Contacting Two Or More Solid Polymers With A Phenolic Reactant; Or Contacting A Solid Polymer With A Phenolic Reactant And Subsequently Contacting The Treated Polymer With An Additional Solid Polymer Patents (Class 525/133)
  • Patent number: 5407706
    Abstract: There is disclosed a resin composition for powder coatings, which comprises a blend of two acrylic resins obtained by polymerizing a prescribed amount of monomer component (a-1) represented by formula (I) and a prescribed amount of another monomer component (a-2), respectively, and having different polymerization degrees represented by viscosities at 140.degree. C. and a polybasic acid compound in 1.5 to 0.5 equivalent ratio of the glycidyl groups in said acrylic resins to the acid groups in the polybasic acid compound. ##STR1## wherein R.sub.1 and R.sub.2 each represent a hydrogen atom or a lower alkyl group. The resin composition for powder coatings that can form a coating film having a mat smooth appearance and being excellent in flexibility as shown by Du Pont impact resistance and the Ericksen test as well as being excellent in nail scratch resistance.
    Type: Grant
    Filed: December 29, 1992
    Date of Patent: April 18, 1995
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Taisaku Kano, Takayoshi Sekido, Eiichiro Miyazaki, Makoto Nishimori
  • Patent number: 5407998
    Abstract: The present invention provides a golf ball with preferred hit feeling, controllability and satisfactory level of flying performance and cut resistance. The golf ball comprises a core and a cover covering the core, wherein said cover is mainly made of a mixture composed of an ionomer resin and a diene type rubber at a weight ratio (ionomer resin:diene rubber) of 95:5-60:40 and said diene type rubber is crosslinked by a crosslinking agent.
    Type: Grant
    Filed: September 1, 1993
    Date of Patent: April 18, 1995
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Kuniyasu Horiuchi, Akira Kato
  • Patent number: 5397838
    Abstract: The present inventions provides polyphenylene ether (PPE)/polyamide (PA) resin compositions having excellent dimensional stability when they absorb moisture, and good mechanical and other properties. Resin compositions of (A) 10-80 wt. parts PPE resins and (B) 90-20 wt. parts PA resins, in which the PA resins (a) are polymers formed by condensation of linear aliphatic diamines with linear aliphatic dicarboxylic acids and aromatic dicarboxylic acids, and (b) have terminal amino group contents of at least 0.4 mequiv/g.
    Type: Grant
    Filed: October 14, 1992
    Date of Patent: March 14, 1995
    Assignee: General Electric Company
    Inventors: Takashi Ohtomo, Hiromi Ishida, Hidekazu Kabaya
  • Patent number: 5391670
    Abstract: The alkylation resins of this invention comprise the alkylation reaction product of (a) at least one substituted or unsubstituted polycyclic aromatic compound and (b) at least one ethylenically unsaturated hydrocarbon monomer having at least two carbon-carbon double bonds that reacts with the polycyclic aromatic compound by alkylation in the presence of an acid catalyst, wherein the ratio of (a) to (b) in the resin is about 1:9 to about 3:1 by weight. The resins have a weight average molecular weight of less than 10,000 measured by size exclusion chromatography, and a Ring & Ball softening point of about 50.degree. to about 250.degree. C. Because of their high softening point and low molecular weight, the resins are useful in a variety of applications such as flow rate modifiers for engineering polymers, tackifiers for adhesives, and flushing agents for inks.
    Type: Grant
    Filed: August 9, 1993
    Date of Patent: February 21, 1995
    Assignee: Hercules Incorporated
    Inventors: Atanu Biswas, Daniel W. Klosiewicz
  • Patent number: 5391616
    Abstract: Novel polycarbonate compositions comprising blends which contain thermoplastic olefin copolymers are prepared from precursor orthoester and orthocarbonate functionalized olefin polymers and functionalized polymers and the novel polycarbonate compositions display improved physical properties.
    Type: Grant
    Filed: December 22, 1993
    Date of Patent: February 21, 1995
    Assignee: General Electric Company
    Inventors: Farid F. Khouri, Gregory J. Stoddard
  • Patent number: 5389714
    Abstract: Resin compositions comprising (A) polyethylene ether resins, (B) polyamide resins, (C) elastomeric substances, and (D) needle-shaped titanium oxide are disclosed. The disclosed resins exhibit an excellent balance of stiffness and impact resistance, low linear coefficient of expansion, and good heat resistance, oil resistance, forming processability and molding surface appearance.
    Type: Grant
    Filed: December 23, 1992
    Date of Patent: February 14, 1995
    Assignee: GE Plastics, Japan, Ltd.
    Inventors: Takashi Ohtomo, Hiromi Ishida, Hidekazu Kabaya, Hiroshi Kubo
  • Patent number: 5387647
    Abstract: The invention relates to thermoplastic molding compounds of 70 to 99.5% by weight thermoplastic polyamides and 30 to 0.5% by weight hydrogenated nitrile rubber and 0 to 29.5% by weight thermoplastic resin components and, optionally, standard additives in typical quantities. These thermoplastic molding compounds show high strength values, very good moldability and, above all, high weathering resistance.
