Polycarboxylic Acid Or Derivative Or Polyol Contains An Atom Other Than C, H, Or O; Or Wherein A Polycarboxylic Acid Or Derivative Or Polyol Or Condensate Thereof Is Reacted With A Reactant Containing Atoms Other Than C, H, Or O Prior To Blending With The Solid Polymer; Or Wherein A Coreactant With The Polycarboxylic Acid Or Derivative Or Polyol Contains An Atom Other Than C, H, Or O Patents (Class 525/167)
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Patent number: 11390710Abstract: A reversibly crosslinked polymer and methods for producing and using the obtained polymer are disclosed. In particular, reversibly crosslinked polymers of the invention comprise polyesters formed by the reaction of mercaptosuccinic acid and a diol to form a monomeric unit that includes thiol groups as crosslinking moieties. Oxidation of the thiol groups affords crosslinked polymer comprising a disulfide linkage that, upon reduction of the disulfide linkage, provides a non-crosslinked polymer. In some embodiments, polymers of the invention are degradable and are biocompatible.Type: GrantFiled: April 29, 2013Date of Patent: July 19, 2022Assignee: WiSys Technology Foundation, Inc.Inventor: John P. Droske
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Patent number: 11345823Abstract: Suggested is a method for modifying the rheology of a casting resin and/or coating composition, comprising the following steps: providing a composition comprising at least one monomer capable of forming a casting resin or coating upon polymerisation; and adding to said composition a working amount of a urea urethane obtained under specific conditions as a thixotropic agent.Type: GrantFiled: September 24, 2020Date of Patent: May 31, 2022Assignee: CLiQ SwissTech B.V.Inventors: Detlef Van Pey, René Stèphan Bouwman, Daniel Haveman
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Patent number: 10358555Abstract: Composition including: (A) 50% to 95% of at least one semicrystalline polyamide of formula A/Z in which: A is an aliphatic repeating unit chosen from a unit obtained from the polycondensation of at least one amino acid and a unit obtained from the polycondensation of at least one lactam or a unit X.Y obtained from the polycondensation of at least one diamine, and of at least one dicarboxylic acid, and Z represents another polyamide and is included from 0 to 20%; (B) 5% to 50% of at least one semicrystalline copolyamide comprising amide units (Ba1) and including polyether units (Ba2), having a glass transition temperature (Tg) below 75° C.; (C) 0% to 20% by weight of fibres and/or fillers, (D) 0% to 20% of at least one impact modifier, (E) 0% to 5% of at least one additive, for the manufacture of a sports article.Type: GrantFiled: March 23, 2015Date of Patent: July 23, 2019Assignee: ARKEMA FRANCEInventors: François Fernagut, René-Paul Eustache, Mathieu Sabard, Yves Deyrail
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Patent number: 10166742Abstract: The invention concerns a metal laminate comprising between two outer metal sheets an adhesive polymer layer, characterized in that the adhesive polymer layer comprises polyamide, a copolymer of ethylene and an unsaturated carboxylic acid and/or a derivative thereof and a reactive copolymer. The invention further concerns a process for the manufacture of such a metal laminate and the use of such metal laminates for the manufacture of automotive body parts.Type: GrantFiled: August 4, 2004Date of Patent: January 1, 2019Assignees: USINOR, THYSSEN KRUPP STAHL AGInventors: Antoine Gauriat, Cédric Calvez, Francis Schmit, Cetin Nazikkol, Christoph Filthaut, Roland Herd Smith, Jiri Pac
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Patent number: 9815922Abstract: It is an object of the present invention to provide a method for producing a terminal-modified polybutadiene or terminal-modified hydrogenated polybutadiene that does not become colored or white and turbid, without using an organotin compound. The production method of the present invention includes reacting an acrylate or methacrylate represented by formula (I), a diisocyanate compound represented by formula (II), and a polybutadiene or hydrogenated polybutadiene having a hydroxyl group at a polymer terminal, represented by formula (III), in the presence of at least one selected from an organoaluminum compound and an organozinc compound (with the proviso that zinc naphthenate is excluded).Type: GrantFiled: October 11, 2013Date of Patent: November 14, 2017Assignee: NIPPON SODA CO., LTD.Inventor: Hiroki Hashimoto
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Patent number: 9757984Abstract: The present invention relates to a film for a tire inner liner including a base film layer including a copolymer or a mixture of a polyamide-based resin and a polyether-based resin, and an adhesive layer including a resorcinol-formalin-latex (RFL)-based adhesive, and having low shrinkage rate when elongated at a high temperature and then cooled to room temperature, and a method for manufacturing the same.Type: GrantFiled: December 30, 2011Date of Patent: September 12, 2017Assignee: KOLON INDUSTRIES, INC.Inventors: So-Yeon Kwon, Young-Han Jeong, Il Chung, Ok-Hwa Jeon
