Polycarboxylic Acid Or Derivative, Polyol, Or Other Coreactant Contains An Ethylenic Group; Or Wherein A Condensate Thereof Has Been Prepared From A Polycarboxylic Acid Or Derivative And A Polyol And Subsequently Reacted With An Ethylenic Reactant Patents (Class 525/168)
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Patent number: 6696521Abstract: A high performance UPR (unsaturated polyester resin) is disclosed. The UPR comprises recurring units of phthalic anhydride, 2-methyl-1,3-propanediol, and maleic anhydride. It has a fumarate/maleate ratio 85/15 or greater. It has a bi- or multi-modal molecular weight distribution. A high molecular weight portion of the UPR has a peak molecular weight (Mp) 50,000 or greater. It has a weight average molecular weight (Mw) 15,000 or greater. An ortho UPR of the invention performs as well as or better than traditional iso UPR.Type: GrantFiled: July 29, 2002Date of Patent: February 24, 2004Assignee: Arco Chemical Technology, LPInventors: Lau S. Yang, Paul Malcolm Puckett
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Patent number: 6696522Abstract: A substantially non-gelled polymeric composition is disclosed and comprises the reaction product of an A polymer which is an addition polymer having 3.5 or more reactive functional groups per polymer chain and a B polymer having about 2 to about 3 functional groups per polymer chain that are co-reactive with the reactive functional groups of the A polymer. Also disclosed is a process for preparing such polymeric compositions, powder coatings and 100% solids ink resins prepared with such polymeric compositions, and a method for deglossing a powder coating using such polymeric compositions.Type: GrantFiled: August 16, 2001Date of Patent: February 24, 2004Assignee: Johnson Polymer, Inc.Inventors: Jeffrey L. Anderson, Alan J. Pekarik, Edward Tokas
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Patent number: 6642306Abstract: The invention concerns a method for preparing stable (co)polymer dispersions in a polyol by polymerising in situ a monomer or a mixture of ethylenically unsaturated monomers, in the presence of one or several azocarboxylic acid ester(s).Type: GrantFiled: August 15, 2002Date of Patent: November 4, 2003Assignee: AtofinaInventors: Martine Cerf, Mieczyslaw Wnuk
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Patent number: 6639017Abstract: The invention relates to flame-retardant, unsaturated polyester resins made from unsaturated and saturated dicarboxylic acids and/or their anhydrides, from polyhydric alcohols, from one or more monomers and from a reactive phosphorus compound, which contain structural units of the formula IV where R1 is straight-chain or branched alkyl, cycloalkyl, aryl or alkylaryl groups having from 1 to 18 carbon atoms and R2 is methyl or hydrogen. The invention likewise relates to a process for preparing such polyester resins and to their use.Type: GrantFiled: August 28, 1997Date of Patent: October 28, 2003Assignee: Clariant GmbHInventors: Sebastian Hörold, Hans-Peter Schmitz
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Patent number: 6617394Abstract: The invention relates to low molecular weight LPA surface quality enhancers derived from C36-44 dimer acids capped with a glycol or a polyether polyol. The capped dimer acids are incompatible in the cured matrix of a polyester molding composition.Type: GrantFiled: September 21, 2001Date of Patent: September 9, 2003Assignee: Ashland Inc.Inventors: Cynthia L. Smith, Dennis H. Fisher
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Patent number: 6576722Abstract: The present invention is directed to a method for producing a copolymer and a copolymer product of the method. The copolymer is prepared by a controlled radical polymerization process, typically an atom transfer radical polymerization process, in which polymerizable alkene monomers are polymerized in the presence of a halogenated polyolefin macroinitiator. The copolymer product of this process is useful in a film-forming composition that adheres strongly to polyolefinic substrates and to which non-polyolefinic film-forming compositions strongly adhere. The copolymer can be applied to a substrate in an adhesion-promoting layer or can be incorporated into a film-forming composition, such as a primer, that contains additional resinous compounds.Type: GrantFiled: December 13, 2000Date of Patent: June 10, 2003Assignee: PPG Industries Ohio, Inc.Inventors: Simion Coca, Brian K. Rearick, James B. O'Dwyer
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Publication number: 20030092841Abstract: The invention relates to low molecular weight LPA surface quality enhancers derived from C36-44 dimer acids capped with a glycol or a polyether polyol. The capped dimer acids are incompatible in the cured matrix of a polyester molding composition.Type: ApplicationFiled: September 21, 2001Publication date: May 15, 2003Inventors: Cynthia L. Smith, Dennis H. Fisher
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Patent number: 6555623Abstract: A process for making unsaturated polyesters from 2-methyl-1,3-propanediol (MPD) is disclosed. The process comprises reacting one equivalent of an aromatic diacid with about two equivalents of MPD to produce an ester diol and then reacting one equivalent of the ester diol with from about 1.1 to about 1.9 equivalents of maleic anhydride to produce the polyester. The polyester has a fumarate/maleate ratio of 90/10 or greater.Type: GrantFiled: March 18, 2002Date of Patent: April 29, 2003Assignee: Arco Chemical Technology, L.P.Inventors: Lau S. Yang, Paul Malcolm Puckett, Lawrence J. Karas, Diandre Armstead, Paul A. Albano
