Solid Polymer Derived From Ethylenic Reactants Only Derived From At Least One Reactant Containing An Atom Other Than C, H, O, Or Hal Patents (Class 525/175)
-
Patent number: 5552480Abstract: There is disclosed a thermoplastic resin composition comprising as principal components a [A] thermoplastic resin having a functional group reactive with an amino group, a [B] olefinic polymer and/or styrenic polymer, the subtotal of the above [A]+[B] being 100 parts by weight, and 0.Type: GrantFiled: February 25, 1993Date of Patent: September 3, 1996Assignees: Idemitsu Petrochemical Co., Ltd., Dai-ichi Kogyo Seiyaku Co., Ltd.Inventors: Yasuhisa Sugita, Naoki Kitazawa, Hiroshi Hotta
-
Patent number: 5549932Abstract: Thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating, a specific vinyl ether or vinyl thioether and a thermal latent acid catalyst. The blocked carboxy group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule. The thermosetting composition gives cured products having excellent chemical properties, physical properties, weathering resistant and storage stability and is advantageously utilized for coating compositions, ink, adhesive and molded plastics.Type: GrantFiled: March 9, 1995Date of Patent: August 27, 1996Assignee: Nippon Oil and Fats Company, LimitedInventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
-
Patent number: 5550190Abstract: The composition of the present invention is a thermoplastic elastomer composition obtained by dynamically crosslinking (A) 51-95% by weight of a thermoplastic polyester elastomer and (B) 49-5% by weight of a rubber during kneading. The composition is excellent in all of hardness, tensile strength, tensile elongation, compression set, thermal aging resistance, oil resistance and molded product appearance, and is suitably used as a material for automobile parts such as joint boot and the like.Type: GrantFiled: March 27, 1992Date of Patent: August 27, 1996Assignees: Japan Synthetic Rubber Co., Ltd., NTN CorporationInventors: Ko Hasegawa, Toshio Teramoto, Tatsuo Nakajima, Takeyoshi Konomoto
-
Patent number: 5547710Abstract: Aqueous curable polymer dispersion comprising a polyester and/or polyurethane and a polymeric product having a Tg from 25.degree.-100.degree. C. obtainable by free-radical polymerisation of a mixture of (a) an olefinic monomer free from epoxy and epoxy reactive groups, (b) a monomer and/or oligomer having at least two epoxy groups and (c) a group reactive towards epoxy groups.Type: GrantFiled: November 3, 1994Date of Patent: August 20, 1996Assignee: Zeneca LimitedInventors: Rajasingham Satgurunathan, David C. Hinde, John C. Padget, John G. Carey
-
Patent number: 5541259Abstract: Resin compositions having excellent heat resistance, izod impact strength, rigidity and dimensional resistance and the like, applied in the fields of the automobile, electric and electronic, and the like industries. The resin composition comprising: a) a resin in which 30 to 98 mole % of the component (I) are contained in the whole polymer and 70 to 2 mole % of the component (II) are contained in the whole polymer, its weight-average molecular weight converted into that of polystyrene being 1.times.10.sup.3 or more to 5.times.10.sup.6 or less, and b) an olefin resin; then the a)/b) content being 5/95 to 99/1 as a weight ratio, ##STR1## wherein R.sub.1 is an alkyl group having 1 to 18 carbon atom(s) or a cycloalkyl group having 3 to 12 carbon atoms; and ##STR2## wherein R.sub.2 is hydrogen or an alkyl group having 1 to 8 carbon atom(s), and R.sub.3 and R.sub.4 is an alkyl group having 1 to 8 carbon atoms.Type: GrantFiled: June 21, 1994Date of Patent: July 30, 1996Assignee: Tosoh CorporationInventor: Toru Doi
-
Patent number: 5496888Abstract: Resin compositions, comprising (A) a styrene/acrylic polymer and (B) a polyester dispersed therein with an average particle size of not more than 3 .mu., are obtained by quenching a mixture of (A) and (B) melted at 150.degree.-200.degree. C., below the glass transition temperature of the polymer (A) within 5 minutes, and are of good thermal shelf stability and electrical properties and provide toner binders of high hot offset causing temperature and improved low temperature fixing properties.Type: GrantFiled: March 15, 1994Date of Patent: March 5, 1996Assignee: Sanyo Chemical Industries, Ltd.Inventors: Masaharu Nishida, Tohru Ohhama
-
