With Additional Heterocyclic Reactant Free Of 1,2-epoxy Group Patents (Class 525/114)
  • Patent number: 10858549
    Abstract: The present invention relates to a pressure-sensitive adhesive tape comprising or consisting of a moisture-curing composition comprising or consisting of: A 5 to 60 parts by weight of at least one film-former component; B 40 to 95 parts by weight of at least one epoxide component; C 10 to 500 parts by weight of at least one moisture-activatable curing agent; D optionally 0.1 to 15 parts by weight of at least one stabilizer, and E optionally 0.1 to 200 parts by weight of at least one additive, based in each case on the moisture-curing composition, with the parts by weight of components A and B adding up to 100 and with the moisture-curing composition being characterized in that the moisture-activatable hardener C comprises or consists of at least one blocked amine. The invention further relates to a method for assembling two components using such adhesive tape.
    Type: Grant
    Filed: April 18, 2017
    Date of Patent: December 8, 2020
    Assignee: TESA SE
    Inventors: Christian Schuh, Olga Kirpicenok, Yvonne Querdel
  • Patent number: 8901207
    Abstract: It is an object of the present invention to provide an adhesive for electronic components that prevents warpage of electronic components and reflow cracks even in the case of bonding thin electronic components. The present invention relates to an adhesive for electronic components, comprising: an epoxy compound having an aliphatic polyether backbone and a glycidyl ether group; an epoxy group-containing acrylic polymer; an episulfide compound; and a curing agent, wherein the amount of the episulfide compound is 1 parts by weight or more, and less than 30 parts by weight relative to 100 parts by weight of the epoxy compound having an aliphatic polyether backbone and a glycidyl ether group.
    Type: Grant
    Filed: January 29, 2010
    Date of Patent: December 2, 2014
    Assignee: Sekisui Chemical Co., Ltd.
    Inventors: Akinobu Hayakawa, Hideaki Ishizawa, Kohei Takeda, Ryohei Masui
  • Patent number: 8784711
    Abstract: The invention relates to a process for preparing a reinforced and reactive thermoplastic composition having a continuous phase which is based on at least one thermoplastic polymer and dispersed in which is a discontinuous phase based on at least one reactive reinforcing agent that may be immiscible with said at least one thermoplastic polymer, and also to a composition obtained by this process.
    Type: Grant
    Filed: August 2, 2011
    Date of Patent: July 22, 2014
    Assignee: Hutchinson
    Inventors: Nicolas Garois, Philippe Sonntag, Grégory Martin, Matthieu Vatan, Jacques Drouvroy
  • Patent number: 8742018
    Abstract: A thermoset resin, including the reaction product of: an epoxy resin mixture including at least one cycloaliphatic epoxy resins; a cycloaliphatic anhydride hardener; and a catalyst; wherein the reaction product has a glass transition temperature greater than or equal to 210° C. Also disclosed is a process for forming a thermoset resin, including: admixing two or more epoxy resins and a cycloaliphatic anhydride hardener to form a curable composition, wherein the epoxy resins include at least one cycloaliphatic epoxy resin; thermally curing the curable composition at a temperature of at least 150° C. to result in a thermoset resin having a glass transition temperature of at least 210° C. Such curable compositions may include: 35 to 65 weight percent of an epoxy resin mixture having at least one cycloaliphatic epoxy resins; 35 to 65 weight percent of a cycloaliphatic anhydride hardener; and from greater than 0 to 10 weight percent of a catalyst.
    Type: Grant
    Filed: January 5, 2009
    Date of Patent: June 3, 2014
    Assignee: Dow Global Technologies LLC
    Inventors: Jeffery L. Reynolds, Rajesh H. Turakhia, George Jacob, Marty J. Null
  • Patent number: 8716401
    Abstract: A semiconductor chip laminate comprises a plurality of semiconductor chips and an adhesive layer through which the plurality of semiconductor chips are laminated, wherein the adhesive layer is composed of an adhesive composition comprising an acrylic polymer (A); an epoxy resin (B); a thermal curing agent (C); and a certain organophosphonium compound (D) as a thermal curing accelerator, and the content of the organophosphonium compound (D) relative to 100 parts by weight in total of the epoxy resin (B) and the thermal curing agent (C) is 0.001 to 15 parts by weight.
    Type: Grant
    Filed: November 25, 2009
    Date of Patent: May 6, 2014
    Assignee: Lintec Corporation
    Inventors: Yasunori Karasawa, Isao Ichikawa
  • Publication number: 20140121308
    Abstract: The present invention is directed to a vulcanizable rubber composition comprising at least one diene based elastomer and an in-situ resin, the in-situ resin comprising a methylene acceptor and a methylene donor, wherein one of the methylene acceptor and methylene donor is microencapsulated.