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Publication number: 20030072734Abstract: Water-soluble and/or water-dispersible comb polymers consisting of a polymer main chain and polyester side-arms which contain sulphone groups and are linked to said polymer main chain via ester groups.Type: ApplicationFiled: March 4, 2002Publication date: April 17, 2003Applicant: Beiersdorf AGInventors: Marion Detert, Andreas Koller, Roman Morschhauser
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Patent number: 6509415Abstract: A low dielectric constant material has a first backbone with an aromatic moiety and a first reactive group, and a second backbone with an aromatic moiety and a second reactive group, wherein the first and second backbones are crosslinked via the first and second reactive groups in a crosslinking reaction without an additional crosslinker, and wherein a cage structure having at least 10 atoms is covalently bound to at least one of the first and second backbone.Type: GrantFiled: April 7, 2000Date of Patent: January 21, 2003Assignee: Honeywell International Inc.Inventors: Kreisler Lau, Feng Quan Liu, Boris Korolev, Emma Brouk, Rusian Zherebin, Roger Leung
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Publication number: 20020193522Abstract: The present invention relates to a kind of synthesis and luminescent characteristic of novel phosphorus containing light-emitting polymers, especially one improving the luminescence efficiency of the synthesis light-emitting polymers. According to the method of the present invention, the electron-transporting chromophores are introduced into an emission polymer to increase its electron affinity. Further, several phosphorus-containing emission chromophores are synthesized and incorporated with electron-transporting chromophores finally resulting in the novel phosphorus chromophores emitting blue light as expected, improving thermal stability of resulting polymers such that the absorption peaks of these polymers are restricted to a stable range.Type: ApplicationFiled: June 14, 2001Publication date: December 19, 2002Inventor: Yih-Min Sun
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Patent number: 6492462Abstract: The rheological properties of a crosslinkable resin system are modified by the presence of a side chain crystalline (SCC) polymer (or a similar crystalline polymer which melts over a narrow temperature range). The polymer dissolves in the curable system at temperatures above the melting point of the crystalline polymer (Tp), but when the system is then cooled to a temperature below Tp, at least partially forms a separate phase in the curable system. Below Tp, this separate phase substantially increases the viscosity of the curable system (i.e. makes it thicker than the same system without the crystalline polymer). This is particularly valuable for sheet molding composites (SMCs) in which the increase in viscosity makes the composites less tacky, and for dry film resists (DFRs). Above Tp, the curable system containing the dissolved crystalline polymer has a viscosity which is substantially less than its viscosity below Tp.Type: GrantFiled: December 19, 2000Date of Patent: December 10, 2002Assignee: Landec CorporationInventors: Steven P. Bitler, David D. Taft, Ray F. Stewart
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Patent number: 6469123Abstract: In a method of producing a low dielectric constant polymer, a thermosetting monomer is provided, wherein the thermosetting monomer has a cage compound or aryl core structure, and a plurality of arms that are covalently bound to the cage compound or core structure. In a subsequent step, the thermosetting monomer is incorporated into a polymer to form the low dielectric constant polymer, wherein the incorporation into the polymer comprises a chemical reaction of a triple bond that is located in at least one of the arms. Contemplated cage compounds and core structures include adamantane, diamantane, silicon, a phenyl group and a sexiphenylene group, while preferred arms include an arylene, a branched arylene, and an arylene ether. The thermosetting monomers may advantageously be employed to produce low-k dielectric material in electronic devices, and the dielectric constant of the polymer can be controlled by varying the overall length of the arms.Type: GrantFiled: July 19, 2000Date of Patent: October 22, 2002Assignee: Honeywell International Inc.Inventors: Kreisler S. Lau, Feng Quan Liu, Boris A. Korolev, Emma Brouk, Ruslan Zherebin, David Nalewajek
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Patent number: 6414085Abstract: Unsaturated terephthalate-based polyester resins (UPR) based on 2-methyl-1,3-propanediol, a saturated dicarboxylic acid or derivative thereof, and an unsaturated dicarboxylic acid or derivative thereof be prepared without use of a catalyst in reasonable cycle times. UPR based on these monomers exhibit exceptional solubility in styrene, and are thus useful in polyester molding resins.Type: GrantFiled: November 22, 2000Date of Patent: July 2, 2002Assignee: Arco Chemical Technology, L.P.Inventors: Lawrence J. Karas, Paul M. Puckett
