At Least One Reactant Which Forms Additional Polymer Contains A Sulfur Atom Patents (Class 525/189)
  • Patent number: 6127483
    Abstract: The invention relates to dispersion-powder compositions redispersible in water and containing (a) a vinyl ester ethylene copolymer with 50 to 90% by weight of vinyl esters of C.sub.2 to C.sub.12 carboxylic acid, 1 to 30% by weight of ethylene, 0-20% by weight of vinyl esters of .alpha.-branched monocarboxylic acids with 5 to 10 C-atoms, each in relation to the total weight of the vinyl ester ethylene copolymer, and (b) a water soluble copolymer with 20 to 80% by weight of hydrophobic, substantially water insoluble monomers, 20 to 80% by weight of water-soluble, salt-forming monomers from the group of ethylenically unsaturated sulfonic acids, and 0 to 50% by weight of ethylenically unsaturated monocarboxylic or dicarboxylic acids or the anhydrides thereof, each in relation to the total weight of the water soluble copolymer.
    Type: Grant
    Filed: June 15, 1998
    Date of Patent: October 3, 2000
    Assignee: Wacker-Chemie GmbH
    Inventors: Hans-Peter Weitzel, Peter Ball, Reiner Figge
  • Patent number: 6124408
    Abstract: A novel resin composite consists of a thermosetting resin or photosensitive resin and a thermoplastic resin and has a quasi-homogeneous compatible structure not only having properties inherent to the thermosetting or photosensitive resin but also exhibiting values of properties higher than those inherent to the thermoplastic resin.
    Type: Grant
    Filed: February 26, 1999
    Date of Patent: September 26, 2000
    Assignee: Ibiden Co., Ltd.
    Inventors: Dong Dong Wang, Motoo Asai
  • Patent number: 6124386
    Abstract: A composition which contains ETFE and PAS in a weight ratio of 5-95/5-95, and which further contains an organic onium compound in such a proportion that the weight ratio of the total amount of the above two component polymers and the organic onium compound is 80-99.99/0.01-20.
    Type: Grant
    Filed: February 18, 1999
    Date of Patent: September 26, 2000
    Assignee: Asahi Glass Company Ltd.
    Inventors: Masataka Yokota, Masao Umino
  • Patent number: 6087435
    Abstract: A polystyrene-based resin composition, comprising (A) a styrene-based resin with a mainly syndiotactic configuration, (B) a polyolefin, and (C) rubber polymer particles as main components, exhibits excellent heat resistance and impact resistance.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: July 11, 2000
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Akikazu Nakano, Takashi Sumitomo, Keisuke Funaki, Toshikazu Ijitsu, Michihiro Sawada, Masahiko Kuramoto, Masakazu Suzuki
  • Patent number: 6069202
    Abstract: Desirable thermoplastic vulcanizates can be prepared from a polar engineering thermoplastic; a halogenated copolymer of p-alkylstyrene and an isomonoolefin having from 4 to 7 carbon atoms; and either an ethylene rubbery polymer or a diene based rubbery polymer or combinations thereof. The ethylene rubbery polymer desirably has at least one pendant carboxylic acid group, amine group, epoxy group, hydroxyl group or an anhydride of two carboxylic acid groups or combinations thereof. Desirable diene based rubbery polymers include epoxidized natural rubber and epoxidized homopolymers and copolymers of dienes.
    Type: Grant
    Filed: December 10, 1997
    Date of Patent: May 30, 2000
    Assignee: Advanced Elastomer Systems, L.P.
    Inventors: Krishna Venkataswamy, Jacques Horrion
  • Patent number: 6057393
    Abstract: Disclosed herein is a sulfide polymer composition for a sliding member, comprising:3-40 wt % of polyethylene tetrafluoride having a three-dimensional network structure forming-ability,5-40 wt % of granulated polyethylene tetrafluoride having a number average molecular weight of from not less than 2,000 to less than 300,000,0.1-15 wt % of a phosphate(s), andthe balance of a sulfide polymer; anda sliding member obtained therefrom.
    Type: Grant
    Filed: September 12, 1994
    Date of Patent: May 2, 2000
    Assignee: Oiles Corporation
    Inventor: Kazuo Hirai
  • Patent number: 6054537
    Abstract: A thermoplastic resin composition comprising a blend obtainable by blending 0.1 to 99% by weight of (a) a fluorine-containing polymer having a number-average molecular weight of 2000 to 1000000 and having hydroxy group or epoxy group at least at one of end portions of a main chain and side chain of the polymer, and 1 to 99.9% by weight of (b) a heat resisting thermoplastic resin having a crystalline melting point or glass transition temperature of not less than 150.degree. C. The present invention can provide a composition comprising various heat resisting thermoplastic resins and a fluorine-containing polymer having a functional group which is capable of developing an affinity with said resins and forming a uniform dispersion.
    Type: Grant
    Filed: November 5, 1998
    Date of Patent: April 25, 2000
    Assignee: Daikin Industries, Ltd.