    Type: Application
    Filed: September 16, 2013
    Publication date: May 1, 2014
    Applicant: The Goodyear Tire & Rubber Company
    Inventor: Carolin Anna Welter
  • Patent number: 8609767
    Abstract: Toughened thermosetting resins comprising thermosetting resins and rubber particles having an average particle size in the range of 20 to 500nm. The toughened resins are obtained by mixing a fully vulcanized powdery rubber having an average particle size in the range of 20 to 500nm with thermosetting resin prepolymers and then curing them. The toughened thermosetting resins comprise rubber phases having a small, uniform and stable particle size, which results in a very significant toughening effect, especially when crazes rapidly grow (as in a standard Izod impact test). The toughened thermosetting resins are excellent in impact resistance, strength, modulus and heat resistance, and when appropriately toughened, the thermosetting resins can be enhanced in terms of impact strength, glass transition temperature and heat distortion temperature.
    Type: Grant
    Filed: October 8, 2002
    Date of Patent: December 17, 2013
    Assignees: China Petroleum and Chemical Corporation, Sinopec Beijing Research Institute of Chemical Industry
    Inventors: Fan Huang, Jinliang Qiao, Yiqun Liu, Xiaohong Zhang, Jianming Gao, Zhihai Song
  • Patent number: 8470936
    Abstract: A liquid epoxy resin composition for semiconductor encapsulation comprising: (A) at least one epoxy resin, (B) at least one curing accelerator and (C) at least one acid anhydride terminated polyamic acid. The liquid epoxy resin composition provides a cured material that has an excellent adhesiveness to a semiconductor chip surface and has an excellent moisture resistance.
    Type: Grant
    Filed: July 29, 2011
    Date of Patent: June 25, 2013
    Assignee: Namics Corporation
    Inventors: Pawel Czubarow, Osamu Suzuki, Toshiyuki Sato, Kazuyoshi Yamada, Kaori Matsumura
  • Patent number: 8450433
    Abstract: Provided are a resin composition for the manufacture of marble chips including a halogenated epoxy resin binder and showing high heat resistance, high chemical resistance, high impact resistance, high specific gravity and high transparency, a marble chip manufacturing method using the resin composition and an artificial marble made from marble chips.
    Type: Grant
    Filed: August 13, 2010
    Date of Patent: May 28, 2013
    Inventor: Young-Min Kim
  • Publication number: 20130056686
    Abstract: To provide a curable resin composition that can improve resistant properties such as thermal impact resistance even in a high-temperature and high-humidity environment and has a high adhesive property, high conduction reliability and superior crack resistant property. The curable resin composition contains an epoxy resin and an epoxy resin-use curing agent, and is characterized in that a difference between a maximum value of tan ? in a viscoelastic spectrum and a value of the tan ? at ?40° C. thereof is 0.1 or more.
    Type: Application
    Filed: April 13, 2011
    Publication date: March 7, 2013
    Applicant: SONY CHEMICAL & INFORMATION DEVICE CORPORATION
    Inventors: Hidetsugu Namiki, Akira Ishigami, Hideaki Umakoshi, Shiyuki Kanisawa
  • Patent number: 8221862
    Abstract: A polyphenylene sulfide resin composition including 100 parts by weight of a resin composition that consists of 99 to 60 wt % of a polyphenylene sulfide resin (a), and 1 to 40 wt % of at least one type of noncrystalline resin (b) selected from the group consisting of polyetherimide resin and polyether sulfone resin and 0.1 to 10 parts by weight of a compound (c) containing at least one group selected from epoxy group, amino group and isocyanate group, wherein the non-crystalline resin (b) forms an island phase and the number-average dispersed particle size of the noncrystalline resin (b) is 1,000 nm or less.
    Type: Grant
    Filed: March 14, 2007
    Date of Patent: July 17, 2012
    Assignee: Toray Industries, Inc.
    Inventors: Kei Saitoh, Naoya Nakamura, Atsushi Ishio
  • Patent number: 8206808
    Abstract: A prepreg composite material that includes a fiber layer and a resin comprising a thermoset resin component, a curing agent and a fibrous micropulp. The micropulp component is an aramid fiber having a volume average length of from 0.01 to 100 micrometers. The prepreg is useful in composite panel construction for minimizing fluid permeation into the cured structure. This prepreg is particularly suitable for making honeycomb sandwich panels. Film adhesives, liquid and paste resins containing aramid fiber micropulp are also disclosed.
