Heterocyclic Ring Is An 1,2-epoxy Ring Patents (Class 525/187)
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Publication number: 20090105419Abstract: Disclosed is a water-based resin composition containing a copolymer (A) which is obtained by carrying out emulsion polymerization of an unsaturated monomer composed of 0.5 to 50 parts by mass of a specific ethylenically unsaturated monomer (a) having a piperidyl group in a molecule and 50 to 99.5 parts by mass of an ethylenically unsaturated monomer (b), which does not substantially contain an ethylenically unsaturated monomer having a specific functional group in a molecule, with the total of the ethylenically unsaturated monomers (a) and (b) being 100 parts by mass, under the coexistence of 0.1 to 10 parts by mass of an emulsifier. Also disclosed are a weather resistance improver for water-based paints using the foregoing water-based resin composition, a weather resistance improver for thermoplastic resins, and a weather resistance improver for solvent-based paints.Type: ApplicationFiled: May 26, 2006Publication date: April 23, 2009Inventors: Takahiro Mukuda, Masaaki Kiura, Motomi Tanaka
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Publication number: 20090088527Abstract: The present invention relates to an attach paste composition for a semiconductor package. The attach paste composition for a semiconductor package includes a mixed resin, or a blend of an elastic resin and an epoxy resin as a basic resin. At this time, preferably the basic resin includes 50 to 95 weight % of the elastic resin and 5 to 50 weight % of the epoxy resin. The present invention enables a conventional semiconductor packaging method using a die adhesive to eliminate a pre-drying process performed after application of a die adhesive through screen printing and a thermal hardening process performed after an encapsulation process, maintains the properties of the die adhesive, ensures reliability of semiconductor products, and realizes a simple process.Type: ApplicationFiled: September 26, 2008Publication date: April 2, 2009Applicant: LS Mtron Ltd.Inventors: Joon-Mo Seo, Byoung-Un Kang, Jae-Hoon Kim, Ji-Eun Kim, Jun-Woo Lee
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Publication number: 20090054568Abstract: The objective of the present invention is to provide a thermoplastic resin composition excelling in translucency, impact resistance, heat resistance and fluidity, particularly a thermoplastic resin composition that in the production of thermoplastic resin molded items through extrusion processing, molding processing, etc., permits a wide tolerance range of processing conditions, such as low susceptibility to quality deterioration by thermal history, excelling in translucency, impact resistance, heat resistance and fluidity; and a molding thereof. The present composition comprises a rubber-reinforced resin consisting of a rubber-reinforced copolymeric resin obtained by polymerization of a vinyl-based monomer including an aromatic vinyl compound in the presence of a rubbery polymer having refractive index in the range from 1.520-1.Type: ApplicationFiled: April 14, 2006Publication date: February 26, 2009Applicant: TECHNO POLYMER CO., LTD.Inventors: Toshifumi Uejima, Koji Ishikawa, Toshiyuki Higashijima, Shigeki Sugino
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Publication number: 20090014920Abstract: The invention relates to polymer filaments and methods for their production. In particular, although not exclusively, the invention relates to conducting polymer filaments and their production from solutions of polymerisable oxidizable monomer units.Type: ApplicationFiled: June 24, 2005Publication date: January 15, 2009Applicant: MASSEY UNIVERSITYInventors: Warwick John Belcher, Alan Graham MacDiarmid, David Leslie Officer, Simon Berners Hall
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Publication number: 20090012237Abstract: It is an object of the present invention to provide a curable which has good storage stability and can give cured products retaining the high elongation characteristic originating from the polyether polymer and showing a high gel fraction and good weatherability. Thus, the present invention provides a durable composition which comprises the following two components: a polyether polymer having at least one crosslinkable functional group and a vinyl polymer which is compatible with said polyether polymer having at least one crosslinkable functional group at a polymer terminus. Further, the present invention provides a curable composition which comprises the following three components: a polyether polymer having at least one crosslinkable functional group, a vinyl polymer incompatible with said polyether polymer and having at least one crosslinkable function group, and a compatibilizing agent capable of compatibilizing said polyether polymer and said vinyl polymer with each other when added to a mixture thereof.Type: ApplicationFiled: August 6, 2008Publication date: January 8, 2009Applicant: Kaneka CorporationInventors: Nao Fujita, Yasuo Shimizu, Nobuhiro Hasegawa, Yoshiki Nakagawa
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Patent number: 7470752Abstract: Low-cure powder coating compositions are disclosed, comprising at least one epoxy-containing resin and/or at least one siloxane-containing resin, and at least one material having the structure wherein R1 is an organic radical having 6 to 25 carbon atoms; each R2 is independently a multivalent hydrocarbon group having 1 to 20 carbon atoms; Y is each R3 and R4 are independently alkyl or aryl groups having 1 to 8 carbon atoms; each Z is independently oxygen or nitrogen; R5 is absent when Z is oxygen and R5 is hydrogen, an alkyl or aryl group having 1 to 20 carbon atoms, or (Y)a—R2— when Z is nitrogen; a and b are integers; a is at least 1; b is 1 to 3; and (b) at least one epoxy-containing resin and/or at least one siloxane-containing resin. The material can optionally be reacted with an acidic hydrogen-containing compound. Some compositions are curable without using crosslinking agents or accelerators.Type: GrantFiled: June 7, 2006Date of Patent: December 30, 2008Assignee: PPG Industries Ohio, Inc.Inventors: Shawn P. Duffy, Anthony M. Chasser, Ronald R. Ambrose
