Solid Polymer Derived From Ethylenic Reactants Only Derived From Unsaturated Hydrocarbon Patents (Class 525/177)
  • Patent number: 5550190
    Abstract: The composition of the present invention is a thermoplastic elastomer composition obtained by dynamically crosslinking (A) 51-95% by weight of a thermoplastic polyester elastomer and (B) 49-5% by weight of a rubber during kneading. The composition is excellent in all of hardness, tensile strength, tensile elongation, compression set, thermal aging resistance, oil resistance and molded product appearance, and is suitably used as a material for automobile parts such as joint boot and the like.
    Type: Grant
    Filed: March 27, 1992
    Date of Patent: August 27, 1996
    Assignees: Japan Synthetic Rubber Co., Ltd., NTN Corporation
    Inventors: Ko Hasegawa, Toshio Teramoto, Tatsuo Nakajima, Takeyoshi Konomoto
  • Patent number: 5545686
    Abstract: This invention discloses a rubber composition having a high modulus and excellent processability which is comprised of a blend of (1) at least one elastomer selected from the group consisting of polybutadiene rubber, styrene-butadiene rubber, synthetic polyisoprene rubber, natural rubber, isoprene-butadiene rubber, isoprene-butadiene-styrene rubber, nitrile rubber, carboxylated nitrile rubber, and EPDM rubber, (2) at least one thermotropic liquid crystalline polymer containing an aliphatic spacer, wherein the thermotropic liquid crystalline polymer exhibits no apparent crystalline to nematic transition, wherein the thermotropic liquid crystalline polymer exhibits nematic order above its glass transition temperature, and wherein the glass transition temperature of the thermotropic liquid crystalline polymer is within the range of 20.degree. C. to 180.degree. C., and (3) carbon black.
    Type: Grant
    Filed: October 3, 1994
    Date of Patent: August 13, 1996
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: John D. Carter, Richard R. Smith
  • Patent number: 5541259
    Abstract: Resin compositions having excellent heat resistance, izod impact strength, rigidity and dimensional resistance and the like, applied in the fields of the automobile, electric and electronic, and the like industries. The resin composition comprising: a) a resin in which 30 to 98 mole % of the component (I) are contained in the whole polymer and 70 to 2 mole % of the component (II) are contained in the whole polymer, its weight-average molecular weight converted into that of polystyrene being 1.times.10.sup.3 or more to 5.times.10.sup.6 or less, and b) an olefin resin; then the a)/b) content being 5/95 to 99/1 as a weight ratio, ##STR1## wherein R.sub.1 is an alkyl group having 1 to 18 carbon atom(s) or a cycloalkyl group having 3 to 12 carbon atoms; and ##STR2## wherein R.sub.2 is hydrogen or an alkyl group having 1 to 8 carbon atom(s), and R.sub.3 and R.sub.4 is an alkyl group having 1 to 8 carbon atoms.
    Type: Grant
    Filed: June 21, 1994
    Date of Patent: July 30, 1996
    Assignee: Tosoh Corporation
    Inventor: Toru Doi
  • Patent number: 5539052
    Abstract: A crosslinked thermoplastic elastomer blend prepared by the process comprising blending together:(a) a thermoplastic resin containing at least three alternating blocks:A.sub.x --B--A.sub.xwherein A is a block of at least one polymerized unsaturated ethylene monomer of the following formula:--CH.sub.2 --C(R.sub.1)(R.sub.2)--wherein R.sub.1 and R.sub.2 are each a hydrogen, alkyl or aromatic group, provided that when one of R.sub.1 or R.sub.2 is a hydrogen or an alkyl group, the other R group is an aromatic group; andwherein B is a block of a polymer or copolymer containing at least one conjugated diene monomer in polymerized form, having at least four (4) carbon atoms and the following formula for the residual double bond in the diene after polymerization:--C(R.sub.3)(R.sub.4)--C(R.sub.5).dbd.C(R.sub.6)--C(R.sub.7)(R.sub.8)--wherein R.sub.3 -R.sub.
    Type: Grant
    Filed: February 3, 1995
    Date of Patent: July 23, 1996
    Assignee: Surprenant Cable Corp.
    Inventors: Tsu-chia Shieh, William A. Nicoll
  • Patent number: 5514472
    Abstract: The dirt-repellent monofilament with a toughness of at least 36 cN/tex and an extension of under 44% has a soiling index A1>2 after five soiling and cleaning cycles. To manufacture the dirt-repellent monofilaments, a copolymer with a melting point of 255.degree. to 275.degree. C. and consisting of alkenes and perfluoroalkenes is added to a polymer melt of polythylene terephthalate before extrusion. The dirt-repellent monofilament is advantageously used in the manufacture of cleaning filters for the dry section of a paper machine, i.e. paper machine fabric filters. It may also be used to produce fabrics for general use as technical fabrics which have to be cleaned in difficult conditions.
