Solid Polymer Derived From Ethylenic Reactants Only Derived From At Least One Reactant Containing An Atom Other Than C, H, O, Or Hal Patents (Class 525/175)
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Patent number: 5006604Abstract: A blend of a terephthalic acid/ethylene glycol/cyclohexanedimethanol copolyester and an acrylonitrile/butadiene/styrene copolymer is disclosed. This blend possesses high notched Izod impact strength while maintaining a good balance of flexural modulus properties, tensile properties, heat diffusion temperature properties and hardness properties. This blend is useful in making automotive and appliance components.Type: GrantFiled: September 11, 1989Date of Patent: April 9, 1991Assignee: Eastman Kodak CompanyInventor: Kenneth A. Romance
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Patent number: 5004777Abstract: Glutarimide polymers having an acid and anhydride content lower than the acid and/or anhydride content normally present in the glutarimide polymers. Blends of the reduced acid and anhydride glutarimide polymers with thermoplastic materials are disclosed. A process for altering the properties of imide polymers by reducing or substantially removing acid and anhydride levels normally present in the imide polymer is also disclosed.Type: GrantFiled: May 24, 1990Date of Patent: April 2, 1991Assignee: Rohm and Haas CompanyInventors: Michael P. Hallden-Abberton, Newman M. Bortnick, Leslie A. Cohen, William T. Freed, Harry C. Fromuth
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Patent number: 4996262Abstract: It is often desirable to increase the modulus of rubbers utilized in a wide variety of applications. This invention discloses a technique for modifying rubbers to improve their modulus without sacrificing other properties. By utilizing the process of this invention, rubber compositions having increased modulus are prepared by grafting polyester onto rubber. This can be accomplished by reacting a polydiene rubber with a thioacid or maleic anhydride and subsequently with the polyester. It is also possible to prepare such polyester modified rubber compositions by reacting an epoxidized rubber with the polyester.Type: GrantFiled: March 27, 1989Date of Patent: February 26, 1991Assignee: The Goodyear Tire & Rubber CompanyInventors: James B. Pyke, Richard G. Bauer, Donald J. Burlett
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Patent number: 4987172Abstract: A flame-retardant synthetic resin composition comprising a thermoplastic resin selected from the group consisting of polyolefin, acrylonitrile-butadiene-styrene copolymer and ethylene-ethyl acrylate copolymer resins as a base polymer and, incorporated therein (A) a polyester fiber cut into a length smaller than 10 mm and/or a polyester powder having a particle size smaller than 10 mesh and (B) a polyphosphoric acid compound having a higher water resistance, wherein the amount of the thermoplastic resin is 40 to 95% by weight, the total amount of the components (A) and (B) is 5 to 60% by weight and the component (A)/component (B) weight ratio is in the range of from 5/1 to 1/20.Type: GrantFiled: October 28, 1988Date of Patent: January 22, 1991Assignee: Marubishi Oil Chemical Co., Ltd.Inventors: Ken Higashitsuji, Hiroshi Kimoto, Yasunobu Takahashi, Teruhisa Kojima, Yutaka Nadehara
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Patent number: 4987187Abstract: A molding composition prepared from a blend of: (A) a copolyester of a dicarboxylic acid moiety, such as terephthalic acid or dimethyl terephthalate and a dihydric alcohol moiety, such as ethylene glycol in combination with diethylene glycol or 1,4-cyclohexanedimethanol, and (B) a copolymer prepared from a styrenic monomer and an ethylenically unsaturated nitrile, wherein articles molded from such compositions have improved clarity and toughness.Type: GrantFiled: December 20, 1989Date of Patent: January 22, 1991Assignee: Monsanto CompanyInventors: Kishore Udipi, Allen R. Padwa
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Patent number: 4962157Abstract: Thermoplastic molding materials contain(A) not less than 5% by weight of a polymer component consisting of from 50 to 10 % by weight by polyphenylene ethers and from 0 to 50% by weight of a styrene polymer differing from component (C),(B) not less than 5% by weight of a polyester,(C) not less than 0.1% by weight of a copolymer consisting of(C.sub.1) not less than 20% by weight of .alpha.-olefins of 2 to 8 carbon atoms, styrene or substituted styrenes of the general formula I ##STR1## where R and R.sup.1 is alkyl of 1 to 8 carbon atoms, hydrogen and/or halogen and n is 0, 1 or 2, or a mixture of these monomers,(C.sub.2) not less than 0.5% by weight of a polymerizable monomer containing epoxide groups,and/or(C.sub.3) not less than 0.05% by weight of a halobenzyl-containing polymerizable monomer having the structural unit (II) ##STR2## where X is halogen and R.sup.2 and R.sup.3 are each alkyl of 1 to 8 carbon atoms or hydrogen and n is 1, 2 or 3,and/or(C.sub.4) not less than 0.Type: GrantFiled: June 20, 1988Date of Patent: October 9, 1990Assignee: BASF AktiengesellschaftInventors: Christof Taubitz, Erhard Seiler, Klaus Boehlke, Dietrich Lausberg
