Polycarboxylic Acid Or Derivative, Polyol, Or Other Coreactant Contains An Ethylenic Group; Or Wherein A Condensate Thereof Has Been Prepared From A Polycarboxylic Acid Or Derivative And A Polyol And Subsequently Reacted With An Ethylenic Reactant Patents (Class 525/168)
  • Patent number: 4297389
    Abstract: The foaming of resinous insulating materials under vacuum is substantially reduced by adding to the material a polydiene having primarily vinyl unsaturation.
    Type: Grant
    Filed: May 27, 1980
    Date of Patent: October 27, 1981
    Assignee: General Electric Company
    Inventor: Robert W. Smearing
  • Patent number: 4258148
    Abstract: Graft copolymers are prepared by the polymerization of an ethylenically unsaturated monomer, or a mixture of such monomers, in the presence of an azo di-ester polyol. Presence of the azo group in the polyol reactant itself serves as a free radical initiator site for the graft copolymerization reaction. The copolymers formed are utilized in the formulation of polyurethane compositions.
    Type: Grant
    Filed: March 22, 1977
    Date of Patent: March 24, 1981
    Assignee: Olin Corporation
    Inventors: Kiran B. Chandalia, Frank J. Preston
  • Patent number: 4248997
    Abstract: A process for the production of a final curable resin comprising the steps of reacting a cyclopentadiene type compound with a compound having a double bond and hydroxyl group in the molecule to obtain a hydroxyl group-containing resin, reacting the thus obtained resinous polyol and at least one other polyol with a polybasic acid to obtain a hydroxyl group-containing alkyd resin and then esterifying the alkyd resin with an .alpha.,.beta.-unsaturated carboxylic acid thereby obtain the final curable resin. In one embodiment, this invention relates to said final curable resins and also to curable coating compositions containing same.
    Type: Grant
    Filed: July 30, 1979
    Date of Patent: February 3, 1981
    Assignee: Toyo Ink Manufacturing Co., Ltd.
    Inventor: Kazuyoshi Ihida
  • Patent number: 4245059
    Abstract: An unsaturated polyester composition for molding compounds, consisting essentially of (1) 20 to 70 parts by weight of an unsaturated polyester obtained by condensing an acid component comprising a major amount of an .alpha.,.beta.-ethylenically unsaturated dicarboxylic acid with a polyol, (2) 25 to 75 parts by weight of a vinyl monomer copolymerizable with said unsaturated polyester, (3) 1 to 25 parts by weight of a thermoplastic polymer, and (4) at least one member selected from the group consisting of hydroxyl-containing vinyl monomers and epoxy-containing vinyl monomers in a ratio of 1 to 40 parts by weight to 100 parts by weight of said unsaturated polyester (to form 100 parts by weight of the composition). The composition may be molded and cured to yield articles which provide good adhesion to surface coatings and are susceptible of decorative finishes.
    Type: Grant
    Filed: October 31, 1978
    Date of Patent: January 13, 1981
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Yutaka Ichimura, Takahiro Kishino, Naoyuki Fukahori
  • Patent number: 4237244
    Abstract: Molding compositions comprising terminally unsaturated polyesters, vinyl or vinylidene compounds copolymerizable therewith and elastomeric polymers have an excellent impact strength and a good heat distortion temperature, strength and rigidity.
    Type: Grant
    Filed: January 3, 1979
    Date of Patent: December 2, 1980
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hannes von Harpe, Ludwig Bottenbruch, Bernd Peltzer, Hansjochen Schulz-Walz
  • Patent number: 4233413
    Abstract: A resin composition comprising (A) 25 to 45 parts by weight of an unsaturated polyester having special structure, (B) 40 to 60 parts by weight of polymerizable monomer such as styrene, and (C) 4.5 to 15 parts by weight of a polystyrene, has low shrink properties and excellent electrical properties when molded, particularly by casting.
