Solid Polymer From Ethylenic Reactants Only Is Derived From Reactant Containing Halogen Atom Patents (Class 525/104)
  • Patent number: 5506302
    Abstract: An organopolysiloxane composition contains (A) a both end hydroxyl-blocked diorganopoly-siloxane, (B) a hydroxyl-free diorganopoly-siloxane having a degree of polymerization equal to or greater than that of (A), (C) an organo-hydrogenpolysiloxane having at least three hydrogen atoms in a molecule, (D) an organosilane containing at least two alkoxy groups and an amino group attached to a silicon atom through an alkylene group in a molecule and/or a partial hydrolyzate thereof, (E) a fatty acid metal salt, (F) polycarbonate powder having a mean particle size of up to 50 .mu.m, and optionally (G) an organo-silane containing at least two alkoxy groups and a mercapto group attached to a silicon atom through an alkylene group in a molecule and/or a partial hydrolyzate thereof. It is applied to a rubber substrate to form a wear resistance coating thereon.
    Type: Grant
    Filed: June 21, 1995
    Date of Patent: April 9, 1996
    Assignee: Shin-Etsu Chemical Co., Inc.
    Inventors: Mikio Shiono, Kazumi Okada, Hironao Fujiki
  • Patent number: 5492969
    Abstract: There is disclosed a composition which can cure to provide a coating showing excellent release against tacky substances, particularly silicone pressure-sensitive adhesive, said composition comprising:(A) 100 parts by weight of an organopolysiloxane that contains at least one fluorinated organic group and at least two alkenyl groups in each molecule;(B) 0.3 to 40 parts by weight of an organohydrogenpolysiloxane that contains at least two silicon-bonded hydrogen atoms in each molecule;(C) 0.1 to 20 parts by weight of a fluorine-containing acrylic polymer;(D) a catalytic quantity of a hydrosilylation catalyst; and(E) a sufficient amount of an organic solvent to impart coatability to said composition.
    Type: Grant
    Filed: November 14, 1994
    Date of Patent: February 20, 1996
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Yuji Hamada, Hideki Kobayashi
  • Patent number: 5488086
    Abstract: A polycarbonate resin composition which is superior in impact resistance, fluidity, solvent resistance, wear resistance and sliding characteristics. The polycarbonate resin composition comprises (A) a mixture of polycarbonate (PC) and a polycarbonate-polydimethylsiloxane (PC-PDMS) copolymer and (B) at least one of (i) a thermoplastic resin such as a thermoplastic crystalline resin or a thermoplastic amorphous resin and (ii) a rubber elastomer.
    Type: Grant
    Filed: March 10, 1994
    Date of Patent: January 30, 1996
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Takashi Umeda, Masaya Okamoto
  • Patent number: 5486421
    Abstract: There is disclosed a polymer composition which can cure rapidly to provide a release coating that has a low surface tension, said composition comprising:(A) a fluorine-containing polymer that contains at least 2 alkenyl groups in each molecule, said polymer being obtained by the copolymerization of(a) an acrylic monomer having the general formulaCH.sub.2 .dbd.CX--COOR'wherein X is selected from the group consisting of hydrogen and a methyl radical and R' denotes a monovalent hydrocarbon group having 4 to 15 carbon atoms which contain at least one --CF.sub.2 -- group, and(b) a silicone macromonomer with the general formulaCH.sub.2 .dbd.CX--COO--Q--(RMeSiO).sub.n --Me.sub.
    Type: Grant
    Filed: November 14, 1994
    Date of Patent: January 23, 1996
    Assignee: Dow Corning Toray Silicone Company, Ltd.
    Inventor: Hideki Kobayashi
  • Patent number: 5482649
    Abstract: The present invention relates to aminoacrylates which have a viscosity of 200 to 3000 mPa.s at 23.degree. C. and 100% solids, a content of olefinic double bonds (calculated as C=C, molecular weight=24) of 8 to 20% by weight and a nitrogen content of 0.4 to 2.0% by weight, and which are prepared by an addition reaction by reacting at a molar ratio of primary amino groups from component a) to olefinic double bonds from component b) of 0.05:1 to 0.25:1a) mono- or diamines having a molecular weight of 31 to 300 and having aliphatically bound amino groups withb) acrylic esters of polyhydric alcohols which have been prepared at a COOH/OH equivalent ratio of 0.8:1 to 1:1 fromb1) acrylic acid andb2) ether-alcohols which have 3 or 4 hydroxyl groups and a molecular weight of 136 to 1000, possess at least one ethylene oxide unit --CH.sub.2 --CH.sub.2 --O-- as part of the ether structure and do not contain propylene oxide units --CH.sub.2 --CH(CH.sub.3)--O--.