    Type: Grant
    Filed: August 10, 1995
    Date of Patent: May 7, 1996
    Assignee: Rhone-Poulenc Viscosuisse S.A.
    Inventors: Halim Baris, Erwin Lerch
  • Patent number: 5506300
    Abstract: The present invention provides a composition that softens at a predetermined temperature, preferably between about 20.degree. C. and 90.degree. C., and more preferably between about 20.degree. C. and about 62.degree. C., comprising at least one block copolymer having at least two thermal transition temperatures. The composition is characterized by at least two thermal transition temperatures, one of which is a predetermined lower transition temperature, preferably between about 20.degree. C. to 90.degree. C., and more preferably between about 20.degree. C. to about 62.degree. C., and one of which is an upper transition temperature. The present invention also provides a method of making the composition, a method of making biomedical materials and articles, and toys and toy components, with shape-memory properties from the composition, and biomedical materials and articles, and toys and toy components, with shape-memory properties made from the composition.
    Type: Grant
    Filed: February 18, 1993
    Date of Patent: April 9, 1996
    Assignee: Thoratec Laboratories Corporation
    Inventors: Robert S. Ward, Judy S. Riffle
  • Patent number: 5502160
    Abstract: The invention provides melt-spun polyolefin/polyarylate alloy fibers having an elevated softening point. These fibers are useful in staple lengths for the reinforcement of synthetic geoways (e.g., roadways, runways), especially those fabricated from asphalt-based pavements. The improved softening point of the fibers allows their incorporation into the hot-mix pavement used to fabricate and repair such surfaces without degradation of the fibers by the elevated temperatures found in plants for these manufacture of hot-mix pavements. This invention also provides an improved process for making melts of such allows.
    Type: Grant
    Filed: August 3, 1994
    Date of Patent: March 26, 1996
    Assignee: Hercules Incorporated
    Inventor: James P. Modrak
  • Patent number: 5496888
    Abstract: Resin compositions, comprising (A) a styrene/acrylic polymer and (B) a polyester dispersed therein with an average particle size of not more than 3 .mu., are obtained by quenching a mixture of (A) and (B) melted at 150.degree.-200.degree. C., below the glass transition temperature of the polymer (A) within 5 minutes, and are of good thermal shelf stability and electrical properties and provide toner binders of high hot offset causing temperature and improved low temperature fixing properties.
    Type: Grant
    Filed: March 15, 1994
    Date of Patent: March 5, 1996
    Assignee: Sanyo Chemical Industries, Ltd.
    Inventors: Masaharu Nishida, Tohru Ohhama
  • Patent number: 5472818
    Abstract: Spherical resin particles having a sharp particle size distribution and a method for producing such particles are disclosed. Resin particles according to this invention contain at least a polyester polymer and a polymer formed from a polymerizable monomer, and have an average diameter (D) of 1 to 500 .mu.m. At least 70% by weight of the particles have a diameter in the range of 0.5 D to 2.0 D. Such resin particles can be produced by swelling polyester-containing seed particles with a polymerizable monomer and then polymerizing the polymerizable monomer in swelled seed particles.
    Type: Grant
    Filed: October 6, 1994
    Date of Patent: December 5, 1995
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Yasunari Hotta, Satoshi Maeda, Yozo Yamada, Shinichiro Mori, Toshio Tanaka, Koji Tanaka, Hiroshi Ono
  • Patent number: 5472780
    Abstract: The soil-repellent monofilament for paper machine wire-cloths consists of at least 85% by weight of polyethylene terephthalate having a viscosity index (V.I.) of at least 96 dl/g and an added copolymer prepared from alkenes and perfluoroalkenes having a melting point from 255.degree. to 275.degree. C. To make the soil-repellent monofilament 1.5 to 5% by weight of tetrafluoroethylene is included by addition to the polymer melt of polyethylene terephthalate prior to extrusion. The soil-repellent monofilament produced by this method has a soiling index of <2 after 5 soiling and cleaning cycles.
    Type: Grant
    Filed: April 29, 1994
    Date of Patent: December 5, 1995
    Assignee: Rhone-Poulenc Viscosuisse SA
    Inventors: Halim Baris, Erwin Lerch
  • Patent number: 5449722
    Abstract: Disclosed is a thermoplastic resin composition comprising:30 to 97% by weight of at least one of (a) a crystalline thermoplastic resin component and (b) a non-crystalline thermoplastic resin component, 3 to 70% by weight of (c) a rubbery polymer component which is ununiformly mixed with at least one of Component (a) and Component (b) and 0 to 40% by weight of (d) an inorganic filler,wherein Component (c) forms a network and at least one of the ratio of flexural modulus of Component (a) to Component (c) and that of Component (b) to Component (c) is 5 or more.
