic functional group selected from, but not limited to, a mercapto group and an amino group, the organic functional group exhibiting high bondability to polytetrafluoroethylene. A method of preparing the polytetrafluoroethylene coating agent and a method of using the polytetrafluoroethylene coating agent are also provided.Type: ApplicationFiled: September 23, 2009Publication date: September 16, 2010Applicants: HYUNDAI MOTOR COMPANY, KIA MOTORS CORPORATION, KOREA UNIVERSITY RESEARCH AND BUSINESS FOUNDATIONInventors: Yool Koo Kim, In Ki Hwang, Sung Moon Choi, In Woong Lyo, Seung Gyun Ahn, Joong Soo Kim, Dae Soon Lim, Joon Sung Park