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Patent number: 6399700Abstract: Synthetic comb copolymers which elicit controlled cellular response, methods of applying these polymers to various surfaces, and methods of using the polymers for modifying biomaterial surfaces, in tissue engineering applications and as drug delivery devices are provided. The comb copolymers are comprised of hydrophobic polymer backbones and hydrophilic, non-cell binding side chains which can be end-capped with cell-signaling ligands that guide cellular response. By mixing non-cell binding combs with ligand-bearing combs, the surface concentration and spatial distribution of one or more types of ligands, including adhesion peptides and growth factors, can be tuned on a surface to achieve desired cellular response. In one embodiment, the combs are used as stabilizing agents for dispersion polymerization of latexes. The comb-stabilized latexes can be applied to substrates by standard coating operations to create a bioregulating surface, or used as drug delivery agents.Type: GrantFiled: March 26, 2001Date of Patent: June 4, 2002Assignee: Massachusetts Institute of TechnologyInventors: Anne M. Mayes, Linda G. Griffith, Darrell J. Irvine, Pallab Banerjee, Terry D. Johnson
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Patent number: 6380279Abstract: Radiation-curable powder compositions, usable as paint or varnish, which comprise a mixture of at least one semi-crystalline polyester containing end methacryloyl groups and of at least one amorphous polyester containing end methacryloyl groups, comprising the reaction products of a glycidyl methacrylate and of a semi-crystalline or amorphous polyester containing end carboxyl groups.Type: GrantFiled: April 17, 2000Date of Patent: April 30, 2002Assignee: UCB S.A.Inventors: Luc Moens, Jean-Marie Loutz, Daniel Maetens, Patrick Loosen, Marc Van Kerckhove
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Patent number: 6359064Abstract: A process for forming an elastomeric polymer gel composition includes forming a blend by combining a poly(alkenyl-co-maleimide) that includes a maleimide and at least one monomer contributed unit derived from vinyl aromatic hydrocarbons, R1R2 ethylenes, and alkyl vinyl ethers; with a maleated polyalkylene. This is followed by addition of a crosslinking agent, which is allowed to react with the poly(alkenyl-co-maleimide) and maleated polyalkylene to form a polyalkyenyl grafted poly(alkenyl-co-maleimide). The polyalkenyl grafted poly(alkenyl-co-maleimide) is further blended with a polyester.Type: GrantFiled: September 8, 2000Date of Patent: March 19, 2002Assignee: Bridgestone CorporationInventors: Xiaorong Wang, James E. Hall
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Patent number: 6348270Abstract: A polyetherester-based laminating resin composition includes an unsaturated polyetherester resin, and an epoxy acrylate oligomer. The laminating resin has no greater than about 35 percent by weight of ethylenically unsaturated monomer.Type: GrantFiled: August 30, 2000Date of Patent: February 19, 2002Assignee: Reichhold Inc.Inventors: Lixin Jin, Hildeberto Nava
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Patent number: 6346308Abstract: Active oxygen scavenging compositions and their use in packaging articles are disclosed. The compositions are all plastic materials and are typically deployed as at least one layer in a multi-layered wall of a packaging article such as a bottle, can or film. The compositions are usually used in conjunction with added transition metal catalyst to enhance the uptake of oxygen. Use of the compositions and package constructions disclosed serves to lengthen the shelf life of packaged oxygen sensitive substances and/or diminish the need for refrigeration of the packages.Type: GrantFiled: February 11, 2000Date of Patent: February 12, 2002Assignee: BP Corporation North America Inc.Inventors: Paul J. Cahill, Joel A. Richardson, George E. Rotter, Granville L. Smyser, Roman F. Barski, Jr., Raymond V. Wass, Walter M. Nyderek
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Publication number: 20020016414Abstract: A low dielectric constant material has a first backbone with an aromatic moiety and a first reactive group, and a second backbone with an aromatic moiety and a second reactive group, wherein the first and second backbones are crosslinked via the first and second reactive groups in a crosslinking reaction without an additional crosslinker, and wherein a cage structure having at least 10 atoms is covalently bound to at least one of the first and second backbone.Type: ApplicationFiled: August 20, 2001Publication date: February 7, 2002Applicant: Honeywell International Inc.Inventors: Kreisler Lau, Feng Quan Liu, Boris Korolev, Emma Brouk, Ruslan Zherebin, Roger Leung
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Patent number: 6316538Abstract: An aqueous polymeric dispersion is described containing at least one substantially non-gelled polymeric composition comprising the reaction product of an A polymer which is an addition polymer having 3.5 or more reactive functional groups per polymer chain and a B polymer having about 2 to about 3 functional groups per polymer chain that are co-reactive with the reactive functional groups of the A polymer and an aqueous solvent. The aqueous polymeric dispersion is particularly useful in or as overprint varnishes, inks, pigment dispersions, paints, adhesives, coatings, support resins, emulsion polymers and the like.Type: GrantFiled: October 17, 2000Date of Patent: November 13, 2001Assignee: S. C. Johnson Commerical Markets, Inc.Inventors: Jeffrey L. Anderson, Edward Tokas