    Type: Grant
    Filed: July 22, 1993
    Date of Patent: January 9, 1996
    Assignee: Bayer Aktiengesellschaft
    Inventors: Jurgen Meixner, Wolfgang Fischer, Christian Zwiener
  • Patent number: 5483000
    Abstract: A vulcanizable rubber composition comprising:(A) 100 parts by weight of a fluororubber polymer containing at least 10 mol % of vinylidene fluoride as constituting monomer units;(B) from 0.1 to 300 parts by weight of an organic silicon compound having an amino group; and(C) a vulcanizing agent in an amount sufficient to vulcanize Component (A).
    Type: Grant
    Filed: March 13, 1995
    Date of Patent: January 9, 1996
    Assignee: Asahi Glass Company Ltd.
    Inventors: Isamu Kaneko, Hiroki Kamiya
  • Patent number: 5480938
    Abstract: A low surface energy material comprising a volume grafted elastomer which is a substantially uniform integral interpenetrating network of a hybrid composition of a fluoroelastomer and a polyorganosiloxane, said volume graft having been formed by dehydrofluorination of said fluoroelastomer by a nucleophilic dehydrofluorinating agent, followed by a hydrosilation reaction, addition of a hydrogen functionally terminated polyorganosiloxane and a hydrosilation reaction catalyst.
    Type: Grant
    Filed: November 22, 1993
    Date of Patent: January 2, 1996
    Assignee: Xerox Corporation
    Inventors: Santokh S. Badesha, George J. Heeks, Arnold W. Henry, David H. Pan, Louis D. Fratangelo, Robert M. Ferguson
  • Patent number: 5480930
    Abstract: The present invention describes uncured fluorocarbon elastomer base compositions and cured fluorocarbon elastomer compositions comprising a fluorocarbon elastomer, an amorphous silicone resin, and optionally a polydiorganosiloxane gum or a hydrocarbon polymer elastomer. The cured fluorocarbon elastomers typically contain additional components such as an acid acceptor, a cure agent, and a filler. The cured compositions have high strength, low temperature flexibility, high solvent resistivity, and low fuel permeability.
    Type: Grant
    Filed: August 18, 1994
    Date of Patent: January 2, 1996
    Assignee: Dow Corning Corporation
    Inventors: Thomas M. Gentle, Gerald A. Gornowicz
  • Patent number: 5468794
    Abstract: Room temperature vulcanizable platinum group metal catalyzed silicone compositions are provided which utilize an N-heterocyclic adhesion promoter, such as 2,6 bis(trimethoxysilyltrimethyleneoxy)pyridine. Cohesive bonding is effected on various substrates.
    Type: Grant
    Filed: September 13, 1994
    Date of Patent: November 21, 1995
    Assignee: General Electric Company
    Inventors: Judith Stein, Mark W. Davis
  • Patent number: 5459199
    Abstract: A graft polymer wherein an iodine-containing fluororubber has been grafted on an ethylene-.alpha.-olefin copolymer or other polymer can be obtained by mixing 30 parts by weight of an iodine-containing fluororubber (a vinylidene fluoride-hexafluoropropylene copolymer containing iodine) and 70 parts by weight of an ethylene-propylene copolymer rubber at 180.degree. C. for 30 minutes while applying shear deformation using a Brabender mixer.
    Type: Grant
    Filed: September 21, 1993
    Date of Patent: October 17, 1995
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Keisaku Yamamoto, Yoshio Tanimoto, Kiyosi Ikeda, Nobuhiro Natsuyama
  • Patent number: 5459198
    Abstract: Fluoroinfused composites exhibiting low surface energy and low kinetic coefficent of energy are prepared via contact of a swellable polymeric material with a solution comprising a swelling solvent, an organofluorosilane and a gelling agent.
    Type: Grant
    Filed: July 29, 1994
    Date of Patent: October 17, 1995
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Kenneth G. Sharp
  • Patent number: 5457158
    Abstract: A process is described for preparing blends of fluorocarbon plastomers such as vinylidene fluoride polymers with fluorosilicone elastomers to obtain materials having a unique combination of flexibility at low temperature and high mechanical strength. Vinylidene fluoride polymer is first exposed to radiation and then mixed with the fluorosilicone. Coagents such as diallylphtalate and triallylisocyanurate are also used to assist in grafting and compatibilizing the two polymers.
