Polycarboxylic Acid Or Derivative Or Polyol Contains An Atom Other Than C, H, Or O; Or Wherein A Polycarboxylic Acid Or Derivative Or Polyol Or Condensate Thereof Is Reacted With A Reactant Containing Atoms Other Than C, H, Or O Prior To Blending With The Solid Polymer; Or Wherein A Coreactant With The Polycarboxylic Acid Or Derivative Or Polyol Contains An Atom Other Than C, H, Or O Patents (Class 525/167)
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Patent number: 6420004Abstract: The invention concerns composite polyester films with good barrier properties relative to gases. More precisely, it concerns a biaxially drawn film, based on polyester and having improved barrier properties relative to gases, characterised in that it comprises a base polyester film of 5 to 50 &mgr;m, coated on one of its two surfaces with a deposit containing polyvinyl alcohol and a water dispersible copolyester with sulphonyloxy units, said composite film having permeability to oxygen measured at 23° C. under 50% relative humidity, not more than 5 cm3/m2/24 h. Said composite films have, besides being transparent and having barrier properties, excellent resistance to mechanical stresses, such as in particular crumpling.Type: GrantFiled: March 20, 2000Date of Patent: July 16, 2002Assignee: Toray Plastics Europe S.A.Inventors: Didier Veyrat, Eric Maitre
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Patent number: 6410627Abstract: A hot melt adhesive composition comprising (a) greater than 40% by weight of a polymeric component; and (b) 5 to 40% by weight of a high hydroxyl number compound, with hydroxyl number greater than 100 mg KOH/g.Type: GrantFiled: April 9, 1999Date of Patent: June 25, 2002Assignee: National Starch and Chemical Investment Holding CorporationInventors: Charles W. Paul, Mitchell J. Blumenthal
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Publication number: 20010051701Abstract: An adhesive composition that includes a free radical-polymerizable monomer component that includes a reaction product of a (hydroxy)acrylate with an anhydride and is substantially free of at least methyl methacrylate or methacrylic acid. The adhesive composition exhibits substantially reduced objectionable odor.Type: ApplicationFiled: June 10, 1999Publication date: December 13, 2001Inventor: IAN C. QUARMBY
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Patent number: 6221500Abstract: Insulation compounds are described that have been formulated for use in a refrigeration environment. The materials consist of crosslinkable compounds made from ionomer (EAS), polyether block amide (PEBA), polybutyleneterephthalate (PBT) homo- or copolymers, and/or polyvinylidenefluoride (PVDF). The insulation compounds are intended for use as wire insulation and in the fabrication of gaskets and liners. The compounds show superior resistance to refrigerants such as HCFC-22, HCFC-123, and HFC-134a. Crosslinking provides resistance to creeping under heat and pressure.Type: GrantFiled: August 12, 1999Date of Patent: April 24, 2001Assignee: Champlain Cable CorporationInventor: Stefan Ultsch
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Patent number: 6217961Abstract: Composite including a rubber/thermoplastic blend adherent by itself to a thermoplastic material; the blend is in the form of a thermoplastic matrix containing rubber nodules functionalized and vulcanized during the mixing with the thermoplastic. Composite articles obtained by overmolding the vulcanized rubber/thermoplastic blend onto the thermoplastic.Type: GrantFiled: December 31, 1996Date of Patent: April 17, 2001Assignee: AltofinaInventors: Marius Hert, Patrick Alex, Martine Cerf, Christian Dousson
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Patent number: 6203913Abstract: The present invention provides coating compositions including: (a) about 75 to about 99.9 weight percent of a crosslinkable film-forming system including one or more crosslinkable film-forming resins and one or more crosslinking materials which is capable of reacting with the film-forming resin to form a crosslinked film; and (b) one or more substantially saturated, predominantly hydrocarbon adhesion promoting agents having an average of more than one pendant or terminal polar group per molecule which are capable of reacting with the crosslinking material, the adhesion promoting agent(s) being present in an amount ranging from about 0.1 to about 25 weight percent on a basis of total resin solids of the coating composition. The coating compositions are useful for directly coating surfaces of thermoplastic and thermosetting plastic substrates, such as TPO and RIM, without the aid of flame or corona pretreatment, or the use of an adhesion promoter.Type: GrantFiled: December 16, 1998Date of Patent: March 20, 2001Assignee: PPG Industries Ohio, Inc.Inventors: Constantine A. Kondos, Edward E. McEntire, Masayuki Nakajima, Richard M. Nugent, Jr.
