At Least One Reactant Which Forms Additional Polymer Contains A Sulfur Atom Patents (Class 525/189)
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Patent number: 11773260Abstract: A thermoplastic resin composition includes base resin, which includes a polycarbonate resin and an acrylonitrile-butadiene-styrene (ABS) resin, and an additive. The ABS resin includes a rubber-modified vinyl-based graft copolymer resin, an aromatic vinyl-vinyl cyanide-based copolymer resin. The polycarbonate resin has a weight-average molecular weight of 20,000 g/mol to 40,000 g/mol, and the rubber-modified vinyl-based graft copolymer resin comprises 50 wt % to 60 wt % of polybutadiene rubber based on a total wt % of the thermoplastic resin composition.Type: GrantFiled: October 19, 2021Date of Patent: October 3, 2023Assignees: Hyundai Motor Company, Kia Corporation, Lotte Chemical CorporationInventors: Woo Chul Jung, Jun Ho Song, Choon Soo Lee, Choon Ho Lee, Kyoung Ju Kim, Young Seung Kim, Young Hyo Kim, Hyun Uk Jeon
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Patent number: 11458767Abstract: A pneumatic tire includes bead cores, a carcass ply, an inner liner and the tread, and the crosslinked rubber composition, of the present invention, wherein the tread and the crosslinked rubber composition have a volume of the low density region of 35% or more at elongation by an applied stress of 1.5 MPa, a volume of the void portion of 7.5 or less at elongation by an applied stress of 3.0 MPa and a ratio of 40% by mass or more of a component having a weight-average molecular weight of not less than 1,000,000 in a molecular weight distribution measured by gel permeation chromatography are excellent in abrasion resistance.Type: GrantFiled: October 21, 2016Date of Patent: October 4, 2022Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.Inventors: Ryo Mashita, Hiroyuki Kishimoto, Ryota Kitago
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Patent number: 11319441Abstract: A method for forming a polyarylene sulfide with a relatively low content of volatile malodorous compounds is provided. More particularly, such low compound levels may be achieved by subjecting a washed polyarylene sulfide to a heat treatment in the presence of an atmosphere that includes an inert gas, wherein the heat treatment occurs at a temperature of from about 150° C. to about 275° C.Type: GrantFiled: December 4, 2020Date of Patent: May 3, 2022Assignee: Ticona LLCInventor: Hendrich A. Chiong
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Patent number: 11167263Abstract: A polymeric polysulfide is disclosed. The polymeric polysulfide is formed by reacting a fatty acid composition comprising at least one unsaturated fatty acid or derivative thereof with sulfur, at a weight ratio between 9:1 and 1:9, under inverse vulcanisation conditions to produce a polymeric polysulfide wherein at least 50% of the fatty acids or derivatives thereof in the fatty acid composition are unsaturated.Type: GrantFiled: April 20, 2017Date of Patent: November 9, 2021Assignee: CLEAN EARTH TECHNOLOGY PTY LTDInventors: Justin Mark Chalker, Max John Haldane Worthington
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Patent number: 11066542Abstract: The present invention relates to a method of preparing a thermoplastic resin, a method of preparing a thermoplastic resin composition including the same, and a method of manufacturing an injection-molded article using the thermoplastic resin composition. By using a mixture of molecular weight modifiers having different reactivities according to the present invention, coagulation may be performed using a small amount of coagulant, productivity may be increased, and a molded article, which is manufactured using a thermoplastic resin, having excellent appearance characteristics along with superior mechanical strength, processability, or the like may be provided.Type: GrantFiled: November 15, 2017Date of Patent: July 20, 2021Assignee: LG CHEM, LTD.Inventors: Jong Beom Kim, Joo Byung Chai, Yu Sung Jung, Chang Sull Kim, Eun Seon Park, Tae Young Jeon, Young Min Kim
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Patent number: 10730981Abstract: A thermoplastic resin composition includes a graft copolymer (A) obtained by graft copolymerization of a monomer mixture (a) that includes at least an aromatic vinyl monomer (a1) and a (meth)acrylate monomer (a2), but does not practically contain a vinyl cyanide monomer (a3), in the presence of a rubbery polymer (r) having a refractive index of not lower than 1.510 and not higher than 1.520; and a vinyl copolymer (B). An acetone insoluble component (C) of the thermoplastic resin composition does not practically contain a vinyl cyanide monomer-derived unit. An acetone soluble component (D) of the thermoplastic resin composition contains the vinyl cyanide monomer-derived unit. The content of the vinyl cyanide monomer-derived unit is not lower than 2% by mass and not higher than 20% by mass relative to 100% by mass of the acetone soluble component (D).Type: GrantFiled: March 23, 2018Date of Patent: August 4, 2020Assignee: Toray Industries, Inc.Inventors: Takuya Shibata, Taku Araki, Takayuki Hase