    Type: Grant
    Filed: July 11, 1994
    Date of Patent: October 10, 1995
    Assignee: Dow Corning Corporation
    Inventors: Gerardo Caporiccio, Liberato Mascia
  • Patent number: 5451632
    Abstract: A polycarbonate-polyorganosiloxane copolymer comprising a repeating unit I represented by the general formula: ##STR1## a repeating unit II represented by the general formula: ##STR2## a structural unit III represented by the general formula: ##STR3## and a terminal group IV of polyhalogenophenoxy group represented by the general formula: ##STR4## wherein symbols in the formulae are the same as those described in the specification, is disclosed. Content of the repeating unit II based on the total of contents of the repeating unit I and the repeating unit II and content of the structural unit III based on the total of contents of the repeating unit I, the repeating unit II and the structural unit III are in specific ranges, respectively. Resin compositions comprising the polycarbonate-polyorganosiloxane copolymer and a resin, such as a polycarbonate, a fluororesin, a styrenic resin and the like, inorganic filler or pigment is also disclosed.
    Type: Grant
    Filed: October 4, 1993
    Date of Patent: September 19, 1995
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Ryozo Okumura, Masaya Okamoto
  • Patent number: 5428097
    Abstract: A silicone rubber composition having good processability and good molding properties is disclosed, said composition comprising:(A) an organopolysiloxane containing vinyl groups;(B) a fluorine resin powder;(C) an organopolysiloxane containing units having the formulaF(CF.sub.2).sub.a CH.sub.2 CH.sub.2 Si(Me).sub.n O.sub.3-n/2in which a is an integer of at least 4, n is 0, 1 or 2 and Me denotes a methyl radical;(D) a reinforcing silica powder having a surface area of at least 50 m.sup.2 /g; and(E) a sufficient quantity of a curing agent to cure said composition.
    Type: Grant
    Filed: March 30, 1994
    Date of Patent: June 27, 1995
    Assignee: Dow Corning Toray Silicon Co., Ltd.
    Inventor: Hideki Kobayashi
  • Patent number: 5409993
    Abstract: Fluid gasket composition with fine rubber particles has sufficient elasticity. The particle size of the rubber particles contained in the fluid gasket composition is desired to be 0.1 to 3.0 mm. The fluid gasket composition applied to a joint portion between mechanical parts or the like exhibits an effect of sealing and absorbing vibrations, dislocation and mechanical movements taking place in the mechanical parts.
    Type: Grant
    Filed: December 23, 1993
    Date of Patent: April 25, 1995
    Assignee: Three Bond Co., Ltd.
    Inventors: Kazuhiro Kojima, Minami Hanada
  • Patent number: 5408001
    Abstract: Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two-component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.
    Type: Grant
    Filed: August 18, 1993
    Date of Patent: April 18, 1995
    Assignee: Kansai Paint Company, Limited
    Inventors: Akimasa Nakahata, Nobushige Numa, Masahiro Yamane, Osamu Isozaki, Noboru Nakai
  • Patent number: 5391594
    Abstract: A free-flowing silicone polymer powder, having an average particle size of 1 to 1000 microns and prepared by mixing a polydiorganosiloxane with a silica filler, is uniformly dispersed in an organic resin using conventional equipment, such as a single screw or, preferably, a twin screw extruder. When employed at a concentration of about 0.5 to 25 parts by weight of powder per 100 parts by weight of resin, a significant improvement in the burn character of the modified resin is obtained such that the rate of heat release, generation of smoke and evolution of toxic carbon monoxide gas is significantly reduced relative to the unmodified resin.
    Type: Grant
    Filed: June 29, 1992
    Date of Patent: February 21, 1995
    Assignee: Dow Corning Corporation
    Inventors: David J. Romenesko, Robert R. Buch
  • Patent number: 5387646
    Abstract: The invention provides:1) a fluorine-containing resin composition including:a) a fluorine-containing resin having (i) a hydrolyzable group attached directly to a silicon atom and/or a silanol group and (ii) an epoxy group in the molecule, orb) a mixture of a component (I) having a hydrolyzable group attached directly to a silicon atom and/or a silanol group and a component (II) having an epoxy group, such that at least one of the components (I) and (II) is a fluorine-containing resin;2) a curable composition including the resin composition and a metal chelate compound; and3) a coating composition including this resin composition or this curable composition.