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Patent number: 4959434Abstract: Modified impact-resistant vinylaromatic copolymers containing from 2 to 10% by weight of an ethylenically unsaturated nutrile and from 0 to 30% by weight of alpha-methyl-styrene and having a gel content higher than 23%, a cracking resistance, in an olive oil/oleic acid mixture under a load of 10 MPa, higher than 100 min., and a melt index below 1.5 g/10 minutes.Type: GrantFiled: December 28, 1989Date of Patent: September 25, 1990Assignee: Montedison S.p.A.Inventors: Gianfranco Biglione, Savino Matarrese
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Patent number: 4937280Abstract: Blends based on vinyl-aromatic polymers having high tenacity and impact strength, comprising:a vinyl-aromatic copolymer containing from 2 to 25% by weight of an ethylenically unsaturated nitrile and a rubber amount not higher than 15% by weight; anda grafted polymer consisting of an elastomeric core having a transition temperature of the second order lower than 10.degree. C. containing, in the grafted form, chains of vinyl monomers.Type: GrantFiled: January 31, 1989Date of Patent: June 26, 1990Assignee: Montedipe S.p.A.Inventor: Gianfranco Biglione
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Patent number: 4937288Abstract: A thermosetting powder coating composition which has good handling properties and which has a good blend of physical properties such as appearance, flexibility, hardness, solvent resistance, corrosion resistance and exterior durability is disclosed. The composition comprises a co-reactable particulate mixture of a carboxylic acid group-containing acrylic polymer, a second carboxylic acid group-containing material having sufficient crystallinity to assist in flow of the powder coating compositions and a beta-hydroxalkylamide crosslinking agent.Type: GrantFiled: September 18, 1989Date of Patent: June 26, 1990Assignee: PPG Industries, Inc.Inventors: Paul H. Pettit, Jr., Debra L. Singer, Marvin L. Kaufman
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Patent number: 4931502Abstract: Moldable blends of rubber modified styrene/maleic anhydride copolymer, core-shell graft copolymer modified polybutylene terephthalate ester, and styrene-maleimide copolymer having pendant carboxyl or hydroxyl groups are provided. The compositions of this invention exhibit co-continuous resin phases and facilitate the production of blow molded articles which exhibit ductility.Type: GrantFiled: October 11, 1988Date of Patent: June 5, 1990Assignee: Arco Chemical Technology, Inc.Inventor: Russell J. McCready
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Patent number: 4902748Abstract: Polymeric blends containing 20-80% by weight of a modified vinyl-aromatic polymer containing from 5 to 15% by weight of a ethylenically unsaturated nitrile, and 80-20% by weight of at least one resin containing aromatic groups selected from aromatic polycarbonates and crystalline aromatic polyesters.Type: GrantFiled: March 10, 1988Date of Patent: February 20, 1990Assignee: Montedison, S.p.A.Inventors: Gianfranco Biglione, Gian C. Fasulo
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Patent number: 4898765Abstract: An impregnation-printed molded article comprises an article molded of a composition consisting of a thermoplastic polyester resin (A) and, in mixture therewith, a thermoplastic polymer compound (B) containing as a polymer skelton component unit at least one kind of material from the group consisting of butadienes, styrenes, acrylonitriles, and acrylates, said molded article being impregnation-printed.Type: GrantFiled: October 8, 1987Date of Patent: February 6, 1990Assignee: Polyplastics Co., Ltd.Inventors: Tsunenobu Sato, Kiitiro Fukui
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Patent number: 4891405Abstract: Moldable blends of styrene/maleic anhydride copolymer, polybutylene terephthalate ester, and styrene-maleimide copolymer having pendant carboxyl or hydroxyl groups are provided. In one embodimnent, the incorporation of the styrene-maleimide copolymer results in a composition having co-continuous phases. The compositions of this invention facilitate the production of blow molded articles.Type: GrantFiled: September 1, 1988Date of Patent: January 2, 1990Assignee: ARCO Chemical Technology, Inc.Inventor: Russell J. McCready