    Type: Grant
    Filed: March 18, 1994
    Date of Patent: September 12, 1995
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Koji Nishida, Kiyoji Takagi, Hironari Sano, Motohiro Seki
  • Patent number: 5447991
    Abstract: Polyolefinic fibres and films are made flame-resistant by the addition of a flame-resistant additive made up of a copolyester containing units deriving from: a) terephthalic acid; b) alkylenic glycol (C.sub.2 --C.sub.6) ; and c) phenyl hydroxymethylene phosphinic acid.These fibres and films are prepared by the transformation into its molten state of a mixture of polyolefin and flame-resistant additive.
    Type: Grant
    Filed: May 12, 1994
    Date of Patent: September 5, 1995
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Gianluigi Landoni, Carlo Neri
  • Patent number: 5415943
    Abstract: Wood composite materials containing veneer layers interposed with a thermoplastic adhesive containing a polyester such as polyethylene terephthalate and other thermoplastic polymer show increased impact resistance. The composite material may be manufactured using an adhesive transfer method or film extrusion.
    Type: Grant
    Filed: March 2, 1993
    Date of Patent: May 16, 1995
    Assignee: American Research Corporation of Virginia
    Inventors: Howard P. Groger, Frederick A. Kamke, Russell J. Churchill
  • Patent number: 5407736
    Abstract: A polyester monofilament which exhibits improved abrasion resistance and is formed from the extrusion of a polymer blend of a polyester resin and a melt extruded fluoropolymer resin. The monofilament exhibits an improved resistance to abrasion as compared to standard high temperature polyester monofilament.
    Type: Grant
    Filed: August 12, 1993
    Date of Patent: April 18, 1995
    Assignee: Shakespeare Company
    Inventor: Timothy E. McKeon
  • Patent number: 5397610
    Abstract: A plastic molding produced by molding a resin composition comprising 98 to 50 parts by weight of a thermoplastic polyester resin (A) and 2 to 50 parts by weight of a resin (B) incompatible with the thermoplastic polyester resin (A), the resin (B) being dispersed in the resin (A), wherein the resin (B) has in a layer that is situated at an arbitrary depth from the outer surface of the plastic molding a substantially rodlike form satisfying the requirement represented by the following formulae (1) and (2) and is oriented in parallel to the outer surface of the plastic molding and in the direction of flow of the resin composition in molding:1.ltoreq.P/Q.ltoreq.10 (1)(P+Q)/L.ltoreq.0.5 (2)wherein L, P and Q represent the size of the particle of said resin (B) and respectively have the following values:L: the average length (.mu.m) in the direction of stretching of the particle;P: the average major axis (.mu.
    Type: Grant
    Filed: January 29, 1993
    Date of Patent: March 14, 1995
    Assignee: Kao Corporation
    Inventors: Shingo Odajima, Shoji Ohtani, Tetsuhiro Osawa, Masanori Takita, Yukihiro Nakano
  • Patent number: 5395890
    Abstract: A styrene-based resin composition containing (A) a styrene-based resin with mainly syndiotactic configuration and (B) a thermoplastic resin other than the styrene-based resin exhibit excellent heat resistance and impact resistance. Optionally, the styrene-based resin composition may further contain (C) a rubber polymer and/or (D) an inorganic filler. More particularly, a composition containing 1-98% by weight (A) 1-98% by weight of a styrene-based resin with mainly syndiotactic configuration and 1-98% by weight (B) a polyethylene terephthalate resin or a polyester resin is disclosed.
    Type: Grant
    Filed: April 17, 1990
    Date of Patent: March 7, 1995
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Akikazu Nakano, Takashi Sumitomo, Keisuke Funaki, Toshikazu Ijitsu, Michihiro Sawada, Masahiko Kuramoto, Masakazu Suzuki
  • Patent number: 5382628
    Abstract: The present invention relates to thermoformed plastic articles such as frozen food trays which exhibit unexpectedly high impact strength at low temperatures. The articles are obtained from polyester blends containing 88 to 99 weight percent of a poly(ethylene terephthalate) resin and 1 to 12 weight percent of a poly(1,4-cyclohexylenedimethylene terephthalate) resin which contains at least 30 mole percent of 1,4-cyclohexanedimethanol.
    Type: Grant
    Filed: February 28, 1994
    Date of Patent: January 17, 1995
    Assignee: Eastman Chemical Company
    Inventors: Jennifer L. Stewart, Emily T. Bell
  • Patent number: 5376711
    Abstract: A poly(ethylene 2,6-naphthalate) film obtained by stretching a poly(ethylene 2,6-naphthalate) sheet containing cross-linked polymer particles which have at least one ethylene glycol unit and have an average particle size of from 0.05 to 3 .mu.m and a spherical ratio of from 1.0 to 1.1, wherein a deformation ratio of the cross-linked polymer particles in the stretching is from 1.2 to 3.0, has excellent runnability, abrasive resistance and strength.
