With Reactant Which Is Free Of An 1,2-epoxy Group And Which Contains A -n=c=x Group Or Polymer Thereof (x Is Chalcogen); Or With A Polyol And A Polycarboxylic Acid Or Reaction Product Thereof Which Is Free Of An 1,2 Epoxy Group Patents (Class 525/111)
  • Patent number: 11872589
    Abstract: The present invention is directed to a method for manufacturing a corrosion resistant wheel adapted for securement to a vehicle and/or trailer, including the steps of: providing a wheel body, applying a primary anticorrosion composition, and forming a primary anticorrosion layer.
    Type: Grant
    Filed: June 28, 2022
    Date of Patent: January 16, 2024
    Assignee: PRP Industries, Inc.
    Inventor: Phil Pierce
  • Patent number: 11773303
    Abstract: Solvent-based adhesive composition are disclosed, the compositions comprising (A) a polyester-urethane resin, (B) a phosphate ester compound, and (C) an aliphatic isocyanate curing agent. Methods for preparing a solvent-based adhesive composition, the methods comprising providing a polyester-urethane resin, providing a phosphate ester compound, mixing the polyester-urethane resin and phosphate ester compound to form a resin mixture, diluting the resin mixture in a solvent to form a diluted resin mixture having an application solid content of from 25 to 55 weight percent, based on the total weight of the diluted resin mixture, and curing the diluted resin mixture with an aliphatic isocyanate curing agent at a mix ratio (parts by weight resin mixture before dilution:parts by weight aliphatic isocyanate curing agent) of from 100:1 to 100:12. Laminates prepared comprising the solvent-based adhesives and according to the disclosed methods are also disclosed.
    Type: Grant
    Filed: April 4, 2018
    Date of Patent: October 3, 2023
    Assignees: Dow Global Technologies LLC, Rohm and Haas Company
    Inventors: Wenwen Li, Joseph J. Zupancic, Paul Clark, Thorsten Schmidt
  • Patent number: 11624013
    Abstract: Methods in which toughness improvers based on terminally blocked polyurethane prepolymers are used to increase the maximum linear expansion of single component heat-curing epoxy resin compositions, in particular for joining substrates having different thermal expansion coefficients, in particular in the framework of transport agents or white goods.
    Type: Grant
    Filed: December 18, 2018
    Date of Patent: April 11, 2023
    Assignee: SIKA TECHNOLOGY AG
    Inventors: Urs Rheinegger, Elyes Jendoubi, Dominique Gallo, Christian Krüger
  • Patent number: 11285708
    Abstract: Heat resistant brittle films can be made from impact-modified poly(meth)acrylimide, and forgery prevention labels can contain the heat resistant brittle films. The films can be advantageously prepared by extrusion and, depending on the desired purpose, can be designed to be transparent, translucent, or entirely non-transparent, e.g., white. Ideally, the brittle films and the forgery prevention labels containing the brittle films have no intended break points such as slits, perforation, etc.
    Type: Grant
    Filed: February 7, 2020
    Date of Patent: March 29, 2022
    Assignees: Röhm GmbH, Roehm America LLC
    Inventors: Ghirmay Seyoum, Markus Parusel, Kim Struwe, Anderson Costa, Claude Guénanten, Helmut Häring
  • Patent number: 11203681
    Abstract: Disclosed are new precursors of recyclable cross-linked diene elastomers including chain-end units with furanyl groups, their use in the preparation of the recyclable elastomers and their process of preparation. Also disclosed are new recyclable cross-linked diene elastomers, their preparation process and their uses.
    Type: Grant
    Filed: March 29, 2018
    Date of Patent: December 21, 2021
    Assignees: UNIVERSITÉ DE BORDEAUX, INSTITUT POLYTECHNIQUE DE BORDEAUX, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
    Inventors: Frédéric Peruch, Pierre Berto, Stéphane Grelier
  • Patent number: 11180674
    Abstract: The present invention relates to a powder coating composition for preparing a dielectric coating. The powder coating composition includes: (a) an epoxy functional polymer; (b) a poly-carboxylic acid functional polyester polymer reactive with the epoxy functional polymer and which has an acid value of less than 100 mg KOH/g; and (c) a poly-carboxylic acid functional (meth)acrylate polymer reactive with the epoxy functional polymer. Further, if a colorant is present, the powder coating composition comprises 35 weight % or less of the colorant, based on the total solids weight of the coating composition.