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Patent number: 9605546Abstract: Novel extruded ceiling fan blades, compositions and methods of making the blades from plastic material such as polystyrene are disclosed. The blades can be formed from two extruders so that different colors and/or finishes, such as wood grain looks can be formed on the upper and lower surfaces of the blades.Type: GrantFiled: June 21, 2013Date of Patent: March 28, 2017Assignee: Chien Luen Industries Co., Ltd., Inc.Inventors: Tien S. Lowe, Eliezer E. Rivera, Zachary Zauhar
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Patent number: 9527254Abstract: This disclosure relates to a film for a tire inner liner including a base film layer that has 3 glass transition temperature peaks and an adhesive layer including a resorcinol-formalin-latex(RFL)-based adhesive, and a method for manufacturing the film for a tire inner liner.Type: GrantFiled: September 28, 2012Date of Patent: December 27, 2016Assignee: KOLON INDUSTRIES, INC.Inventors: So-Yeon Kwon, Hyun Namgoong, Young-Han Jeong
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Patent number: 9505924Abstract: An ABS resin composition including: (A) 100 parts by mass of an ABS resin having a total light transmittance of 70% or more; (B) 1 to 70 parts by mass of an antistatic agent including a polyether ester amide having a polyamide 12 skeleton; (C) 1 to 70 parts by mass of an acid-modified methacrylic acid-based polymer having a refractive index of 1.50 to 1.56.Type: GrantFiled: March 11, 2015Date of Patent: November 29, 2016Assignee: DAICEL POLYMER LTD.Inventor: Toshihiro Tai
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Patent number: 9492981Abstract: This disclosure relates to a film for a tire inner liner including a base film layer including a copolymer or a mixture of 50 wt % to 95 wt % of a polyamide-based resin and 5 wt % to 50 wt % of a polyether-based resin, and an adhesive layer including a resorcinol-formalin-latex (RFL)-based adhesive formed on at least one side of the base film layer, wherein a difference between a maximum thickness and an average thickness of the base film layer and a difference between a minimum thickness and the average thickness of the base film layer are respectively 6% or less of the base film, and a method for manufacturing the same. According to the present invention, an excellent gas barrier property may be achieved with a thin thickness, and thus the weight of a tire may become light and the mileage of automobiles may be improved, and as the inner liner film may have a uniform thickness, excellent forming stability and a tire having excellent durability may be provided.Type: GrantFiled: September 28, 2012Date of Patent: November 15, 2016Assignee: KOLON INDUSTRIES, INC.Inventors: Ki-Sang Song, Yun-Jo Kim, Hyun Cho, Si-Min Kim
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Patent number: 9457613Abstract: The present invention relates to cyanoacrylate compositions in non-flowable and gel forms. More particularly, the present invention relates to non-flowable cyanoacrylate compositions which can be packaged in a convenient pocket-sized applicator dispenser for use in spreading the cyanoacrylate compositions onto substrates.Type: GrantFiled: March 18, 2011Date of Patent: October 4, 2016Assignee: Henkel IP & Holding GmbHInventor: Shabbir Attarwala
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Patent number: 8785557Abstract: The present invention relates to the use of aqueous hybrid binders for producing coating compositions, more particularly in high-gloss coating materials (high-gloss paints), and also to a process for their preparation with low residual monomer content.Type: GrantFiled: December 13, 2010Date of Patent: July 22, 2014Assignee: BASF SEInventors: Sebastian Roller, Roelof Balk, Rolf Dersch
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Publication number: 20130323505Abstract: A fiber made of a polyester copolymer (B), wherein the polyester copolymer (B) comprises a dicarboxylic acid component and a glycol component, and the dicarboxylic acid component comprises 75 mol % or more of a terephthalic acid component, 1.0 mol % to 3.5 mol % of component (a) derived from a compound represented by formula (I), 2.0 mol % to 10.0 mol % of a cyclohexane dicarboxylic acid component (b), and 2.0 mol % to 8.0 mol % of an aliphatic dicarboxylic acid component (c). This can afford a polyester fiber that exhibits deep color property to cation dyes and disperse dyes under a normal pressure environment and is superior in color fastness to washing and color fastness to light and can secure good spinnability.Type: ApplicationFiled: February 17, 2012Publication date: December 5, 2013Applicant: KURARAY CO., LTD.Inventors: Hitoshi Nakatsuka, Kazuhiko Tanaka, Kazuhide Oka, Daisuke Ohga, Shinya Kawakado