    Type: Grant
    Filed: June 2, 2011
    Date of Patent: June 26, 2012
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Subhotosh Khan, Halvar Young Loken
  • Patent number: 8198381
    Abstract: Disclosed is a phenol aralkyl epoxy resin having a structure wherein at least a phenol or a naphthol is bound by using an aralkyl group as a linking group and a structure represented by formula (1) below, while satisfying the condition 1 below. This epoxy resin is excellent in workability during production of a composition and is easy to control quality. Condition 1: The following relation (?) is satisfied with A being the hydroxyl equivalent (as measured in accordance with JIS K 0070) of a phenol-modified epoxy resin obtained by adding an equivalent molar amount of phenol relative to the epoxy equivalent of the epoxy resin, and B being the epoxy equivalent of the epoxy resin. 50?1000×(A?B)/B?250 (?).
    Type: Grant
    Filed: October 16, 2006
    Date of Patent: June 12, 2012
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Masataka Nakanishi, Katsuhiko Oshimi, Kazuyuki Ohhashi, Toru Kurihashi
  • Patent number: 8192840
    Abstract: A spring with high durability has a coating film composed of an epoxy resin powder coating containing softening agent which contains an epoxy resin and a softening agent comprising a thermoplastic resin for improving impact resistance of the coating film. A method of coating a spring with high durability comprises a coating step of making an epoxy resin powder coating containing softening agent which contains an epoxy resin and a softening agent comprising a thermoplastic resin for improving impact resistance of a coating film adhere to a surface on which the coating film is formed, and a baking step of baking the epoxy resin powder coating containing softening agent adhered to the surface.
    Type: Grant
    Filed: June 21, 2010
    Date of Patent: June 5, 2012
    Assignees: Chuo Hatsujo Kabushiki Kaisha, Rock Paint Co., Ltd.
    Inventors: Yasuhiko Kunita, Takayuki Sakakibara, Masami Wakita, Yuichi Kondo, Norio Sawatari
  • Publication number: 20120016057
    Abstract: It is an object of the present invention to provide an adhesive for electronic components that prevents warpage of electronic components and reflow cracks even in the case of bonding thin electronic components. The present invention relates to an adhesive for electronic components, comprising: an epoxy compound having an aliphatic polyether backbone and a glycidyl ether group; an epoxy group-containing acrylic polymer; an episulfide compound; and a curing agent, wherein the amount of the episulfide compound is 1 parts by weight or more, and less than 30 parts by weight relative to 100 parts by weight of the epoxy compound having an aliphatic polyether backbone and a glycidyl ether group.
    Type: Application
    Filed: January 29, 2010
    Publication date: January 19, 2012
    Inventors: Akinobu Hayakawa, Hideaki Ishizawa, Kohei Takeda, Ryohei Masui
  • Patent number: 8053533
    Abstract: A solvent-free polyimide silicone resin composition, and a cured product thereof, includes (A) a polyimide silicone resin having recurring units having a specific type of structure and having a weight average molecular weight of 5,000 to 150,000, (B) an epoxy resin, and (C) an epoxy resin curing agent wherein the resin composition having a fluidity at 25° C. and is free of a solvent.
    Type: Grant
    Filed: August 26, 2009
    Date of Patent: November 8, 2011
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Yoshinori Yoneda, Michihiro Sugo
  • Patent number: 7927691
    Abstract: A prepreg composite material that includes a fiber layer and a resin comprising a thermoset resin component, a curing agent and a fibrous micropulp. The micropulp component is an aramid fiber having a volume average length of from 0.01 to 100 micrometers. The prepreg is useful in composite panel construction for minimizing fluid permeation into the cured structure. This prepreg is particularly suitable for making honeycomb sandwich panels. Film adhesives, liquid and paste resins containing aramid fiber micropulp are also disclosed.
    Type: Grant
    Filed: April 3, 2009
    Date of Patent: April 19, 2011
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Subhotosh Khan, Halvar Young Loken
  • Patent number: 7776440
    Abstract: A spring with high durability has a coating film composed of an epoxy resin powder coating containing softening agent which contains an epoxy resin and a softening agent comprising a thermoplastic resin for improving impact resistance of the coating film. A method of coating a spring with high durability comprises a coating step of making an epoxy resin powder coating containing softening agent which contains an epoxy resin and a softening agent comprising a thermoplastic resin for improving impact resistance of a coating film adhere to a surface on which the coating film is formed, and a baking step of baking the epoxy resin powder coating containing softening agent adhered to the surface.