Patent number: 5486562Abstract: Compositions are provided which comprise (A) a polyester resin which comprises the reaction product of at least one straight chain, branched, or cycloaliphatic C.sub.2 -C.sub.10 alkane diol or chemical equivalent thereof, and a cycloaliphatic diacid or chemical equivalent thereof; and (B) an effective impact strength or tensile property modifying amount of a substantially amorphous copolymer resin. These compositions are homogeneous and exhibit excellent light stability, chemical resistance, particularly to gasoline and similar automotive chemicals, excellent impact strength even at low temperatures and excellent tensile properties.Type: GrantFiled: August 2, 1994Date of Patent: January 23, 1996Assignee: General Electric CompanyInventors: Willem F. H. Borman, Nan-I Liu
-
Patent number: 5466754Abstract: A curable resin composition utilizing as the crosslinking mechanism thereof an acid catalyzed addition reaction of a cyclic alkylenecarbonate group with an alcoholic hydroxyl group is disclosed. The composition contains a compound or polymer having a plurality of 6-membered cyclic alkylenecarbonate groups and a polymer having a plurality of alcoholic hydroxyl groups. A polymer having pluralities of the cyclic alkylenecarbonate and hydroxyl groups in a single entity may also be used. The composition cures at room or elevated temperatures depending upon the acidity and amount of particular acid catalyst incorporated to the composition.Type: GrantFiled: January 27, 1995Date of Patent: November 14, 1995Assignees: Nippon Paint Co., Ltd., Daicel Chemical Industries, Ltd.Inventors: Takao Morimoto, Shinji Nakano
-
Patent number: 5455304Abstract: Compositions are disclosed that are the urea derivatives of succinylated polyolefins (maleated polyolefins). The urea derivatives of succinylated polyolefins are of the formula; ##STR1## wherein R is a polyolefin attached at any point along the hydrocarbon chain. The urea derivative of succinylated polyolefins is useful as a coupling agent to couple polyolefins with dissimilar polymers having an excess of unreacted acid groups such as polyesters.Type: GrantFiled: February 27, 1995Date of Patent: October 3, 1995Assignee: Eastman Chemical CompanyInventor: Thomas D. Roberts
-
Patent number: 5436296Abstract: Compositions comprising polyalkylene terephthalate, polyethylene and a compatibilizer copolymer of a C.sub.2 -C.sub.10 alpha-olefin and a glycidyl or isocyanate group-containing functional compound, wherein the functional compound comprises about 0.4 to about 50 weight percent of the compatibilizer copolymer, provide improved impact properties and heat resistance. The compositions feature improved compatibility of polyalkylene terephthalate and polyethylene, and are useful in forming a wide variety of articles therefrom.Type: GrantFiled: March 31, 1994Date of Patent: July 25, 1995Assignee: AlliedSignal Inc.Inventors: A. Xavier Swamikannu, Murali K. Akkapeddi
-
Patent number: 5419929Abstract: Thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating, a specific vinyl ether or vinyl thioether and a thermal latent acid catalyst. The blocked carboxyl group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule. The thermosetting composition gives cured products having excellent chemical properties, physical properties, weathering resistance and storage stability and is advantageously utilized for coating compositions, ink, adhesive and molded plastics.Type: GrantFiled: September 21, 1992Date of Patent: May 30, 1995Assignee: Nippon Oil and Fats Company, LimitedInventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
-
Patent number: 5414036Abstract: Molding compositions of thermoplastic polyesters and polymeric nucleating additives having pendant ionizable alkali metal phenolate groups. A process for increasing the crystallization rate and crystallization temperature of thermoplastic polyesters by incorporating into the polyesters the polymeric nucleating additives of the present invention.Type: GrantFiled: April 12, 1993Date of Patent: May 9, 1995Assignee: Enichem S.p.A.Inventor: John W. Gilmer
-
Patent number: 5408002Abstract: An azlactone-functional thermoplastic composition is disclosed. The composition is a blend of an azlactone-functional composition and a thermoplastic polymer. A method of making azlactone-functional homopolymers by bulk homopolymerization is disclosed, optionally also concurrent or sequential blending of a thermoplastic polymer. A method of blending azlactone-functional compositions and thermoplastic polymers is disclosed. Molded articles and adduct molded articles formed from the thermoplastic composition are disclosed.Type: GrantFiled: September 9, 1993Date of Patent: April 18, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: Patrick L. Coleman, Steven M. Heilmann, Steven L. Kangas, Robert H. Menzies, Jerald K. Rasmussen, Richard J. Rolando, Jennifer J. Sahlin, Julie B. Stahl
-