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Publication number: 20130295040Abstract: The application provides a method of producing a comb polymer comprising the steps of: (a) Providing: (i) a plurality of monomers which are linear, branched or star-shaped, substituted or non-substituted, and have an olefinically unsaturated moiety, the olefinically unsaturated moiety being capable of undergoing addition polymerisation; (ii) an initiator compound; the initiator compound comprising a homolytically cleavable bond. (iii) a catalyst capable of catalysing the polymerisation of the monomer; and (b) Causing the catalyst to catalyse, in combination with the initiator, the polymerisation of a plurality of the monomers to produce the comb polymer. Catalysts and polymers obtainable by the process are also provided. Preferably, the comb polymer is capable of binding proteins and may be produced from monomers which are alkoxy polyethers, such as poly(alkyleneglycol) or polytetrahydrofuran.Type: ApplicationFiled: April 5, 2013Publication date: November 7, 2013Inventor: Warwick Effect Polymers Limited
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Patent number: 8574466Abstract: A pigment dispersant which includes a modified polyamine obtained by the reaction of a polyamine having two or more primary and/or secondary amino groups per molecule and containing 2 to 1800 nitrogen atoms per molecule, a polyester, and a phosphorus-containing compound. The modified polyamine exhibits excellent pigment dispersion performance, shows little change in color tone upon heating, and has excellent heat resistance.Type: GrantFiled: January 15, 2013Date of Patent: November 5, 2013Assignee: Ajinomoto Co., Inc.Inventor: Yuji Koshima
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Patent number: 8563106Abstract: The present invention provides a thermoplastic resin composition producing an extremely small amount of outgas and providing a molded article having excellent antistaticity. The present thermoplastic resin composition comprises a thermoplastic resin and is characterized in that the amount of outgas is 1500 ?g/g or less. The composition may comprise a surface resistivity reducing substance in an amount of 0.1 to 70 parts by mass relative to 100 parts by mass of the thermoplastic resin. The present invention is suitable to a composition comprising a styrenic resin as the thermoplastic resin. The surface resistivity reducing substrate is preferably a polyamide elastomer comprising a hard segment formed of polyamide 12 and a soft segment formed of poly(alkylene oxide)glycol. The polyamide elastomer preferably has a refractive index of 1.5 to 1.53, a melting point of 130 to 160° C., a solution viscosity of 1.35 to 1.70 and a surface resistivity of 1×108 to 1×1011?.Type: GrantFiled: May 14, 2010Date of Patent: October 22, 2013Assignee: Techno Polymer Co., Ltd.Inventor: Norifumi Sumimoto
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Publication number: 20130189727Abstract: The invention is a compound represented by any one of Structural Formulas (I)-(IV), or a salt thereof, wherein the values and alternative values for the variables are as defined in the Detailed Description of the Invention. Methods using a compound of Structural Formula (I)-(IV), or a salt thereof, are also presented.Type: ApplicationFiled: March 15, 2013Publication date: July 25, 2013Applicant: NATIONAL UNIVERSITY OF SINGAPOREInventor: NATIONAL UNIVERSITY OF SINGAPORE
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Publication number: 20130126804Abstract: A pigment dispersant which includes a modified polyamine obtained by the reaction of a polyamine having two or more primary and/or secondary amino groups per molecule and containing 2 to 1800 nitrogen atoms per molecule, a polyester, and a phosphorus-containing compound. The modified polyamine exhibits excellent pigment dispersion performance, shows little change in color tone upon heating, and has excellent heat resistance.Type: ApplicationFiled: January 15, 2013Publication date: May 23, 2013Applicant: AJINOMOTO CO., INC.Inventor: AJINOMOTO CO., INC.
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Publication number: 20130102761Abstract: Proteins are purified by a mixed-mode chromatography system formed by attaching a ligand with cation exchange and hydrophobic functionalities to a large-pore support matrix, the only linkage between the ligand and the support matrix being a chain having a backbone of no more than three atoms between the hydrophobic group and the support matrix.Type: ApplicationFiled: October 18, 2012Publication date: April 25, 2013Applicant: Bio-Rad Laboratories, Inc.Inventor: Bio-Rad Laboratories, Inc.