    Type: Grant
    Filed: January 26, 2007
    Date of Patent: August 17, 2010
    Assignees: Chuo Hatsujo Kabushiki Kaisha, Rock Paint Co., Ltd.
    Inventors: Yasuhiko Kunita, Takayuki Sakakibara, Masami Wakita, Yuichi Kondo, Norio Sawatari
  • Patent number: 7691944
    Abstract: The present invention provides a primer for a thermoplastic and/or elastomeric substrate, the primer comprising a film of an epoxy-modified polymer selected from the group consisting of an epoxy-modified-thermoplastic polymer, an epoxy-modified-thermoplastic polymeric composite, an epoxy-modified-elastomeric polymer, an epoxy-modified-elastomeric polymeric composite, a blend thereof, and any mixture thereof. Also provided are methods of repairing, inserting, assembling and coating a thermoplastic or elastomeric substrate using the primer of the present invention.
    Type: Grant
    Filed: August 12, 2009
    Date of Patent: April 6, 2010
    Assignee: National Research Council of Canada
    Inventors: Minh-Tan Ton-That, Johanne Denault, Kenneth C. Cole, Margaret Cole, legal representative
  • Patent number: 7674859
    Abstract: An adhesive sheet which can actualize a high package reliability wherein there is no separation at the adhesive interface and no package cracking, in a package in which a semiconductor chip being reduced in thickness is mounted under severe reflow conditions after exposure to a hot and humid environment. The adhesive sheet includes a base material and, formed thereon, an adhesive layer having an adhesive composition including an acrylic copolymer (A) containing 20 to 95% by weight of a structural unit derived from a benzyl (meth)acrylate, an epoxy thermosetting resin (B), and a thermosetting agent (C).
    Type: Grant
    Filed: June 24, 2008
    Date of Patent: March 9, 2010
    Assignee: Lintec Corporation
    Inventors: Naoya Saiki, Isao Ichikawa, Hironori Shizuhata
  • Patent number: 7579405
    Abstract: The present invention provides a primer for a thermoplastic and/or elastomeric substrate, the primer comprising a film of an epoxy-modified polymer selected from the group consisting of an epoxy-modified-thermoplastic polymer, an epoxy-modified-thermoplastic polymeric composite, an epoxy-modified-elastomeric polymer, an epoxy-modified-elastomeric polymeric composite, a blend thereof, and any mixture thereof. Also provided are methods of repairing, inserting, assembling and coating a thermoplastic or elastomeric substrate using the primer of the present invention.
    Type: Grant
    Filed: May 20, 2005
    Date of Patent: August 25, 2009
    Assignee: National Research Council of Canada
    Inventors: Minh-Tan Ton-That, Kenneth C. Cole, Johanne Denault
  • Patent number: 7423096
    Abstract: An underfill composition includes a thermosetting resin and a thermally cleavable component that releases sulfonic acid upon thermal activation. The underfill composition is applied to flip-chip technology during no-flow underfill mounting of the flip-chip to a mounting substrate. The mounting substrate can be further mounted on a board. A process includes formation of the underfill composition. A method includes assembly of the underfill composition with the flip-chip, and further can include assembly of the mounting substrate to a board. A computing system is also included that uses the underfill composition.
    Type: Grant
    Filed: September 29, 2004
    Date of Patent: September 9, 2008
    Assignee: Intel Corporation
    Inventor: Saikumar Jayaraman
  • Patent number: 7390849
    Abstract: Resins for powder coatings which are thermally and radiation curable containing both olefinically unsaturated groups and at least one other reactive group in the same molecules selected from epoxide groups and acid groups, a method for their preparation, and the use thereof in powder coating compositions.
    Type: Grant
    Filed: February 2, 2004
    Date of Patent: June 24, 2008
    Assignee: Surface Specialties Italy s.r.l.
    Inventors: Roberto Cavalieri, Sergio Gazzea
  • Patent number: 7323521
    Abstract: Comb polymers prepared by reacting an epoxy resin and a lactone are disclosed. These comb polymers find particular application as additives for powder coating compositions, to improve various performance properties thereof. Powder coating composition comprising the described comb polymers are also disclosed.
    Type: Grant
    Filed: March 19, 2004
    Date of Patent: January 29, 2008
    Assignee: PP6 Industries Ohio, Inc.
    Inventors: Michael J. Ziegler, Anthony M. Chasser, Jackie L. Kulfan
  • Patent number: 7247683
    Abstract: A no flow fluxing underfill having a hardener component comprising a phenolic component and an anhydride component in a molar ratio of phenolic component to anhydride component of between about 0.1:1 and about 2:1; or between about 0.8:1 and about 1.2:1. An underfill preparation method involving blending an epoxy component and a phenolic component, heating the blend, and cooling the blend, prior to incorporation of an anhydride component.