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Patent number: 6207762Abstract: The invention provides a thermally reversible crosslinked matter, which displays a sufficiently low melt viscosity during heating and is also excellent in the stability of the melt viscosity, and further provides a hot melt resin comprising this crosslinked matter. The thermally reversible crosslinked matter comprises a compound (A)-based moiety and a compound (B)-based moiety, wherein both moieties are bonded to each other through a crosslinked structure, which is characterized in that: the crosslinked structure includes a structure making steric hindrance, and breaks due to heating and then reverts due to cooling; and when the crosslinked structure breaks due to heating, the melt viscosity of the thermally reversible crosslinked matter decreases to not higher than twice the melt viscosity of compound (A) alone or the melt viscosity of compound (B) alone, whichever is higher, as heated at the same temperature that the thermally reversible crosslinked matter is heated at.Type: GrantFiled: April 4, 1998Date of Patent: March 27, 2001Assignee: Nippon Shokubai Co., Ltd.Inventors: Nobuhiro Kobayashi, Masatoshi Yoshida
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Patent number: 6200686Abstract: An unsaturated polyester resin composition includes: (A) 100 parts by weight of an unsaturated polyester having a dicyclopentenyl group; (B) 20 to 100 parts by weight of a polymerizable aromatic vinyl monomer; (C) 0.5 to 20 parts by weight of a polymerizable aliphatic vinyl monomer; and (D) 50 to 10000 ppm of a thermoplastic polymer relative to the total weight of the components (A), (B) and (C), in which the thermoplastic polymer is soluble in the polymerizable aliphatic vinyl monomer, and the weight ratio (D/C) of the component (D) to the component (C) is equal to or less than ⅕. The unsaturated polyester resin composition can provide a laminated or joint monolithic molding having markedly high secondary bond strength without deteriorating inherent drying characteristics of the unsaturated polyester resin composition having a dicyclopentenyl group. Moldings obtained by using the resin composition are also provided.Type: GrantFiled: November 16, 1999Date of Patent: March 13, 2001Assignee: Nippon Shokubai Co., Ltd.Inventors: Yukinori Ozaki, Tsugishige Iwaki
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Patent number: 6184283Abstract: A rubber composition for treads which contains silica and has a low electric resistance and further well-balanced characteristics such as a low rolling resistance, abrasion resistance and good wet performance can be obtained. The rubber composition comprises 40 to 90 parts by weight of silica and 5 to 40 parts by weight of diester of adipic acid based on 100 parts by weight of a diene rubber.Type: GrantFiled: December 21, 1998Date of Patent: February 6, 2001Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Masato Komatsuki, Tetsuya Kunisawa, Isamu Tsumori
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Patent number: 6166136Abstract: A resin composition utilizing coated resin moldings, the resin composition comprising 100 parts by weight of a crushed material of coated polyolefin resin moldings compounded with from 3 to 15 parts by weight of an ethylene polymer having a weight average molecular weight of from 50,000 to 180,000.Type: GrantFiled: July 21, 1998Date of Patent: December 26, 2000Assignees: Japan Polyolefins Co., Ltd., Honda Giken Kogyo Kabushiki KaishaInventors: Hirofumi Murakami, Kazuhiko Sakai, Akihiro Katagiri, Yoshio Kitawaki, Takashi Nakayama, Kazuo Ito, Atushi Takeuchi, Minoru Makuta, Hitoshi Ohgane, Kenji Hamabe, Osamu Aoki
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Patent number: 6162882Abstract: The present invention is directed to a process of atom (or group) transfer radical polymerization for the synthesis of novel homopolymer or a block or graft copolymer, optionally containing at least one polar group, with well defined molecular architecture and narrow polydipersity index, in the presence of an initiating system comprising (i) an initiator having a radically transferrable atom or group, (ii) a transition metal compound, and (iii) a ligand, the present invention is also directed to the synthesis of a macromolecule having at least two halogen groups which can be used as a macroinitiator component (i) to subsequently form a block or graft copolymer by an atom or group transfer radical polymerization process; the present invention is also directed to a process of atom or group transfer radical polymerization for the synthesis of a branched or hyperbranched polymer; in addition, the present invention is directed to a process of atom or group transfer radical polymerization for the synthesis of a macType: GrantFiled: November 2, 1999Date of Patent: December 19, 2000Assignee: Carnegie Mellon UniversityInventors: Krzysztof Matyjaszewski, Simion Coca, Scott G. Gaynor, Yoshiki Nakagawa, Seong Mu Jo