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Patent number: 8349621Abstract: A ligand molecule-immobilized polymer has a structure represented by the following general formula (1). In the general formula (1), R1 represents a ligand molecule-containing group, R2 represents a hydrophobic group, R3 represents a spacer site, R4 represents a hydrophilic group, R5 represents a group having charge, a to d specify a composition ratio and each represent an integer of 1 or more, and n and m specify chain lengths and represent integers satisfying the relationships of 1?n(a+b+c+d)?10,000 and 1?m?350.Type: GrantFiled: November 24, 2008Date of Patent: January 8, 2013Assignee: Canon Kabushiki KaishaInventor: Kousuke Mukumoto
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Publication number: 20120283386Abstract: There is provided an antistatic agent that preserves its antistatic property for a long period of time and has the appearance and the transparency that are not impaired when kneaded into a resin, and a resin composition containing the antistatic agent. An antistatic agent including a block copolymer which is obtained from a reaction product of a polyolefin (a) having one end being acid-modified and a diol and/or a diamine (b) having a polyoxyalkylene chain, and in which a part or all of acid groups remaining in the reaction product is neutralized with an alkaline substance. A thermoplastic resin composition including the antistatic resin. A film or sheet including the thermoplastic resin composition.Type: ApplicationFiled: January 7, 2011Publication date: November 8, 2012Applicant: TOHO CHEMICAL INDUSTRY CO., LTD.Inventor: Tetsuhiro Utsumi
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Publication number: 20120172529Abstract: The invention relates to coloured and/or fluorescent copolycondensates which are obtained by reaction of colourants substituted by at least two reactive groups which do not interfere with one another, with selected cyclic dicarboxylic acids (especially 1,4-cyclohexanedicarboxylic acid), aliphatic diols (especially ethylene glycol), cyclic diamines (especially isophoronediamine) and/or amino acids in particular amounts.Type: ApplicationFiled: September 15, 2010Publication date: July 5, 2012Applicant: BASF SEInventors: Thomas Ruch, Thomas Eichenberger, Peter Sutter, Christoph Krebs, Ursula Luterbacher
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Publication number: 20110269873Abstract: The invention relates to biodegradable polyester mixture, comprising i) from 5 to 80% by weight, based on the total weight of components i to ii, of at least one polyester based on aliphatic and aromatic dicarboxylic acids and on aliphatic dihydroxy compounds, and ii) from 20 to 95% by weight, based on the total weight of components i to ii, of at least one biodegradable homo- or copolyester selected from the group consisting of polylactide, polycaprolactone, polyhydroxyalkanoates, and polyesters composed of aliphatic dicarboxylic acids and of aliphatic diols, and iii) from 0.Type: ApplicationFiled: July 13, 2011Publication date: November 3, 2011Applicant: BASF SEInventors: Ursula Seeliger, Gabriel Skupin, Dirk Stärke
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Patent number: 7989548Abstract: The invention relates to a new polymer blend comprising: 20 to 70 wt % of a mixture (A) of two or more polyalkylene phthalates; 2 to 60 wt % of a cross-linked acrylate rubber; 0.5 to 20 wt % of an ionomer; and 1 to 30 wt % of a terpolymer of ethylene, butylacrylate (BA) and glycidylmethacrylate (GMA); wherein the weight percentages are based on the sum of the above ingredients. The polymer blend of the invention is particularly suitable for blow-moulding, to make parts for high-temperature, high-oil-exposure uses.Type: GrantFiled: July 7, 2009Date of Patent: August 2, 2011Assignee: E.I. du Pont de Nemours and CompanyInventors: Vincent Descombes, Philippe Leboeuf, Jean-Michel Philippoz, Michel C. Renaud, Serge Cavalli
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Publication number: 20100222511Abstract: The present invention provides a thermoplastic resin composition producing an extremely small amount of outgas and providing a molded article having excellent antistaticity. The present thermoplastic resin composition comprises a thermoplastic resin and is characterized in that the amount of outgas is 1500 ?g/g or less. The composition may comprise a surface resistivity reducing substance in an amount of 0.1 to 70 parts by mass relative to 100 parts by mass of the thermoplastic resin. The present invention is suitable to a composition comprising a styrenic resin as the thermoplastic resin. The surface resistivity reducing substrate is preferably a polyamide elastomer comprising a hard segment formed of polyamide 12 and a soft segment formed of poly(alkylene oxide)glycol. The polyamide elastomer preferably has a refractive index of 1.5 to 1.53, a melting point of 130 to 160° C., a solution viscosity of 1.35 to 1.70 and a surface resistivity of 1×108 to 1×1011?.Type: ApplicationFiled: May 14, 2010Publication date: September 2, 2010Applicant: TECHNO POLYMER CO., LTD.Inventor: Norifumi SUMIMOTO