    Type: Grant
    Filed: August 5, 2004
    Date of Patent: July 24, 2007
    Assignee: Fry's Metals, Inc.
    Inventors: James M. Hurley, Mark Wilson, Xiaoyun Ye
  • Patent number: 7193016
    Abstract: In accordance with the present invention, there are provided toughening agents which are useful for improving the performance properties of epoxy-based adhesive formulations. For example, epoxidized polybutylacrylates have been found to be useful toughening agents of component level underfill adhesive compositions. Invention materials are generally liquid rubbers which provided improved fracture toughness while maintaining satisfactory capillary flow properties. Invention materials can be synthesized in neat (solventless) reactions from readily available low-cost raw materials and isolated in high yields. They have a branched telechelic structure with terminal epoxide functional groups. The polyacrylate is typically obtained as a mixture of epoxidized polymer, chain extended polyoligomer and unreacted monomer. Invention materials are compatible with common epoxy formulations and may be used without purification.
    Type: Grant
    Filed: October 27, 2003
    Date of Patent: March 20, 2007
    Assignee: Henkel Corporation
    Inventors: John G. Woods, Mark M. Konarski, Kyra M. Kozak, Yuhshi Luh
  • Patent number: 7087664
    Abstract: A resin film comprising (A) an epoxy resin having two or more glycidyl groups in a molecule, (B) an epoxy resin curing agent, (C) a thermoplastic resin, and (D) a filler, wherein the filler content in at least either one of the surface regions on the cross-section of the film is less than the filler concentration in the central region. The resin film has not only toughness but also fire retardancy, high interlayer adhesion strength and good processability of metal plating.
    Type: Grant
    Filed: January 23, 2004
    Date of Patent: August 8, 2006
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Toshiaki Hayashi, Katsuhiro Furuta
  • Patent number: 7009009
    Abstract: A latent fluxing agent comprising a material which liberates phenol or a carboxylic acid containing compound when heated above 140° C. The latent fluxing agent may be incorporated into a thermoset resin, which includes an epoxy resin. The uncured epoxy resin, which includes the epoxy resin, the latent fluxing agent and an epoxy curing agent are useful as an underfill composition in a method for applying a chip die, having one or more solder balls, to a substrate. The method is used to produce an integrated circuit chip that includes a chip die having electrical contacts arranged in a predetermined pattern and capable of providing electrical engagement with a carrier substrate.
    Type: Grant
    Filed: September 8, 2003
    Date of Patent: March 7, 2006
    Assignee: Henkel Corporation
    Inventors: Lawrence N. Crane, Mark M. Konarski, J. Paul Krug, Andrew D. Messana, John G. Woods
  • Patent number: 6943219
    Abstract: The present invention provides a vinyl polymer with an epoxy group terminally introduced therein and an epoxy resin composition comprising (A) an epoxy resin and (B) a vinyl polymer which has a main chain produced by living radical polymerization and has a reactive functional group at a main chain terminus. A flexible epoxy resin composition can be obtained using these compounds. The invention further provides an epoxy resin composition having an epoxy group at a main chain terminus thereof.
    Type: Grant
    Filed: February 24, 2003
    Date of Patent: September 13, 2005
    Assignee: Kaneka Corporation
    Inventors: Kenichi Kitano, Yoshiki Nakagawa, Masayuki Fujita
  • Patent number: 6900269
    Abstract: Disclosed is a halogen-free resin composition comprising: (A) one or more phosphorus-containing epoxy resins; (B) a hardener; (C) a hardening accelerator; (D) a polyphenylene oxide resin; and (E) a filling material, wherein the hardener of component B has the structure represented by the following formula (I): wherein each symbol is as defined above. The halogen-free resin composition of the present invention without adding halogen has excellent heat resistance and flame retardant property, and excellent dielectric property. The halogen-free resin composition of the present invention is particularly useful in the application of bonding sheets, composite materials, laminated plates, printed circuit boards, copper foil adhesives, inks used for build-up process, semiconductor packaging materials and the like.
    Type: Grant
    Filed: April 11, 2003
    Date of Patent: May 31, 2005
    Assignee: Chang Chun Plastics Co., Ltd.