    Type: Grant
    Filed: April 7, 1993
    Date of Patent: February 7, 1995
    Assignee: Kansai Paint Company, Limited
    Inventors: Akimasa Nakahata, Nobushige Numa, Masahiro Yamane, Osamu Isozaki, Noboru Nakai
  • Patent number: 5373042
    Abstract: A one-component moulding and sealing compound based on prepolymers with terminal silyl groups with at least one hydrolyzable substituent on the Si atom, organo-metallic tin compounds as the catalyst and also inorganic fillers containing a polyvinyl chloride and fatty acid amide having thixotropic effect to reduce surface tackiness.
    Type: Grant
    Filed: July 14, 1993
    Date of Patent: December 13, 1994
    Assignee: Teroson GmbH
    Inventors: Gabriele Bride, Gisbert Kern, Wolfgang Lepka, Michael Schatzle
  • Patent number: 5367023
    Abstract: This invention relates to fluorohydrocarbon polymers which are modified by the incorporation of substitiuents bearing a functional group such as vinyl, allyl, acrylate, alkoxysilane, amido, sulfonic acid salt, pyridine, carboxylic ester, and carboxylic salt. The functional groups may be further reacted to obtain branching, grafting, or crosslinking of the polymers. Copolymers of vinylidene fluoride and hexafluoropropene such as VITON A rubber and KYNAR FLEX 2801 plastomer, are typical of the class of fluorohydrocarbon polymers which are modified to obtain the new materials of this invention.
    Type: Grant
    Filed: April 12, 1993
    Date of Patent: November 22, 1994
    Assignee: Dow Corning Corporation
    Inventors: Gerardo Caporiccio, Gerald A. Gornowicz
  • Patent number: 5350804
    Abstract: A novel method is proposed for the effective utilization of scraps of cured silicone rubbers, of which no method of disposal is known heretofore other than discarding as a waste material. Namely, scraps of cured silicone rubbers can be compounded in a considerably large amount with a vulcanizable composition based on an organic rubbery elastomer such as fluorocarbon rubbers, e.g., binary copolymers of hexafluoropropylene and vinylidene fluoride, and dispersed therein in such fineness that particles of the cured silicone rubber can no longer be recognized by the naked eyes only when the organic rubbery elastomer composition has a specific Mooney viscosity (ML.sub.1+4 100.degree. C.) of at least 70 to give a uniform curable rubber composition capable of being cured into vulcanized rubber articles having various properties as good as or comparable with those of the vulcanized rubber articles from the same organic rubbery elastomer without admixture of cured silicone rubber scraps.
    Type: Grant
    Filed: July 30, 1993
    Date of Patent: September 27, 1994
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Ken-ichi Takita, Masaharu Takahashi
  • Patent number: 5328974
    Abstract: A platinum catalyst which is prepared by reacting a platinum halide with an organic compound having at least one --C.tbd.C-- group in the presence or absence of a base to form a complex which promotes the addition of silicon-bonded hydrogen atoms to silicon-bonded aliphatic unsaturated hydrocarbon groups in the presence of no-clean flux.
    Type: Grant
    Filed: May 6, 1993
    Date of Patent: July 12, 1994
    Assignee: Wacker Silicones Corporation
    Inventors: Richard McAfee, James R. Adkins, John C. Getson
  • Patent number: 5321083
    Abstract: Disclosed herein are coating compositions comprising a fluoropolymer modified with a modifier. The modifier is a reaction product of at least one compound selected from polysiloxane compounds, fluorine-containing compounds and silane coupling agents, each containing at least one reactive organic functional group, with an organic polyisocyanate; and contains at least one free isocyanate group.
    Type: Grant
    Filed: May 12, 1992
    Date of Patent: June 14, 1994
    Assignees: Dainichiseika Color & Chemicals Mfg. Co., Ltd., Ukima Colour & Chemicals Mfg. Co., Ltd.
    Inventors: Kazuyuki Hanada, Iwao Misaizu, Katsumi Kuriyama
  • Patent number: 5318815
    Abstract: A substrate is provided with a release surface by application of an emulsion of a vinyl-addition silicone system and catalyst therefor and a particulate component, preferably a resin. The vinyl addition silicone system is cured upon application of heat and removal of water.