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Publication number: 20080287593Abstract: The present invention relates to amphiphilic polymer compositions, to a process for their preparation and to their use for preparing aqueous active compound compositions of water-insoluble active compounds, in particular active compounds for crop protection. The amphiphilic polymer compositions can be obtained by reacting a) at least one hydrophobic polymer P1 which carries functional groups R1 which are reactive toward isocyanate groups and which is constructed of ethylenically unsaturated monomers M1, comprising: a1) at least 10% by weight, based on the total amount of monomers M1, of monomers M1a of the formula I in which X is oxygen or a group N—R4; R1, R2, R3 and R4 are as defined in the claims and the description; a2) up to 90% by weight, based on the total amount of monomers M1, of neutral monoethylenically unsaturated monomers M1b whose solubility in water at 25° C.Type: ApplicationFiled: June 7, 2005Publication date: November 20, 2008Inventors: Gunter Oetter, Christian Kruger, Harald Kohle, Maria Scherer, Norbert Wagner, Matthias Bratz, Rainer Berghaus, Richard van Gelder
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Publication number: 20080248227Abstract: The present invention provides a thermoplastic resin composition producing an extremely small amount of outgas and providing a molded article having excellent antistaticity. The present thermoplastic resin composition comprises a thermoplastic resin and is characterized in that the amount of outgas is 1500 ?g/g or less. The composition may comprise a surface resistivity reducing substance in an amount of 0.1 to 70 parts by mass relative to 100 parts by mass of the thermoplastic resin. The present invention is suitable to a composition comprising a styrenic resin as the thermoplastic resin. The surface resistivity reducing substrate is preferably a polyamide elastomer comprising a hard segment formed of polyamide 12 and a soft segment formed of poly(alkylene oxide)glycol. The polyamide elastomer preferably has a refractive index of 1.5 to 1.53, a melting point of 130 to 160° C., a solution viscosity of 1.35 to 1.70 and a surface resistivity of 1×108 to 1×1011?.Type: ApplicationFiled: March 25, 2005Publication date: October 9, 2008Inventor: Norifumi Sumimoto
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Patent number: 7432333Abstract: Low-cure powder coating compositions are disclosed, comprising at least one epoxy-containing resin and/or at least one siloxane-containing resin, and at least one material having the structure wherein R1 is an organic radical having 6 to 25 carbon atoms; each R2 is independently a multivalent hydrocarbon group having 1 to 20 carbon atoms; Y is each R3 and R4 are independently alkyl or aryl groups having 1 to 8 carbon atoms; each Z is independently oxygen or nitrogen; R5 is absent when Z is oxygen and R5 is hydrogen, an alkyl or aryl group having 1 to 20 carbon atoms, or (Y)a—R2— when Z is nitrogen; a and b are integers; a is at least 1; b is 1 to 3; and (b) at least one epoxy-containing resin and/or at least one siloxane-containing resin. The material can optionally be reacted with an acidic hydrogen-containing compound. Some compositions are curable without using crosslinking agents or accelerators.Type: GrantFiled: June 7, 2006Date of Patent: October 7, 2008Assignee: PPG Industries Ohio, Inc.Inventors: Shawn P. Duffy, Anthony M. Chasser, Ronald R. Ambrose
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Publication number: 20080242058Abstract: The adhesive composition according to the present invention is characterized by including an acrylic polymer, an epoxy resin having an epoxy equivalent of 180 g/eq or less and a thermosetting agent. According to the present invention, provided are an adhesive composition which can achieve a high package reliability in a package in which a semiconductor chip being reduced in a thickness is mounted even when exposed to severe reflow conditions, an adhesive sheet having an adhesive layer comprising the above adhesive composition and a production process for a semiconductor device using the above adhesive sheet.Type: ApplicationFiled: March 26, 2008Publication date: October 2, 2008Applicant: LINTEC CORPORATIONInventors: Isao Ichikawa, Naoya Saiki, Hironori Shizuhata
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Publication number: 20080227917Abstract: Disclosed are copolymers made of alkylene oxides and glycidyl ethers according to formula (I) in which R1 is hydrogen or a C1-C4-alkyl radical, R2 and R4 are an alkyl or aryl radical having 1 to 30 carbon atoms, and R3 is an alkyl or aryl radical having 1 to 50 carbon atoms, which may also contain heteroatoms. A is an alkylene unit having 2 to 6 carbon atoms. In formula (1), x is a number from 0 to 10, y is a number from 0 to 10, n is a number from 0 to 100, k is a number from 1 to 100, R5 is an acid group or hydrogen, and m is a number from 1 to 500, with the proviso that (y+n) must be at least 1.Type: ApplicationFiled: May 14, 2008Publication date: September 18, 2008Inventors: Uwe Falk, Hendrik Ahrens, Klaus Poellmann, Martin Glos, Eckart Kraemer
