Solid Polymer Derived From Ethylenic Reactants Only Derived From Unsaturated Hydrocarbon Patents (Class 525/177)
  • Patent number: 4287014
    Abstract: A crosslinkable resin composition comprising (A) a polyethylene resin composition containing 0.1 to 10% by weight of a crosslinking agent and (B) a thermosetting resin composition selected from the group consisting of cyanate ester resin compositions, polyester resin compositions and epoxy resin compositions; said crosslinkable resin composition comprising (1) 95 to 5% by weight of the resin composition (A) and 5 to 95% by weight of the resin composition (B) when the resin composition (B) is a cyanate ester resin composition, and (2) 95 to 20% by weight of the resin composition (A) and 5 to 80% by weight of the resin composition (B) when the resin composition (B) is a polyester resin composition or an epoxy resin composition; and a method for producing a laminate using said composition.
    Type: Grant
    Filed: December 27, 1979
    Date of Patent: September 1, 1981
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Morio Gaku, Norio Nagai, Yasunari Osaki
  • Patent number: 4281079
    Abstract: Polyarylene ester compositions comprising an intimate admixture of polyarylene ester and up to about 10 weight percent of an elastomeric ethylene 1-alkene copolymer. The compositions possess greatly improved impact resistance and reduced notch sensitivity in comparison with the polyarylene ester and exhibit improved melt flow with minimal loss in flame retardance, heat distortion resistance and tensile properties. The compositions are useful as molding powders and sheet extrusion compounds.
    Type: Grant
    Filed: December 11, 1978
    Date of Patent: July 28, 1981
    Assignee: Monsanto Company
    Inventor: Massimo Baer
  • Patent number: 4267286
    Abstract: Modified thermoplastic polyester compositions are provided which comprise (a) a poly(1,4-butylene terephthalate) resin or polyester copolymer and, optionally, a poly(ethylene terephthalate) resin and (b) a modifier therefor comprising a combination of a polyacrylate resin or a vinyl aromatic-diene block copolymer resin and a poly(1,3-butylene terephthalate), and, optionally (c) filler and/or reinforcing agent and/or (d) a flame retardant or combination of flame retardants. Modifier (b) provides enhanced resistance to impact fracture in articles molded from the compositions.
    Type: Grant
    Filed: July 3, 1979
    Date of Patent: May 12, 1981
    Assignee: General Electric Company
    Inventor: Richard W. Campbell
  • Patent number: 4259458
    Abstract: Described herein are molding compositions comprising a blend of a polyarylate, a polyester, and at least one thermoplastic polymer selected from the group consisting of an aromatic polycarbonate, a styrene resin, an alkyl acrylate resin, a polyurethane, a vinyl chloride polymer, a poly(aryl ether), a copolyetherester block polymer or a polyhydroxyether. These blends have excellent compatability and can be molded into a variety of articles.
    Type: Grant
    Filed: August 9, 1979
    Date of Patent: March 31, 1981
    Assignee: Union Carbide Corporation
    Inventor: Lloyd M. Robeson
  • Patent number: 4251644
    Abstract: The improvement of physical and mechanical properties of polar resins such as nylon and dacron resins by blending with EPM and EPDM resins which have been rendered more compatible by the modification to incorporate polar groups.
    Type: Grant
    Filed: October 1, 1979
    Date of Patent: February 17, 1981
    Assignee: Copolymer Rubber & Chemical Corporation
    Inventor: Ralph K. Joffrion
  • Patent number: 4246368
    Abstract: A powder coating composition for forming multi layer coatings comprising:(1) at least one of finely divided thermosetting addition copolymers having a glass transition temperature of 35.degree. to 75.degree. C. and comprising as comonomers a wt. % of a hardness imparting monomer and b wt. % of a softness imparting monomer based on the copolymer wherein a+b.ltoreq.60, b.ltoreq.a and b.ltoreq.20, and(2) at least one of finely divided thermosetting resinous materials having incompatibility or low compatibility with the copolymer and a substantially greater surface tension than the copolymer when melted at the same temperature and substantially differing from the copolymer in composite parameter.
    Type: Grant
    Filed: May 5, 1978
    Date of Patent: January 20, 1981
    Assignee: Kansai Paint Company, Limited
    Inventor: Heihachi Murase
  • Patent number: 4243702
    Abstract: It has been discovered that pastes of particulate thermoplastic polymers dispersed in a soft resinous phase can be prepared which heat-set by fusion of the thermoplastic binder. Polyesters and polyamides have been found to be particularly useful. When pigmented or otherwise colored, these formulations have utility as printing inks. When uncolored, they can be used as clear overprint coatings. In addition, these fusible pastes have utility as specialty coatings in adhesives and can be fabricated into self-supporting shapes.
    Type: Grant
    Filed: June 29, 1979
    Date of Patent: January 6, 1981
    Assignee: Hercules Incorporated
    Inventor: Robert M. Walsh
  • Patent number: 4233413
    Abstract: A resin composition comprising (A) 25 to 45 parts by weight of an unsaturated polyester having special structure, (B) 40 to 60 parts by weight of polymerizable monomer such as styrene, and (C) 4.5 to 15 parts by weight of a polystyrene, has low shrink properties and excellent electrical properties when molded, particularly by casting.
    Type: Grant
    Filed: November 28, 1978
    Date of Patent: November 11, 1980
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Noboru Monma, Iwao Maekawa, Tutomu Sarudate, Hidetaka Sato, Isao Uchigasaki
  • Patent number: 4228251
    Abstract: A resin composition which comprises (A) 50 to 90 parts by weight of an unsaturated ester oligomer produced by reacting a glycol, hydroxylated dicyclopentadiene, and at least one unsaturated dibasic acid or anhydride thereof until an acid value of less than 40, (B) 50 to 10 parts by weight of one or more polymerizable monomers, and (C) 3 to 15 parts by weight of polystyrene based on 100 parts by weight of the total of the components (A) and (B), can give molded articles having low shrink properties and improved color shading, cracks, etc.