    Type: Grant
    Filed: March 24, 1993
    Date of Patent: December 27, 1994
    Assignee: Diafoil Hoechst Company, Limited
    Inventors: Masahiko Fujimoto, Kazuhiro Kunugihara
  • Patent number: 5372879
    Abstract: The present invention provides a biaxially oriented polyester film made of a polyester containing 0.01 to 5% by weight of crosslinked polymer particles characterized by:(1) having a particle size distribution ratio (.gamma.) of 1.3 to 3.5,(2) having an average particle diameter of 0.1 to 2 .mu.m,(3) having a non-circularity of 3.4 or more, and(4) having a standard deviation of noncircularity, of at least 0.16.The polyester film of the present invention has a flat surface having a small number of large protuberances, excellent running property and excellent winding property, and can be produced economically. The film has excellent properties for use as a base for various magnetic recording media.
    Type: Grant
    Filed: February 18, 1994
    Date of Patent: December 13, 1994
    Assignee: Teijin Limited
    Inventors: Makoto Handa, Tomoyuki Kishino
  • Patent number: 5367025
    Abstract: A crosslinkable polyethylene-based composition useful for rotational molding and, when cured, beneficially characterized by exceptional percent elongation after long term exposure to degradation conditions, is provided. The composition advantageously includes a polyalkylene terephthalate as a polymeric additive.
    Type: Grant
    Filed: October 29, 1993
    Date of Patent: November 22, 1994
    Assignee: Wedtech, (USA) Inc.
    Inventor: Donald G. Needham
  • Patent number: 5364905
    Abstract: A continuous method for the in-situ polymerization of plastic in an elastomeric material in a form suitable for reinforcing the elastomeric material is provided. The method comprises feeding elastomer and a monomer or monomer precursor of a reinforcing material into a mixing device, mixing the elastomer and the monomer or monomer precursor vigorously, initiating polymerization, and causing the monomers to continue to polymerize until the polymer solidifies when the melting point of the polymer produced exceeds the mixing temperature of the elastomer, terminating polymerization.
    Type: Grant
    Filed: April 26, 1991
    Date of Patent: November 15, 1994
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Richard G. Bauer, Donald J. Burlett, Joseph W. Miller, Jr., Gordon R. Schorr, Pradeep M. Bapat
  • Patent number: 5361818
    Abstract: The present invention relates to polymeric alloys which comprise the reaction product of a mixture of:(a) a polyester resin produced from the precondensation reaction of a diol and a dicarboxylic compound, said polyester subsequently condensed and having an intrinsic viscosity from about 0.13 to about 0.35 dl/g, a glass transition temperature of at least 50.degree. C., an acid number from about 5 to 50;(b) at least one polyepoxide having at least two epoxy groups per molecule; and(c) an unvulcanized rubber.
    Type: Grant
    Filed: September 27, 1993
    Date of Patent: November 8, 1994
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Deborah A. Tung, Thomas J. Segatta, John J. A. Verthe, Paul H. Sandstrom, Richard G. Bauer, Mark A. Marinko
  • Patent number: 5349007
    Abstract: Lightweight polyester resin molding compositions include a melt-blend of (A) between 97 to 20 parts by weight, based on 100 parts by weight of the total composition weight, of a polyester base resin, (B) between 3 to 80 parts by weight, based on 100 parts by weight of the total composition weight, of a polyolefin resin, (C) between 0.1 to 15 parts by weight, based on 100 parts by weight of the total composition weight, of a compatibilizing compound having a carbon-carbon double bond and an epoxy group in its molecule, (D) between 0.1 to 20% by weight, based on the weight of the compatibilizing compound, of a free radical initiator, and optionally, (E) up to 120 parts by weight, based on 100 parts by weight of the total composition, of a filler material. The free radical initiator is at least one compound having a one-minute half-life temperature of 130.degree. C.
    Type: Grant
    Filed: July 1, 1993
    Date of Patent: September 20, 1994
    Assignees: Polyplastics Co., Ltd., Takeda Chemical Industries, Ltd.
    Inventors: Hajime Serizawa, Masaru Kubota, Hiroyuki Sano, Yoshihisa Tajima
  • Patent number: 5342893
    Abstract: A thermosetting powder coating composition containing a solid saturated thermosetting polyester having an acid value of at least 25 and a glass transition temperature (Tg) of at least 45.degree. C. and a curing agent such as a hydroxyalkyl amide capable of reacting with carboxylic acid groups of the polyester additionally contains, as an anti-popping agent, a thermoplastic polymer which i) is solid, ii) has a Tg of 30.degree.-100.degree. C., iii) comprises, at least mainly, units derived from at least one alkyl acrylate or alkacrylate and iv) has an acid value of no more than 10.
    Type: Grant
    Filed: March 10, 1993
    Date of Patent: August 30, 1994
    Assignee: Scott Bader Company Limited
    Inventors: Roy R. Wilkinson, Anthony Phillips
  • Patent number: 5318871
    Abstract: A toner for electrophotography obtained by melting and kneading a kneaded material prepared by melting and kneading a domain resin and a coloring agent, a matrix resin having a low compatibility with the domain resin, and a dispersion assistant having a compatibility with both of the domain resin and matrix resin and a Izod impact value higher than the matrix resin to obtain a colored composition, followed by pulverizing and classifying the colored composition.