    Type: Grant
    Filed: April 6, 2018
    Date of Patent: November 23, 2021
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Anthony Michael Chasser, Paul F. Cheetham, Holli Allison Gonder, Stacey Lynn Orzech, Brian Edward Woodworth, Brent Allen Schwartz, Kevin Lee Ford
  • Patent number: 11168187
    Abstract: A fiber sizing agent includes: a vinyl ester resin (A) having an alkoxy polyoxyalkylene structure and a urethane bond; and an aqueous medium. The fiber sizing agent has excellent fiber sizing properties for various fibers such as glass fibers and carbon fibers. A molded article obtained from a molding material including the fiber sizing agent is excellent in various physical properties such as bending strength, compressive strength, and interlaminar shear strength, and thus can be used, for example, for an automobile member, an aircraft member, a windmill member, and an industrial member.
    Type: Grant
    Filed: May 8, 2018
    Date of Patent: November 9, 2021
    Assignee: DIC CORPORATION
    Inventor: Kenji Nagao
  • Patent number: 10538610
    Abstract: A thermosetting resin composition using a transesterification reaction as a curing reaction, which has a good curability and can be used in various applications. A thermosetting resin composition comprising a polymer (A) composed of a monomer having a (meth) acrylic acid tertiary alkyl ester and a monomer having a hydroxyl group as a structural unit, and a transesterification catalyst (B) as an essential component, and being organic solvent-type or water-borne, wherein the polymer (A) has a glass transition temperature of 80° C. or lower.
    Type: Grant
    Filed: November 30, 2018
    Date of Patent: January 21, 2020
    Assignee: KYOEISHA CHEMICAL CO., LTD.
    Inventors: Yuya Moriwaki, Kosuke Asada, Masaru Donkai
  • Patent number: 10322209
    Abstract: Biological-based polyurethanes and methods of making the same. The polyurethanes are formed by reacting a biodegradable polyisocyanate (such as lysine diisocyanate) with an optionally hydroxylated biomolecule to form polyurethane. The polymers formed may be combined with ceramic and/or bone particles to form a composite, which may be used as an osteoimplant.
    Type: Grant
    Filed: May 8, 2018
    Date of Patent: June 18, 2019
    Assignee: Warsaw Orthopedic, Inc.
    Inventors: David Knaack, John Winterbottom, David R. Kaes, Todd Boyce, Lawrence A. Shimp
  • Patent number: 10216045
    Abstract: Disclosed is a liquid crystal display (LCD) device. The LCD device includes a first substrate and a second substrate facing each other, a liquid crystal layer between the first substrate and the second substrate, an alignment layer on at least one of the first and second substrates for alignment of liquid crystals in the liquid crystal layer, and a sealant in an edge area of each of the first and second substrates to bond the first substrate to the second substrate, the sealant including a diene compound.
    Type: Grant
    Filed: January 27, 2017
    Date of Patent: February 26, 2019
    Assignee: LG Display Co., Ltd.
    Inventors: Sung Jin Kim, Hyun Jeong Park
  • Patent number: 10195641
    Abstract: An electrostatic powder coating method includes spraying a charged powder coating material including powder particles that contain a thermosetting resin and a thermosetting agent, and an external additive that includes oxide particles containing at least one of titania and alumina to electrostatically attach the powder coating material to an object to be coated, and heating the powder coating material that is electrostatically attached to the object to be coated to thereby form a coating film, wherein a content Ac of the oxide particles in the powder coating material that is electrostatically attached to the object to be coated and a content Ao of the oxide particles in the powder coating material before being sprayed satisfy a relationship of Expression: Ao×0.80?Ac?Ao×1.20.
    Type: Grant
    Filed: April 5, 2016
    Date of Patent: February 5, 2019
    Assignee: FUJI XEROX CO., LTD.
    Inventors: Takahiro Ishizuka, Takeshi Agata, Susumu Yoshino, Shigeru Seitoku
  • Patent number: 10174155
    Abstract: A method and system for oxygen molecule scavenging is disclosed. The system employs as a novel copolymer as the reducing agent for oxygen molecules. The copolymer is the polymerization product of cyclic aliphatic monomer and unsaturated functional polymer.
    Type: Grant
    Filed: February 27, 2017
    Date of Patent: January 8, 2019
    Assignee: PolyOne Corporation
    Inventors: Ling Hu, Roger W. Avakian
  • Patent number: 9993579
    Abstract: Biological-based polyurethanes and methods of making the same. The polyurethanes are formed by reacting a biodegradable polyisocyanate (such as lysine diisocyanate) with an optionally hydroxylated biomolecule to form polyurethane. The polymers formed may be combined with ceramic and/or bone particles to form a composite, which may be used as an osteoimplant.
    Type: Grant
    Filed: July 6, 2017
    Date of Patent: June 12, 2018
    Assignee: Warsaw Orthopedic, Inc.