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Patent number: 10308745Abstract: A copolymer has blood compatibility and antithrombotic properties of greatly suppressing protein adhesion to be usable even when in contact with a biological component such as blood for a long period of time, and a medical device uses the copolymer. The copolymer is characterized by including a hydrophilic unit and a hydrophobic unit, wherein the hydrophobic unit contains at least one type of a carboxylic acid vinyl unit, and the number of carbon atoms at the terminal of a side chain of the carboxylic acid vinyl unit is 2-7.Type: GrantFiled: March 15, 2016Date of Patent: June 4, 2019Assignee: Toray Industries, Inc.Inventors: Suguru Ushiro, Hiroshi Takahashi, Yoshiyuki Ueno
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Patent number: 10156303Abstract: Molded articles are disclosed having a complex three-dimensional shape. In one embodiment, the molded articles comprise tubular members formed through blow molding that have multiple linear sections separated by curved sections. The curved sections can include multiple angular displacements in multiple planes. The tubular members are molded from a polymer composition containing a high temperature polymer, such as a polymer having a melting point of greater than about 280° C., such as greater than about 290° C. In one embodiment, the tubular member includes at least three angular displacements of from about 60° to about 120°, such as from about 70° to about 110°.Type: GrantFiled: December 22, 2011Date of Patent: December 18, 2018Assignee: Ticona LLCInventors: Ke Feng, Jeroen Visjager, Xinyu Zhao
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Patent number: 9217725Abstract: Compositions containing vinyl polymers and ionophores selective for lead ions (e.g., aniline copolymers), and methods for making these compositions are disclosed herein. The compositions can, for example, be used for detecting lead ions in a sample.Type: GrantFiled: November 25, 2011Date of Patent: December 22, 2015Assignee: Tongji UniversityInventors: Mei-rong Huang, Hao Feng, Xin-gui Li
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Publication number: 20150141550Abstract: The present invention relates to a polyarylene sulfide resin composition having excellent impact resistance in which a polyarylene sulfide resin having a specific end group, an epoxy-containing olefin-based elastomer, and/or an organic or inorganic filler are included, and a preparation method thereof.Type: ApplicationFiled: June 5, 2013Publication date: May 21, 2015Applicant: SK CHEMICALS CO.,LTD.Inventors: Byoung Gook Kang, Il-Hoon Cha, Sung-Gi Kim, Se-Ho Lee
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Publication number: 20150135403Abstract: Polymer compositions including blends of approximately 90 to approximately 60 percent by weight acrylonitrile butadiene copolymer and approximately 10 to approximately 40 percent by weight polychloroprene copolymer are disclosed. Methods for manufacturing unsupported gloves and for supported gloves including a knitted liner with the polymer compositions, producing gloves having an ANSI abrasion resistance level 4, are also disclosed.Type: ApplicationFiled: November 17, 2014Publication date: May 21, 2015Inventors: Agustin Portillo Mercado, Miguel Angel Sanchez Gonzalez, Fernando Dominguez, Marco Antonio Carrillo Urenda
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Patent number: 9023914Abstract: A new process is provided for preparing nitrile rubbers by free-radical polymerization in an organic solvent and in the presence of specific modifier substances. This polymerization may be followed by hydrogenation to give likewise new hydrogenated nitrile rubbers, the hydrogenation advantageously taking place likewise in organic solvent. The optionally hydrogenated nitrile rubbers obtained are notable for having fragments of the employed modifier substances in the main polymer chain and/or as end groups. They can be prepared with a wide diversity of molecular weights and polydispersity indices, especially with very low polydispersity indices.Type: GrantFiled: August 31, 2010Date of Patent: May 5, 2015Assignee: LANXESS Deutschland GmbHInventors: Michael Klimpel, Sven Brandau, Uwe Westeppe, Christopher Barner-Kowollik, Andreas Kaiser
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Publication number: 20150072093Abstract: Thermoplastic compositions are described that exhibit resistance to hydrocarbon absorption. Methods for forming the thermoplastic compositions are also described. Formation methods include combining a polyarylene sulfide with a first impact modifier and a second impact modifier such that the impact modifiers are dispersed throughout the polyarylene sulfide. A crosslinking agent can be combined with the other components of the composition following dispersal of the additives throughout the composition to dynamically crosslink at least one of the first and second impact modifiers.Type: ApplicationFiled: August 25, 2014Publication date: March 12, 2015Inventors: Bin Zhang, Rong Luo, Xiaoyan Tu