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Patent number: 6165602Abstract: A laminated polyester film stretched in at least one direction, comprising:a polyester support, andat least one enhanced adhesion layer laminated on the polyester support, comprising a composition comprising:(1) an aromatic copolyester (A1) having a water-dispersible functional group, a polyvinyl alcohol resin (B1), and a vinylpyrrolidone copolymer resin (C1); or(2) an aromatic copolyester (A1) having a water-dispersible functional group, a polyvinyl alcohol resin (B1), and a polyglycerol polyglycidyl ether (C2); or(3) an aqueous-type polyurethane (A3), a polyvinyl alcohol resin (B3), and inert particles wherein the thickness (L) of the adhesion layer and the average particle diameter (d) of said inert particles satisfies the equation1/3.ltoreq.d/L.ltoreq.3.Type: GrantFiled: June 11, 1998Date of Patent: December 26, 2000Assignee: Mitsubishi Polyester Film CorporationInventor: Masato Fujita
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Patent number: 6153303Abstract: Fluoropolymer compositions containing melt-flowable tetrafluoroethylene copolymers with reactive end groups and isotropic polyesters have excellent adhesion to metal substrates, especially steel, and excellent water resistance.Type: GrantFiled: August 19, 1998Date of Patent: November 28, 2000Assignee: Dupont Mitsui FluorochemicalsInventors: Sinichi Namura, Takahiko Iwasaki
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Patent number: 6121382Abstract: Disclosed is a surface treatment agent for aqueous ink receiving media such as ink jet recording paper, printing sheets, coating materials and so on. The surface treatment agent according to the invention comprises a water-based resin and a carboxylic acid-containing hydrophilic sulfopolyester which provides superior adhesion and water resistance. With the superior adhesion properties, the surface treatment agent can be directly coated on substrates without the inconvenience of primer coating. The surface treatment agent of the invention is suitable for aqueous ink jet printing, coating, or recording media, particularly those of ink jet printers and ink jet plotters.Type: GrantFiled: April 16, 1998Date of Patent: September 19, 2000Assignee: Industrial Technology Research InstituteInventors: Shinn-Jen Chang, Yih-Her Chang, Rong-Shuh Chang, Wan-Jung Teng, Yuan-Tung Hung
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Patent number: 6069202Abstract: Desirable thermoplastic vulcanizates can be prepared from a polar engineering thermoplastic; a halogenated copolymer of p-alkylstyrene and an isomonoolefin having from 4 to 7 carbon atoms; and either an ethylene rubbery polymer or a diene based rubbery polymer or combinations thereof. The ethylene rubbery polymer desirably has at least one pendant carboxylic acid group, amine group, epoxy group, hydroxyl group or an anhydride of two carboxylic acid groups or combinations thereof. Desirable diene based rubbery polymers include epoxidized natural rubber and epoxidized homopolymers and copolymers of dienes.Type: GrantFiled: December 10, 1997Date of Patent: May 30, 2000Assignee: Advanced Elastomer Systems, L.P.Inventors: Krishna Venkataswamy, Jacques Horrion
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Patent number: 6048937Abstract: Thermoplastic molding materials contain, as essential components,A) from 95 to 99.99% by weight of an ethylene polymer andB) from 0.01 to 5% by weight of a thermoplastic polyester having a maximum melting point of less than or equal to 150.degree. C.Type: GrantFiled: January 20, 1998Date of Patent: April 11, 2000Assignee: BASF AktiengesellschaftInventors: Peter Bauer, Ursula Seeliger, Uwe Faller
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Patent number: 6046275Abstract: A composition comprises (A) a syndiotactic styrene-based resin and (C) rubber polymer particles such as graft copolymers, butadiene or isoprene block copolymers optionally hydrogenated and/or modified with maleic anhydride, and other rubbers, and, optionally, (B) a thermoplastic resin such as a polycarbonate, and/or (D) a filler such as glass fibers.Type: GrantFiled: June 5, 1995Date of Patent: April 4, 2000Assignee: Idemitsu Kosan Co., Ltd.Inventors: Akikazu Nakano, Takashi Sumitomo, Keisuke Funaki, Toshikazu Ijitsu, Michihiro Sawada, Masahiko Kuramoto, Masakazu Suzuki
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Patent number: 6027814Abstract: The invention relates to a composition including (i) at least one polyamide and at least one copolymer (A) of ethylene with at least one comonomer chosen from unsaturated carboxylic acids, esters of unsaturated carboxylic acids or vinyl esters of saturated carboxylic acids and (ii) being in powder form. These compositions are subsequently deposited on metal substrates and then a highly corrosion-resistant coating is obtained by melting.Type: GrantFiled: October 6, 1997Date of Patent: February 22, 2000Assignee: Elf Atochem S.A.Inventors: Olivier Julien, Michael Werth, Arnaud Tedoldi, Jean-Marc Sage