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Patent number: 7638201Abstract: The present invention provides storage stable powder compositions comprising one or more carboxylic acid or anhydride functional, phosphorus-containing polyester chosen from aromatic polyesters having an acid number of 15 or higher mg KOH/g polyester, aliphatic polyesters having an acid number of 20 or higher mg KOH/g polyester. The acid functional, phosphorus-containing polyester comprises the reaction product of one or more polyacid, one or more phosphorus-containing acid or salt thereof and one or more polyol. Preferably, the one or more polyol reactant contains no ?-hydrogen such as, for example, neopentyl glycol (NPG). The acid functional, phosphorus-containing polyester may comprise all or part of a binder powder composition, such as a coating powder, or it may comprise an additive thereto that imparts improved pigment wetting and corrosion resistance to a binder composition.Type: GrantFiled: May 2, 2007Date of Patent: December 29, 2009Assignee: Rohm and Haas CompanyInventors: Douglas S. Cinoman, Andrew T. Daly, Gordon L. Tullos
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Publication number: 20090111928Abstract: Macromonomers capable of both physical crosslinking and chemical crosslinking. The combination of chemical crosslinking and physical crosslinking provides the ability to generate rapidly gelling hydrogels for many different applications. Moreover, the macromonomers may incorporate functional groups that allow for two different gelation mechanisms—thermal gelation and ionic gelation—further improving mechanical stability of hydrogels formed from the disclosed macromonomers.Type: ApplicationFiled: October 27, 2008Publication date: April 30, 2009Inventors: Antonios G. Mikos, Michael C. Hacker
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Patent number: 7521508Abstract: Two-phase or single-phase admixtures of a plastic and an elastomer, two or more thermoplastics, or two or more elastomers are irradiated (preferably with electron beam radiation) to cross-link the thermoplastic and, in the case of elastomer and thermoplastic admixtures, generate bi-modal molecules having moieties derived from both the elastomer and the thermoplastic.Type: GrantFiled: June 30, 2004Date of Patent: April 21, 2009Assignee: Freudenberg-NOK General PartnershipInventors: Edward Hosung Park, Francis Joseph Walker
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Patent number: 7507474Abstract: The invention relates to thermoplastic compositions comprising a polymer matrix and an additive which modifies the rheological behavior of the matrix in the molten state. The purpose of the invention is to provide a preferably non-reactive additive which can be dispersed in the matrix and which can be used to obtain a good compromise in terms of rheological properties/mechanical properties. According to the invention, the additive is a hyperbranched polymer which is functionalized by R<2> radicals, R<2> being a radical of the following type: substituted or non-substituted hydrocarbon, of the silicon type, linear or branched alkyl, aromatic, arylalkyl, alkylaryl or cycloaliphatic, which can comprise one or more unsaturations and/or one or more heteroatoms.Type: GrantFiled: December 16, 2002Date of Patent: March 24, 2009Assignee: RhodianylInventors: Joël Varlet, Florence Clement, Franck Touraud, Sandrine Rochat, Natalia Scherbakoff
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Patent number: 7408010Abstract: The present invention relates to primer compositions in non-flowable form. More particularly, the present invention relates to non-flowable primer compositions which are particularly useful for use with curable adhesive and sealant compositions in threadlocking, retaining, bonding and sealing applications and which can be packaged in a convenient pocket-sized applicator dispenser.Type: GrantFiled: December 15, 2006Date of Patent: August 5, 2008Assignee: Henkel CorporationInventors: Prakash S. Patel, Shabbir Attarwala, Matthew P. Burdzy, Qinyan Zhu
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Patent number: 7378470Abstract: This invention relates to thermoplastic molding compositions with improved flowability based on a thermoplastic polyester and on at least one copolymer composed of at least one olefin with at least one methacrylic ester or acrylic ester of an aliphatic alcohol, the MFI of the copolymer being not less than 50 g/10 min, to a process for preparation of these molding compositions, and also the use of these molding compositions for production of moldings for the electrical, electronics, telecommunications, motor vehicle or computer industry, in sports, in the household, in medicine or for the entertainment industry.Type: GrantFiled: November 30, 2005Date of Patent: May 27, 2008Assignee: LANXESS Deutschland GmbHInventors: Peter Persigehl, Detlev Joachimi, Kurt Jeschke, Marcus Schäfer, Ralph Ulrich, Robert Hubertus Van Mullekom, Jochen Endtner, Jens Peter Joschek, Matthias Bienmüller
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Publication number: 20080045658Abstract: The invention is based on the use of high-energy grinding mills for treating by combined mechanical and chemical action materials comprising one or more polymers in the liquid state thereof, in view of modifying the chemical/physical performance properties thereof. The polymers may be treated in the mill either alone or mixed with other materials, even non-polymeric organic or inorganic ones, which may themselves be either in liquid form or in the form of particles. An elastic transpiring membrane and an additive for protective coatings for wooden surfaces are specifically indicated and claimed as typical products among a variety of products that can be obtained with this method.Type: ApplicationFiled: May 24, 2007Publication date: February 21, 2008Applicants: VAGOTEX WINDTEX SPA, MBN NANOMATERIALIA SPAInventors: Paolo Matteazzi, Diego Basset, Ferdinando Fiorio