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Patent number: 8956723Abstract: A coating liquid for coating glass fiber cords, containing: a chlorophenol-formaldehyde condensate (A) obtained by condensing a chlorophenol (D) and formaldehyde (E) in water; an emulsion of a vinylpyridine-styrene-butadiene copolymer (B); and an emulsion of a chlorosulfonated polyethylene (C).Type: GrantFiled: March 29, 2007Date of Patent: February 17, 2015Assignee: Central Glass Company, LimitedInventors: Katsuhiko Ogaki, Toshiya Monden, Takafumi Iwano
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Publication number: 20140350187Abstract: Provided is a curable resin composition comprising a thermoplastic resin (A) that includes a cyclic structure in its main chain, and has a glass transition temperature (Tg) of 140° C. or more, and a monofunctional curable monomer (B). The present invention provides: a cured resin formed article that has heat resistance and low birefringence, a method for producing the same, a curable resin composition and a curable resin formed article that are useful as a raw material for producing the cured resin formed article, and a laminate that includes a layer formed of a cured resin.Type: ApplicationFiled: December 11, 2012Publication date: November 27, 2014Applicant: LINTEC CORPORATIONInventors: Masaharu Ito, Wataru Iwaya, Hironobu Fujimoto, Naoki Taya
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Publication number: 20140308866Abstract: A multicomponent fiber having an exposed outer surface with the fiber having at least a first component of polyarylene sulfide polymer; and at least a second component of a thermoplastic polymer free of polyarylene sulfide polymer, wherein said thermoplastic polymer forms the entire exposed surface of the multicomponent fiber and is polymethylpentene.Type: ApplicationFiled: April 10, 2013Publication date: October 16, 2014Applicant: E I DU PONT DE NEMOURS AND COMPANYInventors: RAKESH NAMBIAR, HARRY VAUGHN SAMUELSON
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Publication number: 20140303268Abstract: Compositions and processes for development of sustainable materials based upon a method of thermoplastic polymer recycling with a solvent that is also a monomer for renewable polymer synthesis. By combining petroleum-derived polymers with bio-based monomer feedstocks, biphasic, blended polymer products are produced and are shown to exhibit facile tunability of physical and material properties. This one-pot, solvent-based recycling approach yields neat recycled products without the use of solvent evaporation or solute precipitation, and the functional utility of the resulting polymer blends greatly exceeds that of either homopolymer alone.Type: ApplicationFiled: March 11, 2014Publication date: October 9, 2014Applicant: POLY6 TECHNOLOGIES,INC.Inventor: Keith Hearon
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Patent number: 8852707Abstract: Provided is a PAS resin composition with which molded articles having excellent high- and low-temperature impact properties can be obtained and which can be highly inhibited from leaving mold deposits when molded and is suitable for use in insert molding. Also provided is an insert-molded article obtained using the resin composition. The PAS-derived resin composition comprises a PAS resin having carboxylic terminal groups and an olefin-derived copolymer, wherein the olefin-derived copolymer comprises units of an ?-olefin, a glycidyl ester of an ?,?-unsaturated acid, and an acrylic ester as comonomer units, the PAS resin has a number average molecular weight of 1,000-10,000, and the content of the comonomer units derived from the glycidyl ester in the resin composition is 0.08-0.20 mass %, the ratio of the content of the comonomer units derived from the glycidyl ester (mmol/kg) to the amount of the carboxylic terminal groups (mmol/kg) being 0.35-1.00.Type: GrantFiled: December 2, 2010Date of Patent: October 7, 2014Assignee: Polyplastics Co., Ltd.Inventors: Raita Nishikawa, Tatsuya Kanezuka, Hiroki Arai, Yoshihito Fukasawa
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Patent number: 8846811Abstract: A dual catalyst system comprising a phosphinimine ligand containing catalyst and phenoxide ligand (preferably a salicylaldimine) on a support treated with a metal salt has improved reactor continuity in a dispersed phase reaction in terms of initial activation and subsequent deactivation The resulting catalyst has a lower consumption of ethylene during initiation and a lower rate of deactivation. Preferably the catalyst is used with an antistatic agent.Type: GrantFiled: March 26, 2012Date of Patent: September 30, 2014Assignee: Nova Chemicals (International) S.A.Inventors: Lee Douglas Henderson, Peter Phung Minh Hoang, Ian Ronald Jobe, Xiaoliang Gao