    Inventors: Kuen-Yuan Hwang, An-Pang Tu, Mong Liang, Chi-Yi Ju, Sheng-Yen Wu, Chun-Hsiung Kao, Fang-Shian Su
  • Patent number: 6831113
    Abstract: A method for making a one-component epoxy resin system comprises reacting (A) an epoxy resin and (B) an amine solidifying system present in insufficient quantities to cause gelation in the presence of a latent hardener (C) and an expanding agent (E), each of which remains unreacted under the reaction conditions for (A) and (B), to yield a product with a Kofler Heat Bank melting point of less than 55° C. and a melting point stability of at least six months at normal workshop temperatures.
    Type: Grant
    Filed: November 13, 2001
    Date of Patent: December 14, 2004
    Assignee: Huntsman Advanced Materials Americas Inc.
    Inventor: Peter Drummond Boys White
  • Patent number: 6828382
    Abstract: This invention relates to a jointing compound of an acrylate/acrylonitrile copolymer containing 2 to 8 carbon atoms in the alcohol component as binder and fatty compounds as plasticizer and also fillers and auxiliaries. Epoxystearic acid methyl ester in particular may be used as the fatty compound while a butyl acrylate/acrylonitrile copolymer in particular may be used as the acrylate/acrylonitrile copolymer. The combination of the two substances results in jointing compounds characterized by a dramatic improvement in elasticity (resilience). Accordingly, they are particularly suitable for substrates with different coefficients of thermal expansion.
    Type: Grant
    Filed: July 12, 2000
    Date of Patent: December 7, 2004
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Helmut Loth, Klaus Helpenstein, Wolfgang Klauck, Johann Klein, Lydia Duhm
  • Patent number: 6822047
    Abstract: An adhesive for use on metal substrates, and particularly on copper substrates, comprises (a) carboxyl benzotriazole, (b) an epoxy resin having a reactive double bond, (c) a radical curing resin, and (d) a radical initiator. The combination of elements (a) and (b) in a radical curing resin system composed of the elements (c) and (d) provides improved adhesion strength to copper metal compared to compositions containing (c) and (d) without (a) and (b).
    Type: Grant
    Filed: January 2, 2003
    Date of Patent: November 23, 2004
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventor: Tadashi Takano
  • Patent number: 6818702
    Abstract: A thermosetting resin composition that is useful as an epoxy resin-based overcoating agent for flexible circuit boards or for film carriers for the TAB method, and the like, providing basic properties required of general insulation protective films, since the cured coated films are excellent in adhesiveness, electric insulation property, chemical resistance, thermal resistance, and the like, reduced in warp caused by cure shrinkage, and excellent in flexibility.
    Type: Grant
    Filed: December 28, 2001
    Date of Patent: November 16, 2004
    Assignee: Ajinomoto Co., Inc.
    Inventors: Hiroshi Orikabe, Hiroshi Sakamoto, Tadahiko Yokota
  • Publication number: 20040192804
    Abstract: A photosensitive composition comprising, (A) an oligomer or polymer containing at least one carboxylic acid group in the molecule and having a molecular weight of 200′ooo or less; (B) at least one photoinitiator compound of formula I, R1, is lenear or banched C1-C12alkyl; R2 is linear or branched C1-C4alkyl; R3 and R4 independently of one another are linear or branched C1-C8alkyl; and (C) a monomeric, oligoneric or polymeric compound having at least one olefinic double bond, is especially suitable for preparting photoresists, in particular color filters.
    Type: Application
    Filed: January 20, 2004
    Publication date: September 30, 2004
    Inventors: Hisatoshi Kura, Hidetaka Oka, Masaki Ohwa
  • Patent number: 6787606
    Abstract: A composition useful as a sealing element for electrochromic devices comprises (a) an epoxy resin component including at least two of a dicyclopentadiene epoxy resin, a naphthalene epoxy resin, a bisphenol A epoxy resin, a bisphenol F epoxy resin and a novolac epoxy resin; (b) a toughening agent; and (c) a latent curative.
    Type: Grant
    Filed: September 13, 2002
    Date of Patent: September 7, 2004
    Assignee: Henkel Corporation
    Inventor: Chunfu Chen
  • Patent number: 6579588
    Abstract: An article comprises a substrate wherein at least a portion of its surface is provided with a thermosettable adhesive composition prepared from a polyepoxide resin, a curing agent and a plurality of microspheres. The cured composition forms a semi-structural bond with said substrate which is inseparable at the use temperature and is cleanly removable from said substrate when heated to a temperature of greater than the use temperature.