    Inventors: David Knaack, John Winterbottom, David R. Kaes, Todd M. Boyce, Lawrence A. Shimp
  • Patent number: 9963533
    Abstract: A copolymer is provided, which includes a chemical structure of: R is C1-6 alkylene group. T is a terminal group including C1-6 alkyl group, C3-6 cycloalkyl group, or C6-12 aromatic group. l is 0.05 to 0.3, m is 0.1 to 0.2, n is 0.5 to 0.8, l+m+n=1, x is 40 to 100, and o is 10 to 120. An epoxy resin composite is also provided, which includes 100 parts by weight of epoxy resin and 1 to 20 parts by weight of toughness enhancer such as the above copolymer.
    Type: Grant
    Filed: December 22, 2015
    Date of Patent: May 8, 2018
    Assignee: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE
    Inventors: Chien-Pang Wu, Li-Cheng Jheng, Chia-Hao Li, Jyh-Horng Wu, Hsi-Hsin Shih
  • Patent number: 9920215
    Abstract: A nonaqueous coating material composition and coatings thereof are provided. The composition contains an oligomeric and/or polymeric compound (A) having at least two hydroxyl groups, an oligomeric and/or polymeric compound (B) having at least two alkylidene-1,3-dioxolan-2-one groups of formula (I?), and a catalyst (D) where # stands for the attachment to the polymer backbone and R1, R2 independently of one another are hydrogen, C1-C6 alkyl, C1-C4 alkoxy-C1-C4 alkyl, C5-C6 cycloalkyl, phenyl or phenyl-C1-C4 alkyl; R3 is hydrogen, C1-C6 alkyl, C1-C4 alkoxy-C1-C4 alkyl, C5-C6 cycloalkyl, phenyl, or phenyl-C1-C4 alkyl; A is a chemical bond or C1-C4 alkanediyl; X is O or NR7; Z is a chemical bond, PO2, SO2, or C?O, Y is a chemical bond, CH2, or CHCH3, and R7 where present is C1-C6 alkyl.
    Type: Grant
    Filed: August 8, 2014
    Date of Patent: March 20, 2018
    Assignee: BASF Coatings GmbH
    Inventors: Reinhold Clauss, Rainer Klopsch, Susanne Katharina Kreth, Britta Schnieders, Ursula Heimeier, Cathrin Corten, Peter Hoffmann, Aaron Flores-Figueroa, Kristin Michel, Annika Werning
  • Patent number: 9783626
    Abstract: The present invention provides a photosensitive resin composition having good developing performance, which belongs to the technical field of polymer material, so as to solve the problem of the poor developing performance of the current photosensitive resin composition. The photosensitive resin composition comprising: based on the total mass of the photosensitive resin composition, 5% to 45% of an alkali-soluble resin, 5% to 40% of an unsaturated monomer having polyffunctional groups, 1% to 10% of a photoinitiator, 10% to 60% of a pigment dispersion, 0% to 5% of an addition, and 20% to 70% of a solvent. In the present invention, tetrahydrofuran groups (flexible functional group) is introduced into the alkali-soluble resin by highly reactive unsaturated monomer, which can improve the developing property of the alkali-soluble resin and can produce a photoresist film with a smooth surface and no corrosion on its side wall.
    Type: Grant
    Filed: February 21, 2017
    Date of Patent: October 10, 2017
    Assignee: BOE TECHNOLOGY GROUP CO., LTD.
    Inventors: Shan Chang, Zhuo Zhang, Xuelan Wang, Chen Tang
  • Patent number: 9617375
    Abstract: A method and system for oxygen molecule scavenging is disclosed. The system employs as a novel copolymer as the reducing agent for oxygen molecules. The copolymer is the polymerization product of cyclic aliphatic monomer and unsaturated functional polymer.
    Type: Grant
    Filed: May 22, 2013
    Date of Patent: April 11, 2017
    Assignee: PolyOne Corporation
    Inventors: Ling Hu, Roger W. Avakian
  • Patent number: 9617367
    Abstract: The present invention provides an alkali-soluble resin having good developing performance, which belongs to the technical field of polymer material, so as to solve the problem of the poor developing performance of the current alkali-soluble resin and the photosensitive composition made of the same; and a method for preparing the same. In the present invention, tetrahydrofuran groups (flexible functional group) is introduced into the alkali-soluble resin by highly reactive unsaturated monomer, which can improve the developing property of the alkali-soluble resin and can produce a photoresist film with a smooth surface and no corrosion on its side wall.
    Type: Grant
    Filed: June 30, 2014
    Date of Patent: April 11, 2017
    Assignee: BOE TECHNOLOGY GROUP CO., LTD.
    Inventors: Shan Chang, Zhuo Zhang, Xuelan Wang, Chen Tang
  • Patent number: 9150742
    Abstract: The present invention describes a linear polyester resin comprising a di-epoxide monomer and a di-acid monomer useful in energy curable lithographic inks. The linear polyester resin exhibits a number average molecular weight less than 20,000. The present invention also describes an energy curable lithographic ink formulation including the linear polyester resin. The ink exhibits improved print density, print contrast, water window and rheological (total body) characteristics.