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Patent number: 8809455Abstract: A dynamically vulcanized alloy contains at least one isobutylene-containing elastomer and at least one thermoplastic resin, wherein the elastomer is present as a dispersed phase of small vulcanized or partially vulcanized particles in a continuous phase of the thermoplastic resin. The dynamically vulcanized alloy also contains an anhydride functionalized oligomer. The alloy maintains a high Shore A hardness value while obtaining improved flowability for processing.Type: GrantFiled: August 27, 2009Date of Patent: August 19, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: Maria D. Ellul, Anthony Jay Dias, Rodney May
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Publication number: 20140226256Abstract: A dielectric resin composition for a film capacitor is a mixture containing an organic material A and an organic material B. The organic material A includes at least two kinds of organic material components A1, A2, . . . having reactive groups (for example, OH, NCO) that cross-link each other. The organic material B does not have a reactive site capable of reacting with the organic material A and has a dielectric loss tan ? of 0.3% or less at a temperature of 125° C. The mixture has a glass transition temperature of 130° C. or higher and preferably 280° C. or lower.Type: ApplicationFiled: April 17, 2014Publication date: August 14, 2014Applicant: MURATA MANUFACTURING CO., LTD.Inventors: Tomomichi Ichikawa, Norihiro Yoshikawa, Ichiro Nakamura, Shinichi Kobayashi, Ichiro Nakaso, Yasunori Hioki, Tomoki Inakura
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Patent number: 8784711Abstract: The invention relates to a process for preparing a reinforced and reactive thermoplastic composition having a continuous phase which is based on at least one thermoplastic polymer and dispersed in which is a discontinuous phase based on at least one reactive reinforcing agent that may be immiscible with said at least one thermoplastic polymer, and also to a composition obtained by this process.Type: GrantFiled: August 2, 2011Date of Patent: July 22, 2014Assignee: HutchinsonInventors: Nicolas Garois, Philippe Sonntag, Grégory Martin, Matthieu Vatan, Jacques Drouvroy
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Patent number: 8748538Abstract: Graft copolymers of hydrophobic polymers and hydrophilic polymers, a method for their preparation, and their use in membranes for medical treatments such as hemodialysis, hemodiafiltration and hemofiltration, in membranes for water purification, and in membranes for bioprocessing.Type: GrantFiled: March 9, 2011Date of Patent: June 10, 2014Assignee: Gambro Lundia ABInventors: Bernd Krause, Hermann Goehl, Markus Storr, Ralf Menda, Hans-Georg Herz, Joerg Williardt
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Patent number: 8629213Abstract: The invention relates to a composition including at least one elastomer and at least one supramolecular polymer. The supramolecular polymer is obtained by the reaction of at least one trifunctional compound (A), having first and second functions, with: at least one compound (B) having at least one reactive group capable of reacting with the first functions of (A) and at least one associative group; and at least one at least bifunctional compound (C) having functions capable of reacting with the second functions of compound (A) in order to form ester, thioester and amide bridges.Type: GrantFiled: September 21, 2010Date of Patent: January 14, 2014Assignee: Arkema FranceInventors: Manuel Hidalgo, Christelle Plaut, Alfredo Defrancisci
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Patent number: 8623967Abstract: A method for preparing a functionalized polymer, the method comprising the steps of: (i) polymerizing monomer with a coordination catalyst to form a reactive polymer; and (ii) reacting the reactive polymer with a nitroso compound.Type: GrantFiled: May 14, 2012Date of Patent: January 7, 2014Assignee: Bridgestone CorporationInventor: Steven Luo
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Patent number: 8603599Abstract: There are provided, according to the present invention, a resin composition for hollow blow-molded article which is obtained in a high productivity on an industrial scale with excellent moldability and drawdown resistance, and the production method thereof, by melting and mixing a polyarylene sulfide resin including a terminal carboxyl group within the resin in an amount of 25 to 45 (?mol/g), and having a non-Newtonian index of 0.90 to 1.15 and also a melt viscosity as measured at 300° C. within the range of 1,000 poise to 3,000 poise and an epoxy group-containing polyolefin so that the proportion of the epoxy group-containing polyolefin is 5 to 30 parts by mass with respect to 100 parts by mass of the polyarylene sulfide resin; and a hollow blow-molded article with excellent mechanical strength, such as the heat resistance and impact resistance, and surface appearance, and the production method thereof.Type: GrantFiled: May 24, 2011Date of Patent: December 10, 2013Assignee: DIC CorporationInventors: Shingo Matsuo, Toshio Hinokimori