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Publication number: 20080227913Abstract: A carboxyl group-containing diene-based rubber latex composition comprising (a) a carboxyl group-containing diene-based rubber latex and one or more compounds selected from the following (b) to (e): (b) an organometallic crosslinking agent containing two or more hydroxyl groups each bonded to a metal atom; (c) a cationic property-deactivated, modified polyamine-based resin, a cationic property-deactivated polyamide-epichlorohydrin resin, a cationic property-deactivated polyamine-epichlorohydrin resin, a cationic property-deactivated amine group- or quaternary ammonium base-containing polyvinyl alcohol, a cationic property-deactivated amine group- or quaternary ammonium base-containing polyacrylamide, a cationic property-deactivated amine group- or quaternary ammonium base-containing carbohydrate, or a polyacrylamide, polyvinyl alcohol, or carbohydrate into which a crosslinkable functional group is introduced; (d) an anionic or nonionic polyvinyl alcohol, anionic or nonionic polyacrylamide, or anionic or nonType: ApplicationFiled: December 27, 2007Publication date: September 18, 2008Applicant: FOUR ROAD RESEARCH LTD.Inventor: Kazuo KOIDE
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Patent number: 7425594Abstract: A copolymer and a process of making the copolymer are disclosed. The copolymer is produced from reacting a glycidyl ester and/or ether with a polyol comprising a functionality of at least 2 wherein at least 50% by weight of the copolymer comprises a minimum of 3n+X repeating units, wherein n is a monomer unit and X is a monomer unit and/or other reactant. The copolymer may also include less than 50% of the polymeric units having the same molecular weight. The present invention is further directed to processes for preparing the copolymer and to coating compositions employing the copolymer.Type: GrantFiled: November 23, 2005Date of Patent: September 16, 2008Assignee: PPG Industries Ohio, Inc.Inventors: Jonathan T. Martz, Stephen J. Thomas
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Patent number: 7419703Abstract: The invention provides heat-curable thixotropic mixtures containing carbamate and/or allophanate groups, including at least one oligomer and/or polymer containing at least one of carbamate and allophanate groups, and at least one thixotropic agent that is a urea derivative preparable by reacting at least one amine and/or water with at least one isocyanate in the presence of at least one amino resin. The invention further provides processes for preparing the mixtures and coating materials, adhesives and sealing compounds prepared from the mixtures.Type: GrantFiled: August 26, 2005Date of Patent: September 2, 2008Assignee: BASF Coatings AGInventors: Hubert Baumgart, Michael A Gessner, Bruce Oermann, Paul J Harris
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Publication number: 20080206829Abstract: The present invention provides a polymer membrane enhanced with cured epoxy resin for use as the outer membrane of biosensors. The membrane includes approximately 30-80% epoxy resin adhesives, 10-60% polymer such as poly(vinyl chloride), polycarbonate and polyurethane and 0-30% plasticizers and 5-15% surface modifier reagent such as polyethylene oxide-containing block copolymers. Utilizing the polymer membrane of the present invention, a three-layered sensing element has been developed. This sensing element will be particularly useful for miniaturized biosensors used for in vitro blood measurements or for continuous in vivo monitoring such as implantable biosensors. This element includes an enzyme layer, an interference-eliminating layer and the novel polymer member of the present invention as the outer polymer layer. This novel sensing element shows excellent response characteristics in solutions and has an extremely long lifetime.Type: ApplicationFiled: January 17, 2008Publication date: August 28, 2008Applicant: UNIVERSITY OF SOUTH FLORIDAInventors: Bazhang Yu, Francis Moussy
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Publication number: 20080200599Abstract: An aqueous epoxy resin system ABC comprising an aqueously dispersed epoxy resin A having, on the average, at least one epoxy group per molecule, a water-soluble or water-dispersible curing agent B which comprises the reaction product of an amine B1 having at least one primary and at least one secondary amino group, and an adduct B2 of a polyalkylene ether polyol B21 and an opexide component B22, and aminoplast compound C having a mass fraction of at least 0.1% of sulphonate or sulphonic acid groups, a coating composition ABCD for thick layer applications comprising the aqueous epoxy resin system ABC and at least one particulate filler D selected from the group consisting of talc, mica, quartz, titanium dioxide, aluminium dioxide, calcium carbonate, and dolomite, and a process for coating mineral or concrete based substrates or floors with such coating compositions.Type: ApplicationFiled: September 30, 2005Publication date: August 21, 2008Applicant: Cytec Surface Specialties Austria GmbHInventors: Rosemaria Grasboeck, Manfred Gobb, Martin Gerlitz, Andreas Gollner, Johann Wonner, Florian Lunzer
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Patent number: 7402629Abstract: The present invention is directed to a golf ball having at least one layer, such as a center, a cover layer, or an intermediate layer, which is formed from a polymer composition comprising at least 25 wt %, based on the total polymeric weight of the polymer composition, of an acid polymer having acid groups, wherein at least 90% of the acid groups are neutralized. The polymer composition also comprises at least 10 wt %, based on the total polymeric weight of the polymer composition, of a non-fatty acid melt flow modifier selected from polyesters, polyacrylates, polyurethanes, polyethers, thermoplastic polyureas, and combinations thereof. The polymer composition is substantially free of fatty acids and their salts and has a melt flow index of from 0.5 g/10 min to 10.0 g/10 min.Type: GrantFiled: August 31, 2005Date of Patent: July 22, 2008Assignee: Acushnet CompanyInventor: Murali Rajagopalan