    Type: Grant
    Filed: August 30, 2012
    Date of Patent: October 6, 2015
    Assignee: Sun Chemical Corporation
    Inventors: Michael J. Jurek, Joseph Malanga
  • Patent number: 8962771
    Abstract: Elastomer composites are prepared by wetting particles of a natural or synthetic rubber with a liquid one-component moisture-curable resin composition and then exposing the wetted particles to moisture to cure the resin composition. The moisture-curable resin composition comprises (a) an isocyanate-terminated polyurethane prepolymer having an isocyanate content of from 0.5 to 12% by weight and (b) from 1 to 30%, based on the combined weight of components (a) and (b), of an epoxide or lactone compound having a molecular weight of from about 70 to about 1000 and which is miscible in the prepolymer at the relative proportions thereof that are present. In addition, the composition contains no more than 0.1% by weight of compounds having a primary or secondary amino group.
    Type: Grant
    Filed: May 26, 2011
    Date of Patent: February 24, 2015
    Assignee: Dow Global Technologies LLC
    Inventors: Blndu Radhakrishnan, William Aaron Koonce
  • Publication number: 20150045510
    Abstract: The invention relates to epoxy adhesives. An epoxy adhesive is provided that simultaneously has low E-modulus and high glass temperature. Such adhesives are useful in the manufacture of large machinery (e.g., automobiles), and are useful for bonding different materials, such as metal and carbon fiber composite. The cured epoxy adhesive can be formulated to have an E-modulus of less than 1000 MPa, and a glass transition temperature of at least 80 C. The epoxy adhesive comprises a capped polyurethane pre polymer, a core shell rubber, and polyetheramine-epoxy adduct.
    Type: Application
    Filed: March 27, 2013
    Publication date: February 12, 2015
    Inventors: Christof Braendli, Andreas Lutz, Gary L. Jialanella
  • Patent number: 8952097
    Abstract: A composition including at least one curable structural adhesive, and at least one chemically cross-linked elastomer, wherein the chemically cross-linked elastomer is present in the structural adhesive as penetrating polymer network. Such a composition constitutes a so-called shape memory material and is suitable for reinforcing cavities in structural components, such as, for example, in automobile bodies.
    Type: Grant
    Filed: September 26, 2012
    Date of Patent: February 10, 2015
    Assignee: Sika Technology AG
    Inventors: Jürgen Finter, Matthias Gössi
  • Patent number: 8916656
    Abstract: A glass printing ink and a glass printing lacquer comprising at least one pigment, at least one photoinitiator, at least two resins and radicial photoinitiators. One resin is an epoxy resin having an average molecular weight based on bisphenol A, diluted in a UV hardening monomer. The other resin is a resin which contains free functional amino, hydroxy, epoxy, acid, acid anhydride and/or acrylate groups. Also, the use of the glass printing ink and glass printing lacquer when printing a glass substrate and to a method for printing a glass substrate.
    Type: Grant
    Filed: July 1, 2013
    Date of Patent: December 23, 2014
    Assignee: Marabu GmbH & Co., KG
    Inventors: Saskia Lehmann, Wolfgang Schaefer
  • Patent number: 8901250
    Abstract: The present invention relates to a powder coating composition for low temperature cure which comprises a mixture of a carboxylic acid group containing first polyester; at least one of a second polyester having a glass transition temperature ?45° C. and/or a crystalline polycarboxylic acid; a glycidyl group containing acrylic copolymer; a further compound and/or resin having functional groups readable with the carboxylic acid groups; and a thermosetting curing catalyst. These thermosetting powder coatings are designed for coating heat-sensitive substrates such as wood, fiber board and other materials which can not withstand the excessive heat/time conditions necessary to cure traditional coatings. The powder coatings of the invention, when cured at temperatures below 150° C., produce a finish which exhibits a high gloss, smooth surface along with an outstanding hardness and weatherability.
    Type: Grant
    Filed: June 28, 2010
    Date of Patent: December 2, 2014
    Assignee: Allnex Belgium S.A.
    Inventor: Luc Moens
  • Patent number: 8722767
    Abstract: A coating composition, an anticorrosion film formed by the composition, as well as an anticorrosive article, are disclosed. The coating composition comprises 1-35% by weight of one or more fluoropolymer; 1-70% by weight of one or more epoxy resin; 5-70% by weight of one or more polyamideimide; 0-40% by weight an auxiliary binder consisting of one or more of polyethersulfone, polyphenylene sulfide, polyamide, polyimide, polyether ether ketone, polyetherimide, polyurethane, alkyd resin, polyester, or acrylic polymers; and, based on 100 parts by weight of the above components, 100-400 parts by weight of solvent.