    Type: Grant
    Filed: July 26, 2001
    Date of Patent: June 17, 2003
    Assignee: 3M Innovative Properties Company
    Inventor: Robert D. Waid
  • Patent number: 6489023
    Abstract: A sealant composition comprising a curable epoxy-containing material, a thermoplastic polyamide component having a melting point lower than a curing temperature of the epoxy-containing material, and a curative for the epoxy-containing material. After curing of the epoxy-containing material, the sealant composition exhibits an elongation at −20° C. of at least 2. The sealant composition is capable of effectively sealing discontinuities while maintaining enough flexibility to absorb applied stress, thereby preventing the formation of defects in the sealant which permit the intrusion of dirt, moisture, and other undesirable substances.
    Type: Grant
    Filed: June 20, 2001
    Date of Patent: December 3, 2002
    Assignee: 3M Innovative Properties Company
    Inventors: Kotaro Shinozaki, Kazuyoshi Shiozaki
  • Patent number: 6437056
    Abstract: Coating composition suitable for multilayer lacquering, containing, in addition to organic solvent, anti-sagging agents, optionally pigments, extenders and additives, a binder/crosslinkin agent system containing A) from 20 to 80 wt. % of carboxyl-functional (meth)acrylic copolymers and/or carboxyl-functional polyesters having an acid number of from 20 to 300, B) from 20 to 80 wt. % of epoxy-functional crosslinking agents, the percentages by weight of A) and B) adding up to 100 wt. %. C) from 0 to 30 wt. % of polymer polyol C), based on the sum of the weights of A) and B), E) from 0 to 20 wt. % of further crosslinking agents, based on the sum of the weights of A, B, and C), F) from 0 to 10 wt. % of monoepoxides, based on the sum of the weights of A) and B), and D) as anti-sagging agents, from 0.1 to 3 wt.
    Type: Grant
    Filed: December 11, 2000
    Date of Patent: August 20, 2002
    Assignee: E. I. du Pont de Nmeours and Company
    Inventors: Ralf Dahm, Carmen Flosbach, Hermann Kerber, Walter Schubert, Astrid Tückmantel
  • Patent number: 6388009
    Abstract: A low dielectric constant composition used in electric circuit boards is disclosed. The composition includes (a) 20-99.9 parts by weight of a functionalized syndiotactic styrene/para-alkystyrene copolymer having microfoaming when being cured; (b) 0.01-80 parts by weight of a mixture of epoxy resins; and (c) less than 50 parts by weight of a curing agent.
    Type: Grant
    Filed: November 24, 1999
    Date of Patent: May 14, 2002
    Assignee: Industrial Technology Research Institute
    Inventors: Wei-Han Liao, Hsien-Yin Tsai, In-Mau Chen
  • Patent number: 6372823
    Abstract: The present invention provides a cationically electrodepositable coating composition comprising: (A) a water-soluble or water-dispersible resin obtained by reacting a hydroxyl group of a bisphenol A type epoxy resin with a cyclic ester compound, (B) a vinyl resin having a solubility parameter value of less than 9.6, (C) polyalkylene glycol having a solubility parameter value of less than 9.6, and (D) a pigment component having an average particle diameter of 0.5 &mgr;m or less.
    Type: Grant
    Filed: September 27, 2000
    Date of Patent: April 16, 2002
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Hidenori Furukawa, Takahisa Kasukawa
  • Patent number: 6359039
    Abstract: An epoxy based adhesive composition contains: (i) a barbituric acid-modified bismaleimide; (ii) an epoxy resin selected from the group consisting of tetraglycidylmethylenedianiline, diglycidyl ortho-phthalate, diglycidyl ether of bisphenol A, polyglycidyl ether of novolac, and epoxy cresol novolac; (iii) an elastomer such as a carboxylated acrylontrile rubber containing between 19 and 41 wt % of acrylontrile; (v) a hardening agent and (vi) a catalyst.
    Type: Grant
    Filed: July 25, 2000
    Date of Patent: March 19, 2002
    Assignee: Industrial Technology Research Institute
    Inventors: Chih-Chiang Chen, Jing-Pin Pan, Shur-Fen Liu
  • Patent number: 6346573
    Abstract: A method for the manufacture of a one-component epoxy resin system comprises mixing at 15-30° C. and reacting at room temperature over 2-14 days (A) an epoxy resin and (B) an amine solidifying system present in insufficient quantities to cause gelation to yield a product with a Kofler Heat Bank melting point of less than 55° C. and a melting point stability of at least six months at normal workshop temperatures in the presence of (C) a hardener for (A) and the reaction product of (A) and (B) which is different from (B) and remains unreacted with (A) and (B) during the their reaction, (E) an expanding agent and (D) additives other than the expanding agent, provided that the reaction between (A) and (B) does not generate enough heat to activate a reaction between the remaining epoxy groups and hardener (C) or expanding agent (E).