Patent number: 5405909Abstract: A thermoplastic elastomer composition which is useful for bumper, boot, sound absorbing gear, sports shoes etc. is provided by mixing the following (A)-(D).A: 30-58 parts by wt of saturated polyester resin,B: 42-70 parts by wt of an epoxy group-containing ethylene copolymer ofa) 50-99% by wt of ethylene unit,b) 0.1-30% by wt of unsaturated carboxylic acid glycidyl ester unit or unsaturated glycidyl ether unit andc) 0-49% by wt of ethylenically unsaturated ester unitC: 0.01-20 parts by wt of specific polyfunctional compound containing two or more functional groups, andD: 1-30 parts by wt of block copolyether ester elastomer.The amounts of C and D are based on 100 parts of A and B.Type: GrantFiled: October 26, 1993Date of Patent: April 11, 1995Assignee: Sumitomo Chemical Co., Ltd.Inventors: Tadayuki Ohmae, Yoshiki Toyoshima, Kentaro Mashita, Noboru Yamaguchi, Kenzo Chikanari
-
Patent number: 5397839Abstract: Elastomeric compositions having improved heat aging properties are provided by blends of thermoplastic polyester resin and hydrogenated nitrile rubber. The rubber component of the composition is at least partially cured.Type: GrantFiled: December 13, 1993Date of Patent: March 14, 1995Assignee: Advanced Elastomer Systems, L.P.Inventor: Raman Patel
-
Patent number: 5393583Abstract: A connector comprising a housing comprising a resin composition comprising (A) from 30 to 90% by weight of an aromatic polyester, (B) from 5 to 40% by weight of a modified polyolefin, and (C) from 5 to 30% by weight of a polyglutarimide having a repeating unit represented by the following formula (1): ##STR1## wherein R.sup.1 and R.sup.2 each represents a hydrogen atom or a lower alkyl group, and R.sup.3 represents a hydrogen atom, an alkyl group, an aryl group, an alkaryl group, or an aralkyl group.Type: GrantFiled: May 19, 1993Date of Patent: February 28, 1995Assignee: Yazaki CorporationInventors: Tetsuo Kato, Masahiro Kanda
-
Patent number: 5376711Abstract: A poly(ethylene 2,6-naphthalate) film obtained by stretching a poly(ethylene 2,6-naphthalate) sheet containing cross-linked polymer particles which have at least one ethylene glycol unit and have an average particle size of from 0.05 to 3 .mu.m and a spherical ratio of from 1.0 to 1.1, wherein a deformation ratio of the cross-linked polymer particles in the stretching is from 1.2 to 3.0, has excellent runnability, abrasive resistance and strength.Type: GrantFiled: March 24, 1993Date of Patent: December 27, 1994Assignee: Diafoil Hoechst Company, LimitedInventors: Masahiko Fujimoto, Kazuhiro Kunugihara
-
Patent number: 5359005Abstract: Stable, non-gelled, one-package coating compositions capable of being cured at ambient conditions to produce durable coatings comprising at least one polymer and/or oligomer having a molecular weight of at least about 100 and bearing at least two specific aziridine moieties, at least two specific carbodiimide moieties or combinations thereof and at least one polymer and/or oligomer having a molecular weight of at least about 100 and bearing at least two covalently blocked carboxylic acid moieties. Process for coating a substrate using such compositions are also claimed.Type: GrantFiled: December 29, 1992Date of Patent: October 25, 1994Assignee: PPG Industries, Inc.Inventors: Charles M. Kania, Padmanabhan Sundararaman, David T. McKeough, Gregory J. McCollum, James B. O'Dwyer
-
Patent number: 5354620Abstract: The invention relates to polymer mixtures which comprise a polyalkylenephthalate ester and a cyclic imino ether functionalized polystyrene. Layers can be manufactured from these mixtures. Said layers show a good bonding to layers of polystyrene.Type: GrantFiled: July 9, 1993Date of Patent: October 11, 1994Assignee: General Electric Co.Inventors: Wilhelmus J. L. A. Hamersma, Roger W. Avakian
-
Patent number: 5352740Abstract: Thermosetting composition is excellent in storage stability, useful as one component thermosetting composition, gives cured products having excellent chemical properties, physical properties and weathering resistance and is favorably utilized in coating compositions, ink, adhesive and molded plastics.The thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating and optionally a thermal latent acid catalyst. The blocked carboxyl group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule.Type: GrantFiled: April 4, 1991Date of Patent: October 4, 1994Assignee: Nippon Oil and Fats Company, LimitedInventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
-