    Type: Grant
    Filed: May 19, 1994
    Date of Patent: February 7, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventors: Herbert Eichenauer, Hartmuth Buding, Josef Merten, Karl-Heinz Ott
  • Patent number: 5384366
    Abstract: The present invention relates to a process for preparing elastomeric thermoplastic blends which comprises the following steps:a) mastication of a blend which comprises a polyolefin elastomer, polyolefin thermoplastic resin and a vulcanizing agent;b) mastication of a blend which comprises the product obtained in step (a), a polyolefin thermoplastic resin and vulcanizing agent.
    Type: Grant
    Filed: July 14, 1993
    Date of Patent: January 24, 1995
    Inventor: Guido Paganelli
  • Patent number: 5369172
    Abstract: The invention provides a low gloss polymer blend comprising an aromatic carbonate without reactive groups, a polymer or copolymer having a reactive epoxygroup and an aromatic carbonate polymer or copolymer having a reactive group which react with the epoxy group. Optionally, the composition may contain further usual compounds, such as polymeric materials which are normally used to modify the mechanical properties of polycarbonate, particularly rubbery or non-rubbery polymeric materials containing units of a styrene; also additives like colorants, flame retarding agents may be routinely incorporated.
    Type: Grant
    Filed: January 31, 1994
    Date of Patent: November 29, 1994
    Assignee: General Electric Company
    Inventors: Sarah E. Morgan, Charles F. Pratt, Hermannus B. Savenije
  • Patent number: 5369154
    Abstract: A polycarbonate blend of good impact and flexural strength, good heat distortion and weldline properties, low gloss, and good solvent resistance prepared by admixing with polycarbonate an aromatic polyester, an olefinic epoxide-containing modifier, and one or more members of the group conssisting of a thermoplastic elastomer and a rubber-modified styrene/acrylonitrile copolymer. Optionally, a graft copolymer of the core-shell type may be used as an additional impact modifier.
    Type: Grant
    Filed: October 9, 1992
    Date of Patent: November 29, 1994
    Assignee: The Dow Chemical Company
    Inventor: Michael K. Laughner
  • Patent number: 5367010
    Abstract: An adhesive composition containing a chlorinated ethylene/vinyl acetate copolymer and at least one of a phenolic resin and an aromatic nitroso compound as an adhesion-promoting additive. The chlorinated ethylene/vinyl acetate copolymer can be prepared without the utilization of environmentally hazardous chlorinated solvents and provides for adhesive compositions which exhibit excellent adhesion and resistance to adverse environmental conditions.
    Type: Grant
    Filed: March 22, 1993
    Date of Patent: November 22, 1994
    Assignee: Lord Corporation
    Inventors: Nicholas J. Gervase, Louie G. Manino
  • Patent number: 5362809
    Abstract: A polymer blend of a polyglutarimide and liquid crystalline copolyester polymer or benzimidazole polymer. The blend is a melt-compoundable polymer blend.
    Type: Grant
    Filed: October 22, 1992
    Date of Patent: November 8, 1994
    Assignee: Rohm and Haas Company
    Inventors: Michael P. Hallden-Abberton, Newman M. Bortnick, William J. Work
  • Patent number: 5359006
    Abstract: Hot-melt adhesives based upon a mixture composed of poly(vinylmethylether), greater than about 10 weight percent of a thermoplastic resin and, optionally a tackifier resin and/or extender, are found to be superior for the binding of polyolefins such as polyethylene, polypropylene, and ethylene-propylene copolymers to themselves and to other substrates. In particular, the hot-melt adhesives are useful for bonding polyethylene-backed and latex-backed carpet to polyethylene, polypropylene, or ethylene-propylene copolymer.
    Type: Grant
    Filed: March 22, 1993
    Date of Patent: October 25, 1994
    Assignee: Amoco Corporation
    Inventors: Matthew A. Kulzick, Wayne R. Pretzer, Tsuei-Yun Lynch, Paul A. Koning
  • Patent number: 5356991
    Abstract: Polyester-based shock-resistant compositions, endowed with a high shock resistance, particularly at low temperatures comprising:(a) a matrix constituted by one or more unsaturated polyesters;(b) an elastomer constituted by butadiene or acrylic rubbers; and(c) a block-copolyester.
    Type: Grant
    Filed: May 18, 1993
    Date of Patent: October 18, 1994
    Assignee: Ausimont S.p.A.