    Inventors: Tetsuo Shimizu, Yoshihisa Yamamoto, Seitaro Yamaguchi, Nobuhiko Tsuda, Noriyasu Yamane, Takafumi Yamato, Masahiro Kumegawa, Takayuki Araki
  • Patent number: 6051655
    Abstract: A composition amenable to injection molding and extrusion comprises a syndiotactic styrene resin, a thermoplastic resin such as a polyolefin and an inorganic filler optionally contains a rubber.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: April 18, 2000
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Akikazu Nakano, Takashi Sumitomo, Keisuke Funaki, Toshikazu Ijitsu, Michihiro Sawada, Masahiko Kuramoto, Masakazu Suzuki
  • Patent number: 6046285
    Abstract: Polymer blends obtainable by thermal treatment, at not less than 150.degree. C., of a mixture containing at least one high-performance polymer and from 15 to 99 parts by weight or preferably from 40 to 90 parts by weight and particularly preferably from 55 to 75 parts by weight, of a polymer containing sulfoxide groups, and crosslinked or partly crosslinked polymer blend obtainable by thermal treatment, at not less than 150.degree. C., of a mixture containing at least one of the high-performance polymers polyesters, partly fluorinated polymers, polyethersulfones, polysulfones, polyetherimides, polyamidoimides or polyacetals and at least one polymer containing sulfoxide groups, are distinguished by high thermal and chemical stability. Polymers containing sulfoxide groups are polyarylene sulfoxides, in particular polyphenylene sulfoxide. The polymer blends are used for the production of fibers, films or shaped articles.
    Type: Grant
    Filed: September 3, 1997
    Date of Patent: April 4, 2000
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Helmut Scheckenbach
  • Patent number: 6046275
    Abstract: A composition comprises (A) a syndiotactic styrene-based resin and (C) rubber polymer particles such as graft copolymers, butadiene or isoprene block copolymers optionally hydrogenated and/or modified with maleic anhydride, and other rubbers, and, optionally, (B) a thermoplastic resin such as a polycarbonate, and/or (D) a filler such as glass fibers.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: April 4, 2000
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Akikazu Nakano, Takashi Sumitomo, Keisuke Funaki, Toshikazu Ijitsu, Michihiro Sawada, Masahiko Kuramoto, Masakazu Suzuki
  • Patent number: 6025440
    Abstract: A blend of at least one fluorine polymer, at least one oxidized polyarylene sulfide, at least one polyarylene sulfide and, if required, conventional additives results in a reduction in the expulsion of the oxidized polyarylene sulfides in gaseous form in the production of shaped articles from this blend, so that no cracks occur in the shaped article and problem-free processing by a cutting method is permitted.
    Type: Grant
    Filed: December 18, 1997
    Date of Patent: February 15, 2000
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Helmut Scheckenbach, Gregor Buche
  • Patent number: 6025439
    Abstract: Molecular dispersions of rigid-rod polybenzobisazole polymer/copolymer in thermoplastic matrices in a weight ratio of about 1:99 to 50:50 are prepared by dissolving the rigid-rod polymer in an alcoholic or aprotic solvent, dissolving the thermoplastic polymer in an alcoholic or aprotic solvent, combining the two solutions and recovering the resulting molecular composite from the combined solution. These molecular dispersions consist essentially of rigid-rod polybenzobisazole polymer/copolymer having sulfonic acid groups pendant to the polymer/copolymer backbone and thermoplastic polymers selected from the group consisting of polyvinylpyridines, poly(arylene ether ketone)s with a pyridyl functionality, aromatic poly(pyridine ether)s and poly(pyridine ether sulfone) copolymers, and polyimides with a pyridyl functionality.
    Type: Grant
    Filed: July 30, 1998
    Date of Patent: February 15, 2000
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Fred E. Arnold, Narayanan Venkatasubramanian, Thuy D. Dang, Derrick R. Dean
  • Patent number: 6013727
    Abstract: A thermoplastic composition which may be unvulcanized or vulcanized is provided which comprises a polymer blend of an elastomeric thermoplastic engineering resin and a halogen-containing copolymer of a C.sub.4 to C.sub.7 isomonoolefin and a para-alkylstyrene. A process for preparing a dynamically vulcanized composition is also provided.
    Type: Grant
    Filed: January 31, 1991
    Date of Patent: January 11, 2000
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Narayanaswami Raja Dharmarajan, Robert Chester Puydak, Hsien Chang Wang, Kenneth William Powers, Thomas Chen-Chi Yu, Donald Ross Hazelton
  • Patent number: 6013719
    Abstract: Low melt viscosity polytetrafluorethylene (PTFE), i.e. having a melt viscosity of 50 to 1.times.10.sup.5 Pa.multidot.s at 372.degree. C., is combined with non-fluorinated thermally stable polymer such as polyarleneetherketone to provide melt-fabricability application for the low MV PTFE and provide improved properties for the thermally stable polymer.