    Type: Grant
    Filed: April 14, 1992
    Date of Patent: June 7, 1994
    Assignees: Minolta Camera Kabushiki Kaisha, Mitsubishi Petrochemical Co., Ltd.
    Inventors: Sanji Inagaki, Shoichi Tsuge, Mineyuki Sako, Kenzo Toya, Yasuhiro Terunuma, Yukako Oya, Michio Ohmori
  • Patent number: 5314948
    Abstract: Thermoplastic polyester, copolyester and polyblend molding compositions impact-modified by glycidyl methacrylate grafted EPDM exhibit high impact strength combined with good knit-line characteristics, when the grafted comonomer content exceeds 2 percent by weight in the impact modifier, it has a gel content in the range of from about 10 to about 80 weight percent.
    Type: Grant
    Filed: June 24, 1991
    Date of Patent: May 24, 1994
    Assignees: Copolymer Rubber, Chemical Corporation
    Inventors: Charles F. Pratt, Shrikant V. Phadke, Errol Olivier
  • Patent number: 5306785
    Abstract: Compositions are provided which comprise a polyester resin which comprises the reaction product of at least one straight chain, branched, or cycloaliphatic C.sub.2 -C.sub.10 alkane diol or chemical equivalent thereof; and a cycloaliphatic diacid or chemical equivalent thereof; and a poly(ether ester) elastomer, a poly(etherimide ester) elastomer, a copolymer elastomer comprising (ether ester) monomers and (etherimide ester) monomers, a copolymer comprising ethylene and one or more comonomers copolymerizable therewith to provide a solid copolymer, or a combination of any of the foregoing. These compositions have excellent tensile properties.
    Type: Grant
    Filed: October 5, 1992
    Date of Patent: April 26, 1994
    Assignee: General Electric Company
    Inventors: Willem F. H. Borman, Nan-I Liu
  • Patent number: 5298560
    Abstract: A partially crosslinked thermoplastic resin composition is prepared by dynamically heat-treating a thermoplastic resin (A) in the presence of a carbon radical inducing agent (B) comprising a charge transfer complex or a combination of a hydrogen donating compound and a hydrogen accepting compound.
    Type: Grant
    Filed: May 14, 1991
    Date of Patent: March 29, 1994
    Assignee: Nippon Petrochemicals Company, Limited
    Inventors: Fuyuki Aida, Masaaki Miyazaki, Mamoru Nagai
  • Patent number: 5283291
    Abstract: It is desirable to increase the modulus of rubbers utilized in a wide variety of applications. This invention discloses a technique for preparing high modulus rubber compositions. By utilizing this technique, high modulus can be attained without sacrificing other properties, such as processability. The subject invention more specifically relates to a process for preparing a high modulus rubber composition which comprises: (1) polymerizing at least one diacid or diacid halide with at least one member selected from the group consisting of diols and diamines in a polymer cement of a rubbery elastomer under conditions which result in the formation of a rubber cement having a polyester or a polyamide dispersed therein; and (2) recovering the high modulus rubber composition from the rubber cement. It is highly desirable to make the high modulus rubber composition by interfacial polymerization.
    Type: Grant
    Filed: June 19, 1991
    Date of Patent: February 1, 1994
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Bruce R. Hahn, Wen-Liang Hsu, Douglas D. Callander, Adel F. Halasa
  • Patent number: 5281668
    Abstract: A thermoplastic resin composition comprising100 parts by weight of a resin mixture comprising(A) 5-95% by weight of polyolefin and(B) 95-5% by weight of polyester and/or polyamide, and(C) 1-20 parts by weight of chlorinated polyethylene incorporated into the resin mixture.
    Type: Grant
    Filed: July 25, 1991
    Date of Patent: January 25, 1994
    Assignee: Sumitomo Bakelite Company Limited
    Inventors: Richard Heggs, Carol Geary
  • Patent number: 5281669
    Abstract: Intimate blends of macrocyclic oligomer compositions, such as cyclic polycarbonate or poly(alkylene dicarboxylate) oligomer mixtures, are blended with linear polymers, especially addition polymers. The blends flow easily and are frequently homogeneous. The macrocyclic oligomers therein may be polymerized to produce resin blends having advantageous properties.