    Inventors: Antonio Chiolle, Gaetano Andreoli
  • Patent number: 5350802
    Abstract: Blends of carbonate and monovinylidene aromatic copolymers containing selected low molecular weight halogenated epoxy compounds, in combination with tetrafluoroethylene polymers, are shown to have surprising combinations of impact and ignition resistance and be very suitable for electroplating applications. In general the selected epoxy compounds can be represented by the following formula: ##STR1## where, preferably, R is hydrogen; X is bromine; i is 2; L is 2,2-isopropyl; n is from 0 to 1. Polymer blends based on from about 65 to about 98 weight percent carbonate polymer, from about 2 to about 25 percent by weight monovinylidene aromatic copolymer, preferably rubber modified, and from 0 to about 10 percent by weight of a rubbery core/shell graft copolymer impact modifier are suitable for preparation of these compositions. It has been found desirable to employ from about 1 to about 20 percent by weight low molecular weight halogenated epoxy compound, and from 0.
    Type: Grant
    Filed: June 23, 1993
    Date of Patent: September 27, 1994
    Assignee: The Dow Chemical Company
    Inventors: Jack W. Muskopf, M. Robert Christy, Jaysn F. Jameson, deceased, Jerry M. Jameson, heir, Donna R. Jameson, heiress, Tami S. Hallmark
  • Patent number: 5346952
    Abstract: Disclosed is a thermoplastic resin composition comprised of (A) 10-60 weight parts of a polyphenylene ether resin, (B) 20-70 weight parts of (b-1) an aromatic vinyl resin and/or (b-2) a copolymer of an aromatic vinyl monomer with a heterocyclic compound having a vinyl group and containing nitrogen as the hetero atom and (C) 10-60 weight parts of (c-1) a graft copolymer obtained by polymerizing an aromatic vinyl monomer, optionally with other vinyl monomer, in the presence of a butadiene type rubbery polymer or (c-2) a graft copolymer obtained by polymerizing an aromatic vinyl monomer and a heterocyclic compound having a vinyl group and containing nitrogen as the hereto atom, optionally with other ethylenically unsaturated compound, in the presence of a butadiene type rubbery polymer, wherein at least one of the components (B) and (C) is a polymer of the nitrogen-containing heterocyclic compound, and the total amount of the components (A), (B) and (C) is 100 parts by weight.
    Type: Grant
    Filed: April 30, 1993
    Date of Patent: September 13, 1994
    Assignee: Mitsubishi Rayon Company Ltd.
    Inventors: Masafumi Hongo, Hideki Yano, Hideyuki Shigemitsu
  • Patent number: 5338789
    Abstract: A fiber-reinforced molding composition, comprising:a) 97 to 50% by weight, relative to the sum of (a) and (b), of a mixture of 30 to 100 parts by weight of a polyphenylene ether, 0 to 70 parts by weight of a styrene polymer, 0 to 10 parts by weight of a polyoctenylene and 0.1 to 2.5 parts by weight of an .alpha.,.beta.-unsaturated carboxylic acid derivative or a precursor thereof;b) 3 to 50% by weight of carbon fibers and/or glass fibers whose surfaces bear functional groups which are capable of entering into chemical coupling reactions with the .alpha.,.beta.-unsaturated carboxylic acid derivatives; and optionallyc) dyes, pigments, plasticizers, flame retardant additives, processing auxiliaries, other customary additives or combinations thereof.
    Type: Grant
    Filed: April 9, 1992
    Date of Patent: August 16, 1994
    Assignee: Huels Aktiengesellschaft
    Inventors: Thomas Grosse-Puppendahl, Christian Baron, Friedrich G. Schmidt
  • Patent number: 5338796
    Abstract: A thermoplastic composition having a good balance of mechanical and thermal properties, an improved impact strength and a good processability includes a functionalized polyphenylene ether, a polyamide, and an olefinic elastomer containing a vinylaromatic monomer grafted thereon.
    Type: Grant
    Filed: February 9, 1993
    Date of Patent: August 16, 1994
    Assignee: Montedipe s.r.l.
    Inventors: Domenico Vianello, Armando Benetton, Alessandro Moro, Roberto Pippa, Aldo Longo
  • Patent number: 5332780
    Abstract: Thermoplastic resin compositions having the following component A-1 or A-2, component B and component C:(A-1): a polymer component having a functional group capable of reacting with an amino group, or(A-2): a composition of component (A-1) and a resin that is non-reactive with an amino group and is different from the resin used in the following component B(B) a thermoplastic resin component that is non-reactive with an amino group under the conditions required to mold the entire resin composition; and(C) a graft copolymer obtained by a graft reaction of a thermoplastic polymer, with a compound (I), or a copolymer having the repeating unit (II) and the repeating unit of an ethylenic unsaturated monomer, ##STR1## wherein R.sup.1 -R.sup.4, the same or different represent a hydrogen atom, an alkyl group, a cycloalkyl group, an aryl group or an aralkyl group.