    Type: Grant
    Filed: November 23, 1992
    Date of Patent: June 7, 1994
    Assignee: Avery Dennison Corporation
    Inventors: Charles W. Newing, Robert S. Dordick, Adrian J. Hulme, Erick R. Atkinson, Peter L. Emerson, Bert R. Potjer
  • Patent number: 5306759
    Abstract: A coating composition prepared by adding 0 to 150 parts by weight, in terms of diorganosilane, of a hydrolyzate and/or a partial condensate of an diorganosilane (b), 2 to 300 parts by weight of a vinyl resin containing a silyl group (c), 0.01 to 50 parts by weight of a metal chelate compound (d), and an organic solvent (e), to 100 parts by weight in terms of organosilane of a hydrolyzate and/or a partial condensate of an organosilane (a), to which are added two or more mols of a type of .beta.-diketone and/or .beta.-ketoester (f) for one mol of the metal chelate compound (d).
    Type: Grant
    Filed: February 11, 1993
    Date of Patent: April 26, 1994
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Toshinori Sakagami, Koichi Nagano, Tomonobu Shimizu, Kinji Yamada
  • Patent number: 5296569
    Abstract: Complex microspheres consist of polysiloxane and vinyl polymers which are unistructurally mixed together and substantially free of covalent bonds therebetween. Polysiloxane and vinyl polymer are contained at ratio of 97/3.about.30/70 by weight, the average diameter of the complex microspheres is 0.05.about.30 .mu.m, the standard deviation of their particle size is 1.0.about.2.5, and the ratio between their major and minor axes is 1.0.about.1.2. Thermoplastic films containing such complex microspheres at a specified rate have improved lubricity and anti-blocking properties.
    Type: Grant
    Filed: April 12, 1993
    Date of Patent: March 22, 1994
    Assignee: Takemoto Yushi Kabushiki Kaisha
    Inventors: Ippei Noda, Masanobu Abe, Fumitoshi Sugiura
  • Patent number: 5290601
    Abstract: A primer composition for application to a substrate to promote adhesion of a room-temperature-vulcanizable silicone rubber coating, comprises (A) an aminosilane material, (B) a chlorinated polyolefin and (C) a room-temperature-curable polydiorganosiloxane. The aminosilane material (A) is a primary amine-functional silane or the reaction product of a primary amine-functional silane with an epoxy-functional silane or an alpha, omega-dihydroxypolydimethylsiloxane oil.
    Type: Grant
    Filed: September 22, 1992
    Date of Patent: March 1, 1994
    Assignee: Courtaulds Coatings (Holdings) Limited
    Inventors: Rodney R. Brooks, Michael J. Winter
  • Patent number: 5290847
    Abstract: A curable composition including (A) 100 parts by weight of an organic polymer having at least one cross-linkable group containing a silicon atom to which a hydrolyzable group is bonded, and (B) 10 to 500 parts by weight of a vinyl chloride polymer. In the curable composition of the present invention, the viscosity is not lowered even after the storage for a long time and therefore the workability as sealants is not lowered.
    Type: Grant
    Filed: October 15, 1991
    Date of Patent: March 1, 1994
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Sadao Yukimoto, Fumio Kawakubo
  • Patent number: 5283288
    Abstract: This invention involved the discovery of novel polymers and a process for their preparation. The polymers were prepared by the nucleophilic substitution, at room temperature, of PVC with substituted alkyltrialkoxysilanes, which can be cured at room temperature to give adhesion of PVC to hydrophilic substrates. These polymers are particularly useful as adhesion promoters in ion-selective electrodes. The invention also involved the application of these adhesive primers to planar electrode substrates to give greatly improved performance in the response of ion-selective electrodes.
    Type: Grant
    Filed: January 7, 1992
    Date of Patent: February 1, 1994
    Assignee: Ciba Corning Diagnostics Corp.
    Inventors: Mark W. Boden, Vincent A. Perciaccante, Stephen B. Ruiz
  • Patent number: 5281444
    Abstract: A coating composition containing fluoropolymer adapted for roll coating is provided with a solvent system that is free of isophorone. The solvent system comprises an ester of an aromatic acid, a high molecular weight ketone, a high molecular weight alcohol, a glycol ether ester, and a hydrocarbon solvent having a high evaporation rate.
    Type: Grant
    Filed: January 2, 1992
    Date of Patent: January 25, 1994
    Assignee: PPG Industries, Inc.
    Inventor: Robin L. Hunt
  • Patent number: 5274042
    Abstract: A graft polymer wherein an iodine-containing fluororubber has been grafted on an ethylene-.alpha.-olefin copolymer can be obtained by mixing 30 parts by weight of an iodine-containing fluororubber (a vinylidene fluoride-hexafluoropropylene copolymer containing iodine) and 70 parts by weight of an ethylene-propylene copolymer rubber at 180.degree. C. for 30 minutes while applying shear deformation using a Brabender mixer.