    Type: Grant
    Filed: May 18, 1998
    Date of Patent: February 12, 2002
    Assignee: Vantico Inc.
    Inventor: Peter Drummond Boys White
  • Patent number: 6288170
    Abstract: A thermosetting adhesive comprising a polyepoxide resin, a curing agent such as an imidazole and polymeric or elastomeric microspheres is removable when heated to a temperature greater than the use temperature of from about room temperature to about 185° C.
    Type: Grant
    Filed: October 6, 1999
    Date of Patent: September 11, 2001
    Assignee: 3M Innovative Properties Company
    Inventor: Robert D. Waid
  • Patent number: 6274673
    Abstract: Reaction products of a microgel that contains carboxylic acid groups with a nitrogen-containing base have a high latency and high stability towards mechanical influences and are suitable as hardeners for one-component epoxy resin systems.
    Type: Grant
    Filed: August 18, 1999
    Date of Patent: August 14, 2001
    Assignee: Vantico, Inc.
    Inventors: Martin Roth, Qian Tang, Sameer Hosam Eldin
  • Patent number: 6235842
    Abstract: The present invention provides a phase-separation structure comprising a phenoxy resin modified with a carboxylated elastomer, prepared from a phenoxy resin and a carboxylated elastomer, the resin and the elastomer constituting a phase-separation structure, wherein the light transmittance of the structure in a 75 &mgr;m-thick film form at a wavelength of 500 nm is not less than 10% of the light transmittance of the air, which is useful as adhesives, film materials, and molding materials for encapsulating electronic components.
    Type: Grant
    Filed: June 7, 1999
    Date of Patent: May 22, 2001
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Atsushi Kuwano, Shinsuke Hagiwara
  • Patent number: 6114473
    Abstract: A resin composition for powder coating, which comprises the following components (A), (B) and (C): (A) a carboxyl group-containing resin having a number average molecular weight of from 1,000 to 20,000, an acid value of from 5 to 200 and a glass transition temperature of from 30 to 120.degree. C.; (B) tris(.beta.-methylglycidyl) isocyanurate of formula (1); and (C) as a ring opening polymerization inhibitor, at least one compound selected from the group consisting of amines having in their molecules a bond of formula (2); and onium salts.
    Type: Grant
    Filed: May 28, 1997
    Date of Patent: September 5, 2000
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Satoru Miyake, Hisao Ikeda, Motohiko Hidaka, Takeo Moro
  • Patent number: 6090891
    Abstract: Curable compositions, which comprise the following components:(A) a polymer component consisting of one or more than one of the following components:polymers based on acrylate monomers and/or methacrylate monomers containing free carboxyl groups, and carboxyl-terminated polyesters;(B) a crosslinker for component (A) selected from the group consisting of:(B1) one or more than one compound having a molecular weight of less than 800 and containing at least two (2-oxo-1,3-dioxolan-4-yl)methyl groups per molecule, and(B2) a mixture consisting of one or more than one compound having a molecular weight of less than 800 and containing at least two (2-oxo-1,3-dioxolan-4-yl)methyl groups per molecule, and of one or more than one epoxy resin, at least 60 percent of the total number of (2-oxo-1,3-dioxolan-4-yl)methyl groups and epoxy groups of the mixture being (2-oxo-1,3-dioxolan-4-yl)methyl groups;(C) a catalyst for accelerating the crosslinking reaction between the components (A) and (B), and(D) a solvent for the comp
    Type: Grant
    Filed: May 11, 1998
    Date of Patent: July 18, 2000
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Isabelle Frischinger, Jacques-Alain Cotting, Jurgen Finter, Jacques Fran.cedilla.ois
  • Patent number: 6060540
    Abstract: The present invention provides a modeling paste comprising a latent material which can be applied as a thick layer to a substrate and which after activation rapidly crosslinks to a machinable surface.
    Type: Grant
    Filed: February 13, 1998
    Date of Patent: May 9, 2000
    Assignee: Landec Corporation
    Inventors: Mark A. Wanthal, Paul C. Paetzke, Guy J. Stokes
  • Patent number: 6046257
    Abstract: A composition is useful as a prepreg containing reinforcing fibers comprises an epoxy resin, a thermoplastic elastomer of a polyamide and/or polyester block copolymer, a curing agent such as dicyandiamide, and optionally a thermoplastic resin such as a polyvinyl formal resin.
    Type: Grant
    Filed: March 18, 1996
    Date of Patent: April 4, 2000
    Assignee: Toray Industries, Inc.
    Inventors: Hiroki Oosedo, Shunsaku Noda