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Patent number: 6022927Abstract: Coating powder compositions comprise A) between about 60 and about 90 wt %, relative to total weight of A) plus B) plus C), of an acrylic polymer having a weight average molecular weight of between about 1000 and about 30,000, a carboxylic acid equivalent weight of from about 300 to about 1000 and a glass transition temperature of about 45.degree. C. or above and B) between about 5 and about 30 wt %, relative to total weight of A) plus B) plus C) of an adduct prepared from i) between about 20 and about 50 wt %, relative to total weight of i) plus ii), of a curing agent reactive with carboxylic acid groups and ii) between about 50 and about 80 wt %, relative to total weight of i) plus ii), of a polyester resin formed primarily from linear aliphatic diols and dicarboxylic acids, the polyester having functional groups reactive with said curing agent i), and C) between about 2 and about 30 wt % relative to the total weight of A) plus B) plus C) of a curing agent reactive with carboxylic acid groups.Type: GrantFiled: December 15, 1997Date of Patent: February 8, 2000Assignee: Morton International, Inc.Inventors: Owen H. Decker, Charles P. Tarnoski
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Patent number: 5985392Abstract: Composite including a rubber/thermoplastic blend adherent by itself to a thermoplastic material; the blend is in the form of a thermoplastic matrix containing rubber nodules functionalized and vulcanized during the mixing with the thermoplastic. Composite articles obtained by overmoulding the vulcanized rubber/thermoplastic blend onto the thermoplastic.Type: GrantFiled: January 2, 1997Date of Patent: November 16, 1999Assignee: Elf Atochem S.A.Inventors: Marius Hert, Patrick Alex, Martine Cerf, Christian Dousson
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Patent number: 5962557Abstract: A colored polyester copolymer comprising the reaction product of at least one linear thermoplastic polyester precursor and at least ten parts per million by weight of a residue of at least one 1,4-bis (2,6-dialkylanilino)-9,10-anthraquinone colorant. A composition may be formed comprising the copolymer in admixture with at least one thermoplastic polymer. The copolymer may be formed by reacting at least one thermoplastic polyester precursor with a 1,4-bis (2,6-dialkylanilino)-9,10-anthraquinone colorant which has a polyester reactive group.Type: GrantFiled: August 7, 1997Date of Patent: October 5, 1999Assignee: Eastman Chemical CorporationInventors: Max Allen Weaver, Brian Edison Maxwell, Gerry Foust Rhodes, James John Krutak, Sr.
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Patent number: 5959040Abstract: A film-forming composition is provided comprising: (i) pigment; (ii) an aminoplast crosslinking agent containing methylol and/or methylol ether groups; and (iii) a polymer or oligomer selected from the group consisting of (a) an acrylic polymer or oligomer containing a plurality of groups of the structure: ##STR1## wherein R.sub.1 is hydrogen or methyl and R.sub.2 is a divalent group; (b) a polyester polymer or oligomer containing a plurality of terminal carbamate groups of the structure: ##STR2## and (c) mixtures thereof. The film-forming composition is suitable for application over a substrate as a monocoat which exhibits a high level of acid etch resistance.Type: GrantFiled: August 22, 1997Date of Patent: September 28, 1999Assignee: PPG Industries Ohio, Inc.Inventors: Michael A. Mayo, Leigh-Ann Humbert
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Patent number: 5886100Abstract: The thermosetting coating composition in a powdery form, includes (a) a binder resin prepared by the steps comprising preparing a starting material monomer mixture of two different polymerization reactions, each of the polymerization reaction being carried out in an independent reaction path, and then concurrently carrying out both of the two different polymerization reactions in one reaction vessel; (b) a colorant; and (c) a crosslinking agent. The coating film is prepared by curing the above thermosetting coating composition.Type: GrantFiled: March 4, 1997Date of Patent: March 23, 1999Assignee: KAO CorporationInventors: Katsutoshi Aoki, Yukiya Sato, Masayuki Maruta, Yasunori Inagaki, Kuniyasu Kawabe