    Type: Grant
    Filed: April 13, 1992
    Date of Patent: January 25, 1994
    Assignee: General Electric Company
    Inventors: Roger P. Kambour, Warren L. Nachlis, Eric J. Pearce, Jeffrey D. Carbeck
  • Patent number: 5280071
    Abstract: The present invention relates to a composition which exhibits antiozonant activity in diene containing rubbers comprising the reaction product of a multi-step process comprising:(1) reacting under condensation conditions an aldehyde and an amine containing compound to form a condensation product, whereinsaid aldehyde is selected from the group consisting of formaldehyde, acetaldehyde or mixtures thereof; andsaid amine containing compound is selected from the group consisting of:N,N'-di-substituted-p-phenylene diamines of the structural formula: ##STR1## wherein R.sup.1 and R.sup.2 are independently selected from the group of radicals consisting of alkyls having 3 to 12 carbon atoms, aryls having 6 to 12 carbon atoms and aralkyls having 7 to 12 carbon atoms; and wherein said condensation conditions include:(i) the presence of an acid catalyst,(ii) a mole ratio of aldehyde to amine containing compound ranging from about 1.
    Type: Grant
    Filed: April 5, 1991
    Date of Patent: January 18, 1994
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Budd H. Sturm, Joseph A. Kuczkowski, Paul H. Sandstrom, George F. Balogh
  • Patent number: 5264491
    Abstract: Compatibilizing agents suitable for blending otherwise immiscible polymers comprise a block or graft copolymer in which at least one of the block segments is formed by a living anionic polymerization and thereafter chemically converted to provide a polymer having at least one functional end group. The functional groups of the polymer blocks thus formed are reacted with a functionalized monomer, or an oligomer to provide a second block polymer segment. Compatibilizing agents containing more than two blocks may be formed in similar fashion. The compatibilizing agents are used to provide uniform blends of polar and non-polar polymers having superior uniformity and other physical properties.
    Type: Grant
    Filed: August 26, 1992
    Date of Patent: November 23, 1993
    Assignee: Edison Polymer Innovation Corporation
    Inventor: Roderic P. Quirk
  • Patent number: 5260380
    Abstract: A self-reinforced polymer composite in the form of a non-laminated shaped article is prepared by (a) melt blending (I) a matrix polymer which is a melt processable flexible chain polymer or first liquid crystal polymer (LCP) and (2) a fiber forming melt processable second LCP under high strain mixing conditions inducing fiber formation, cooling and stretching the resulting blend, and (b) shaping the resulting blend by injection molding or extrusion at a temperature which is above the minimum melt processing temperature of the matrix polymer but below that of the fiber forming second LCP. By shaping at a temperature below the minimum processing temperature of the fiber-forming LCP, the fiber structure formed during cooling is preserved. The resulting shaped articles have outstanding mechanical properties, e./g., tensile strength, modulus and impact strength.
    Type: Grant
    Filed: January 23, 1992
    Date of Patent: November 9, 1993
    Assignee: The University of Akron
    Inventor: Avraam Isayev
  • Patent number: 5256735
    Abstract: A process is disclosed for the preparation of aromatic polyester-polystyrene block copolymers by solution polycondensation of styrene polymers (A) having terminal functional groups reactive with acid halide or hydroxyl groups, aromatic dihydroxy compounds (B), and aromatic dicarboxylic acid dihalides (C) at (A)/[(B)+(C)] (by weight) of 5/95 to 80/20 and the polymers are suitable as molding materials for optical instruments for their good transparency, particularly low birefringence, low melt viscosity, and good mechanical strength.
    Type: Grant
    Filed: October 17, 1991
    Date of Patent: October 26, 1993
    Assignees: Nippon Steel Corporation, Nippon Steel Chemical Co., Ltd.
    Inventors: Hiroshi Ohishi, Masao Kimura, Shinji Inaba, Masanao Kawabe
  • Patent number: 5244972
    Abstract: A molding composition having improved toughness and impact strength comprising 60-90 percent by weight of a matrix resin in the form of a polyester or polyamide resin, reacted with 40-10 percent by weight of a rubber formed by copolymerization of ethylene, one or more mono-olefins, and preferably one or more polyenes, and an ester of an alpha, beta-unsaturated acid having an epoxide functionality on the alkoxy portion. The composition is prepared by forming a masterbatch containing the backbone rubber, a monomer having the epoxide functionality, a catalyst and a portion of the matrix resin of the final composition in a single step bulk process, and thereafter blending the masterbatch with the remainder of the matrix resin.
    Type: Grant
    Filed: August 7, 1990
    Date of Patent: September 14, 1993
    Assignee: General Electric Company
    Inventor: Shrikant V. Phadke
  • Patent number: 5232977
    Abstract: It is often desirable to increase the modulus of rubbers which are utilized in manufacturing a wide variety of articles. For instance, carbon black is frequently added to rubbers to increase the modulus thereof. However, the incorporation of fillers, such as carbon black, into rubbers typically results in the rubber being more difficult to process. This invention discloses the incorporation of certain thermotropic liquid crystalline polymers into rubbers in order to improve the processability of the rubber and also to increase the modulus thereof. This invention specifically discloses a rubber composition having a high modulus and excellent processability which is comprised of a blend of (1) at least one elastomer, and (2) from about 2 phr to about 40 phr of at least one thermotropic liquid crystalline polymer containing an aliphatic spacer which has a crystalline to nematic transition at a temperature which is within the range of about 110.degree. C. to about 180.degree. C.