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Publication number: 20130323121Abstract: A compound suitable for hydroclaving is disclosed, comprising polyester, polysulfone, and an epoxy-functional styrene-acrylate oligomer. In order for successful repetitious hydroclaving to be possible, the compound must also have a polysulfone content of greater than 45 weight percent of the compound.Type: ApplicationFiled: February 21, 2012Publication date: December 5, 2013Applicant: POLYONE CORPORATIONInventors: Jing Liu, Rahul Bhardwaj
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Patent number: 8586673Abstract: Polymer composition (C) containing (i) a poly(aryl ether sulfone) material (M12) composed of a poly(biphenyl ether sulfone) (P1) and, optionally in addition, a poly(aryl ether sulfone) (P2) containing recurring units with arylene groups linked to each other via a secondary, ternary or quaternary carbon atom, and (ii) a per(halo)fluoropolymer material (M34), composed of a per(halo)fluoropolymer (P3) of which at least 2.0 wt. % of the recurring units are derived from a per(halo)fluoromonomer other than tetrafluoroethylene, and a polytetrafluoroethylene (P4). Shaped article, especially aircraft interior component, comprising the polymer composition (C).Type: GrantFiled: May 7, 2009Date of Patent: November 19, 2013Assignee: Solvay Advanced Polymers, L.L.C.Inventor: Shari A. Weinberg
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Publication number: 20130273290Abstract: Polyarylene sulfide compositions are described that exhibit high strength and flexibility. Methods for forming the polyarylene sulfide compositions are also described. Formation methods include dynamic vulcanization of a polyarylene sulfide composition that includes an impact modifier dispersed throughout the polyarylene sulfide. A crosslinking agent is combined with the other components of the composition following dispersal of the impact modifier throughout the composition. The crosslinking agent reacts with the impact modifier to form crosslinks within and among the polymer chains of the impact modifier. The compositions can exhibit excellent physical characteristics at extreme temperatures and can be used to form, e.g., tubular member such as pipes and hoses and fibers.Type: ApplicationFiled: March 14, 2013Publication date: October 17, 2013Inventors: Rong Luo, Joseph J. Grenci, Christopher McGrady, Xinyu Zhao
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Publication number: 20130273288Abstract: Flowlines for use in oil and gas applications are described. The flowlines include a barrier layer that includes polyarylene sulfide composition that exhibits high strength and flexibility characteristics. Methods for forming the flowlines are also described. Formation methods include dynamic vulcanization of a polyarylene sulfide composition that includes an impact modifier dispersed throughout the polyarylene sulfide. A crosslinking agent is combined with the other components of the composition following dispersal of the impact modifier throughout the composition. The flowlines can include production fluid flowlines, supporting fluid flowlines, bundled flowlines, etc. and can be utilized as risers, pipelines, jumpers, and the like.Type: ApplicationFiled: March 14, 2013Publication date: October 17, 2013Applicant: TICONA LLCInventors: Rong Luo, Xinyu Zhao
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Publication number: 20130273799Abstract: Polyarylene sulfide fibers and products that incorporate the polyarylene sulfide fibers are described as are methods of forming the fibers and products. The polyarylene sulfide fibers can incorporate a reactively functionalized polyarylene sulfide that can provide improved compatibility between the polyarylene sulfide and other materials, including both additives to the polyarylene sulfide composition that is used to form the fibers and external materials that may be located adjacent to the fibers in a composite.Type: ApplicationFiled: March 13, 2013Publication date: October 17, 2013Applicant: Ticona LLCInventors: Rong Luo, Xinyu Zhao
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Publication number: 20130273286Abstract: Components for heavy duty trucks are described that exhibit high strength and flexibility. The components are formed from a polyarylene sulfide that exhibits high strength and flexibility characteristics. Methods for forming the components are also described. Formation methods include dynamic vulcanization of a polyarylene sulfide composition that includes an impact modifier dispersed throughout the polyarylene sulfide. A crosslinking agent is combined with the other components of the composition following dispersal of the impact modifier throughout the composition. The heavy duty truck components can include tubular member such as pipes and hoses that can be utilized in exhaust systems, charge air systems, urea tanks, fuel systems, and so forth.Type: ApplicationFiled: March 14, 2013Publication date: October 17, 2013Applicant: Ticona LLCInventors: Rong Luo, Xinyu Zhao