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Patent number: 5886098Abstract: A polyetheresteramide having good heat resistance, permanent antistatic property and superior compatibility with thermoplastic resins and a resin composition containing the polyetheresteramide are disclosed, wherein the polyetherester-amide consists essentially of a polyamide oligomer with carboxylic chain ends having a number average molecular weight between 200 and 5,000 and a bisphenol compound with oxyalkylene units having a number average molecular weight between 300 and 3,000. Antistatic resin compositions with good antistatic property and heat resistance are obtained from compositions comprising 3 to 40% by weight of the polyetheresteramide and 60 to 97% by weight of thermoplastic resins. The antistatic resin compositions can contain as compatibilizers vinyl polymers having functional groups such as carboxyl and epoxy groups or block polymers containing polyolefin blocks and aromatic vinyl polymer blocks.Type: GrantFiled: November 10, 1997Date of Patent: March 23, 1999Assignee: Sanyo Chemical Industries, Ltd.Inventors: Yasuhiro Ueda, Eiichi Senda, Yoshitsugu Takai, Tokiko Kokubu, Toshiaki Okamoto, Eiji Ichihara
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Patent number: 5886097Abstract: Thermoplastic resin compositions consisting of 1 to 40 wt % a polyether ester amide (A) and 99 to 60 wt % of at least one thermoplastic resin (B) selected from styrene based resins, further containing (C) 0.1-10% of a modified vinyl polymer containing carboxyl groups, are permanently antistatic, excellent in mechanical properties represented by impact resistance, heat resistance moldability and also in the appearance and gloss of the moldings, and suitable for housings of optical or magnetic recording media.Type: GrantFiled: September 17, 1997Date of Patent: March 23, 1999Assignee: Toray Industries, Inc.Inventors: Tadao Fukumoto, Masatoshi Iwamoto, Akihiko Kishimoto
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Patent number: 5883195Abstract: Novel thermoplastic polymer alloys adopted for easy conversion, e.g., by injection molding or extrusion techniques, into useful shaped articles having improved mechanical properties, for example, high impact strengths, include a polyamide, e.g., nylon 6 or nylon 12, a thermoplastic elastomer, e.g., ABS, MBS or EPDM, and a polyetheramide, advantageously a polyetheresteramide.Type: GrantFiled: June 25, 1997Date of Patent: March 16, 1999Assignee: AtochemInventors: Jean-Jacques Couchoud, Michel Glotin, Bernard Guerin, Georges Parmeland
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Patent number: 5877257Abstract: A blend of ethylene/vinyl alcohol copolymers with crystalline nylon, and ionomers and optionally amorphous nylon that have a unique balance of properties and to packaging films, laminates, co-extrusions and containers prepared therefrom.Type: GrantFiled: September 5, 1996Date of Patent: March 2, 1999Assignee: E. I. du Pont de Nemours and CompanyInventor: Arthur Irving Fetell
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Patent number: 5861462Abstract: The present invention relates to a method for forming the LCP composite having LCP fibers dispersed in the matrix resin even if the LCP content may be smaller than the lower limit of the fiber formable range.The method is characterized in that a resin composite reinforced by the LCP fiber in a mixture ratio beyond the fiber formable range or the preferred fiber formable range by means of an extrusion or injection molding of a resin mixture containing a liquid crystal resin composite extruded in the fiber formable range or the preferred fiber formable range.Type: GrantFiled: September 30, 1992Date of Patent: January 19, 1999Assignee: Mazda Motor CorporationInventors: Keita Sasaki, Masatoshi Shinomori
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Patent number: 5834561Abstract: Thermoplastic resin compositions consisting of 1 to 40 wt % a polyether ester amide (A) and 99 to 60 wt % of at least one thermoplastic resin (B) selected from styrene based resins, further containing (C) 0.1-10% of a modified vinyl polymer containing carboxyl groups, area permanently antistatic, excellent in mechanical properties represented by impact resistance, heat resistance moldability and also in the appearance and gloss of the moldings, and suitable for housings of optical or magnetic recording media.Type: GrantFiled: November 20, 1995Date of Patent: November 10, 1998Assignee: Toray Industries, Inc.Inventors: Tadao Fukumoto, Masatoshi Iwamoto, Akihiko Kishimoto