    Type: Grant
    Filed: February 7, 1991
    Date of Patent: August 3, 1993
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: John D. Carter, Richard R. Smith
  • Patent number: 5231137
    Abstract: Novel grafted polymers having backbones formed from unsaturated monomers and having pendent isocyanate containing sidechains derived from isopropenyl-alpha,alpha-dimethylbenzyl isocyanate or copolymers thereof are described.Curable coating and molding compositions employing the novel grafted polymers of the invention in combination with isocyanate reactive materials are also described.
    Type: Grant
    Filed: August 17, 1992
    Date of Patent: July 27, 1993
    Assignee: American Cyanamid Company
    Inventors: Michael M. Fisher, Leroy A. White, Howard R. Lucas
  • Patent number: 5225490
    Abstract: Biodisintegrable thermoplastic resin moldings and a process for producing same are disclosed, the biodisintegrable thermoplastic resin moldings being comprised of a thermoplastic aliphatic polyester resin as a matrix resin having dispersed therein an other type of thermoplastic resin in a proportion of 40-75 weight % based on the whole resin. The biodisintegrable thermoplastic resin moldings is easily disintegrable after disposal in an environment where microorganisms exist so that the moldings can be reduced in bulkness and give no harmful effect on the life of natural plants and animals. Thus, the present invention affords an effective means for solving various problems in the treatment of disposed plastic articles.
    Type: Grant
    Filed: November 7, 1990
    Date of Patent: July 6, 1993
    Assignees: Director-General of Agency of Industrial Science and Technology, JSP Corporation
    Inventors: Yutaka Tokiwa, Akira Iwamoto, Kiyoshi Takeda
  • Patent number: 5216079
    Abstract: Lubricant systems are provided in which a polyolefin or polyolefin/polytetrafluoroethylene blend functions as a lubricant in a polymer matrix material. The resulting polymer composites containing about 1 to 30 weight percent of the novel lubricant or lubricant blend have greatly improved friction and wear properties, including lower coefficients of friction and increased surface wear resistence. The polyolefin does not remain as discrete, identifiable particles after mixing with the polymer matrix, and has an average molecular weight of less than 500,000.
    Type: Grant
    Filed: February 23, 1990
    Date of Patent: June 1, 1993
    Assignee: Kawasaki LNP Inc.
    Inventors: Jane M. Crosby, John E. Theberge
  • Patent number: 5202384
    Abstract: It is often desirable to increase the modulus of rubbers utilized in a wide variety of applications. This invention discloses a technique for modifying rubbers to improve their modulus without sacrificing other properties. By utilizing the process of this invention, rubber compositions having increased modulus are prepared by grafting polyester onto rubber. This can be accomplished by reacting a polydiene rubber with a thioacid or maleic anhydride and subsequently with the polyester. It is also possible to prepare such polyester modified rubber compositions by reacting an epoxidized rubber with the polyester.
    Type: Grant
    Filed: November 7, 1990
    Date of Patent: April 13, 1993
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: James B. Pyle, Richard G. Bauer, Donald J. Burlett
  • Patent number: 5196484
    Abstract: ABA triblock polymers, the A block being rigid having a transition away from its rigid phase above 70.degree. C., the B block being wholly or partly ion-coordinating, elastomeric or amorphous, the B/A block length ratio being greater than 1. When the B block is complexed with an ionic salt these polymers act as polymeric electrolytes which may be used in cells etc. Preferred polymers are those where HC.dbd.CH sites in the polybutadiene segment of a polystyrene-polybutadiene-polystyrene polymer are replaced by --CH.sub.2 CH--X--(CH.sub.2 CH.sub.2 O).sub.m --R, where X is link, R is alkyl. A preferred salt is LiCF.sub.3 SO.sub.3.
    Type: Grant
    Filed: January 24, 1992
    Date of Patent: March 23, 1993
    Assignee: The Secretary of State for Defence in her Britannic Majesty's Government of the United Kingdom of Great Britain and Northern Ireland
    Inventors: Jeremy R. M. Giles, Fiona M. Gray, Colin A. Vincent, James R. MacCallum
  • Patent number: 5166267
    Abstract: It is desirable to increase the modulus of rubbers utilized in a wide variety of applications. For example, it is typically desirable to increase the modulus of rubber compounds which are utilized in tire tread base compositions and in tire wire coat compounds. Unfortunately, most conventional techniques for increasing the modulus of a rubber compound are detrimental to other rubber properties, such as hysteresis and cut growth resistance. By utilizing the techniques of this invention rubber compounds can be prepared which exhibit high tensile strength, high modulus, and good cut growth resistance. The subject invention specifically relates to a process for preparing a highly dispersed blend of a polyester in an elastomer which comprises (1) blending a solution of a rubber in an organic solvent with a solution of a polyester in an organic solvent to produce a dispersion containing said rubber and said polyester, and (2) recovering the highly dispersed blend from the dispersion.