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Patent number: 4868246Abstract: Ultraviolet light stabilizers are chemically bound to anhydride containing polymers or copolymers. The polymeric stabilizers are prepared by the reaction of primary amino or hydrazido-substituted UV absorbers with some or all of the anhydride groups of the polymer or copolymer to form pendant stabilizer substituted imide or amic acid groups. The polymer bound stabilizers are not lost from the polymer system by volatilization, migration, or extraction, even at high temperature. The polymer of this invention may be used as they are or as concentrates to stabilize other polymer systems.Type: GrantFiled: August 12, 1987Date of Patent: September 19, 1989Assignee: Pennwalt CorporationInventors: Ronald E. MacLeay, Terry N. Myers
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Patent number: 4863999Abstract: Polymer bound stabilizer compounds are provided in which two or more different classes of stabilizers are chemically bound to anhydride containing polymers or copolymers. The polymeric stabilizers are prepared by the reaction of primary amino or hydrazido substituted stabilizers (i.e., antioxidants, light stabilizers, etc.) with some or all of the anhydride groups of the polymer or copolymer to form pendant stabilizer substituted imide or amic acid groups. The polymer bound stabilizers are not lost from the polymer system by volatilization, migration or extraction, even at high temperatures. The polymer bound stabilizer compounds may be used as concentrates to stabilize other polymer systems.Type: GrantFiled: August 12, 1987Date of Patent: September 5, 1989Assignee: Pennwalt CorporationInventors: Ronald E. MacLeay, Terry N. Myers
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Patent number: 4857595Abstract: Polymer bound hindered amine light stabilizers are prepared by reacting hindered amine light stabilizers containing reactive hydrazide functionalities with anhydride containing polymers or copolymers. The reactions may be carried out in an inert solvent or in a melt blending step. The polymer bound hindered amine light stabilizers are useful alone or may also be used to stabilize other polymers, copolymers or polymer blends against the deleterious effects of heat and/or light.Type: GrantFiled: August 12, 1987Date of Patent: August 15, 1989Assignee: Pennwalt CorporationInventors: Robert T. Kazmierzak, Ronald E. MacLeay
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Patent number: 4857596Abstract: Polymer bound antioxidants are provided in which the antioxidant stabilizer groups are chemically bound to polymers or copolymers by an acylaminoimide or diacylhydrazide function. The polymer bound antioxidants are prepared by reacting hydrazido substituted antioxidants with some or all of the anhydride groups of anhydride containing polymers or copolymers. The concentration of the stabilizers bound to the polymer may be readily varied depending upon the particular end-use of said polymer. Polymer with high concentrations of bound antioxidants can be used as masterbatches to stabilize other polymer systems.Type: GrantFiled: August 12, 1987Date of Patent: August 15, 1989Assignee: Pennwalt CorporationInventors: Ronald E. MacLeay, Terry N. Myers
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Patent number: 4851465Abstract: A copolymer useful for magnetic paints is provided which is composed of (1) at least 60% by weight of vinyl chloride units, (2) 0.1 to 4.0% by weight, as a sulfur- or phosphorus-containing strong acid group, of strong acid group-containing monomer units (3) at least 0.1% by weight, as the hydroxyl groups, of units of a monomer which gives a side chain represented by the formula --X--OH wherein X is an organic group, and (4) 0 to 20% by weight of units of another monomer.Type: GrantFiled: November 17, 1986Date of Patent: July 25, 1989Assignee: Nippon Zeon Co., Ltd.Inventors: Masahiro Yamakawa, Eitaro Nakamura
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Patent number: 4820753Abstract: A sonic window suitable for use in sonar applications wherein an elastomer such as natural or synthetic natural rubbers, a low air entrapping fiber or fibril used for reinforcement, fillers, and thermosetting resins are formed into desired window configuration. The low air entrapment associated with the fiber or fibrils produces a remarkably sonicly transparent window.Type: GrantFiled: March 15, 1988Date of Patent: April 11, 1989Assignee: The B. F. Goodrich CompanyInventors: Samuel J. Caprette, Jr., Wilson N. Smith, Jr.