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Patent number: 5820780Abstract: The present invention provides a liquid crystal polyester resin composition, which is manufactured at low cost and has favorable gas barrier properties and improved impact resistance, vibration-damping properties, thin-wall properties (mechanical properties of thin-wall molded articles), and film-forming properties, while maintaining excellent heat resistance and mechanical properties of a liquid crystal polyester. A liquid crystal polyester resin composition of the invention includes 55.0 through 99.9 percent by weight of a liquid crystal polyester as a component (A) and 0.1 through 45.0 percent by weight of an epoxy group-containing ethylene copolymer as a component (B), wherein the component (B) includes: (a) 50 through 96.5 percent by weight of an ethylene unit; (b) 0.5 through 30 percent by weight of an unsaturated glycidyl carboxylate unit or an unsaturated glycidyl ether unit; and (c) 3 through 40 percent by weight of an ethylenically unsaturated ester compound unit.Type: GrantFiled: January 23, 1997Date of Patent: October 13, 1998Assignee: Sumitomo Chemical Company, LimitedInventors: Motonubu Furuta, Takanari Yamaguchi
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Patent number: 5817712Abstract: Self-crosslinking aqueous polymer dispersions comprising water-thinnable polyesters, vinyl polymers that have either carbonyl or hydrazine functional groups, and a crosslinker having at least two hydrazine or other groups which react with carbonyl groups or crosslinkers having at least two carbonyl groups; and where the vinyl polymer is prepared by free-radical-initiated emulsion polymerization in the presence of an aqueous solution or dispersion of the polyester.Type: GrantFiled: June 25, 1997Date of Patent: October 6, 1998Assignee: Vianova Resins GmbHInventors: Manfred Weinberger, Joachim Zoeller
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Patent number: 5733965Abstract: Rubber mixtures containing at least one rubber, one filler, optionally additional rubber auxiliary agents and also at least one sulphurous polyester are outstandingly suitable for the production of rubber vulcanisate having good mechanical properties and good hysteresis behaviour.Type: GrantFiled: May 22, 1996Date of Patent: March 31, 1998Assignee: Bayer AGInventors: Thomas Scholl, Hermann-Josef Weidenhaupt, Ulrich Eisele
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Patent number: 5710213Abstract: Novel functionalized peroxides which may be used as crosslinking, grafting and curing agents, initiators for polymerization reactions and as monomers for condensation polymerizations to form peroxy-containing polymers, which in turn can be used to prepare block and graft copolymers, have the following Formula I: ##STR1## R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, X, Y.sup.1, Y.sup.2, Y.sup.3, Z.sup.1, Z.sup.2, x, y and z are as defined in the Summary of the Invention. The compounds of Formula I may be prepared by reacting hydroxy-containing tertiary hydroperoxides with diacid halides, phosgene, dichloroformates, diisocyanates, anhydrides and lactones to form the functionalized peroxides. These reaction products may be further reacted, if desired, with dialcohols, diamines, aminoalcohols, epoxides, epoxy alcohols, epoxy amines, diacid halides, dichloroformates and diisocyanates to form additional functionalized peroxides.Type: GrantFiled: June 6, 1995Date of Patent: January 20, 1998Assignee: Elf Atochem North America, Inc.Inventor: Daryl L. Stein
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Patent number: 5710210Abstract: Novel functionalized peroxides which may be used as crosslinking, grafting and curing agents, initiators for polymerization reactions and as monomers for condensation polymerizations to form peroxy-containing polymers, which in turn can be used to prepare block and graft copolymers, have the following Formula I: ##STR1## R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, X, Y.sup.1, Y.sup.2, Y.sup.3, Z.sup.1, Z.sup.2, x, y and z are as defined in the Summary of the Invention. The compounds of Formula I may be prepared by reacting hydroxy-containing tertiary hydroperoxides with diacid halides, phosgene, dichloroformates, diisocyanates, anhydrides and lactones to form the functionalized peroxides. These reaction products may be further reacted, if desired, with dialcohols, diamines, aminoalcohols, epoxides, epoxy alcohols, epoxy amines, diacid halides, dichloroformates and diisocyanates to form additional functionalized peroxides.Type: GrantFiled: June 6, 1995Date of Patent: January 20, 1998Assignee: Elf Atochem North America, Inc.Inventor: Daryl L. Stein
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Patent number: 5674943Abstract: A blended composition containing polycarbonate, polyester, an olefinic epoxide-containing copolymer and a polyamine compound, which composition possesses a desirable balance of impact resistance, solvent resistance, and resistance to thermal deformation.Type: GrantFiled: February 14, 1995Date of Patent: October 7, 1997Assignee: The Dow Chemical CompanyInventors: Hani Farah, Leo Novak, Michael K. Laughner, Ralph D. Priester, Jr.