    Type: Grant
    Filed: November 28, 1978
    Date of Patent: November 11, 1980
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Noboru Monma, Iwao Maekawa, Tutomu Sarudate, Hidetaka Sato, Isao Uchigasaki
  • Patent number: 4228251
    Abstract: A resin composition which comprises (A) 50 to 90 parts by weight of an unsaturated ester oligomer produced by reacting a glycol, hydroxylated dicyclopentadiene, and at least one unsaturated dibasic acid or anhydride thereof until an acid value of less than 40, (B) 50 to 10 parts by weight of one or more polymerizable monomers, and (C) 3 to 15 parts by weight of polystyrene based on 100 parts by weight of the total of the components (A) and (B), can give molded articles having low shrink properties and improved color shading, cracks, etc.
    Type: Grant
    Filed: November 30, 1978
    Date of Patent: October 14, 1980
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Iwao Maekawa, Isao Uchigasaki, Noboru Monma
  • Patent number: 4172103
    Abstract: Thermoplastic moulding compounds of1. 10-95% by weight of an aromatic polycarbonate in which at least 50% of the linear chains comprise recurrent structural units of the formula ##STR1## in which R represents C.sub.1 -C.sub.3 alkyl and X represents a single bond, --O--, --CO--, --SO.sub.2 --, C.sub.1 -C.sub.10 alkylene, C.sub.1 -C.sub.10 alkylidene, C.sub.5 -C.sub.15 cycloalkylene, C.sub.5 -C.sub.15 cycloalkylidene or ##STR2## 2. 5-90% by weight of a thermoplastic resin and/or 3. 5-90% BY WEIGHT OF RUBBER WHICH MAY BE MODIFIED.
    Type: Grant
    Filed: August 23, 1977
    Date of Patent: October 23, 1979
    Assignee: Bayer Aktiengesellschaft
    Inventors: Volker Serini, Wolfgang Cohen, Hugo Vernaleken, Gunter Perlstocker
  • Patent number: 4161471
    Abstract: Filled unsaturated ester bulk molding, sheet molding, premix or mat molding compositions are modified with elastomer to give finished products with both improved impact strength and improved surface characteristics. The elastomeric modifier is selected from the group consisting of chloroprene polymers and hydrocarbon polymers such as ethylene/propylene di-, ter-, or tetrapolymers.
    Type: Grant
    Filed: April 13, 1978
    Date of Patent: July 17, 1979
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Robert J. Kassal
  • Patent number: 4160759
    Abstract: Reinforced molding compounds are disclosed comprising elastomer modified thermosetting unsaturated polyesters which include conjugated diene butyl rubber elastomer copolymer dispersed therein, and which further include inorganic particulate filler material and a free radical polymerizable monomer. Preferably, they also include a thermoplastic component, and such compounds have improved surface appearance, toughness and impact strength as demonstrated by the molded articles produced from such a low profile system.
    Type: Grant
    Filed: January 30, 1978
    Date of Patent: July 10, 1979
    Assignee: Exxon Research & Engineering Co.
    Inventors: Irwin J. Gardner, Francis P. Baldwin
  • Patent number: 4160758
    Abstract: Methods for preparing reinforced molding compounds are disclosed, comprising preparing a first paste component from a mixture of a thermosetting unsaturated polyester component, a free radical polymerizable monomer component and an inorganic particulate filler component, preparing a second paste component from a conjugated diene butyl elastomer copolymer component, a free radical polymerizable monomer component, and an inorganic particulate filler component, and combining the first and second paste components in order to produce an elastomer modified thermosetting unsaturated polyester molding compound having improved surface appearance, toughness and impact strength. Preferably, one or both of the paste components will include a thermoplastic polymer additive component to provide low profile qualities to the product.
    Type: Grant
    Filed: January 30, 1978
    Date of Patent: July 10, 1979
    Assignee: Exxon Research & Engineering Co.
    Inventor: Irwin J. Gardner