    Type: Grant
    Filed: April 8, 1993
    Date of Patent: July 26, 1994
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Naoki Kitazawa, Manabu Kikuta, Hiroshi Hotta, Yutaka Nakayama, Hideyuki Sumi
  • Patent number: 5326813
    Abstract: There are disclosed a thermoplastic resin composition comprising (A) a styrenic polymer having a high degree of syndiotactic configuration, (B) an inorganic filler and (C) a polyphenylene ether that is modified with a compound having an ethylenic double bond and a polar group in the same molecule, especially maleic anhydride, the ether having a modification rate of 1.3% or more by weight; a thermoplastic resin composition further comprising (D) a rubbery elastomer in addition to the above components (A), (B) and (C); a process for producing modified polyphenylene ether (PPO) comprising reacting 100 parts by weight of PPO with 1 to 20 parts by weight of the above compound or a derivative thereof in an aromatic hydrocarbon solvent in the presence of 15 or less parts by weight of a radical generator; and a process for producing the modified PPO comprising reacting 100 parts by weight of PPO with 1 to 5 parts by weight of the above compound or a derivative thereof at 300.degree. to 350.degree. C.
    Type: Grant
    Filed: December 10, 1992
    Date of Patent: July 5, 1994
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Akihiko Okada, Akitoshi Masuyama
  • Patent number: 5322663
    Abstract: A rapidly-crystallizing modified poly(ethylene terephthalate) contains an acrylic core/shell impact modifier, a small amount of a polycarbonate, and a small amount of a copolymer of ethylene with a vinyl or vinylidene monomer containing ester groups. Improved mold release and lessened plate-out are observed over other additive combinations.
    Type: Grant
    Filed: May 25, 1993
    Date of Patent: June 21, 1994
    Assignee: Rohm and Haas Company
    Inventors: Choung-Houng Lai, Jean M. Brady
  • Patent number: 5310793
    Abstract: The mixtures according to the present invention of polyalkylene terephthalates, certain new polycarbonates and/or polyester-carbonates and elastomers have a particularly favourable low temperature strength/heat distortion point relationship compared with conventional moulding compositions containing known polycarbonates. The mixtures are used for the production of, in particular, shaped articles.
    Type: Grant
    Filed: February 12, 1993
    Date of Patent: May 10, 1994
    Assignee: Bayer Aktiengesellschaft
    Inventors: Dieter Freitag, Karsten-Josef Idel, Gerd Fengler, Ulrich Grigo, Jurgen Kirsch, Uwe Westeppe
  • Patent number: 5308489
    Abstract: The invention relates to blends of polyether copolycarbonates and other thermoplastics, to their production and to their use for the production of membranes, more particularly for dialysis.
    Type: Grant
    Filed: December 11, 1992
    Date of Patent: May 3, 1994
    Assignee: Bayer Aktiengesellschaft
    Inventors: Rolf Dhein, Wolfgang Ebert, Herbert Hugl, Holger Ohst
  • Patent number: 5308894
    Abstract: A polycarbonate blend of good impact and flexural strength, good weldline properties, and good solvent resistance prepared by admixing with polycarbonate an aromatic polyester, an olefinic epoxide-containing modifier, and a thermoplastic elastomer. Optionally, a graft copolymer of the core-shell type and a rubber-modified styrene/acrylonitrile copolymer may be used as an additional impact modifiers.
    Type: Grant
    Filed: January 6, 1993
    Date of Patent: May 3, 1994
    Assignee: The Dow Chemical Company
    Inventor: Michael K. Laughner
  • Patent number: 5304593
    Abstract: A novel thermoplastic resin composition excellent in heat resistance, mechanical properties and processability is provided which comprises a composition containing (A) a dispersing phase of polyphenylene ether obtained by oxidation polymerization of at least one phenol compound represented by the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 each represents a hydrogen atom, a halogen atom or a substituted or unsubstituted hydrocarbon residue and at least one of them is a hydrogen atom and (B) a crystalline thermoplastic resin matrix phase and (C) a mutual compatibilizer compatible with (A) and/or (B), an average particle diameter in said dispersing phase having of 0.01-10.mu..
    Type: Grant
    Filed: September 30, 1992
    Date of Patent: April 19, 1994
    Assignee: Sumitomo Chemical Co., Ltd.
    Inventors: Taichi Nishio, Takashi Sanada, Satoru Hosoda, Kenji Nagaoka, Takayuki Okada
  • Patent number: 5302662
    Abstract: Novel blends have been discovered comprising: (A) a polyamide; (B) a polymer that is miscible with polystrene; and (C) a compatibilizer comprising a copolymer having repeating units derived from an aromatic vinyl compound monomer and repeating units derived from vinylphenol monomers, wherein at least about 50% of said aromatic vinyl compound monomers are styrene monomeric units. The blends show improvements in mechanical properties as compared to similar blends without the compatibilizer.