    Type: Grant
    Filed: September 30, 2010
    Date of Patent: May 13, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventor: Xuepu Mao
  • Patent number: 8653202
    Abstract: An adhesive composition for semiconductor containing an organic-solvent-soluble polyimide (a), an epoxy compound (b) and a hardening accelerator (c), wherein per 100 wt parts of the epoxy compound (b), there are contained 15 to 90 wt parts of the organic-solvent-soluble polyimide (a) and 0.1 to 10 wt parts of the hardening accelerator (c), wherein the epoxy compound (b) contains a compound being liquid at 25° C. under 1.013×105 N/m2 and a compound being solid at 25° C. under 1.013×105 N/m2, and wherein a ratio of compound being liquid based on all the epoxy compounds is 20 wt % or more and 60 wt % or less.
    Type: Grant
    Filed: June 5, 2006
    Date of Patent: February 18, 2014
    Assignee: TORAY Industries, Inc.
    Inventors: Koichi Fujimaru, Toshihisa Nonaka
  • Patent number: 8450433
    Abstract: Provided are a resin composition for the manufacture of marble chips including a halogenated epoxy resin binder and showing high heat resistance, high chemical resistance, high impact resistance, high specific gravity and high transparency, a marble chip manufacturing method using the resin composition and an artificial marble made from marble chips.
    Type: Grant
    Filed: August 13, 2010
    Date of Patent: May 28, 2013
    Inventor: Young-Min Kim
  • Publication number: 20130037213
    Abstract: The present disclosure relates to impact strength modifiers, the derivative products thereof, and the use thereof in producing two-component epoxy resin compositions. The disclosure in particular relates to amino group terminated impact strength modifiers prepared by reacting a polyurethane prepolymer having isocyanate groups, a primary diamine, and optionally at least one Michael acceptor. The two-component epoxy resin compositions thus formulated are characterized by a great increase in impact strength while retaining an acceptable tensile shear strength. The impact strength modifiers according to the disclosure and the epoxy resin compositions comprising same are in particular suitable for vehicle manufacturing.
    Type: Application
    Filed: September 4, 2012
    Publication date: February 14, 2013
    Applicant: Sika Technology AG
    Inventors: Karsten FRICK, Jürgen FINTER, Andreas KRAMER, Ulrich GERBER
  • Patent number: 8148474
    Abstract: An object of the present invention is to provide a golf ball which has excellent durability and wear-resistance and provides an excellent shot feeling. The present invention is directed to a golf ball comprising: a core; and a cover covering the core, wherein the cover is formed from a cover composition containing a thermoplastic polyurethane (A), a polyisocyanate (B) having at least two isocyanate groups, and a polyhydroxyether (C) as a resin component, and wherein the core has a surface hardness of 85 or smaller in JIS-C hardness.
    Type: Grant
    Filed: December 24, 2008
    Date of Patent: April 3, 2012
    Assignee: SRI Sports Limited
    Inventors: Keiji Ohama, Hirotaka Nakamura, Toshiyuki Tarao
  • Patent number: 8133956
    Abstract: The object of the present invention is to provide a golf ball which has excellent durability and wear-resistance and provides an excellent shot feeling. The present invention provides a golf ball comprising: a core consisting of a center and at least one intermediate layer covering the center; and a cover covering the core, wherein the cover is formed from a cover composition containing a thermoplastic polyurethane (A), a polyisocyanate compound (B) having at least two isocyanate groups, and a polyhydroxyether (C) as a resin component, wherein the cover composition has a slab hardness from 20 to 55 in shore D hardness, and the cover has a thickness from 0.1 mm to 1.5 mm.
    Type: Grant
    Filed: December 24, 2008
    Date of Patent: March 13, 2012
    Assignee: SRI Sports Limited
    Inventors: Kazuya Kamino, Keiji Ohama, Toshiyuki Tarao
  • Publication number: 20120007259
    Abstract: A curing agent for epoxy resins that is comprised of the reaction product of an amine, an epoxy resin, and an elastomer-epoxy adduct; compositions containing the curing agent and an epoxy resin; the compositions are useful in electronic displays, circuit boards, semi conductor devices, flip chips and other applications.
    Type: Application
    Filed: September 20, 2011
    Publication date: January 12, 2012
    Applicant: TRILLION SCIENCE, INC.
    Inventors: Yurong Ying, John J. McNamara, Jing Liang, Rong-Chang Liang
  • Patent number: 8053533
    Abstract: A solvent-free polyimide silicone resin composition, and a cured product thereof, includes (A) a polyimide silicone resin having recurring units having a specific type of structure and having a weight average molecular weight of 5,000 to 150,000, (B) an epoxy resin, and (C) an epoxy resin curing agent wherein the resin composition having a fluidity at 25° C. and is free of a solvent.