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Patent number: 6150459Abstract: Synthetic comb copolymers which elicit controlled cellular response, methods of applying these polymers to various surfaces, and methods of using the polymers for modifying biomaterial surfaces, in tissue engineering applications and as drug delivery devices are provided. The comb copolymers are comprised of hydrophobic polymer backbones and hydrophilic, non-cell binding side chains which can be end-capped with cell-signaling ligands that guide cellular response. By mixing non-cell binding combs with ligand-bearing combs, the surface concentration and spatial distribution of one or more types of ligands, including adhesion peptides and growth factors, can be tuned on a surface to achieve desired cellular response. In one embodiment, the combs are used as stabilizing agents for dispersion polymerization of latexes. The comb-stabilized latexes can be applied to substrates by standard coating operations to create a bioregulating surface, or used as drug delivery agents.Type: GrantFiled: April 13, 1999Date of Patent: November 21, 2000Assignee: Massachusetts Institute of TechnologyInventors: Anne M. Mayes, Linda G. Griffith, Darrell J. Irvine, Pallab Banerjee, Terry D. Johnson
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Patent number: 6124411Abstract: The present invention is directed to a process of atom (or group) transfer radical polymerization for the synthesis of novel homopolymer or a block or graft copolymer, optionally containing at least one polar group, with well defined molecular architecture and narrow polydispersity index, in the presence of an initiating system comprising (i) an initiator having a radically transferrable atom or group, (ii) a transition metal compound, and (iii) a ligand; the present invention is also directed to the synthesis of a macromolecule having at least two halogen groups which can be used as a macroinitiator component (i) to subsequently form a block or graft copolymer by an atom or group transfer radical polymerization process; the present invention is also directed to a process of atom or group transfer radical polymerization for the synthesis of a branched or hyperbranched polymer; in addition, the present invention is directed to a process of atom or group transfer radical polymerization for the synthesis of a maType: GrantFiled: September 14, 1999Date of Patent: September 26, 2000Assignee: Carnegie Mellon UniversityInventors: Krzysztof Matyjaszewski, Simion Coca, Scott G. Gaynor, Yoshiki Nakagawa, Seong Mu Jo
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Patent number: 6111022Abstract: The present invention is directed to a process of atom (or group) transfer radical polymerization for the synthesis of novel homopolymer or a block or graft copolymer, optionally containing at least one polar group, with well defined molecular architecture and narrow polydispersity index, in the presence of an initiating system comprising (i) an initiator having a radically transferrable atom or group, (ii) a transition metal compound, and (iii) a ligand; the present invention is also directed to the synthesis of a macromolecule having at least two halogen groups which can be used as a macroinitiator component (i) to subsequently form a block or graft copolymer by an atom or group transfer radical polymerization process; the present invention is also directed to a process of atom or group transfer radical polymerization for the synthesis of a branched or hyperbranched polymer; in addition, the present invention is directed to a process of atom or group transfer radical polymerization for the synthesis of a maType: GrantFiled: December 8, 1998Date of Patent: August 29, 2000Assignee: Carnegie-Mellon UniversityInventors: Krzysztof Matyjaszewski, Simion Coca, Scott G. Gaynor, Yoshiki Nakagawa, Seong Mu Jo
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Patent number: 6037413Abstract: A polyester having a hydroxyl value of at least 30 mg KOH/g and a weight average molecular weight (Mw) of preferably from 1,000 to 500,000 and prepared by polycondensation of a polycarboxylic acid ingredient predominantly comprised of an aromatic dicarboxylic acid and a polyhydric alcohol ingredient predominantly comprised of a hindered alcohol. This polyester is suitable for modifying a resinous or rubbery polymer.Type: GrantFiled: December 16, 1998Date of Patent: March 14, 2000Assignee: Nippon Zeon Co, Ltd.Inventors: Shizuo Kitahara, Shinya Ikeda
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Patent number: 6027814Abstract: The invention relates to a composition including (i) at least one polyamide and at least one copolymer (A) of ethylene with at least one comonomer chosen from unsaturated carboxylic acids, esters of unsaturated carboxylic acids or vinyl esters of saturated carboxylic acids and (ii) being in powder form. These compositions are subsequently deposited on metal substrates and then a highly corrosion-resistant coating is obtained by melting.Type: GrantFiled: October 6, 1997Date of Patent: February 22, 2000Assignee: Elf Atochem S.A.Inventors: Olivier Julien, Michael Werth, Arnaud Tedoldi, Jean-Marc Sage
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Patent number: 5972272Abstract: An unsaturated polyester resin composition for molding comprising (A) an unsaturated polyester resin, (B) a thickening agent containing powder of a thermoplastic resin as the effective component thereof in an amount of 20 to 120 parts by weight per 100 parts by weight of the unsaturated polyester resin, (C) a liquid polymerizable monomer in an amount of 30 to 120 parts by weight per 100 parts by weight of the unsaturated polyester resin, and (D) a curing agent; SMC and BMC prepared by adding (E) a reinforcing material to the composition; and a process for molding the SMC and the BMC at a low temperature under a low pressure. The unsaturated polyester resin composition of the present invention can be converted into SMC in a short time. The obtained SMC has an excellent storage stability, can be molded at a low temperature under a low pressure, and provides a molded product exhibiting low shrinkage, excellent surface smoothness, a large strength, and a large modulus.Type: GrantFiled: December 26, 1996Date of Patent: October 26, 1999Assignee: Nippon Zeon Co., Ltd.Inventors: Toshio Nagase, Takeo Kobayashi, Atsushi Tsukamoto