    Type: Grant
    Filed: February 19, 1993
    Date of Patent: April 12, 1994
    Assignee: Eastman Kodak Company
    Inventors: Christine J. Landry, Dennis J. Massa, Timothy E. Long, Michael R. Landry, David M. Teegarden, Ralph H. Colby
  • Patent number: 5300568
    Abstract: A thermoplastic resin composition which comprises 100 parts by weight of a composition comprising 95-5% by weight of at least one polyolefin-resin (A) selected from homopolymers of ethylene or .alpha.-olefin or copolymers thereof and these homopolymers or copolymers modified with a polyfunctional compound (E) and/or an unsaturated monomer (L) and 5-95% by weight of at least one polyphenylene-ether-resin (B) selected from polyphenylene ether, modified polyphenylene ether with the above (E) and/or (L) and a composition comprising the polyphenylene or modified polyphenylene ether and an aromatic vinyl polymer resin (M) and 0.001-10 parts by weight of a dinitrodiamine (D) of the following formula (I). ##STR1## (wherein X represents a divalent chain aliphatic group, a cyclic aliphatic group or an aromatic group which may contain a halogen or an oxygen atom, R.sup.1 represents a hydrogen atom, a chain aliphatic group, a cyclic aliphatic group or an aromatic group and when both of X and R.sup.
    Type: Grant
    Filed: April 8, 1991
    Date of Patent: April 5, 1994
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Hiroomi Abe, Takeshi Fujii, Masashi Yamamoto, Shinichi Yachigo, Hideo Nagasaki, Naoki Inui
  • Patent number: 5296540
    Abstract: Disclosed is a shaped resin article comprising (1) a continuous phase of a polyphenylene ether and (2) a dispersed phase dispersed in the continuous phase (1). The dispersed phase comprises (a) a particulate dispersed polyolefin phase which is comprised of a polyolefin and has a minor diameter of not greater than 0.5 .mu.m, the outer surface of the dispersed polyolefin phase (a) having, cohered thereto, particles of at least one copolymer selected from the group consisting of a copolymer of a vinyl aromatic compound and a conjugated diene compound and a hydrogenation product thereof, and (b) a particulate dispersed copolymer phase having a minor diameter of not greater than 0.3 .mu.m, which is comprised of at least one copolymer selected from the above-mentioned group and is dispersed in the continuous phase (1) and not cohered to the dispersed polyolefin phase (a).
    Type: Grant
    Filed: November 25, 1992
    Date of Patent: March 22, 1994
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Yoshikuni Akiyama, Ken Mizushiro
  • Patent number: 5296563
    Abstract: In order to prepare thermoplastic molding materials ofA) 5-95% by weight of a modified polyphenylene ether,B) 5 to 95% by weight of a thermoplastic polyamide,C) 0 to 25% by weight of an impact-modifying rubber, andD) 0 to 50% by weight of auxiliaries and/or additives,the components A and B and if necessary the components C and D are fed individually at one or more points into an extruder, mixed with one another, and melted. The component A present in a pulverulent consistency is compacted and/or sintered under pressure and if necessary with the addition of heat, preferably at a pressure corresponding to a nip pressure of 1 to 100 kn/cm to form a porous compact before it is fed into the extruder. The compact is then modified and added as granules to the feed zone of the extruder. In this way the proportion of the fines in the polyphenylene ether is considerably reduced, so that there is virtually no further danger of dust explosions.
    Type: Grant
    Filed: December 21, 1992
    Date of Patent: March 22, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Axel Gottschalk, Robert Weiss, Klaus Muehlbach, Carola Hedtmann-Rein, Robert Heinz
  • Patent number: 5296533
    Abstract: A resin composition having improved resistance to discoloration by sunlight comprising (A) a polymer mixture which comprises a polyphenylene ether, a polyamide and optionally a polystyrene and/or an agent to improve the impact resistance, and (B) an inorganic powder whose mean particle size is less than or equql to 5 micrometer, in an amount of more than or equal to 15 parts by weight based on 100 parts by weight of the polyphenylene ether in the polymer mixture (A), which is selected from the group consisting of titanium oxide, mica coated with titanium oxide, barium sulphate, zinc oxide and zinc sulfide.
    Type: Grant
    Filed: October 28, 1992
    Date of Patent: March 22, 1994
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kenji Nagaoka, Hiroshi Hagimori, Yasurou Suzuki, Takashi Sanada, Etsuji Okumura
  • Patent number: 5292789
    Abstract: A polyphenylene sulfide/polyphenylene ether composition is provided, which has excellent dimensional stability and impact resistance, as well as good heat resistance, rigidity and surface appearance. The composition also includes certain polyamide resins, hydrogenated conjugated diene/aromatic monovinyl block copolymers, modified polyolefins, compatibilizer agents, and inorganic fillers.
    Type: Grant
    Filed: May 15, 1992
    Date of Patent: March 8, 1994
    Assignee: GE Plastics Japan, Ltd.