    Type: Grant
    Filed: August 26, 2009
    Date of Patent: November 8, 2011
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Yoshinori Yoneda, Michihiro Sugo
  • Publication number: 20110245393
    Abstract: The invention pertains to low profile additives (“LPA”) comprising branched polymers having a weight average molecular weight (Mw) of at least about 20,000 grams/mole and a number average molecular weight (Mn) of at least about 3,000 grams/mole and methods for making the LPAs. The invention further concerns compositions comprising LPAs synthesized from one or more Bifunctional monomers and one or more branching agents. Also, disclosed are thermosettable resinous compositions and molded articles comprising the LPAs.
    Type: Application
    Filed: June 17, 2011
    Publication date: October 6, 2011
    Inventors: Husam A.A. Rasoul, Dejan D. Andjelkovic, Dennis H. Fisher
  • Publication number: 20110122343
    Abstract: Provided are a pressure-sensitive adhesive (PSA) composition including an interpenetrating polymer network structure in a cured state, and including an acrylic resin and a crosslinking agent component that consists of a bifunctional crosslinking agent, a polarizer and a liquid crystal display. Provided are the PSA composition, the polarizer including a cured product of the PSA composition, and the liquid crystal display, which have excellent workability and optical properties, durability and reliability, at high temperature or humidity condition, and significantly increase productivity of optical members such as a polarizer, since the time-dependent change of the pressure-sensitive adhesive strength is rapidly ended after fabrication.
    Type: Application
    Filed: July 16, 2009
    Publication date: May 26, 2011
    Inventors: Min Soo Park, In Cheon Han, Ki Seok Jang
  • Patent number: 7932322
    Abstract: The invention relates to viscosifiers, especially terminated polymers that have functional terminal groups, said polymers being pre-extended by polyamines, polymercaptans, (poly)aminoalcohols, (poly)mercaptoalcohols or (poly)aminomercaptans and being reacted to give polymers that are terminated by other functional groups. The viscosifiers have a low content in educts or educt descendants that deteriorate the properties of compositions. They are also charaterized in that the formation of high-molecular addition products is considerably reduced or even excluded so that products obtained have low viscosity and good storage stability. The epoxy-terminated polymer of formula (I) is especially preferred.
    Type: Grant
    Filed: December 21, 2007
    Date of Patent: April 26, 2011
    Assignee: Sika Technology AG
    Inventors: Andreas Kramer, Jan Olaf Schulenburg, Jürgen Finter, Norman Blank
  • Patent number: 7915344
    Abstract: Viscosifiers, especially terminated polymers that have functional terminal groups, the polymers being pre-extended by polyols and being reacted to give polymers that are terminated by other functional groups, are produced. The viscosifiers have a low content in educts or educt descendants that deteriorate the properties of compositions. The formation of high-molecular addition products is considerably reduced or even excluded so that the products obtained have low viscosity and good storage stability. The epoxy-terminated polymer of formula (I) is especially preferred.
    Type: Grant
    Filed: December 21, 2007
    Date of Patent: March 29, 2011
    Assignee: Sika Technology AG
    Inventors: Andreas Kramer, Jan Olaf Schulenburg
  • Patent number: 7772334
    Abstract: A crosslinker for polymerizing a film-forming material including an alkyl or aromatic compound comprising at least two functional groups reactive with a film-forming resin and at least one pendent group having a nonionic metal coordinating structure. Coating compositions can include a film-forming material and the crosslinker. The coating compositions can be used to coat a substrate, such as a metal substrate. Applied coating layers on substrates can be cured to form coating films.
    Type: Grant
    Filed: October 26, 2006
    Date of Patent: August 10, 2010
    Assignee: BASF Coatings GmbH
    Inventors: Timothy S. December, Sergio Gonzalez, Günther Ott, Karl-Heinz Grosse-Brinkhaus
  • Publication number: 20100062275
    Abstract: Disclosed are ionomer compositions neutralized by a combination of cesium and potassium that have antistatic properties. Also disclosed are articles, including laminates and monolayer or multilayer structures comprising such compositions to which neither powders nor dusts easily adhere electrostatically.