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Patent number: 7332547Abstract: The present invention relates to adhesive and sealant compositions in non-flowable form. More particularly, the present invention relates to non-flowable adhesive and sealant compositions which are particularly useful in the threadlocking and sealing applications and which can be packaged in a convenient pocket-sized applicator dispenser.Type: GrantFiled: December 5, 2006Date of Patent: February 19, 2008Assignee: Henkel CorporationInventors: Shabbir Attarwala, Zhu Qinyan, Matthew P. Burdzy
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Patent number: 7300979Abstract: Light-stable and weather-stable coating films contain a powder coating composition, containing from 30 to 98.5% by mass of a binder containing at least one urethane (meth)acrylate having a melting point of from 40 to 130° C.; from 1 to 20% by mass of at least one micronized wax; and from 0.5 to 50% by mass of at least one auxiliary and/or at least one additive, the composition being cross-linked by actinic radiation.Type: GrantFiled: September 15, 2004Date of Patent: November 27, 2007Assignee: Degussa A.G.Inventors: Andreas Wenning, Emmanouil Spyrou
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Patent number: 7144956Abstract: The present invention relates to adhesive and sealant compositions in non-flowable form. More particularly, the present invention relates to non-flowable adhesive and sealant compositions which are particularly useful in the threadlocking and sealing applications and which can be packaged in a convenient pocket-sized applicator dispenser.Type: GrantFiled: March 1, 2005Date of Patent: December 5, 2006Assignee: Henkel CorporationInventors: Shabbir Attarwala, Zhu Qinyan, Matthew P. Burdzy
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Patent number: 7135524Abstract: The present invention relates to a mixture encompassing at least one plastic A, in particular polyvinyl chloride (PVC), polyvinyl butyral (PVB), or a polysulfide, and at least one polyester B which can be prepared from a dicarboxylic acid I, and from at least one diol II selected from the group consisting of 1,2-propanediol, 1,3-butanediol, and 1,4-butanediol, and from a monocarboxylic acid III, in particular acetic acid, and also to the use of the mixtures of the invention in casings for electrical devices, in kitchen machines, in computer cases, in piping, chemical apparatus, cables, wire sheathing, window profiles, in interior fittings, in vehicle construction and furniture construction, in floorcoverings, for producing medical items, packaging for food or drink, gaskets, sealing compounds, including those for sealed glazing, films, including roofing films, composite films, phonographic disks, synthetic leather, toys, packaging containers, adhesive tape films, clothing, or coatings, or as fibers for fabricType: GrantFiled: August 22, 2002Date of Patent: November 14, 2006Assignee: BASF AktiengesellschaftInventors: Boris Breitscheidel, Thomas Schäfer
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Patent number: 6998438Abstract: The present invention provides plastics with high toughness and the preparation thereof. The plastics with high toughness, which have the balance of stiffness and toughness, stable properties and good processability, are obtained by blending the rubber particles having an average particle size of 20 to 200 nm with the pseudoductile plastics, wherein the weight ratio of the rubber particles to the plastics is from 0.5:99.5 to 70:30. The present invention also provides plastics with both high stiffness and high toughness and the preparation thereof. The plastics with both high stiffness and high toughness, which have also an improved heat resistance and good processability, are prepared by blending the rubber particles having an average particle size of 20 to 500 nm and the crystalline plastics, wherein the amount of the rubber particles added in the plastics matrix is from 0.3 to 5 weight parts.Type: GrantFiled: April 18, 2002Date of Patent: February 14, 2006Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical IndustryInventors: Jinliang Qiao, Shijun Zhang, Xiaohong Zhang, Yiqun Liu, Jianming Gao, Wei Zhang, Genshuan Wei, Jingbo Shao, Hua Yin, Renli Zhai, Zhihai Song, Fan Huang, Jiuqiang Li
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Patent number: 6936647Abstract: The present invention relates to novel crosslinked bead polymers having an average particle size of 1 to 1000 ?m containing specific, halogen-free phosphorus compounds including triphenyl phosphate as the halogen-free phosphorus compound, and to a process for the production of these bead polymers and to the use thereof as flame retardants in thermoplastics.Type: GrantFiled: February 26, 2001Date of Patent: August 30, 2005Assignee: Bayer AktiengesellschaftInventors: Wolfgang Podszun, Andreas Seidel, Thomas Eckel, Dieter Wittmann, Kamelia Karlou-Eyrisch