Patent number: 5332780Abstract: Thermoplastic resin compositions having the following component A-1 or A-2, component B and component C:(A-1): a polymer component having a functional group capable of reacting with an amino group, or(A-2): a composition of component (A-1) and a resin that is non-reactive with an amino group and is different from the resin used in the following component B(B) a thermoplastic resin component that is non-reactive with an amino group under the conditions required to mold the entire resin composition; and(C) a graft copolymer obtained by a graft reaction of a thermoplastic polymer, with a compound (I), or a copolymer having the repeating unit (II) and the repeating unit of an ethylenic unsaturated monomer, ##STR1## wherein R.sup.1 -R.sup.4, the same or different represent a hydrogen atom, an alkyl group, a cycloalkyl group, an aryl group or an aralkyl group.Type: GrantFiled: April 8, 1993Date of Patent: July 26, 1994Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.Inventors: Naoki Kitazawa, Manabu Kikuta, Hiroshi Hotta, Yutaka Nakayama, Hideyuki Sumi
-
Patent number: 5306785Abstract: Compositions are provided which comprise a polyester resin which comprises the reaction product of at least one straight chain, branched, or cycloaliphatic C.sub.2 -C.sub.10 alkane diol or chemical equivalent thereof; and a cycloaliphatic diacid or chemical equivalent thereof; and a poly(ether ester) elastomer, a poly(etherimide ester) elastomer, a copolymer elastomer comprising (ether ester) monomers and (etherimide ester) monomers, a copolymer comprising ethylene and one or more comonomers copolymerizable therewith to provide a solid copolymer, or a combination of any of the foregoing. These compositions have excellent tensile properties.Type: GrantFiled: October 5, 1992Date of Patent: April 26, 1994Assignee: General Electric CompanyInventors: Willem F. H. Borman, Nan-I Liu
-
Patent number: 5296551Abstract: The present invention provides(1) a self-crosslinking resin (I) having a blocked isocyanate group and a hydroxyl group in the molecule and characterized in that the resin is prepared from a vinyl polymer (A) having at least two free isocyanate groups in the molecule and a polyester resin (B) having at least two hydroxyl groups in the molecule by reacting some of the hydroxyl groups of the resin (B) with some of the free isocyanate groups of the polymer (A), and subsequently reacting a blocking agent with all the remaining free isocyanate groups, and(2) a self-crosslinking resin (II) having a blocked isocyanate group and a hydroxyl group in the molecule and characterized in that the resin is prepared from a vinyl polymer (C) having a free isocyanate group and a blocked isocyanate group in the molecule and the polyester resin (B) having at least two hydroxyl groups in the molecule by reacting some of the hydroxyl groups of the resin (B) with all the free isocyanate groups of the polymer (C).Type: GrantFiled: July 27, 1993Date of Patent: March 22, 1994Assignee: Kansai Paint Company, LimitedInventors: Yoshiyuki Yukawa, Motoshi Yabuta, Akimasa Nakahata, Kazunori Mayumi
-
Patent number: 5296529Abstract: The present invention provides (1) a self-crosslinking resin (I) having a carboxyl group, a blocked isocyanate group and a hydroxyl group in the molecule and characterized in that the resin is prepared from a vinyl polymer (A) having at least two free isocyanate groups in the molecule and a polyester resin (B) having at least two hydroxyl groups and at least one carboxyl group in the molecule by reacting some of the hydroxyl groups of the resin (B) with some of the free isocyanate groups of the polymer (A), and subsequently reacting a blocking agent with all the remaining free isocyanate groups, and (2) a self-crosslinking resin (II) having a carboxyl group, a blocked isocyanate group and a hydroxyl group in the molecule and characterized in that the resin is prepared from a vinyl polymer (C) having a free isocyanate group and a blocked isocyanate group in the molecule and the polyester resin (B) having at least two hydroxyl groups and at least one carboxyl group in the molecule by reacting some of the hydroxType: GrantFiled: August 3, 1993Date of Patent: March 22, 1994Assignee: Kansai Paint Company, LimitedInventors: Yoshiyuki Yukawa, Motoshi Yabuta, Akimasa Nakahata, Kazunori Mayumi
-
Patent number: 5276089Abstract: There is disclosed a blend of certain polyesters and polymers that are miscible with polystyrene, such as polyphenylene oxide. The blend is characterized by the presence of a compatibilizing amount of a copolymer having repeating units derived from an aromatic vinyl compound monomer and a vinylphenol monomer. The polyester is thermoplastic and is characterized in that the diacid component of the polyester includes aromatic groups and the diol component comprises at least about 20 percent by weight of a noncyclic, aliphatic diol.Type: GrantFiled: August 26, 1991Date of Patent: January 4, 1994Assignee: Eastman Kodak CompanyInventors: Ralph H. Colby, Christine J. T. Landry, Michael R. Landry, Timothy E. Long, Dennis J. Massa, David M. Teegarden