    Inventors: Hiromi Ishida, Hidekazu Kabaya
  • Patent number: 5292780
    Abstract: This invention relates to a composition suitable for use in friction elements and comprises a frictional material and a binder, the latter being a blend of a polyvinyl alkyl ether with a phenolic resin and optionally a rubber.Compared with conventional friction elements based on organic polymers, the elements produced using the compositions of the present invention shows increases in flexural strength of up to 50% with no loss in wear or friction performance.
    Type: Grant
    Filed: July 11, 1990
    Date of Patent: March 8, 1994
    Assignee: BP Chemicals Limited
    Inventors: Christopher G. Godfrey, Bryan H. McCormick
  • Patent number: 5290860
    Abstract: Commercially available solid rubber modified acrylic multipolymers and polycarbonate polymer are tumble blended and melted and extruded through an extruder. Resulting alloys comprise an unsaturated rubber such as polybutadiene grafted with methylmethacrylate and styrene; a multipolymer comprising methylmethacrylate and styrene, and acrylonitrile, ethylacrylate, or methylacrylate; and polycarbonate. The ratio of rubber to graft monomers ranges from about 1:1 to about 6:1 and is preferably about 3:1. Graft monomers comprise from about 60 to about 85 parts methylmethacrylate, about 15 to about 30 parts styrene, and up to about 15 parts methylacrylate, ethylacrylate, or acrylonitrile. The multipolymer comprises from about 60 to about 80 parts of methylmethacrylate, about 15 to about 30 parts of styrene, and up to 15 parts of methylacrylate, ethylacrylate, or acrylonitrile. The ratio of graft rubber to multipolymer ranges from about 5:95 to about 25:75.
    Type: Grant
    Filed: November 12, 1992
    Date of Patent: March 1, 1994
    Assignee: Cyro Industries
    Inventors: Daniel D. Zimmerman, Gary Vieiro, Dennis S. Pavlick
  • Patent number: 5286790
    Abstract: Acrylate or methacrylate polymers, or copolymers of acrylates and/or methacrylates with other vinyl monomers, are blended in compositions with poly(phenylene ether), and/or with a poly(phenylene ether) concentrate containing poly(phenylene ether), polystyrene, a vinyl aromatic copolymer, polyamide, polycarbonate, polyester, poly(alkyl acrylate), and/or poly(alkyl methacrylate). The blended compositions may also optionally contain additional vinyl aromatic copolymer as a separate component, impact modifiers, thermoplastic molding materials including polycarbonate, polyester, polystyrene, polyolefin, polyamide, poly(vinyl chloride), polyurethane, polyacetal, and conventional additives such as dyes and pigments.
    Type: Grant
    Filed: March 10, 1992
    Date of Patent: February 15, 1994
    Assignee: The Dow Chemical Company
    Inventor: Michael K. Laughner
  • Patent number: 5284914
    Abstract: A thermoplastic polyester resin composition characterized by comprising30-70% by weight of a polyester resin (A) constituted mainly of a polyalkylene terephthalate,5-35% by weight of a graft polymer (B) obtained by graft-polymerizing at least one selected from the group consisting of an aromatic vinyl monomer and a methacrylate monomer in the presence of a rubbery polymer, and10-45% by weight of a polyphenylene ether resin (C) andresulting from blending these polymers so that the content of said polyester resin (A) may be higher than that of said polyphenylene ether resin (C).
    Type: Grant
    Filed: April 26, 1991
    Date of Patent: February 8, 1994
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Yutaka Toyooka, Masafumi Hongo, Hideyuki Shigemitsu
  • Patent number: 5283289
    Abstract: A fiber-reinforced rubber composition capable of providing a vulcanizate having an excellent strength and modulus and a production process thereof. This fiber-reinforced rubber composition includes fine short fibers of thermoplastic polymer having ##STR1## groups buried in vulcanizable rubber. The vulcanizable rubber and the thermoplastic polymer are grafted to each other through a resol type alkylphenol formaldehyde resin precondensate or a novolak type phenol formaldehyde resin precondensate at an interface of the fiber. The ratio of the fiber to the vulcanizable rubber (A) 1 to 70 parts by weight based on 100 parts by weight of the rubber in the case of the resol type alkylphenol formaldehyde resin precondensate or (B) 1 to 100 parts by weight based on 100 parts by weight of the rubber in the case of the novolak type phenol formaldehyde resin precondensate.
    Type: Grant
    Filed: June 19, 1991
    Date of Patent: February 1, 1994
    Assignee: UBE Industries, Ltd.
    Inventors: Shinji Yamamoto, Kouhei Kaijiri, Kouichi Nagakura, Denichi Oda, Yasuo Matsumori, Kimio Nakayama
  • Patent number: 5283285
    Abstract: This invention relates to a blend comprising a polyester, polycarbonate and an amine functinalized elastomer and optionally an effective amount of an effective graft coupling agent.
    Type: Grant
    Filed: April 5, 1993
    Date of Patent: February 1, 1994
    Assignee: AlliedSignal Inc.