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Patent number: 4820748Abstract: An antifouling coating composition comprising (A) a film-forming polymer, (B) a volatile organic liquid diluent in which the polymer (A) is dissolved, (C) an antifouling agent and (D) optional other additives, characterizing by containing, in addition to said (A), (B), (C) and (D), disintegration type crosslinked acrylic resin microparticles having an average grain diameter of 0.01 to 250 .mu. and containing a number of metal ester bond bearing crosslinks uniformly distributed within the particle bodies, prepared by polymerizing 5 to 98% by weight of at least one metal ester bond bearing multifunctional polymerizable monomer defined in the specification 95 to 2% by weight of at least one polymerizable monomer other than said metal ester bond bearing multifunctional monomer, the solid weight ratio of said microparticles to the film-forming polymer being 1:99 to 77:30. The present antifouling coating composition can exhibit excellent polishing property and long-lasting antifouling effect.Type: GrantFiled: September 15, 1987Date of Patent: April 11, 1989Assignee: Nippon Paint Co., Ltd.Inventors: Naoki Yamamori, Kazunori Kanda
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Patent number: 4797437Abstract: Segmented thermoplastic copolyester elastomers containing recurring polymeric long chain ester units derived from phthalic acids and long chain glycols and short chain ester units derived from phthalic acids and 1,4-butanediol or 1,4-butenediol. The elastomers also contain polyvinylpyrrolidone and preferably also contain guanidine stabilizer, phosphorus stabilizer and diphenylamine.Type: GrantFiled: December 1, 1983Date of Patent: January 10, 1989Assignee: Hoechst Celanese CorporationInventors: Michael D. Golder, Stanley J. Gromelski, Jr.
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Patent number: 4785053Abstract: An optical resin material comprising at least two constituent units each having positive and negative main polarizability differences of at least 50.times.10.sup.-25 cm.sup.3 in terms of absolute values has small birefringence and good water absorbance, heat resistance and moldability.Type: GrantFiled: July 2, 1986Date of Patent: November 15, 1988Assignee: Sumitomo Chemical Company, LimitedInventors: Iko Ito, Shozaburo Imai, Michihisa Isobe
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Patent number: 4778839Abstract: Segmented thermoplastic copolyester elastomers containing recurring polymeric long chain ester units derived from phthalic acids and long chain glycols and short chain ester units derived from phthalic acids and 1,4-butanediol or 1,4-butenediol. The elastomers also contain polyvinylpyrrolidone and preferably also contain small amounts of guanidine stabilizer, phosphorus stabilizer and diphenylamine.Type: GrantFiled: December 1, 1983Date of Patent: October 18, 1988Assignee: Hoechst Celanese CorporationInventors: Michael D. Golder, Stanley J. Gromelski, Jr.