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Publication number: 20130260071Abstract: This application discloses the use of polyamide-polydiene blends to improve the oxygen reactivity in the presence of ionic polyester compatibilizers.Type: ApplicationFiled: March 14, 2013Publication date: October 3, 2013Applicant: M&G USA CORPORATIONInventors: Ricardo Knudsen, Jeffrey D. Black
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Patent number: 8530576Abstract: The present invention provides a thermoplastic resin composition comprising a polysulfone (A) having oxygen-containing groups selected from among hydroxyl groups and oxyanion groups, a fluororesin (B) and a thermoplastic resin (C) other than the polysulfone (A) and the fluororesin (B). The composition has high slidability. By molding the composition, a molded article with high slidability can be obtained.Type: GrantFiled: February 24, 2011Date of Patent: September 10, 2013Assignee: Sumitomo Chemical Company, LimitedInventors: Hirokazu Matsui, Hiroshi Harada
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Publication number: 20130137784Abstract: Graft copolymers of hydrophobic polymers and hydrophilic polymers, a method for their preparation, and their use in membranes for medical treatments such as hemodialysis, hemodiafiltration and hemofiltration, in membranes for water purification, and in membranes for bioprocessing.Type: ApplicationFiled: March 9, 2011Publication date: May 30, 2013Applicant: GAMBRO LUNDIA ABInventors: Bernd Krause, Hermann Goehl, Markus Storr, Ralf Menda, Hans-Georg Herz, Joerg Williardt
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Patent number: 8436091Abstract: Through the use of an improved iron-based redox system it is possible to prepare special new, optionally hydrogenated, nitrile rubbers which feature a more uniform monomer distribution and a lower fraction of long-chain branches and hence are distinguished by enhanced flow properties at the same time as very good properties on processing.Type: GrantFiled: October 15, 2010Date of Patent: May 7, 2013Assignee: LANXESS Deutschland GmbHInventors: Sven Brandau, Hans Magg, Michael Klimpel
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Patent number: 8431679Abstract: A polyphenylene sulfide resin coated article comprising: a molded article (A) of a polyphenylene sulfide resin material (a) which comprises a polyphenylene sulfide resin (a1), and a coated film layer (B) which is formed by applying a coating which comprises as a solid component a chlorinated polyolefin resin (b1) having a chlorine atom content of 20 to 45% by mass on the surface of the molded article (A).Type: GrantFiled: June 28, 2006Date of Patent: April 30, 2013Assignees: DIC Corporation, Origin Electric Company, LimitedInventors: Shifumi Aizawa, Taku Shimaya, Keizo Okabe, Tomohiro Nagano
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Publication number: 20130079469Abstract: A copolymer containing, in addition to recurring elements of a sulfonated poly(arylene) containing exclusively recurring structural element(s) of the general formulas —[—Ar1(SO3M)n-X—]— and —[—Ar2(SO3M)n-Y—]—, wherein X and Y, which are identical or different from each other, each represent an electron-acceptor group, Ar1 and Ar2, which are either identical or different from each other, represent an aromatic or heteroaromatic ring system with 5-18 ring atoms; wherein the aromatic or heteroaromatic ring system, in addition to the SO3M and the substituents X and Y, optionally comprises additional substituents which are not electron-donor groups; M represents monovalent cation and n is an integral number between 1 and 4; and wherein X, Y, Ar1, Ar2, M and n can be identical or different in various structural elements, independently of each other, one or several additional elements of at least one additional monomer or macromonomer.Type: ApplicationFiled: November 16, 2012Publication date: March 28, 2013Applicant: Max-Planck-Gesellschaft zur Forderung der Wissenschaften e V.Inventor: Max-Planck-Gesellschaft zur Forderung der Wisse
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Publication number: 20130059976Abstract: There are provided, according to the present invention, a resin composition for hollow blow-molded article which is obtained in a high productivity on an industrial scale with excellent moldability and drawdown resistance, and the production method thereof, by melting and mixing a polyarylene sulfide resin including a terminal carboxyl group within the resin in an amount of 25 to 45 (?mol/g), and having a non-Newtonian index of 0.90 to 1.15 and also a melt viscosity as measured at 300° C. within the range of 1,000 poise to 3,000 poise and an epoxy group-containing polyolefin so that the proportion of the epoxy group-containing polyolefin is 5 to 30 parts by mass with respect to 100 parts by mass of the polyarylene sulfide resin; and a hollow blow-molded article with excellent mechanical strength, such as the heat resistance and impact resistance, and surface appearance, and the production method thereof.Type: ApplicationFiled: May 24, 2011Publication date: March 7, 2013Applicant: DIC CORPORATIONInventors: Shingo Matsuo, Toshio Hinokimori