-
Patent number: 5268412Abstract: Disclosed are polymer blends of polyesters or polyesteramides and a polymer containing an acrylamide sulfonate monomer. The blends are preferably prepared by polymerizing monomers in the presence of the polyester or polyesteramide. The blends impart superior freeze-thaw stability to aqueous compositions such as inks.Type: GrantFiled: November 21, 1990Date of Patent: December 7, 1993Assignee: Eastman Kodak CompanyInventor: Peter W. Raynolds
-
Patent number: 5260378Abstract: The invention relates to a block copolymer according to the general formula A-b-B on the basis of a furan derivative as binding group (b) and the process for the preparation hereof. The furan derivative as binding group (b) is a compound according to formula (I). ##STR1## The block copolymer can simply be prepared in one single reactor and is suitable for use as compatibilizer.Type: GrantFiled: January 18, 1990Date of Patent: November 9, 1993Assignee: Stamicarbon B.V.Inventors: Alessandro Gandini, Marie C. Salon
-
Patent number: 5253871Abstract: The invention concerns a golf ball constituted of a three part structure, constituted of an elastomer core, an intermediate layer, and a thermoplastic envelope. The intermediate layer is made of a thermoplastic material containing at least 10%, and preferably at least 35% of ether block copolymer. The material may also be advantageously constituted of ether block copolymer to which is added 0 to 90% of ionomer(s) with respect to the total weight of the compound.Type: GrantFiled: August 14, 1991Date of Patent: October 19, 1993Assignee: Taylor Made Golf Company, Inc.Inventor: Francois Viollaz
-
Patent number: 5240999Abstract: A resin composition which includes (A) 100 parts of a blend of a polyacrylate and a poly(alkylene-phenylene ester) and (B) 1-50 parts of a chemically modified polyolefin copolymer exhibits superior impact resistance, particularly low temperature impact resistance, while retaining good melt viscosity for molding. The polyacrylate may be produced by polymerizing a dihydric phenol formula I: ##STR1## with an aromatic dicarboxylic acid, a dichloride derivative, an alkylated derivative or an arylated derivative thereof. The chemically modified polyolefin copolymer has a structural unit containing at least one amide group at and at least one glycidyloxy or glycidyl group, with the number of the structural unit contained in the copolymer being one per from 4 to 5,000 carbon atoms of the polyolefin moiety.Type: GrantFiled: June 2, 1992Date of Patent: August 31, 1993Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaishaInventors: Noriyuki Suzuki, Haruo Tomita, Masahiro Asada
-
Patent number: 5223578Abstract: Polymers containing glutarimide units and also acid and/or anhydride units are compatible with polyesters, such as poly(ethylene terephthalate) to form blends. Chemical interaction (grafting) between the polyester and the acid/anhydride groups of the polyglutarimide occurs on processing the blends. The extent of grafting and the properties of the resultant blend can be enhanced by appropriate catalysts.Type: GrantFiled: February 21, 1991Date of Patent: June 29, 1993Assignee: Rohm and Haas CompanyInventor: Michael P. Hallden-Abberton
-
Patent number: 5214101Abstract: A thermosetting powder coating composition which has good handling properties and which has a good bland of physical properties such as appearance, flexibility, hardness, solvent resistance, corrosion resistance and exterior durability is disclosed. The composition comprises a co-reactable particulate mixture of a carboxylic acid group-containing acrylic polymer, a second carboxylic acid group-containing polyurethane having sufficient crystallinity to assist in flow of the powder coating compositions, a beta-hydroxyalkylamide crosslinking agent and an amorphous acid group-containing polyurethane.Type: GrantFiled: August 24, 1992Date of Patent: May 25, 1993Assignee: PPG Industries, Inc.Inventors: Paul H. Pettit, Jr., Debra L. Singer, Marvin L. Kaufman
-
Patent number: 5202384Abstract: It is often desirable to increase the modulus of rubbers utilized in a wide variety of applications. This invention discloses a technique for modifying rubbers to improve their modulus without sacrificing other properties. By utilizing the process of this invention, rubber compositions having increased modulus are prepared by grafting polyester onto rubber. This can be accomplished by reacting a polydiene rubber with a thioacid or maleic anhydride and subsequently with the polyester. It is also possible to prepare such polyester modified rubber compositions by reacting an epoxidized rubber with the polyester.Type: GrantFiled: November 7, 1990Date of Patent: April 13, 1993Assignee: The Goodyear Tire & Rubber CompanyInventors: James B. Pyle, Richard G. Bauer, Donald J. Burlett