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Patent number: 5969046Abstract: A method for reacting a methylene-containing component such as an acrylic polymer prepared from acetoacetoxyalkyl (meth)acrylate and an alkene-containing component such as a polyfumarate, polymaleate, a polyester containing both fumarate and maleate groups or a polyacrylate comprises the reaction of a tertiary amine such as triethylene diamine and an epoxide such as a glycidyl-functional (meth)acrylic polymer in the presence of the methylene-containing component and alkene-containing component. The tertiary amine can be incorporated into the alkene-containing component such as the reaction of an unsaturated polyester with a compound having both tertiary amine and primary or secondary amine groups. The tertiary amine can be incorporated into the methylene-containing component such as an acrylic polymer derived from a tertiary amino-functional monmer and acetoacetoxyalkyl (meth)acrylate.Type: GrantFiled: April 9, 1991Date of Patent: October 19, 1999Assignee: Rohm and Haas CompanyInventors: F. J. Schindler, M. J. Hurwitz, M. H. Wolfersberger, R. L. Fulton, Jr., W. E. Feely
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Patent number: 5945491Abstract: The present invention is directed to a process of atom (or group) transfer radical polymerization for the synthesis of novel homopolymer or a block or graft copolymer, optionally containing at least one polar group, with well defined molecular architecture and narrow polydispersity index, in the presence of an initiating system comprising (i) an initiator having a radically transferrable atom or group, (ii) a transition metal compound, and (iii) a ligand; the present invention is also directed to the synthesis of a macromolecule having at least two halogen groups which can be used as a macroinitiator component (i) to subsequently form a block or graft copolymer by an atom or group transfer radical polymerization process; the present invention is also directed to a process of atom or group transfer radical polymerization for the synthesis of a branched or hyperbranched polymer; in addition, the present invention is directed to a process of atom or group transfer radical polymerization for the synthesis of a maType: GrantFiled: September 30, 1997Date of Patent: August 31, 1999Assignee: Carnegie-Mellon UniversityInventors: Krzysztof Matyjaszewski, Simion Coca, Scott G. Gaynor, Yoshiki Nakagawa, Seong Mu Jo
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Patent number: 5874503Abstract: This invention relates to a polyester resin comprising (A) from about 5% to about 50% by weight reactive diluent and (B) from about 50% to about 95% by weight of an unsaturated polyester resin prepared from at least one component selected from the group consisting of (i) from about 0.5% up to about 8% by mole of a polyhydric alcohol, having at least three hydroxyl groups, and at least one transesterification catalyst, (ii) from about 2% up to about 12% by mole of a reaction product of a polyol and a fatty carboxylic acid, and (iii) from about 2% up to about 12% by mole of a fatty reactant selected from the group consisting of a fatty primary alcohol, a fatty epoxide, a fatty monocarboxylic acid and mixtures thereof, wherein each member of the group has up to about 100 carbon atoms. In another aspect, the invention relates to mixtures of the above polyester resins with conventional polyester resins. Methods of reducing volatile organic compound emissions are also part of the invention.Type: GrantFiled: August 22, 1997Date of Patent: February 23, 1999Assignee: Ferro CorporationInventors: Anthony S. Scheibelhoffer, Gerald W. Drabeck, Ronald E. Thompson, Dianna B. Dusek, Timothy W. Birch, Jeffrey L. Wilcoxson
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Patent number: 5824421Abstract: Condensation-curable coating compositions are prepared from a mixture of and organic resin (A) and a flurosilicone (B). Water or an organic solvent may be used to provide a vehicle for application of the composition. The cured coatings of the invention exhibit superior water and oil repellency.Type: GrantFiled: October 30, 1996Date of Patent: October 20, 1998Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Hideki Kobayashi, Toru Masatomi
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Patent number: 5811478Abstract: Molding compositions comprising certain epoxy compounds, at least one antioxidant, an unsaturated thermosetting resin and an olefinically unsaturated monomer are disclosed. The disclosed compositions can provide enhanced yellowing resistance to articles molded from the compositions, particularly when the molding compositions contain white pigment. Processes from molding articles having enhanced yellowing resistance are also disclosed.Type: GrantFiled: December 23, 1996Date of Patent: September 22, 1998Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Gary Charles Rex, Kenneth Earl Atkins