    Type: Grant
    Filed: June 15, 1998
    Date of Patent: January 11, 2000
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Jacob Lahijani
  • Patent number: 5981662
    Abstract: The present invention relates to rubber compounds containing polymeric bis-succinimide polysulfides of the formula: ##STR1## wherein R is selected from the group consisting of phenylene and xylylene; R.sup.1 is selected from the group consisting hydrogen and alkyls having from 1 to 18 carbon atoms; x is an integer of from 2 to 8 and y is an integer of from 2 to 10.
    Type: Grant
    Filed: September 16, 1997
    Date of Patent: November 9, 1999
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Richard Michael D'Sidocky, Lawson Gibson Wideman
  • Patent number: 5977257
    Abstract: A high molecular material and a medical material which is a mixed material containing a copolymer A produced by copolymerization of a monomer composition containing a monomer having a side chain represented by the formula (1) ##STR1## (R.sup.1, R.sup.2, R.sup.3 ; H or a C1-4 alkyl group) and a hydrophobic monomer, and one or more sorts of hydrophobic polymer B other than the copolymer A; wherein structure of said mixed material shows phase separation in which domains of several hundred micrometers or less in size consisting of the copolymer A are uniformly distributed in a phase consisting of said hydrophobic polymer B. A liquid high molecular composition in which the copolymer A and the hydrophobic polymer B are dissolved in a mixed solvent consisting of a halogenated hydrocarbon solvent and a lower alcohol solvent, which has turbidity of 60% or less.
    Type: Grant
    Filed: October 28, 1997
    Date of Patent: November 2, 1999
    Assignees: NOF Corporation, Japan Science and Technology Corporation
    Inventors: Kazunori Waki, Daijiro Shiino, Kazuo Matsuyama, Nobuo Nakabayashi, Kazuhiko Ishihara
  • Patent number: 5969082
    Abstract: A novel polyalkyl ether/polyaryl ether sulfone or ketone copolymer and a specific polyether ester copolymer are useful for producing a medical material to be used to contact the blood; and methods for producing the medical material comprising said polyalkyl ether/polyaryl ether sulfone or ketone copolymer or a specific polyether ester copolymer.
    Type: Grant
    Filed: December 23, 1996
    Date of Patent: October 19, 1999
    Assignee: Teijin Limited
    Inventors: Hiroaki Kuwahara, Takeyuki Kawaguchi, Satoru Ohmori, Shunichi Matsumura
  • Patent number: 5891956
    Abstract: Water-soluble polymers including functionalization from the group of amino groups, carboxylic acid groups, phosphonic acid groups, phosphonic ester groups, acylpyrazolone groups, hydroxamic acid groups, aza crown ether groups, oxy crown ethers groups, guanidinium groups, amide groups, ester groups, aminodicarboxylic groups, permethylated polyvinylpyridine groups, permethylated amine groups, mercaptosuccinic acid groups, alkyl thiol groups, and N-alkylthiourea groups are disclosed.
    Type: Grant
    Filed: May 30, 1995
    Date of Patent: April 6, 1999
    Assignee: The Regents of the University of California, Office of Technology Transfer
    Inventors: Barbara F. Smith, Thomas W. Robison, Joel W. Gohdes
  • Patent number: 5885718
    Abstract: A treating agent comprises a nitrile group-containing highly saturated polymer rubber latex (A) having an iodine value of 120 or less, a rubber latex (B) other than the highly saturated polymer rubber latex, and a water-soluble resorcinol/formaldehyde condensate in amounts of 15 to 80%, 5 to 70% and 2 to 15%, all by weight in terms of solids, respectively. A rubber-reinforcing fiber product is coated with the treating agent. A rubber article such as a toothed belt, a tire and the like is made using this rubber-reinforcing fiber product. The glass fiber product coated with the treating agent may be further coated with a halogen-containing polymer-based adhesive as a secondary treating agent. Thus, the treating agent exhibits a large bonding force between the reinforcing fiber product and a matrix. Even if the rubber article is repeatedly subjected to a flexing stress, the strength thereof cannot be reduced. A peel-off cannot occurs between the reinforcing fiber product and the rubber matrix.
    Type: Grant
    Filed: January 31, 1996
    Date of Patent: March 23, 1999
    Assignee: Nippon Glass Fiber Co., Ltd.
    Inventors: Akira Okamura, Masato Sekiguchi
  • Patent number: 5872188
    Abstract: A rubber composition which is the vulcanization reaction product of a rubber, particular anti-reversion coagents, and a sulfide resin, is disclosed. The invention also relates to a vulcanization process which is carried out in the presence of an anti-reversion coagent and a sulfide resin and the use of an anti-reversion coagent in combination with sulfide resin in a process for the vulcanization of rubber. The resulting vulcanized rubbers have significantly improved physical properties.