    Type: Grant
    Filed: February 12, 1992
    Date of Patent: December 28, 1993
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Keisaku Yamamoto, Yoshio Tanimoto, Kiyosi Ikeda, Nobuhiro Natsuyama
  • Patent number: 5272193
    Abstract: Thermoplastic polycarbonate moulding compounds containing 40 to 90 parts by weight of a thermoplastic aromatic polycarbonate; 0 to 80 parts by weight of a copolymer or polycondensate consisting of 0 to 50 parts by weight of a thermoplastic copolymer of 50 to 95% by weight of styrene, .alpha.-methylstyrene, styrene alkylated in the nucleus, halogenated styrene or mixtures thereof and 5 to 50% by weight of acrylonitrile, methacrylonitrile, alkyl acrylate, alkyl methacrylate, maleic acid anhydride, N-substituted maleiimide, vinyl acetate or mixtures thereof and/or 0 to 80 parts by weight of a thermoplastic polyalkylene terephthalate; 1 to 25 parts by weight of graft polymer prepared from 5 to 90 parts by weight of a mixture of: 50 to 95% by weight of styrene, .alpha.
    Type: Grant
    Filed: June 29, 1992
    Date of Patent: December 21, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl Fuhr, Friedemann Muller, Karl-Heinz Ott
  • Patent number: 5268029
    Abstract: This invention provides cationic emulsions of bituminous binders of the bitumen/polymer type, formed by a dispersion of an organic phase of the binder in an aqueous phase containing a cationic nitrogenous emulsifier and a mineral or organic acid, the acid being in appropriate quantity so that the pH of the aqueous phase is comprised between 3 and 9. The aqueous phase also contains an agent consisting of at least one water-soluble sequestering salt of polyfunctional nitrogenized carboxylic acid, particularly a salt of alkaline metal or of amine of mono- and di (hydroxy-2 ethyl) glycine and optionally a water-soluble thickening agent. To obtain the emulsions, which are usable for road applications, the emulsifying agent, the sequestering agent and optionally the thickening agent may be used in the form of a premixture containing the agents and called cationic emulsifying system.
    Type: Grant
    Filed: September 17, 1991
    Date of Patent: December 7, 1993
    Assignee: ELF France
    Inventors: Francis Demangeon, Emile Lopez
  • Patent number: 5266637
    Abstract: The present invention relates to functionalized chlorinated (co)polymers and methods for their preparation. The functionalization is performed with an organometallic compound where the metal may be tin, lead, antimony or bismuth. The organic groups are hydrocarbons which may be substituted and one group is either a secondary amine or an ether which is eventually substituted by a trialkoxysilane or a hydroxy group. The preferred chlorinated polymer is PVC and the preferred functionalizing agent is an organotin compound.
    Type: Grant
    Filed: October 28, 1991
    Date of Patent: November 30, 1993
    Assignees: Centre National de la Recherche Scientifique, Sotra Industries
    Inventors: Christian Gondard, Alain Michel
  • Patent number: 5264523
    Abstract: A uniform mixture of a polytetrafluoroethylene molding powder and an organic filler, which can provide moldings having improved properties without lowering the appearance and mechanical property, is obtained without sticking the filler to the wall of a mixer by mixing the molding powder and the filler in the presence of a silane coupling agent and a polar solvent, or by previously treating the organic filler with the silane coupling agent and mixing the treated filler with the molding powder.
    Type: Grant
    Filed: August 1, 1990
    Date of Patent: November 23, 1993
    Assignee: Daikin Industries, Ltd.
    Inventors: Norimasa Honda, Tomohiko Hirata, Hirokazu Yukawa
  • Patent number: 5260376
    Abstract: Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.
    Type: Grant
    Filed: June 25, 1992
    Date of Patent: November 9, 1993
    Assignee: Kansai Paint Company, Limited
    Inventors: Akimasa Nakahata, Nobushige Numa, Masahiro Yamane, Osamu Isozaki, Noboru Nakai
  • Patent number: 5258458
    Abstract: A composition for treating fibrous substrates such as textiles to provide oil and water repellency is provided. The composition comprises a) a terpolymer comprising randomly distributed i) units containing a fluoroaliphatic group, R.sub.f, ii) fluorine-free hydrocarbon units, and iii) units containing silicone and b) a fluorine-containing polymer having isocyanate derived linking groups and blocked isocyanate moieties. Also provided is a method for providing oil and water repellency to a fibrous substrate.