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Patent number: 4773624Abstract: Into a material based on a caoutchouc-type or caoutchouc-containing mixture for producing hard rubber, there is incorporated a pre-mix containing high-strength organic fibers and a liquid hardenable plastic material. The high-strength and temperature resistant material thus obtained is particularly suitable for the attenuation of noise in combustion engines when heavy-weight fillers are also added to such material. Engine components like, for example, valve covers, timing gear covers and oil pans can be manufactured from this material.Type: GrantFiled: April 28, 1986Date of Patent: September 27, 1988Assignee: Semperit AktiengesellschaftInventors: Josef Affenzeller, Wolf-Dieter Jost
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Patent number: 4771089Abstract: Miscible blends of solids, non-crosslinked polymers are disclosed. The blends comprise from 2 to 95 parts by weight of a water-insoluble, hydrophobic polymer and, correspondingly from 98 to 5 parts by weight of a hydrophilic polymer. The blends are capable of absorbing at least their own weight in water.Type: GrantFiled: July 10, 1985Date of Patent: September 13, 1988Assignee: Minnesota Mining and Manufacturing Co.Inventor: Ronald F. Ofstead
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Patent number: 4766164Abstract: Segmented thermoplastic copolyester elastomers containing recurring polymeric long chain ester units derived from phthalic acids and long chain glycols and short chain ester units derived from phthalic acids and 1,4-butanediol or 1,4-butenediol. The elastomers also contain polyvinylpyrrolidone and preferably also contain guanidine stabilizer, phosphorus stabilizer and diphenylamine.Type: GrantFiled: December 1, 1983Date of Patent: August 23, 1988Inventors: Michael D. Golder, Stanley J. Gromelski, Jr.
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Patent number: 4749745Abstract: Polymeric blends containing 20-80% by weight of a modified vinyl-aromatic polymer containing from 5 to 15% by weight of an ethylenically unsaturated nitrile, and 80-20% by weight of at least one resin containing aromatic groups selected from aromatic polycarbonates and crystalline aromatic polyesters.Type: GrantFiled: March 10, 1986Date of Patent: June 7, 1988Assignee: Montedison S.p.A.Inventors: Gianfranco Biglione, Gian C. Fasulo
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Patent number: 4731413Abstract: Polyesters are modified by adding an aqueous latex having a solids content of <50% by weight. The synthetic resin contained in the latex has a glass transition temperature of .ltoreq.0.degree. C. and contains 0.1-20 mol-% of functional groups.Type: GrantFiled: February 14, 1986Date of Patent: March 15, 1988Assignee: Huels AktiengesellschaftInventors: Michael Droscher, Christian Gerth, Harald Sturm
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Patent number: 4725647Abstract: Described herein is a process for preparing polyesters which comprises reacting a dihydric phenol with a diester derivative of an aromatic diacid in the presence of from about 10 to about 60 weight percent of a processing aid having a boiling point of greater than about 200.degree. C., under polyester forming conditions.Type: GrantFiled: November 8, 1984Date of Patent: February 16, 1988Assignee: Amoco CorporationInventors: Louis M. Maresca, Markus Matzner
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Patent number: 4717751Abstract: Resinous compositions comprising blends of linear polyesters such as poly(butylene terephthalate) with nitrile rubbers have very high impact strengths. The blends may also contain other polymers such as elastomers free from nitrile structural units, addition polymers of olefins or chlorinated olefins, or polylactones; such other polymers frequently improve properties such as gloss and low temperature impact strength.Type: GrantFiled: June 19, 1986Date of Patent: January 5, 1988Assignee: General Electric CompanyInventors: John B. Yates, III, Timothy J. Ullman
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Patent number: 4717752Abstract: Resinous compositions comprising blends of linear polyesters such as poly(butylene terephthalate) with nitrile rubbers have very high impact strengths. The blends may also contain other polymers such as elastomers free from nitrile structural units, addition polymers of olefins or chlorinated olefins, or polylactones; such other polymers frequently improve properties such as gloss and low temperature impact strength.Type: GrantFiled: June 19, 1986Date of Patent: January 5, 1988Assignee: General Electric CompanyInventors: John B. Yates, III, Timothy J. Ullman