-
Patent number: 5194506Abstract: Polyethylene terephthalate molding compositions are provided which comprise polyethylene terephthalate, an aliphatic polyester, a warp resisting amount of an arylene sulfide copolymer, filler, and optionally, colorants.Type: GrantFiled: December 20, 1990Date of Patent: March 16, 1993Assignee: Phillips Petroleum CompanyInventors: Howard F. Efner, Michael C. Yu, Ray D. Ramsay
-
Patent number: 5182337Abstract: A thermosetting powder coating composition which has good handling properties and which has a good blend of physical properties such as appearance, flexibility, hardness, solvent resistance, corrosion resistance and exterior durability is disclosed. The composition comprises a co-reactable particulate mixture of a carboxylic acid group-containing acrylic polymer, a second carboxylic acid group-containing polyester having sufficient crystallinity to assist in flow of the powder coating compositions, a beta-hydroxyalkylamide crosslinking agent and an amorphous acid group-containing polyester.Type: GrantFiled: October 16, 1991Date of Patent: January 26, 1993Assignee: PPG Industries, Inc.Inventors: Paul H. Pettit, Jr., Debra L. Singer, Marvin L. Kaufman
-
Patent number: 5179162Abstract: As N-substituted maleimide polymer composition contains 20 to 90 parts by weight of an N-substituted maleimide polymer and 80 to 10 parts by weight of a thermoplastic resin selected from a polycarbonate polymer, a polysulfone polymer, a polyphenylene ether polymer, a polyarylene sulfide polymer, and a modified polymer of the polymer or polymers, a polyoxymethylene polymer, a polyester polymer, a polyamide polymer and mixtures thereof.Type: GrantFiled: June 10, 1991Date of Patent: January 12, 1993Assignee: Nippon Oil & Fats Co., Ltd.Inventors: Kenji Kato, Yasumi Koinuma, Kazunori Doiuchi, Seigo Kinoshita, Yukinori Haruta
-
Patent number: 5166267Abstract: It is desirable to increase the modulus of rubbers utilized in a wide variety of applications. For example, it is typically desirable to increase the modulus of rubber compounds which are utilized in tire tread base compositions and in tire wire coat compounds. Unfortunately, most conventional techniques for increasing the modulus of a rubber compound are detrimental to other rubber properties, such as hysteresis and cut growth resistance. By utilizing the techniques of this invention rubber compounds can be prepared which exhibit high tensile strength, high modulus, and good cut growth resistance. The subject invention specifically relates to a process for preparing a highly dispersed blend of a polyester in an elastomer which comprises (1) blending a solution of a rubber in an organic solvent with a solution of a polyester in an organic solvent to produce a dispersion containing said rubber and said polyester, and (2) recovering the highly dispersed blend from the dispersion.Type: GrantFiled: September 17, 1990Date of Patent: November 24, 1992Assignee: The Goodyear Tire & Rubber CompanyInventors: Gerald Cohn, Douglas D. Callander, William C. T. Tung
-
Patent number: 5134194Abstract: Thermoplastic resin composition comprising the following components A and B is presented which improves the compatibility of component resins, to achieve a thermoplastic resin having excellent molding property and mechanical strength:A. 90 to 10 wt % of a polyolefin resin containing a substituted silyl group represented by general formula;--SiR.sub.n Y.sub.3-n(wherein, R is aliphatic hydrocarbon group; Y is hydrolyzable group or hydroxyl group; n represents 0, 1 or 2), andB. 10 to 90 wt % of saturated polyester resin or hydroxyalkylated polycarbonate resin or hydroxyalkylated polyphenylene ether resin.Type: GrantFiled: January 23, 1991Date of Patent: July 28, 1992Assignee: Mitsubishi Petrochemical Co., Ltd.Inventors: Takayuki Inoue, Yusuke Arashiro, Shin-ichi Yamauchi, Michiharu Kihira, Haruo Ohmura, Fumiyoshi Yamada
-
Patent number: 5132361Abstract: Ethylenically unsaturated cyclic ortho esters are prepared by the reaction of a hydroxy-substituted cyclic ortho ester such as 4-hydroxymethyl-2-methoxy-2-methyl-1,3-dioxolane with acryloyl chloride, methacryolyl choride, vinylbenzyl chloride or the like. They form polymers, especially EPDM graft copolymers, which are useful in the formation of copolymer-containing compositions with polyesters, polyamides and the like. The copolymer-containing compositions have excellent physical properties and may be employed to compatabilize blends of the same polymers.Type: GrantFiled: January 24, 1991Date of Patent: July 21, 1992Assignee: General Electric CompanyInventors: Timothy J. Shea, Andra J. Moffett, John R. Campbell, Marinus E. J. Dekkers, Farid F. Khouri