    Type: Grant
    Filed: December 11, 1995
    Date of Patent: February 16, 1999
    Assignee: Akzo Nobel nv
    Inventors: Rabindra Nath Datta, Arie Jacob de Hoog, Johannes Hermanus Wilbrink
  • Patent number: 5869574
    Abstract: A thermoplastic resin composition comprising a blend obtainable by blending 0.1 to 99% by weight of (a) a fluorine-containing polymer having a number-average molecular weight of 2000 to 1000000 and having hydroxy group or epoxy group at least at one of end portions of a main chain and side chain of the polymer, and 1 to 99.9% by weight of (b) a heat resisting thermoplastic resin having a crystalline melting point or glass transition temperature of not less than 150.degree. C. The present invention can provide a composition comprising various heat resisting thermoplastic resins and a fluorine-containing polymer having a functional group which is capable of developing an affinity with said resins and forming a uniform dispersion.
    Type: Grant
    Filed: April 17, 1997
    Date of Patent: February 9, 1999
    Assignee: Daikin Industries, Ltd.
    Inventors: Tetsuo Shimizu, Yoshihisa Yamamoto, Seitaro Yamaguchi, Nobuhiko Tsuda, Noriyasu Yamane, Takafumi Yamato, Masahiro Kumegawa, Takayuki Araki
  • Patent number: 5864095
    Abstract: An abrasion-resistant fluoropolymer mixture comprising(A) from 75 to 99% by weight of a fluorocarbon polymer(B) from 1 to 25% by weight of an oxidized polyarylene sulfide and, based on the sum (A)+(B),(C) from 0 to 15% by weight of a filler,is used for the production of feed pipes for Bowden cables which are pressure-resistant and abrasion-resistant.
    Type: Grant
    Filed: December 11, 1997
    Date of Patent: January 26, 1999
    Assignee: Ticona GmbH
    Inventors: Helmut Scheckenbach, Andreas Schleicher, Jurgen Kulpe, Wolfgang Neumann, Bernd Jansen
  • Patent number: 5856403
    Abstract: A process for efficiently manufacturing polyarylene sulfide copolymer in which polymers are well dispersed and which copolymer exhibiting superior mechanical properties. The process comprises reacting a polyarylene sulfide resin (A) and an amination agent (B) in a non-protonic organic solvent (C), and copolymerizing the resulting amino polyarylene sulfide resin (A') and a reactive elastomer (D) in a non-protonic organic solvent (C'), thereby obtaining a polyarylene sulfide resin (A") with the elastomer dispersed in the resin matrix.
    Type: Grant
    Filed: May 30, 1996
    Date of Patent: January 5, 1999
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Minoru Senga, Koji Namiki
  • Patent number: 5840793
    Abstract: Disclosed are thermoplastic resin compositions having improved heat resistance, e.g., IR soldering and HDT; increased ductility and flowability; and reduced flash. In particular, the thermoplastic resin compositions have at least one high heat amorphous resin, at least one polysulfide; and, optionally, at least one reinforcing filler and/or at least one polyolefin and/or at least one polyolefin compound and/or at least one polyepoxy compound. The high heat amorphous resin is preferably a polyetherimide and the polyolefin is preferably a high crystalline polyethylene. The compositions of the invention are particularly well suited for preparing no flash high heat electrical connectors.
    Type: Grant
    Filed: August 9, 1994
    Date of Patent: November 24, 1998
    Assignee: General Electric Company
    Inventors: Raymond H. Glaser, Darryl Nazareth, Jerry Jan-nan Yang
  • Patent number: 5807941
    Abstract: An saturated nitrile-conjugated diene copolymer obtained by copolymerizing acrylonitrile with butadiene in the presence of a free radical initiator and an alkylthiol compound as a molecular weight modifier. A part of the molecular weight modifier is incorporated in a monomer charge before polymerization, and the remainder thereof is incorporated in a polymerization mixture during polymerization. The alkylthiol compound has 12 to 16 carbon atoms, which include at least three tertiary carbon atoms, and further has a sulfur atom directly bound to at least one of the tertiary carbon atoms. The copolymer has a Mooney viscosity of 15 to 150 and contains 3 to 20 weight % of a fraction having a number average molecular weight of not larger than 35,000. The copolymer is used in combination with a sulfur-containing vulcanizer.
    Type: Grant
    Filed: February 28, 1997
    Date of Patent: September 15, 1998
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Suguru Tsuji, Yuichi Uchizono
  • Patent number: 5786422
    Abstract: A polyphenylene sulfide resin composition improved in the impact strength, toughness, high temperature resistance and solvent resistance properties is disclosed. The composition comprises(A) 60-99.5% by weight of a thermally cured polyphenylene sulfide material having a melt viscosity of 500-30,000 poises and which has been derived, by thermally curing, from a polyphenylene sulfide having a melt viscosity of 400 poises of higher and containing 0.05-5 mol % of amino groups on the basis of the phenylene sulfide repeating units, and(B) 40-0.5% by weight of a modified polyethylene material comprising at least one polyethylene onto which at least one unsaturated carboxylic acid and/or derivative thereof is graft-copolymerized in a proportion of 0.1-10% by weight of the total weight of said modified polyethylene material.