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Patent number: 5804658Abstract: A process for producing a composite article made of at least one hard component and at least one soft component, wherein the hard component contains a thermoplastic polyester containing non-aromatic C.dbd.C double bonds, and the soft component contains a vulcanizate, wherein the vulcanizate is produced by vulcanization of a rubber composition having the following components:(i) 100 parts by weight of a rubber containing carboxyl or anhydride groups;(ii) from 0 to 300 parts by weight of fillers;(iii) from 1 to 10 parts by weight of peroxidic vulcanizers;(iv) from 0 to 150 parts by weight of plasticizers, and(v) more than 4 parts by weight of a difunctional or polyfunctional vulcanization activator of the formulaR.sup.1 (--Z--CO--CR.sup.2 .dbd.CR.sup.3 R.sup.4).sub.n,whereinR.sup.1 is a divalent or higher-valent radical or a single bond, R.sup.2 to R.sup.Type: GrantFiled: October 11, 1996Date of Patent: September 8, 1998Assignee: Huels AktiengesellschaftInventors: Friedrich Georg Schmidt, Horst Heuer
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Patent number: 5798415Abstract: The invention relates to fluoro copolymers containing hydroxyl groups and amino groups in salified or quaternized form.With such a copolymer and a polyisocyanate, an aqueous composition which is useful for the oleophobic and hydrophobic treatment of building materials may be prepared.Type: GrantFiled: November 29, 1995Date of Patent: August 25, 1998Assignee: Elf Atochem S.A.Inventors: Jean-Marc Corpart, Marie-Jose Lina, Christian Bonardi, Andre Dessaint
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Patent number: 5783635Abstract: An unsaturated polyester resin composition which comprises 100 parts by weight of a resin mixture comprising 25 to 80 parts by weight of an unsaturated polyester, 20 to 60 parts by weight of a comonomer and 1 to 10 parts by weight of a particulate crosslinked polymer and 100 to 400 parts by weight of an inorganic filler and in which the difference in refractive index between a product of copolymerization of the unsaturated polyester with the comonomer and the inorganic filler is 0.02 or below; and molded articles produced by curing the resin composition by heating under pressure. The resin composition has a high productivity, exhibits a texture excellent in both light transmittance and gloss, and is excellent in water resistance and which is suitable for the production of artificial marble.Type: GrantFiled: April 30, 1997Date of Patent: July 21, 1998Assignee: Takeda Chemical Industries, Ltd.Inventors: Koichi Akiyama, Kenichi Morita, Hideki Terada
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Patent number: 5770653Abstract: A resin composition includes a dicyclopentenyl-group containing unsaturated polyester resin, a phenothiazine derivative (a) and an anion producing compound (b). On the other hand, resin composition includes a thermosetting resin, a phenothiazine derivative (a), an anion producing compound (b) and a phosphorous ester (c). A manufacturing method of resin composition includes the step of obtaining a dicyclopentenyl-group-containing unsaturated polyester by polycondensing unsaturated polyester material including a compound having a dicyclopentenyl group, and the step of mixing a cross-linking monomer with the obtained dicyclopentenyl-group-containing unsaturated polyester, wherein the phenothiazine (a) and the anion producing compound (b) are added in at least one of those steps.Type: GrantFiled: August 5, 1996Date of Patent: June 23, 1998Assignee: Nippon Shokubai Co., Ltd.Inventors: Kenji Matsukawa, Toshio Hayashiya, Daisaku Yamamoto
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Patent number: 5747607Abstract: A sheet molding composition is provided which exhibits controllable thickening. The composition includes a low molecular weight polyester in which some of the chain ends have been endcapped with functional groups which are unable to react with the thickeners employed in the sheet molding composition. The sheet molding composition has a low viscosity of from about 6 to about 20 million centipoise which allows molding at low pressures of from about 100 to about 300 psi.Type: GrantFiled: June 27, 1996Date of Patent: May 5, 1998Assignee: Owens-Corning Fiberglas Technology, Inc.Inventors: William G. Hager, Edward L. Wilson, Paul R. Krumlauf
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Patent number: 5747548Abstract: Apparatus and method for the production of hopper feedable thermoplastic pellets having zones or compartments which contain physically separated reactants which react only after being melt-mixed, as in a screw type extruder, reciproscrew injection machine, or similar device which heat forms pellets into a larger mass. This new class of thermoplastic molding materials relies mainly on the relatively slow reaction kinetics of contained large molecule molding materials to provide a time interval after melt-mixing of zoned pelletized reactants in an extruder barrel or injection molding machine. During this time period, the thermoplastic molding material is easily filled into injection molds. As the reaction progresses, the material becomes more viscous and such flow is difficult or impossible. The involved reactions may continue after demolding at room temperature during a post molding cure, or appliance service generated heat may cause post molding cure.Type: GrantFiled: March 14, 1997Date of Patent: May 5, 1998Assignee: Materials Research Innovations CorporationInventor: Rexford H. Bradt