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Patent number: 7381774Abstract: Perfluoroelastomers that contain high levels (i.e. about 40 mole percent or more) of perfluoro(alkyl vinyl ether) copolymerized units can form stable blends with higher levels of perfluoropolyethers than can perfluoroelastomers that contain lower levels of perfluoro(alkyl vinyl ether) units. Thus, the former blends have better low temperature properties than the latter.Type: GrantFiled: October 25, 2005Date of Patent: June 3, 2008Assignee: DuPont Performance Elastomers, LLCInventors: Christopher John Bish, Michael Cregg Coughlin
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Publication number: 20080115291Abstract: A composition useful for treating fabrics. The composition contains a silver-containing copolymer having polymerized units of a monomer X and a monomer Y; wherein monomer X is an ethylenically unsaturated compound having a substituent group selected from an unsaturated or aromatic heterocyclic group having at least one hetero atom selected from N, O and S; wherein monomer Y is selected from carboxylic acids, carboxylic acid salts, carboxylic acid esters, organosulfuric acids, organosulfuric acid salts, sulfonic acids, sulfonic acid salts, phosphonic acids, phosphonic acid salts, vinyl esters, (meth)acrylamides, C8-C20 aromatic monomers containing at least one exocyclic ethylenic unsaturation and combinations thereof.Type: ApplicationFiled: October 29, 2007Publication date: May 22, 2008Inventors: Stephanie Nussbaum Cottrell, Tirthankar Ghosh
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Publication number: 20080119613Abstract: The present invention provides water-soluble products formed by reacting a monofunctional, amine-terminated polyether with a glycidyl ether of a polyol, which products are useful as dispersants in end uses and formulations known to employ dispersants. The invention also provides processes which comprises reacting a monofunctional, amine-terminated polyether with a glycidyl ether of a polyol.Type: ApplicationFiled: May 10, 2005Publication date: May 22, 2008Applicant: Huntsman Petrochemical CorporationInventors: Howard P. Klein, Christopher J. Whewell
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Patent number: 7365123Abstract: Thermoplastic polymer compositions, films, continues, closures, laminates can comprise a modified vinyl polymer said modified polymer having a moiety comprising a cyclodextrin compound. The cyclodextrin compound, locked into the polymer structure, can absorb impurities, permeants, or other undesirable volatile materials. The cooperation between the cyclodextrin grafted onto the thermoplastic polymer and the polymer structure can provide barrier properties to a film, web or other polymer structure. A permeant or a contaminant can be complexed or trapped within the polymer and held within the film or Web preventing the permeant or contaminant from passing into the interior of a container or enclosure.Type: GrantFiled: April 13, 2006Date of Patent: April 29, 2008Assignee: Cellresin Technologies, LLCInventors: Willard E. Wood, Neil J. Beaverson, Kasyap V. Seethamraju
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Patent number: 7365128Abstract: The present invention is directed to a golf ball having at least one layer which includes a polymer composition containing at least 50 wt % of an acid polymer and at least 0.5 wt % of a polyhydric alcohol, wherein the weight percentages are based on the total polymeric weight of the polymer composition. At least 70% of the acid groups of the acid polymer are neutralized by a cation source or a metal salt thereof.Type: GrantFiled: August 31, 2005Date of Patent: April 29, 2008Assignee: Acushnet CompanyInventor: Michael J. Sullivan
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Publication number: 20080021163Abstract: The present invention provides a resin composition for an adhesive sheet, comprising an acrylic copolymer containing (A) an acrylate ester, methacrylate ester, or a mixture thereof, (B) acrylonitrile, methacrylonitrile, or a mixture thereof, and (C) an unsaturated carboxylic acid; an epoxy resin; and a curing agent, wherein the curing agent comprises at least one selection from Lewis acid-amine complexes.Type: ApplicationFiled: July 17, 2007Publication date: January 24, 2008Applicant: Arisawa Mfg. Co., Ltd.Inventors: Shinichi Hasegawa, Fumiki Higuchi, Toru Ueki
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Patent number: 7279546Abstract: The present invention provides thermoplastic hydroxy-functional polyesters. The polyesters have at least 10 sequential units, wherein the sequential units consist of units selected from units represented by the following formula (1) and units represented by the following formula (2); Wherein each of R1 independently represents hydrogen or a substituted or unsubstituted homoalkyl or heteroalkyl group; each of R2 independently represents hydrogen or a substituted or unsubstituted homoalkyl or heteroalkyl group; each of R3 independently represents hydrogen or a substituted or unsubstituted homoalkyl or heteroalkyl group; Each of R4 independently represents a substituted or unsubstituted homoalkyl or heteroalkyl group; and said moiety having no fewer than 1 unit represented by formula (1) and no fewer than 1 unit represented by formula (2).Type: GrantFiled: July 16, 2002Date of Patent: October 9, 2007Assignee: Dow Global Technologies, Inc.Inventors: Jerry E. White, Zenon Lysenko, Jimmy D. Earls, Marvin L. Dettloff, James A. Rabon, Jr., Leonardo C. Lopez