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Patent number: 4708985Abstract: The invention relates to a hydrophilic moulding compound of homopolyester and/or copolyester which contains 1 to 20 percent by weight of an alkaline and/or alkaline-earth salt of salt-forming polymer and/or copolymers from ethylenic unsaturated monomers as finely dispersed filling material, having in particualr a maximum particle size of 1 um, the salt-forming polymers being composed in particular of the following single monomers or mixtures thereof: vinyl-sulfonic acid, acrylamidoalkylene-sulfonic acid, sulfonated styrene, acrylic acid, methacrylic acid, maleic acid, fumaric acid, itaconic acid, crotonic acid, vinyl-phosphonic acid, monoalkyl ester of maleic acid, monoalkyl ester of fumaric acid.The invention also relates to a process according to which the salts are preferably added to the polycondensation mixture of the polyester starting materials before and/or during poly-condensation as a suspension in polyhydric alcohol.Type: GrantFiled: March 22, 1982Date of Patent: November 24, 1987Assignee: Akzona IncorporatedInventors: Michael Diamantoglou, Helmut Magerlein, Walter Brodowski, Wolfgang Grimm, Gerhard Meyer
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Patent number: 4645805Abstract: An adhesive composition comprising at least(A) at least one cyanate ester compound selected from the group consisting of:(i) polyfunctional aromatic cyanate ester monomers having the formulaR--O--C.tbd.N).sub.nwherein n is integer of 2-10 and R is an aromatic organic group, the cyanate groups being bonded to an aromatic ring or said aromatic organic group;(ii) homoprepolymers of (i) and(iii) coprepolymer of (i) and an amine, and(B) at least one thermoplastic saturated polyester resin which is non-crystalline, substantially non-crystalline or of low crystallinity is disclosed. The adhesive composition has excellent heat resistance, moisture resistance and chemical resistance.Type: GrantFiled: March 13, 1985Date of Patent: February 24, 1987Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Morio Gaku, Nobuyuki Ikeguchi, Hidenori Kimbara
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Patent number: 4619971Abstract: Resinous compositions comprising blends of linear polyesters such as poly(butylene terephthalate) with nitrile rubbers have very high impact strengths. The blends may also contain other polymers such as elastomers free from nitrile structural units, addition polymers of olefins or chlorinated olefins, or polylactones; such other polymers frequently improve properties such as gloss and low temperature impact strength.Type: GrantFiled: March 29, 1985Date of Patent: October 28, 1986Assignee: General Electric CompanyInventors: John B. Yates, III, Timothy J. Ullman
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Patent number: 4571418Abstract: The char residue formation of molded compositions, upon combustion, is improved by incorporating into the moldable composition a char-forming polymer containing recurring units of at least one monomer capable of undergoing tautomerization, at least one monomer capable of undergoing a nucleophilic substitution reaction by said monomer capable of undergoing tautomerization and, optionally, at least one additional copolymerizable monomer.Type: GrantFiled: March 12, 1984Date of Patent: February 18, 1986Assignee: Atlantic Richfield CompanyInventor: Usama E. Younes
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Patent number: 4528307Abstract: This invention relates to radiation hardenable primers based on prepolymers containing (meth) acryloyl groups and conventional auxiliary agents. The primers are characterized in that they contain organic and/or inorganic fibres having a fibre length distribution curve reaching its maximum in the region of from 50 to 600 .mu.m. These primers are suitable for coating articles which have absorbent surfaces, in particular for the continuous coating of wood-concrete articles such as wood-concrete boards.Type: GrantFiled: September 15, 1983Date of Patent: July 9, 1985Assignee: Bayer AktiengesellschaftInventors: Karl Fuhr, Hans-Joachim Freier
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Patent number: 4525535Abstract: A protective surface coating composition particularly useful for wood coating containing hydroxylated polyester, glycoluril, and emulsion polymer can be heat cured to produce cured films on substrates. The coating is particularly useful as wood coatings.Type: GrantFiled: October 22, 1984Date of Patent: June 25, 1985Assignee: SCM CorporationInventors: Gary P. Craun, Henry J. DeGraaf