    Type: Grant
    Filed: February 10, 1992
    Date of Patent: July 28, 1998
    Assignee: Tosoh Corporation
    Inventors: Yosinobu Mizutani, Takeo Asakawa, Hiroshi Inoue, Toshikazu Kato
  • Patent number: 5756589
    Abstract: The present invention relates to a rubber composition containing substantial silica reinforcement and pneumatic tires having treads comprised of such rubber composition. The rubber composition comprises an elastomer, substantial silica reinforcement, optionally a minor amount of carbon black reinforcement, and a triblock copolymer of terminal hard styrene based segments and of internal diene based elastomer segments.
    Type: Grant
    Filed: September 19, 1996
    Date of Patent: May 26, 1998
    Assignee: Goodyear Tire & Rubber Company
    Inventors: Paul Harry Sandstrom, David John Zanzig, Mark Samuel Sinsky
  • Patent number: 5753773
    Abstract: Multiphase block copolymers of propylene comprisinga) a polymer of propylene with from 0 to 5% by weight of further C.sub.2 -C.sub.10 1-alkenes,b) a copolymer of propylene with from 5 to 98% by weight of further C.sub.2 -C.sub.10 1-alkenes,the multiphase block copolymers having a melting point of less than 155.degree. C. and a stiffness (shear modulus G) conforming to the following condition (I): ##EQU1## where M.sub.a) denotes the amount of propylene polymer a) and M.sub.co denotes the amount of the multiphase block copolymer.are obtainable in particular by polymerization by means of metallocene-containing catalyst systems.
    Type: Grant
    Filed: November 9, 1995
    Date of Patent: May 19, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Franz Langhauser, Juergen Kerth, Patrik Mueller, Meinolf Kersting, Guenther Schweier
  • Patent number: 5750221
    Abstract: An abrasion-resistant fluoropolymer mixture comprising(A) from 75 to 99% by weight of a fluorocarbon polymer(B) from 1 to 25% by weight of an oxidized polyarylene sulfide and, based on the sum (A)+(B),(C) from 0 to 15% by weight of a filler,is used for the production of feed pipes for Bowden cables which are pressure-resistant and abrasion-resistant.
    Type: Grant
    Filed: March 26, 1997
    Date of Patent: May 12, 1998
    Assignee: Hoechst AG
    Inventors: Helmut Scheckenbach, Andreas Schleicher, Jurgen Kulpe, Wolfgang Neumann, Bernd Jansen
  • Patent number: 5750626
    Abstract: A thermoplastic resin composition comprising a blend obtainable by blending 0.1 to 99% by weight of (a) a fluorine-containing polymer having a number-average molecular weight of 2000 to 1000000 and having hydroxy group or epoxy group at least at one of end portions of a main chain and side chain of the polymer, and 1 to 99.9% by weight of (b) a heat resisting thermoplastic resin having a crystalline melting point or glass transition temperature of not less than 150.degree. C. The present invention can provide a composition comprising various heat resisting thermoplastic resins and a fluorine-containing polymer having a functional group which is capable of developing an affinity with said resins and forming a uniform dispersion.
    Type: Grant
    Filed: August 9, 1994
    Date of Patent: May 12, 1998
    Assignee: Daikin Industries, Ltd.
    Inventors: Tetsuo Shimizu, Yoshihisa Yamamoto, Seitaro Yamaguchi, Nobuhiko Tsuda, Noriyasu Yamane, Takafumi Yamato, Masahiro Kumegawa, Takayuki Araki
  • Patent number: 5721282
    Abstract: Molding composition based on fluoropolymers and process for producing foam material therefromThe invention relates to a molding composition based on fluoropolymers which additionally contain from 1 to 50% by weight of at least one polymer containing sulfoxide groups. The polymer containing sulfoxide groups comprises, in particular, polyarylene sulfoxide units of the formula:--(--C.sub.6 H.sub.4 --SO--)--.
    Type: Grant
    Filed: November 2, 1995
    Date of Patent: February 24, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Axel Schonfeld, Andreas Schleicher, Georg Frank, Helmut Scheckenbach
  • Patent number: 5712315
    Abstract: In this invention a new form of polytetrafluoroethylene has been found to be compression moldable to provide strong molded articles. It is also useful as an additive or strength binder. The new form is a compression molding powder comprised of comminuted, sheared particles of expanded porous polytetrafluoroethylene, said particles having a nudular-microfibrillar structure of irregular shape, and a mean particle size between 5 and 500 micrometers, and having a coating of a thermoplastic fluoropolymer on at least a portion of the particle. By irregular shape is meant that the nodes and fibrils do not have an ordered arrangement. The bulk density is about 0.06 to 0.2 g/cc.
    Type: Grant
    Filed: October 18, 1995
    Date of Patent: January 27, 1998
    Assignee: W. L. Gore & Associates, Inc.