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Patent number: 7166675Abstract: A thermosetting protective and/or decorative coating composition that includes a co-reactable solid, particulate mixture of a film-forming material that includes a copolymer containing functional groups and a crosslinking agent having at least two functional groups that are reactive with the functional groups in the copolymer. The film-forming material makes up from 20 to 95 wt. % and the crosslinking agent makes up from 5 to 80 wt. % of the composition. The composition is applied as a coating and cured, forming a bicontinuous morphology where the film-forming material and the crosslinking agent form separate phases resulting in a low gloss coating as indicated by a specular gloss measurement of not more than 10 gloss units measured at 60° with an appropriate instrument. A method of coating a substrate using the composition, substrates coated using the method, and a multi-component composite coating composition that includes the composition are disclosed.Type: GrantFiled: January 30, 2004Date of Patent: January 23, 2007Assignee: PPG Industries Ohio, Inc.Inventors: Kristin M. Bartlett, Simion Coca, Anthony M. Chasser
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Patent number: 7160707Abstract: A process for the preparation of coated polymer particles containing superparamagnetic crystals, said process comprising reacting porous, surface-functionalized, superparamagnetic crystal-containing polymer particles of diameter 0.5 to 1.8 ?m with at least one polyisocyanate and at least one diol or at least one epoxide.Type: GrantFiled: March 3, 2005Date of Patent: January 9, 2007Assignee: Dynal Biotech ASAInventors: Geir Fonnum, Nini Kjus Hofsløkken, Elin Marie Aksnes, Lars Kilaas, Arvid Trygve Berge, Ruth Schmid, Jon Olav Bjorgum
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Patent number: 7160962Abstract: Elastomer-modified Epoxy-polysiloxane compositions of this invention are prepared by combining a silicone intermediate, with an epoxy resin, an elastomeric resinous intermediate, a polyfunctional amine, an optional organometallic catalyst, and optional fillers, pigments, and processing agents. The composition is prepared using a sufficient amount of water to promote hydrolysis of the polysiloxane and the polycondensation of the silanols produced by such hydrolysis. In its cured form, the epoxy-polysiloxane composition exists as a uniformly dispersed arrangement of linear epoxy chain fragments that are cross-linked with a continuous polysiloxane polymer chain, wherein either or both of the epoxy and/or polysiloxane polymers are elastomer modified to provide coatings and floorings having significantly improved properties of impact resistance, flexibility, crack resistance, and abrasion resistance with compared to conventional epoxy systems.Type: GrantFiled: October 27, 2003Date of Patent: January 9, 2007Assignee: Ameron International CorporationInventor: Haruji Sakugawa
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Patent number: 7144950Abstract: Methods, compositions and articles of manufacture involving cationic conjugated conformationally flexible polymers are provided. A method for the synthesis of cationic water-soluble polymers with linkages along the polymer main chain structure which disrupt the ability of the polymers to form extended-rod structures is provided. Such polymers may serve in the fabrication of novel optoelectronic devices and in the development of highly efficient biosensors. The invention further relates to the application of these polymers in assay methods.Type: GrantFiled: September 17, 2003Date of Patent: December 5, 2006Assignee: The Regents of the University of CaliforniaInventors: Guillermo C. Bazan, Bin Liu
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Patent number: 7109258Abstract: A polymeric material with antistatic properties, characterised by comprising a dispersion of ions within a polymeric matrix containing heteroatoms.Type: GrantFiled: January 5, 2000Date of Patent: September 19, 2006Assignees: Cryvet S.R.L.Inventors: Gualtiero Valeri, Vito Di Noto
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Patent number: 7091286Abstract: Low-cure powder coating compositions are disclosed, comprising at least one epoxy-containing resin and/or at least one siloxane-containing resin, and at least one material having the structure wherein R1 is an organic radical having 6 to 25 carbon atoms; each R2 is independently a multivalent hydrocarbon group having 1 to 20 carbon atoms; Y is each R3 and R4 are independently alkyl or aryl groups having 1 to 8 carbon atoms; each Z is independently oxygen or nitrogen; R5 is absent when Z is oxygen and R5 is hydrogen, an alkyl or aryl group having 1 to 20 carbon atoms, or (Y)a —R2— when Z is nitrogen; a and b are integers; a is at least 1; b is 1 to 3; and (b) at least one epoxy-containing resin and/or at least one siloxane-containing resin. The material can optionally be reacted with an acidic hydrogen-containing compound. Some compositions are curable without using crosslinking agents or accelerators.Type: GrantFiled: September 29, 2003Date of Patent: August 15, 2006Assignee: PPG Industries Ohio, Inc.Inventors: Shawn P. Duffy, Anthony M. Chasser, Ronald R. Ambrose