    Type: Grant
    Filed: February 28, 1991
    Date of Patent: November 2, 1993
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Kathy Allewaert, Inge Bohez, Pierre V. Elst
  • Patent number: 5252668
    Abstract: One-pack chloroprene adhesive having excellent adhesion and excellent heat resistance, particularly excellent heat aging resistance, which comprises a chloroprene rubber modified with an aminosilane, a petroleum resin as a tackifier resin and an organic solvent, which is useful for adhering and laminating various products such as metallic materials, woven fabrics, fiber products, wooden products, leather products, plastic materials, etc.
    Type: Grant
    Filed: May 30, 1989
    Date of Patent: October 12, 1993
    Assignee: Sunstar Giken Kabushiki Kaisha
    Inventors: Masahito Mori, Masaaki So
  • Patent number: 5250607
    Abstract: An interpenetrating polymer system prepared from a mixture of a moisture-cured prepolymer component and an elastomeric component which is non-reactive with the prepolymer component, wherein exposure of the mixture to ambient moisture cures the prepolymer component entrapping the elastomeric component and forming a product which is essentially thermoset. The product may be essentially non-foamed or highly foamed and and either tack-free or self-adhesive. It is particularly suitable for use as sealing gaskets, sheet stock, tubing, and as sealant-encapsulants.
    Type: Grant
    Filed: January 22, 1990
    Date of Patent: October 5, 1993
    Assignee: Norton Company
    Inventors: Ahmet Comert, Michel Ladang, Dominique Petit
  • Patent number: 5244938
    Abstract: The present invention is characterized by adding and mixing an organosilicon compound having alkoxy, groups and an ester linkage in the molecule represented by the following formula: ##STR1## in an amount of 1 to 20 parts by weight per 100 parts by weight of a trifluoropropylalkylpolysiloxane. Said organosilicon compound has a function as a storage stabilizer as well as a curing agent and, according to the present invention, an RTV fluorosilicone composition that has hitherto been difficult to be applied as an adhesive for electric and electronic parts has been made possible to be used in the particular field.
    Type: Grant
    Filed: December 13, 1991
    Date of Patent: September 14, 1993
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Masatoshi Arai, Yoshifumi Inoue, Yoshio Inoue
  • Patent number: 5210143
    Abstract: The present invention relates to elastomeric copolymers and block copolymers, e.g., based upon styrene/isoprene, having a novel condensed phase structure wherein polymer branches occur along the polymer backbone, either at a predetermined location or at random locations. The polymers are made by a method which comprises the step of reacting, under polymerization conditions, hydrocarbyl lithium initiator, at least one anionically polymerizable compound, and an organometallic- substituted styrene condensing agent. The reactants may be added simultaneously to produce a copolymer with polymer branch segments randomly located along the polymer backbone or sequentially to produce a copolymer with branches located at the same predetermined location along the polymer backbone. The resultant polymers may be further reacted with a linking agent to form multi-arm copolymers.
    Type: Grant
    Filed: January 9, 1992
    Date of Patent: May 11, 1993
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Spencer Silver, William R. Bronn, Eugene G. Joseph
  • Patent number: 5202190
    Abstract: A method of preparing vinyl-silicone copolymers which involves the use of a mercapto-functional silicone compound as a macromolecular chain transfer agent. Release coatings and low adhesion backsizes comprising the vinyl-silicone copolymers.
    Type: Grant
    Filed: March 18, 1992
    Date of Patent: April 13, 1993
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Steven S. Kantner, Ramesh C. Kumar, Gilbert L. Eian
  • Patent number: 5179142
    Abstract: A polylactone-modified organopolysiloxane compound, wherein a polylactone-containing group represented by the formula (I) is bound to a silicon atom located at at least either of the terminal positions and/or intermediate positions to impart excellent properties as a synthetic resin modifier (when Y in (I) is an acetyl group or a hydrogen atom) or as a film former (when Y in (I) is a hydrogen atom): ##STR1## wherein Z represents a trivalent hydrocarbon residue which may contain oxygen, sulfur or/and nitrogen atom(s); X represents a lactone group of the formula, ##STR2## (wherein R represents a hydrogen atom or an alkyl group containing from 1 to 12 carbon atoms; a represents an integer from 4 to 6), k and L each represents an integer of 1 or more; and Y represents a hydrogen atom or an acetyl group.