    Inventors: Murali K. Akkapeddi, Bruce VanBuskirk
  • Patent number: 5283282
    Abstract: A polyamide composition comprising an aromatic ring-containing polyamide resin and a specific amount of an aliphatic polyester. The composition has improved molding properties, such as mold release characteristics, and exhibits excellent physical properties, such as stiffness, which will not be lowered upon contact with moisture. The polyamide composition may contain additional components which have been used to improve properties other than molding properties, such as Izod impact strength and hinge effect properties, so that the effects of the components are also exerted in the present composition without sacrificing the main effect aimed at by the present invention, i.e., excellent molding properties. Therefore, the polyamide composition of the present invention is useful as a molding material in various fields, e.g., automobile, electrical and electronic industries.
    Type: Grant
    Filed: December 10, 1991
    Date of Patent: February 1, 1994
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Tetsuo Hamada, Sadayuki Yakabe, Akira Ito
  • Patent number: 5281664
    Abstract: A novel process of sequentially mixing polymers comprisinga. mixing together and melt blending impact modifier and semicrystalline polymer to form a preblend, andb. mixing together and melt blending the preblend with amorphous polymer,and polymer compositions produced as a result of the novel process are disclosed.
    Type: Grant
    Filed: July 20, 1992
    Date of Patent: January 25, 1994
    Assignee: Ford Motor Company
    Inventors: Amos Golovoy, Mo-Fung Cheung
  • Patent number: 5280070
    Abstract: Polycarbonates can be blended with 1-99% of polymethyl methacrylate (PMMA) polymers in which at least 60% of the monomer units are in the syndiotactic configuration to form thermodynamically miscible, single phase, transparent blends at all compositions.
    Type: Grant
    Filed: June 1, 1992
    Date of Patent: January 18, 1994
    Assignee: Enichem S.p.A.
    Inventor: Michael A. Drzewinski
  • Patent number: 5276089
    Abstract: There is disclosed a blend of certain polyesters and polymers that are miscible with polystyrene, such as polyphenylene oxide. The blend is characterized by the presence of a compatibilizing amount of a copolymer having repeating units derived from an aromatic vinyl compound monomer and a vinylphenol monomer. The polyester is thermoplastic and is characterized in that the diacid component of the polyester includes aromatic groups and the diol component comprises at least about 20 percent by weight of a noncyclic, aliphatic diol.
    Type: Grant
    Filed: August 26, 1991
    Date of Patent: January 4, 1994
    Assignee: Eastman Kodak Company
    Inventors: Ralph H. Colby, Christine J. T. Landry, Michael R. Landry, Timothy E. Long, Dennis J. Massa, David M. Teegarden
  • Patent number: 5274034
    Abstract: The invention relates to polymer compositions comprising an aromatic polycarbonate, an aromatic polycarbonate with acid or ester functionality, a styrene based polymer and a styrene polymer with oxazoline groups.The polymer composition of the invention is suitable for molding objects with a mat surface.
    Type: Grant
    Filed: May 22, 1992
    Date of Patent: December 28, 1993
    Assignee: General Electric Company
    Inventors: Sarah E. Morgan, Charles F. Pratt, Constantinus L. J. A. Verbraak, Stanley Y. Hobbs, Edward J. Fewkes, Jr.
  • Patent number: 5270386
    Abstract: A blend of a vinyl aromatic copolymer, and a poly(phenylene ether) concentrate containing poly(phenylene ether), a vinyl aromatic copolymer, polyamide, polycarbonate, polyester, poly(alkyl acrylate), and/or poly(alkyl methacrylate). The blend may optionally contain impact modifiers, thermoplastic molding materials including polyester, polystyrene, polyolefin, polyamide, poly(vinyl chloride), polyurethane, polyacetal, and conventional additives such as dyes and pigments.
    Type: Grant
    Filed: March 10, 1992
    Date of Patent: December 14, 1993
    Assignee: The Dow Chemical Company
    Inventor: Michael K. Laughner
  • Patent number: 5268424
    Abstract: A chlorinated polyvinyl chloride/polycarbonate blend is prepared utilizing a conventional vinyl impact modifier such as methyl methacrylate-butadiene-styrene (MBS) copolymer as a compatibilizing agent. The blend has good thermomechanical properties such as good dimensional stability under heat, good impact resistance, and improved processability. The chlorinated polyvinyl chloride, polycarbonate, and impact modifier are simultaneously mixed or, alternatively, a preblend of the polycarbonate and the conventional impact modifier is made to which the CPVC is subsequently added and blended.