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Patent number: 7071263Abstract: Epoxy adhesives are reported that comprise: (i) about 20% to about 40% weight of a reactive oligomer having a glass transition temperature of about ?40° C. or less after curing and having at least two functional groups selected from epoxide, isocyanate, and amine; (ii) an amine curative; and (iii) an epoxide-group containing compound. The epoxy adhesives are resistant to thermal shock and have a low shear creep. The epoxy adhesives are particularly suitable for bonding substrates having mismatched coefficients of thermal expansion.Type: GrantFiled: May 19, 2003Date of Patent: July 4, 2006Assignee: 3M Innovative Properties CompanyInventors: Ming Cheng, Ying-Yuh Lu
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Patent number: 7045576Abstract: The present invention comprises novel polyoxyethylene/polyoxypropylene block copolymers compositions and compounds. The compositions comprise block copolymers that are useful in gene therapy methods.Type: GrantFiled: July 9, 2004Date of Patent: May 16, 2006Assignee: Cytrx CorporationInventors: Mannarsamy Balasubramanian, Mark Joseph Newman, R. Martin Emanuele, Carlos A. Rivera-Marrero, Charles William Todd, Robert Newton Brey, III
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Patent number: 7001951Abstract: Extrusion processability of non-fluorinated melt-processable polymers is improved by introducing a fluoropolymer process aid by means whereby the weight average particle size of the fluoropolymer is greater than 2 microns as it reaches the extruder die entrance.Type: GrantFiled: February 11, 2003Date of Patent: February 21, 2006Assignee: Dupont Dow Elastomers, LLCInventors: George Richard Chapman, Jr., Steven Richard Oriani
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Patent number: 6894113Abstract: The present invention relates to a thermoset material with improved impact resistance comprising: 99 to 20% of a thermoset resin, and 1 to 80% of an impact modifier comprising at least one copolymer comprising S-B-M, B-M and M-B-M blocks, wherein: each block is connected to the other by means of a covalent bond or of an intermediate molecule connected to one of the blocks via a covalent bond and to the other block via another covalent bond, M is a PMMA homopolymer or a copolymer comprising at least 50% by weight of methyl methacrylate, B is incompatible with the thermoset resin and with the M block and its glass transition temperature Tg is less than the operating temperature of the thermoset material, and S is incompatible with the thermoset resin, the B block and the M block and its Tg or its melting temperature is greater than the Tg of B. S is advantageously polystyrene and B polybutadiene.Type: GrantFiled: May 17, 2001Date of Patent: May 17, 2005Assignee: AtofinaInventors: Francois Court, Ludwik Leibler, Jean-Pierre Pascault, Sophie Ritzenthaler
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Patent number: 6835776Abstract: Thermoplastic molding materials containing the following ingredients with regard to components A-F: A) 5-70 wt. % of at least one graft copolymer A) consisting of a rubber elastic base with a glass transition temperature below 0° and a grafted overlay made of a styrene compound and acrylonitrile or methacrylonitrile or mixture thereof in addition to, optionally, other monoethylenically unsaturated monomers, B) 29-90 wt. % of a hard copolymer made of at least one styrene compound, acrylonitrile or methacrylonitrile or mixtures thereof and, optionally, other monoethylenically unsaturated monomers, C) 0-5 wt. % of at least one three-block copolymer X-Y-X with a middle block Y propylenoxide units and terminal block X made of ethyleneoxide units, D) 0.01-5 wt. % of at least one butylated reaction product of cresol with dicyclopentadiene, E) 0.01-5 wt. % of at least one thiocarboxylic acid ester, F) 0.01-5 wt.Type: GrantFiled: November 25, 2002Date of Patent: December 28, 2004Assignee: BASF AktiengesellschaftInventors: Norbert Güntherberg, Bernhard Czauderna, Peter Ittemann
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Patent number: 6831130Abstract: A curable composition comprises a polyether polymer having at least one crosslinkable functional group and a vinyl polymer compatible therewith having at least one crosslinkable functional group at a terminus. Another aspect includes a compatibilizing agent capable of compatibilizing the polyether polymer and vinyl polymer when added to the mixture thereof.Type: GrantFiled: April 4, 2003Date of Patent: December 14, 2004Assignee: Kaneka CorporationInventors: Nao Fujita, Yasuo Shimizu, Nobuhiro Hasegawa, Yoshiki Nakagawa
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Patent number: 6815499Abstract: An object of the present invention is to substantially improve the compatibility between a radical copolymerizable unsaturated resin and an addition polymerized polymer (thermoplastic resin) which is added for the purpose of low profile and improvement of physical properties. The present invention provides a compatibilizing agent for compatibilizing a radical copolymerizable unsaturated resin with an addition polymerized polymer, characterized in that said compatibilizing agent is a graft copolymer (A) which contains a styrene monomer as a principal component, and has a principal chain (A1) consisting of a copolymer with a (meth)acrylate monomer and a side chain (A2) selected from a ring-opening polymerized polyether side chain consisting of a polyoxyalkylene ether, a polyester side chain, and a polycarbonate side chain, the side chain (A2) being bonded to the principal chain.Type: GrantFiled: February 14, 2002Date of Patent: November 9, 2004Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Takashi Yasumura, Akira Takano