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Patent number: 5660937Abstract: Thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating, a specific vinyl ether or vinyl thioether and a thermal latent acid catalyst. The blocked carboxyl group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule. The thermosetting composition gives cured products having excellent chemical properties, physical properties, weathering resistance and storage stability and is advantageously utilized for coating compositions, ink, adhesive and molded plastics.Type: GrantFiled: March 9, 1995Date of Patent: August 26, 1997Assignee: Nippon Oil And Fats Company, LimitedInventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
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Patent number: 5648434Abstract: Sulfonimide cure catalysts are used with aminoplast crosslinking agents and resins capable of reacting with aminoplast crosslinking agents to prepare heat curable compositions capable of crosslinking to form coatings and articles. Liquid or solid curable compositions may be prepared. Solid sulfonimide catalysts used in combination with solid glycoluril type crosslinking agents are well suited for powder coating systems containing hydroxy- and carboxy-functional resins.Type: GrantFiled: June 5, 1995Date of Patent: July 15, 1997Assignee: Cytec Technology Corp.Inventors: Jeno G. Szita, Subban Ramesh, William Jacobs, III, John Colin Brogan
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Patent number: 5639821Abstract: The invention relates to powder coatings which are characterized in that they contain as film-forming material a mixture of(A) from 19.9 to 90.0 percent by weight of a synthetic resin which contains epoxide groups and may contain ethylenically unsaturated double bonds, or of a mixture of such epoxide group-containing synthetic resins,(B) from 9.9 to 80.0 percent by weight of a compound which contains carboxyl groups and may contain ethylenically unsaturated double bonds, or of a mixture of such carboxyl group-containing compounds,(C) from 0 to 20 percent by weight of a compound which contains ethylenically unsaturated double bonds and is different from (A) and (B), or of a mixture of such compounds, and(D) from 0.1 to 3.0 percent by weight of an initiator for free-radical polymerizations or of a mixture of initiators for free-radical polymerizations,the percentages by weight of (A)+(B)+(C)+(D) being=200% by weight and the mixture of components (A), (B), (C) and (D) containing from 0.1 to 6.Type: GrantFiled: March 28, 1995Date of Patent: June 17, 1997Assignee: BASF Lacke+Farben, AGInventors: Wolfgang Kranig, Klaus Cibura, Joachim Woltering, Christopher Hilger, Josef Rademacher
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Patent number: 5637407Abstract: Composite including a rubber/thermoplastic blend adherent by itself to a thermoplastic material; the blend is in the form of a thermoplastic matrix containing rubber nodules functionalized and vulcanized during the mixing with the thermoplastic. Composite articles obtained by overmoulding the vulcanized rubber/thermoplastic blend onto the thermoplastic.Type: GrantFiled: November 10, 1994Date of Patent: June 10, 1997Assignee: Elf Atochem S. A.Inventors: Marius Hert, Patrick Alex, Martine Cerf, Christian Dousson
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Patent number: 5616418Abstract: Polyblend compositions well adopted for the production of a wide variety of useful shaped articles having improved physical/chemical properties, e.g., fibers, films, sheets, composites, and the like, comprise (a) at least one polyamide thermoplastic elastomer, e.g., a polyetheresteramide, and (b) at least one modified polyolefin, e.g, an optionally maleized copolymerizate of ethylene and vinyl acetate, a copolymerizate of ethylene and (meth)acrylic acid, a copolymerizate of ethylene, vinyl acetate and (meth)acrylic acid and/or an alkyl (meth)acrylate, a copolymerizate of ethylene, an alkyl (meth)acrylate and, optionally, maleic anhydride, or maleized SBS, SIS or SEBS.Type: GrantFiled: December 28, 1994Date of Patent: April 1, 1997Assignee: AtochemInventors: Thierry Vasselin, Michel Vuachet
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Patent number: 5612445Abstract: The epoxidation of alkyds containing anhydrides or diacids with cycloaliphatic unsaturation results in epoxy resins which cure rapidly in UV light to produce uniform films without the use of flow modifiers. The fatty acid portion of the alkyd functions as an internal plasticizer. Crosslinking occurs through oxirane rings in both the anhydride and fatty acid moieties of the alkyd to produce hard, but not brittle films. Excellent water resistance is obtained without thermal post curing.Type: GrantFiled: February 15, 1995Date of Patent: March 18, 1997Assignee: Arizona Chemical Co.Inventor: Raymond H. Jones
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Patent number: 5601878Abstract: The invention relates to a process for the production of two-coat finishes, in which a pigmented basecoat is first applied, the resulting basecoat film is coated with a powder clearcoat, and basecoat and clearcoat are subsequently baked together. In accordance with the invention, the powder clearcoat employed is a powder coating which contains an epoxide group-containing polyacrylate resin as binder and a mixture of (A) a polyanhydride and (B) a carboxyl group-containing polyester resin as crosslinking agent. The polyester resin can be prepared by reacting a diol (b1), a compound (b2) which contains per molecule at least three functional groups selected from hydroxyl, primary amino, secondary amino, carboxyl and acid anhydride groups, and (b3) a dicarboxylic acid in a molar ratio of (b1): (b2): (b3)=0.0 to 3.0: 1.0: 1.5 to 9.0 to give a polyester resin having an acid value of 40 to 300.Type: GrantFiled: January 26, 1995Date of Patent: February 11, 1997Assignee: BASF Lacke + Farben. AGInventors: Wolfgang Kranig, Klaus Cibura, Joachim Woltering, Christopher Hilger, Josef Rademacher