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Patent number: 5717032Abstract: A filming composition comprises an acryl emulsion having a molecular weight of 1.5.about.2.5 million and a decomposition starting temperature of 200.degree..about.250.degree. C., as a main component. The composition has a tendency to decompose at low temperature and can be completely decomposed and removed during frit sealing, without the need for separate baking or complex equipment. A screen having good characteristics can be obtained through an advantageous method.Type: GrantFiled: March 10, 1995Date of Patent: February 10, 1998Assignee: Samsung Display Devices Co., Ltd.Inventors: Hyeon-sang Kim, Jong-ho Oh
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Patent number: 5700856Abstract: A peroxide-generating composition for use in curing an unsaturated polyester resin and to the cured unsaturated polyester resin composition so prepared, particularly unsaturated polyester resin compositions containing inert filler materials used prepare a cast or molded product. The peroxide-generating composition comprises an allyl alcohol alkanoate, such as allyl alcohol propoxylate, which in the presence of a metal salt promoter, such as cobalt carboxylate, either with the allyl alcohol alkanoate or separately as a prepromoter in the unsaturated polyester resin composition provides for the generation from the allyl alcohol alkanoate of a peroxide to effect the in situ cure of the unsaturated polyester resin composition.Type: GrantFiled: April 10, 1996Date of Patent: December 23, 1997Assignee: Hehr International Inc.Inventor: Stuart B. Smith
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Patent number: 5688867Abstract: This invention relates to a polyester resin comprising (A) from about 5% to about 50% by weight reactive diluent and (B) from about 50% to about 95% by weight of an unsaturated polyester resin prepared from at least one component selected from the group consisting of (i) from about 0.5% up to about 8% by mole of a polyhydric alcohol, having at least three hydroxyl groups, and at least one transesterification catalyst, (ii) from about 2% up to about 12% by mole of a reaction product of a polyol and a fatty carboxylic acid, and (iii) from about 2% up to about 12% by mole of a fatty reactant selected from the group consisting of a fatty primary alcohol, a fatty epoxide, a fatty monocarboxylic acid and mixtures thereof, wherein each member of the group has up to about 100 carbon atoms. In another aspect, the invention relates to mixtures of the above polyester resins with conventional polyester resins. Methods of reducing volatile organic compound emissions are also part of the invention.Type: GrantFiled: May 1, 1995Date of Patent: November 18, 1997Assignee: Ferro CorporationInventors: Anthony S. Scheibelhoffer, Gerald W. Drabeck, Ronald E. Thompson, Dianna B. Dusek, Timothy W. Birch, Jeffrey L. Wilcoxson
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Patent number: 5637630Abstract: A molding composition comprises a) an unsaturated polyester resin, b) a copolymerizable olefinically unsaturated monomer, c) a pigment, d) fiber reinforcement and e) a poly(vinyl ether) polymer with a weight average molecular weight of at least 50,000 to control shrinkage and promote the uniform distribution of the pigment in the molding composition.Type: GrantFiled: November 22, 1991Date of Patent: June 10, 1997Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventor: Kenneth E. Atkins
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Patent number: 5633320Abstract: There is provided a thermoplastic polyester resin composition comprising a thermoplastic polyester resin (A) and a graft modified product (B) of a mixture of two different specific ethylene.1-butene random copolymers in a weight ratio of 95/5 to 50/50. A molded article having excellent impact resistance at low temperatures and mechanical strength can be obtained from this composition.Type: GrantFiled: May 7, 1996Date of Patent: May 27, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Yasuo Tanaka, Yohji Hayakawa
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Patent number: 5614299Abstract: The heat-resistant unsaturated polyester resin composition of the present invention consists essentially of (a.sub.1) an unsaturated polyester which is obtained by the reaction of (.alpha..sub.1) a polybasic acid component containing at least an ethylenic unsaturated polybasic acid with (.alpha..sub.2) a polyhydric alcohol component, and (a.sub.2) a diluent monomer component for the unsaturated polyester, wherein the polyhydric alcohol component (.alpha..sub.2) contains 2-methyl-1,3-propanediol and 1,4-cyclohexanedimethanol in the total amount of 50 mol % or more, and 2-methyl-1,3-propanediol and 1,4-cyclohexanedimethanol are in the molar ratio of 9:1 to 5:5. The fiber-reinforced composite material of the present invention comprises the above resin composition and reinforcing fibers. The molded article manufactured using this composite material exhibits excellent strength and rigidity even under high temperatures of over 200.degree. C.Type: GrantFiled: February 26, 1996Date of Patent: March 25, 1997Assignee: Kabushiki Kaisha Kobe Seiko ShoInventors: Koji Yamamoto, Takeshi Kuri
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Patent number: 5597651Abstract: Multi-component composites containing a linear polyester of an alkyl glycol and an aromatic diacid as one component, rubber as a second component, and a third component which is a compatibilizing polyester (polystyrene copolymer).Type: GrantFiled: October 26, 1995Date of Patent: January 28, 1997Assignee: Hoechst Celanese Corp.Inventors: Eui W. Choe, Charles E. Forbes, Jennifer A. Filbey, Stephan F. Sherriff