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Publication number: 20130012635Abstract: A thermoplastic material comprises the cure product of a thermoplastic polymer having a thermal decomposition temperature greater than or equal to about 200° C., the thermoplastic polymer being cured at a temperature of about 200° C. to about 400° C., for a total time of less than or equal to 200 hours. An article is formed from the thermoplastic material.Type: ApplicationFiled: July 8, 2011Publication date: January 10, 2013Applicant: BAKER HUGHES INCORPORATEDInventors: Jiaxiang Ren, David Peter Gerrard, James Edward Goodson, Lillian Guo, Ping Duan
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Publication number: 20120283351Abstract: A new process is provided for preparing nitrile rubbers by free-radical polymerization in an organic solvent and in the presence of specific modifier substances. This polymerization may be followed by hydrogenation to give likewise new hydrogenated nitrile rubbers, the hydrogenation advantageously taking place likewise in organic solvent. The optionally hydrogenated nitrile rubbers obtained are notable for having fragments of the employed modifier substances in the main polymer chain and/or as end groups. They can he prepared with a wide diversity of molecular weights and polydispersity indices, especially with very low polydispersity indices.Type: ApplicationFiled: August 31, 2010Publication date: November 8, 2012Applicant: LANXESS DEUTSCHLAND GMBHInventors: Michael Klimpel, Sven Brandau, Uwe Westeppe, Christopher Barner-Kowollik, Andreas Kaiser
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Publication number: 20120259070Abstract: A dual catalyst system comprising a phosphinimine ligand containing catalyst and phenoxide ligand (preferably a salicylaldimine) on a support treated with a metal salt has improved reactor continuity in a dispersed phase reaction in terms of initial activation and subsequent deactivation The resulting catalyst has a lower consumption of ethylene during initiation and a lower rate of deactivation. Preferably the catalyst is used with an antistatic agent.Type: ApplicationFiled: March 26, 2012Publication date: October 11, 2012Applicant: NOVA CHEMICALS (INTERNATIONAL) S.A.Inventors: Lee Douglas Henderson, Peter Phung Minh Hoang, Ian Ronald Jobe, Xiaoliang Gao
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Publication number: 20120237714Abstract: Provided is a PAS resin composition with which molded articles having excellent high- and low-temperature impact properties can be obtained and which can be highly inhibited from leaving mold deposits when molded and is suitable for use in insert molding. Also provided is an insert-molded article obtained using the resin composition. The PAS-derived resin composition comprises a PAS resin having carboxylic terminal groups and an olefin-derived copolymer, wherein the olefin-derived copolymer comprises units of an ?-olefin, a glycidyl ester of an ?,?-unsaturated acid, and an acrylic ester as comonomer units, the PAS resin has a number average molecular weight of 1,000-10,000, and the content of the comonomer units derived from the glycidyl ester in the resin composition is 0.08-0.20 mass %, the ratio of the amount of the carboxylic terminal groups (mmol/kg) and the content of the comonomer units derived from the glycidyl ester (mmol/kg) being 0.35-1.00.Type: ApplicationFiled: December 2, 2010Publication date: September 20, 2012Applicant: POLYPLASTICS CO., LTD.Inventors: Raita Nishikawa, Tatsuya Kanezuka, Hiroki Arai, Yoshihito Fukasawa
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Publication number: 20120211704Abstract: Flexible members for use in imaging devices comprise a polymerizable release agent.Type: ApplicationFiled: February 17, 2011Publication date: August 23, 2012Applicant: XEROX CORPORATIONInventors: Edward F. Grabowski, Yuhua Tong
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Publication number: 20120196983Abstract: A thermoplastic resin composition and a method of producing the thermoplastic resin composition are provided. The thermoplastic resin composition has an excellent balance of flexibility, heat resistance, and abrasion resistance, and has an excellent moldability. The method includes the steps of heating in which a heat-processed product is heated at a maximum heating temperature of 327° C. or higher, the heat-processed product being obtained by heat-processing a mixture containing the thermoplastic resin and the PTFE particles; and cooling in which the heat-processed product is cooled at a cooling speed of 10° C./min or slower to 293° C. from the maximum heating temperature after the step of heating.Type: ApplicationFiled: January 30, 2012Publication date: August 2, 2012Applicant: Olympus CorporationInventors: Naoyuki ONO, Hiroaki KASAI, Naohito SHIGA