    Type: Grant
    Filed: November 30, 1978
    Date of Patent: October 14, 1980
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Iwao Maekawa, Isao Uchigasaki, Noboru Monma
  • Patent number: 4219628
    Abstract: Polyester composition characterized by a balance of physical properties more suitable for molding purposes than possible with the polyesters themselves, including blends of a polyester, poly(ethylene-co-propylene) rubber (EPR) and an ionomer of poly(ethylene-co-acrylic acid); the polyesters being selected from poly(tetramethylene terephthalate) (PBT), poly(1,4-cyclohexylenedimethylene terephthalate) (PCDT), and poly(1,4-cyclohexylenedimethylene terephthalate) (PCDT) modified with up to about 10 percent by weight of poly(oxyethylene) glycol having a molecular weight of about 500 to about 2000.
    Type: Grant
    Filed: April 2, 1979
    Date of Patent: August 26, 1980
    Assignee: Eastman Kodak Company
    Inventors: Doyle A. Weemes, Robert W. Seymour
  • Patent number: 4217426
    Abstract: Semi-crystalline polyester/low viscosity polyethylene melt blends, which are non-tacky and non-blocking and are more readily grindable by cryogenic grinding techniques, for providing powders suitable for powder adhesives particularly useful for fusible interlinings or for providing powder coating materials.
    Type: Grant
    Filed: January 19, 1979
    Date of Patent: August 12, 1980
    Assignee: Eastman Kodak Company
    Inventors: Richard L. McConnell, Doyle A. Weemes
  • Patent number: 4217427
    Abstract: Compositions comprising from 70 to 95 wt % polybutylene terephthalate modified by copolymerizing therewith from 30 to 5 wt % of a diol-terminated polystyrene as pendant chains exhibit marked increase in heat deflection temperature at 264 psi stress, together with an unexpected increase in melt flowability.
    Type: Grant
    Filed: May 2, 1979
    Date of Patent: August 12, 1980
    Assignee: Borg-Warner Corporation
    Inventors: John C. Falk, James Wyatt
  • Patent number: 4207230
    Abstract: The current invention is concerned with block copolyesters of low glass transition temperature segments and ethylene glycol based polyester segments linked together by carboxylic acid ester groups and special diols, and a process for preparing these copolyesters. These copolyesters display molded resin properties similar to polyethylene terephthalate but crystallization behavior similar to polybutylene terephthalate, i.e. they have high strength and superior solvent resistance, but they also crystallize rapidly. They are made by subjecting low glass transition temperature (less than 0.degree. C.) polymers with carboxyl, hydroxyl or reactive ester end groups to esterification or transesterification conditions with ethylene glycol based polyester segments having a minimum intrinsic viscosity of 0.2 dl/g and special diols having four to ten carbon atoms with 3 or 4 carbon atoms between the hydroxyl groups in the presence of appropriate catalysts.
    Type: Grant
    Filed: February 3, 1978
    Date of Patent: June 10, 1980
    Assignee: Bayer Aktiengesellschaft
    Inventors: Peter Bier, Rudolf Binsack
  • Patent number: 4206093
    Abstract: A process for the preparation of chlorinated aliphatic polymers wherein chlorine-free polymers are chlorinated by using gaseous chlorine in chlorinated hydrocarbons as solvents and the chlorinated aliphatic polymers are recovered from the chlorinating solution by steam distillation in which process from 15 to 50% by weight of a lacquer resin is added to the chlorinating solution before steam distillation. The chlorinated polymers contain less residual solvent.
    Type: Grant
    Filed: April 27, 1977
    Date of Patent: June 3, 1980
    Assignee: Bayer Aktiengesellschaft
    Inventors: Klaus Hoehne, Johann Jelen, Diez Heine, Rolf Baatz
  • Patent number: 4205142
    Abstract: Flame retardant resin compositions are disclosed, comprising a thermoplastic condensation polymer selected from the group consisting of polyesters, polycarbonates and polyamides, a halogenated flame-retardant, and a rubber-occluded flame retardant synergist. The compositions possess superior stability in melt processing and improved flame retardancy and impact strength.
    Type: Grant
    Filed: November 2, 1977
    Date of Patent: May 27, 1980
    Assignee: Monsanto Company
    Inventor: Massimo Baer
  • Patent number: 4199493
    Abstract: Molding resins are disclosed which comprise a polyarylene ester containing recurring units derived from 1,2-bis(4-hydroxyphenyl)ethane, an inorganic reinforcing agent and a thermoplastic vinyl addition polymer. The reinforcing agent preferably comprises capsules in which glass fiber strands are encapsulated in collimated array within the thermoplastic vinyl addition polymer.
    Type: Grant
    Filed: July 14, 1978
    Date of Patent: April 22, 1980
    Assignee: Monsanto Company
    Inventor: Massimo Baer
  • Patent number: 4169821
    Abstract: A composition for use as a binder in a non-aqueous printing ink which comprises a modified hydrocarbon resin containing carboxylic acid units, the carboxylic groups of which are partially esterified with a polyhydric alcohol in such an amount that the modified hydrocarbon resin product contains from 0.01 to 0.7 ester groups of polyhydric alcohol based on each acid group originally present and a process for its preparation.
    Type: Grant
    Filed: June 24, 1977
    Date of Patent: October 2, 1979
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Gerhard Werner, Hans-Jurgen Tietz, Reinhard Wagner, Wolfgang Dathe