    Type: Grant
    Filed: June 1, 1992
    Date of Patent: December 7, 1993
    Assignee: The B. F. Goodrich Company
    Inventor: Dennis L. Lawson
  • Patent number: 5268425
    Abstract: Disclosed are thermoplastic resin compositions, comprising:(a) a polyphenylene ether resin or a resin composition containing a poplyphenylene ether,(b) a modified propylene polymer, or a propylene based resin composition containing the modified propylene polymer and/or a propylene polymer, and(c) optionally, a rubbery substance,wherein the proportion of the component (a) to the sum of the components (a) and (b) is 1 to 90% by weight, and that of the component (b) to the sum of the components (a) and (b) is 99 to 10% by weight, and when the component (c) is present, the proportion of the component (c) to the sum of the components (a) and (b) is 1 to 50 parts by weight per 100 parts by weight of (a) plus (b).
    Type: Grant
    Filed: May 29, 1992
    Date of Patent: December 7, 1993
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Motonobu Furuta, Kazuki Wakamatsu, Takashi Maruyama, Mitsuji Tsuji
  • Patent number: 5266638
    Abstract: A thermoplastic molding material which is made up of components A, B, C, and D. Component A comprises 10-90% of the composition and is a copolymer made up of 30-95% styrene; 4-40% (meth)acrylonitrile, methyl methacrylate, or maleic anhydride; 1-30% of a monomer described by formula in the specification, N-vinylimidazole or N-vinylcarbazole; and up to 40% of a copolymerizable ethylenically unsaturated monomer. Component B comprises 10-90% of the composition and is a copolymer made up of 50-99.9% of an alpha-olefin; 0.1-50% of a monomer containing acid groups; and up to 40% of a copolymerizable ethylenically unsaturated monomer. Component C comprises up to 80% of the composition and is a copolymer made up of 50-95% styrene and 5-50% (meth)acrylonitrile, methyl methacrylate or maleic anhydride. Component D comprises up to 80% of the composition and is made up of a polycarbonate. All percentages are by weight.
    Type: Grant
    Filed: November 13, 1992
    Date of Patent: November 30, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Norbert Niessner, Klaus Muehlbach, Friedrich Seitz
  • Patent number: 5266634
    Abstract: A resin composition containing a mixture of a polycarbonate resin and a rubber-reinforced styrene base resin which is prepared by polymerizing, in the presence of a rubbery polymer, a monomer mixture of an aromatic vinyl monomer, at least one of cyanated vinyl monomers and alkyl esters of unsaturated carboxylic acids and at least one other vinyl monomer; a polyolefin graft polymer which is prepared by polymerizing, in the presence of a crystalline polyolefin, a monomer of an aromatic vinyl monomer and at least one of cyanated vinyl monomers and alkyl esters of unsaturated carboxylic acids; and optionally a terpolymer of an olefin, an unsaturated dicarboxylic anhydride and an alkyl ester of an unsaturated carboxylic acid or an epoxy group-containing olefin copolymer of an unsaturated epoxy compound, an olefin and optionally an ethylenically unsaturated compound, which composition has good coating properties.
    Type: Grant
    Filed: November 20, 1991
    Date of Patent: November 30, 1993
    Assignee: Sumitomo Naugatuck Co., Ltd.
    Inventors: Akitoshi Ito, Yutaka Yoshida
  • Patent number: 5264487
    Abstract: Resinous compositions are prepared by blending an ABS copolymer or similar addition polymer, a polyphenylene ether-polystyrene blend, and a copolymer of an olefin such as ethylene and an epoxy compound such as glycidyl methacrylate. The first two constituents may be scrap materials. The resulting compositions have high impact strength and other advantageous properties.
    Type: Grant
    Filed: May 26, 1992
    Date of Patent: November 23, 1993
    Assignee: General Electric Company
    Inventors: James J. Scobbo, Jr., Michael P. Laughner, Marinus E. J. Dekkers
  • Patent number: 5262476
    Abstract: Blends of polycarbonate and polyester are admixed in compositions with poly(phenylene ether), and/or with a poly(phenylene ether) concentrate containing poly(phenylene ether), polystyrene, a vinyl aromatic copolymer, polyamide, polycarbonate, polyester, poly(alkyl acrylate), and/or poly(alkyl methacrylate). The blended compositions may also optionally contain additional vinyl aromatic copolymer as a separate component, impact modifiers, thermoplastic molding materials including polystyrene, polyolefin, polyamide, poly(vinyl chloride), polyurethane, poly(methyl methacrylate) and polyacetal, and conventional additives such as dyes and pigments.
    Type: Grant
    Filed: March 10, 1992
    Date of Patent: November 16, 1993
    Assignee: The Dow Chemical Company
    Inventor: Michael K. Laughner
  • Patent number: 5262480
    Abstract: Polyphenylene ether resin/polypropylene resin compositions are disclosed which have improved heat deflection temperature and stiffness. The improvements result from the use of a polyphenylene ether resin having an intrinsic viscosity of below about 0.30 dl./gm. The compositions may further comprise an impact modifier.
    Type: Grant
    Filed: June 25, 1992
    Date of Patent: November 16, 1993
    Assignee: General Electric Company
    Inventor: Gim F. Lee, Jr.