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Patent number: 8227566Abstract: The present invention relates to polythiophenes, particularly regioregular head-to-tail poly(3-alkylthiophenes) (HT-PATs), block copolymers made therefrom, and their methods of formation. The present invention provides HT-PATs with well-defined, specific end-groups, functionalization of the defined HT-PATs, and incorporation of end group functionalized HT-PATs into block copolymers with structural polymers. The intrinsically conductive diblock and triblock copolymers, formed from the HT-PATs, have excellent conductivity and low polydispersities that are useful in a number of applications. The block copolymers of the present invention have been found to exhibit conductivities that range from a low of 10?8 S/cm for certain applications to as high as several hundred S/cm or more.Type: GrantFiled: March 23, 2005Date of Patent: July 24, 2012Assignee: Carnegie Mellon UniversityInventors: Richard D. McCullough, Jinsong Liu, Paul C. Ewbank, Elena E. Sheina
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Publication number: 20120178865Abstract: The invention provides a composition comprising at least the following: A) interpolymer comprising, in polymerized form, ethylene, an ?-olefm and a nonconjugated polyene; B) sulfur; C) at least one phase transfer catalyst (PTC) selected from the group consisting of the following: Formula (1), wherein each R group is, independently, an alky group having from 4 to 32 carbon atoms, and X is a halogen ion; Formula (2), Wherein the R group is an alky group having from 4 to 32, and X is a halogen ion; Formula (3), wherein R1 is the alky group having from 1 to 4 carbon atoms, R2 is an alkyl group having from 1 to 32 carbon atoms, and X is a halogen ion; and combinations of (1), (2) and (3); and D) at least one primary accelerator selected from the group consisting of the following: Formula (a), wherein R is H, or a heterocyclic substituent; Formula (b), wherein M is Zn2+, K+, Na+, Cu2+ or an alkyl ammonium; Formula (c), wherein R? and R? are each, independently, H, an alkyl, a cyclic alkyl, an aromatic, or a heterocType: ApplicationFiled: September 29, 2009Publication date: July 12, 2012Applicant: Dow Global Technologies LLCInventors: Yabin Sun, Gary R. Marchand, Xiang Yang Tai, Shuwen Peng, Shaoguang Feng
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Patent number: 8211979Abstract: A multicomponent system is provided, composed of a thermoplastic component and of a rubber component, which comprises at least two different peroxidic crosslinking agents with specific decomposition temperatures, as also is a process for production of rubber-thermoplastic composite mouldings using the multicomponent system, and also the resultant rubber-thermoplastic composite mouldings.Type: GrantFiled: December 15, 2006Date of Patent: July 3, 2012Assignee: LANXESS Deutschland GmbHInventors: Dirk Achten, Stefanie Nickel, Maik Schulte, Michael Münker, Detlev Joachimi
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Publication number: 20120157318Abstract: The present invention relates to the use of a branched addition copolymer in combination with a polymer in a solution or melt formulation to reduce the viscosity of the solution formulation and/or melt formulation compared to the viscosity of a solution and/or melt comprising the polymer alone wherein the branched addition copolymer is obtainable by an addition polymerisation process, methods for the preparation of the formulations, and novel branched addition copolymers for use as same.Type: ApplicationFiled: September 8, 2010Publication date: June 21, 2012Applicant: UNILEVER PLCInventors: Paul Hugh Findlay, Brodyck James Lachlan Royles, Roselyne Marie Andree Baudry, Neil John Simpson, Sharon Todd, Steven Paul Rannard
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Patent number: 8138278Abstract: A composition comprising a reaction product of reactants comprising (a) a compound comprising (i) a polysulfide moiety and (ii) an oxygen atom in a ?-position to a sulfur link having the formula: where each R is independently selected from H or a C1 to C20 organyl group, R? is independently selected from a C1 to C20 organyl group, R?? is independently selected from H or a C1 to C20 organyl group, and x has an average of greater than 2, (b) a compound comprising a nucleophilic moiety; and (c) a compound comprising a moiety reactive to active hydrogen.Type: GrantFiled: June 25, 2010Date of Patent: March 20, 2012Assignee: POLYMERight, Inc.Inventors: Leonid Rappoport, Alexander Vainer, Aleksander Yam