    Type: Grant
    Filed: September 17, 1990
    Date of Patent: November 24, 1992
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Gerald Cohn, Douglas D. Callander, William C. T. Tung
  • Patent number: 5162424
    Abstract: The invention relates to polymer mixtures which comprise a polybutylene terephthalate, a thermoplastic elastomer, and a brominated polystyrene. The polymer mixtures according to the invention have a combination of the following favorable properties: a good flexibility, a good flow of the melt, good flame-retarding properties and a high tracking index.
    Type: Grant
    Filed: April 10, 1990
    Date of Patent: November 10, 1992
    Assignee: General Electric Company
    Inventors: Jan de Boer, Farshid Tabankia
  • Patent number: 5159016
    Abstract: A thermoplastic resin composition is prepared by heat-treating a mixture of a thermoplastic resin substantially containing no olefinic unsaturated carbon-carbon bond and an elastomer having an olefinic unsaturated carbon-carbon bond, dynamically in the presence of a crosslinking agent, characterized in that as said elastomer there is used at least one member selected from the group consisting of styrene-butadiene-styrene block copolymer (SBS), styrene-iosprene-styrene block copolymer (SIS), 1,2-polybutadiene rubber and ethylene-propylene-diene random copolymer (EPDM), and that as said crosslinking agent there is used a dihydroaromatic compound or a polymer thereof.
    Type: Grant
    Filed: December 27, 1988
    Date of Patent: October 27, 1992
    Assignee: Nippon Petrochemicals Company, Limited
    Inventors: Toshio Inoue, Shiyuji Kashiwase, Masaaki Miyazaki, Toshitsune Yoshikawa, Masaaki Kobayashi
  • Patent number: 5151466
    Abstract: A molding composition having improved toughness and impact strength comprising 60-90 percent by weight of a matrix resin in the form of a polyester or polyamide resin, reacted with 40-10 percent by weight of a rubber formed by copolymerization of ethylene, one or more mono-olefins, and preferably one or more polyenes, and an ester of an alpha, beta-unsaturated acid having an epoxide functionality on the alkoxy portion. The composition is prepared by forming a masterbatch containing the backbone rubber, a monomer having the epoxide functionality, a catalyst and a portion of the matrix resin of the final composition in a single step bulk process, and thereafter blending the masterbatch with the remainder of the matrix resin.
    Type: Grant
    Filed: March 28, 1990
    Date of Patent: September 29, 1992
    Inventor: Shrikant V. Phadke
  • Patent number: 5149589
    Abstract: A thermoplastic elastomer composition of excellent fusion bond property, which is useful to produce a composite molded product having a molded part that is made of a synthetic resin material, for example, an engineering plastic material, which has excellent mechanical strength, and a molded part that is made of a high-elasticity thermoplastic elastomer. The thermoplastic elastomer composition comprises 100 parts by weight of a thermoplastic elastomer and 25 to 185 parts by weight of a thermoplastic polyester elastomer.
    Type: Grant
    Filed: September 6, 1990
    Date of Patent: September 22, 1992
    Assignee: Taisei Purasu Co., Ltd.
    Inventors: Masanori Naritomi, Noritaka Ogawa
  • Patent number: 5137973
    Abstract: The invention relates to a crystalline polyolefin composition having dispersed therein a nucleating agent composed of one or more polyesters.
    Type: Grant
    Filed: September 10, 1990
    Date of Patent: August 11, 1992
    Assignee: Allied-Signal Inc.
    Inventors: Yash P. Khanna, Kevin R. Slusarz, Georgette Chomyn, Tammy L. Smith
  • Patent number: 5120586
    Abstract: Bags having increased blocking resistance properties are formed of a film composed of a resin blend of a polyethylene (PE) resin and a polybutylene terephthalate (PBT) resin having an intrinsic viscosity or 0.7 of more. Preferably, the film is a multi-layer structure formed via coextrusion inflation molding techniques having inner and outer layers laminated to one another. The inner layer is a polyolefin, while the outer layer is composed of a PE/PBT blend, in which the PBT is present in an amount of between 5 to 30 wt. % based on the total weight of the resin composition and has a melt index of 0.7 or more. The thickness ratio of the internal layer to the external layer is preferably between 95/5 to 30/70.
    Type: Grant
    Filed: October 26, 1989
    Date of Patent: June 9, 1992
    Assignee: Polyplastics Co., Ltd.
    Inventors: Shigeru Nedzu, Haruyasu Ito
  • Patent number: 5118760
    Abstract: Disclosed is a polymer blend of a copolyesterether and an isotactic homopolymer of propylene, molded articles of which have improved impact strength.
    Type: Grant
    Filed: December 26, 1990
    Date of Patent: June 2, 1992
    Assignee: Eastman Kodak Company
    Inventors: Dale M. Blakely, Robert W. Seymour