    Inventor: John W. Dolan
  • Patent number: 5710205
    Abstract: A wear-resistant solid fluoropolymer composition, e.g. of homo- and copolymers of tetrafluoroethylene (TFE), which has an extremely low coefficient of friction in dry sliding contact with metal, without the application of additional fluid lubricant, which composition comprises: a) a fluoropolymer, b) a poly(arylene sulphide) and c) another high aromatic polymer; and a process for preparing the foregoing solid fluoropolymer composition.
    Type: Grant
    Filed: March 19, 1996
    Date of Patent: January 20, 1998
    Assignee: Imperial Chemical Industries PLC
    Inventors: Mark Davies, Paul Martin Hatton
  • Patent number: 5708089
    Abstract: Mixtures of fluoropolymers and oxidized polyarylene sulfidesA polymer mixture ofA) at least one fluoropolymer in a proportion of from 50 to 99% by weight andB) at least one polyarylene sulfone or polyarylene compound containing at least two of the bridges --S--, --SO-- and --SO.sub.2 -- or a mixture of the two in a proportion of from 1 to 50% by weight,where the sum of components A) and B) is always 100% by weight.This mixture is used for the production of sliding bearings or gasket materials having a reduced tendency to creep and reduced abrasion.
    Type: Grant
    Filed: March 22, 1996
    Date of Patent: January 13, 1998
    Assignee: Hoecht AG
    Inventors: Helmut Scheckenbach, Andreas Schleicher, Jurgen Kulpe, Bernd Jansen
  • Patent number: 5703165
    Abstract: A method of achieving a novel superior dispersion of insoluble sulfur comprises mixing polysulfur while it is in the rubbery state with a diluent, such as rubber, to obtain a novel uniform dispersion of the sulfur in the diluent.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: December 30, 1997
    Assignees: Saynad Corporation, The Brands Family Illinois Limited Partnership
    Inventor: George B. Brands
  • Patent number: 5690873
    Abstract: The present invention provides a method of preparing polyarylene sulfide fibers, particularly polyphenylene sulfide fibers, comprising melt blowing a blend of polyarylene sulfide and a polyolefin, wherein the polyolefin is present in the blend in an amount of up to about 40% by weight of the total blend. The present invention also provides fibers, webs, and other products prepared in accordance with the present inventive method.
    Type: Grant
    Filed: February 8, 1996
    Date of Patent: November 25, 1997
    Assignee: Pall Corporation
    Inventors: Colin F. Harwood, Isaak Vasserman, Thomas C. Gsell
  • Patent number: 5683819
    Abstract: A composite comprised of a nitrile group-containing highly saturated copolymer rubber and a fibrous material, which copolymer rubber is a product obtained by hydrogenating the conjugated diene portion of an unsaturated nitrile-conjugated diene copolymer. The highly saturated copolymer rubber has an alkylthio group having 12 to 16 carbon atoms, which include at least three tertiary carbon atoms, and having a sulfur atom which is directly bound to at least one of the tertiary carbon atoms; and the copolymer rubber further has a Mooney viscosity of 15 to 200 and an iodine value not larger than 80. This composite is useful for a belt.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: November 4, 1997
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Osamu Mori, Mitsugu Ishihara, Motofumi Oyama
  • Patent number: 5684088
    Abstract: The present invention relates to a PPS resin composition comprising a matrix of the PPS which is filled with a PTFE powder baked at a temperature not less than a melting point thereof and having a number-average molecular weight of not less than 1.5 million or PTFE fine particles having an average particle size of 0.05 to 1 .mu.m and comprising a fibrillating core portion of a high molecular weight PTFE with a number-average molecular weight of not less than 1.5 million and a non-fibrillating shell portion of a low molecular weight PTFE so that a content thereof is 40 to 80% by weight in the composition, and also relates to a process for preparing said PPS resin composition, which is characterized in that melting and kneading are carried out at a temperature from a temperature of not less than a melting point of PPS to a temperature of not more lower than a melting point of a high molecular weight PTFE.
    Type: Grant
    Filed: March 29, 1995
    Date of Patent: November 4, 1997
    Assignee: Daikin Industries, Ltd.
    Inventors: Tsuyoshi Miyamori, Yoshihisa Yamamoto, Masami Kato, Masaji Komori, Tetsuo Shimizu
  • Patent number: 5681893
    Abstract: The invention relates to a polymer mixture comprising A) a polyarylene sulphide, B) an elastomeric polymer having reactive groups which are capable of reacting with the polyarylene sulphide, the polymer mixture moreover comprising as constituent C) a metal salt of a fatty acid having a melting temperature lower than the compounding temperature of the polymer mixture. The presence of the metal salt C contributes to an improvement of the mechanical properties, in particular the ductility.