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Patent number: 5596041Abstract: A hydrogenated block copolymer or hydrogenated block copolymer mixture consisting essentially of (a) hydrogenation product of a star-branched block copolymer represented by the structural formula (A-B).sub.n X wherein A is a polybutadiene block having a 1,2-vinyl content of less than 25% by weight and B is a copolymer block containing 50% by weight or more of a conjugated diene compound whose vinyl content is 25% by weight or more, X is a coupling agent residue and n is an integer of 3 or more, and (b) a hydrogenation product of a straight chain block copolymer represented by the structural formula A-B wherein A and B are as defined above, the weight ratio of the component (a) to the component (b) being 100/0 to 5/95, and a hydrogenated block copolymer composition comprising (I) 1 to 99 parts by weight of said hydrogenated block copolymer or hydrogenated block copolymer mixture and (II) 99 to 1 part by weight of a thermoplastic resin and/or a rubbery polymer.Type: GrantFiled: March 31, 1995Date of Patent: January 21, 1997Assignee: Japan Synthetic Rubber Co., Ltd.Inventors: Yoshiharu Hashiguchi, Minoru Hasegawa, Kunio Goshima, Yasuhiko Takemura, Yoshiyuki Higuchi, Motokazu Takeuchi
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Patent number: 5578677Abstract: A thermosetting composition which comprises:(D) a self-crosslinking compound having in the molecule (a) one or more functional groups of the formula (2): ##STR1## wherein R.sup.5, R.sup.6 and R.sup.7 are each hydrogen or an organic group of 1 to 18 carbons, R.sup.8 is an organic group of 1 to 18 carbons, Y.sup.2 is oxygen or sulfur, or R.sup.7 and R.sup.8 are bonded with each other to form a heterocyclic structure which comprises Y.sup.2 as the heteroatom component; and (b) one or more reactive functional groups which can form a chemical bond with carboxyl functional groups which are regenerated from (a) by heating; (C) optionally, a thermal latent acid catalyst which is activated during curing of the composition by heating; (A) optionally, a compound having in the molecule two or more functional groups of the formula (1): ##STR2## wherein R.sup.1, R.sup.2 and R.sup.3 are each hydrogen or an organic group of 1 to 18 carbons, R.sup.4 is an organic group of 1 to 18 carbons, Y.sup.1 is oxygen or sulfur, or R.Type: GrantFiled: December 27, 1995Date of Patent: November 26, 1996Assignee: Nippon Oil and Fats Company, LimitedInventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
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Patent number: 5576366Abstract: Compositions of ethylene alkyl acrylate grafted onto polypropylene are dyeable with disperse or cationic dyes. A small amount of polyester may be include, along with a hydrophilic modifier comprising a monoglyceride and a salt of a liner alkyl. The hydrophilic modifier also acts as a compatibilizer to bridge the polyester and the polypropylene. A process for dyeing polypropylene fibers comprises combining the polypropylene with a thermoplastic copolymer of ethylene and alkyl acrylates having 1 to 4 carbon atoms in the alkyl group into fibers, adding the polyester to the polypropylene matrix, spinning the composition into fibers, and exposing the fibers to a dye bath. The sulfonic group may be added to the polyester for exposing the fibers to a cationic dye.Type: GrantFiled: May 16, 1995Date of Patent: November 19, 1996Assignee: Lyondell Petrochemical CompanyInventor: Paresh J. Sheth
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Patent number: 5574101Abstract: An acrylic resin composition comprising at least one polyamide elastomer consisting of hard segments and soft segments in a specified ratio, an acrylic resin and optionally at least one electrolyte, which has excellent permanent antistatic properties, is good in transparency, has a very faint color, is inexpensive, and is only slightly deteriorated in transparency even when immersed in water.Type: GrantFiled: May 26, 1995Date of Patent: November 12, 1996Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Kiyoshi Kawakami, Yuzuru Ishibashi, Toshio Suzuki
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Patent number: 5549932Abstract: Thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating, a specific vinyl ether or vinyl thioether and a thermal latent acid catalyst. The blocked carboxy group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule. The thermosetting composition gives cured products having excellent chemical properties, physical properties, weathering resistant and storage stability and is advantageously utilized for coating compositions, ink, adhesive and molded plastics.Type: GrantFiled: March 9, 1995Date of Patent: August 27, 1996Assignee: Nippon Oil and Fats Company, LimitedInventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