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Publication number: 20040157997Abstract: Disclosed are adhesive compositions include polymerizable resin, preferably in an amount of from about 10 wt % to about 90 wt % and multifunctional acrylate, preferably in an amount of from about 5 wt % to about 30 wt %. The polymerizable resin can include free radical initiated vinyl addition resins. The adhesives in preferred embodiments exhibit enhanced bonding strength of the adhesive at high temperatures, such as at about 80° C., and enhanced the fire resistance.Type: ApplicationFiled: October 6, 2003Publication date: August 12, 2004Applicant: Illinois Tool Works Inc.Inventors: Wen-Feng Liu, Barbara Chabut
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Patent number: 6753069Abstract: A resin composition for an ink jet recording sheet, an ink jet recording sheet, a method for ink jet recording, and a method for producing an ink jet recording sheet are provided, wherein an ink absorption ability and a blurring suppressive effect are satisfactorily achieved. The ink jet recording sheet is prepared from a substrate layer and an ink-receiving layer that is overlaid said substrate layer. The ink-receiving layer contains (1) a major component of a water-absorbing polymer compound represented by the formula (I), and (2) a cationic polymer compound. A mixing ratio by weight of the water-absorbing polymer compound (1) and the cationic polymer compound (2) may be in the range between 50/50 and 99/1. A cationic or nonionic surface active agent (3) may be contained in the ink-receiving layer in an amount from 1% by weight to 10% by weight.Type: GrantFiled: March 29, 2001Date of Patent: June 22, 2004Assignees: Dai-Ichi Kogyo Seiyaku Co., Ltd., Mitsubishi Plastics, Inc.Inventors: Katsuaki Matsuo, Takayuki Tsubaki
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Patent number: 6753079Abstract: A process for preparing polyacrylic hotmelt pressure sensitive adhesives, which comprises the following steps: (a) compounding an acrylic hotmelt pressure sensitive adhesive containing at least one functional group X, having a solvent content of not more than 0.5% by weight and a molecular mass MW of from 100,000 to 2,000,000 g/mol, with at least one chemical substance R—Y containing at least one functional group Y, said at least one functional group X and said at least one functional group Y being chosen such that they are capable of undergoing a coupling reaction with one another, (b) treating the compound in a reactor with a mixing apparatus at a specific drive energy of not more than 0.09 kWh/kg and at a temperature of from 80 to 200° C., (c) transferring the self-adhesive composition thus treated to a downstream coating unit, and applying it from the melt to a backing material.Type: GrantFiled: June 12, 2002Date of Patent: June 22, 2004Assignee: Tesa AGInventors: Marc Husemann, Stephan Zöllner
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Patent number: 6734252Abstract: A polymer processing aid composition, a melt processable thermoplastic hydrocarbon polymer composition that uses the polymer processing aid, and a method of improving the melt processability of a thermoplastic hydrocarbon polymer are provided. The polymer processing aid composition comprises a major amount of a fluorothermoplastic polymer that comprises interpolymerized units derived from vinylidene fluoride, at least one ethylenically unsaturated copolymerizable fluorinated monomer, and, optionally, at least one low molecular weight non-fluorinated olefin monomer.Type: GrantFiled: January 29, 1999Date of Patent: May 11, 2004Assignee: 3M Innovative Properties CompanyInventor: Susan S. Woods
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Patent number: 6726961Abstract: It is an object of the present invention to provide a method of forming a composite coating film having high flip-flop properties by applying a water-based base coat coating to a substrate, then applying a clear top coat coating thereonto and curing both coatings simultaneously while controlling the interlayer imbibing or inversion of coating films under high humidity conditions. The present invention provides a method of forming a composite coating film by applying a water-based base coat coating to a substrate and then applying a clear top coat coating thereonto, wherein the water-based base coat coating comprises: a polyether polyol having at least 0.02 primary hydroxyl group, on average, per molecule, a number average molecular weight of 300 to 3,000 and a water tolerance of not less than 2.Type: GrantFiled: February 26, 2001Date of Patent: April 27, 2004Assignee: Nippon Paint Co., Ltd.Inventors: Manabu Yoshioka, Shigeyuki Sasaki, Hifumi Egusa, Atsuo Magoshi
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Publication number: 20040076820Abstract: A method for producing a composite product including a substrate material and a binder, wherein either the binder includes a plastics material in an emulsion form, or a plastics material is added to an emulsion including the substrate material. The invention is also directed to composite products including a particulate substrate and particles of a plastics material therein.Type: ApplicationFiled: October 31, 2003Publication date: April 22, 2004Inventor: Thomas Clarence Hodgson
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Patent number: 6673446Abstract: A fiber composition which comprises a blend of modified polypropylene and modified poly(ethylene oxide). This fiber composition can be melt-processed to make fibers useful in flushable personal care products. A process for making this fiber composition is also provided.Type: GrantFiled: April 23, 2001Date of Patent: January 6, 2004Assignee: Kimberly-Clark Worldwide, Inc.Inventors: James H. Wang, David M. Schertz