    Type: Application
    Filed: September 9, 2008
    Publication date: March 11, 2010
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventors: Kazuyuki Nakata, David J. Walsh
  • Patent number: 7612130
    Abstract: A composition contains a polyester; an aromatic epoxy compound, in an amount sufficient to provide 5 to 300 milliequivalents of epoxy per kilogram of polyester; and 0.5 to 6 weight percent, based on the weight of the polyester, and an ethylene-glycidyl methacrylate containing copolymer; and/or a copolyester copolymer, wherein the copolyester comprises, based on the weight of the copolyester, 15 to 95 weight percent of polyester units derived from the reaction of a C6-C24 aromatic dicarboxylic acid or a chemical equivalent thereof with a C2-C6 aliphatic diol, and 5 to 85 weight percent of polyester units derived from the reaction of a C6-C24 aromatic dicarboxylic acid or a chemical equivalent thereof with a poly(alkylene oxide) glycol having a molecular weight of 400-6,000 and a carbon to oxygen ratio of 2.0-4.3. The compositions have excellent hydrolytic resistance, and are suitable for making automotive and electronic parts.
    Type: Grant
    Filed: October 16, 2006
    Date of Patent: November 3, 2009
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventor: Sung Dug Kim
  • Publication number: 20090264558
    Abstract: The invention relates to differently blocked polyurethane polymers of formula, to their use as impact resistance modifiers, to heat-curable epoxy resin compositions containing said impact resistance modifiers and to methods for the production of said compositions. The invention also relates to bonding methods using said compositions and to articles produced by said methods.
    Type: Application
    Filed: October 24, 2007
    Publication date: October 22, 2009
    Applicant: SIKA TECHNOLOGY AG
    Inventors: Andreas Kramer, Jurgen Finter, Urs Rheinegger, Jan Olaf Schulenburg
  • Patent number: 7339013
    Abstract: Polymers which comprise polymer chains of terpolymer type which are constituted by poly(ethylene oxide) (PEO) and poly(propylene oxide) (PPO) of PEO-PPO-PEO form, which are modified at their termini by groups which can essentially be other chains of PEO-PPO-PEO, acid segments, amine groups or PEOs, these chains being linked to the terpolymer chains via chemical bridges which are constituted by urethane bridges, urea bridges, allophanate bridges and biuret bridges, and which comprise more than 80% by weight of said PEO-PPO-PEO. Thermoreversible physical gels of high viscosification index, which contain these polymers, and their uses. Preparation of these polymers and of these gels.
    Type: Grant
    Filed: December 13, 2004
    Date of Patent: March 4, 2008
    Assignee: Polymerexpert SA
    Inventors: Anne Pagnoux, Marc Dolatkhani, Patricia Chaffaux
  • Patent number: 7323521
    Abstract: Comb polymers prepared by reacting an epoxy resin and a lactone are disclosed. These comb polymers find particular application as additives for powder coating compositions, to improve various performance properties thereof. Powder coating composition comprising the described comb polymers are also disclosed.
    Type: Grant
    Filed: March 19, 2004
    Date of Patent: January 29, 2008
    Assignee: PP6 Industries Ohio, Inc.
    Inventors: Michael J. Ziegler, Anthony M. Chasser, Jackie L. Kulfan
  • Patent number: 7193010
    Abstract: An aqueous resin composition satisfying the following criteria (I)–(III). (I) The aqueous resin composition contains (a) an aqueous dispersion of a polyurethane resin obtained from a macromolecular polyol, organic polyisocyanate, chain extending agent and 2,2-dimethylolbutanoic acid, and, if required, (b) an aqueous dispersion of an acrylic resin. (II) When the resin comprising this aqueous resin composition contains mainly a polyurethane resin, the inherent viscosity (?inh) of the polyurethane resin measured at a concentration of 0.5 g/dL in dimethylformamide solution is in the range of 0.2–0.7 dL/g. After this aqueous resin composition is dried, the elastic modulus at 25° C. of the film obtained by heat treatment at 80° C. for 8 hours is in the range of 8.0×106–5.0×108 Pa, and the elastic modulus at 80° C. is 8.0×107 Pa or less.
    Type: Grant
    Filed: September 29, 2003
    Date of Patent: March 20, 2007
    Assignee: Kuraray Co., Ltd.
    Inventors: Mitsuru Kato, Yukitoshi Higashinaka
  • Patent number: 7071264
    Abstract: This invention relates to rapid curing coating compositions that are particularly useful for automotive OEM and refinish applications. The coating composition includes a crosslinkable component that contains a novel highly branched acrylic polymer, and a crosslinking component that contains conventional crosslinking agents, such as polyisocyanate and melamine. This invention is also directed to a process for producing coatings from the rapid curing coating compositions. These compositions are especially useful in providing hard highly crosslinked coatings.