-
Patent number: 5132368Abstract: The subject invention provides a composition having excellent extrusion characteristics comprising a difficulty-melt-processible polymer and 0.002-0.5 wt. % of one or more fluoropolymer process aids wherein the fluoropolymer has a fluorine to carbon ratio of at least 1:2, is capable of forming a die-coating film under the prevailing conditions of extrusion temperature and pressure, and contains an effective amount of polar functional polymer chain end groups, --W, wherein --W is selected from --COF, --SO.sub.2 F, --SO.sub.3 M, --OSO.sub.3 M, --COOR, and --COOM, wherein R is C.sub.1-3 alkyl and M is hydrogen, a metal cation, preferably an alkali or alkaline earth metal cation, or a quaternary ammonium cation.Type: GrantFiled: September 3, 1991Date of Patent: July 21, 1992Assignee: E. I. Du Pont de Nemours and CompanyInventors: George R. Chapman, Jr., Donnan E. Priester, Charles W. Stewart, Robert E. Tarney
-
Patent number: 5124176Abstract: A powder coating composition comprises a component (A) containing carboxylic acid or anhydride functionality and a component (B) containing hydroxy functionality. The components (A) and (B) are both solids at temperatures up to 50.degree. C. and at least one of them is a synthetic resin having a glass transition temperature in the range 0.degree. to 120.degree. C. The carboxylic acid or anhydride-functional component (A) is a compound or polymer containing at least two cyclic carboxylic anhydride groups per molecule or is a compound containing a moiety of the formula: ##STR1## where X is a hydrogen atom or an alkyl group, or a cyclic anhydride thereof. The hydroxy-functional component (B) contains at least two hydroxy groups per molecule and contains at least one amine group in its molecule to catalyze the reaction of the carboxylic acid or anhydride groups of component (A) with the hydroxy groups of component (B).Type: GrantFiled: May 3, 1989Date of Patent: June 23, 1992Assignee: International Paint public limited companyInventor: Alastair R. Marrion
-
Patent number: 5115022Abstract: Impact modified thermoplastic blends of components A, B and optionally C, consisting of:A) from 99 to 60 percent by weight of a polymeric rigid matrix consisting of polybutylene terephthalate or polyethylene terephthalateB) from 1 to 40 percent by weight of a polymeric flexibilizing component comprisingb1) 100-60 percent by weight of a monomer from the group of the 1,3-dienes which is present as copolymerized units andb2) 0-40 percent by weight of an aromatic vinyl compound present as copolymerized units andC) optionally customary additives in customary amounts, the polymers of flexibilizing component B having amino end groups, are used for producing moldings.Type: GrantFiled: February 20, 1990Date of Patent: May 19, 1992Assignee: BASF AktiengesellschaftInventors: Klaus Bronstert, Hans-Dieter Schwaben, Adolf Echte
-
Patent number: 5106897Abstract: A method for improving the low temperature impact strength of a thermoplastic polyblend of PETG and SAN which method comprises incorporating therein an effective amount of a dispersant selected from the group consisting of mono- and di-carboxylic acids containing 6 to 36 carbon atoms; alkali and alkaline-earth metal salts and amides of such acids; and aliphatic alcohols containing 6 to 36 carbon atoms.Type: GrantFiled: February 20, 1990Date of Patent: April 21, 1992Assignee: Monsanto CompanyInventors: James Y. Chen, Donald B. Baldridge
-
Patent number: 5096968Abstract: A thermoplastic methacrylimide-containing polymer comprising 2 to 100% by weight of structural units represented by the following formula (I): ##STR1## wherein R is hydrogen or a hydrocarbon group having 1 to 20 carbon atoms, and 0 to 98% by weight of structural units derived from an ethylenically unsaturated monomer, wherein the content of iron in the polymer is not larger than 20 ppm and the difference between the maximum value and minimum value of the degree of imidization is preferably not larger than 5% by weight. This methacrylimide-containing polymer is used alone or as a blend thereof with another thermoplastic polymer.Type: GrantFiled: December 28, 1989Date of Patent: March 17, 1992Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Isao Sasaki, Kozi Nishida, Hisao Anzai, Masaharu Fujimoto
-