    Type: Grant
    Filed: June 4, 1990
    Date of Patent: January 12, 1993
    Assignee: Shin-Etsu Chemical Company, Limited
    Inventors: Ichiro Ono, Hiroshi Yoshioka
  • Patent number: 5175214
    Abstract: The invention relates to a pressure-sensitive conductive elastomer compound which exhibits high resistance (insulating performance) when it is in non-pressed condition and the resistance of which, as the compound is pressed, varies according to the magnitude of the pressure. The compound comprises a matrix material having insulating and elastomeric properties and baked and carbonized conductive spherical particles of a macromolecular material incorporated and dispersed into the matrix material. The conductivity of the conductive particles varies according to the degree of their carbonization.
    Type: Grant
    Filed: November 27, 1991
    Date of Patent: December 29, 1992
    Assignee: Nitta Industries Corporation
    Inventors: Mitsuo Takaya, Kiyotaka Inoue, Katsumi Higuchi
  • Patent number: 5171786
    Abstract: The invention relates to thermoplastic PVC molding compounds containing specially synthesized silicone graft rubbers. These thermoplastic molding compounds show an excellent combination of properties such as impact strength at room temperature, impact strength at low temperatures and particularly high resistance to ageing under the effect of light, moisture and heat.
    Type: Grant
    Filed: June 23, 1989
    Date of Patent: December 15, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christian Lindner, Volker Damrath, Karl-Erwin Piejko, Karl-Heinz Ott
  • Patent number: 5166265
    Abstract: Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two-component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.
    Type: Grant
    Filed: March 1, 1990
    Date of Patent: November 24, 1992
    Assignee: Kansai Paint Company, Limited
    Inventors: Akimasa Nakahata, Nobushige Numa, Masahiro Yamane, Osamu Isozaki, Noboru Nakai
  • Patent number: 5157065
    Abstract: Thermoplastic molding compositions containing thermoplastic, aromatic polycarbonates, graft polymers, special phosphorus compounds, antidripping agents and optionally other thermoplasts as well as conventional additives are disclosed. The compositions are characterized by their flame resistance and mechanical properties. Also disclosed is a process for the preparation of the molding compositions.
    Type: Grant
    Filed: June 17, 1991
    Date of Patent: October 20, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl Fuhr, Friedemann Muller, Karl-Heinz Ott
  • Patent number: 5157058
    Abstract: Microporous waterproof and moisture vapor permeable products are described which are formed from a matrix having an internal microstructure which is coated with a hydrophobic material. A process is described including the steps of (1) applying to the surface of the matrix a liquid hydrophobic material, (2) allowing the liquid to penetrate into the microstructure and then (3) drying, vulcanizing or curing the product.
    Type: Grant
    Filed: June 7, 1991
    Date of Patent: October 20, 1992
    Assignee: Tetratec Corporation
    Inventors: Joseph E. Dillon, Mark E. Dillon
  • Patent number: 5149732
    Abstract: Rubber compositions are disclosed for integral attachment of polymeric and metallic materials. Improved bondability is attributed to the use of a selected base rubber blended with a selected class of inorganic or organic fillers, silane compounds and vulcanizing agents such that the finished composition is provided with a specified range of Mooney viscosities. Also disclosed is a method of hose-metal fitting connection by the application of the composition. Gas- and oil-impermeability characteristics are greatly enhanced.
    Type: Grant
    Filed: March 6, 1990
    Date of Patent: September 22, 1992
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventors: Shigeru Igarashi, Osamu Ozawa, Tetsu Kitami
  • Patent number: 5145901
    Abstract: Aqueous dispersions of a silicone crosslinkable into elastomeric state by elimination of water therefrom, include:(A) 100 parts of an oil-in-water emulsion of an .alpha.,.omega.-(dihydroxy)polydiorganosiloxane, stabilized with an anionic and/or nonionic surfactant;(B) 0.1 to 20 parts of an alkenyloxysilane;(C) 0.01 to 3 parts of a metal curing catalyst; and(D) 0 to 250 parts of a nonsiliceous inorganic filler material;and such emulsion having a pH of from 7 to 13 and a solids content of at least 40%; the subject emulsions are especially adapted for the production of paints and of silicone elastomer seals, and for the coating of pharmaceuticals, agricultural chemicals and food packaging materials.
    Type: Grant
    Filed: October 11, 1989
    Date of Patent: September 8, 1992
    Assignee: Rhone-Poulenc Chimie
    Inventor: Michel Feder