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Patent number: 6893731Abstract: This invention provides a water-based composition suitable for use on polyester-based substrates for increasing adhesion between the substrate and a topcoat or overcoat. The composition comprises: (1) a latex polymer formed from the polymerization of at least one monomer selected from the group consisting of bicyclic alkyl (meth)acrylates and aromatic (meth)acrylates and at least one monomer which imparts to the polymer the ability to be crosslinked; (2) a water soluble or water dispersible polymer selected from the group consisting of acrylate-based resins, sulfonated polyester-based resins and combinations thereof; and (3) a crosslinking agent.Type: GrantFiled: September 25, 2001Date of Patent: May 17, 2005Assignee: 3M Innovative Properties CompanyInventor: William L. Kausch
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Patent number: 6849693Abstract: Hydroxyl group-containing polymers which comprise moieties of polyesters and of addition polymers formed from olefinically unsaturated monomers, the polyesters containing units from aliphatic cyclic or polycyclic dihydroxy or polyhydroxy compounds or diepoxy or polyepoxy compounds A and aliphatic cyclic dicarboxylic or polycarboxylic acids B and the addition polymers containing units from olefinically unsaturated alkyl esters G of aliphatic, linear, branched or cyclic olefinically unsaturated monocarboxylic and/or dicarboxylic acids, olefinically unsaturated hydroxyalkyl esters H of one of the acids specified under G, at least one further olefinically unsaturated monomer I selected from vinylaromatics, vinyl esters, halogenated monomers, unsaturated nitriles, amides or diamides of unsaturated monocarboxylic acids, vinyl ethers, and allyl ethers, and also, where appropriate, carboxylic acids J, selected from the monocarboxylic acids specified under G or dicarboxylic acids specified under G in unesterified or mType: GrantFiled: December 12, 2002Date of Patent: February 1, 2005Assignee: Solutia Austria GmbHInventors: Ulrich Epple, Martin Geisberger, Fritz Gartler
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Patent number: 6770378Abstract: Compounds which, for example, can be used as a compact substance and which are comprised of polyamide substance(s) and perfluoralkyl substance(s), and to mixtures of these compounds with additional polymer substance(s). Methods for producing such compounds are also provided in which aliphatic and/or partially aromatic homopolyamides and/or copolyamides and/or polyester amides and/or polyether amides and/or polyester ether amides and/or polyimide amides and/or polyamide amides and/or mixtures of these polyamide compound(s) with additional polymer(s) and modified perfluoralkyl substance(s) are compounded in a single step or multistep and are reactively converted during or afterwards. The homogenization of perfluoralkyl substance(s) in polyamide substance(s) melted masses is improved.Type: GrantFiled: January 5, 2001Date of Patent: August 3, 2004Assignee: Institut fur Polymerforschung E.V. DresdenInventor: Dieter Lehmann
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Patent number: 6727320Abstract: The present invention relates to adhesive and sealant compositions in non-flowable form. More particularly, the present invention relates to non-flowable adhesive and sealant compositions which are particularly useful in the threadlocking and sealing applications and which can be packaged in a convenient pocket-sized applicator dispenser.Type: GrantFiled: January 18, 2002Date of Patent: April 27, 2004Assignee: Henkel Loctite CorporationInventors: Shabbir Attarwala, Zhu Qinyan, Matthew P. Burdzy
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Patent number: 6706851Abstract: The present invention relates to polyetheresteramides (B) containing polyamide blocks comprising dicarboxylic acid sulphonates either as polyamide-block chain limiters or combined with a diamine as one of the constituent monomers of the polyamide block, and containing polyether blocks consisting essentially of alkylene oxide units. The invention also relates to polyetheresteramides (B) containing polyamide blocks of the polyamide oligomer type of low molecular mass or of the copolyamide type which comprise dicarboxylic acid sulphonates and containing polyether blocks which are adducts of alkylene oxide with an aromatic diol. The invention also relates to antistatic or breathable polymer compositions comprising a thermoplastic polymer (A) and at least one of the above polyetheresteramides (B).Type: GrantFiled: August 17, 2001Date of Patent: March 16, 2004Assignee: AtofinaInventors: Reinhard Linemann, Thierry Briffaud, Hermann Hilgers, Christophe Lacroix
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Publication number: 20040024126Abstract: Oriented films are prepared. A thermoplastic vulcanizate, prepared by mixing at least 20 wt % of a thermoset rubber by weight of the total composition into a thermoplastic polymer are disclosed. After the mixture is prepared the thermoset rubber is entrained as discrete particles within the continuous thermoplastic polymer phase. The resulting composite is subjected to a stress either by pulling, blow molding, or any other film-forming process as is known in the art. This stress causes the continuous phase polymer molecules to become aligned or oriented in the direction in which the stress was applied, thus creating the oriented thermoplastic vulcanizate of the invention. This material has improved gas permeability and improved flexibility properties.Type: ApplicationFiled: July 3, 2003Publication date: February 5, 2004Inventors: Andy H. Tsou, Ilan Duvdevani, Hsien-Chang Wang