    Type: Grant
    Filed: September 11, 1995
    Date of Patent: October 28, 1997
    Assignee: General Electric Company
    Inventors: Christian Maria Emile Bailly, Jeremy Paul Shaw, Chorng-Fure Robin Hwang
  • Patent number: 5670225
    Abstract: A uniaxially stretched multilayered film obtained by uniaxially stretching a laminated film at a stretch ratio of from 3 to 10 to form many closed fine voids in each layer, said laminated film comprising a base layer (A) made of a resin composition comprising resinous ingredients comprising from 50 to 90% by weight crystalline polyolefin (a) and from 50 to 10% by weight thermoplastic resin (b) having a lower melting point than the crystalline polyolefin (a) and an inorganic fine powder (c) in an amount of from 0 to 35% by weight based on the sum of the weight of the resinous ingredients and, formed on at least one side of said base layer (A), a surface layer (B) made of a resin composition comprising from 20 to 80% by weight inorganic fine powder (d) and from 80 to 20% by weight crystalline polyolefin (e), said uniaxially stretching being conducted at a temperature lower than the melting point of said crystalline polyolefin (a) and lower than the melting point of said crystalline polyolefin (e) but at a tempe
    Type: Grant
    Filed: November 21, 1995
    Date of Patent: September 23, 1997
    Assignee: Oji-Yuka Synthetic Paper Co., Ltd.
    Inventors: Masaaki Yamanaka, Masaki Shiina
  • Patent number: 5665825
    Abstract: A plain bearing is disclosed comprising a bearing layer bonded to a sintered metallic layer, which in turn is mounted on a backing plate. The bearing layer comprises a material formed from two interpenetrating networks, one of polytetrafluoroethylene and the other of polyphenylenesulphide. The percentage by volume of polyphenylenesulphide is between about 45% and about 55%.
    Type: Grant
    Filed: July 31, 1995
    Date of Patent: September 9, 1997
    Assignee: T&N Technology Limited
    Inventors: Glyndwr John Davies, Philip Moisey
  • Patent number: 5658960
    Abstract: In this invention a new form of polytetrafluoroethylene has been found to be compression moldable to provide strong molded articles. It is also useful as an additive or strength binder. The new form is a compression molding powder comprised of comminuted, sheared particles of expanded porous polytetrafluoroethylene, said particles having a modular-microfibrillar structure of irregular shape, and a mean particle size between 5 and 500 micrometers, and having a coating of a thermoplastic fluoropolymer on at least a portion of the particle. By irregular shape is meant that the nodes and fibrils do not have an ordered arrangement. The bulk density is about 0.06 to 0.2 g/cc.
    Type: Grant
    Filed: October 12, 1994
    Date of Patent: August 19, 1997
    Assignee: W.L. Gore & Associates, Inc.
    Inventor: John W. Dolan
  • Patent number: 5625002
    Abstract: Disclosed are a polyphenylene sulfide composition having excellent impact characteristics, melt flow characteristics and flexibility which comprises, as indispensable components, (A) a polyphenylene sulfide, (B) an epoxy group-containing olefinic polymer, and (C) at least one elastomer selected from ethylene/propylene copolymers, ethylene/butene copolymers, ethylene/propylene/diene copolymers, hydrogenated styrene/butadiene/styrene block copolymers, copolymers of ethylene with a monomer selected from acrylic acid, methacrylic acid and alkyl esters and metal salts thereof, and polyamide elastomers; and a shaped article made from the polyphenylene sulfide composition.
    Type: Grant
    Filed: March 27, 1995
    Date of Patent: April 29, 1997
    Assignee: Toray Industries, Inc.
    Inventors: Sho Kadoi, Norio Shimasaki, Kazuhiko Kobayashi, Katuya Ohno
  • Patent number: 5589544
    Abstract: The invention relates to a soft thermoplastic elastomeric composition having improved resistance to oil swell and compression set comprising a blend of an engineering thermoplastic resin, a cured rubber concentrate and optionally a compatibilizer and a method for its preparation. The invention further relates to the cured rubber concentrate, a method for its preparation and the use thereof.
    Type: Grant
    Filed: May 15, 1995
    Date of Patent: December 31, 1996
    Assignee: Advanced Elastomer Systems, L.P.
    Inventor: Jacques Horrion
  • Patent number: 5578679
    Abstract: The disclosure describes a flame-resisting resin composition comprising:(A) 90 to 99.5% by weight of a polyarylene sulfide; and(B) 0.5 to 10% by weight of a graft copolymer composed of an olefinic copolymer (a) having 30 to 59% by weight (based on the weight of said graft copolymer) of an .alpha.-olefin repeating unit and a glycidyl ester residue repeating unit of an .alpha.,.beta.-unsaturated mono-carboxylic acid, and at least one of polymers (b) having the repeating unit represented by the following formula (I):said olefinic copolymer (a) being branched or crosslinked with at least one of the polymers (b), ##STR1## wherein R represents a hydrogen atom or a lower alkyl group having from 1 to about 6 carbon atoms, X represents a benzyl group, --COOCH.sub.3, --COOC.sub.2 H.sub.5, --COOC.sub.4 H.sub.9, --COOCH.sub.2 CH(C.sub.2 H.sub.5)C.sub.4 H.sub.9, --CN, a phenyl group or a maleimide group.