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Patent number: 5549963Abstract: A treated fibrous polyamide substrate having durable resistance to staining by acid colorants comprising a fibrous polyamide substrate having applied thereto an aqueous solution of a partially sulfonated, partially phosphated resol resin; which aqueous solution may include polymethylmethacrylates or combinations thereof, and that may include a fluorochemical; and the method of treating said substrate, and the resol resins themselves.Type: GrantFiled: November 9, 1994Date of Patent: August 27, 1996Assignee: Trichromatic Carpet Inc.Inventors: Yassin M. Elgarhy, Barry R. Knowlton
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Patent number: 5541258Abstract: A thermoplastic elastomer composition comprising (A) a thermoplastic copolyester or copolyamide elastomer, (B) an epoxy group-containing methacrylate or acrylate copolymer rubber and (C) a carboxyl group-containing methacrylate or acrylate copolymer rubber, wherein the content of component (A) is 30-90 wt. %, the total content of components (B) and (C) is 10-70 wt. %, and components (B) and (C) are crosslinked with each other. The composition provides flexible rubber articles having enhanced modulus, heat aging resistance and compression set resistance.Type: GrantFiled: October 16, 1995Date of Patent: July 30, 1996Assignees: Nippon Zeon Co., Ltd., General Electric CompanyInventors: Mitsuyoshi Aonuma, Kimiaki Sasamoto, Kozo Ikegami
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Patent number: 5541242Abstract: The present invention provides an antistatic and flame retardant thermoplastic resin composition which comprises [A] 100 weight parts of a thermoplastic resin, [B] 2.0 to 40 weight parts of a bromine-containing organic flame retardant, and [C] 1.0 to 30 weight parts of a (meth)acrylamide-based copolymer and/or a (meth)acrylate ester-based copolymer each comprising 65 to 99 mole percent of an olefin-derived structural unit (I), 0 to 15 mole percent of a (meth)acrylate-derived structural unit (II) and 1 to 35 mole percent of a (meth)acrylamide-derived or (meth)acrylate ester-derived structural unit (III), as arranged linearly, with a weight average molecular weight of 1,000 to 50,000.Type: GrantFiled: July 28, 1994Date of Patent: July 30, 1996Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.Inventors: Yutaka Nakayama, Hideyuki Sumi, Hiroshi Hotta
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Patent number: 5516578Abstract: The invention relates to a water and oil repellency imparting composition which comprises:(a) a fluoroaliphatic radical-containing agent; and(b) a polymer comprising cyclic carboxylic anhydride groups.Additionally, the composition may comprise:(c) a softener and/or a plasticizer. The composition provides water and oil repellent properties to fibrous and other substrates treated therewith and it shows high compatibility with the commonly used softeners.Type: GrantFiled: October 14, 1994Date of Patent: May 14, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventor: Dirk M. Coppens
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Thermoplastic composition and method for producing thermoplastic composition by melt blending carpet
Patent number: 5498667Abstract: The present invention is directed to a process for forming a thermoplastic composition from carpet wherein a carpet sample are melt blended without separating the carpet into its component parts. The process of the present invention produces a thermoplastic composition useful as a substitute for virgin thermoplastics in a variety of applications.Type: GrantFiled: March 2, 1995Date of Patent: March 12, 1996Assignee: Monsanto CompanyInventors: Donald J. David, Jerauld L. Dickerson, Thomas F. Sincock, Susan R. Williams -
Patent number: 5496876Abstract: Improved thermoplastic compositions adopted for easy conversion, e.g., by injection molding or extrusion techniques, into useful shaped articles having high flexibility, and good tear resistance and elasticity, include a polyetheramide, advantageously a polyetheresteramide, and a styrene/diene copolymer, e.g., a copolymer of styrene with butadiene or isoprene, notably a linear or branched chain styrene/butadiene/styrene or styrene/isoprene/styrene copolymer.Type: GrantFiled: September 28, 1994Date of Patent: March 5, 1996Assignee: AtochemInventors: Jean-Pierre Jacquemin, Gerard Deleens
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Patent number: 5492980Abstract: Thermoplastic molding resin composition comprising 70-95 weight % of aliphatic polyamide, 5-30 weight % of phenolic resin, and 0-20 % of semi-aromatic amorphous polyamide, and further high density polyamide composition comprising 100 parts by weight of the mixture of 60-95 parts by weight of aliphatic crystalline polyamide, 5-30 parts by weight of phenolic resin, and 200-1000 parts by weight of metal powder or metal oxide powder or inorganic filler having specific gravity of more than 2.6.Type: GrantFiled: October 7, 1993Date of Patent: February 20, 1996Assignee: Kishimoto Sangyo Co., Ltd.Inventor: Takeshi Moriwaki
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Patent number: 5447991Abstract: Polyolefinic fibres and films are made flame-resistant by the addition of a flame-resistant additive made up of a copolyester containing units deriving from: a) terephthalic acid; b) alkylenic glycol (C.sub.2 --C.sub.6) ; and c) phenyl hydroxymethylene phosphinic acid.These fibres and films are prepared by the transformation into its molten state of a mixture of polyolefin and flame-resistant additive.Type: GrantFiled: May 12, 1994Date of Patent: September 5, 1995Assignee: Enichem Synthesis S.p.A.Inventors: Gianluigi Landoni, Carlo Neri