Patent number: 5091478Abstract: Partially grafted flexible thermoplastic compositions formed by melt blending under high shear, a thermoplastic material having available graft sites, said thermoplastic material being at least one continuous phase of the composition, an ethylene copolymer containing an unsaturated mono-carboxylic acid, and a polymeric grafting agent having reactive groups capable of reacting with the mono-carboxylic acid in the ethylene copolymer and with the available graft sites in the thermoplastic material. These compositions have use in a wide range of molding, coating and adhesive applications, including various automotive applications, wire and cable coating applications and high temperature adhesive applications.Type: GrantFiled: May 21, 1990Date of Patent: February 25, 1992Assignee: E. I. Du Pont de Nemours and CompanyInventor: Robert P. Saltman
-
Patent number: 5068283Abstract: Disclosed is a method for producing a thermoplastic resin composition which can be easily molded into articles having good balance in properties and good appearance. Said method comprises melt-kneading (A) 60-97 parts by weight of a saturated polyester resin and (B) 40-3 parts by weight of an epoxy group-containing ethylene copolymer and then melt-kneading the resulting composition with (C) 0.01-20 parts by weight of a polyfunctional compound containing in one molecule at least two functional groups having reactivity with epoxy group, carboxyl group or hydroxyl group to carry out partial crosslinking reaction.Type: GrantFiled: March 12, 1990Date of Patent: November 26, 1991Assignee: Sumitomo Chemical Co., Ltd.Inventors: Tadayuki Ohmae, Yoshiki Toyoshima, Kentaro Mashita, Jinsho Nambu
-
Patent number: 5066695Abstract: High-molecular weight organic material containing at least one metal complex of a ligand of formula I: ##STR1## wherein A is a carbocyclic aromatic or heterocyclic aromatic radical, B is a carbocyclic aromatic radical or a heterocyclic aromatic radical containing at least one N atom, it being necessary for at least one of the radicals A and B to be heterocyclic, and R.sub.1 is --C.sub.1 -C.sub.18 -alkyl, a carbocyclic aromatic radical or a heterocyclic aromatic radical containing at least one N atom, and the metal is a transition metal cation carrying a double positive charge selected from Ni.sup.2+, Cu.sup.2+, Co.sup.2+, Zn.sup.2+, Mn.sup.2+, Fe.sup.2+, Cd.sup.2+ or Pt.sup.2+ or the radical VO.sup.2+.Type: GrantFiled: June 29, 1989Date of Patent: November 19, 1991Assignee: Ciba-Geigy CorporationInventors: Georg Cseh, Paul Lienhard, Walter Wiedemann
-
Patent number: 5051475Abstract: The present invention is directed to a polyester film comprising at least at its surface portion oriented sulfonic acid groups and/or salts thereof with an orientation degree of 5-100, which has an excellent adhesiveness, especially excellent anti-alkaline adhesiveness. The present invention also makes it possible to provide a polyester film having, in addition to the excellent adhesiveness, an excellent transparency, antistatic property and waterproof property.Type: GrantFiled: December 20, 1989Date of Patent: September 24, 1991Assignee: Toray Industries, Inc.Inventors: Kenji Tsunashima, Takashi Mimura, Takashi Sumiya, Hiroshi Kuboyama
-
Patent number: 5047470Abstract: Thermoplastic polymer compositions comprise a thermoplastic copolyether-ester elastomer, a rubber graft polymer and a rigid polymer. The rigid polymer is formed from one or more monomers selected from styrene, .alpha.-methyl styrene and halogen-substituted styrenes, at least 20 weight percent acrylonitrile, and N-phenyl maleimide, and is included in the compositions to provide improved impact strength and tensile elongation without significantly deteriorating other physical properties of the compositions.Type: GrantFiled: July 28, 1989Date of Patent: September 10, 1991Assignee: General Electric CompanyInventors: David Whalen, Oliver P. Creecy
-
Patent number: 5037889Abstract: A resin composition comprising:(i) at least one aromatic carbonate resin;(ii) at least one polyester resin; and(iii) an impact improving effective amount of at least one two-phase interpolymer comprised of at least one cross-linked polyacrylate and at least one cross-linked styrene-acrylonitrile resin.Type: GrantFiled: January 12, 1990Date of Patent: August 6, 1991Assignee: General Electric CompanyInventors: Angelika H. McHale, Warren J. Peascoe
-
Patent number: RE34791Abstract: Polymer bound hindered amine light stabilizers are prepared by reacting hindered amine light stabilizers containing reactive hydrazide functionalities with anhydride containing polymers or copolymers. The reactions may be carried out in an inert solvent or in a melt blending step. The polymer bound hindered amine light stabilizers are useful alone or may also be used to stabilize other polymers, copolymers or polymers blends against the deleterious effects of heat and/or light.Type: GrantFiled: July 16, 1991Date of Patent: November 15, 1994Assignee: Atochem North America, Inc.Inventors: Robert T. Kazmierzak, Ronald E. MacLeay