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Patent number: 6679754Abstract: Polyolefin fibers, filaments and fabrics made therefrom which comprise a melt blend which comprises (A) a polyolefin; and (B) at least one polyetheresteramide which contains aromatic diol-derived sections, exhibit excellent durable dyeability. The fabrics are useful in woven garments, carpeting, furniture and automobile upholstery, woven industrial fabrics, non-woven absorbents used in disposable diapers, non-woven garments including disposable medical garments, filter media, synthetic paper and the like.Type: GrantFiled: December 6, 2001Date of Patent: January 20, 2004Assignee: Ciba Specialty Chemicals CorporationInventors: Sheng-Shing Li, Andrew J. Leggio, Nadi Ergenc
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Patent number: 6664333Abstract: Selectively cold-water responsive compositions constructed of combinations of polymers including at least one hydrolytically degradable polymer and at least one cold-water soluble polymer are provided. Additionally, methods of making and using selectively cold-water sensitive compositions are described. In one embodiment, the method comprises combining a polylactide and a cold-water soluble polyvinyl alcohol at a temperature above the melting point of the polymer having the higher melting point, and below the decomposition point of the polymer having the lower decomposition point, to form a homogeneous polymer blend is also provided. The cold-water responsive properties of the compositions of the present invention may be varied include water dispersible, water disintegratable, and water weakenable.Type: GrantFiled: March 1, 1999Date of Patent: December 16, 2003Assignee: Kimberly-Clark Worldwide, Inc.Inventors: James Hongxue Wang, David Michael Schertz
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Patent number: 6559257Abstract: An adhesive composition that includes a free radical-polymerizable monomer component that includes a reaction product of a (hydroxy)acrylate with an anhydride and is substantially free of at least methyl methacrylate or methacrylic acid. The adhesive composition exhibits substantially reduced objectionable odor.Type: GrantFiled: June 10, 1999Date of Patent: May 6, 2003Assignee: Lord CorporationInventor: Ian C. Quarmby
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Patent number: 6492521Abstract: Compounds and methods of preparing compounds of the formula: RZ—CO—CRaRb—(CRcRd)n—NH—(Y)m—CO—A (I) wherein n is an integer from 1 to 15, m is either 0 or 1; Ra, Rb, Rc, and Rd are each a hydrogen or a hydrocarbyl group; Y is CO—(CReRf)p, wherein Re and Rf are each a hydrogen or hydrocarbyl group and p is zero or an integer from 1 to 20 or CO—C6H4—, wherein the substitution pattern on the phenylene group is an ortho, meta, or para substitution pattern and one or more of the hydrogens of the phenylene group may be substituted by a hydrocarbyl group or a functional group; Z is —O— or —NG—, wherein G is H, C1-C12 alkyl or the radical R; wherein R is wherein R1 is hydrogen, C1-C18 alkyl, O, OH, CH2CN, C1-C18 alkoxy, C1-C18 hydroxyalkoxy, C5-C12 cycloalkoxy, C5-C12 hydroxycycloalkoxy, C3-C6 alkenyl, C1-C18 alkynyl, C7-C9 phenylalkyl, unsubstituted or substituted on the phenyl with 1, 2 or 3 C1-C4 alkylType: GrantFiled: October 25, 2001Date of Patent: December 10, 2002Assignee: Cytec Technology Corp.Inventors: Thomas P. Sassi, Ram B. Gupta
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Patent number: 6428900Abstract: A water-sensitive hot melt adhesive composition based on sulfonated branched copolyester polymers for use with articles such as paper products, disposable nonwoven products, tapes, labels and packaging materials. The adhesive composition includes about 10% to about 90%, by weight, of a sulfonated polyester copolymer or a blend of one or more sulfonated polyester polymers; about 0% to about 80%, by weight, of a tackifying resin; about 0% to about 40%, by weight, of a compatible plasticizer; about 5% to about 50% by weight of a polyethylene glycol having a molecular weight greater than 2000 and a melting point greater than 50° C; and about 0% to about 3% by weight of one or more antioxidant. The adhesive maintains the article in an assembled condition by providing adequate adhesive bond strength during normal use, but dissolves in the presence of water thereby permitting the article to be recycled or otherwise disposed of in an environmentally friendly manner.Type: GrantFiled: March 9, 2000Date of Patent: August 6, 2002Assignee: Ato Findley, Inc.Inventor: Baoyu Wang
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Patent number: RE39994Abstract: The present invention relates to polyetheresteramides (B) containing polyamide blocks comprising dicarboxylic acid sulphonates either as polyamide-block chain limiters or combined with a diamine as one of the constituent monomers of the polyamide block, and the containing polyether blocks consisting essentially of alkylene oxide units. The invention also relates to polyetheresteramides (B) containing polyamide blocks of the polyamide oligomer type of low molecular mass or of the copolyamide type which comprise dicarboxylic acid sulphonates and containing polyether blocks which are adducts of alkylene oxide with an aromatic diol. The invention also relates to antistatic or breathable polymer compositions comprising a thermoplastic polymer (A) and at least one of the above polyetheresteramides (B).Type: GrantFiled: October 17, 2000Date of Patent: January 1, 2008Assignee: Arkema FranceInventors: Reinhard Linemann, Thierry Briffaud, Hermann Hilgers, Christophe Lacroix