    Type: Grant
    Filed: July 7, 2004
    Date of Patent: July 4, 2006
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Thomas Robert Darling, Robert John Barsotti, Alexei A. Gridnev, Patricia Mary Ellen Sormani
  • Patent number: 7045575
    Abstract: A cationic electro-deposition coating composition, comprises: Component (A): an amino-containing epoxy resin (A) obtained by adding an amino-containing compound (a-2) to an epoxy resin (a-1) having an epoxy equivalent of from 400 to 3000, Component (B): an amino-containing acrylic resin (B) obtained by adding an amino-containing compound (b-4) to a copolymer resin obtained by radical copolymerization of, as essential components, a polylactone-modified hydroxyl-containing radical copolymerizable monomer (b-1), which is obtained by adding a lactone to a hydroxyl-containing acrylic monomer (b), and glycidyl (meth)acrylate (b-2), and another radical copolymerizable monomer (b-3); and Component (C): a blocked polyisocyanate curing agent (C) as a curing component, the component (A), component (B) and component (C) being added in amounts of 5 to 80 wt %, 5 to 80 wt % and 10 to 40 wt %, respectively, based on the total solid content of the components (A), (B) and (C).
    Type: Grant
    Filed: February 14, 2003
    Date of Patent: May 16, 2006
    Assignee: Kansai Paint Co. Ltd.
    Inventors: Hidenori Sawada, Hideki Iijima, Shigeo Nishiguchi, Koji Kamikado
  • Patent number: 6998011
    Abstract: In the preparation of an improved adhesive composition, an epoxy-based prepolymer is obtained by the reaction of one or more epoxy resins with amino-terminated polyethers and/or carboxyl-terminated butadiene-nitrile rubbers. In one embodiment of the invention, both a solid epoxy resin and a liquid epoxy resin, each of which is a diglycidyl ether of a polyphenol such as bisphenol A, are used. The epoxy-based prepolymer is mixed with an acrylate-terminated urethane resin (preferably, one based on a polyol having a number average molecular weight of at least about 400) and a heat-activated latent curing agent to make an adhesive composition which can be pumpable at room temperature. Curable adhesives capable of expansion to about 100% with high impact resistance after curing may be obtained by inclusion of expanding agents such as expandable microspheres.
    Type: Grant
    Filed: March 13, 2003
    Date of Patent: February 14, 2006
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Rainer Schoenfeld, James F. Hubert, Murteza Erman
  • Patent number: 6977279
    Abstract: The present invention relates to novel solventless reactive systems curable at room temperature, based on blocked polyisocyanates, primary amines, compounds with oxirane groups, and 2,3-dimethyl-3,4,5,6-tetrahydropyrimidine, and to processes for the preparation of these solventless reactive systems curable at room temperature.
    Type: Grant
    Filed: July 17, 2000
    Date of Patent: December 20, 2005
    Assignee: Bayer Aktiengesellschaft
    Inventors: Jörg Tillack, Wolfgang Puetz, Lutz Schmalstieg
  • Patent number: 6924328
    Abstract: A coating composition includes a thermoplastic dispersion and a stabilizer. The stabilizer includes the reaction product of an epoxy resin and an acid, wherein the stabilizer has at least two oxirane functional groups per molecule.
    Type: Grant
    Filed: August 20, 2002
    Date of Patent: August 2, 2005
    Assignee: Valspar Sourcing, Inc.
    Inventors: Jason M. Legleiter, Robert M. O'Brien
  • Patent number: 6913043
    Abstract: A composition comprising by weight: 70 to 96% of at least one polyamide chosen from PA-11, PA-12, aliphatic polyamides resulting from the condensation of an aliphatic diamine having from 6 to 12 carbon atoms and an aliphatic diacid having from 9 to 12 carbon atoms, and 11/12 copolyamides having either more than 90% of nylon-11 units or more than 90% of nylon-12 units; 4 to 10% of a plasticizer; 0 to 25% of an NBR or H-NBR elastomer; and the sum of the amount of plasticizer and the amount of elastomer is between 4 and 30%; can be manufactured by melt-blending the various constituents using standard techniques for thermoplastics. The composition is particularly useful for pipes used in the operation of offshore oil and gas fields. They exhibit very good ageing resistance. They are also useful for simpler pipes in motor vehicles, these compositions withstanding the ageing caused by the temperature under the bonnet of motor vehicles and the nature of the fluids transported.
    Type: Grant
    Filed: March 4, 2003
    Date of Patent: July 5, 2005
    Assignee: ARKEMA
    Inventors: Bernard Jacques, Bernard Pees, Michael Werth
  • Patent number: 6905778
    Abstract: A powder coating composition includes an acid-functional polyester resin and a matting agent selected from styrene-maleic anhydride copolymers and acid-functional acrylic resins. The compositions provide low gloss finishes at low curing temperatures, as well as consistent gloss over a wide range of curing temperatures.
    Type: Grant
    Filed: October 9, 2002
    Date of Patent: June 14, 2005
    Assignee: Rohm and Haas Company
    Inventors: Tina L. Tullos, Brian T. Myers, Charles P. Tarnoski