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Patent number: 4520168Abstract: Color improved polyarylates having a reduced viscosity of from about 0.1 to greater than 1.0 dl/gm produced by a process comprising the following steps:(a) reacting an acid anhydride derived from an acid containing from 2 to 8 carbon atoms with at least one dihydric phenol to form the corresponding diester; and(b) reacting said diester with at least one aromatic dicarboxylic acid at a temperature sufficient to form the polyarylate, wherein the improvement comprises carrying out said process in the presence of a particular solid adsorbent.Type: GrantFiled: March 27, 1984Date of Patent: May 28, 1985Assignee: Union Carbide CorporationInventors: James H. Kawakami, Benito See, Thomas R. Jones, Louis M. Maresca
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Patent number: 4500679Abstract: Molding compositions are prepared from blends of (A) a thermoplastic copolyetherester elastomer; (B) a styrene maleic anhydride polymer; and (C) an ABS or MBS polymer. Component B, the styrene maleic anhydride polymer may optionally contain a termonomer such as methylmethacrylate or acrylonitrile and a rubber component.Type: GrantFiled: August 9, 1982Date of Patent: February 19, 1985Assignee: Monsanto CompanyInventor: Daniel L. DuFour
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Patent number: 4472553Abstract: Thermoplastic compositions comprising, in intimate admixture, 10 to 90 weight percent of polyethylene terephthalate and from 90 to 10 percent of a rubber-modified copolymer of a vinyl aromatic compound and an .alpha.,.beta.-unsaturated cyclic imide. These compositions display desirable thermal properties, particularly elevated heat deflection temperatures.Type: GrantFiled: September 30, 1982Date of Patent: September 18, 1984Assignee: Ethyl CorporationInventors: Edwin D. Hornbaker, Jesse D. Jones
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Patent number: 4439586Abstract: An improved process for preparing a polyarylate having a reduced viscosity of from about 0.1 to greater than 1.0 dl/gm comprising the following steps:(a) reacting an acid anhydride derived from an acid containing from 2 to 8 carbon atoms with at least one dihydric phenol to form the corresponding diester; and(b) reacting said diester with at least one aromatic dicarboxylic acid at a temperature sufficient to form the polyarylate, wherein the improvement comprises carrying out said process in the presence of a particular solid adsorbent.Type: GrantFiled: June 30, 1982Date of Patent: March 27, 1984Assignee: Union Carbide CorporationInventors: James H. Kawakami, Benito See, Thomas R. Jones, Louis M. Maresca
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Patent number: 4401792Abstract: A process is provided for increasing the rate of crystallization of polyester compounds, such as poly (alkylene arylates), more particularly poly(alkylene terephthalates), or blends or mixtures thereof, as for example, poly(ethylene terephthalate), poly(butylene terephthalate) or mixtures of blends thereof, by incorporating therein a small amount of a polyethylene ionomer, or an alkali metal salt of benzoic acid, such as sodium benzoate. The faster crystallization rates improve injection molding performance of the polyesters and blends thereof, such as reduced post-mold shrinkage, faster mold cycle times and lower mold temperature. Also, the resultant products show increases in physical properties such as flex modulus, flex strength, deflection temperature under load (DTUL), tensile strength and solvent resistance.Type: GrantFiled: March 16, 1982Date of Patent: August 30, 1983Assignee: General Electric CompanyInventors: Robert J. Axelrod, Frank N. Liberti, John Semen
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Patent number: 4397986Abstract: Polyblends comprising polyethylene terephthalate, or a copolyester or blend thereof containing at least 80 percent by weight of polyethylene terephthalate, and a thermoplastic copolymer of (1) at least one vinyl aromatic monomer, (2) acrylic acid or methacrylic acid, or both, and (3) optionally at least one additional copolymerizable termonomer have useful properties, notably higher heat deflection temperatures than the corresponding unblended polyester.Type: GrantFiled: March 3, 1982Date of Patent: August 9, 1983Assignee: Ethyl CorporationInventor: Edwin D. Hornbaker
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Patent number: 4393177Abstract: The present invention relates to a thermosetting resin composition, a process for the preparation of this composition and a cured product obtained by heating and curing this composition. Both the thermosetting resin composition and cured product of the present invention comprise triallylisocyanurate (TAIC) and a poly(phenylmethylene)polymaleimide represented by the following general formula: ##STR1## wherein n is a number of at least 1. This composition is obtained by heating and dissolving the polymaleimide into TAIC. According to the intended use of the molded product, various additives may be added to the composition. For example, there may be added a radical-polymerizable thermosetting resin such as an unsaturated polyester, an epoxy acrylate resin or a diallyl phthalate prepolymer and a filler represented by a thermoplastic resin. The composition of the present invention is excellent in the compatibility and therefore, a good moldability is obtained at the molding step.Type: GrantFiled: March 11, 1981Date of Patent: July 12, 1983Assignee: Hitachi, Ltd.Inventors: Takeo Ishii, Masatsugu Ogata, Toshikazu Narahara