    Type: Grant
    Filed: December 22, 1994
    Date of Patent: November 26, 1996
    Assignee: Kureha Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yasuhiro Suzuki, Masahito Tada
  • Patent number: 5556919
    Abstract: A rubber composition comprising (i) a nitrile group-containing highly saturated copolymer rubber, which is a product obtained by hydrogenating the conjugated diene portion of an unsaturated nitrile-conjugated diene copolymer, and (ii) an ethylene-.alpha.-olefin-non-conjugated diene copolymer rubber. The highly saturated copolymer rubber has an alkylthio group having 12 to 16 carbon atoms, which include at least three tertiary carbon atoms, and has a sulfur atom which is directly bound to at least one of the tertiary carbon atoms; and the highly saturated copolymer. rubber further has a Mooney viscosity of 15 to 200 and an iodine value not larger than 80.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: September 17, 1996
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Motofumi Oyama, Kazuyoshi Nakajima
  • Patent number: 5543465
    Abstract: A process for the production of hydrophilic membranes using at least one hydrophobic polymer and polyvinyl pyrrolidone as a hydrophilic polymer, membrane-forming shaping of the polymers and immobilization of the polyvinyl pyrrolidone is characterized in that the polyvinyl pyrrolidone is immobilized on and/or in the membrane by treatment with an aqueous solution of peroxodisulphate in a hot condition. The solution of peroxodisulphate is kept substantially free of oxygen during immobilization by degassing the solution. The membranes are used for hemodialysis, hemodiafiltration and hemofiltration of blood.
    Type: Grant
    Filed: December 30, 1994
    Date of Patent: August 6, 1996
    Assignee: Gambro Dialysatoren GmbH & Co.
    Inventors: Carl-Martin Bell, Manfred Pirner, Reinhold Buck, Hermann J. Gohl
  • Patent number: 5520849
    Abstract: New electrically conductive polymer compositions comprisei) an electrically conductive polymer a) of one or more oxidatively polymerizable aromatic compounds andii) a polymer d) having ammonium, phosphonium or sulfonium groups in the polymer chain(s).The polymer compositions comprising polymers a) and d) are prepared by oxidative polymerization of one or more aromatic compounds in the presence of a polymer b) having ammonium, phosphonium or sulfonium groups in the polymer chain(s) and containing a polydentate anionic complex which has a redox potential sufficient for enabling oxidative polymerization of the aromatic compounds. Said polymer b) which has a non-metallic anionic complex such as S.sub.2 O.sub.8.sup.2- is also novel.
    Type: Grant
    Filed: June 23, 1994
    Date of Patent: May 28, 1996
    Assignees: The Dow Chemical Company, Deborah C. Dulude
    Inventor: Jurgen Eiffler
  • Patent number: 5510412
    Abstract: A resinous soft magnetic composition is constituted by (a) 80-95 wt. % of a powdery soft magnetic material, and (b) 5-20 wt. % of a resin component comprising (1) 70-99.5 wt. % of a polyarylene sulfide resin, and (2) 0.5-30 wt. % of an ultrahigh-molecular weight polyethylene having a weight-average molecular weight of from about 4.times.10.sup.5 to about 7.times.10.sup.6. Because of the inclusion of the ultrahigh-molecular weight polyethylene, the magnetic composition is provided with an improved melt-flowability suitable for injection molding while retaining a sufficient soldering heat-resistance as represented by a freeness of a molded product thereof from cracking after dipping in a solder bath at about 260.degree. C. for 10 sec.
    Type: Grant
    Filed: February 22, 1994
    Date of Patent: April 23, 1996
    Assignee: Kureha Kagaku Kogyo Kabushiki Kaisha
    Inventors: Keiichiro Suzuki, Masahito Tada
  • Patent number: 5510457
    Abstract: A method for preparing a processable polyisothianaphthene polymer includes steps of dissolving an isothianaphthene monomer in a solvent and introducing therein an initiator to initiate a polymerization reaction to produce a precursor of poly(dihydroisothianaphthene), dissolving thoroughly the precursor of poly(dihydroisothianaphthene) in the solvent in an appropriate ratio to obtain a poly(dihydroisothianaphthene) solution, proceeding a dehydrogenation reaction for the poly(dihydroisothianaphthene) solution by introducing a dehydrogenation agent to obtain a polyisothianaphthene microgel solution, and terminating the dehydrogenation reaction by introducing an inhibitor. This invention offers a simple, feasible, and economical way to prepare a large-area film with uniform film thickness, excellent stability, and good electrochromic, conducting, and mechanical properties.
    Type: Grant
    Filed: April 24, 1995
    Date of Patent: April 23, 1996
    Assignee: National Science Council
    Inventors: Show-An Chen, Chin-Chang Lee