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Patent number: 6670428Abstract: An object of the present invention is to substantially improve the compatibility between a radical copolymerizable unsaturated resin and an addition polymerized polymer (thermoplastic resin) which is added for the purpose of low profile and improvement of physical properties. The present invention provides a compatibilizing agent for compatibilizing a radical copolymerizable unsaturated resin with an addition polymerized polymer, characterized in that said compatibilizing agent is a graft copolymer (A) which contains a styrene monomer as a principal component, and has a principal chain (A1) consisting of a copolymer with a (meth)acrylate monomer and a side chain (A2) selected from a ring-opening polymerized polyether side chain consisting of a polyoxyalkylene ether, a polyester side chain, and a polycarbonate side chain, the side chain (A2) being bonded to the principal chain.Type: GrantFiled: November 15, 2000Date of Patent: December 30, 2003Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Takashi Yasumura, Akira Takano
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Patent number: 6657007Abstract: Clearcoat coating composition for automotive exterior coatings with improved intercoat adhesion to a subsequently applied coating layer and improved flexibility contains (a) a first vinyl copolymer prepared from a monomer mixture including no more than about 35% by weight of nonfunctional monomers that has carbamate functionality and hydroxyl functionality, at least part of the hydroxyl functionality being on monomer units including an optionally branched alkyl group having at least about six carbon atoms; (b) a second vinyl copolymer having hydroxyl functionality, preferably primary hydroxyl functionality; and (c) a curing agent component that includes at least an aminoplast curing agent and optionally a polyisocyanate curing agent. The polyisocyanate curing agent is preferably blocked with a blocking agent that volatilizes during the cure reaction, regenerating a reactive isocyanate group.Type: GrantFiled: December 14, 2001Date of Patent: December 2, 2003Assignee: BASF CorporationInventors: John A. Gilbert, Donald H. Campbell, Vincent Cook
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Patent number: 6649700Abstract: A thermosetting powder coating composition prepared by a wet process, which contains a mixture comprising (a) an epoxy-containing acrylic resin, (b) a polycarboxylic acid compound curing agent, (c) fine crosslinked resin particles and, optionally, (d) a resin that exists in the liquid form at room temperature.Type: GrantFiled: September 21, 2001Date of Patent: November 18, 2003Assignee: Nippon Paint Co., Ltd.Inventors: Masami Yabuta, Yutaka Harada, Atsushi Yamada, Yasuhiko Nakae, Kazuhiko Nishimura, Haruhiko Sato
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Patent number: 6639025Abstract: Elastomer-modified Epoxy-polysiloxane compositions of this invention are prepared by combining a silicone intermediate, with an epoxy resin, an elastomeric resinous intermediate, a polyfunctional amine, an optional organometallic catalyst, and optional fillers, pigments, and processing agents. The composition is prepared using a sufficient amount of water to promote hydrolysis of the polysiloxane and the polycondensation of the silanols produced by such hydrolysis. In its cured form, the epoxy-polysiloxane composition exists as a uniformly dispersed arrangement of linear epoxy chain fragments that are cross-linked with a continuous polysiloxane polymer chain, wherein either or both of the epoxy and/or polysiloxane polymers are elastomer modified to provide coatings and floorings having significantly improved properties of impact resistance, flexibility, crack resistance, and abrasion resistance with compared to conventional epoxy systems.Type: GrantFiled: February 1, 2002Date of Patent: October 28, 2003Assignee: Ameron International CorporationInventor: Haruji Sakugawa
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Patent number: 6635351Abstract: It is an object of the invention to provide a clear coating composition, which can give coating films showing good water repellency, in other words a factor giving a care-free and deluxe feeling to car owners, and which are excellent in non-sanding recoatability in recoating dirtied coatings after due repair, as well as a method of forming a coating film and a multilayerd coating film. The invention provides a clear coating composition which comprises (A) 100 parts by mass of the sum of a crosslinkable coating film-forming resin and a crosslinking agent on the solid basis and (B) 0.01 to 2 parts by mass of a ladder silicone copolymer obtainable by copolymerizing (b-1) a (meth)acryloxyalkyl-containing ladder silicone oligomer, (b-2) a crosslinkable functional group-containing ethylenically unsaturated monomer and optionally (b-3) another copolymerizable ethylenically unsaturated monomer.Type: GrantFiled: July 31, 2001Date of Patent: October 21, 2003Assignees: Nissan Motor Co., Ltd., Nippon Paint Co., Ltd.Inventors: Tatsuya Ishihara, Masahiko Yamanaka, Tetsuji Mizuno, Takashi Moriwake, Hisaki Tanabe, Goro Nagao
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Patent number: 6599979Abstract: A polymer composition containing carboxyl group which is excellent in water solubility, thickening properties and flow characteristics. This composition comprises (A) a cross-linked polymer comprising (a) an &agr;,&bgr;-unsaturated carboxylic acid and (b) a compound having at least two ethylenically unsaturated groups, and (B) at least one polymer selected from among polymers comprising vinylpyrrolidone as an essential monomer and polyethylene oxide.Type: GrantFiled: November 15, 1999Date of Patent: July 29, 2003Assignee: Sumitomo Seika Chemicals Co., Ltd.Inventors: Masato Fujikake, Shinji Kobayashi, Shigeki Hamamoto, Mitsutaka Tabata, Tomoki Kawakita