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Patent number: 4388446Abstract: Thermoplastic compositions comprising, in intimate admixture, 10 to 90 weight percent of polyethylene terephthalate and from 90 to 10 percent of a copolymer of a vinyl aromatic compound and an .alpha.,.beta.-unsaturated cyclic imide. These compositions display desirable thermal properties, particularly elevated heat deflection temperatures.Type: GrantFiled: September 14, 1981Date of Patent: June 14, 1983Assignee: Ethyl CorporationInventors: Edwin D. Hornbaker, Jesse D. Jones
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Patent number: 4387190Abstract: An improved autoxidizable coating and/or impregnating composition consisting essentially of:(1) from about 35% to about 80% by weight, based on the total weight of components (1), (2), and (3), of a film-forming component selected from the group consisting of drying oils, alkyd resins, and mixtures of drying oils and alkyd resins,(2) from about 10% to about 50% by weight, based on the total weight of components (1), (2), and (3), of a polymer of a molecular weight in the range of 1,000-50,000 (Mn) polymerized from a monomer system comprising:(a) from about 40% to 100% by weight of at least one monomer selected from the group consisting of dicyclopentenyl methacrylate and dicyclopentenyloxyalkyl methacrylate, and(b) from about 60% to 0% by weight of at least one compatible monomer,(3) from 0 to about 40% by weight, based on the total weight of components (1), (2), and (3), of a reactive, non-volatile diluent monomer, and(4) an effective amount of at least one polyvalent metal salt or complex that catalyzes theType: GrantFiled: August 3, 1981Date of Patent: June 7, 1983Assignee: Rohm & Haas CompanyInventor: Wayne E. Feely
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Patent number: 4386186Abstract: Described herein is an improved process for preparing a polyarylate having a reduced viscosity of from about 0.1 to greater than 1.0 dl/gm which process comprises the following steps:(a) reacting an acid anhydride derived from an acid containing from 2 to 8 carbon atoms with at least one dihydric phenol to form the corresponding diester; and(b) reacting said diester with at least one aromatic dicarboxylic acid at a temperature sufficient to form the polyarylate, wherein the improvement comprises carrying out said process in the presence of at least one thermoplastic polymer. Also described herein are the products produced by said process.Type: GrantFiled: March 29, 1982Date of Patent: May 31, 1983Assignee: Union Carbide CorporationInventors: Louis M. Maresca, Markus Matzner
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Patent number: 4342846Abstract: Blends of a polyester resin, such as polyethylene or polybutylene terephthalate, and an impact resistant interpolymer comprising crosslinked acrylic or methacrylic rubber, crosslinked styrene-acrylonitrile, and uncrosslinked styrene-acrylonitrile polymer components are disclosed.Type: GrantFiled: March 9, 1981Date of Patent: August 3, 1982Assignee: Stauffer Chemical CompanyInventor: Joseph Silberberg
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Patent number: 4320045Abstract: A resin molding composition comprising a thermoplastic polymer, a monomer and an unsaturated polyester which is the reaction product of at least one polyol having at least two, but not more than four hydroxyl groups, the polyols comprising not less than about 48% of the weight of the reactants forming the polyester.Type: GrantFiled: April 10, 1981Date of Patent: March 16, 1982Assignee: Owens-Corning Fiberglas CorporationInventor: Gwilym Owen
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Patent number: 4284550Abstract: A flame-retarding resin composition comprising (1) polybutylene terephthalate, (2) an organohalogen compound as a flame-retarding agent, (3) a flame-retarding supplementary agent, (4) calcium sulfate, and (5) an inorganic fibrous reinforcing agent, and optionally (6) at least one polymer selected from a saponified polyvinyl acetate having a saponification degree of greater than 50 mole %, an ethylene/vinyl acetate copolymer, and a saponified ethylene/vinyl acetate copolymer.Type: GrantFiled: September 4, 1980Date of Patent: August 18, 1981Assignee: Dainippon Ink and Chemicals Inc.Inventors: Shioji Mizuno, Norio Enokimoto, Kazuyoshi Oji